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By Leiting Yue, Peng Ren, Yu Shen, Zhihong Liu, Haibao Shao, Longgong Xia, Feng Yu

The Kennecott-Outotec Flash Converting technology has been proven as an advanced and mature process in 5 individual plants during the past 2 decades. High grade copper matte (65–72%) produced in the flash smelting, or other smelting technologies is granulated to 3-5mm granules in a water torrent, and further crushed to fine powder (≈50µm) and dried to contain less than 0.3% H2O. Oxygen enriched air, together with fine copper matte powder and lime flux are injected into the reaction shaft by a matte burner. The copper making and slag making reactions will happen in very short time and distance during the particle falling and settling. However, industrial practice has found negative effects caused by sodium contamination. Na is introduced in the copper matte granulating process, and appears as Na2SO4 on particle surface. When Na content was high, scaling problems in the boiler will be worse, and the processing air will be blocked by the growing accretion around the matte burner, and as-produced blister copper is always high in S and O. In this present study, an industrial matte sample was used in the experimental work. Na was introduced into the matte powder by Na2SO4 solution soaking. The burning behaviour of the doped copper matte powder has been investigated as a function of the impurity concentration and processing temperature. Morphology and composition of these samples explained how Na2SO4 converts and reacts in the oxidizing atmosphere, and how they or their converting species influence the burning behaviour of matte particles. Cross-sections of as-prepared samples were analyzed with SEM-EDS, and the reaction mechanism has been carefully interpreted. Results from the present study can benefit both academic and industrial people. INTRODUCTION "Flash Converting" technology was developed jointly by Kennecott Utah Copper Smelter and Outotec (Finland) OY in 1992. The first industrialization of the technology was in Utah Smelter in 1995. Since 2006, it has been successfully applied in Xiangguang Copper, Tongling Jinguan Copper Branch, Fangchengang Jinchuan Copper, and Ningde Southeast Copper. The technology has also been further developed in those smelters. At present, roughly 2 million tons blister copper is produced annually through the Kennecott-Outotec Flash Converting technology, accounting for more than 10% of global primary copper production. The technology has advantages of high efficiency, high sulfur capture rate, good in environmental issues, mature equipment supporting, high automatic control level, low comprehensive energy consumption and flexible connection with the smelting unit, which make the technology to be one of the best choices in investing a new large-scale copper smelter or updating an old copper project in the world.

Jan 1, 2019

By Dong-kil Lee

Field tests have been conducted to investigate the characteristics of flow and physical chemistry of acid mine drainage(AMD) in the Hwangji-Yuchang settling pond in south Korea. pH and ferrous concentration of AMD flowed in the settling pond is 6.79 and 25.5 mg/l, respectively. As a results, we found that the ferrous oxidation reacted strongly around the inlet of the pond and the distributions of physicochemical properties is depended on flow characteristics and ferrous oxidation rate of AMD.

May 1, 2011

"Classification is an important aspect of mineral processing plants and if not operated efficiently can compromise both the throughput and recovery of the circuit. This paper discusses the benefits that can be obtained by operating the classification section efficiently. Since classification in most of the mineral processing plants is carried out using either hydrocyclones or screens the case studies involving the two classifiers were used in the discussion. Studies where optimising the classification circuit lead to improvements in the performance of the overall plant were included to show the benefits of paying attention to this area that is usually neglected. The data from the mill-float mill float, SABC, and Single Stage SAG mill circuit case studies have shown that the circuit throughput can be increased throughputs without compromising recoveries by optimising the classification circuit. On plants where the ore can be liberated at coarser sizes the experimental results have shown that replacing hydrocyclones with high frequency screens can lead to improved plant throughput with no detrimental effect on recovery. The discussion has included information on design and operational considerations for plants that have or intend to use hydrocyclones or screens that could make the classification circuit more efficient.INTRODUCTIONComminution is the process in which particles are reduced in size mainly by crushing and grinding. In most mineral processing circuits comminution is carried out to liberate the valuable minerals prior to subjecting the ore to a recovery process were values are concentrated or extracted (Mainza, Evertsson, Benzer, Tavares, Powell, Rule, Plint, …, 2013). Comminution is an energy intensive process and is usually achieved in stages. It is common to have a classifier after each comminution stage. The process is carried out in stages to minimize energy usage and to improve the efficiency of the process in meeting product specifications. Although comminution circuits have been advancing classification has remained a key component of the comminution circuit design (Mainza et al., 2013). Mainza et al. (2013) summarised the role of classification in mineral processing circuit as: to allow material in the equipment that can promote high operational efficiency, to improve material handling in the circuit, to minimize overgrinding of material to reduce energy consumption, and to provide the best quality product to enter the next stage of processing. Classification stages are employed in comminution circuits to ensure that high throughputs are processed without compromising the product quality or to produce a fine product at relatively low energy. If neglected classification can have detrimental effects on plant performance."

Jan 1, 2016

By D. E. Parson, W. A. Morgan

This paper offers a brief review of current literature pertaining to vacuum degassing or vacuum casting of steel as practiced in the U.S.A., Germany and the U.S.S.R. The advantages of vacuum degassing of large forging ingots, heavy section casting, for the conversion of rimming bessemer steels to killed steel and for the production of transformer steels are discussed. Operating pressures, reduction in gas contents and improvements in hydrogen segregation, steel cleanliness and mechanical properties, obtained with the various techniques, are described. The paper includes a description of an experimental vacuum stream-droplet degassing unit and some preliminary results obtained at the Physical Metallurgy Division Research Laboratories Department of Mines and Technical Surveys, Ottawa on laboratory steel melts. Experimental 500 lb direct arc, basic melts have been spray cast into either ingot moulds or dry sand moulds, held inside a vacuum tank. Also 500 lb melts have been

Jan 1, 1961

By Esau Arinaitwe

The most extensively used methods and approaches for characterizing and selecting frothers for plant application are based on measurements in clean water in the absence of solids and without consideration of physicochemical factors that are known to influence the properties and behavior of practical flotation froths, and hence metallurgical performance. These factors include aquatic chemistry, collectors, modifiers, particle shape and size, and pH. Understanding interactions between these factors and the role and relevance that they play in characterizing frothers and froth zone properties will greatly aid in the frother selection and evaluation process. Such an understanding will also greatly enhance the ability to create frother solutions that are sufficiently robust to plant variability (such as mineralogical, comminution, operational, physical and chemical). This paper reports results of a “systems approach” study designed to probe ways in which physicochemical factors a) influence frothing and bubble size in 2- and 3-phase systems, and b) confound correlation of fundamental measurements with flotation outcome. The concepts and insights gleaned from fundamental frother studies, together with empirical laboratory flotation tests and a thorough understanding of plant needs and challenges were used to develop and implement customized frother formulation at a Cu-Mo flotation plant. Plant metallurgical data and qualitative assessment of froth zone properties showed that a frother formulation developed using the approach described here provided marked improvements in froth characteristics (mineralization, mobility, stability, persistence). These improvements resulted in better circuit control and significant performance advantages, such as improved coarse particle recovery, without detrimental downstream effects. INTRODUCTION Successful recovery of value minerals of sufficient grade via the flotation process requires selective manipulation of the value minerals to render them hydrophobic using collectors and modifiers. The hydrophobized minerals then attach to air bubbles and the mineral-bubble aggregates are selectively transported through the froth zone into the launder. Frothers play a critical role in froth formation and more importantly in achieving and maintaining desirable froth characteristics (for example, stability, mobility, persistence) that are essential in facilitating the selective transport and recovery of value minerals. Fundamentally, frothers contribute to the transient stability of thin liquid films and so aid in reducing bubble coalescence rates in the pulp and froth zones, thus maintaining the small bubbles required for efficient bubble-particle attachment. Invariably, the action of frothers at the liquid/gas interface in the pulp and froth zones impacts bubble stability, water and solids transport to the froth, which in turn impacts froth mobility, froth carrying capacity, and the concentrate grade. Consequently, selection and evaluation of frothers for flotation plants requires careful consideration of the frother type, though the choice is limited to only two main classes of compounds in terms of fundamental chemistry (short chain alcohols and polyglycols). Even with the selection of what is thought to be the best frother for a given application, practical knowledge of the froth zone and experience in controlling its properties is essential for maximizing metallurgical performance.

Jan 1, 2019

By T. P. R. de Jong, H. Harbeck

"This contribution reports recent mineral sorting experience and lists the opportunities of the newest generation of automatic sorters with a special focus on electromagnetic detection and Xray transmission. With the available sensor resolutions and actuator systems that are available today sorting of minerals down to 2 mm size and up to 250 mm lump size is technically feasible. In industry, ore as well as coal is still hand-picked and current automation potential only utilised in a handful of specific applications. Recently a number of technological developments took place that may increase sorting potential, save mill costs and lead to lower overall tonnage costs.They are:??High speed and high resolution sorting systems based on X-ray transmission imaging??High speed on-line image processing and further development of advanced data processing??Modular multi-sensor automatic sorting units (using one or more sensors such as colour, electromagnetic and X-ray in a single device)??Sensitive electromagnetic sensors for sorting based on differences in magnetic susceptibility and electric conductivityThe above enables compact dry separation, insensitive for moisture fluctuations and at high separation sharpness, as well as “electronic” high gradient magnetic separation for larger particles. Besides conventional X-ray transmission (XRT), dual-energy XRT (DE-XRT) is now being redesigned to meet the requirements of the mining industry. The mentioned technologies provide automatic dry separation of minerals and rock as alternative for conventional processing."

Jan 1, 2005

By A. P. Annan, C. Vaughan, J. L. Davis

"The increase in the price of gold in the last decade has led to a significant increase in placer gold exploration around the world. Placer deposits occur in depressions along ancient river and stream channels. In many instances these channels have been covered with materials from subsequent erosion or glacial activity. Use of high resolution geophysical techniques to map the bedrock and soil strata can improve the probability of finding the placer deposits. The buried bedrock surface is often the factor controlling deposition. Ground probing radar (GPR) and seismic sounding are complementary high resolution techniques which can be used to map bedrock topography and soil stratigraphy. Current radar instrumentation operates best in coarse grained soils. Penetration depths of up to 30 m have been attained, and stratigraphic horizons have been mapped with spatial resolutions of better than 0.5 m. Although its spatial resolution is considerably lower than radar, seismic refraction achieves superior penetration in electrically conductive environments such as clay and silt soils. The seismic refraction method thus proves to be complementary to the radar method. The seismic reflection technique is analogous to the radar method. Current seismic instrumentation and energy sources however, provide limited spatial resolution and do not permit the use of seismic reflection for reflecting horizons lying at depths of less than 20 m to 30 m.This paper discusses the use of both radar and seismic methods for placer exploration. The radar and seismic techniques, the field methods, equipment, and data displays are presented. Field examples illustrate the high resolution mapping capabilities of the techniques. The radar data agree very well with the borehole data, and in fact they sometimes detect subtle soil strata variations associated with changes of permeability that were not initially observed in the borehole logging. The radar method can give a continuous profile of water table and bedrock in sandy soils. Seismic soundings are necessary to differentiate between the bedrock and water table reflections observed by the radar."

Jan 1, 1987

By Alan S. Lock

Large scale feasibility studies for the establishment of oil-seed and cellulose producing crops on mine tailings have been successfully conducted over 1 growing season with the purpose of these crops to be used as feedstock to the biofuels industry. An acid sulphide tailings impoundment in Copper Cliff, Ontario and a near neutral pH goldmine tailings impoundment in Timmins, Ontario were both tested by amending half hectare plots to approximately 1 m thick with residual biosolids from the pulp and paper industry and growing canola and corn on these plots. Full scale agricultural equipment was used to cultivate seed and harvest the plots to prove the full scale feasibility of farming on these biosolids. The vegetation development, growth, yield, quality and composition were assessed to identify the best species that would maximize biomass development for feedstock to the biofuels industry and carbon credits for the mining industry. Groundwater, biosolids and tailings chemistries were investigated to identify potential deleterious impacts of degrading organic matter on tailings metal mobility. Preliminary hydrologic investigations using moisture sensor profiles elucidate potential conservation of water in amended plots. Tailings amended with biosolids have the potential to provide the mining industry with carbon credits and supply feedstock to this new industry while reclaiming brownfields to a new level, utilizing industrial and municipal organic waste material.

May 1, 2009

By W. Wallace

The aerospace industry celebrated 100 years of powered flight in 2003, and the remarkable achievements that have occurred during the past 100 years are in no small way due to major developments in materials. Modern alloys for airframes, engines and other major sub-systems have evolved through the intelligent application of new processing concepts involving melting, casting, hot and cold working, heat treatment and more recently vapour phase processing. Alloy design has evolved in parallel to allow maximum benefits to be achieved from these processing advances. However, the pace of development seems to be slowing and future gains are likely to be made by learning how to extract major value from aerospace assets. Understanding the modes of deterioration and establishing cost effective lifetimes by holistic life cycle management seem to be the way of the future. Extending component lifetimes by repair, rejuvenation and refurbishment are all viable possibilities and they offer great opportunities for Canada, which, traditionally, has been a major user of modern aerospace materials rather than a supplier. The challenges for metallurgist, physicists and engineers will be no less than in the past and should create new business opportunities for Canada. The scenario described above will be developed by calling upon examples drawn from the author's experience.

Jan 1, 2004

By V. Casaletto, L. Widdifield

"Equipment capable of higher production requires more sophisticated maintenance programs. Reduction in fleet size through use of modern technology requires higher utilization and greater availability.Caterpillar's maintenance control system program will display the capabilities of computer technology in a maintenance environment. Utilizing such resources will provide increased availability, lower inventory requirements, fewer last minute disasters, and lower cost per ton for maintenance. High production from premium quality equipment can only be realized by good planning and care, executed by maintenance and operating personnel acting cooperatively.IntroductionAccurate information is the key to accurate decision making. In today' s competitive industry, mines' teeter on the brink between profit and loss. Their survival will be predicated on their ability to retrieve, analyze, and formulate accurate information regarding the operating costs of mobile equipment. This paper deals with the impact of managing equipment operating costs and introduces a computerized control system designed for monitoring and controlling these costs.Caterpillar has produced several computerized modelling programs designed at taking the guesswork out of equipment selection and management. The most basic of these is Equipment Investment Analysis (E.LA.). This model compares two or more alternatives over the projected life of the machine. It deals with comparisons in the owning and operating costs of equipment, as well as, their productivity over a specified period of time.In order for a computer model to be credible as a decision making tool, it must be simple to use and the results measurable and accountable . Caterpillar has introduced several computer models to assist the industry in selecting and managing an equipment fleet. These programs allow the user to predict and monitor the operating costs and production capability of mobile equipment. They are often used in the machine selection process to select equipment which best suits a mine's long-term cost per tonne objectives. After the optimum selection is made, Caterpillar's Maintenance Control System provides an efficient management tool to monitor and verify the data used in the selection model."

Jan 1, 1992

By R. Bruce Ferguson

"IntroductionThe Beaverlodge Operation of Eldorado Nuclear Limited is a uranium property located near the north shore of Lake Athabasca about 7 miles from Uranium City, Saskatchewan.The mill is a 2000 tpd carbonate leach operation producing a high grade yellowcake concentrate.The Lamella Thickener was purchased to replace a 55 foot conventional unit which had deteriorated beyond repair. The cost of the unit was considerably lower than for a conventional unit, installation was much simpler and the unit is much more compact allowing it to be installed in the mill basement and be insulated completely.The unit was sized according to the results of tests performed both by the supplier and Beaverlodge engineering staff. The supplier guaranteed overflow clarities of less than 100 ppm suspended solids. The Lamella thickener was developed by A. Johnson Co. of Stockholm, Sweden, is manufactured under license by Parkson Corporation of Ft. Lauderdale, Florida and is distributed in Canada by A. Johnson Co. of Montreal."

Jan 1, 1975

By Dale Scott

"The Aggregate Resources Inventory Program was initiated 10 produce reports which assess the aggregate resources of municipalities designated under the Pits and Quarries Control ACI, 1971.Each report consists of three copies accompanied by a text. The text describes the local mineral aggregate resources, extractive activity and characteristics of the ""Selected Deposits"". The first map shows the known sand and gravel resources and their quality. The second map indicates selected sand and gravel resources of primary, secondary and tertiary significance. The third map indicates both bedrock resources and bedrock areas suitable f or extraction. These maps and the text are prepared in a formal suited for use by planning personnel.Recently, the Aggregate Resources Inventory Program has undergone evolutionary changes. New sources of data are being utilized in the inventory reports; in particular, detailed field assessment by inspecting, sampling, drilling and backhoe pitting. Liaison and joint assessment with district and regional Mineral Resources staff of the Ministry of Natural Resources, and personnel of the Ministry of Transportation and Communications, are key components of the Program.Twenty-two reports were available to the public as of December 1980, with a further thirty-six awaiting publication. Our present production rate is 3.5 reports per month. The reports appear to be well accepted by the municipalities and have proven effective in conserving prime aggregate resource areas.IntroductionThe urbanization of Southern Ontario has resulted in a major increase in the production of industrial minerals, such as sand, gravel, clay, shale, gypsum and stone, for use as cru shed aggregate, building stone, lime and cement.Although mineral aggregate deposits are plentiful in Southern Ontario, they are fixed-location, non-renewable resources. The potential for extractive development is usually greatest in urban fringe areas where land-use competition is extreme. Comprehensive planning and resource management strategies are required to make the best use of available resources, especially in those areas experiencing rapid development. Such strategies must be based on a sound knowledge of the total mineral aggregate resource base at both local and regional levels."

Jan 1, 1982

By Dale Scott

"The Aggregate Resources Inventory Program was initiated 10 produce reports which assess the aggregate resources of municipalities designated under the Pits and Quarries Control ACI, 1971.Each report consists of three copies accompanied by a text. The text describes the local mineral aggregate resources, extractive activity and characteristics of the ""Selected Deposits"". The first map shows the known sand and gravel resources and their quality. The second map indicates selected sand and gravel resources of primary, secondary and tertiary significance. The third map indicates both bedrock resources and bedrock areas suitable f or extraction. These maps and the text are prepared in a formal suited for use by planning personnel.Recently, the Aggregate Resources Inventory Program has undergone evolutionary changes. New sources of data are being utilized in the inventory reports; in particular, detailed field assessment by inspecting, sampling, drilling and backhoe pitting. Liaison and joint assessment with district and regional Mineral Resources staff of the Ministry of Natural Resources, and personnel of the Ministry of Transportation and Communications, are key components of the Program.Twenty-two reports were available to the public as of December 1980, with a further thirty-six awaiting publication. Our present production rate is 3.5 reports per month. The reports appear to be well accepted by the municipalities and have proven effective in conserving prime aggregate resource areas.IntroductionThe urbanization of Southern Ontario has resulted in a major increase in the production of industrial minerals, such as sand, gravel, clay, shale, gypsum and stone, for use as cru shed aggregate, building stone, lime and cement.Although mineral aggregate deposits are plentiful in Southern Ontario, they are fixed-location, non-renewable resources. The potential for extractive development is usually greatest in urban fringe areas where land-use competition is extreme. Comprehensive planning and resource management strategies are required to make the best use of available resources, especially in those areas experiencing rapid development. Such strategies must be based on a sound knowledge of the total mineral aggregate resource base at both local and regional levels."

Jan 1, 1982

By Henry Hengeveld

Are the IPCC results credible? The most recent IPCC assessment is??an admirable summary of research activities in climate science? US National Academy of Science 2001 report to President Bush Joint statement by Academies of Science from 17 other countries ? May 2001 ?The work of the?IPCC represents the consensus of the international science community on climate change science. We recognize IPCC as the world?s most reliable source of information?and endorse its method of achieving this consensus.?

Nov 1, 2002

By Andrew R. Marchbank

The application of biologically assisted methods for metal extraction in the mining industry has a long history, but development of modern techniques has been relatively slow. There is, however, a resurgence of interest in the industry with the recent development of methods to successfully treat base metals concentrates. Two major pilot plant programs for treatment of chalcopyrite concentrates have been initiated in the past year and results from one are beginning to be released. This paper provides an overview of methods that have been applied in the past; from the earliest deliberate applications of the technology, through the copper and uranium heap and dump leach applications, the more highly engineered agitated tank leach gold applications and the developments currently taking place in the industry.

May 1, 2002

By D. Duffy, V. Papangelakis

"MgCl2 brines present a number of potential advantages for the processing of saprolite ores for nickel production. With a chloride system it is economically requisite to recover hydrochloric acid, which can be performed in a more energy efficient manner by precipitation and subsequent decomposition, as compared with conventional pyrohydrolysis. In addition, concentrated MgCl2 solutions enhance the activity of acid used, allow atmospheric leaching at elevated temperature and inhibit magnesium dissolution, which reduces acid consumption and increases metal selectivity. Leaching and iron control experiments have been conducted in concentrated MgCl2 brines, up to 4.5 m, to determine the most amenable process conditions. INTRODUCTIONChloride metallurgy has received an increasing amount of attention in recent years, especially with respect to the treatment of nickel laterites. Although the limonitic fraction can sometimes be economically treated by High Pressure Acid Leaching (HPAL), acid-consumption problems are encountered with the higher magnesium content of the saprolite fraction. As magnesium does not hydrolyze under HPAL conditions, as iron and aluminum do, any sulphuric acid used to leach magnesium is subsequently neutralized and wasted. In addition, this magnesium must later be disposed of in some fashion, further complicating the process. The most common method used to process saprolite is the Rotary Kiln-Electric Furnace (RKEF). This uses a kiln to dry and preferentially reduce nickel, before sending the calcine to an electric furnace. Although nickel recoveries are high, and the problems of acid consumption are avoided, the capital and energy costs associated with this process are high (de Bakker, 2011).The problems outlined above have led to the investigation of an atmospheric chloride process for the treatment of saprolite ores. The use of a chloride system presents a number of advantages, but also a few limitations. Metal chlorides tend to be very soluble, with a few notable exceptions (silver, mercury and lead), allowing for smaller processing equipment through more concentrated solutions. This solubility also serves to reduce the potential for scale formation. In addition, a hydrochloric acid leach is more aggressive than a comparable sulphuric acid system, and the activity of the hydrogen ion can be augmented by further chloride addition (Peek, 2011). This activity augmentation in concentrated chloride systems, first reported by Jansz, has repeatedly been referenced as a motivating factor behind chloride hydrometallurgy (Jansz, 1983; Harris and Magee, 2003; Harris et al., 2004; Demopoulos et al., 2008; McDonald and Whittington, 2008; Demopoulos, 2011; Peek, 2011; Verhulst and Lakshmanan, 2011). This activity increase allows a similar amount of acid to perform more in a concentrated solution than in a dilute solution, decreasing overall acid requirements. As such, much focus has been placed on leaching in concentrated chloride systems, or brines, using calcium, magnesium or sodium as the cation (McDonald and Whittington, 2008)."

Jan 1, 2012

By James A. Finch

"I offer a personal view of what the next 30 years holds for mineral processing. Re-stating that mineral processing will remain a vibrant industry in raw material production, growth opportunities in waste management are identified. The processing sequence familiar now (mining -mineral processing -extraction) will become more interwoven. In situ processing (i.e., milling underground) will evolve from concept to demonstration. Opportunities to exploit physical properties altered in chemical (pyro-and hydro-) processing will present themselves. In primary grinding, the path to AG/SAG milling will progress with little deviation but opportunities in regrinding are wide open. Flotation will see the trend to designing bubble/particle reactors accelerate simultaneously with a vigorous response from mechanical cell suppliers. Gravity separation remains a bastion of the lone inventor but I anticipate that the new lines will come from the waste management business. I finish by examining the ""research cycle"", identifying growth in small ""high tech"" companies and university research centres.IntroductionI have been asked to offer a personal view of""where we are going in mineral processing?"". Gazing into crystal balls is quite a cottage industry as we approach the end of the millennium. Academics are often asked to assume the role of visionary, I presume because it is considered in their mandate, to reflect and philosophize (or, less charitably, because they are considered to have the time). Since this is the 30th Annual Canadian Mineral Processors Operators Conference, I am tempted to suggest the next 30 years as my frame of reference. This is about equivalent to one engineer's career or, given it takes typically 15 years to go from concept to realization in mineral process engineering (Napier-Munn, l 997a), about 2 ""invention cycles"". With this length of cycle, much that is familiar now will remain so over the 30 years.Research and development (R&D) is in response to need. The overarching need in mining is to find new ore bodies. Process developments cannot compensate for a depleting deposit or a declining commodity price. Mineral processing R&D is characterized by incremental gains, aimed at pushing the mine down the cost per tonne league table. Breakthroughs are the exception (flotation at the turn of the century was one). This must be kept in mind when trying to predict the future in our business."

Jan 1, 1998

By R. G. L. McCready, Marco Zentilli

"Brogan coal containing mean averages of 6,93% w/w total sulphur (1.1% sulphate sulphur, 1.6% organic sulphur and 4.24% pyritic sulphur) and 16.34% mineral ash was used as the test coal in these studies.Shake-culture leaching studies on seven size fractions of the coal, ranging in size from 0.045 mm to 1.7 mm, showed that the rate of pyrite leaching was inversely proportional to the particle size. As the use of continuous stirred tank reactors would be uneconomical for the reclamation of waste coal, column leaching studies were initiated on coal sieved to >6.35 mm to < 12.7 mm, The leachate was monitored for all metal ions and the release of iron was used to monitor the rate of pyrite oxidation . Measurable amounts of Zn, Co, Ni, Mn, and V, all of which can replace iron in the pyrite crystal structure, were released during the initial stages of leaching. Further, high concentrations of AI, Ca and Sr and trace amounts of Sn, As. Se, B, Ca, Cr, Si, and Ti were detected in the column effluents.These studies suggest that bacterial leaching will remove the pyrite and qualitative amounts of environmentally undesirable trace metals from the coal if such a process is developed for waste coal reclamation.IntroductionIn 1947, Colmer and Hinkle showed that acid mine drainage was the result of an oxidative attack of the iron-mineral sulphides by Thiobacillus ferrooxidans to produce sulphuric acid . Ashmead (1955) proposed the use of these organisms to desulphurize coal , but the subsequent research effort was concentrated on the metabolism and physiology of these extreme acidophiles.A limited number of studies have been reported on the bacterial leaching of pyrite from coal (Silverman et al., 1963; Dugan, 1977). However, the bacterial oxidation of pyrite is a self-limiting first-order reaction, probably due to the precipitation of Fe(OH)J and elemental sulphur , which progressively inhibits intimate contact between the bacterial cells and the sulphide-mineral surface. Consequently, the best pyrite oxidation experiments with coal reported to date required five days to remove 97070 of the pyrite (Dugan &Apel , 1978) using mixed cultures of T. ferrooxidans and T. thiooxidans."

Jan 1, 1985

By V. S. Melamud, A. G. Bulaev

"Sulfide ore processing is characterized by significant losses of metals, for example, with flotation tailings. Therefore, flotation tailings can present an important source of metals. The treatment of flotation tailings is a technological issue due to low content of valuable metals (e.g. copper and zinc) and high iron content. The goal of the present work was to investigate extraction of base metals and gold from old flotation tailings containing 17% iron, 0.26% copper, 0.22% zinc, and 0.7 g/t gold. Chemical leaching in columns with 0.5 to 10% sulfuric acid solutions and bioleaching in air-lift percolators were used for the extraction of base metals. 1% H2SO4 provided high extraction of base metals and best selectivity. Recovery of copper and zinc reached 35% and 40%. Increasing H2SO4 concentration did not lead to significant increase in base metals extraction, but led to increased iron concentration in the pregnant solutions. The 1% H2SO4 leaching solid residues were used for further experiments. Acid leaching and bioleaching did not result in significant increase in base metals recovery. Leaching of the residue with 10% H2SO4 provided extraction of 4% copper and 20% zinc, and bioleaching for 100 days provided extraction of 16% copper and 12% zinc. The recovery of gold by cyanidation from the flotation tailings, the 1% H2SO4 leaching solid residue and residue of two-step acid leaching were 50, 49, and 65%, respectively. The results suggest that acid leaching can be effective approach for treatment of old flotation tailings.INTRODUCTIONAbout 80% of base metals (copper, nickel, zinc) are produced through pyrometallurgical treatment of sulfide ores. Mining and metallurgical treatments of sulfide ores are presently characterized by significant losses of non-ferrous and precious metals into the various wastes. For example, flotation of sulfidic ores yields formation sulfide flotation tailings. These wastes pose a problem not just because of their sheer volume, but some of them may affect local ecosystems. Nowadays, mining and metallurgical wastes can be considered as technogenical source of base metals."

Jan 1, 2016

By L. Vollert

In-situ recovery of metals is presently experiencing a revival not seen since early applications in amenable copper oxide deposits, uranium and generally applications where neither, porosity and permeability, nor process chemistry have been prohibitively difficult. With ever decreasing grades in current mining operations or Greenfields projects and ever increasing capital and operating costs, in-situ recovery is looked to as the processing option that will both unlock these deposits as well as potentially derive revenue from mineralised waste remaining in the ground once traditional mining and processing methods become uneconomical. In-situ recovery is also being looked to as a mining method that minimises the environmental impact sustained in the application of traditional energy and water intensive mining and processing operations where millions of tonnes of ore are mined from the earth, processed on surface and then disposed of in both waste dumps and tailings facilities. The key challenge facing companies like Newcrest is that these low-grade deposits or remnant mines are generally hard rock applications that require costly methods to liberate the valuable minerals. A further challenge includes identifying suitable chemistries that both facilitate the economic recovery of gold and copper and that may be considered environmentally acceptable. This paper presents a desktop study whereby the issues of access creation and chemical extraction are discussed and evaluated with a view to driving future research in the area and unlocking this application as a real processing option. INTRODUCTION Mining companies are increasingly challenged by low grade, deep and complex ore deposits which are no longer economically exploitable by current methods. The large footprint of current open pit operations can present obstacles for permitting and social acceptance. For these reasons in-situ recovery (ISR) technologies are receiving renewed attention as a technology which could be used to exploit these more complex deposits economically and with less environmental impact. The environmental impact may be further reduced if emphasis is placed on use of renewable energy sources rather than traditional grid power, gas turbine or diesel generators are employed to drive the operation. A potential renewable energy driven ISR mine of the future is shown in Figure 1.

Jan 1, 2019