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By Malcolm Black

Introduction Before beginning to write this paper, I decided that I should first find suitable definitions of the words Sample and Sampling. The dictionary gives: "Sample.-A portion indicative of the whole"; and according to Baillie (1), sampling is "That process whereby a representative and comparatively small portion of material is selected from a large bulk, and preserved under such conditions as shall prevent contamination or avoidable alteration, with a view to the formation of valid conclusions regarding the suitability of the bulk for specified purposes". These comprehensive definitions are alike in substance, and indicate that unless a truly representative portion is taken, it is not a sample. Ore 'as mined' generally varies a good deal in composition, and, in crushing, segregation takes place. Some of the minerals present, due to differences in hardness and friability, break into smaller pieces than others, and, on reaching the bin, the coarse particles roll away, leaving the fines behind. The result of this segregation is generally quite noticeable on the conveyor feeding the mill, especially when the bin is nearly empty and the crushing plant shut down. Should the sampling period synchronize with either the coarse or the fines, the sample obviously would not be representative. I agree that this is rather far fetched, but I maintain that such a condition is possible. Assuming that a representative sample may be procured from the feed conveyor, the method of cutting it down for assay has considerable influence in maintaining the original condition of the sample. The finer the material is ground after each cut, the more uniform the sample will remain. To illustrate this point, let us take a quantity of fine sand and add, say, three grains of rice to represent metallic particles. We may mix this sample by any of the known methods, then cut it into four equal portions. It is obvious that at least one of the portions will be without a rice grain. But let us grind the three grains of rice into flour and proceed as before. Now there will be a much greater chance of including some of the rice in each portion.

Jan 1, 1935

By Garth D. Kirkham, James P. Siddorn, Hendri Falck

"Abstract - As an integral part of the Geological Survey of Canada’s EXTECH III Project, a threedimensional computer model has been created of the Con and Giant gold mines in the Yellowknife Greenstone Belt. The Yellowknife Mining Camp has produced a great deal of gold (over 15 million ounces, or 400 000 kg) in the past sixty years and the prevailing assumption is that the mines are at the end of their lives. However, the potential for discovering additional resources using new ideas and technology, and maximizing use of existing data, offers an opportunity to sustain the old mining operations and maintain their contribution to the community.The objectives of this study included the compilation and creation of a three-dimensional Geographic Information System model (combining 3D subsurface data with surface information) to provide a framework for concurrent structural and alteration studies, and to encourage new exploration in the area. A secondary objective was to retain the data in digital format as a historical reference for future remediation efforts, and to document a portion of Canada’s rich mining history.The end result is a database and set of models that have been instrumental in facilitating further exploration in the area, as well as in developing targets for future exploration and mining activities. In addition, the EXTECH III 3D GIS model has made a valuable contribution toward the understanding of the arsenic remediation issues at the Giant mine, and has served as a tool in support of a variety of highly technical engineering studies and for communicating information and problems to the layman and community as a whole."

Jan 1, 2003

By R. E. G. Caines, P. Alport

"Operating heavy equipment in Labrador, where the winters are 8 months long and the temperature frequently drops below -40°F (-40°C) for days and sometimes weeks presents unique problems in both the operation and maintenance junctions. Winterization programs must be well designed and implemented at the proper time. These programs must include the proper selection of fuel oil, engine oil, hydraulic oils, greases, cooling system fluids, etc. More often than not, modifications have to be made to the original equipment in order that it can be operated safely and economically in the Canadian North. Manufacturers usually design equipment for a less harsh environment and the user makes adaptations by trial and error.Operators have to be trained for the proper operation on ice- and snow-covered roads in an open-pit mine. Special emphasis must be put on haulage road conditions. In this paper, the authors will cover some specific maintenance procedures, equipment modifications and operator training problems experienced by the Iron Ore Company of Canada in its open-pit operation in Labrador.IntroductionT he Iron Ore Company of Canada is engaged in open-pit mining , concentrating and pelletizing of iron ore. The company operates in two provinces, Quebec and Newfoundland (Fig . 1) . The Knob Lake operation "", based in Schefferville, Quebec, has mine sites located both in Labrador and Quebec . The Caro l Lake Project is situated in Labrador, 25 kilometres east o f the Quebec border at Labrador City. The Carol operation mines, concentrates and pelletizes it s o re before rail transportation to the seaport o f Sept-lies via the Quebec North Shore and Labrador Railway."

Jan 1, 1984

By Mehmet Canbazoglu, Kaarlo Haavanlammi, Hannu Laitala

Cobalt is currently a critical metal because of the increasing number of electrical vehicles forecast for production. Copper and zinc are base metals that are used in many everyday applications, including vehicle production. Eti Bakir Co. Mazidagi Phosphate Plants in the Mazidagi district of Mardin, Turkey is a multi-product facility that produces cobalt, copper, and zinc, as well as fertilizers, from the roaster calcine. Roaster off gas is treated in a sulfuric acid plant (SAP) and the acid itself is utilized in fertilizer production. The comminution circuit, roaster, SAP, and calcine leaching process were developed by Outotec and integrated with the fertilizer production process implemented by Eti Bakir A.Ş. This paper describes the hydrometallurgical calcine leaching process used at the plant, with a focus on the oxidative pressure leaching of the cobalt, zinc, and copper-containing calcine. The cold and hot commissioning phases of the pressure leaching autoclave start-up are discussed together with experiences from the ramp-up period. The production processes of the copper cathode and cobalt and zinc-containing salts are also presented together with some of the plant’s operating parameters. INTRODUCTION The ETI Bakir A.S. fertilizer plant, Turkey, is located in Mardin Province near the border with Syria, (Figure 1). The leaching plant project was started in 2012. The purpose of the plant is to separate the valuable metals from the calcine produced by the pyrite roasters, which are used to produce a SO2 containing gas for the new sulfuric acid plant. Fertilizer production requires sulfuric acid, and for this reason a sulfuric acid plant was built; customer already had access to pyrite concentrate, which is used as the roaster feed. During the engineering phase of the roaster and acid plants it was noticed that the roasted calcine contained considerable amounts of valuable metals like cobalt, copper, and zinc. To recover these metals, a calcine leaching process was developed at the Outotec Research Center in Pori, Finland. The main process connections of the Mazidagi site are shown in Figure 2.

Jan 1, 2019

Stress induced, gravity-assisted failure processes typically dominate long before stress levels approach the strength of the intact rock (at approximately smax > 0.4UCS where smax = 3s1 ? s3 and UCS is the Unconfined Compressive Strength of the intact rock (Martin et al. 1999)). Under these conditions, discontinuities typically become clamped and the failure process becomes brittle. This brittle failure process is dominated by new stress induced fractures growing subparallel to the excavation boundary. While it is possible to identify areas with the potential for brittle failure, for example, using the general assumption that brittle failure will occur in areas at right angles to the major principal stress (Hoek et al., 1995), when the threshold smax > 0.4UCS is reached in areas around the tunnel boundary, or elastic modelling and the Hoek-Brown brittle parameters proposed by Martin et al., (1999) (i.e. m? 0 and s ? 0.11), amongst others, recent observations discussed by Everitt & Lajtai (2004), and Kaiser (2005; 2006) suggest that brittle failure processes are enhanced when structural features such as joints, weakness zones, bedding planes or foliations are preferentially orientated around the excavation boundary creating stress raisers which in turn facilitate the stress-driven rock mass disintegration process (e.g., as illustrated by Everitt & Lajtai (2004) on Figure 1b). Such weaknesses induce stress heterogeneities that thus promote tensile-spalling failure processes (Diederichs 2000). The observations suggest that stress induced damage can occur ?prematurely? depending on the orientation of micro and macro structures in situations where the known stress conditions should not yet initiate brittle failure processes. In general, when structural features (micro and/or macro), especially foliations, are present in a rock mass, the strength is effectively reduced, largely due to tensile strength heterogeneity in areas depending on the orientation of the structural features with respect to the excavation boundary. As a result, stress induced damage could occur in areas not normally considered due to the influence of anisotropy (Figure 1).

May 1, 2009

By R. W. Baker

"The development of uppers drilling at Brunswick Mining is reviewed. This paper describes design criteria for drilling patterns and the research required for selection of a suitable drill jumbo. The success of the uppers drilling program based on operating procedures is highlighted. IntroductionBrunswick Mining and Smelting Corporation Ltd., operates a 10 500 tonnes per day lead /zinc/copper I silver underground mine some seventeen miles southwest of Bathurst, New Brunswick .The No. 12 orebody, first discovered in 1952 by a group headed by M.J. Boylen, had extensive development, including two shallow shafts (500 ft), and test work carried out on it by St. Joe Lead between 1953-1957. However due to complex metallurgy and depressed metal prices, the operation was suspended.In 1961, a group comprised of M.J . Boylen, K.C . Irving and Patino acquired the rights of St. Joe Lead to the No. 12 property. A concerted development plan was initiated along with construction of the necessary sur face facilities and by July 1964, the property was in production at 4500 tons per day.In 1967 Noranda Mines Ltd. acquired operating control of Brunswick Mining and Smelting Corporation Ltd."

Jan 1, 1988

By D. Moffat

Rio Algom Limited has mined uranium at Elliot Lake, Ontario for 20 years. The production of this energy-generating element results in the need to dispose of low-level radioactive solid wastes and liquid effluents. Because of the wet-temperate climate at Elliot Lake, the liquid effluents are of particular importance. Radium-226 is the isotope which requires most attention, and the current practice for its control is by addition of barium chloride and retention of the resultant precipitates in large settling ponds. Analyses of typical effluents and waste streams are discussed and typical levels of radium-226, thorium-230, thorium-232, thorium-228, lead-2iO, polonium-2iO, and uranium isotopes are presented.

Jan 1, 1979

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb-Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb-Zn ore was traced to apH effect. In the pH range, 9.5 to 11.0 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH)2 is suggested, the Fe- + ions being derived from superficial oxidation of pyrite in the ore. IntroductionGalena and sphalerite commonly occur together. A typical procedure, using xanthate collectors, is to float the galena first, at pH - 8, followed by flotation of sphalerite after activation with copper (II) sulphate at pH - 10 (to depress pyrite).Flotation tests following this procedure in an undergraduate laboratory course with a Pb-Zn ore from Polaris failed to achieve consistent selective flotation of galena. Occasionally a considerable amount of sphalerite, even though unactivated with CUSO4, floated. This was traced to accidentally high pH. A systematic study was carried out which revealed that sphalerite floated readily in the pH range 9.5 to 11.0 without activation by CuSO4 This paper describes the results of the study and discusses a possible mechanism of this flotation of sphalerite."

Jan 1, 1987

By M. G. Lipsett

General Challenges for Mining & Mineral Processing Operations ? Capital-intensive industry ? Ongoing cost pressures ? Remote locations ? Workforce demographics ? Dynamic, unstructured, rugged environment

May 1, 2008

"This paper describes some of the methods and equipment used for fine milling of minerals, and gives particular attention to the Vibro Energy system.In addition, the paper describes a specific application in the gold mining industry. This is the 200 tpd plant built by Anglo American Corporation at the President Brand Mine in South Africa in 1985, now a division of Freegold. This plant treats a gold bearing pyrite flotation concentrate which is finely ground to 15 microns prior to cyanidation and carbon-in-pulp (CIP). l .0 INTRODUCTIONFree milling gold ores are those that yield acceptable dissolution and recovery of the gold following grinding to what can be described as normal fineness, frequently between 50% and 90% passing 74 microns.Increasingly, gold metallurgists are faced with ores that are refractory. The traditiona1 treatment route for refractory gal d ores and concentrates has been by roasting, but for environmental reasons this is becoming less acceptable, or in some areas of the world, totally unacceptable. New methods of treating refractory gold ores are being developed and applied in practice. These new methods include pressure and biological oxidation. Higher gold liberation can also be attained by increasing the fineness of grind, although with conventional systems there are economic limits to this.In flowsheet development and test programs on new deposits, a standard procedure is to establish the relationship between the grind and subsequent go 1 d extraction. The normal situation is that gold extraction increases as the ore, or concentrate, is ground finer. Typically, this relationship is as shown in Fig. l, where the incremental additional extraction is very small once an optimum, or economic, grind has been achieved. This generally app1ies whether the material is free milling or refractory. The limits to grinding are set by the type of equipment which is commonly in use, usually ball mills. These mills have the obvious advantage of high capacity, however, they are increasingly inefficient as finer grinds are required. In general, ball mills are used to reduce ore to some agreed percentage passing 74, or possibly 53 microns."

Jan 1, 1988

By Z. Pilecki

This work concerns the identification of weak zones in the structure of a rock mass endangered by outburst of gases and rocks in the Rudna copper ore mine at greater depths (approximately 1200 m). A special methodology has been undertaken for the recognition of that threat in the wake of an outburst in the mine in 2009. No similar phenomena have been previously recorded in KGHM Polska Miedz copper ore mines. The research described in this paper was carried out in the new part of the deposit prepared for mining. Geophysical methods were used: seismic tomography and borehole ground penetrating radar (BGPR), along with particular identifications using geological engineering methods. In the researched area, Permian layers of sandstone and shale clay (Weissliegendes formation) and of Zechstein dolomite (top of Rotliegend formation) and anhydrite occur in the copper ore deposit. The rock layers are characterized by variable thickness and intensity of mineralization, varying internal structure, and local fracturing containing different gases and water. It is assumed that accumulation of gases occurs in the tectonically fractured dolomite. The study was focused on the recognition of the structure and properties of the dolomite layer lying directly within the roof of excavations. The first tests were performed with seismic tomography for the recognition of anomalous changes in the elastic properties of the rock mass. The results of these studies were used to design a control borehole for a detailed geological engineering assessment and BGPR surveys with 100MHz antennas. Seismic tomography enabled the identification of changes in Pwave and S-wave velocity, the Vp/Vs ratio, dynamic Poisson's ratio and dynamic Young's modulus. It was clear that seismic anomalies required verification by other methods. The BGPR survey was performed in a specially designed borehole, passing through the selected seismic anomalies. While the borehole was being drilled, the outflow of gases was identified, with varying amounts of CH4, CO2, and H2S detected, as well as water outflow. The results of BGPR confirmed the location of a reservoir of water and gases, about 30 m in length, found in layer of dolomite. The direct cause of the BGPR anomaly was assumed to be intensive fracturing, a greater content of clay material in the dolomite, and the presence of water in the fractured zone. The BGPR image was correlated with information on lithology, fracturing based on the RQD index and additional information acquired during drilling about water and gases surveys and other symptoms. The achieved results also showed a very strong correlation between the location of the zone containing gases and water and the anomalous S-wave velocity and field of dynamic Poisson?s ratio, and to a lesser extent other seismic parameters. It was found that the other measured seismic anomalies may be of the same nature as those identified in the control borehole and accordingly will require the implementation of detailed identification. The performed tests have also shown the usefulness of geophysical methods to identify geodynamic hazards under the geological and mining conditions of the copper ore deposit in the Rudna mine.

Aug 1, 2013

By Anna M. Ferrero

Stability condition of underground excavations have to be assessed to guarantee safe operations within the quarrying working areas. This objective requires a reliable assessment of the rock mass natural state of stress and of the stress redistribution induced by the excavations. This goal is often complicated by difficult geological conditions induced by tectonic stresses, complex topographies and large and irregular excavation geometries. Consequently, the acting state of stress needs to be measured by specific in situ measurement devices. This work refers on an in situ measurements campaign carried out by CSIRO tests in an underground quarry located in the Carrara marble basin. The difficult path carried out for interpretation of the measurements is described in this paper. In particular, the numerical modeling performed using the Boundary Element Method (BEM) first, to study the influence of both surface topography and excavation geometry and then the Distinct Element Method (DEM) to evaluate the influence of rock discontinuities in the measurement zone are illustrated in this work. Parametrical analysis of the rock mass mechanical features is also described in order to calibrate the numerical models and analyze the experimental results. The work has been carried out trough several phases, which are: characterization of the rock mass through geostructural surveys: this allowed us to classify the rock mass and determine the mechanical and physical parameters necessary for modeling; on-site measurement of stress levels through the application of over coring techniques; numerical analyses for the simulation of excavation phases, using the Examine3D (BEM) engineering analysis code. comparison between the measured stress levels and those numerically calculated and subsequent calibration of the BEM model; Numerical model of the forecasted excavation based on the calibrated (BEM) model.

May 1, 2009

By J. M. Houston

"In October 1982, Rio Algom Limited, purchased a tin prospect near East Kemptville, Nova Scotia, from Shell Canada Resources. This purchase led to the development of the first substantial tin mine in North America. This paper deals with the drillingand blasting operations at Rio Algom, in particular the use of emulsion explosives technology.This presentation describes what emulsion explosives and Heavy AN/FO are, and the support system used to deliver these products to the blast site.HistoryThe East Kemptville mine site was discovered by Shell Canada Resources (SCR) in July 1978. SCR started diamond drilling on the tin prospect in March 1979. After 8220 m of BQ drilling, it was estimated a reserve of 56 000 000 tonnes of 0.165% Sn was present.The property, which is located 54 km northeast of Yarmouth, Nova Scotia (Fig. 1), showed, after a feasibility study that, given an ore treatment rate of 9000 tonnes per day, a mine life of 17 years could be expected.GeologyThe tin deposit of the East Kemptville Mine, occurs in granitic rocks at their contact with metasedimentary rocks. The mineralization is in the form of cassiterite with associated sulphides of copper and zinc. The tin occurs in a stockwork of tin bearing Greisen alteration zones.East Kemptville MineThe mine planned an open pit operation with the first five years being mined at a rate of 14 000 tonnes per day, of which 5000 tonnes will be waste and low grade ore. Eventually, the total mining rate will be 21 000 tonnes per day, including 12 000 tonnes of waste and low grade ore. Figure 2 shows the general layout of the mine site.East Kemptville Chooses Emulsion ExplosivesIn December 1984, East Kemptville Mine awarded the Explosives Division of C-I-L Inc. a contract to supply explosives to the borehole. The system chosen gives East Kemptville the on-the-bench choice of regular AN/Fa, or a high density, Heavy AN /Fa product called SuperAN· or a water resistant emulsion explosive called MAGNAFRAC· for holes that cannot be dewatered.Emulsion ExplosivesAn emulsion is an intimate mixture of two liquids that do not dissolve in each other. Emulsions have contributed to our daily lives in such products as insecticides, salad dressings and cosmetics."

Jan 1, 1987

By R. W. Lawrence, J. B. Austin, P. B. Marchant, J. T. Chapman

"Biohydrometallurgy is the use of microbiological reactions to assist in the extraction of metals. Bioleaching offers an innovative alternative for the treatment of refractory gold-bearing sulphides (1). One particular cost advantage of bioleaching is the potential to enhance gold extraction after only partial sulphide oxidation. The apparent selective sulphide oxidation is more prevalent where the refractory gold is associated with arsenic and antimony (2). Oxidation of the pyrite minerals and arsenopyrite at different oxidation rates can result in high gold extractions at relatively low levels of sulphide oxidation due to preferential, or selective, oxidation of the arsenic mineral. Arsenic extraction rates in a bioleach process typically exceed the iron extraction rate. Therefore, in concentrates in which the precious metals are principally associated with arsenic minerals, liberation of the precious metals may be possible with high recoveries and less than complete sulphide oxidation. The capital and operating cost advantages of partial sulphide oxidation are inherently obvious and are briefly illustrated herein.Ultra fine milling (UFM) is another alternative for enhancing gold extraction from refractory sulphides. Some refractory gold is simply particle size sensitive and UFM can improve gold extraction without the need for costly sulphide oxidation (3). Fine grinding technology for enhanced gold recovery developed by Metprotech, South Africa, is currently producing 2 - 4 micron ground product using a single pass, stirred ball mill. Proper application engineering has ensured that plug flow occurs through the mill. Plug flow from the feed inlet at the bottom of the reactor ensures that short circuiting of feed does not occur and as a result, the mill product does not require classification.A combination of UFM as a pretreatment for bioleaching could provide a mechanism for enhanced selective sulphide biooxidation and/or increased overall gold extraction following biooxidation due to improved particle liberation ( 4). The effect of UFM on biooxidation costs will be discussed. Only sulphide concentrates are considered herein for application of UFM in combination with biooxidation."

Jan 1, 1990

By Andrew G. Patton

The Alimak mining method was introduced at the David Bell mine in 1998 to extract an otherwise uneconomic and inaccessible reserve. The success associated with the extraction of these reserves led to major expansion of the method. To date, results have been extremely positive in terms of grade control, reduced dilution, stope recoveries, productivities and mining costs. It is hoped that through further development of the method at David Bell mine we will continue to see positive results in these areas and be able to increase mineable reserves to include proven resources that do not currently meet the criteria of our current stoping plan.

Oct 1, 2001

By Damian Connelly

The metallurgical heart of the majority of copper oxide processes is the heap leaching operation. Fresh low grade sulfide ores is a far greater challenge.The success of this unit operation is so important that operators need to understand the ramifications of their decisions or non-decisions and how they could affect the downstream processing. Heap leaching is an operation that can be described as a scientific art whereby principles of science can be used to guide experienced personnel in attaining their goals. Recent advances have been made based on better understanding the ore characteristics. The success of a heap leach operation, or otherwise, is dependent upon a number of factors, notably: The type of ore to be treated The extent of testwork completed to define the process The interpretation of the testwork results Ore preparation prior to stacking Agglomeration and curing requirements Other issues are: Compliance with the ’smaller’ requirements of environmental authorities Adequate and timely drainage of solution from the base of a leaching lift The degree of saturation in the pads Heap porosity – coarser or finer ore, which is better? Higher or lower irrigation rates – which would produce a better result? Laying out irrigation pipework for ease of operation and maintenance The addition of water, raffinate during agglomeration where needed The heap leaching of sulfide ores, including chalcopyrite, via enhanced bacterial leaching is discussed. INTRODUCTION Over the last twenty years, production of extremely pure copper from solvent extraction and electrowinning (SX/EW) has become more common in a market of real declining prices for copper metal. This paper touches on a number of heap leach operations and experiences. These projects were subjected to extensive engineering design and resulted in low capital cost, efficient operations with a number of lessons learned. The key to these operations was the performance of the heaps and associated fluid collection systems rather than the plants themselves.

Jan 1, 2019

By F. F. Roberto

Sulfuric acid has been demonstrated to be an efficient lixiviant for in situ extraction of copper in the past. It has also been proposed that microbial production (by iron-oxidizing acidophilic bacteria) of acidic ferric solution either in situ or ex situ could provide an economic strategy to generate an effective lixiviant for secondary copper sulfides like chalcocite and covellite. Copper heap bioleaching also takes advantage of this approach. One of the major environmental challenges for in situ copper recovery projects is the containment of acidic solution within the ore deposit, and ultimate restoration of the depleted ore body to its original state. A perhaps overlooked aspect of projected site operations is the possibility that transient acidic conditions and pumping of solutions from surface reservoirs into the subsurface could stimulate the growth of iron- or sulfur-oxidizing species of acidophilic microbes in the ore body, leading to additional generation of sulfate, acid, and ferric iron. This outcome would benefit extraction of copper in mixed oxide/sulfide deposits in the near term, but could complicate restoration activities. Possible impacts of pumping acidic solutions into the subsurface on microbes resident in, or introduced into the extraction zone will be discussed in the context of our understanding of copper heap bioleaching and acid rock drainage. INTRODUCTION As high-grade deposits of metals such as copper continue to decline, conventional mining methods have evolved to mine and process larger and larger quantities of ore. What is currently defined as ore today often contains less metal than the tailings of past operations. The throughput of current-day mines also leads to tremendous amounts of waste rock and tailings that may threaten the environment and communities around the mines, as has recently been experienced by 3 major tailings disposal facility (TSF) dam failures in the past 5 years. Community acceptance of large mine operations thus becomes more difficult to achieve—loss of the social license to operate. In response, the mining industry urgently pursues innovations that can fundamentally change the way in which metals are mined. In situ recovery (ISR) of metals represents one approach to a more sustainable mining industry, by virtually eliminating the need for a pit or underground excavation, eliminating the excavation and transportation of ore to a process plant and the ensuing noise and dust that is generated, and any need for waste rock dumps or TSFs. An ISR mine could have very little visible footprint beyond a network of wells, pumps, and piping to transport pregnant solution to a recovery facility, such as a solvent extraction- electrowinning (SX-EW) plant for copper. Some solid waste streams and/or storage ponds may still be necessary to treat and store bleed streams, PLS and raffinate, or as part of groundwater restoration activities. Thus capital and operating investments would be potentially much lower than that required for a conventional mine. In theory production could also be controlled to adjust to subsurface ore grade and match market demand. A not insignificant challenge of in situ recovery is the requirement for an efficient, low-toxicity, and ideally selective lixiviant for the metal that is targeted.

Jan 1, 2019

By Peter White

Mine Planning Shaft Collar Shaft Sinking Raises Ramp Underground Water Storage

May 1, 2009

The theory and practice of sampling of particulate material have been the focus of a continued attention on the part of the mining industry worldwide for almost a century now, because of its critical importance at all phases of a mining project, from exploration (bulk sampling, assaying) to production (grade control) and marketing (quality control). A powerful, complete theory was put together by P. Oy (1968 to i982), but its applications to gold ores have met with limited success to date, due to the inadequacy of its sampling variance and minimum sample mass determination formulae to the challenging case of gold ores. This paper presents a research project completed at Inco Exploration and Technical Services Inc., using a geostatistical approach, to shed light on the results of P.Gy's theory, and adapt them to the case of particulate gold ores. After a reminder of Gy's formulae and a simplified demonstration of the generic form of Gy's and more traditional formulae, an empirical approach, based on sampling experiments from four gold deposits, shows how Gy's formulae must be corrected to adjust to the case of gold ores. The generality of the results formula is then substantiated with a geostatistical analysis of the problem. A parameterized formula results, and indications are given on how to fit its parameters to experimental data. Application guidelines and charts to fit any case and budget are presented, along with a detailed practical example.

Jan 1, 1991

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019