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By R. M. Clowes

"As part of LITHOPROBE's multidisciplinary earth science research program to understand the evolution of the North American continent, studies have been undertaken in a number of key areas in Canada. In the Trans-Hudson Orogen of Manitoba and Saskatchewan, LITHOPROBE results require re-evaluation of tectonic models related to its origin. In the Abitibi greenstone belt of Quebec and Ontario, results indicate a more complex evolution for the southern Superior province, one that links with the development of gold and massive sulphide deposits. As part of the program, the seismic reflection profiling method is being adapted for the mining industry. Three examples demonstrate the subsurface information that can be obtained. In Noranda, the base of the volcanic Blake River group is imaged and reflectivity is tied to geology through well logs; in Matagami, the zone of mineralization is shown to be downdropped along a majorfault; in Sudbury, a new structural model is developed, one that shows marked asymmetry at depth and indicates that some ore-bearing units on the margins of the igneous complex may be repeated at depth. IntroductionLITHOPROBE is Canada's national, collaborative earth science research project, established to develop a comprehensive understanding of how the North American continent has evolved. Ten transects, or study areas, were chosen to investigate pivotal geological features to their deep lithospheric roots. They span the country from the Pacific to the Atlantic Oceans and from the U.S. border to the Yukon and Northwest Territories, and geological time from four billion years ago to the present. A multidisciplinary approach, which is spearheaded by seismic reflection techniques, is essential to developing complete interpretations and outstanding scientific results. LITHOPROBE also has pioneered the use and demonstrated the value of using reflection technology to determine subsurface geology in mining camps.This paper provides an overview of the transects and their significance for the tectonic evolution of North America. Two specific examples demonstrate how we detennine present three-dimensional lithospheric structure and past geotectonic processes which formed it. The application of the reflection method to imaging complex structures in ""shallow"" crystalline rocks has been developed with funding and other support from the mining industry and provincial geological surveys. Sustaining funds, however, are derived from the Natural Sciences and Engineering Research Council and Geological Survey of Canada. Emphasis has been placed on developing deeper penetrating tools for exploration of deeply buried, but economically retrievable, mineral resources near existing mines, where an expensive infrastructure already is in place. Three examples, Rouyn-Noranda in western Quebec, Matagami in northwestern Quebec and Sudbury in northeastern Ontario, illustrate these developments."

Jan 1, 1994

By Peter A. Hacquebard

"The coals of the Sydney and Pictou coalfields are generally classed as high volatile ""A "" and medium volatile bituminous coals but there are significant differences within and even beyond this rank. These are related to the observation that the coalification in eastern Canada is essentially post-deformational, resulting in a general increase of rank with depth in individual seams.Exploration drilling in the Sydney coalfield has shown that the rank increases offshore to M. V. bituminous at mineable depths and in the Pictou field to L. V. bituminous coal. There is also a marked easterly shift in rank within one seam at the same depth at Sydney, with the result that M. V. coal will be reached sooner in the Donkin Reserve area (at 700 m depth) than in the Lingan-No , 26 Reserve area (at 900 m depth). These rank changes are important for the manufacturing of metallurgical coke as shown with coke stability predictions based on petrographic analyses. The L. V. coal of the Pictou field can be used for blending purposes and is the only known L. V. deposit of mineable thickness in eastern Canada.In addition, the vertical rank changes between seams have been studied in ten boreholes. They are not constant within the confines of the Sydney coalfield. Four separate areas can be recognized, each with different coalification gradients, which can be related to changes in the paleogeothermal gradients . Variations of 2.5 degrees to 6. 7 degrees CI IOO m are indicated and geological causes for these changes are suggested.IntroductionThe Sydney coalfield is the largest and most important field in eastern Can ad a, and although it has been in production some 200 years, the remaining ""demonstrated "" resources of 1.6 billion metric tons can extend its production capability for at least another 100 years. All coals mined are high volatile "" A"" bituminous and have been used for both thermal and metallurgical purposes. For the latter rank variations even of a minor scale are of critical importance for the manufacturing of metallurgical coke.The significance at the present time of the Pictou coalfield, which has only modest remaining "" demonstrated"" resources of 60 million metric ton s, lies in the discovery in 1975 of a 14-million-ton deposit of low volatile bituminous coal. It is the only known low-volatile coal in eastern Canada and is suitable for use as a blend for metallurgical coal. As such, it could supply the Sydney coke ovens for a period of 30 years at the current rate o f coke production and replace imported American low volatile coal.Consequently, coal rank studies of the Sydney and Pictou fields are important not only from a geological point of view, but also because of economic considerations."

Jan 1, 1984

By R. A. Sudisman, T. Yamabe, M. Osada

"Geological material can be subjected to some different loading conditions, mainly due to three inter-related physical processes which are mechanical, thermal, and hydrological. Freezing and thawing process of rock that occurs in sub-zero temperature condition may contain some or all those three physical processes depended on its initial condition. Those inter-related physical processes may lead the ground into failures. Therefore, understanding the physical properties such as deformation process of geological material under freezing and thawing condition is required for the artificial ground freezing projects and engineering construction activity in the natural cold region.In order to study the strain characteristic of rocks during freezing and thawing process, a series of freezing and thawing experiments of core samples of three different rock types and mortar has been conducted under varying temperature from -20 °C to +20 °C. Four core sample types are Sandstone, Granite, Tuff, and Mortar with 50 mm diameter and 50 mm height, which were naturally dried before the freezing-thawing experiment. Freezing-thawing experiment was conducted by submerging the vinyl covered core samples into a temperature-controlled liquid coolant box. Firstly, temperature of liquid (brine solution) was set at -20 °C so that the temperature of subjected sample was decreasing to as low as -20 °C. And then the temperature of brine was returning to initial room temperature after the coolant system was stopped. Strain gauge and thermo couple were attached on the core’s perimeter to measure strains and temperature changes.Sandstone and Mortar samples show relatively similar results than other two samples. Both presents linearly shrink with the temperature decrease and expand almost to its initial condition with the temperature increase. Granite shows less-linear strain-temperature relationship during thawing process, while the Tuff sample shows abrupt strain increase during thawing process on the temperature higher than +10 °C. Thermal expansion value of each rock types were obtained by fitting the major strain-temperature relationship on -19 °C to +10 °C temperature range. Overall, anisotropic deformation was observed on the entire samples and possible mechanisms for each hysteresis characteristic are discussed, which need to be confirmed by further experiments."

Jan 1, 2015

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By S. Rash Ahmadi

One of the most important elements in power plants is rotors and repairing the damaged rotors is very important in view point of economics. One of the most complicated problems in power plants is increasing of stiffness of the turbine rotors. This problem which occurs mainly due to thermal shock or rubbing makes to exit damaged rotor from service. These elements can be repaired effectively by heat treatment methods. Tempering heat treatment is the most common solution for straightening of damaged rotors but it requires having good knowledge about heat treatment parameters (temperature and time) and their affects on fundamental properties of rotors. In this article, a suitable method is introduced in order to modify the increased stiffness in journal part of rotors due to martensite transformation, using heat treatment tempering process.

Oct 1, 2011

By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By J. B. Hamilton

The advantages of generating and distributing electrical energy direct from the coal-fields so closely affects the mining industry that a few remarks on the unbalanced phases of coal distribution is worthy of attention. The value of coal imported into Canada from 1912 to 1921 exceeded the sum of $580,000,000. In 1922 Ontario imported 1,640,000 tons of anthracite and 9,440,000 tons of bituminous coal. I submit that the use of Saskatchewan lignite in an electrical super-power plant equipped for the carbonizing of coal, and disposal of excess gases would be the commencement of a solution of the fuel shortage in Ontario. As Saskatchewan becomes more and more populated and manufacturing increases, the amount of by-product carbonized fuel available for shipment to Ontario will increase, and its shipment to that province would decrease the trade deficit of the national balance sheet. If and when this is carried out it will mean a better and wider market for Alberta fuels in Saskatchewan and Manitoba.

Jan 1, 1924

By H. C. Cooke

This paper will discuss two comparatively unrelated subjects; first, a general review of the advances made at the more important properties in the last year; and second, a statement of the conditions controlling the deposition of the copper ores in the Rouyn area, as determined by last summer's field work. FIRST PART Development has been very rapid since I stood before the Institute one year ago to discuss this same subject. Then, there were many properties on which gold had been discovered, any of which might develop into a mine. Further work has eliminated the most of them as possible mines, or at least has shown that before they can attain that status further discoveries must be made on them. Then, all gold veins held forth much the same promise; now the indications are that one particular type of gold vein is of greater prospective value than others. Then, all eyes were turned toward gold as the metal of prime economic importance; now copper has taken the centre of the stage, and gold is distinctly in the background.

Jan 1, 1926

By S. A. Willis

For over 150 years gypsum from Nova Scotia has been shipped via water to the United States east coast. The history of the movement has been one of continual improvements in quarrying, loading, and shipping. At the start, man-size rock quarried by hand auger and black powder was loaded into horse-drawn carts, hauled to the waterfront, and dumped into 100-ton sailing schooners. Last year the Canadian Gypsum Company completed the latest and most modern of these successive installations for the movement of this Nova Scotia product. The new system loads crushed gypsum into 11,600-ton vessels at Hantsport in two hours' time at high tide. At the head of the bay of Fundy are located vast deposits of gypsum. The tidal rise and fall of 45 feet twice a day, with its attendant swift currents, has always presented major navigation and shipping problems. When the tide is low, the Hantsport ship-loading pier is high and dry, with no water within 400 feet. Three hours later a large river has flooded in (running up hill) and large steamers can dock at the wharf. Before high water, the ship has been loaded and -there is a depth of 30 feet or more of water around the wharf. At high water, the ship sails away on the ebbing tide as the river runs in the other direction. Tides are caused by the gravitational attraction of the moon and sun on the ocean. When both celestial bodies are pulling together the 'spring tide' results, which means a 50-foot variation from high to low. This occurs at new and full moon. A week later, when the sun and moon work in opposition, the difference is only 32 feet between high and low water. The bay of Fundy, having a funnel shape (150 miles wide at mouth from Yarmouth to Portland, while the upper estuary at Hantsport is only one mile wide), builds up a tidal influence from 10 feet at the mouth to an average of 45 feet at Hantsport.

Jan 1, 1948

By H. Stillman

The International Copper Association, Ltd. (ICA) is responsible for guiding strategy and policy, and funding international initiatives that help deliver the benefits of copper around the world. ICA's technology initiative supports this mission by funding pre-competitive technology development and accelerating the commercialization of new copper-related technologies. The R&D portfolio includes some projects that defend existing applications such as plumbing tube and data cabling, but the majority of projects are designed to enable new applications for copper. The current technology portfolio is focused on leveraging copper's unique electrical, thermal, mechanical and antimicrobial properties to define and expand the role of copper in areas poised for future technological growth: reducing disease transmission, sustainable energy generation, reducing the environmental impact of production processes, and in increasing energy efficiency. Projects related to these areas are conducted at qualified external organizations including universities, early-stage firms, and large OEMs worldwide. This talk will provide an overview of ICA's technology initiative's principles, projects and partnerships to stimulate the audience to think about copper-related innovations.

Jan 1, 2007

By B. Loveday, G. W. Delaney, S. Cummins

"Applying DEM to prediction of tumbling mill performance is challenging because several different modes of breakage are active in the process. As our knowledge of breakage and computational capacity improve, it is worth revisiting previous simulation tasks which did not produce a satisfactorily realistic description of a measured process. At SAG 2006, we reported the simulated and measured outcomes of treating a well characterised ore in a 1.2 m diameter mill. This well instrumented, pilot scale mill at the University of KwaZulu-Natal has been combined with some new approaches to ore testing to allow different modes of breakage to be tested. The mill design allows the rate of generation of fine material to be measured in close to real time for autogenous and SAG mill charges. The updated simulation model estimates mass loss with particle evolution and embeds the cumulative damage and breakage.The simulated results are compared with the measured results. Issues such as relating modelling inputs to particle breakage characterisation data and the accuracy of the predictions of the models are discussed."

Jan 1, 2012

By D. W. Davis, P. Landais, L. J. Robb

Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Ph-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter Ol3C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoidand sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994

By Marc C. Bétoumay

Workplace safety, health, climatic conditions and rising oil prices are aspects that are important to the mining industry. The need for cleaner energy for underground mine vehicles is requiring serious consideration. A number of alternate energy systems offer clean solutions to diesel emissions while maintaining the current liberty of vehicle movement. This watershed article provides a broad comparison of cleaner diesel and alternative energies for underground production vehicles. Most alternate energies and clean diesel have already been tested in underground production vehicles. There are no technology gaps that would prevent the development of commercial alternative energy power plants, but in the case of alternate energies, second and third generation versions will be required to fully test for safety and operation viability. Full regulatory development is also required and could be done in parallel to power plant testing. Vehicle operation and maintenance manpower would be the same for alternate energy application as for clean diesel. Capital cost for alternate energy power plants will remain higher until the medium term. Owing to significant ventilation savings possible with alternate technologies, operating costs would be reduced.

May 1, 2011

By Peter Makuvise, Alain M. Bantshi

"The Mazowe Gold Mine is managed by Metallon Gold (Zimbabwe) and is situated in the west-central part of the Harare greenstone belt. Orebodies here generally comprise shear zones which are in-filled with gold-bearing sulphides and quartz. The mineralised zones are up to 1 m in width, have average grades of 4 to 5 g/t, and mostly dip between 10º and 60º to the north.Mazowe Mine is one of the oldest mines in Zimbabwe, and exploration and development in this region dates back to 1890, with over 1.4 million ounces of gold produced to date. Mazowe mine comprises two underground operations, Mazowe and the BSV sections. Ore is processed in a single plant which consists of conventional crushing and milling and carbon-in-leach facility.Baldmin Projects was awarded the contract for the design, construction and commissioning of the 60,000 tonnes per month plant at Mazowe mine in 2014 for the processing of sand and slimes tailings from previous operations at Mazowe mine. The average grade of the tailings is 1.1 g/t. The plant consists of feed preparation, grinding, flotation, thickening of flotation concentrate, and carbon in leach (CIL). A pump station for hydraulic mining of the slimes tailings dam also part of the plant.Key features of the Mazowe sands Plant are described and include:• Hydraulic mining of gold tailings dump.• Feed preparation section that includes a (W x L) 2.4 m wide x 4.8 m trash screen, 250 m3 surge tank, a cluster cyclones with 2 x 500 mm diam. Cyclone.• Comminution circuit designed for a bond work index range of 10-12 kwh/tonne. comminution circuit is constituted with 3 ball mills, 1.83 m diam. X 6.71 m Long, 280 kW.• Flotation circuit comprising rougher bank, scavenger bank and cleaner bank. Rougher Scavenger bank is constituted of 6 x 6m3 flotation cells and 3 x 30 m3 flotation cells and the cleaner is constituted of 3 x 6 m3 flotation cells.• Concentrate Thickening with 6 m diam. Thickener.• Concentrate CIL (carbon in leaching): CIL circuit is comprised of 7 tanks with 2 leach tanks and 5 Carbon in leach."

Jan 1, 2017

By V. N. Rampton, C. F. Gleeson

"Exploration results over three overburden drilling anomalies defined by the Ontario Geological Survey in 1981 in the Kirkland Lake area, Ontario are presented. The anomalies come from lowland areas where overburden is thickest. By mapping the bedrock and surficial geology, by prospecting, humus sampling and shallow till sampling over the surrounding upland surfaces, one can initially evaluate such overburden drill anomalies without costly reverse circulation drilling. The drilling should follow, if necessary, only after surficial base data has been obtained. Preliminary work on these three properties has defined the presence of at least two styles of gold mineralization. One occurs in silicified zones in intermediate volcanics closely associated with northwesterly trending faults and shear zones. The second occurs in quartz-carbonate alternation zones in volcanics intruded by quartz-feldspar porphyry dykes. IntroductionThe three examples presented in this paper present first-hand information on an approach to the follow up of several geochemical anomalies that were found by the Ontario Geological Survey when they carried out reverse circulation overburden drilling as part of the Kirkland Lake Initiative Program (KLIP) in 1980 (Routledge et al., 1981). The initial approach is relatively simple, systematic, and cost and technically effective. It readies the properties for further exploration, or conversely, it could downgrade the properties as viable gold targets."

Jan 1, 1987

By S. R. Gilbert, C. O. Bounds, R. R. Ice

"Many ores are upgraded to produce auriferous sulphide concentrates (principally pyrite) which are not amenable to direct cyanidation. Often these refractory gold-bearing concentrates contain undesirable elements such as arsenic, antimony, etc., which present environmental and/or processing problems. The pretreatment techniques most often considered for processing these concentrates prior to cyanidation include roasting, pressure oxidation, chemical oxidation, pre-aeration, and recently, bacterial oxidation. In this paper, the technical performance and economics of bacterial pre-oxidation vs the classical roasting approach for treating a specific auriferous pyrite concentrate are compared. The results provide flow sheets, preliminary operating and capital cost estimates, and rates of return for the two processes and demonstrate the potential advantages of bacterial pre-oxidation. IntroductionThe increased attention that gold has received in the last ten years has prompted mining companies to look for lower grade orebodies. Many of these low-grade ores do not respond well to conventional direct cyanidation recovery techniques. As free-milling ores decline, gold is sought in refractory environments which, ultimately, drive up the treatment costs.There are a number of reasons for a gold ore to be termed refractory, most of which can be identified by thorough mineralogical examination. The mineralogical occurrence of gold can, to a great extent, impact the method by which the ore is treated and, consequently, the capital and operating costs. Gold in a refractory ore can often occur as discrete particles locked in a host of silicate or carbonate gangue, or associated with sulphides or sulphosalts. Depending on its particle size, gold can be liberated and recovered by mechanical size reduction such as regrinding. This approach is most effective for gold in the 10 - 50 micron range. Gold can also be associated with clay, iron hydroxides, or other minerals which tend to coat the gold surface and inhibit the penetration of the cyanide solution, resulting in poor plant recovery. Because of their resistance to cyanide dissolution, gold tellurides and other refractory gold minerals are also responsible for losses to the tailings. For these reasons, it is paramount that the mineralogical occurrence of the gold be thoroughly and accurately determined before selecting a final process flowsheet."

Jan 1, 1988

By Jean-Marc Simard, Vincent Jourdain, Denis W. Roy

"Seven lithologic units, informally characterized, were recognized in the vicinity of the Montauban orebody. The first five lie in stratigraphic order. From structural bottom to structural top these are: (1) grey composite gneiss; (2) dark grey quartz-biotite gneiss; (3) quartz-biotite-garnet gneiss hosting several calcareous, aluminous and magnesian members and gold mineralization; (4) light grey quartz-muscovite-(sericite)-biotite gneiss; and (5) metabasafts. The last two intrude the sequence: (6) amphibolite dykes and (7) pegmatite veins. The orebody lies on the inverted limb of an overturned synform verging to the west with the metabasafts marking the core of the fold. As the foliation is folded, this fold is attributed to deformation ""D2""; deformation ""DI"" being responsible for the formation of the foliation. A late brittle deformation developed shear zones with probable strike-slip motions. The refined stratigraphy and the identification of the structural position of the orebody provide new tools for regional interpretation and prospecting.RESUMESept unités lithologiques ont été définies informeffement à proximité du gisement de Montauban. Les cinq premieres reposent en ordre stratigraphique; ce sont de la base au sommet structural: (1) le ""gneiss mixte gris""; (2) le gneiss gris forcé à quartz biotite; (3) le gneiss a quartz-biotite-grenat comprenant plusieurs membres calcareux, alumineux et magnésiens ainsi que la minéralisation aurifère; (4) le gneiss gris clair à quartz muscovite- Isericitel-biotite; et (5) les métabasaltes. Les deux autres unites sont intrusives dans la sequence: (6) les dykes d ‘amphibolite et (7) les veines de pegmatite. Le gisement se sitlie sur le flanc inverse d'un synforme déverse vers I' ouest dont les métabasaltes occuperaient le cœur. Comm e la foliation est plissée, ce pli est considère appartenir d la deformation ""D2""; la deformat ion ""DI"" etant responsable de la formation de lafoliation. Une deformation cassante tardive se traduit par des zones de cisaillement, d rejet apparemment directionnel. Cette stratigraphie plus précisé et l'indentification de la position structurale du gisement fournissent de nouveaux omits de prospection et d'interprétation regionalé."

Jan 1, 1987

By H. C. Boydell

Those connected with mining, prospecting, or mining geology in northern Ontario are familiar with the fact that it is a comparatively unusual thing to have assayed a sample for which the assay report shows no gold. Values of 20 cents to 80 cents per ton, or even higher, are extremely common. Whilst contamination by fluxes, faulty manipulation, or a desire, on the part of the assayer, to sugar-coat the pill for the client, may account for 20 to 40 cent values at times, it is un1ikely that they would a1ways do so. Exonerating the assayer from being necessarily at fault, what can be the cause of such a widespread distribution of gold (and silver) in minute quantities- of a dissemination .that, in the writer's experience, and so far as he is? aware, is not met with on a simi1ar scale in other parts of the world? Explanations that suggest themselves are, that the dissemination is due: 1. To a very widespread auriferous minera1ization, post-dating (epigenetic) the formation of the rocks in which it occurs. 2. To a general syngenetic distribution of gold in the volcanic rocks of Keewatin age that form so large a part of the sections of northern Ontario that have been prospected.

Jan 1, 1928

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012

By J. A. Hansuld

"THIS SESSION marks something of a milestone in that it is, as far as I know, the first session at a CIM Annual Meeting devoted entirely to exploration geochemistry. This is an indication of the general acceptance and widespread recognition by industry of geochemistry in mineral exploration. As a first, I hope it proves sufficiently successful and interesting that geochemical exploration sessions will become a routine part of future CIM annual meetings. The greater use and acceptance of geochemistry has resulted in many investigations and advances, especially in areas such as the Canadian Shield. For a first session on geochemistry, the meeting in Quebec suggested an ideal opportunity to assess these advances and report on the current application of geochemistry in the Shield. The theme of the session is ""Geochemical Exploration in the Canadian Shield - The State of the Art."" A series of six papers will be presented dealing with the various dispersion media - rocks, heavy minerals, ""soils"", lake sediments, waters and vegetation. As a background to the individual presentations, I would like to take a few minutes to briefly trace the history of the use of geochemistry in the Canadian Shield."

Jan 1, 1971