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By Y. Hayashi, A. Fuwa

To analyze zinc vaporization kinetics of zinc smelting slag in the ISP furnace, reduction reaction rate of zinc oxide from ZnO-FeOx-CaO-SiO2 slag system with CO-CO2-Ar gas mixtures has been measured by a therm o-gravim etric apparatus at various ZnO content, Pco, and temperature. The reduction rate was measured under a chemical reaction control in the initial three minutes where surface zinc content can be assumed constant. Through the reaction rate dependency analysis on ZnO contents, Pco and temperature, discussion has been made on its reaction mechanistic information in terms of rate coefficient, adsorption/desorption mechanism and activation energy.

Jan 1, 2008

By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By Å. Partapuoli, M. Henriksson, P. Wikström, J. Worth, G. Adolfsson

The control of AG mills fed by ores with harder and softer components can be challenging due to the sensitivity of the mill to the ratio of hard to soft components. The mills at LKAB’s iron ore operations are generally well controlled, but there are periods when the throughput falls off dramatically, due to a loss of mill filling. As the ore is upgraded in the sorting plant through magnetic separation prior to milling, this presents an opportunity to manipulate the feed blend in advance. In order to assess this opportunity, a fullscale mill charge was dumped and assayed by size to quantify the build-up of competent waste in the mills. This was supplemented by pilot and locked-cycle laboratory tests at a wide range of feed blends in order to facilitate the development of an appropriate multi-component AG mill model. This paper reports the experimental campaign requirements and methodologies, as well as the major outcomes from analysis and modelling exercises using the industrial, pilot and laboratory multi-component data.

Jan 1, 2012

By Bennett McLaughlin, Gille Brousseau, John F. Cook

"La Mine Bousquet commenced operations in October 1979. Mining has been by underground methods from two main zones which dip steeply to the south , Sub-level stoping methods with following fill are used.The orebody and immediate country rocks are sericitic and highly schistose. The intensity of schistosity varies significantly and poor ground conditions prevail, especially within the orebody,Initially few mining problems were encountered but in May 1981, significant damage occurred. A system of stabilizing pillars was introduced with improved support systems. Predevelopment in ore and pre-drilling of blastholes were reduced with extra footwall development.Damage has continued to occur on a regular basis particularly during the spring thaw. Generally, the adverse conditions have been successfully overcome.IntroductionMost of the mining problems that have been experienced at Bousquet have been caused by poor ground conditions . This pa per describes these conditions, considers the cause and describes the ways in which the conditions have been dealt with . Despite the problems, Bousquet is a successful operation which in 1983 produced 95,000 ozs of gold from 514,000 tons of ore."

Jan 1, 1985

By K. M. Ed

AN explosive is a solid or liquid substance which, when fired by some means, changes into a gaseous product occupying a volume very much greater than its original volume. The great speed at which this change takes place causes the explosive to exert a sudden blow on adjacent material. It is this action which is effective in blasting operations when the explosive, confined in a shot-hole, is fired. All explosives are similar in one respect, in that the change into the gaseous state is accompanied by the production of hot gases or flame. This results from the rapid combustion of the solid or liquid ingredients. Ex-plosives differ greatly, however, in the speed at which the reaction takes place. Black blasting powder, for instance, reacts comparatively slowly, hence the flame persists for an appreciable length of time. High explosives, on the other hand, react much more quickly; consequently, the flame is of much shorter duration. In 'closed-light' or 'gaseous' coal mines, the use of ordinary explosives is generally prohibited, due to their inherent ability to ignite gas or coal-dust by reason of the flame which they produce when fired. For instance, black blasting powder, which produces a flame of long duration, is not ordinarily considered safe to use in such mines; neither are ordinary dynamites, as their flames, while shorter than that of black blasting powder are, nevertheless, of sufficient temperature and duration to cause ignition of fire-damp or coal-dust. For this reason, specially formulated high explosives, called 'permitted' explosives, should invariably be used in such mines.

Jan 1, 1940

By H. L. Cameron

General Statement In July, 1948, experimental aerial photography o shallow water zones on Northumberland strait was carried out by the Nova Scotia Research Foundation. This work was designed to test the feasibility of aerial photography for coastal surveys o various types, including seaweed and bottom detail surveys. In the course of the work at Lismore, undersea faulting was noted visually and was later clearly apparent in the photographs. In order to prove beyond doubt that the lineations photographed are actually faults, a ground check was made, and terrestrial stereoscopic photographs were obtained of these features where they intersect the shore line. There can be no doubt of their nature, and the type of faulting is probably thrusting due to compressive forces. This is indicated by the successive right- and left-hand displacements on intersecting faults. The age of the fracturing is post Lower-Pennsylvanian (Lismore) and is correlated with similar compression faulting in western Cape Breton. As far as can be ascertained, this is the first time that subsea faulting has been photographed, though it is quite possible that similar structures have been observed elsewhere. Location and Area Lismore is on Northumberland strait, approximately thirty-five miles east of Pictou (see index map, Figure 1). The area mapped from aerial photographs (Figure 2) is a strip approximately two miles long by a quarter of a mile wide. Figure 3 shows a stereo-pair of the aerial photographs used to construct this map. The terrestrial stereoscopic photographs (Figure 4) show one of the faults.

Jan 1, 1949

By K. B. Han, S. Winkler, M. J. Benoit, M. J. Worswick

"Automotive heat exchangers are fabricated by forming multi-layered aluminum (Al) alloy brazing sheets into the desired geometry and subsequently passing the assembly through a furnace for brazing. As manufacturers seek to use thinner gauge and higher strength sheet to reduce vehicle weight, forming of the Al alloy sheets has become a challenge. Warm forming has previously proven to allay these forming concerns, but no consideration was given to the effect of increasing the forming temperature on brazing. Recently, it was shown that annealed sheet was more susceptible to the detrimental phenomenon of liquid film migration (LFM) during brazing if formed above 150°C, while work hardened sheets showed no increased susceptibility to LFM with increasing forming temperature, up to 250°C. In the current study, the brazing performance of simulated battery cooling plates was investigated. The plates were fabricated both from fully annealed and work hardened sheets. Brazing was assessed by microstructural evolution during a brazing cycle. The post-brazed microstructure varied with strain and forming temperature in plates made from annealed sheets, while no variation in microstructure with location or forming temperature was observed in plates formed from work hardened sheets.INTRODUCTION Since the 1970’s, one common method of fabricating automotive heat exchangers has been by forming multi-layered aluminum (Al) alloy sheets, and subsequently brazing the formed components together in a controlled atmosphere furnace. The Al alloy sheets used are comprised of at least two Al alloys roll bonded together, but can consist of additional layers, depending on the application; at minimum, the sheets are comprised of a core and clad layer. The core layer, often an AA3xxx alloy, remains solid throughout processing and provides strength to the assembly. The clad layer is always one of the AA4xxx series alloys which, due to their high silicon (Si) content, have a melting temperature range well below that of the core alloy. When the sheet is passed through the brazing furnace, the clad alloy melts to provide the brazed joint filler metal throughout the assembly, while the core alloy remains solid. In order to achieve cost and weight savings, heat exchanger fabricators have used Al alloy sheets with reduced thickness. However, deformation and brazing of these increasingly thin components remains a concern (Zhao & Woods, 2013). Furthermore, springback has been observed after forming sheets of higher initial strength (i.e. work hardened conditions), leading to flatness issues of formed components. Consequently, the ability to form high quality brazed joints is difficult in components formed from higher strength brazing sheets."

Jan 1, 2018

By Gonzalo Bernstein, David G. Meadows, German Naranjo, Edgardo Tapia

"During the last decade Antofagasta Minerals’ Los Pelambres Mine has dramatically increased its ore throughput following the fast initial phase ramp up through a series of planned incremental expansions. The original 85,000 mtpd, two SAG line plant was commissioned in 1999 and rapidly exceeded nameplate tonnage in only a few months. Following this, the inclusion of a pebble crushing circuit resulted in throughputs in excess of 114,000 mtpd and a recent, final third line SAG and ball mill addition have taken the plant to over 175,000 mtpd even with increasing ore hardness and changing ore feed characteristics. The progressive changes are described in this paper together with how the technical challenges have been met.INTRODUCTIONMinera Los Pelambres is a world class copper-molybdenum operation located in the Salamanca area in Chile, in region four, approximately 500 km north east of Santiago, the capital of Chile. In the late 1990s Antofagasta Minerals developed the Minera Los Pelambres project in Chile at an investment cost of approximately $1.3 billion USDs. The project construction was successfully led and completed by Bechtel Corporation in 1999 and within a matter of months the plant was already exceeding the nameplate capacity of 85,000 mtpd. In 2001 a pebble crushing circuit was added to raise the capacity to 114,000 mtpd. In the early part of 2003-2004, it was recognized that the hardness profile was changing with depth and that in order to maintain the plant capacity additional power would be needed in the SAG mills together with upgrading of the primary crusher. In conjunction with these changes a fifth ball mill and a second primary crusher station would also need to be installed. A further detailed engineering study and evaluation was initiated by Minera Los Pelambres. This was lead by Bechtel Corporation with major design contributions from FLSmidth and Siemens in order to establish the re-powering requirements for the SAG mills. These re-powering changes together with the inclusion of a pebble crushing circuit took the plant to up to 125,000 mtpd even with harder more competent ores. Finally in the last two years an additional grinding line has been added to take the capacity to consistently over 175,000 mtpd. The third line was installed in a record time of 256 days. A schematic of the current comminution circuit, discussed in this paper, is shown in Figure 2."

Jan 1, 2012

By S. Kashani-Nejad

The formation of oxides during the dehydration of MgC12,6H20, Bischofite, was studied by heating the bischofite over a range of time and temperatures in ambient atmosphere. Using a methanol-leaching technique developed by authors, the oxides that formed were isolated, identified and assayed. Three distinct regions of oxide stability were identified. The oxide produced at dehydration temperatures less than 300 °C was Mg2(OH)3C1,2H2O; at 300 °C, mixtures of MgOHC1 and Mg2(OH)3C1.2H2O were formed and at 400 °C, MgOHC1 was the only oxide produced. The presence of MgO observed in the products of the dehydration of bischofite at temperatures above 400 °C was due to the thermal decomposition of the MgOHC1 that was formed while the sample was heating to over 400 °C.

Jan 1, 2006

By S. H. Lucas

"This paper describes the development and application of single-stage fluidized bed continuous ion exchange to the following processes: removal of base metals from mine water; cyanide removal from gold mill waste; uranium removal from sulphuric acid leach liquor; and uranium removal from mine water. IntroductionThe recovery of metals by fixed bed ion exchange has been practiced for many years. However, the operation has been semi-continuous and can only treat clarified liquors. Substantial savings could be made if the operation were continuous, thus reducing the resin inventory, and if the costly filtration and clarification steps could be eliminated. Work has been in progress over the past twenty-five years on the recovery of metals from unfiltered ore leach slurries, heap leach liquors and mine drainage waters containing a small amount of suspended solids. In the case of dilute waste solutions, with suspended matter and high flow rates, filtration is usually prohibitively expensive.Continuous ion exchange operation using fluidized beds has made it possible to reduce considerably the resin inventory and to allow the treatment of unclarified liquors and slurries. The subject has been reviewed on several occasions (1. 2. 3, 4). Although fluidized beds in multi-stage columns are an improvement over previous resin-in-pulp treatment, they have complicated internal structure and I or involved automatic control systems to move the resin stages.Slater and Prud'homme performed studies on multi-stage fluid beds, and concluded that the performance of single, deep fluidized beds of resin with continuous or semi-continuous flow of both phases would be worth investigating, particularly in the case of very dilute metal solutionsoi, A pilot plant was designed and built at CANMET in a cooperative project with Dr. Slateroi. The use of deep fluidized beds of resin (with a large height/diameter ratio) for treating dilute solutions has the attraction of engineering simplicity. Extreme simplicity of equipment design is considered of paramount importance when treating, for example, mine waters at high flow rates, possibly of the order of several million gallons per day. This paper describes the development of the concept of single-stage fluidized bed continuous ion exchange arid reviews the pilotplant development of processes for the treatment of base metal mine water, cyanide waste water, uranium leach liquor and uranium mine water."

Jan 1, 1980

By J. P. Mogan, E. D. Dainty

Polynuclear aromatic hydrocarbon (PAH) levels were measured in underground mines in the vicinity of diesel vehicles equipped with several types of emission control hardware. In general, the emission control devices appeared to reduce PAH levels, but the companion mutagen study suggested that the reduction might not always be beneficial. All underground PAH concentrations were below the threshold at which a significant impact on health might be expected, but recent animal exposure studies have indicated that PAHs may not be the primary hazard from chronic diesel fume exposure.

Jan 1, 1994

By J. Roth

"While not taking issue with the general thesis expressed in Dr. Ridge's analysis of the role of genetic concepts versus observational data in ore exploration (Ridge, 1983), the criticism could be offered that the author tends to slight the importance of conceptual (i.e. theoretical) models in mineral exploration.As a general rule, observational data in science lacks significance and utility without a theoretical construct to organize those observations. Theory in turn dictates what observations are made-and which ones are judged important. Thus, for example, prior to the elaboration-and acceptance- of the current model for volcanogenic base metal deposits, the structural aspect s of these deposits were most closely observed and studied by explorationists. The nature of the enclosing rocks and any attendant alteration was given minimal attention, and certainly didn't figure prominently as an exploration guide.Similarly, the importance of alteration features to exploration for porphyry copper-molybdenum deposits was only perceived when a theoretical model was developed to account for these aspects. Indeed, many of these porphyry copper deposits were regarded as epigenetic vein deposits by geologists of an earlier era observing and examining on a different physical scale-and with a different theoretical bias.In constructing and evaluating such conceptual models, explorationists primarily rely on observation data and proximate associations; speculative thoughts as to ultimate provenance or crustal evolution clearly play a subordinate role, as Dr. Ridge argues. This, however, should not obscure the fact that concepts and theories do indeed exert a major influence in mineral exploration."

Jan 1, 1983

By Göckmann. Klau

"IntroductionCopper has been recycled ever since its discovery. Even in Graeco-Roman times recycling of this resistant, and thus valuable material was carried out as a matter of course. Just take, as an early example, the Colossus of Rhodes: after the figure collapsed during an earthquake, the bronze parts were melted down into ingots and sold.Copper is a material which can be recycled again and again because copper produced from recycling is not different from copper originating from primary materials. This is mainly due to electrolytical copper refining whereby not only the base metals but also the precious metals can be removed. In contrast, with aluminum and iron only the more electropositive elements can be removed by refining, and the resultant scrap must, therefore, be sorted mechanically into various alloys for subsequent smelting.The recycling rate for different base metals is given in Table 1. Despite this ideal prerequisite, the generally quoted recycling rate of copper of about 40070 appears rather low. However, it must not be forgotten that the recycling rate is defined as the ratio of the annually utilized quantities of copper scrap and the annual production figures (Table 2). Moreover due to the economic growth over the last 30 years the availability of copper from scrap materials is lower than its consumption because copper is principally employed in very long-life consumer durables and only returns to the recycling circuit after many years. The average time for the copper of some goods to be recycled is detailed in Figure 1."

Jan 1, 1992

By Rashid Bashir

The presence of groundwater in the form of large aquifers can have an important influence on investment decisions for underground mines. The design for such mines requires development of special mining methods, and mine dewatering infrastructure to avoid hazards during shaft sinking and underground development. The costs associated with mine drainage control and Mine Dewatering Systems (MDS) are relatively small compared to the huge consequential losses that can occur in case of an uncontrolled inflow and subsequent flooding of the mine. The design of MDS needs consideration of accurate prediction of the maximum uncontrolled inflow rate, availability of the system during an uncontrolled inflow while the inflow is mitigated, and decision on pumping system technology to have capability to operate under water. The research presented in this paper provides a theoretical framework for a reliability based design procedure which takes into account the uncertainty in the estimate of the maximum uncontrolled inflow, performance of the system during the period of an uncontrolled inflow and a methodology to decide on appropriate pumping technology considering the reliability of the system and available underground storage. The reliability based mine design procedure integrates the ideas of Effective Reserve and Hydraulic Reliability Index to come up with a unified methodology for design of Mine Dewatering Systems.

Aug 1, 2010

By F. Flynn, P. Downey, G. Ritson

"Bell Creek Mill which has been in continuous operation since 1987 has undergone numerous operational changes in the past three years. The addition of over 2. 5 million tons of resource at over 13 git from Hoyle Pond Mine precipitated an expansion program for the Bell Creek Mill. This paper discusses the major changes that have occurred over the past two years to increase throughput and efficiencies. In addition, the refractory ore treatment options are also discussed.IntroductionThe Bell Creek Mill is located in the Timmins Goldcamp approximately 8km NE of porcupine Ontario. (Fig I.)The mill was originally constructed by Camamax in 1987 to treat the Bell Creek ore at a design throughput of 350tpd. The flowsheet (Fig 2.) consisted of two stage crushing, grinding, thickening, leach and drum filtration with gold recovery by Merrill Crowe.As ore depleted at Bell Creek, the Mill was purchased by Falconbridge to process ore from their Hoyle Pond property. Kinross purchased the Hoyle Pond property and Bell Creek Mill from Falconbridge in 1992.The successful exploration program at Hoyle Pond has led to several expansions and process design changes, with further changes planned over the next twelve months.In 1994, the mine produced 61,865 oz. of gold at an average cost of 197US$ per oz. In 1995 production was 91, 611 oz. at a cost of 187US$ per oz. Projecting the nine months ended September 30, production for 1996 will be 155,000 oz. at a cost of 165US$ per oz.In early 1997, the CIP expansion will be complete, with a target of 175,000 oz. at a cost of 176US$ per oz for 1997. The mill throughput will have increased from 400tpd to 1500tpd between 1994 and 1997.The changes to Bell Creek since 1994 have been numerous with very little of the existing equipment still in operation. The total cost of the expansion to date is 15 million C$. This paper discusses the major projects carried out during in this time. The focus will be to highlight the justification of each project, the design and engineering, some of the initial start-up problems and solutions.Figure 3 shows a plan of the existing mill facility together with the various additions that were carried out."

Jan 1, 1997

By G. Viramontes-Gamboa, A. Encinas-Oropesa, S. Velázquez-Roque, L. A. Ibarra-Bracamontes

Some industrially relevant applications for pyrite nano/micro-particles have been proposed in the literature, such as the catalysis of chalcopyrite leaching, the removal of As(III), As(V) and Cr(VI) from solution, as photovoltaic devices, and others. Even though pyrite can be recovered from solution by flotation, for some applications it may be beneficial to provide pyrite with magnetic properties. In this work, a methodology to synthesize magnetic shell/core composites made of pyrite as the shell and either natural or synthetic magnetite as the core is presented. The size of the magnetic composite may range from tenths to hundreds of microns. The synthesis is basically made by stoichiometrically mixing iron nano/micro-particles with sulfur microparticles with magnetite particles, and bringing the mixture in an oxygen free atmosphere from 200 to 300 °C for 4 h. The composites were characterized by optical microscopy, Scanning Electron Microscopy and X-Ray diffraction.

Jan 1, 2014

By M. J. Sapko, R. W. Watson, E. S. Weiss

The relative incerdivity of several blasting agents was evaluated in the Bureau's Bruceton Experimental Mine (BEM) . The minimum charge weights resulting in the ignition of predispersed oil shale dust clouds were measured for each of the explosives. A 400 g unstennned charge of ANFO (ammonium nitrate-fuel oil) was sufficient to initiate an oil shale dust explosion, whereas a 1000 g unstenuned charge of an emulsion blend did not ignite the dust even with the addition of 4% methane gas. Several stenuning materials were evaluated in the BEM for their effectiveness in preventing the ignition of near stoichiometric methane-air mixtures. Water stenuning was superior to all other inhibitors tested against methane. Explosibility testing of fine sulfide ore dust in a 20 L chamber and in the BEM show that the dust is capable of propagating an explosion given nominal concentrations of 700 to 800 g/m3. Results are encouraging and irrlicate that there is merit in pursuing explosive composition as a means of reducing ignition probability of oil shale and sulfide dust clouds generated during nonnal blasting operations. The proper selection of explosives and stenuning materials should significantly reduce the probability of secondacy dust explosions in oil shale and sulfide ore mining.

May 11, 1988

By M. B. M. Monte, M. L. Torem, E. R. Pecanha, A. G. Merma

The recent literature has unveiled the potential use of microbial strains in mineral bioprocessing. This study presents the use of a Gram-positive bacterium (Bacillus subtilis) as bioreagent for hematite flotation. The bacterium presents the ability to modify the properties of mineral surface (electrophoretic mobility and hydrophobicity). It was studied the electrokinetic behavior of hematite particles, before and after the interaction with the bacterial cells. The results revealed a shift of the isoelectric point (IEP) of the hematite after interaction with bacterial cells, suggesting a chemical adsorption mechanism. Moreover, after bacterial conditioning, the zeta potential curve of hematite presented high values in the alkaline pH range. The hematite and the bacterial surfaces presented contact angle values around 27.4° and 41.0°, respectively. According to the results, the B. subtilis strain was capable of modifying the hematite surface, and after interaction the hematite surface presented a contact angle value around 46.0°. The flotation tests were carried out in a modified Hallimond tube. The experiments revealed a significant increase in hematite flotability using the Gram-positive strain as bioreagent. The tests pointed out a maximum recovery of hematite in the presence of 600 mg/L and pH 5. Therefore, the results from this study showed the potential use of the B. subtilis strain as a biocollector for hematite flotation, and its possible application in the mineral flotation industry.

Jan 1, 2016

By Joachim von Scheele

An oxyfuel-based technology - OXYFINES - has been introduced for in-plant recycling. It provides fines, dust, sludge (without any drying-step) and other by-products arising in the steel and metal producing industries to be recycled directly back into existing processes or a separate unit on-site. Results from full-scale installation (20,000 tpy) for dust treatment, full-scale and pilot-scale trials with dry and wet materials in the steel and ferroalloy industries are presented. Processing rates at 3.5 t/h have been demonstrated. The product is agglomerates or lumpy pieces, the latter if the product has passed an all-liquid stage and thereafter been crushed. The technology does not only provide a solution to the problems connected to dust and sludge generated in metal production. It also turns these materials into a low-cost raw material useful for the production in question, thus replacing part of the raw material input in electric arc furnaces, blast furnaces, etc. Elements harmful to re-use of the processed dust or sludge, e.g., zinc and alkaline components in steel production, are removed as secondary dust, and material yield of main components for re-use is very high, about 98%. The paper reviews the concept, the results obtained and its status; its use for sludge recycling is emphasized.

Jan 1, 2004

By Donald J. Farrish

"Mr. Chairman and fellow CMP members, most of these remarks will be made with particular reference to copper concentrate but the basics apply generally to other metal concentrates as well.For very good reasons, using copper as an example, smelting capacity usually is located either close to mine production or close to areas of high copper consumption. The mine producer can add on smelting capacity to insure that the copper in his concentrate can be processed into a marketable form under more or less controlled conditions including costs. On the other hand, the consumer wishing to assure a better supply of copper likewise can build smelting capacity and offer treatment charges attractive enough to discourage mines from investing in their own facilities. In this regard, freight is an important factor. Bulk shipments from the heart of Africa with a large overland component are uneconomic whereas concentrate movements from Australia or South America compare favourably with smaller metal shipments.A mine project which incorporates smelting capacity, will often, through the presence of this capacity, encourage active exploration and development of additional concentrate production in the vicinity. The usual result is that new mines within reasonable distance of the smelter will be able to avoid the capital required to build their own smelting and refining facilities and that the existing facilities will expand to appreciate economies of scale."

Jan 1, 1978