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By V. Pouyafar

In recent years semi-solid processing of steel alloys has gain more attention among researchers. Production of high quality complex steel parts with higher mechanical properties is the final goal for all these researches. A thorough understanding of the flow behavior of the metal under investigation is the key for a successful process design. The material used in this research is M2 tool steel. The experiments were performed using a Searl-type concentric cylindrical rheometer which is specially designed for high temperature rheological measurements up to 1500 ºC. The rheological techniques were consisted of continuous cooling experiments and isothermal holding and also shear rate step change experiments for different solid fractions. Based on the rheological data a single phase thixotropic model has been derived and adopted to the measured data. The state of the microstructure has been applied through a structural parameter. The model fits well with the experiments.

Oct 1, 2011

By R. D. Brown

On November 16, 1978, Finance Minister Chretien delivered his second formal budget in the House of Commons. Over-all, the provisions of the budget should provide moderate stimulus to the Canadian economy. With respect to the mining industry, the budget offers some welcome changes in the form of' improved write-offs for development expenses and social assets; higher investment tax credits; and a reduction in federal sales tax. On the other hand, income bond financing of new mineral ventures may be restricted.

Jan 1, 1979

By M. Solomon

Giant, sediment-hosted lead-zinc deposits in northern Australia fonned during development of Mid-Proterozoic extensional basins that overlie Lower Proterozoic basement. The basement in the Mount Isa area, exposed by folding and faulting, contains fractionated, high-heat-producing granites. These granites generate heat at a rate of about 6",Wm-3, probably sufficient to fonn giant lead-zinc deposits either by (a) driving episodic convection of saline basement and basin fluids for periods of IOS to 106 years at temperatures of about 230°C, or (b) heating basin fluids moving under the influence of topographic relief or fault movement. The presence or absence of such granites may form a vital component of the genetic model. Ore-fonning fluid flow was probably initiated by continent-scale, extensional basin fracturing.

Jan 1, 1992

By Saeid Akhavan

Accumulative roll bonding (ARB) is a severe plastic deformation process for achieving ultrafine grains in metallic sheets without changing the sample dimensions. In this study, ARB process was carried out on 5083 aluminum alloy sheets up to 6 cycles. In this process, the surfaces of the strips to be joined are roughened and cleaned and then stacked. After stacking, the specimen is roll-bonded by rolling using a 50% reduction. The rolled specimen is cut into two halves, and the above-mentioned procedure is repeated for several times. Microstructural characterizations were analyzed by transmition electron microscopy (TEM). Tension and Vickers hardness tests were performed on produced sheets for evaluating their mechanical properties. In order to clarify the failure mode, fracture surfaces after tensile tests were observed by scanning electron microscopy (SEM). The results indicated that at the early stages of ARB process, grains were subdivided by deformation induced boundaries. After several ARB cycles, lamellar structure elongated in the rolling direction contains lamellar boundaries was formed. With increasing the strain, mean spacing of lamellar boundaries decreased. Finally, continuous recrystallization resulted in a microstructure covered with small recrystallized grains with an average diameter below 100 nm at the end of four cycle. The tensile strength and hardness of the 6 cycle ARB processed 5083 aluminum alloy sheet increased about two and three times of the initial values, respectively. Results indicated conformity between mechanical evolutions and microstructural changes during ARB process. Fracture surfaces observations showed that failure mode in ARB processed aluminum is shear ductile rupture with elongated small dimples.

Oct 1, 2011

Evolution of Maintenance Practices. Mechanization processes in underground mining operation became stronger in the 70?s - 80?s. Did maintenance practices changed over the years ? What are the the major differences of today?s practices? Speaker, Robert Hamilton Working at different positions into maintenance organization since over 25 years, Robert has accumulated a various and rich experience of ways to maintain equipment. He started as mechanic on construction projects and open pit mines. Early in his career Robert had supervision's responsabilities. He started in open pit operation (QCM) and after in underground operation with Lac Minerals, working at Bousquet, Doyon and Louvicourt mines, as U/G mechanical foreman and mechanical general foreman, and Maintenance superintendant with Cambior . He also experienced the underground mines equipments supplier's side working with Sandvik Canada.

Feb 1, 2008

By M. Laframboise, M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterites has received considerable attention in recent years. High paymetals extraction, good selectivity, and advances in pressure hydrometallurgical technology are some of the reasons for this interest. Falconbridge Limited (Sudbury. Ontario) investigated the HPAL process using both fresh water and seawater for ore processing. The use of seawater resulted in a chloride concentration of 7.8 g/L in the autoclave feed. A test program was developed to study the effect of process water and leach temperature on the leaching behaviour of different ore compositions from the Koniambo deposit in New Caledonia. The work showed that salinity has a major effect on autoclave chemistry. This paper explores the results.

Jan 1, 2004

By A. E. Dyment

In formulating an explosive for any specific set of conditions, various factors must be taken into consideration. Is it to be subjected to water or moisture? .If so, it must be designed to have an inherent ability to resist water. Is it to be used in confined spaces underground, where ventilation is limited? If it is, it must possess qualities enabling it to form, upon explosion, the minimum quantity of noxious gases, such as carbon monoxide or oxides of nitrogen. Is it for use where low temperatures may possibly prevail? If so, it must be capable of resisting such temperatures without freezing. Is it for use where dust or inflammable gases may be present? If it is, then it must be so formulated as to produce, upon detonation, a flame of the lowest possible temperature and the shortest possible duration, in order to lessen the chance of ignition of such gas or dust. This is actually the essential property of a permitted explosive, and it is undoubtedly the most important characteristic of an explosive which is to be used in gassy or closed-light mines. This being the quality that distinguishes permitted explosives from other types, it is interesting to investigate the ways and means by which the low-flame-temperature characteristic is obtained . Generally speaking, such explosives are so designed as to contain comparatively small quantities of nitroglycerin and relatively large quantities of the strength-producing salt, ammonium nitrate. This ingredient does not develop as high a temperature upon explosion as does nitroglycerin, so its presence, in large measure, in place of nitroglycerin results in an explosive which has an inherent low-flame-temperature characteristic, as opposed to one which is .made up largely of nitroglycerin, which would ordinarily be in the high-flame-temperature class. Additions are also made of flame-quenching salts such as sodium chloride, ammonium chloride, and up to a certain limiting percentage of sodium nitrate. These salts, with the exception of the last, do not ordinarily take an active part in the explosive reaction, being present primarily to absorb heat liberated by the reacting ingredients.

Jan 1, 1947

By F. Moraw

The use of redox fuel cells in which oxygen is replaced by other oxidants such as ferric ions can have significant advantages [1-3]. For example, the cathodic reaction rate (e.g., exchange current density) can be increased by several orders of magnitude compared to the oxygen reduction reaction, and platinum group metal (PGM) catalysts are not required. As a result of the higher aqueous solubility of the oxidant in a redox fuel cell compared to that of oxygen the rate of mass transfer (e.g., limiting current density) is greater by several orders of magnitude. The redox fuel cell can achieve high efficiencies and has other fuel cell advantages. The main issue with the redox fuel cell cathode is the regeneration of the oxidant where low conversion efficiencies are achieved even with platinum group metal (PGM) catalysts. In the work discussed here the Fe3+/Fe2+ redox fuel cell cathode is characterized over a range of electrolyte concentrations and operating conditions, and electrode materials. Cyclic voltammetry and electrochemical impedance spectroscopy are mainly used for electrochemical characterization and mechanistic determination of the cathode redox couple. Further characterization with selected compositions and materials is done in a redox fuel cell (hydrogen - Fe3+/Fe2+). The mechanism and the advantages and disadvantages of the fuel cell redox cathode are discussed with respect to other approaches and other redox couples.

Jan 1, 2005

An Atomic Force Microscope (AFM) was used to measure the surface forces between glass sphere and silica plate in CnTAC1 (n=12, 14, 16, 18) solutions. The results showed the presence of long-range attractive forces that can be fitted to single exponential functions. With a given surfactant, the attractive force increased with increasing concentration, and reached a maximum at the point of charge neutralization (p.c.n.). The decrease in the attractive force above the p.c.n. is probably due to the inverse orientation of the surfactant molecules. A plot of the log (p.c.n.) vs. the number of carbons in the hydrocarbon chains of the Cn TACI homologues showed a linear relationship with a slope of -0.37, indicating that the surfactant adsorption entails a decrease in free energy by -0.85 kT per mole of CH2 (or CH3) group. These results suggest that the adsorption of long-chain surfactants is controlled by hydrocarbon chain association during the process of forming surface hemi-micelles (or domains). Possible origins of the long-range attractions are discussed on the basis of the results presented in this communication.

Jan 1, 2006

By Dennis Martin

What is Borehole Hoisting Borehole Hoisting is the use of a hoisting plant to hoist rock, workers and materials or both, vertically through a borehole, between a mine level and surface or between two levels of an underground mine. Screen and bolt ground support on walls of 5.5 m diameter borehole hoisting shaft

May 1, 2013

By S. Shairp

Copper is an impurity as well as a necessary reagent in the processing of zinc sulfide concentrate at Hudson Bay Mining & Smelting Co., Limited's (HBMS) zinc pressure leach plant. Copper is present in the zinc concentrate as chalcopyrite, which consumes reagents necessary for zinc leaching. A small percentage of copper precipitates in the autoclaves, discharge lines, and flash tanks, requiring maintenance of the equipment and disposal of the solids. Copper also precipitates in the neutralization stages and is removed to low levels in a specific copper removal stage of purification. Yet some copper, as copper sulfate, is required, along with potassium antimony tartrate, in the final purification stage to improve cobalt removal from the zinc sulfate solution prior to electrowinning. The behaviour of copper experienced at HBMS's zinc pressure leach plant is discussed.

Jan 1, 2008

By Sadough vanini Ali

The silicon anisotropic wet chemical etching technique is widely employed for fabricating various microelectromechanical system (MEMS) structures for advantages such as simple etching equipment and its capability to fabricate special microstructures. In this paper, we consider a complete theoretical derivation of the analytical solution based on geometrical and kinetic aspects of step flow on any surface and with a mathematical method we derive new equation for calculating the microscopic etch rates of surface atoms for a new range of concentrations and temperatures. Furthermore, a novel equation is presented for the calculation of the microscopic activation energies for some typical surface atoms and a new comparison of activation energies between some atoms is made that divides atoms into three categories. The results demonstrate agreement with the experimental results.

Oct 1, 2011

By M. Solomon

Abstract -Giant, sediment-hosted lead-zinc deposits in northern Australia formed during development of Mid-Proterozoic extensional basins that overlie Lower Proterozoic basement. The basement in the Mount Isa area, exposed by folding and faulting, contains fractionated, high-heat-producing granites. These granites generate heat at a rate of about 6 ?Wm-3, probably sufficient to form giant lead-zinc deposits either by (a) driving episodic convection of saline basement and basin fluids for periods of 105 to 106 years at temperatures of about 230°C, or (b) heating basin fluids moving under the influence of topographic relief or fault movement. The presence or absence of such granites may form a vital component of the genetic model. Ore-forming fluid flow was probably initiated by continent-scale, extensional basin fracturing.

Jan 1, 1992

By Marta Polgari, Eva Surova, Bohumil Molak

Abstract -The Ûrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organic­ geochemical methods. Both depositionallocalities were affected by the Lower Jurassic Toarcian anoxic event. Ûrkút shales are rich in organic matter (av. 2.94 wt% total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (?0.2 wt% TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decom­ position of organic matter that also involved Mn reduction.

Jan 1, 1992

By Andreea Catalina Gluhoi

Oxidation and reduction reactions of N-containing molecules have been studied over different types of gold-based catalysts, Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 (M, MI, MII=Li, Rb, Mg, Ce, Zr, Mn, Cu) prepared by deposition precipitation with urea. In general, all the catalysts were already active at low temperatures. NH3 oxidation was effectively catalyzed by Au/CuO/Al2O3, a catalyst which also gives the highest yield in N2. NO reduction by H2 performed over gold-based catalysts produced N2O, N2 and NH3 and N2O reduction resulted in the formation of dinitrogen. For all the reactions, large synergistic effects have been obtained by addition of different kind of additives.

Oct 1, 2003

By Eva Surová, Molák. Bohumil, Márta Polgári

The Úrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organicgeochemical methods. Both depositional localities were affected by the Lower Jurassic Toarcian anoxic event. UrkUt shales are rich in organic matter (av. 2.94 wtOJo total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (~0.2 wt % TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decomposition of organic matter that also involved Mn reduction.

Jan 1, 1992

By J. Donnelly, A. V. Deev

Substitution of coal and coke by renewable carbon (charcoal) is a low-risk and low-capital path to 50% or more reduction in net CO2 emissions by the steel industry. However, the high cost of charcoal and its low availability in most countries are barriers for the implementation of this approach. Development of an efficient wood carbonisation technology (slow pyrolysis) capable of producing large-volumes of charcoal from low-cost wood feed (e.g. wood wastes or forest residues) is an essential step towards the use of renewable carbon by the iron and steel industry. This paper provides a summary of the progress made over several years of R&D covering: (1) development and piloting of a new energy efficient slow pyrolysis process for production of charcoal from woody biomass at a competitive cost to the PCI coal, (2) techno-economic evaluation of the process. The main feature of the process is that the material undergoing pyrolysis is heated spontaneously without the supply of heat or air to the reactor. This makes it possible to carbonize large volumes of small-sized wood (e.g. wastes and residues) in a single reactor unit and capture high calorific value pyrolysis by-products

Jan 1, 2015

By Saeid Akhavan

Accumulative roll bonding (ARB) is a severe plastic deformation process for achieving ultrafine grains in metallic sheets without changing the sample dimensions. In this study, ARB process was carried out on 5083 aluminum alloy sheets up to 6 cycles. In this process, the surfaces of the strips to be joined are roughened and cleaned and then stacked. After stacking, the specimen is roll-bonded by rolling using a 50% reduction. The rolled specimen is cut into two halves, and the above-mentioned procedure is repeated for several times. Microstructural characterizations were analyzed by transmition electron microscopy (TEM). Tension and Vickers hardness tests were performed on produced sheets for evaluating their mechanical properties. Moreover the texture parameter of the ARB-ed samples was calculated using their XRD patterns and the related equation. Additionally, the texture evolution during the ARB process was demonstrate by analyzing the measured pole figures and orientation distribution functions (ODF) and skeleton lines. The results indicated that at the early stages of ARB process, grains were subdivided by deformation induced boundaries. After several ARB cycles continuous recrystallization resulted in a microstructure covered with small recrystallized grains with an average diameter below 100 nm at the end of four cycle. Texture analysis revealed fiber textures have been discovered with continiuose of the ARB process cupper. Brass, S and dillamor textures identify which their differences are in intensity of ARB process. Results indicated conformity between mechanical evolutions and texture evolutions during ARB process.

Oct 1, 2011

By M. Cimenti

Fuel cells have tremendous potential as power sources but much fundamental research is still required. One key component of the research is the experimental set-up used. In particular, the placement of the reference electrode is extremely significant in measuring the half-cell overpotential of solid oxide fuel cells, since differences in area, misalignments, and also differences in the kinetics of the working and counter electrodes can cause both scaling errors and frequency distortions of the measured impedance. The impedance of thin solid electrolyte cells of different electrode geometries has been calculated using the finite element method and the results compared to experimental values obtained for the oxygen reduction reaction on platinum.

Jan 1, 2005

By R. Bainbridge

THE cinnabar deposits of the Consolidated Mining and Smelting Company's Pinchi Lake property, situated near Fort St. James, B.C., were discovered and reported on by a Dominion Government geological party in 1937. Claims were staked by a group of local prospectors and, later, the Consolidated Mining and Smelting Company of Canada, Limited, took an option on the property. By the fall of 1939, exploration work had indicated ore of commercial quantity and grade, and laboratory tests had shown that standard methods of reduction, namely, roasting of the ore, followed by condensation of the mercury vapour produced, would result in satisfactory recovery. In June, 1940, construction of a 50-ton unit arranged for wood firing was completed and operation commenced. The installation consisted of a 46 in. by 60 ft. rotary kiln (see Figure 1) followed by a 14-in. Sirocco cyclone, a cast-iron condenser unit, and a 1,700 c.f.m. fan, exhausting to a stack. Other equipment included a 9 in. by 18 in. Denver jaw crusher with the necessary bins and feeders. As the need for mercury was urgent, because of war requirements, construction of a duplicate unit was begun almost immediately. This first extension started operation in January, 1941, and the plant was then capable of treating about 150 tons of ore daily.

Jan 1, 1945