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By W. J. Dick

THE purpose of this paper is to point out, briefly, the importance of the coal mining industry of Alberta and to stress the economic factors that hinder its development; also to offer suggestions relating to the major problems of the industry. The minor problems will not be dealt with in detail, because, if the major problems are taken care of, it is felt that the industry itself can take care of ,he remainder. COAL MINING NO LESS IMPORTANT THAN GOLO MINING The large increase in metal mining development in all provinces of Canada, excepting Saskatchewan, Alberta, and the Maritimes, has had the effect of focussing public attention on this branch of the industry. The fact, also, that this development came at a time of depression has been of immense benefit to Canada as a whole. On account of the necessity and consequent demand for gold, with its attendant increase in price, through government action, from $20.67 per ounce to $35.00 per ounce, it is safe to say that the public of Canada have become, today, gold mining conscious. While everyone admits the great value. of the gold mrn111g industry, nevertheless, the equal value to Canada of certain other industries must not be lost sight of. The coal mining industry, in particular, is worthy of greater public and government support than has been accorded it in the past. It would seem unnecessary to stress this matter to a meeting of the Canadian Institute of Mining and Metallurgy, but unless certain facts are brought to your attention, there is danger that the coal mining industry will not be developed to the extent its national importance deserves. Too many public men and men in authority are unaware of the value of coal mining.

Jan 1, 1936

By S. M. Moon

Today, underground exploration is spotlighted as an infinitely developable area. For this purpose, many tunneling technologies were created. And until this very day, many techniques are being developed for more efficient underground movement. Although previous technologies have been developed and now being used in various forms like TMB, struck propulsion method and hydraulic propulsion method, it is hard to find a robot type exploring in small scale. But development of small scale underground exploration robot is a promising research subject for its usage in examination of soil, mineral, and subterranean resources, investigation of hazardous regions, and the military. So we developed a robot that can dig and move underground, inspired from the motion of earthworm and mole cricket. Earthworm and mole cricket dig the soil in the front and draw it off backward, so that they can move forward. We developed a mechanism that uses 2 rotating solid of revolution (bits) for pulverizing the firmly united soil in the front and put it inside the body. The bits rotate in the opposite direction of each other. While moving forward, the soil in the front moves along the spiral on the bit and is saved inside the body. The soil saved inside is taken out through an outlet in the back by a ventilation system. The ventilation system on the ground blows through a hosepipe connected to inner part of the robot and the air blows off the soil. The moving mechanism of exploring underground can be classified into 2 parts. One is to fix the blade link on the soil in a form of 4-bar link. The other one is to move forward rotating the whole link. When the blade link system for movement rotates a certain degree, one blade link is fixed, while the other one is folded in. When 2 blade links of different length rotate as it is, different torque is applied on each link. By the law of action and reaction, the link that has larger torque leads the rotation and movement.

Aug 1, 2013

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005

By Jolanta Olkowska-Oetzel

Reactions of gold?phosphino complexes [(AuX)(PR3)] (X= Cl, Br, I; R = organic rest) with Se(SiMe3)2 lead to the formation of gold complexes with chalcogenide bridges. The reaction of the complex Ph3PAuCl and tBuSe(SiMe3) gives the cluster [Au5Se2(PPh3)4]Cl 1. The in situ preparation of the complex [(AuCl)2dpph] (dpph = Ph2P(CH2)6PPh2) by reaction of dpph with Me2SAuCl, and subsequent reaction with Se(SiMe3)2 leads to the formation of [(Au3Se)2(dpph)3]Cl2 2. Reactions of the gold(I) complex [(AuCl)2dpppe], (dpppe = Ph2P(CH2)5PPh2) with Se(SiMe3)2 and InCl3 in different molar ratios lead to the formation of [Au10Se4(dpppe)4]InCl5 3 and [Au4(SeInCl3)2(dpppe)2] 4. The reaction of [(AuCl)2dpph] with Te(SiMe3)2 and GaCl3 produces the isostructural cluster compound [Au4(TeGaCl3)2(dpph)2] 5. From the reaction of Se(SiMe3)2 with [(AuCl)2dppe] (dppe = Ph2P(CH2)2PPh2) and InCl3 [Au8Se4In(dppe)4](InCl4)3 6 can be isolated. The structures of 1 - 6 were determined by X?ray diffraction.

Oct 1, 2003

By W. E. Roscoe

The probability of making an exploration discovery in Canada can be calculated from Derry's (1970) data on exploration expenditures and number of discoveries over the last nineteen years. Considering an average exploration "try" to be $30,000, the probability of a discovery with one try has decreased tenfold from about 0.01 in 1951 to 0.001 in 1969. A plot of these probabilities can be extrapolated to the future, giving a 1969-71 three-year average probability of 0.00096 with 90 per cent confidence limits of 0.00042 and 0.00153. Using this probability, various calculations can be made, such as (1) the probability of making at least one discovery for any given exploration expenditure, (2) the probability of ultimate ruin or survival of the exploration investment process and (3) the expected value of an exploration investment. There is a critical minimum amount per discovery that must be re-invested in exploration, no matter how large the original investment is, for exploration to survive at all in the long run. Currently, this critical minimum is $31,200,000 with 90 per cent confidence limits of $19,600,000 and $71,400,000.

Jan 1, 1971

By Laxman M. Amaratunga, David N. Yaschyshyn

"In the mining industry several types of fills are used for backfill operations. They are broadly categorized into three basic types: rock fill, hydraulic/slurry fill, and paste fill. Recently, paste fill has become the popular alternative for backfilling because of its many environmental and operational advantages including its ability to use total tailings, both fine and coarse fractions.Amaratunga and Annor (1989) first presented the concept of agglomeration of fine tailings, which are otherwise excluded from backfilling, for utilization in backfill as a readily available supplementary fill material. Previous experimental work investigated the use of agglomerated fine gold mill tailings in low density slurry fills (60 -70% pulp density), consisting of varying agglomerate and tailings compositions.This paper presents the ongoing research into utilizing these agglomerates in a high density paste fill (70 -85% pulp density). Various binder dosages, curing period and combinations of pellet to tailings ratios were studied. Slump of the raw fill and compressive strength of the cured fill were examined. Results from the above study indicate that agglomerated tailings paste fill (ATPF) has superior strength characteristics when compared to total tailings paste fills.IntroductionThe Canadian mining industry produces more than 500 million tonnes of tailings and waste rock annually. These tailings consist of a coarse fraction and a fine fraction and can be either reactive (acid generating) or non-reactive. Most mining operations utilize the coarse fraction for backfilling while the fines have been traditionally disposed of in surface tailings ponds. Recently, paste fill has been developed which uses a fraction of the fine tailings (10 - 30% w/w of >45 µ,m) in the fill. This development allows a mining company to use a portion of the fines for backfill, but still requires surface impoundment of the unused portion of fine tailings. Reactive tailings have the added problem of generating acid after being oxidized in the presence of air and water. Treating acid mine drainage (AMD) seepage from these ponds has proven to be a costly environmental problem and long term liabilty.One practical method to reduce the environmental impacts associated with the tailings pond and to modify the physical and chemical properties of the fine mill tailings so that they can be utilized and disposed of in an environmentally safe manner through surface or underground applications is through agglomeration using the Cold-Bond Tailings Agglomeration technology (CBTA). Amaratunga and Annor (1989) first presented the concept of agglomeration of fine tailings for use as coarse aggregates for underground backfill, gravel or surface covering material. CBT A reduces the necessity of impounding tailings on surface while providing a suitable coarse aggregate resource material for practical use. Although the CBT A technology has been mainly limited to pelletization agglomeration alone, other forms of agglomeration like pressure agglomeration which include the techniques of briquetting and extrusion have also proven successful (Amaratunga, 1995)."

Jan 1, 1996

By F. Chiesa

Experimental results on thin and thick castings poured in aluminum A356 and magnesium AZ91E by the low pressure permanent mold process have been compared to the result of filling simulations for thin and thick castings. If the results of modeling is reliable when the liquid remains above the liquidus temperature, this is no longer the case when partial solidification occurs. The visco-elastic behavior of a partially solidified liquid is difficult to put into equation as it depends on the amount of shear it has been been subjected to. Attempts to predict misruns with a commercial software has been proven to be very difficult if not impossible; divergence of the numerical solution has been observed unless prohibitively long computing times are used. In order to overcome these difficulties from a practical standpoint, a simple method is proposed which consists in tracking the temperature of the advancing liquid metal front so as to make sure it will always be above so-called `Misrun Critical Temperature' (MCT) determined experimentally for thin and thick aluminum A356 and magnesium AZ91E castings. If the liquid metal front falls below this temperature, a cold-shut or misrun is likely to happen at this location. The values of MCT for thin and thick in aluminum A356 and magnesium AZ91E were determined experimentally on misrun castings of extreme geometries (a thin 2.5 mm wall cover and a 6mm to 25 mm thick bell housing). MCT was found to be lower for magnesium AZ91E and for the thicker castings.

Jan 1, 2011

By LUKE O. LINDOE

A major clay products industry in the Medicine Hat area since before 1910 has maintained a continued interest in the clays of the Cypress Hills. For the first forty years the materials used were local red-burning Cretaceous and Pleistocene clays and sands and high-quality stoneware clays of the Whitemud Formation at Eastend, Saskatchewan. Recently a much broader spectrum of raw materials has been brought into use. Including the exposures of the Eagle Butte structure, the Cypress Hills present a 1200 m section of clay-like sediments. Of this 1200 m about 94 per cent, the high montmorillonite shales of the Upper Cretaceous, can be considered useless, or nearly so; the remaining six per cent, all fresh-water beds, presents a wide variety of potentially useful materials. The development of these clay resources is complicated by deep surface creep on the south flank of the Cypress Hills, by largescale slumping on the north flank and by a structural complex in the Eagle Butte area.

Jan 1, 1984

By J. Olaf Sund

"The New Brunswick gypsum and an-hydrite deposits make up part of the Windsor group in the Upper Mississippian. The present deposits were formed by surface hydration of the underlying anhydrite beds. The sub-hydrate, hydrate, and di-hydrate stages of gypsum are formed from the anhydrite by this hydration. The anhydrite was precipitated from sea water in embayments that were separated from the sea by a reef or bay-mouth bar. The anhydrite is the original form of the calcium sulphate precipitate.One gypsum deposit near Plaster Rock in northern New Brunswick was precipitated from sea water directly as gypsum, which is its present form."

Jan 1, 1960

By A. Dave Mackintosh

Historical closure data has provided a description of the stress distribution patterns occurring around mine openings and enabled the development of a time ? distance plot predicting the location of the stress peak and its migration away from mine openings with time. Data collected from active mining areas during the 1970?s and 1980?s indicated the peak appeared to stabilize approximately 135m (450 ft.) from openings after four years. The region of high load and accompanying poor ground conditions in which the peak was centred was spread over approximately 45m (150 ft.) to 60m (200 ft.). Recent data from new development headings cut adjacent to 25 year old extraction areas suggests load transfer takes place over a much greater distance and time frame than predicted.

May 1, 2001

By R. D. Brown

In view of the many changes which have taken place since 1950 in the rules of the Income Tax Act concerning the deduction of exploration and development expenses, many corporate taxpayers each year face the tedious task of determining which particular rules their unclaimed exploration and development expenses are subject to and in what sequence these expenses are to be claimed. Recent amendments to the Act have cleared up some of the mystery of the "ordering" of these deductions. This article examines the sequence in which various categories of exploration and development expenses are to be deducted in accordance with the terms of the Act as amended by Bill C-11.

Jan 1, 1978

By Jiuhua Xu, Shuiku Jia, Weiren Sun

"Abstract -The Jinqingding gold deposit, situated in the east Jiaodong Peninsula of Shandong province, is typical of the pyrite-quartz vein gold deposits in the Muping-Rushan gold belt of China . The gold deposit is controlled by a great NNE fracture zone and is composed of several lenticular orebodies within the fracture zone occurring in the Kunyushan granite massif. The Kunyushan granite massif was formed by the replacement of the Archean Jiaodong group.The main minerals associated with gold are pyrite, chalcopyrite, galena and sphalerite; the gangue minerals are dominated by quartz, sericite, microcline and calcite. The mineralizing event can be divided into four stages: (1) pyrite-quartz; (2) quartz-pyrite; (3) siderite-polymetallic sulfides; and (4) calcite-quartz. Gold occurs mainly as native gold and electrum in stage 1 and stage II. There are some evident differences between pyrite from major stages of gold mineralization and that from minor stages; these include differences in crystal forms, size and composition of fluid inclusions.Wallrock alterations consist of sericitization, silicification, pyritization and potash-feldspar alteration. Five alteration zones can be distinguished from unaltered granite (zone 0) to vein lodes (zone IV). Au and Ag increase rapidly from zone 0 to zone IV, Cu increases continuously, while Pb and Zn increase slowly. R-type geological factor analysis indicates that the Au, Ag, Cu, Pb and Zn bear a close relationship to wallrock alteration."

Jan 1, 1994

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

Vale Inco?s Coleman Mine 153 Orebody is a narrow vein deposit with a dip that varies from 30 to 70 degrees. It has a strike length of 1200-feet and the current mining extends from the 4250 level to 5100 level. The primary mining method is mechanized cut-and-fill although drift-and-fill is also used in wider sections of the ore zone. The ore body is divided into six main mining horizons with an average of three mining blocks on each cut. There are some interesting rock mechanics challenges related to mining upward from the 4550 level and these challenges are increasing as the mining front progresses toward the 4400 level. The mining of the 4550 block is currently at cut 13 whereby the crown pillar thickness is approximately 60-feet. Significant factors including increased stress levels in the crown pillar, the change in the orebody dip at this level and a recently indentified geological structure in the footwall, have all combined to introduce seismic activity in the footwall of 4550 level. Closer studies revealed a consistent trend of seismicity that was further examined with core logging and Acoustic TeleViewer technology. The data from these assessment tools disclosed a geological structure that is influencing the mining environment. This paper reviews the seismic analysis for the 4550 level mining zone and the subsequent procedures used to locate the new geological structure. The paper also discusses the key mining practices used to successfully mine cut 13 of 4550 level and briefly reviews the studies that are underway to up-date the mine design for continued extraction of high-grade ore in a safe and productive manner.

May 1, 2009

By J. Cui, Z. Meng, W. Zhao

"The decomposition of rare earth concentrates containing bastnasite and monazite by alkali solutions has been investigated. A slurry of the rare earth concentrate and the alkali solutions was calcined at different temperatures. The impacts of calcination temperature on the decomposition of rare earth minerals, the oxidation of cerium, the deportment of fluorine and phosphorous, and the adaptability of the method to the different grades of rare earth concentrate were all studied. A possible technique for comprehensive recovery is proposed in which the chemical elements such as rare earth, fluorine, phosphorus, calcium, iron and thorium could be recycled or recovered. INTRODUCTIONThe liquid alkali decomposition method is an important technique for the decomposition of mixed rare earth concentrates. The technique is relatively clean compared with the sulfuric acid roasting method. However, its operation is intermittent rather than continuous. The two-step solid-liquid reaction and the subsequent water washing make it not very suitable for mass production and application. An important reason for the disadvantage is that an additional process of ""calcium removal by acid leaching"" is needed for the technique. The content of calcium in Baotou rare earth concentrates is usually 6-12%. The requirement of the current technique is that the content of calcium should be reduced to about 0.2% after the calcium removal process. Otherwise, the decomposition and leaching of rare earth will be affected. Therefore, calcium removal by acid leaching is a necessity before the alkali decomposition process is carried out. Research on different alkali decomposition techniques has been conducted with prior calcium removal by acid leaching (Xu, 1995; Yu, 1993; Han, Li, Chang, Liu & Xu, 1985). There have been some investigations of direct decomposition of the bastnasite (Feng, Pan & Li, 1998; Zhao, Zhang, Yang & Liu, 2002)and monazite (Sun, Li, Li, Su, Zhao & Liu, 1998; Zhou, 2005) by alkali-liquid, however, all studies were carried out in solid-liquid reaction system, and continuous calcination studies have not been reported.This paper investigates the process of direct decomposition of Baotou rare earth concentrates by continuous calcination with concentrated alkali. Using the rotary tubular electric furnace, the mixture of rare earth concentrate and concentrated alkali solution were decomposed continuously. Satisfactory decomposition results were achieved. A method for clean processing and comprehensive resource recovery from Baotou rare earth concentrates is proposed."

Jan 1, 2012

By Jerry M. Whiting, Neil J. Duncan

"Does Canada need a mining industry? Isn&apos;t it a chronically depressed collection of businesses that pollute the air and water and tear up the countryside? Wouldn&apos;t it be better if Canada&apos;s investors devoted their attention to high-technology endeavours, tourism, and other relatively pleasant tasks?Probably the answer to whether Canada needs a mining industry in the 21st century is to look at the real mining industry that is in operation today. The facts indicate that mining is a very important contributor to Canada. It has certainly encountered some challenging times during periods of recession, and it face s severe and continuing problems of cost and competition in world markets. However, uneconomic mines have been closed, others suspended, and productivity has risen dramatically with employment at 77 000, down from 101 000 in 1981. The country&apos;s metal and non-metal mines, metallurgical plants and semi-fabricated metals industries employed an estimated 378000 workers in 1986, and paid wages than any other sector of the Canadian economy. This effort resulted in the production of 60 different metals, non-metals and structural minerals valued at $13.5 billion.The trade aspects of the mining industry are of paramount importance. If there is a reason for this situation to change during the next century. it eludes the authors. Canada has the well-developed expertise to discover, evaluate, develop, operate and profit from existing and new businesses based in an enormous area endowed with a nearly unbelievable variety of mineral resources. Many countries throughout the world must rely on producers like Canada, if they are to maintain and/or improve their standard of living."

Jan 1, 1988

By Costa

The fly-in-fly-out (FIFO) mining model has significant implications for the industry as it plays an important role in fulfilling the economic, social and workforce needs of the contemporary mining industry. It has increasingly been adopted in countries such as Canada and Australia, but is the current nature of the FIFO model challenging the place women have achieved in the mining workforce? Research in the mining and oil and gas industries reveals that major sources of stress for fly-in-fly-out mining workers are the times of parting and of reunion, the challenges in defining roles within the family, parenting, and conflict between spouses over the use of the leave time and money. So how are women in the industry coping with the FIFO schedules and consequent intermittent relationship with families and partners? How is the mining industry adapting to recruit and maintain female employees in FIFO operations? This paper describes an exploratory study conducted in Canada, which intended to provide some initial insights that might help us answer the questions above. There are several inferences made from this exploratory study. It is clear that FIFO poses significant challenges for both female and male workers. It is largely seen as rigid, extremely challenging for employees with young families and workers who are single mothers, and it is generally incompatible with starting a family and caring for small children. FIFO creates severe stress on relationships and on workers psychological well-being. It seems to be indeed harder for women, since they are often in lower paying positions and therefore have less financial reward for the FIFO lifestyle. On the other hand, FIFO creates the opportunity for young women, including Aboriginal women, to jump-start their careers, as well as opportunities for mature women to work while pursuing other personal interests during their time off. This paper concludes with recommendations to improve the FIFO system in order to increase the ability of mining companies to hire and retain women

May 1, 2006

By Zoltan Hajnal

Magnetic studies have been carried out on 88 surface and 157 underground samples from the Coronation Mine area of northern Saskatchewan. The intensity of the surface samples was compared to trace element determinations from the same locality. A good correlation was found between the titaniferous constituent of the rocks and the intensity of magnetization. From the direction of the remanent magnetism, two virtual geomagnetic poles were determined -latitude 12° 54&apos; North, longitude 158" 17&apos; West; and latitude 23" 42&apos; North, longitude 163° 45&apos; West. The sulphide ore specimens showed anisotropic susceptibility characteristics. A relationship was found between the measured maximum susceptibility values of the ore specimens and the direction of the tectonic forces which are considered to have formed the structure at the Coronation mine. Introduction T HIS paper summarizes the results of a study of the magnetic properties of samples from well-known Precambrian formations. The observed data give information for an interpretation of the magnetic field conditions in Precambrian times. The high magnetic intensity values indicate the importance of the study

Jan 1, 1965

By D. T. A. Symons, M. M. Kapnistos

"Gravity profiles were established over five known Middle Silurian pinnacle reef s in Lambton County, southwestern Ontario. The profiles were approximately 3 km long, with stations every 60 m. Four fairly recent technological developments were used which now make the gravity method relatively efficient and inexpensive compared to the techniques available two decades ago. These are: (1) a La Coste-Romberg model G gravimeter to measure the gravitational attraction with a sensitivity of 0.01 mgal; (2) a Sokkisha model B-2 semiautomatic engineers level to measure the station elevations with an accuracy of 0.5 cm; (3) a Huntec FS-3 hammer reflection seismograph to determine the overburden thickness to an accuracy of ± 7%; and (4) a modern microcomputer to process the data sets and mathematically filter the gravity values. Thus, two men can measure and analyze approximately 1 km of profile per day and obtain the residual gravity profile to an accuracy of ± 0. 05 mgal. Positive gravity anomalies of 0.17 to 0.72 mgal were observed along all five profiles that approximately delineate the dimensions of the known pinnacle reefs, which have an average height of 120 m, diameter of 1500 m and depth to top of 575 m. The relative ease of the gravity survey method makes it a cost-effective technique for hydrocarbon exploration in southwestern Ontario. IntroductionPinnacle reefs are important sources of oil and gas. Although the pinnacle reefs in southwestern Ontario are small, they may contain commercial pools of oil and gas because of their proximity to refineries. They are also useful for subsurface storage of gas to meet the winter surge in gas demand.At present, geophysical exploration for new pinnacle reefs is done primarily by relatively expensive seismic methods, which are also limited in southwestern Ontario by prohibitions on blasting. Gravity methods of exploration were attempted more than two decades ago in this region. (Pohly, 1954); however, the level of technology at that time made the method marginal in sensitivity and quite expensive. Several subsequent developments- gravimeters with greater sensitivity and operating ease, ""self-levelling"" levels for elevation control, hammer seismic reflection units for determining overburden thickness and portable microcomputers for efficient data analysis-have significantly improved the precision and cost effectiveness of the gravity method. Five known pinnacle reefs were selected in Lambton County, southwestern Ontario (Fig. 1), to test the effectiveness of integrating these developments to locate and define additional reefs. Isolated reefs were chosen to avoid the problem of the gravity effect s of one reef interfering with those of a neighbouring reef. The surveys were facilitated by choosing reefs with a concession road passing directly over them ."

Jan 1, 1980

By M. Abumiya, N. Onodera

"The synthesis of large scorodite particles in non-ferrous metallurgical industries usually requires a high-cost operation involving heating and high-pressure autoclaving. To overcome these obstacles, an atmospheric-pressure process for scorodite synthesis (DMSP®) was developed, in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. This process gives scorodite of good crystallinity with particle sizes as large as 15-20 µm. The solutions used for scorodite synthesis in the DMSP® are prepared from various residues containing arsenic from non-ferrous smelters. The solutions may be contaminated with Cu, Sb, and Bi, for example, and therefore the effects of such impurities on the formation of crystalline scorodite need to be investigated. In this study, the effects of Cu, Sb, and Bi contaminants on the formation behaviors of scorodite particles in the DMSP® were investigated systematically.INTRODUCTIONThe synthesis of crystalline scorodite (FeAsO4·2H2O) is a suitable method for arsenic (As) stabilization and storage of As-containing by-products such as flue gas dusts in non-ferrous smelters. It is expected that the formation of large, highly-crystalline scorodite particles would be an ideal method for avoiding the release of arsenic to the environment. Generally, autoclave methods under pressurized oxidation conditions at temperatures above 100°C have been used for the formation of arsenic minerals such as scorodite. However, the autoclave method requires sealed vessels that are resistant to high pressure, heat and acids. This process is also unfavorable on account of the high construction expenses, and high running costs as a result of vapor heat loss. Processes for synthesizing scorodite under atmospheric conditions at temperatures below 100°C which do not need an autoclave have therefore been extensively investigated (Demopoulos, Droppert, & VanWeert, 1994; Demopoulos, 1996; Demopoulos, Lagno, Wang, & Singhania, 2003; Droppert, Demopoulos, & Harris, 1996; Filippou & Demopoulos, 1997).Recently, Fujita et al. (Fujita, Taguchi, Abumiya, Matsumoto, Shibata, & Nakamura, 2008a, 2008b, 2009; Fujita, Taguchi, Kubo, Shibata, & Nakamura, 2009; Fujita, Taguchi, Shibata, & Nakamura, 2009) developed a new method for producing large scorodite crystalline particles with improved filtration and washability properties at normal atmospheric pressure and temperatures below 100°C. In the new method, oxygen gas (O2) is blown into solutions containing a high concentration of arsenic ions (As(V)) and ferrous ions (Fe(II)). The Fe(II) ions were subsequently oxidized to ferric ions (Fe(III)), resulting in the formation of large scorodite particles. High supersaturation of solutes such as Fe(III) will result in excessive nucleation, and the formation of poorly crystalline phases. The scorodite formation must therefore be conducted in a manner that avoids the critical supersaturation level being exceeded. It is supposed that the oxidation of Fe(II) to Fe(III) by O2 gas in the new method suppressed the supersaturation of Fe(III) during scorodite formation. The low Fe(III) supersaturation resulted in formations of highly crystalline scorodite particles of size of around 20 µm. In June 2008, based on the developed process described above, DOWA began experiments to verify the industrial capability of a plant with a capacity of 30 MT/month of As. It was successfully proven that it is possible to produce crystalline scorodite industrially on a commercial scale. This process was named and trademarked as DMSP® (Kubo, Abumiya, & Matsumoto, 2010)."

Jan 1, 2012