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By Hiroaki Sakurai

Using batch reactors equipped with CO and CO2 gas sensor, CO oxidation over Au catalysts in room air has been investigated and compared with Pt catalysts. For both Au and Pt catalysts, the logarithm plot of CO concentration data during initial 10 min are well fitted by straight line, which mean the first order dependence on the CO concentration between 10 and 10,000ppm. The rate constant value (k) over Au and Pt catalyst generally decrease with increasing initial CO concentration above 100ppm. The value decrease especially rapidly between 100ppm and 1,000ppm over Pt catalysts, which should be due to the strong adsorption of CO on Pt. The k value over Au catalyst has become ten times or more as large as the Pt catalysts at 1,000ppm. Already for the initial concentration of 100ppm CO, the strongly adsorbed CO on Pt metal has been clearly observed by FT-IR during the reaction over Pt/Al2O3. A part of the strongly adsorbed CO has been remained on Pt after the disappearance of gas phase CO, and has gradually changed to gas phase CO2. Such strongly adsorbed species on Au has never been observed on Au/TiO2 under the same reaction conditions. These features of Au catalysts are favorable for indoor air purification.

Oct 1, 2003

By Brad Sampson

Project Ownership ?Discovery Metals Limited ?ASX (DML), BSX (DML), AIM (DME) ?Market Cap AUD 195M ?Key assets ?Boseto Cu ?Dikoloti Ni The Boseto Copper Project ?Location ?Setting ?History ?Status ?Future

May 1, 2010

By C. O. Aksoy, H. Kose, K. Heasley, E. Yalçin

"In Turkey, the growing demand for lignite has resulted in increased lignite production and an emphasis on improving underground recovery. This has resulted in a gradual increase in the application of the retreat longwall mining method and also in the extraction of the safety pillars protecting permanent underground structures (drifts, shafts) in mines prior to their abandonment.Extracting these safety pillars presents a special hazard to mine employees and the stability of the mine. Often subjected to high stresses, the behaviour of these pillars is not always predictable. Special care must be taken to ensure that infrastructure does not collapse prematurely, and that working conditions remain safe. Otherwise the extraction must be halted, and the remaining coal lost.This investigation reports on a study of the stability of safety pillars during the final extraction phase of the Hustas mine in Soma, Turkey.” The model construction was based on mine plans, and material properties were derived from physical properties testing. Observed subsidence effects from other mining events were used to calibrate the overburden lamination thickness.The model results compared well with surface physical disturbance occurring as a result of mining, as well as with conventional longwall stress redistribution theory and underground observations. The study has shown that properly calibrated models can be useful in assessing mine safety during remnant pillar extraction. The LAMODEL results demonstrate the convenience of this easy to use software."

Jan 1, 2004

By Y. H. Hatzor

"This is an extended abstract for a keynote lecture delivered by the author during the 2015 ISRM congress in Montreal on the application of the numerical discontinuous deformation analysis (DDA) method in rock mechanics practice. Due to the large scope of the topic this lecture will focus on studies performed by the rock mechanics group at Ben-Gurion University, alone or in collaboration which other research groups, and is not intended to provide a comprehensive review of everything that has been done on the subject worldwide during the past two decades. A forthcoming textbook (Hatzor et al., in preparation) will attempt to provide such comprehensive coverage.DDA has been developed by Dr. Gen-hua Shi while he was doing his PhD studies under the supervision of Professor R. E. Goodman at U. C. Berkeley (Shi, 1988). Dr. Shi has invented a new numerical discrete element method which provides a solution for dynamic deformation of block systems, hence its applicability to rock mechanics practice. The method is similar in essence to the finite element method in its implicit formulation of the time integration scheme and where in every time step the minimum potential energy of the entire system is sought, but here every element is a finite block with six degrees of freedom. The blocks are assumed to be stiff (simply deformable) so that most of the energy is consumed by slip along pre-existing discontinuities, the frictional resistance of which is assumed to obey the Coulomb-Mohr failure criterion for rock joints. The greatest advantage of DDA over alternative numerical discrete element methods is its robust area (volume) integration which ensures great accuracy even when the blocks are of irregular shapes, including non-convex blocks which may contain holes. The greatest disadvantage is the necessity to solve in every time step very large matrices of unknowns, imposing great CPU demand when the block system involves a large number of blocks. Another disadvantage is the sensitivity of the solution to the choice of the penalty parameter which is implemented in DDA in the form of stiff springs that are attached to contacts once detected automatically.The inherently dynamic formulation of the DDA method lends itself to solution of dynamic problems in rock mechanics. Dynamic analysis with DDA can be performed in different ways corresponding to different rock mechanics problems and loading conditions. Three main classes of loading conditions which are relevant to rock mechanics applications are discussed here: 1) dynamic loading of a single bock which rests on a stationary foundation, 2) response of a block to dynamic loading of the foundations, 3) wave propagation through a block system.The most common approach is to introduce the dynamic force to a specific block in an otherwise fixed block system and check the resulting deformation, typically the time dependent displacement or rotation of the loaded block. This approach is particularly useful for dynamic rock slope stability studies when a stability of a specific rock block against earthquake vibrations is in question. The first 2D-DDA benchmark test of this approach was performed by Hatzor and Feintuch (2001) who introduced harmonic acceleration functions into a block which rests on an inclined plane. The analytical solution proposed for this problem by Hatzor and Feintuch (2001) was later generalized by Kamai and Hatzor (2008). The first 3D-DDA benchmarking for this approach was presented by Bakun-Mazor et al. (2012) who studied single and double face sliding of blocks which rest on stationary foundations and subjected to harmonic input acceleration functions."

Jan 1, 2015

By J. A. Rogers

"The Arthur W. White Mine (formerly Dickenson Mine) is a structurally controlled, hydrothermal gold deposit. A gold producer since 1948, it has, to December 31, 1990, processed 6.9 million (m) tons (T) of ore grading 0.45 ounces per ton gold (oz/T Au). As of December 31, 1991, Proven and Probable Ore Reserves were 3.2 m. T. at 0.32 oz/T Au. The mine is located just east ofPlacer Dome Inc. 's Campbell Mine, within the Cochenour-Gull.rock Lake deformation zone. It is situated on the hanging-wall side of a southeast-plunging anticline in a sequence of metamorphosed Archean volcanic, sedimentary and plutonic rocks of the Red Lake greenstone belt. Ore-bearing structures, found mainly within basaltic rocks, are brittle within greenschist-facies rocks to the northwest, but become more ductile toward the southeast, in amphibolite-facies rocks. Within and proximal to these structures, carbonate and arsenopyrite alteration decreases, whereas biotite, actinolite, pyrite and pyrrh otite all increase to the southeast.Ore and shear structures occur symmetrically about the northwest-trending, steeply southwest-dipping, flattening foliation . The three most common ore trends are on average: (A) northwest trending with a 55 degree to 85 degree dip to the southwest; (B) north-trending with a 40 degree to 50 degree dip to the west; and (C) due east-west-trending with a vertical dip. In general, the dominant direction of economic gold concentrations are explained and thus predicted by considering deformation style (brittle or ductile), rock anisotropies such as bedding and lithological contacts, and direction/magnitude of relative block movement. Direction ""A"" can be found adjacent to both right- and left-handed faults. Direction ""B "" occurs with dominantly right-handed systems and direction ""C"" is found with predominantly left-handed movement. Major faults active prior to, during, and after ore formation can have offsets in the order of 2500 feet. Movements along these faults were transpressive while their conjugate breaks were dilatant, thus creating zones for alteration and ore solution emplacement. A series of faults , each with offsets up to 30 feet were established under lower temperature brittle conditions during late- to post-ore formation. In more complex zones, formed during more ductile deformation, these faults controlled the localized geometry and, thereby, the depletion and enrichment of ore shoots, causing a high nugget effect.Although an important aspect of production planning and monitoring, grade control is also very important within a complex ore zone so that the nuggets are not missed. Detailed observation of structure at the hand-sample scale and detailed mapping at the stope scale give valuable clues to interpreting the structures on a mine-wide scale. Determining the relative movement along fault structures is very important so that using an action-reaction- type logic, potential dilatant areas can be predicted and targeted for development and diamond drilling."

Jan 1, 1992

By J. Dupre, A. Gontcharov, H. Pepin

Produced by the conventional TIG welding CMSX-4 welds had been studied. It was demostrated that microstructure of welds depended on filler materials, welding parameters and joint design. Epitaxial solidification of CMSX-4 clad deposits produced a directionally solidified structure while welding with the similar filler material. Defects free clad welds were obtained by TIG welding without preheating using similar and dissimilar filler materials.

Jan 1, 2006

By E. Rosseland

Glencore Nikkelverk is operating its Chlorine Leach Process in Kristiansand, Norway, producing nickel, copper and cobalt metals by electrowinning. The copper tankhouse, with an annual capacity of 40 000 tons, is based on traditional technology with copper starting sheets and cast lead anodes. Due to the integration of this copper sulphate process in a nickel chloride refinery, operating conditions are unique. In recent years, operating costs have escalated, and health, safety and environment are top priorities. Test work on a new copper process involving permanent cathodes was therefore initiated in 2007, and a pilot plant was started up in 2012. The objective was to introduce innovative technologies and tailor these to be robust in the Nikkelverk process, to form a basis for a new sustainable copper tankhouse with a high degree of automation. Key learnings from more than 10 years of R&D work is presented, focusing on cathode materials and copper metal deposition including product quality, robotic stripping, coated titanium anodes, electrode contacts and alignment, electrode current monitoring with Hatch HELM tracker technology and acid mist capture using cell hoods with off-gas scrubbing. The new copper tankhouse project was approved in December 2018, and commissioning is planned in 2022. INTRODUCTION The Kristiansand nickel refinery was started up in 1910, processing nickel-copper matte originating from Norwegian mines. It was the first industrial plant in the world to produce nickel by electrolysis using the Hybinette electrorefining process. After roasting to burn off sulphur in the matte, copper was leached and recovered as cathodes by electrowinning with lead anodes. In the first years, the copper cathodes were fire- refined and cast into ingots for sale (Thonstad Sandvik, 2004). The Nikkelverk refinery was acquired by Falconbridge Ltd. in 1929, and since then matte from Sudbury, Canada has been the main feed source. The Hybinette process was in operation until 1975 when conversion to the newly developed Chlorine Leach Process was started (Stensholt, Zachariasen, & Lund, 1986). In this process still used today, nickel and part of the copper in the matte is leached using chlorine gas generated on dimensionally stable anodes in the nickel and cobalt electrowinning tankhouses, as illustrated in Figure 1. The presence of dissolved copper ions in the strong chloride leach solution is essential for effective chlorine absorption and nickel dissolution. To improve copper-nickel separation, slurry from the atmospheric leach is pumped to autoclaves and then to cementation tanks for precipitation of copper as copper sulphide, which is collected in filter presses. The leach residue, also containing the precious metals, goes through a 3-stage wash to remove chlorides before being introduced as a slurry to fluid-bed roasters for sulphur removal. The resulting calcine is then leached in spent electrolyte from the copper electrowinning tankhouse, to dissolve most of the copper and also some nickel, cobalt and other elements. After separation of the leach residue, elements like Bi, Te, As and Ag are removed from the strong copper sulphate solution by reaction with metallic copper in three columns in series filled with cut copper cathodes. The purified solution then passes polishing filters before being mixed with spent electrolyte and returned to the electrowinning cells.

Jan 1, 2019

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019

By Ingrid Hann

The Triple Bottom Line ? Economic Sustainability ? Creation of Joint Venture companies ? Planned evaluation of other kimberlites ? Social Sustainability ? Impact Benefit Agreement and Participation Agreements ? Education and training initiatives ? Environmental Sustainability ? Environmental management ? Mine closure planning

May 1, 2008

By Fernando Canales

In the last decade a great dealt of attention has been paid to the chemistry of polynuclear gold derivatives with a central heteroatom, not only from the experimental and structural but also from the theoretical standpoint (1). Interesting hypercoordinated species of the type [C(AuPR3)5]+, [C(AuPR3)6]2+, [N(AuPR3)5]2+, [P(AuPR3)5]2+ and [P(AuPR3)6]3+ have been described (2), apart from other complexes with more conventional stoichiometry, and all have in common the presence of gold-gold interactions of ca. 3 Å. Usually, the chemistry of the first row elements of the p-block is known to follow classical rules of bonding, and only in cases of extreme electron-deficiency has the traditional electron count to be reconsidered to account for special types of molecular or solid state structures. Many of these heteroatomcentered complexes are electron-deficient and the gold-gold interactions provide a significant contribution to their stability. The attraction between these closed-shell systems has recently captured the attention in inorganic and organometallic chemistry (1). P. Pyykkö has summarized the available theoretical and experimental evidence of intra- and inter-molecular interactions between heavy metal atoms, such as Au(I) (3). In general, when heavy metals are involved in such interaction, the closed-shell attractions are of metallophilic or van der Waals type, as has been found for d8, d10 coinage-metals, and d10s2 centers. Experimental evidence for the aurophilic Au(I)???Au(I) attraction is available from crystallography, NMR and Raman spectroscopies, and optical spectroscopic measurements of the interaction strength (4). It is manifested in molecular conformations with relatively close Au???Au interactions of ca. 3 Å, whose strength has been estimated at ca. 25-50 kJ/mol (5). These attractions are weaker than most covalent or ionic bonds, but stronger than other van der Waals bonds and comparable in strength to typical hydrogen bonds. The phenomenon cannot be satisfactorily explained by classical theories such as hybridization (3). From a theoretical point of view, the attractions close to equilibrium distances are caused by dispersive interactions together with relativistic effects (6). The attractive contributions are dominated by pair-excitations from the heavy metal, such as gold, strengthened by relativistic effects. In all the cases where there are inter- or intramolecular metal-metal attractions, the correlation effects are essential; if they are omitted, at the Hartree-Fock (HF) level, repulsive interactions are obtained (6). Hence, it is necessary to use at least second-order Møller-Plesset level (MP2) methods for the dispersive forces, which are included in the electronic correlation effects (7).

Oct 1, 2003

By Donald S. Cameron

By dispersing gold in high surface area form supported on metal oxides, its inert character can be transformed to make economical, effective catalysts. Gold has already been demonstrated in a number of fuel cell applications such as gas phase catalysts, electro-catalysts, and electrical connectors. In this paper, the various types of fuel cell systems are reviewed, and several opportunities for gold identified. Low temperature fuel cells, including alkaline and solid polymer electrolyte types rely on high surface area platinum group metal catalysts which are highly susceptible to poisoning by low concentrations of carbon monoxide in the fuel supply. Hydrogen is frequently obtained by steam reforming hydrocarbons, followed by the water gas shift (WGS) reaction. A promising initial use for supported gold catalysts is in catalysing this WGS reaction. Research has shown that gold supported on iron oxide (Au/a-Fe2O3 ) WGS catalysts are more active than the current commercial copper oxide / zinc oxide catalysts, and effective at temperatures as low as 120oC. Products from reformer/ water gas shift reactors can be further purified by removing traces of carbon monoxide. If a small proportion of oxygen is introduced into the fuel gas stream, carbon monoxide can be preferentially oxidized to carbon dioxide even in the presence of hydrogen. Gold nanoparticle catalysts on iron oxide support (Au/a-Fe2O3 ) have exhibited higher activity than commercially available platinum on alumina (Pt/?- Al2O3 ) preferential oxidation catalysts. The low temperature of this reaction may make it feasible to incorporate these catalysts within the fuel cell itself. Proton exchange fuel cells provide several possible applications for catalytically active gold and its alloys. Carbon supported platinum group metals would benefit greatly from improved electrical conductivity if gold replaced some or all of the carbon support material. As electrode current densities are raised, electrical resistance constitutes an increasing proportion of voltage losses within the fuel cell. Dramatic reductions in cell stack voltage losses have already been demonstrated by reducing inter-cell contact resistance using gold plating. The low temperature oxidation properties of gold catalysts have been investigated in controlling gaseous emissions from direct methanol fuel cells, and gold also provides essential catalysis in building direct borohydride oxidation fuel cells. The prospect of a range of other applications for gold in fuel cells to contribute useful improvements in corrosion resistance and conductivity is assessed. Globally, fuel cells have been developed for a wide range of applications including stationary generators, cars and buses, industrial vehicles and small portable power supplies, each of which represents a substantial market. Hence there are likely to be many and varied opportunities for gold catalysts to contribute to the performance and economics of the systems being commercialized.

Oct 1, 2003

By R. S. James, D. C. Peck, P. T. Chubb

"The East Bull Lake gabbro-anorthosite intrusion is one of several Early Proterozoic layered mafic intrusions occurring along the Southern Province - Superior Province boundary in the Elliot Lake - Sudbury region, Ontario. The base of the East Bull Lake intrusion comprises abundant plagioclase cumulates (Leucogabbronorite Zone) hosting two distinct styles of sulfide mineralization: (1) disseminated magmatic sulfides, and (2) disseminated to massive, structurally controlled sulfides. Both types of mineralization are enriched in Pd, Pt, Au, Cu and Ni. The host rocks to the sulfide mineralization display a range of interesting features including nodular textures, dendriticpegmatitic mafic pods, inclusion-rich zones (pyroxenite, anorthosite and granitic inclusions) and magmatic breccias. Disseminated chalcopyrite, pyrrhotite and pentlandite occur in concentrations of up to 100/0 within erratically distributed gossan pods near the base of the intrusion. The sulfides were originally precipitated from intercumulus liquids, but were subsequently recrystallized and locally remobilized along fractures during the major period of metamorphism and deformation that affected the East Bull Lake intrusion. The base- and precious-metal tenor of the structurally controlled sulfides can be explained by extensive remobilization and reconcentration of the pre-existing magmatic sulfides in the vicinity of a major shear zone. Both styles of sulfide mineralization locally contain ppm abundances of POE + Au and are generally Pd- and Cu-rich, although both display large variations in Pd:Pt and Cu:Ni ratios. The magmatic sulfides are more strongly enriched in POE and contain up to 1470 ppm Pd in 100% sulfide. Several factors, including source characteristics, magmatic processes (crustal assimilation, fractional crystallization) and post-magmatic interaction with hydrous fluid, have influenced the present distribution of POE, Cu and Ni in the East Bull Lake intrusion.The magmatic sulfide occurrences from the East Bull Lake intrusion compare favorably with marginal-type deposits from rift-related intrusions (Noril'sk-Talnakh region, Siberia; Duluth Complex, U.S.A.) in terms of their distribution, but are most similar to reef-type POE deposits with respect to their base- and precious-metal geochemistry. The combination of high POE tenors and large tonnages that is observed for the POE-Cu-Ni mineralization from the East Bull Lake intrusion suggests that a good potential exists for the presence of economic concentrations of Pd, Pt, Au, Cu and Ni in the intrusion. On a global scale, the East Bull Lake intrusion is part of a suite of Early Proterozoic plutons, many of which contain significant volumes of stratiform and/or marginaltype POE-Cu-Ni mineralization. The East Bull Lake intrusion is also one of the oldest mineralized intrusions derived from a sub-Superior Province mantle source region that has given rise to several significant magmatic POE-Cu-Ni deposits during the period 2.5 Ga to 1.1 Ga."

Jan 1, 1993

By John Wilson

"The unconformity beneath 75 per cent or over 6000 km2 of the Athabasca Basin in Alberta lies within economically exploitable depths. The basement beneath this unconformity consists of an extension of the Wylie Lake Pluton, locally faulted and containing areas of mylonitic rocks. While the rocks of the Wylie Lake Pluton are not promising host rocks for uranium ore deposits, the areas of mylonites, graphitic rocks and possible remnants of granitegneiss would bear closer examination. One area of maficmylonites shows a weathering zone enriched in Si, Ca, Na, Pb, Ni, Ba, Co, Sr, Zn and U in addition to reported values of 0.08 oz/ton gold. This zone occurs beneath 800 m to 900 m of Athabasca Group sediments, but similar rock types are present beneath much thinner cover elsewhere. Detailed geophysical exploration is required over the area of thinner Athabasca Group rocks to define more precisely the areas of promising basement rock type.IntroductionThe Athabasca Basin in Alberta has considerable economic potential which has not yet been realized. The geological setting is closely analogous to parts of the basin in Saskatchewan which host major uranium deposits. Recent advances in geophysical techniques have led to deposits being located in Saskatchewan below 600 m of cover. This means that the unconformity between the Athabasca Group and the basement lies at exploitable depths over 6000 km2 or 75 per cent of the Alberta portion of the basin. Much of this area was only cursorily examined almost a decade ago. In addition, Alberta's new Metallic Mineral Regulations have clarified the regulatory situation in the area, and opened up much land for exploration. This article is based on Wilson's (1985a) study of the Athabasca Group and Wilson's (1986) work on the basement and alteration beneath the Athabasca Group in Alberta."

Jan 1, 1987

By Étienne Yvenou, Martin Désilets

Le procédé d’électroaffinage du Cu est nécessaire pour atteindre les niveaux de pureté requis pour les applications les plus courantes telles que son utilisation comme conducteur électrique ou thermique.

May 2, 2024

By Tony Robles

"A new process is disclosed for the recovery of gold and/or silver values from activated carbon wherein they are adsorbed as cyanide complexes. A unique chemistry allows the new process to use mill process water containing an inexpensive, non-hazardous compound as the eluant. The new process has an elution period of 5 hours at 98°C. The gold in the eluant can be recovered by electrowinning or zinc precipitation. The new elution process is simple, reliable, and provides an eluted carbon that may not require thermal regeneration before reuse. Retrofitting the new process to existing processes such as Zadra, Anglo, and others will not require significant capital expenditures.IntroductionThe efficient and reliable elution process for gold/silver from activated carbon is a very important process in the gold mining industry. The most common techniques for elution of gold cyanide from activated carbon are the Zadra and Anglo procedures.Specialized elution techniques like the Micron and Acetonitrile processes have not been commercialized to significant extent probably due to relatively complex unit operations and expensive reagents.Important functions of the gold recovery circuit are:Efficiently recover gold/silver from the loaded carbon.Carbon is in good condition for reuse for optimum recovery.The pregnant solution is amenable to electrowinning or zinc precipitation to recover gold/silver from the solution.The whole process to be simple and short to reduce gold inventories.Present Elution ProcessesTable 1 shows some carbon elution processes that are available today. The two main elution processes used in the industry are: (1) the Zadra process, in which hot cyanide solution is circulated through an elution column and electrowinning cells; and (2) the Anglo American Research Laboratory (Anglo) process, consisting of a pretreatment step with caustic cyanide solution, followed by elution with deionized water."

Jan 1, 2000

By Michael L. Free, Zongliang Zhang, Joshua M. Werner

In the copper electrowinning process, short-circuiting between the anodes and the cathodes is a critical problem that changes the current allocation among local electrodes and reduces the current efficiency significantly. Possible reasons for the short-circuiting include the improper alignment of the electrode, bent electrode, and nodules on the cathode surface. In typical tankhouses, there is often a time between shorting and harvesting as well as between shorting and clearing. Therefore, it is inevitable to have short-circuiting affect the operation performance in practical electrowinning operations. However, one key piece of missing data is the actual measurements of the current efficiency as short-circuiting is approached and allowed to continue. Consequently, short-circuiting tests that allow tracking of electrowinning parameters before and after short-circuiting were performed in a laboratory scale Cu electrowinning cell. In the tests, the electrode spacing change, the mass of electrodeposited Cu, the deposition morphology, and the current allocation as well as the current efficiency before and after short-circuiting were studied. Results show that the short- circuiting affects the current allocation and the current efficiency significantly. Moreover, it changes the Cu deposition on the short-circuited cathode and therefore causes problems for Cu electrowinning. INTRODUCTION Electrowinning (EW) is commonly used for copper production around the world, with a rated production from 120,000 to 200,000 tons per year per operation (Wiechmann, Aqueveque, Henríquez, Muñoz, & Morales, 2014). In Cu electrowinning, Cu ions in the electrolyte are reduced on the cathode surface as metallic copper with a DC current, while on the anode, a counter anodic reaction occurs with oxygen gas generation (Werner, Zeng, Free, Zhang, & Cho, 2018; Zhang, Werner, & Free, 2018; Zhang, Werner, & Free, 2018). In copper electrowinning, an average current density of 200 to 400 A/m2 is applied to the electrowinning cell (Wiechmann et al., 2014). As the Cu deposits on the cathode, the distance between anode and cathode reduces and most of the time, short-circuiting forms between some anodes and cathodes in a large tankhouse containing thousands of electrodes, reducing the current efficiency and increasing the energy consumption significantly. The current efficiency in well-run copper EW operations is typically above 90 %. Most of the unused current is wasted through short circuits, stray currents, and by-byproduct formation (Davenport, King, Schlesinger, & Biswas, 2002; Wiechmann, Vidal, Pagliero, & Gonzalez, 2002; Wiechmann, Morales, & Aqueveque, 2010). Usually, in the tankhouse, the short-circuiting increases the current in the involved cathode by up to 1500 A (Wiechmann et al., 2010). Multiple reasons can cause the short-circuiting in the cell, and the most common reasons include the uneven current distribution among cathodes, tilted electrodes, bent electrodes, and nodules formed due to the large deposition roughness. Recognition of this challenge in the Cu electrowinning process has led researchers to perform many investigations on approaches to avoid and reduce the short-circuiting in the cell. A series of research investigations have been conducted to develop and improve a new type of intercell bar for Cu electrowinning (Wiechmann et al., 2002; Wiechmann, Morales, Aqueveque, & Burgos, 2007; Wiechmann, Morales, & Aqueveque, 2009; Wiechmann et al., 2010; Wiechmann et al., 2014). The associated test results show that this new design limits the occurrence and magnitude of short circuits and allows operation at higher current densities. Sandoval, Clayton, Dominguez, Unger, and Robinson (2010) stated several keys to control short circuits, such as maintaining the straightness of the cathode, removing “edge hair” from the cathode starter, and maintaining electrode alignment in the cell. Prengaman and Siegmund (1999) from RSR technologies developed a new Pb-Ca-Sn anode to prevent the anode deformation, thereby reducing the short-circuiting in the Cu electrowinning cell. Although the negative effects of short-circuiting on the Cu electrowinning have been recognized, and various investigations have been conducted to address this issue, the actual measurements of the electrowinning behavior and performance as short-circuiting is approached and allowed to continue are seldom reported. However, in typical tankhouses, there is a time between when shorting occurs and harvesting/clearing are performed. One key factor in determining the harvest time is the frequency of shorting. Consequently, we have performed short-circuiting tests that allow us to track electrowinning parameters before and after short-circuiting.

Jan 1, 2019

"Chairman - To start this discussion off, I wonder if Mr. Dave Livingstone or Mr. Jeffrey of Granisle Copper would give a description of the crushing plant at Granisle since it is somewhat different from the usual plant, W. N. Jeffrey - Granisle Copper The main difference between the Granisle crushing plant and many others is the Livingstone method of putting the screens under the crushers instead of above them. This method allows a more compact arrangement and eliminates the heavy superstructure required to take care of the screen vibration when the screens are mounted above the crushers. There is a small surge bin above the tertiary crusher which takes care of the variation in circulating loads.All three crushers are gyratory crushers. There is no grizzly ahead of the primary crusher but the fines are removed from the primary crusher discharge at the first screen and sent directly to the fine ore bins. E, Thornton - Sullivan GroupDo you have any coarse ore storage outside?w. N. Jeffrey - Yes, there is about 6000 tons live storage, We have very little trouble with freezing even though it is open storage.E. Thornton - Sullivan GroupDoes rain cause any problem?w. N. Jeffrey - It sometime creates a problem because the storage area is on a slope. It is mainly a problem of keeping the drainage ditches open.Question – What is the size of the primary gyratory crusher and how does it work on run of mine size materials, in other words, do you have a problem with oversize material and how do you handle the oversize rock?w. N. Jeffrey - The primary gyratory is a 42 x 65 with a nominal open side setting of 61'. We do at times get a run of oversize material. For anything too large for the crusher to handle, we use what is known as the Esco hook, which is a type of grapple used to remove oversize rocks.The disadvantage with this equipment is that the crane is too slow. I am sure there must be better arrangements than the one we have,"

Jan 1, 1971

Mine Safety in Chile ?Since the year 2000 fatality rate averages 34 per year ?1% of world mining labour force but 8% of world?s mining fatalities San Jose Mine Safety ?From 1998 to 2010 eight fatalities ?In 2003 mine inspectors recognized no second means of egress and a raise system was developed ?In 2006 182 workers were injured, 56 of them seriously ?In January 2007, there was a fatality after a rock burst, and the government ordered the mine closed ?Less than a year later the mine was back in operations. It had not complied with some of the basic safety measures ordered. One of those measures was to complete the escape way ladder.

May 1, 2011

By DALE MacGREGOR, VERA TUREK

lndusmin Limited acquired the St. Donat quartzite deposit in 1967 to produce high-quality silica for use in the sandblasting and silicon carbide industries. The quartzite, of Grenville age, is highly friable and porous. This is due to numerous small, kaolinite-coated cavities in the quartzite; the cavities were formed through leaching, probably by rising hot solutions.

Jan 1, 1984

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003