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By Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"In natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the content of MoO3 varies from 2% to 10%. As a result, the flotability of seyrigite (scheelite with molybdenum) turns to be weaker. One seyrigite mine, which has been built for 3 years,still could not produce qualified seyrigite concentrate due to the weak flotability of seyrigite (Mo-bearing scheelite) in raw ore. In our experimental research, through adopting new seyrigite collector TA-3 and advanced mineral processing technology, the seyrigite concentrate with a grade of 65.62% WO3 at a recovery of 87.47% was obtained for the raw ore containing 0.19% WO3 and 0.074% Mo. By applying the new technical achievement, for the raw ore containing 0.272% WO3, the seyrigite concentrate assaying 68.03% WO3 with a recovery of 77.56% was obtained in industrial production.INTRODUCTIONIn natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the scheelite is changed to be seyrigite (Ca[(W,Mo)O4]) (Ma, Bian, & Wang, 2013). The content of MoO3 in seyrigite varies from 2% to 10% usually, the content of MoO3 in some of the seyrigite even reaches 34%. The flotability of seyrigite is weak (Zhang, 2007), and the seyrigite is difficult to be recovered by flotation with common collectors and regulators. One scheelite mine in Anhui China, which is a skarn type seyrigite mine, has not produced qualified concentrate yet since 3 years it has been built due to the limit of beneficiation technology. Therefore, it is necessary to conduct research on the collectors with high efficiency and developing advanced processing flow for this kind of ore."

Jan 1, 2016

By T. A. Wedge

This paper suggests a crude correction for the impact of raw material quality on factor productivity in the Canadian mining industry. Such a correction would give a figure more dependent on the changing efficiency of the use of labour and capital, and less dependent on the effects of unquantified changes in inputs.

Jan 1, 1973

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014

By Harry Jomini

Introduction The Wakefield plant of the Aluminum Company of Canada, Limited - a member of the Aluminum, Limited, group of companies - produces magnesia, magnesia fertilizer ingredient, and hydrated lime, from brucitic limestone. Wakefield is on the Gatineau river in Wakefield township, Quebec, some 22 miles north of Ottawa. The plant is near the western bank of the river adjacent to the Ottawa-Maniwaki highway and branch line of the Canadian Pacific railway. The plant is unique in the sense that it is the only place in Canada where brucite is processed. It is also distinguished for its outstanding safety record, as not a single lost-time accident occurred during either 1948 or 1949. The plant is amply provided with safety and comfort provisions in keeping with the standard practice in all of the twelve plants operated in Canada by Alcan and its associated companies. History Following the identification of brucite in the Rutherglen and Bryson districts in Ontario, occurrences of the mineral were discovered in the Wakefield area, Quebec, in 1939. After exploratory work on these deposits and investigation by the Bureau of Mines, Ottawa, on a method of extracting the brucite from the ore, a plant for treating the ore from the Maxwell property was built in 1941 by the Aluminum Company of Canada and commenced operations in early 1942. The process used is more or less in accordance with the method worked out by Mr. M. F. Goudge of the Bureau of Mines.

Jan 1, 1950

By E. M. De Souza, A. M. Coode

"Since potash was discovered substantial rock mechanics research has been done to develop the technology needed to cope with the unique conditions in Saskatchewan mines, to assure general mine safety and to assess the problems associated with mining potash at depth.The practical result of this research was the development of multiple entry systems incorporating yielding pillars for access ways and the chevron type layouts for production panels. These developments proved the viability of extracting potash from between 950 m and 1100 m depth using a high degree of mechanization. High extraction ratios could not, however, be achieved using the developed technology.The presence of a competent salt back is critical to mining the potash, and underground practice is governed by the presence of anomalous geological zones. These factors may be associated with the occurrence of brine inflows. One potash mine in Saskatchewan ceased its underground operations and was closed due to flooding of the entire mine. Two other potash mines in Saskatchewan had significant brine inflows. The costs involved in brine pumping, equipment relocation, bulkhead construction, grouting, and in auxiliary operations can run into the tens of millions of dollars.At Central Canada Potash, the use of stress relief and yielding pillars in the design of the mining layouts has resulted in over-all stable underground excavations and safe mining practices. There are two types of production room s, the chevron and the hybrid, which result in a planned block average extraction ratio of 35010. Mining activity has resulted in brine ingresses in two areas, and additional operating costs have been incurred over the years. These mining areas have demonstrated abnormally high closure rates, and rapid back deterioration. A program was established in those two areas to ensure the practice of safe mining procedures.The short-term perspectives inherent in the program included the elimination of all uncertainties associated with the possibility of an increase in brine inflow leading to flooding, the elimination of the abnormal ground behaviour and ground deterioration in the inflow areas, and the reduction of the long-term adverse effects of mining on regional mine stability. The program was also designed to provide means for developing alternative safe mine layouts which would improve the exploitation of potash resources. Details of the extensive work performed during the program are found elsewhere (E. De Souza, 1988).Grouting and salt backfilling are viable techniques to control brine inflows in underground excavations in potash mines. Detailed instrumentation of the backfilled test areas provides information on the long-term behaviour and effectiveness of the grout/backfill system, allowing for rational decisions on the complete abandonment of these mined out areas, thus resulting in considerable operational cost savings.This paper is presented in two parts: the first addressed the problems of diamond drilling , grouting and backfilling in Panel 209 and the second, addresses the problems of instrumentation and rock mechanics."

Jan 1, 1990

By Atsuki Sado, Akira Ueno, Kazuaki Takebayashi, Kunio Watanabe

The Saganoseki Refinery of Pan Pacific Copper Co., Ltd., Japan, introduced the ISA 2000® process in 2006 to improve product quality and productivity. After resolving various technical difficulties associated with the process, a current density of 325 A/m2 and electrolytic copper production of 234 000 tons per year were realized in 2018. In recent years, Saganoseki Smelter & Refinery has promoted treatment of recycled materials in addition to copper concentrates. Accordingly, the amount and type of impurities charged to the smelting process have tended to increase. In the electrorefining process, impurities such as nickel and antimony cause anodic passivation and formation of suspended solids, respectively. Although these undesirable phenomena can be avoided by controlling impurity concentrations in the anode and electrolyte to appropriate ranges, this also limits the choice of recycled materials that can be processed by the smelter. To achieve both stable operation of the electrorefining process and flexibility in treatment of recycled materials in the smelting process, Saganoseki Refinery improved the capacity of the impurity recovery processes during 2016 to 2018. This paper describes the expansion of the purification plant to remove and recover nickel and antimony. INTRODUCTION The Saganoseki Refinery of Pan Pacific Copper Co., Ltd., Japan, introduced the ISA 2000® (wax- less permanent cathode method) in 2006 to improve product quality and productivity. Since then, the refinery has gradually increased current density, and has been committed to establishing stable operation and high productivity via various improvements related to the electrolyte filtration and additive management systems. Figure 1 shows the trends of current density and current efficiency at the refinery. Although the current efficiency temporarily dropped when the current density was raised to 322 A/m2, it consistently exceeded 97% thereafter. At present, stable operation at 325 A/m2 has been achieved and continues.

Jan 1, 2019

By M. Kataoka, Y. Obara

It is known that compressive strength and tensile strength of rocks vary significantly with specimen size. Rocks are composed of crystals and grains in a fabric that includes flaws such as microcracks, grain boundaries and pores. As the likelihood of including severer flaws becomes greater for a larger specimen, the strengths are small. On the other hand, the size effect in the fracture toughness of rocks has not been made clear until now because there are few studies focused on it. In this paper, Semi- Circular Bend (SCB) test was performed using Kimachi sandstone with various specimen sizes. A shape of the specimen is a semi-circular disc with an artificial notch. The specimens were prepared with various thickness t and radius r as the following two groups; t was changed from 10 to 37.5 mm with r = 37.5 mm in the specimen of group (a), and r was changed from 12.5 to 150 mm with t/r = 0.8 in the specimen of group (b). As a result, there was no significant change in the fracture toughness with different t. On the other hand, the fracture toughness increased with increasing r and converged on a certain constant value in a range larger than approximately 70 mm of r. Consequently it was clear that the size effect in the fracture toughness of the sandstone exists.

Jan 1, 2015

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951

By R. R. Rogers

Introduction The subject of cathodic protection is not new. In 1824 Sir Humphry Davy, in publishing the results of his investigations for the British navy, pointed out that copper could be protected from sea-water corrosion by connecting it electrically with zinc or iron. Since that time much work has been clone in this field, particularly in the protection of metals from the action of sea water, neutral brines, and treated and untreated waters. Special mention should be made of the successful protection of underground pipe-lines which formerly were badly corroded by the water in the ground. So far, magnesium alloy and zinc anodes have been the most popular. However, fairly recent work has indicated that aluminium anodes will give good service under certain conditions. The principle of cathodic protection has been applied extensively in coating steel articles with zinc and in cladding aluminium alloy sheet with pure aluminium. A valuable discussion of the fundamentals and applications of cathodic protection recently was presented in the Corrosion Handbook. A useful list of references was included in the article.

Jan 1, 1949

By C. Jay Hodgson, Adrienne C. L. Larocque

Abstract -The Mobrun VMS deposit in northwestern Quebec does not fit the classic Noranda­ type model, but exhibits characteristics more consistent with a Mattabi-type deposit. The orebodies are underlain by fragmental volcanic rocks indicative of explosive volcanism in shallow water. Felsic volcanic rocks are more abundant than mafic rocks. Alteration assemblages comprise chlorite, carbonate, sericite, and quartz. Broad semi-conformable alteration occurs high in the footwall to the 1100 lens. Mobrun occurs higher in the stratigraphic sequence than most of the other deposits in the Noranda camp. In this part of the stratigraphy, zones of pervasive carbonatization may be more useful guides for exploration than zones of silicification.

Jan 1, 1993

By R. M. Young

In. East Kootenay, two Companies are operating, the Crow's Nest Pass Coal Company of Fernie, with mines at Coal Creek and Michel, and the Corbin Coal and Coke Company, of Corbin and Spokane. Wash., with mines at Corbin. The Crow's Nest Pass Coal Company has also coke-ovens of the bee-hive type at Fernie and Michel. The mines have a productive capacity, with present development and plant, of approximately 1,500,000 tons of coal, and of 300,000 tons of coke annually. The total production in 1923 was 828, 990 tons of coal and 65.990 tons of coke. In the early years of operation, the mines furnished a very large percentage of their output to the railways and smelters. These were, in fact, the primary markets for which the mines were opened and the ovens constructed. The Great Northern Railway had built into Femie, and later extending its line to Michel, became a heavy consumer of both of these mines. The Spokane International, connecting the Crow's Nest branch of the C.P .R. with Spokane, furnished tonnage to Corbin. The Canadian Pacific Railway bought for Crow's Nest consumption. The smelters at Grand Forks and Trail in the Boundary country were large and steady consumers of coke, while in-termittently Northport, Butte, Helena, and Great Falls shared in the product of the ovens.

Jan 1, 1924

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

The bath level measurement is applied in many furnaces to keep control of the level of slag and metal or matte inside. The BLM is used mainly in bath processes, and has not seen much evolution in its basic functionality. For a closed DC FeCr furnace, special demands based on the furnace design and extreme process conditions were considered for the design of a bath level measurement in order to collect valuable information about the furnace operation. This paper will describe these demands and the solutions for them, followed by some of the uses for the BLM in a closed FeCr furnace. Some of the future developments on the BLM conclude this presentation.

Jan 1, 2015

By N. E. Izatt

Molecular recognition technology (MRT) has a wide range of applications in the hydrometallurgical and chemical processing industries for the selective removal of iron as well as various other impurities from a variety of streams, including aqueous solutions through a wide pH range, as well as organic solutions. An example of a commercial application is provided for the removal of iron from an aluminum chlorohydrate stream. In this example, MRT has a selectivity for iron relative to aluminum which is significantly higher than that of ion exchange resins. A discussion of MRT capabilities for other impurities and streams is also provided.

Jan 1, 2006

By R. E. Eyre, L. P. Landucci

C URRENT practice in the zinc concentrate roasting plant of The Consolidated Mining arid Smelting Company of Canada Limited, at Trail, B.C., involves passing the furnace effluent gases through an electrostatic precipitator for the recovery of dust. After removal of the dust the gas is treated for recovery of sulphur dioxide by conversion into sulphuric acid ( 1). However. as roasting techniques improved, and furnace productivity in-creased, the rated capacity of the precipitator was exceeded and it was necessary to consider various means of improving the dust recovery. A study of methods indicated that a baghouse using silicone-treated glass fabric, might be suitable for this particular application. Glass fabric was chosen because the temperature of the roaster effluent gases would range from 450°F to 500°F and tempering air was undesirable to avoid dilution of the sulphur dioxide gas.

Jan 1, 1962

By Boyd Davis, Brook Zaback

"Among the first published papers from Prof. Torstein Utigard was work on imaging the aluminum electrolysis process and in-situ measurements of aluminum in cryolite melts. He and Prof. Jim Toguri used an x-ray radiographic technique to measure interfacial tension of aluminum drops. Publications using this equipment for aluminum electrolysis spanned from 1985 to 2006. As well, other methods were used to better understand electrolysis in molten salts, including hot-stage microscopy, direct observations from above the bath and water modeling techniques. For chloride systems (for magnesium and lithium), it is possible to see side-on the electrolysis using a quartz cell. In honour of Prof. Utigard’s contribution to this field, this paper presents a summary of work on visualization of molten salt electrolysis, including work done at the authors’ labs and others around the world. The paper will summarize key findings and their possible impact on molten salt electrolysis."

Jan 1, 2015

By John McEwen, Ian R. Jonasson, David H. Watkinson

"Mine Gallen is a zinc-rich pyritic volcanogenic massive sulphide deposit that occurs in a fault-bounded block of intermediate volcanic rocks. The block is completely surrounded at the present erosion level by the eastern part of the Lac Dufault granodiorite. The volcanic succession includes a massive feldspar porphyry that is probably a subvolcanic intrusion, an andesitic flow unit and lapilli tuffs. The latter are variably sericitized and pyritic, especially in the vicinity of the massive sulphide into which they grade.The ore body is predominantly pyritewith local sphalerite contents as high as 20%; minor chalcopyrite and trace galena are disseminated, but are found mainly along late cleavage. Most ore is a breccia of massive to banded pyrite-sphalerite, veined by massive and complexly banded sulphides. These structures formed by repeated blocky jointing, cracking, sealing, healing and annealing as hydrothermal fluid repeatedly passed through a developing sulphide mound. The deposit is interpreted to have grown on the seafloor in a manner similar to active mounds in the Galapagos rift.RESUME La Mine Gallen exploite un gisement de sulfures massifs volcan géniques comprenant essentiellement de la pyrite riche en zinc. Ce gisement se trouve a /'intérieur d’un bloc de roches volcaniques de caractère dacitique a andésitique, limite par failles et entoure de tout cote par la granodiorite du Lac Dufault. La séquence volcanique comprend des coulées andésitiques et des tufs à lapilli ainsi qu'un porphyre feldspathique massif sub-volcanique. Les tufs sont sericitises et pyritises, tout particulièrement au voisinage des sulfures massifs."

Jan 1, 1990

By J. M. Harrison

FIELD PARTIES of the Geological Survey of Canada have, in recent years, mapped several areas east and northeast of Flin Flon (9, 10, 12, 13, 14, 15, 118) (1). In all these areas the mineral deposits show a close geographical relation to faults although the immediate control of most of the known ore deposits appears to be folded structures in the rocks (8, 11, 18, 19). Air photographs and published geological maps were studied in order to ascertain whether or not the mineral deposits in the Flin Flon-Snow Lake mineral belt as a whole show any spatial relationship to faults. It was found that most of them do show a distinct geographical association with faults, or with topographic features that may be faults. It is further apparent on air photographs that a major lineament, for composite of lineaments, follows approximately the contact between gneisses and schists of the Kisseynew complex on the north, and Amisk volcanic rocks on the south. However, this Kisseynew lineament is not continuous and, especially in the eastern half of the district, it is exceedingly irregular in plan. Parts of this lineament have been mapped as faults (9, 10, 12, 14), other parts have been shown as stratigraphic contacts (1, 2, 21, 27), and still other parts have not been studied except by reconnaissance methods. It is suggested that the Kisseynew lineament may be due to a deformed fault that extends easterly from a point about 25 miles west-northwest of Flin Flon to a point at least 10 miles northeast of Wekusko lake and that the mineral deposits.

Jan 1, 1951

By P. Keating, J. Goutier, J. Ayer

"New, high-resolution geophysical surveys were undertaken over parts of the Abitibi Subprovince, Canada, to help with geological mapping and to promote mineral exploration. Gravity surveys in the Rouyn-Noranda and Matagami areas (Québec) allowed better 3-D mapping of important geological structures, and a multiscale edge analysis of ground gravity data over the Blake River Group confirms that major faults behave at depth as predicted by surface geology. Airborne gravimetry west of Matagami (Québec) helped to identify a new trend south of Lake Grasset that is almost perpendicular to the assumed geological trend of the area. Electromagnetic (EM) surveys, flown in the Chibougamau (Québec) and Bartlett Dome (Ontario) areas, allowed new conductors to be identified at greater depths than were achievable with previously used EM systems. Airborne magnetic surveys were flown in the Burntbush area (Ontario), and other available high-resolution magnetic data were compiled to produce a continuous and homogenous magnetic grid of the Abitibi region.The resulting compilation map clearly shows the locations of dikes, faults, and shears zones, and reveals some fault extensions in areas of extensive overburden. This grid also allows the computation of enhanced maps, such as vertical derivative and tilt maps (e.g., a tilt map shows subtle magnetic features in the Blake River Group that are difficult to see in the total magnetic field or its first derivative). Results from these new surveys show there is considerable value in (1) resurveying areas covered by older surveys, and (2) recompiling data sets from these older surveys."

Jan 1, 2012

By J. Lipp

The lion share of lithium produced globally originates from South American salars. The standard operation for lithium production utilizes an array of evaporation ponds. This process consume vast areas and is either very slow when relying on solar evaporation - roughly 18 months of residence time; or with very high energy consumption since over 90% of initial water volume needs to be evaporated. A new technology, based on solvent extraction was developed. Results indicate a distribution coefficient up to 30, and selectivity greater than 1,000 towards Na extraction. The loaded solvent is stripped using a strong mineral acid, and the product solution is the lithium derivative of that stripping acid. Utilization of this new LiSXTM technology results in reducing the area needed for a commercial plant as well as reduces the residence time. In addition applying different stripping acids can diversify the product line of such facility.

Jan 1, 2014

By Stephen Mullowney

Outline ? Setting the stage ? Deal activity ? Q1 2013 update ? Key deal sectors ? Deals by geography ? Outlook for 2013 Key Observations 2012 ? Major retreat in M&A activity ? Glencore-Xstrata deal dwarfs all other deals ? Gold & copper dominate deal activity

May 1, 2013