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By A. M. L. Cushing, S. Kelebek, A. Ghahreman

Iron sulfides are part of many ore deposits affecting flotation separation of non-ferrous base metals from them. Open-circuit potential (OCP), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) measurements were carried out with pyrite and pyrrhotite electrodes to investigate their reactivity under various flotation conditions, which involved the use of TETA, SMBS, and their combination. TETA was found to adsorb on the electrode surfaces causing a significant increase in charge transfer resistance of the product formed, which was most significant at OCP. This effect is much less with SMBS, indicating its greater surface reactivity compared to TETA. The combined use of these reagents decreases charge transfer resistance to a greater degree than that experienced with their individual uses. Addition of Cu2+ as a potential activator to this system nearly eliminates the action of TETA on the electrode surface, which can be attributed to sequestration/chelate formation in liquid phase. The relative effects of these reagents on pyrrhotite electrode are similar to that of pyrite. The main difference between the pyrite and pyrrhotite electrodes is that the observed charge transfer resistance on the pyrrhotite surface with each reagent case is significantly lower by 3 to 4 fold. This is compatible with its anodic nature and ease of oxidation since the OCP value of pyrrhotite is lower than that of pyrite. Results are discussed in relation to flotation/depression behavior of these iron sulfide minerals in mineral separation processes.

Jan 1, 2017

By Dean McDonald

The Committee Bay Greenstone Belt extends over 300km and is one of the largest unexplored greenstone belts in North America with excellent gold and diamond potential. Committee Bay Resources Limited holds over 550,000 acres of land with prospective geology in the Committee Bay area southwest of Melville Peninsula, Nunavut. Committee Bay is a typical Archean greenstone belt comparable to the Yellowknife, Red Lake, Kirkland Lake and other prolific gold belts. Drilling during 2003 at Committee Bay resulted in: 1) the discovery of high-grade gold-bearing quartz veins with silicification and sulphidation at Three Bluffs, and 2) the continuation of high-grade gold mineralization in the hinge area of the iron formation at Inuk. Gold mineralization at Three Bluffs is identified in iron formation and adjacent sediments and has been traced by drilling for over 700m. The Three Bluffs iron formation is open to depth and along strike where is has been traced on surface for over 6km. In January 2004 Committee Bay and joint venture partner Gold Field?s announced a $7.1 million exploration program for the Committee Bay project in 2004. A total of 8,000m in exploration drilling has been approved for the expansion of the Three Bluffs to the resource stage and drilling of at least five new target areas. Additional mapping, sampling and geophysics will be used to identify new gold targets along the very prospective Committee Bay belt.

May 1, 2004

By H. U. Ross

"INTRODUCTION Extensive studies have been carried on pure gold to determine the various factors that affect its dissolution in alkaline cyanide solutions. With the extension of milling to refractory ores more intensive investigations on the effect of impurities in the ore on the dissolution kinetics are needed. The present work describes experiments carried on refractory flotation tailings with the object to determine how the recovery of gold could be increased. The effect of arsenic and antimony in the ore and the excessive use of lime are discussed. Control of cyanide losses is also dealt with.MECHANISM OF THE GOLD DISSOLUTION REACTION In aqueous cyanide solutions, gold is believed to be dissolved by one of the following reactions:4Au + 8NaCN + O2 + 2H20 = 4NaAu (CN)2 + 4NaOH (1)2Au + 4NaCN + 2 + 2H20 = 2NaAu (CN)2 + 2NaOH + H202 (2)2Au + 4NaCN + H202 = 2NaAu (CN)2 + 2NaOH (3) The first of these, known as the Elsner Equation is supported by )4 3,2,1(several authors while others(5,6) support reactions 2 and 3 known as the Bodlander Equations. According to Habashi(7), the overall reaction for the dissolution process is as shown in equation 2. Most of the workers agree that hydrogen peroxide is produced in the course of the reaction."

Jan 1, 1973

By Behzad Vaziri Hassas, Firat Karakas, Esra Tanisali, Mehmet S. Çelik, Ahmad Hassanzadeh

Coagulation is basically an aggregation process where particles settle under the influence of interfacial forces with electrostatic forces playing a governing role. Although particle morphology consisting of shape and roughness dictates the physical encounter of two particles, their eventual coagulation is not only influenced by columbic forces but also other interfacial forces such as hydrophobic interaction, which affects the extent of aggregation of particles through increasing the distance of interaction. Roughness is well known to increase the effective contact angle on hydrophobic surfaces and also enhance interfacial forces. In this study, the effect of morphology of particles and particularly roughness on the settling velocity and in turn coagulation tendency was investigated. Batch settling tests (BSTs) of different particle morphologies were investigated as a function of pH. Two different morphologies of silica particles were utilized with the same particle size distribution (PSD) including smooth-spherical and rough-spherical (Etched). Rough particles were prepared by acid etching technique using hydrofluoric (HF) at different time intervals (15-300 sec). Etched samples were identified and quantified by optic profilometry. Settling test results showed that the settling velocity of particles in a suspension of 2% solids in the massive settling region is significantly affected by particle morphology of the suspension. Coagulation results further revealed that aggregation of rough particles is faster than smooth-spherical particles. Coagulation results are elucidated on the basis of particle morphology and its effect on distance of separation through hydrophobic forces.

Jan 1, 2016

By A. J. Neale, B. C. Flintoff

"A review of the dynamic rod mill-ball mill grinding circuit simulator developed at the University of Alberta, highlighting the modular structure and open-ended design, demonstrates the ease with which classical feedback control strategies can be designed and implemented. Various open loop simulations are presented to demonstrate the highly interactive nature of the grinding circuit and to indicate where potential control problems may be encountered. Closed loop simulations are examined, beginning with the basic SISO classical feedback control of circuit product size. Further improvement in the grinding circuit performance in the presence of various disturbances is realized through the application of a classical MIMO feedback controller. As an example of advanced (multivariable) control, static decoupling is implemented and shown to provide additional improvement in overall circuit performance.INTRODUCTIONIt has long been recognized in the processing industries that a dynamic process simulator is an indispensable tool in the design and evaluation of automatic control schemes. In mineral processing the lack of these simulators is felt to have been a major hindrance to the widespread implementation of effective process control systems. In particular dynamic simulation is a necessary precursor to any study of modern (as opposed to classical) process control methods. This paper discusses the development of a dynamic simulator that can be used to study various feedback control strategies. The simulation software provides a powerful educational tool for those individuals interested in grinding circuit control."

Jan 1, 1988

By Janne Karonen, Stephen Hughes, Mikael Jåfs, Jan Stål, Hannu Johto

End-of-life electrical and electronic scrap material attracts attention as a good opportunity for new value creation through efficient metal and energy recovery of such materials. On the other hand, the treatment of such wastes becomes important to avoid problems for society and environment. Treatment of such secondary raw materials faces multiple challenges due to their increasing complexity and evolving nature. Processing of these complex scrap materials together with recovery of a wide range of valuable metals with a combination of pyrometallurgy and hydrometallurgy using Outotec technology is discussed in this paper. One key consideration is environmental performance which needs attention when processing such complex secondary E-waste materials. Outotec has successful experience with commercial projects in the countries at the forefront of environmental and operational standards. INTRODUCTION Increasing attention has been drawn to the responsible processing of end of life Waste Electrical and Electronic Equipment (WEEE) as part of metals recycling, especially copper. It has been estimated that the amount of WEEE globally in 2016 was around the level of 46 Mtpa (Balde et al., 2017), representing a major disposal challenge but at the same time huge opportunity for resource recovery. The potential for increasing the recovery is high, because the official recycling rate of WEEE is in 2016 only 20% (Balde et al., 2017) and at the same time the estimated increase of the WEEE amount is between 3 and 5% per annum in the EU (Eurostat, 2019).

Jan 1, 2019

By K. M. Sarkar

"In many plant trial s(1,2) it has been proven that very small amounts (10 to 20 ppm) of uranium dissolved in mine water can be effectively recovered by the use of ion exchange resins and this uranium recovery has many advantages. In this paper an economic analysis at different levels of uranium contamination and at different market prices of uranium are described.For this study an operating mine-mill complex with a sulphuric acid leach circuit, followed by solvent extraction (SX) process, is considered, where contaminated mine water is available in excess of process requirements. lt is further assumed that the sulphuric acid eluant containing uranium would be mixed with the mill pregnant liquor stream that proceeds to the SX plant for final uranium recovery.Recovery by Ion ExchangeMine water, in this study, is defined as the water coming from the underground mine, or mine pits, and the run-off water from stockpiles, mine shops, crushing plant , washdown areas, etc.In nature, uranium mainly occurs in two stages; reduced (tetravalent) and oxidized (hexavalent) . The oxidation of sulphides present in the orebody often causes the presence of S04- and acidity in mine water, and this acidic water readily dissolves U+6 part of the depo sit. The react ion between hexavalent uranium, which is dissolved in water as U02+ 2 cation and S04 producing uranyl sulph ate as,"

Jan 1, 1984

By Robert B. Parsons

"There is a widespread concern that certain of Finance Minister Michael Wilson's Tax Reform proposals will likely lead to a significant decline in flow through funding after 1988. This does not bode well for the junior exploration sector, which relies heavily on flow-through to finance exploration programs. The exploration industry is actively pursuing various solutions to the problems posed by Tax Reform, in order to ensure that flow-through has a future.IntroductionWhile the proposals contained in Finance Minister Michael Wilson's Tax Reform White Paper may not be as far-reaching as some people had expected, nevertheless the combination of the existing tax rules and proposed new rules offers sufficient complexity to keep pencils sharpened for many months. After having had an opportunity to study Tax Reform since June 18, 1987, the sharpened pencils are suggesting that the White Paper is not without its shortcomings and pitfalls. Insofar as the mineral exploration industry is affected, there is widespread concern that adoption of certain Tax Reform proposals could spell near disaster for mineral exploration in Canada. More specifically, there seems to be a consensus among the industry, as well as some federal and provincial government officials, that the announced phase-out of the ""mining exploration depletion allowance"" (MEDA) would reduce the appeal of flow-through shares to the point where only a fraction of exploration funding would be financed in the future by flow-through."

Jan 1, 1987

By G. Herget

"A brief visit to European longwall mining operations in potash showed that retreating longwall mining provides a very attractive alternative to room-and pillar mining, especially in areas with bad roof, narrow seams and areas with high ground pressures. Mines de Potasse d'Alsace, France converted all potash operations to longwall mining in 1980. Recovery rates per panel vary between 75o/~ to 85% which compares very favourably with Saskatchewan values. Ground pressure in Saskatchewan are comparable to those of some of the deposits in Europe, but the presence of water in the hanging wall of Saskatchewan orebodies has to be given serious consideration. However, given the mining experience in Saskatchewan and the improved technology f or laboratory and field investigations, a review of present mining practice in Saskatchewan is desirable. IntroductionLongwall mining is practiced widely in coal mining and allows complete mechanization. It is applicable at great mining depth, in thin seams, weak roof and has been applied recently even to coal bed s dipping more than 65 degrees. Ideally this system allows complete extraction of an orebody. However, with high mechanization and emphasis on obtaining high outputs per man shift, extraction ratios rarely reach more than 80010 per panel.France, Spain and the U.S.S.R. have had longwall operations in potash for some time and a brief description is given below. Two of the operations were visited and the Russian operation is described based on German literature"

Jan 1, 1986

By P. A. Studemeister

"A trondhjemite stock intrudes a volcanic sequence that has massive sulphide lenses and that is metamorphosed to the greenschist facies at Gutcher Lake, 25 km north of Wawa, Ontario. The stock is 4 km2 in plan and is partly enveloped by an aureole of chlorite-epidote-amphibolehornfels up to 1 km wide. Within this contact aureole, biotite is partly pseudomorphosed by chlorite;epidote and hornblende are mottled by chlorite, calcite, plus quartz; albite has 0% An to 8% An; and hornblende porphyroblasts have actinolite rims. The stock has chlorite pseudomorphous after biotite; and feldspar is mottled by white mica plus calcite and has a clear rim of albite. Fractures filled with quartz, calcite, ankerite, chlorite, white mica, pyrite, and native gold cross-cut the stock and its hornfels aureole. These gold-bearing veins are enveloped by foliated rocks with quartz, calcite, white mica, and chlorite that grade outward from the veins into trondhjemite or hornfels.The stock, emplaced into a submarine volcanic series, emanated heat that caused seawater to convect and formed a contact aureole of hornblende hornfels. The stock eventually intruded its aureole and this culminated with regional metamorphism to the greenschist facies. Regional metamorphism hydrated the stock and its hornfels aureole. Native gold precipitated with quartz along fractures from metamorphic flu ids in response to cooling and wallrock hydration. exploration for this type of gold deposits should focus around felsic intrusions that have albite and that have contact aureoles retrograded by regional metamorphism."

Jan 1, 1985

By A. G. Storey, J. B. W. Bailey

"The Noranda Process at the Horne Division ofNoranda Mines Limited now smelts approximately 350,000 short dry tons of concentrate a year, which is 40% of the total smelter throughput. Campaigns are averaging 200 days and refractory consumption is much lower than in the conventional smelter.In this paper, details ofrecent operation are given, together with updated projections for operation with higher levels of oxygen enrichment.IntroductionThe Noranda continuous smelting process has been in operation at Noranda, Quebec, for six years and in that time it has smelted a million and a half tons of concentrate. It is currently smelting 1,200 to 1,250 tons per day of concentrate on an instantaneous basis"" and it is handling approximately 40% of the Horne smelter throughput.This paper will describe the current operation of the process and the improvements that have been made since 1976, when the process was described by L.A. Mills et al.lSince early in 1975, a high-grade matte averaging 73% copper has been produced, which is then sent to the converter aisle for final treatment. All the information in this paper refers to the operation of the process in the matte mode .Early in 1978, Kennecott Copper Corporation started up their new smelter near Salt Lake City, Utah , which has three Noranda Process reactors operating with high oxygen enrichment of the tuyere air (2). These furnace s incorporate some design improvements, which will be described briefly."

Jan 1, 1980

By I. S. Thompson

A program of geochemical till prospecting, carried out by Derry, Michener & Booth in 1974, was instrumental in t~ e discovery of a copper deposit in Currie Township, Ontario, beneath thick lacustrine deposits of the Abitibi Clay Belt. The prospecting system involved the continuous collection of glacial sands and gravels beneath the clays, using a track-mounted, dual-tube rotary drill, and the separation and geochemical analysis of the heavy mineral content for Cu, Zn, Pb, Ag and Au. In one of 22 holes drilled down-ice from nine Canadian Nickel airborne EM conductors, fragments of chalcopyrite-bearing graphitic argillite, assaying 12% Cu, were recovered from a 14-foot gravel section beneath 83 feet of clay. Ultimately, mineralization was identified in 10 of 11 additional holes drilled up to 3,000 feet down-ice from the Currie deposit. The glacial fan, when compared to the 1,200- by 165-ft area of the subcropping mineralization, is at least 20 times the area of the deposit and is the result of glacio-fluvial reworking of the mineralized ground moraine. The Currie deposit is contained within a Keewatin succession of graphitic argillite, dacite tuff and graywacke, which is intruded by dacite and feldspar porphyry sills and dykes and truncated by a Keweenawan diabase dyke. Grade and thickness of the mineralization, which lies chiefly within the argillite, is related to felsic intrusives and hydrothermal alteration, and to fold hinges.

Jan 1, 1979

By C. Overton, R. W. Nice

"With todays economic trials and tribulations we have all become deeply engaged in costs and cost cutting in our field of mineral processing. Grinding is one of the most expensive unit operations. The cost of grinding media is the most expensive item in grinding costs. Therefore, it is only reasonable to attack the cost-cutting area by trying to reduce the consumption of media. This introduces the field of autogenous or rock-on-rock grinding.Rock-on-rock grinding is not new to us. It has been known for many decades;The South Africans used pebble grinding in the '20's for gold.Mr. B. Crocker was prompted for the same reasons to introduce pebble grinding at Lakeshore Mines in Kirkland Lake during the last war.The Buffalo Anchorite used beach pebbles in grinding prior to the war.Autogenous and semi-autogenous grinding is used quite successfully in the iron ore field. Base metals have their examples in Australia at Caba, in Africa at Komato and in Sweden at Aitik.Recently three mills in British Columbia and one in Arizona started with autogenous mills in their circuits. One was originally conceived to utilize a modified autogenous grind with a crusher in the circuit. All except the same mill had contingency plans for converting to semi-autogenous. All four mills have since converted to the semi-autogenous mode. These are Island Copper, Lornex, and Similkameen in B.C. and Pima Mining in Arizona."

Jan 1, 1975

By Joanne G. Petrini

ISO 26000 Unique Process Unique Personality ?Almost 10 years in the making ?What type of standard is this? Different type of ISO Standard ISO 26000 Structure and Substance ?Principles ?Core Subjects ?Implementation Guidance ISO 26000 Impact ?Same old, same old? ?So Is there really anything NEW? ?Should I care??

May 1, 2011

By David Humphreys

It is difficult to overstate the importance of China to the future of the world mining and metals industries. In a remarkably short time, China has risen to become the world?s largest producer and consumer of steel and its second largest consumer of non-ferrous metals such as copper and aluminium. It is currently the world?s largest buyer of copper on international markets, the second largest buyer of iron ore, and the third largest buyer of alumina. At the same time, it is the world?s largest or second largest producer and exporter of tin, lead, zinc, magnesium and a host of minor metals and industrial minerals, as well as a fast-growing exporter of coal.

May 1, 2002

By J. Standen T.

The main purpose of this publication is to present relevant advances in processes and technologies of importance for consideration in the design of new refineries and the modernization of existing refinery facilities. Operation at current densities of between 300 A/m2 and 350 A/m2 is already part of the criteria customarily implemented on recent projects. This is due in part to the development of permanent cathode technology. In recent years, this technology has also been integrated with process control and automatic electrode handling and preparation machines. The combined implementation of these technologies has the advantage of enabling the process to be monitored, thus assuring traceability and allowing greater knowledge of the process to accrue.

Jan 1, 2007

By L. V. Chugaev

In the course of the hydrothermal refining of copper-nickel products containing covellite, oxidation of Fe2+ ions by the CuS?Cu2+ pair takes place, and iron is precipitated as hematite. Lower copper concentrations in the solution and higher solution acidity lead to the partial oxidation of sulphide sulphur, whereupon hematite is reduced by covellite causing iron to go back in solution. It is demonstrated that in the process of hydrothermal treatment of the covellite-containing solid product in pure water covellite oxidises millerite to polydymite (Ni3S4). Formation of polydymite during the process of refining seems to be due to millerite oxidation both by covellite and the CuS?Cu2+ pair.

Jan 1, 2007

By G. Brooks, M. Hamed, S. Nightingale, K. Coley

The Marangoni effect plays a significant role in slag line corrosion of refractories. Previous experimental studies for various refractory /slag systems and mathematical models are reviewed and show that Marangoni flow is important in slag line corrosion under static conditions. Recent work by the authors is presented which also shows significant slag-line corrosion of MgO refractory in SiO2-CaO-FeOx-MgO slag. The rate of attack of the MgO was marginally slower in the case of slags containing alumina. A semi-empirical model developed by Hrma based on mass transfer control described reasonably well the observed progression of corrosion with time. Further work is proposed to evaluate this model.

Jan 1, 2004

By H. Zniber El Mouhabbis

Ore dilution or stope overbreak increases the cost of production and ultimately reduces the profitability of a mining operation. The adverse economic impact of ore dilution is due to the added costs associated with the mucking, haulage, crushing, hoisting, milling, and treatment of waste rock or low grade ore in the hangingwall and footwall. One factor that could have a significant influence on stope overbreak is the undercutting of the stope into the walls. Undercutting stope walls is often necessary, in particular in narrow vein mines. Moreover, equipment size has a role in drift sizing where stope undercutting may become a must in order to fit the mobile equipment while respecting legal clearances.

May 1, 2009

By H. Gharahbagheri, S. Shafiei Zadeh, H. Hassan Nejad

Waste Electrical and Electronic Equipment (WEEE) is one of the fastest growing types of solid waste in the world, and often contains precious metals, especially gold. Gold processing and recovery from secondary materials, especially WEEE, have been under investigation for more than a decade now; however, a comprehensive review that illuminates the future path is missing in the literature. The aim of this short paper is to discuss the recent advances in gold processing and recovery from secondary electronic materials and why it has not yet become practical. The role of pyrometallurgical and hydrometallurgical methods, as well as their advantages and disadvantages will be discussed; however, the focus will be on Biosorption and recent advances.

Jan 1, 2014