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By M. Eikerling

The full competition between mass transport and reaction in PEMFC unfolds in cathode catalyst layers (CCLs). Recently developed models provide vital insights into effects of thickness and composition on effectiveness of catalyst utilization and performance. However, the CCL's key function in liquid water removal is rather unexplored. Studies of water balance in PEMFCs focus mostly on other cell components. Notwithstanding this prioritization, a simple calculation shows that the CCL is the PEMFC's favourite medium for conversion of liquid water into vapor. Porous structure and wetting properties steer the interplay of evaporation, transport and reaction. A model will be presented, that links pore space morphology, composition, distributed properties (concentrations, pressures, reaction rates, potential) with global performance (critical phenomena). It reveals how problems of flooding in the fuel cell could be mitigated by properly adjusting catalyst layer structure and operation conditions and under which conditions all liquid water arriving in the CCL would leave it as water vapour through the CCL/GDL interface. Results for a simple variant of the model emphasize the role of the CCL as a watershed for the whole cell.

Jan 1, 2005

By Pierre Montrueil, Marcel St-Amant

Within the next few years, underground mobile equipment will be partially automated. Mining methods will integrate more and more automation. Such an evolution will be possible only if adequate underground communication systems are developed. This is expected due to the available competence in Canadian telecommunication, to the economic pressure on the Canadian mining industries for international competitiveness and to the social changes where a better working environment (i.e. less accidents) becomes a major concern. CCARM propose the concept of a Production Area Network for Automated Mobile Units called PANAMU as an intermediate size communication system. It can be implemented using mature present-day technology and it can be integrated in some mine wide communication systems. It can evolve so as to incorporate new technologies because of its modular concepts. In this paper, the communication requirements are estimated, the amtmptions are defined, the concepts of the PANAMU are presented and an over- view of its implementation is described. CCARM presents this article to the mining industry as a document for discussion.

Jan 1, 1994

By Robert B. Parsons

"Ontario and Quebec taxpayers will have to dig deeper into their pockets to pay more tax, according to budget papers tabled in these provinces in May 1993. Individuals will be hardest hit, but corporations will also have to ante up in the face of higher rates, reduced deductions, and new taxes.Up, up, and away...Somewhere in the bleak picture of the 1993 Quebec and Ontario budgets, there is a bit of good news for the mining industry.Careful scrutiny reveals:• Ontario will correct a capital tax provision which inadvertently penalizes flow through share issuers;• Quebec's flow-through incentives will be extended to December 31, 1995; and • both Quebec and Ontario will allow deductions for mine site reclamation payments.The industry may also find some comfort in the fact that Ontario's new corporate minimum tax will be profit-based (unlike the federal minimum tax), so that non-producers should not face a liability for this tax. There is some concern though, about Quebec's announcement that the refundable credit mechanism in the Mining Duties Act will be reviewed."

Jan 1, 1993

By D. E. Salman, R. R. Maclachlan, R. J. Barclay

"There is a considerable resource of data for spherical charge cratering, both as single charges and in row-of-charge geometr(1). The data are. however, based on cratering performance to a single free planar surface.In practice. the more common circumstance involves an angular surf ace geometry. such as occurs at the toe of a bench or the wall of a stope. It is for the purpose of investigating this circumstance that the described test work was conducted.The test objectives were: (1) to observe the change in single-charge cratering performance between planesurface and angle geometry; (2) to identify the optimum performance of single charges cratering to a plane surface. cratering from a bench sub-grade position and cratering from a condition of zero sub-grade or stope wall geometry; and (3) to observe the performance of row-of-charges cratering to an angular surface at various row burials and spacing. The row charge burial and spacing dimensions were to be expressed in simple numerical multiples of single-charge depth-of-burial data."

Jan 1, 1981

By P. R. A. Andrews, R. K. Collings

"There are more than thirty-five deposits or occurrences of celestite in Canada, chiefly in Newfoundland, Nova Scotia, New Brunswick, Ontario and British Columbia. Deposits of economic interest are the Lake Enon and MacRae deposits in the Loch Lomond district of Cape Breton Island, Nova Scotia. Two Cape Breton deposits were operated from 1969 to 1976 by Kaiser Celestite Mining Limited, which supplied an upgraded celestite concentrate to an associated strontium carbonate plant at Point Edward, near Sydney.The MacRae deposit is of current interest because of its possible development for strontium carbonate production using the ""black ash"" process. This process involves chemical leaching, rotary kiln calcining with petroleum coke, washing and treatment with carbon dioxide.Celestite is the basic material used in the manufacture of strontium chemicals, principally strontium oxide, carbonate, nitrate, chromate, chlorate, chloride, sulphide and phosphate. Strontium chemicals, in turn, are used in the manufacture of glass and ceramics, in pyrotechnic devices, in the production of strontium metal and in other metallurgical applications. Recently, strontium ferrites have been introduced into permanent ceramic magnets."

Jan 1, 1991

By B. S. A. Tatone

The surface roughness of unfilled rock discontinuities has a major influence on the deformational and hydraulic behaviour of discontinuous rock masses. Although it is widely recognized that surface roughness is comprised of a large-scale (waviness) and small-scale (unevenness) components, most investigations of surface roughness have been restricted to small fracture surfaces (< 1m2). Hence, the influences of the large-scale components of roughness are often neglected. Furthermore, these investigations typically focus on analyzing roughness in terms of two-dimensional profiles rather than the complete three-dimensional geometry, which can lead to potentially biased estimates of roughness. This contribution demonstrates the use of a new optical digital measurement system, based on the principle of triangulation, to digitize a large-scale natural rock discontinuity surface at both outcrop-scale (~6m x 2m) and lab-scale (~100mm x 100mm). Subsequently, the digitized surfaces are systematically analyzed using the three-dimensional roughness methodology proposed by Grasselli to investigate the dependency of roughness on sample window size and measurement resolution.

May 1, 2009

By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By James R. Yeager, Eric L. Hoffman, John R. Clark

"Abstract -This paper describes fire assaying and ‘high tech’ alternatives for gold analysis, including advantages and disadvantages of each method. These ‘high tech’ methods include INAA (instrumental neutron activation), aqua regia digestion/AA (atomic absorption), GFAA (graphite furnaceatomic absorption) or ICP/MS (inductively coupled plasma emission mass spectrometry) and a combination of cyanidation with AA, GFAA or ICP/MS methods.Fire assay remains the stalwart among analytical methods for gold but, even with its multiple analytical finishes, is not fool-proof for recovering 100% of the gold present. Consumers of assays should not blindly trust the assay results without consideration of quality control data. Laboratories can and do make mistakes. Some of these can be easily discovered if you do your own due diligence. All these measures should ensure that gold analysis values from successive campaigns and from different laboratories meet acceptable levels of accuracy and precision, and can be correlated together, particularly when they occur in neighboring holes. This is essential just as much for prospect evaluation as for project feasibility."

Jan 1, 1998

By K. L. Eastwood

The ISA PROCESSTM cathode plate is characterised by its copper coated suspension bar, coupled with a blade employing austenitic stainless steel alloy 316L. The blade material has become the mainstay of the technology and has been closely copied by competing cathode designs. Improvement to the cathode plate design remains a key area for research, and ongoing developments by Xstrata Technology&apos;s ISA PROCESSTM have recently been commercialised. Two such developments are the ISA Cathode BRTM and ISA 2000 AB Cathode. The ISA BR cathode is a lower resistance cathode that has proven to enhance operating efficiencies. The AB cathode was designed to improve stripping inefficiencies in the ISA 2000 technology. These developments have now had time to mature and their long term performance will be discussed. Rising material costs and the desire to extend the operating boundaries of the standard 316L cathode plate has triggered a number of significant advances. These involve the use of different stainless steels as alternatives in some operational situations. The technical aspects and results of commercial trials on this development will also be discussed in this paper.

Jan 1, 2007

By Owen Owens, W. P. Armstrong

The process of arriving at the size and grade of: (a) a newly-discovered body of mineralization, (b) a potential ore resource, (c) an orebody proposed for mining, or (d) the ore reserves in a mine, requires fundamental geological, and geometrical determinations as well as physical and chemical analyses. This paper outlines geological and geometrical features considered critical, in the authors&apos; experience, in realistic reserve determination. These are discussed under the headings "The Four Cs". They include the Character, type or nature of the mineralization; the Continuity of various types of mineralization in the deposit; various key concerns in the Calculation besides the mathematics; and the Classification section which refers to basic considerations in classifying a mineral estimate. It is suggested that the responsibility for the calculation of a Resource or Reserve should be that of a geologist experienced in the ore type under review. Further, it should be the responsibility of the board of directors of the company owning the deposit to ensure that a sufficiently experienced person is chosen to carry out the process.

Jan 1, 1993

A series of small scale tests have been conducted to evaluate the effect of micro-fracture development, imposed by blasting, on the material properties of the rock as well as its resistance to crushing and grinding. The uniaxial compressive strength, tensile strength, Poisson?s ratio, P-wave, Swave velocity, point load test index, crushing and grinding work indices were evaluated for samples without any blasting load and for samples which had received a variety of blast loads ranging from a single impact with low strength detonating cord, to combination of impacts at different times and significant impacts with powder factors close to those used in practical blasts. It was shown that the rock mechanics parameters change even at low impacts, suggesting easier crushing of the rock. Damage values appear to be affected by timing as stress wave superposition affects the damage process. Fragmentation is achieved at higher impact levels while work index modification of the fragments is also observed when high powder factors are used, suggesting improvements in grinding.

May 1, 2003

By Emmanuel John M. Carranza, Martin Hale

Abstract- An application of logistic regression to mapping of gold potential in the Baguio district of the Philippines is described. Categorical map data such as lithologic units and proximity classes of curvi-linear features, based on spatial association analyses, are quantified systematically and used as independent variables in logistic regression to predict the probability for presence or absence of gold mineralization. Regression experiments to compare between using all independent variables that are associated spatially with the response variable and using only statistically significant independent variables are performed. The results of the regression experiments are similar; however, the use of all independent variables produces slightly optimistic results but better prediction rates for the known gold deposits in the test district. At least 68% of the ‘model’ large-scale gold deposits and at least 76% of the ‘validation’ small-scale gold deposits were predicted correctly. The predicted geologically favorable zones are also similar to delineated geochemically anomalous zones. The technique presented using logistic regression as a data integration tool is effective for geologically constrained technique of mapping mineral potential.

Jan 1, 2001

By Tibor Horvath

Dust abatement is possible on bulk materials, whether conveyed or stockpiled. Minimum (ppm) quantities of chemical additives can efficiently and rapidly control dust of conveyed substrates with no effect on floatation chemistry. Top coating of large surface areas can control surface dust and wind erosion. Environmental and toxicity impact must be considered in any treatment, especially on areas with percolation runoff, leachates, or limited containment. The most effective dust control is preventing release of substrate fines rather than trapping and removing air borne dust. Techniques to prevent release of fines from conveyed substrates will be discussed. Dust control dynamics are a very complex combination of solid phase physical and chemical interactions between the substrate and the fines. ?Smart Technology? products permit dust abatement of stockpiled substrates and tailing fields with no environmental impact. Using ?Smart Technology?, the dust abatement products remain active and can re-seal damaged areas. Efficient, low environmental and toxicity impact, dust control will be demonstrated through case studies where these principals have been applied.

Oct 1, 2010

By Daniel Gendron, Luc Morin

"Concentrate sampling is a growing concern in the world's mining and smelting industry. The main modes of transportation for concentrate to the smelter are by truck or rail car in a bulk form, thereby limiting access to sample extraction equipment. In many cases, concentrate is shipped to a smelter by several suppliers therefore requiring individual manipulation of different customer samples in a safe and reliable manner. The Heath & Sherwood Bulk Product Sampler offers this feature as well as an economical and effortless way of obtaining samples in rail cars or truck boxes.In 1994, Noranda Metallurgie in Rouyn-Noranda, Québec purchased a self contained Bulk Product Sampler to extract samples directly from inside rail cars before unloading the concentrate. After testing and comparing the results with the conventional sampling method, the bulk product sampler proved to be a practical and advantageous solution for concentrate sampling both for the customer and smelter. Since its installation at the Horne smelter in Rouyn-Noranda, the Bulk Product Sampler has been steadily used on rail cars which contain concentrates from around the world."

Jan 1, 1996

By R. W. Nice

"For many decades the incidence of a highly active graphite-like ore has plagued the McIntyre mine. This ore acts as a precipitant of the gold complex immediately upon formation of this complex. The gold is subsequently discharged with the tailings.Many different methods have been devised by various researchers all of which proved inapplicable for the McIntyre problem.Recently, McIntyre personnel, through their own research, developed a flowsheet. This circuit should give an overall recovery of 36% which is below the 94% experienced in the mill at present. Therefore, less revenue would arise from treatment of these ores. On the other hand there exists a possibility of more efficient mining methods in some of this ore thus allowing more economic recovery.INTRODUCTION This paper has been prepared to serve two purposes:i) To propose a method of recoverying gold from a sizeable orebody at the McIntyre mine at Schumacher.ii) To summarize and present the many methods suggested to solve a very old but very real mineral dressing problem familiar to the industry as long as cyanidation itself."

Jan 1, 1971

By Deng Yang-wu, Zhang Yan, Chen Chun-fei, Luo Xian-ping, Luo Cai-gui

This paper summarizes the ecological imbalance status of abandoned rare-earth element (REE) mines in southern China. These include large areas of vegetation damage, serious water and soil erosion, landslides, mudslides, heavy metal pollution, water pollution, soil contamination, and fluorine pollution. The causes which lead to the ecological imbalances at abandoned rare-earth mines are analyzed, such as: the inadequacies of using vat leaching, heap leaching, and in-situ leaching processes to extract REE resources; low mineral thickness and low grade of REE ore; and low utilization rates of the resource. Southern ionic REE resources are not fully integrated, with limited access and ineffective supervision of REE mining by relevant departments. The ecological recovery research for ionic-type REE mines is lagging behind, and there is no deployable ecological restoration method for REE wasteland. In the end, the following suggestions are made to improve the ecological imbalance status of rare-earth mine in southern China: develop new rare-earth extraction processes, accelerate the integration pace of REE resources, increase investment in ecological restoration research in rare-earth wasteland, and so on.

Jan 1, 2014

By Tiago Webber

Mineral resources estimation comprises basically two stages: (i) data collection, analysis and validation, and (ii) the estimate of the grades and tones of the deposit. The most applied method for sampling survey in mineral exploration is rotary drilling with total core recovery. High drilling costs make borehole geophysical logging attractive to obtain the maximum possible information from each borehole helping to understand ore intersections, grades variability, limits of the deposits and continuity of the mineralization. In this paper, borehole geophysical logging was used to enhance the sampling survey and to derive grades indirectly (without lab analysis) with a certain amount of uncertainty. Indicator kriging (IK) was the estimation method used, as it is adequate to incorporate the uncertainty associated with the geophysical derived grade values. The results were compared to the conventional procedures using grades determined via core analysis and ordinary kriging. Borehole geophysical logging proved to be efficient to define the essential features of ore deposit and IK provided results with acceptable precision and accuracy if compared to the model provided by ordinary kriging.

Oct 1, 2009

By J. Severin

Surface mining operations are increasingly involving the design and development of deeper and larger open pits, often with plans to transition into underground mass mining operations. Experiences at the Palabora Mine in South Africa demonstrate the complex interactions between underground workings and the steep slopes above that may lead to slope movements that potentially pose safety and economic concerns. To properly assess the rock mass response to these interactions for planning of future developments, understanding the controlling influence of geological and geomechanical structures is crucial. Preliminary results are presented from a detailed review of historical slope monitoring data from the Palabora Mine, before and after the initiation of block caving 400-m beneath a 800-m deep pit. This paper demonstrates that a detailed analysis of geology and monitoring data can be used to better understand the kinematic controls of complex rock slope displacements and interactions between open pits and underground mines. This investigative treatment of the monitoring data is important in understanding the failure mechanisms prior to undertaking sophisticated 3-D numerical models.

May 1, 2009

By J. Spross

"The Key Lake mill has operated since the fall of 1983. The ore from both Key Lake open pits will be depleted by 1997. It is planned to use this mill, located about 60 km southwest of McArthur, to process the McArthur River ore.While the geological data collected so far on the McArthur deposit are encouraging, more information of the deposit is needed before any detailed mine planning can begin.The surface drilling program identified the orebody and provided information on the geomechanical and hydrological properties of the overlying sandstone. It was proposed to conduct an underground exploration program to further delineate the orebody. This was air proved following a public hearing and review process. This program involves the sinking of a 630 metre deep shaft and the driving of one or two drifts along a portion of the orebody. From these drifts, exploration drilling every 10 m to 15 m through the orebody will provide the information required for the preparation of a feasibility study and an Environmental Impact Statement (EIS)."

Jan 1, 1994

By M. Labrie, H. L. Gibson, G. Doiron, J. J. Watkins, D. H. Watkinson

The Corbet deposit is one of 17 proximal Cu-Zn massive sulfide deposits located. within the Noranda Cauldron which occurs within the core of the Noranda Volcanic Complex. The deposit is located at the top of the Havrian Formation, the lowermost formation of the 3000 m thick Mine Sequence; the deposit has Yielded 2.75 M tonnes of ore grading 3% Cu, 0.96% Zn, 2.06 g/t Ag and 1.0 g/t Au. The multi-lens Corbet deposit formed within a 250 m wide crater that occurs within a localized breccia pile. The Corbet breccia pile was constructed by explosive magmatic and hydrovolcanic eruptions localized along the south flank of a larger andesitic shield volcano that formed during the waning stages of Havrian volcanism. The breccia footwall of the deposit allowed unfocused and widespread hydrothermal discharge that resulted in the development of a large area of chlorite and fringing sericite alteration that exceeds, by six times, the size of the sulfide lenses and represents a significant exploration target.

Jan 1, 1993