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By M. H. Allan

"This paper presents the geographic and geological setting of Saskatchewan Power Corporation's Poplar River Mine in south-central Saskatchewan, about 8 miles from the U.S. border. Generally the mine, which is being expanded to four million tons per year, is in an extremely disturbed geological area with severe dewatering problems. The lignite coal, which is strip mined, is supplied directly to an electric power generating station by means of a 7-mile unit-train private railroad.A number of unique reclamation and socio-economic problems were encountered because of the proximity to the U.S. border and because of the lack of experience of the regulatory authorities in projects of this kind. These are described in some detail, as well as the performance of one of the largest draglines in Canada. IntroductionThe Saskatchewan Power Corporation is a publicly owned utility which has the franchise to supply electricity and natural gas to all customers within the boundaries of Saskatchewan.Saskatchewan is a province which can almost be divided in two: the populated southern portion, principally devoted to farming, and the northern portion which is mostly on the Precambrian Shield and consists of lakes, rocks and muskeg. This portion is largely uninhabited except for a number of small villages. However, in the last few years there has been considerable mineral exploration and development, notably for uranium. This has helped considerably in the diversification of the basic agricultural economy of the province.Saskatchewan consists of 251,700 square miles, 761 miles north to south and an average of 335 miles east to west. It has a population of approximately 960,000, giving a population density of four persons per square mile. The Saskatchewan Power Corporation supplies 357,249 electrical arid 221,378 natural gas customers."

Jan 1, 1982

By Yujing Jiang, Xuezhen Wu, Bo Li, Tomomi Iura, Gang Wang

"Yielding bolt has been widely used for rock reinforcement in mining and civil engineering in high stress conditions. However, the interaction mechanism of yielding bolt and matrix mass is still not clear at present, and no analytical model is available to predict its reinforcement effect quantitatively. In this paper, the mainstream yielding rock bolts were reviewed firstly. After that, a coupling model is proposed to account for the interaction between yielding bolt and matrix mass. Based on the plane strain axial symmetry assumption and the incremental theory of plasticity, equilibrium equations and compatibility equations of matrix mass, and also the response of yielding rock bolt are deduced theoretically. The proposed method was programmed in Visual Basic development environment, and a semi-analytical solution for the coupling model is achieved. The reinforcement mechanism of yielding bolt in conventional tunnelling is clearly demonstrated through an illustrative case study. The reinforcement effect of yielding bolt is estimated quantitatively, and the distribution of axial force along the bolt is presented. In addition, the validity of proposed method is verified by numerical simulations. INTRODUCTIONHigh stress in surrounding rock mass can cause serious stability problems such as massive squeezing in soft rock and rock burst in hard rock. It is observed that many conventional rock bolts failed when experiencing large displacement, which implies that they are too stiff to sustain large deformation and dynamic conditions (Stillborg, 1994; Hoek et al., 1995). Yielding bolt, which can also be called energy-absorbing bolt, has been widely used for rock reinforcement in mining and civil engineering for these conditions (Neugebauer, E., 2008). This paper focuses on the static reinforcement effects of the yielding bolts with analytical method and numerical simulations."

Jan 1, 2015

By K. Sakaguchi, T. Yokoyama

"In-situ rock stress measurement was carried out in the Kamaishi mine of Iwate Prefecture to quantify the variation of the shallow crustal stress field associated with the 2011 Tohoku-oki earthquake. Stress measurement was conducted by the Compact Conical ended Borehole Overcoring (CCBO) technique, which is one of the stress relief method. The CCBO technique is the one of the suggested method of ISRM. Measurement period is from 1991 to 2014. Main results obtained in this study can be summarized as follows.The direction of the maximum principal stress did not change much before and after the earthquake. However, the directions of the intermediate principal stress and the minimum principal stress of one year after the earthquake changed from those of before earthquake. Namely, the direction of intermediate principal stress was East-West horizontally, and the direction of minimum principal stress was vertically. This state of stress is reverse fault type and was maintained for three years after the earthquake.The magnitudes of principal stresses and the vertical stress of one year after the earthquake became more than the double before the earthquake. However, the magnitudes of the maximum principal of two year after the earthquake became smaller comparing with those of one year after the earthquake. Furthermore, the magnitudes of the intermediate principal stress and the minimum principal stress of two year after the earthquake became almost same as those before earthquake, and the vertical stress of two year after the earthquake became almost equal with the overburden pressure. And the magnitudes of three principal stresses of three year after the earthquake became the same level before the earthquake."

Jan 1, 2015

By John Canterford

Quay Magnesium Limited (QMG) listed on the Australian Stock Exchange in late September 2004 having raised approximately A$30 million with the object of designing, constructing, commissioning and operating a 15,000 t/a magnesium alloy production facility in Nanjing, China, Site construction commenced in February 2005 with installation of all major components completed by the end of October 2005, Hot commissioning was simultaneously commenced with the final stages of installation, leading to the first stage of continuous ingot casting by mid November 2005, Since that time ramp-up to the name plate capacity has been undertaken, This presentation highlights some of the more significant technical and logistical hurdles that have had to be overcome in order to meet the high quality product specifications required by a range of QMG customers.

Jan 1, 2006

By H. Salamanca

HighService has developed different equipment using wireless technology and machine vision systems that were specially designed to allow 1) the online determination of the SAG mills liner's service life, 2) the automatic detection of a missing dipper tooth in mineral extraction shovels, 3) the reduction of accident risk potential in the mineral transportation within the mine, and 4) the reduction of collision risk potential between shovels and wheel dozers during mineral extraction. For the development of all these systems at HighService, extensive research has been done in radio frequency and image processing fields. The integration of both technologies with the expert knowledge of the company on the typical harsh environment conditions of the mining industry has led to the development of heavy duty equipment that tolerate the extreme mechanical requirements of SAG mills and electrical mining shovels.

Jan 1, 2007

By E. A. Morris

It has been shown that Alberta oil-sands fluid coke can be effectively used to reduce SO2 to elemental sulphur while simultaneously producing sulphur-impregnated activated carbon (SlAC). In the capture of mercury from industrial flue gases, SIAC has proven to be a highly effective adsorbent material. The current research aims at developing an existing SlAC technology to meet the needs of copper smelters for mitigating both mercury and SO2 emissions, while making elemental sulphur as a co-product. The challenge behind this undertaking is that these flue gases generally contain percent levels of 02 and H20 vapour (2-12%). The focus of this study is therefore on the feasibility of reducing SO2 using fluid coke under copper smelter flue gas conditions, as well as the optimisation of SIAC properties for capturing vapour phase mercury. It is hypothesised that mercury capacity is strongly affected by the 02 potential of the activation gas due to changes in surface sulphur types arising from different reduced sulphur species. To verify this, gas chromatography is used to analyse the reaction products while XPS and XANES will be used to describe the nature of sulphur on the SlAC surface. CVAFS analysis of mercury capacity will finalise the hypothesis assessment. Preliminary results indicate that 02 at 5% does not play a significant role in SSA or pore development. As expected, increased residence time contributes to SO2 reduction and elemental S yield.

Jan 1, 2007

By G. Lyle

Since its inception CEMI (Centre for Excellence in Mining Innovation) has focused on facilitating innovative solutions to the mining industry in six strategic research areas; GeoRisk, ConstructMine, ValueMine, FindMine, SustainMine and MineTech (visit www.miningexcellence.ca for details). This paper focuses on CEMI?s largest project to date, Ventilation on Demand (VOD). Energy consumption in mines can account for upwards of 40% of a mines operating cost, with a significant portion of this been consumed by the ventilation requirements. VOD provides a significant opportunity to reduce overall mine ventilation requirements and subsequently energy costs, while potentially increasing mine productivity. CEMI is currently in year 2 of an assessment of VOD, focusing on the financial, physical and equipment viability of utilizing such systems in both new and existing mines. This two year program, to be completed by March 31, 2011, is designed to systematically assess such a system to determine if and when it could effectively be applied in underground mines. The paper will describe the process by which the project was initiated, the demonstration projects established to capture data, the means to interpret the data and the modelling developed to calibrate and predict ventilation system requirements.

Oct 1, 2010

By F. P. Hassani, A. Hara, M. Momayez

To be competitive on the international market, the Canadian mining industry must reduce its costs, increase its productivity and maintain a high standard of safety. There is a great need today for improved methods that would allow the detection of geological structures in advance of mining to reduce dilution and the monitoring of underground structures to increase safety. This will facilitate planning for optimum exploitation of the mine and to increase production at lower costs. This paper discusses two examples of more efficient mine planning using new technologies such as Ground Probing Radar (GPR). In Kidd Creek mine, GPR technology was used at the 2500and 2600 levels to (1) monitor the stability of the sill pillar; (2) locate the presence of disseminated sulphide pockets in the sill pillar for extracting the mineral content; (3) monitor the stope backs and wall structures to evaluate the effect of on-time filling sequences; and (4)assess rockfill quality in terms of the presence of voids and fractures within the rockfilled areas. In the New Brunswick coal mine in Minto, GPR was used along with core log data to map and construct a 3D block of a section of the bench showing the relative position of different layers overlying the coal seam.

Jan 1, 1996

By A. G. Matyas

Process improvements which have reduced the lead content of slag from the Brunswick lead blast furnace are described. Microscope examination and electron microprobe analyses, supported by the results of slag settling and viscosity tests, showed that typically about 70% of the lead in the lead blast-furnace slag was present in the form of entrained prills of metallic lead. The total lead content was found to increase with the magnetic susceptibility of the slag. Measurements in the furnace settler indicated the presence of a magnetite-rich layer between bullion and slag, arising from high magnetite levels in the slag. This layer was believed to inhibit the settling of entrained lead from the slag. Tracer tests showed that the average slag residence time in the settler was less than 2 minutes. Improvements in coke quality and sizing, which led to a reduction in the slag magnetite content, and the installation of a larger settler and a continuous Roy tapper, have all contributed to a significant decrease in the slag lead content.

Jan 1, 1977

By S. Steinlechner, S. Wegscheider

"In the past, the metallurgical industry was most of the time dedicated on their main commodity, recovering base metals like zinc, copper or lead but leaving other valuable side elements in the generated residues. As a result, these accompanying minor elements, like gold, silver, indium or also PGMs can be found in the dumps of the corresponding industry. Because of political unrest, strikes, economic reasons or decreasing primary resources leading to a high supply risk, also those mentioned minor elements moved into the focus of the recycling industry. Therefore, beside the base metals, first of all the recovery of those minor metals would be of high interest contributing to the economic viability of recycling processes, although they occur in much smaller quantities in materials. In this context, residues from zinc industry, like leaching residues or precipitation residues show high potential to carry silver as well as indium next to lead and zinc. Therefore, the paper summarizes carried out thermochemical calculations investigating a possible recovery of silver as well as indium by volatilization and the influence of zinc and lead on this process. Based on these theoretical investigations with HSC, trials in lab scale were done verifying the obtained results.INTRODUCTIONHuge amounts of iron precipitate, mainly jarosite get landfilled every year although there is a high content of valuable metals in this residue beside iron. Nevertheless, jarosite has to be dumped due to the presence of contaminating heavy metals. The accumulation of these residues takes up massive land on the one hand but also causes a series of environmental problems in ecosystems on the other. Moreover, some toxic ingredients such as arsenic and cadmium can be dissolved in rain water and are therefore harmful to the health of the aquatic systems. (Erdem & Özverdi, 2011; ÖzverdI & Erdem, 2010) Approximately 0.5 t of dry jarosite accumulate in the production of 1 t of zinc by the hydrometallurgical zinc-winning route (Svens, 2010). Jarosite is a precipitation residue formed during the iron removal. In general, the iron already exists in the zinc ore which is why zinc ferrite builds up during the roasting step of the zinc ore. Zinc ferrite is only soluble in strongly acidic solutions and during the hot acid leaching step it gets dissolved while zinc and iron enter the solution. It is necessary to get rid of the iron because otherwise it would deposit on the cathode first due to its precious character which would be harmful in the zinc-winning electrolysis. Nevertheless successful investigations were done by adding chlorine to the jarosite to recover silver. These findings leads to another residue which occurs in huge amounts – electric arc furnace dust (abbreviated with EAFD) from the iron and steel industry. In 2013 the annual electric steel production reached about 451 million tons. Around 15-20 kg of EAFD is produced per ton of steel in an electric arc furnace (EAF), creating approximately up to 9 million tons of dust per year. (Grabda, Oleszek, Shibata, & Nakamura, 2014; World Steel Association) Next to elements like zinc, lead and iron, chlorine and fluorine are present in this dust. While galvanized steel plates in the scrap act as a source for zinc, casting powders, flame retardants and synthetic coatings are responsible for the chlorine and fluorine contents in the dust."

Jan 1, 2016

By Frank Arthur Forward

FRANK ARTHUR FORWARD was born in Ottawa and attended the University of Toronto, where he received a B.A.Sc. in chemical engineering in 1924. From 1924 to 1929, he was a smelter operator and research metallurgist with the Consolidated Mining and Smelting Company of Canada Ltd. (Cominco) at Trail, B.C. Moving to Australia in 1929, he was assistant smelter superintendent, Mount Isa Mines Ltd., Queensland, until 1934, when he returned to Canada, spend-ing one year as metallurgist with B.C.

Jan 1, 1970

By W M. Gilchrist

This paper gives an estimation of the future requirements of the western world in relation to energy re-sources. It then goes on to outline the role that atomic power -with its basic raw material, uranium -will play in supplying these energy requirements. Canada's position in this picture is covered, and some interesting forecasts are made. Introduction I T is possible that the following remarks will appear to have more to do with power than uranium. However, to fully comprehend what is in store for the Canadian uranium mining industry, we must be able to estimate the potential requirement, and, to do this satisfactorily, a thorough understanding of the circumstances that will give rise to that demand is necessary. The growing need for electrical energy will play by far the major role, as large tonnages of uranium will be required for its generation. The nuclear weapon has, up to the present, comprised the major market for uranium.

Jan 1, 1964

"The technical report form provides the headings to be used and content required when a completing a technical report to be filed in accordance with NI 43-101. The technical report is meant to be a summary of the scientific and technical information on the mineral property. The Instrument (NI 43-101) requires that technical reports be filed with Canadian provincial or territorial securities regulators to support certain disclosure of mineral exploration, development and production activities and results in order to permit the public and analysts to have access to information that will assist them in making investment decisions and recommendations. FORM 43-101F1 TECHNICAL REPORT INSTRUCTIONS (1) The objective of the technical report is to provide a summary of scientific and technical information concerning mineral exploration, development and production activities on a mineral property that is material to an issuer.This Form sets out specific requirements for the preparation and contents of a technical report. (2) Terms used in this Form that are defined or interpreted in National Instrument 43-101 Standards of Disclosure for Mineral Projects (the “Instrument”) will bear that definition or interpretation. In addition, a general definitioninstrument has been adopted as National Instrument 14-101 Definitions that contains definitions of certain terms used in more than one national instrument. Readers of this Form should review both these national instruments for defined terms.(3) The qualified person preparing the technical report must use all of the headings of the items in this Formandmay create sub-headings. If unique or infrequently used technical terms are required, clear and concise explanations must be included. (4) No disclosure need be given in respect of inapplicable items and, unless otherwise required by this Form,negative answers to itemsmay be omitted. Disclosure included under one heading is not required to berepeated under another heading. (5) The technical report is not required to include the information required in Items 6 through 11 of this Form tothe extent that the required information has been previously filed in a technical report for the property being reported on, the previous technical report is referred to in the technical report and there has not been any material change in the information. (6) The technical report for development properties and production properties may summarize the information required in the items of this Form, except for Item 25, provided that the summary includes the materialinformation necessary to understand the project at its current stage of development or production. (7) The technical report may only contain disclaimers that are in accordancewith section 6.4 of the Instrument and Item 5 of this Form."

Jan 1, 2003

By J. B. McKenzie

Since connnencing underground prcxiuction in 1979, the Ruttan Mine has been prone to secon:iacy sulphide dust explosions. Al though infrequent during the early years of prcxiuction, these occurrences did result in major damage and lost time injuries. 'As the mine exparrled and developed to further depths, sulphide dust explosions occurred on a more frequent basis. Incomplete ventilation se:rvices, required to exhaust the affected areas, caused frequent delays resulting in lower prcxiuction rates due to the time required to ventilate the affected areas of the mine. CUrrent procedures to minimize the effects of secon:iacy dust explosions evolved from practical suggestions arrl examining methcx:ls other mines have developed to cope with the problem. Procedures and regulations to protect errployees from exposure to hazards of sulphur dioxide are time consuming, expensive and counter prcxiuctive in their present fonn. This paper describes the history of secon:iacy sulphide dust explosions at the Ruttan Mine and the methcx:ls and proced.ures currently in place to minimize and contain the effects of dust explosions.

May 11, 1988

By Weiren Lin

The Mw 9.0 Tohoku-Oki, Japan earthquake occurred on 11 March 2011 produced a maximum coseismic slip of >50 m near the Japan Trench. To investigate why the plate boundary fault between the subducting Pacific Plate and overriding North American Plate which caused the earthquake had such unprecedented large coseismic displacement and slipped to the trench, Integrated Ocean Drilling Program Expedition 343 called Japan Trench Fast Drilling Project (JFAST) drilled three boreholes at Site C0019 through the earthquake fault about one year after the earthquake. Borehole C0019B dedicated to loggingwhile- drilling (LWD) penetrated ~850 meters below seafloor (mbsf) at a water depth of approximately 6890 m. The plate boundary fault is located at ~820 mbsf in the borehole and has been identified as the slip zone during the Tohoku-Oki earthquake. Borehole wall resistivity images obtained from LWD show that drilling induced borehole breakouts are available in a wide depth range above the fault but are not available below the fault. Breakouts are reliable indicators of the orientations of current maximum and minimum horizontal stresses and can also be used to constrain the horizontal maximum and minimum stress magnitudes. As results of breakout analyses, the maximum horizontal stress orientation highly varied in the upper part of the borehole, but has a clear preferred orientation in a northwest – southeast direction in the deeper part just above the fault. This orientation is approximately parallel to the direction of the Pacific Plate subduction. Stress magnitude constraints indicate that the post-earthquake stress states in the hanging wall are either in or close to the normal faulting stress regime. By inferring the pre-earthquake stress state and comparing with the constrained post-earthquake stress state, a significant coseismic stress change was interpreted. The stress change suggests an active slip of the frontal plate-interface consistent with coseismic fault weakening and a nearly total stress drop.

Jan 1, 2015

By J. W. Rogers, S. K. Schwartz

"The Cape Breton Development Corporation (CBDC) is a federal Crown corporation which operates two coal mines (Phalen and Prince Collieries), a coal preparation plant, a railway, a central workshop and a deep water shipping facility.The Sydney coal field consists of 11 major seams, which range from 0.8 m to over 3.7 m in thickness. Of the 2.4 billion tonnes of known coal resources in the field, approximately 550 million tonnes can be mined with present mining technology. These parameters define reserves which extend more than 8 km beneath the ocean to a depth of 1200 m. With today’s design and present high production faces, the colliery life is projected at approximately 20 years."

Jan 1, 1996

By P. Keller, T. E. Lister, G. G. Clark, L. A. Diaz

As electronic technology continues to evolve there is a growing need to develop processes which recover valuable material from antiquated technology. This need follows from the environmental challenges associated with the recovery of raw materials and fast growing generation of electronic waste. Although present in small quantities in electronic devices, the availability of raw materials such as rare earths and precious metals becomes critical for the production of high tech electronic devices and the development of green technologies (i.e. wind turbines, electric motors, and solar panels). Therefore, the proper recycling and processing of electronic waste presents an opportunity to stabilize the market of critical materials, providing a proper disposal and treatment of a hazardous waste stream. This paper describes the development and techno-economic assessment of a comprehensive process for the recovery of value and critical materials from electronic waste. This hydrometallurgical scheme aims to selectively recover several value streams (base metals, precious metals, and rare earths) present in electronic waste. The economic feasibility for the recovery of rare earths from electronic waste is mostly driven by the efficient recovery of precious metals, such as Au and Pd (ca. 80 % of the total recoverable value). Rare earth elements contained in magnets (speakers, vibrators, and hard disk storage) can be recovered as a mixture of rare earth oxides which can later be reduced to the production of new magnets.

Jan 1, 2016

By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By J. M. Gregg, C. J. Persellin, I. D. Somerville, E. A. Atekwana, K. L. Shelton

"Zn-Pb sulfide mineralization at Abbeytown mine and Twigspark quarry comprise the only known car¬bonate-hosted base metal sulfide deposits in the Sligo syncline, northwest Ireland. Limestone sedimentation occurred uniformly throughout the region during the Early Carboniferous (Mississippian) as observed by field relationships and lithofacies; however, petrographic and stable isotope evidence indicate that host-rock dolomitization occurred under different conditions at localities to the west and east of the Ox Mountains inlier, suggesting significant uplift and geologic isolation of these areas prior to dolomitization. Localized fluid flow systems are thought to be responsible for sulfide mineralization and associated epigenetic carbonate cements. West of the Ox Mountains inlier at Abbeytown, evidence of three geochemically distinct fluids are observed: (1) a lower-temperature, lower-salinity fluid (70°-130-°C, 4-9 wt.% equiv. NaCl); (2) a lower-temperature, higher-salinity fluid (70°-140°C, 15-24 wt.% equiv. NaCl); and (3) a higher-temperature, moderate-salinity fluid (165°-220°C, 8-14 wt.% equiv. NaCl). Similar fluid types were observed at the Twigspark deposit. The source of the higher-salinity fluid is likely seawater evaporated to near the point of halite precipitation. The higher-temperature fluid is thought to have been derived from deep circulation of basinal brines. It is speculated that mixing of the higher-salinity fluid with the high-temperature fluid was vital for ore formation at Abbeytown because fluid inclusions in sphalerite have homogenization temperatures and salinity values that fall along a mixing trajectory of these end member fluids. Also, areas where the high-salinity end member fluid is absent are barren of sulfides. Less complex fluid systems are indicated for sites east of the Ox Mountains inlier where no sulfide mineralization was observed. Data from base metal sulfide prospects in northwest Ireland indicate no connection with the regionally extensive flow system thought to be responsible for Zn-Pb deposits throughout the Irish Midlands.Les minéralisations en sulfures de Zn-Pb de la mine Abbeytown et de la carrière Twigspark sont les seules gîtes de métaux usuels à encaissant carbonaté connus dans le synclinal de Sligo, au nord-ouest de l’Irlande. Ces carbonates se sont déposés d’une manière uniforme dans la région au Carbonifère inférieur (Mississippien) tel que l’indiquent les relations de terrain et les lithofaçiès; les données pétrographiques et d’isotopes stables indiquent toutefois que la dolomitisation de l’encaissant s’est faite sous des conditions différentes aux localités situées à l’ouest ou à l’est de la boutonnière des Ox Mountains, ce qui suggère un soulèvement et une isolation géologique significative de ces secteurs avant la dolomitisation. L’action de systèmes de circulation locaux sont considérés être à l’origine de la minéralisation sulfurée et des ciments carbonatés épigénétiques qui leur sont associés. À Abbeytown, à l’ouest de la boutonnière des Ox Mountains, on note les effets de trois fluides géochimiquement distincts: (1) un fluide à basse température peu salin (70°-130°C, 4-9% poids équivalent NaCl); (2) un fluide à basse température fortement salin (70°-140°C, 15-24% poids équivalent NaCl); and (3) un fluide formé à plus haute température et salinité modérée (165°-220°C, 8-14% poids équivalent NaCl). Des fluides similaires ont été observés au gîte Twigspark. La source présumée du fluide le plus salin est de l’eau de mer amenée par évaporation près du point de précipitation de la halite. Le fluide à plus haute température est probablement dérivé de la circulation profonde de saumures dérivées d’un bas¬sin sédimentaire. Il est possible que le mélange du fluide à haute salinité avec celui à haute température ait joué un rôle central dans la genèse de la minéralisation d’Abbeytown parce que les températures d’homogénéisation et les valeurs de salinité des inclusions fluide"

Jan 1, 2009

By S. Surapunt, C. M. Nyamai, K. Itagaki

"The use of liquid copper as a medium for zinc extraction has been used in the Warner Process as a method of processing zinc-lead sulphide ore. The recovery of zinc metal is based on the reaction:ZnS(s) + 2Cu(l) = Zn(g) + Cu2S(l)In this method, thermodynamic and phase equilibria investigations of the Cu2S-FeS-ZnS and Cu2S-PbS-ZnS systems are of importance and form the basis for the liquid sulphide phase which appears as a product and is used as a solvent in the Warner Process. Phase relations in the Cu2S-FeS-ZnS and Cu2S-PbS-ZnS ternary systems were determined experimentally at 1473°K to provide a fundamental basis for the new zinc smelting process. The results show that the solid solubility of ZnS in the two systems is very small (2 wt% to 3 wt% ZnS in FeS, 4 wt% ZnS in Cu2S for the Cu2S-FeS-ZnS system; less than 0.5 wt% ZnS in both PbS and Cu2S for the Cu2S-PbS-ZnS system). The Raoultian Activity Coefficient of ZnS in the liquid mixtures and the vapour pressure of zinc over the matte in both systems is relatively large (?° = 7.7 – 15.8, Pzn(atm) = 0.088 – 1.026 for the Cu2S-FeS-ZnS system; ?° = 8.9 – 12.9, PZn(atm) = 0.075 – 0.214 for the Cu2S-PbS-ZnS system). On the FeS-ZnS join, the only phases detected are FeS and iron-rich sphalerite (Zn, Fe)S. The binary join mixture occurs at about 92 wt% FeS-8 wt% ZnS at 1473°K. Electron microprobe examination of the quenched samples indicate about 47 wt% to 48 wt% FeS in sphalerite and about 2 wt% to 3 wt% ZnS in the iron sulphide phase. On the Cu2S-ZnS join, microprobe analysis reveals that the maximum solubility is 4 wt% Zn in liquid Cu2S and 3.6 wt% Cu in solid ZnS. In the Cu2S-PbS-ZnS ternary system, microprobe analysis of the quenched samples indicate on average, 5 wt% ZnS in the liquid phase region. The only phases detected on the PbS- ZnS join are ZnS and PbS. The eutectic phase contains, on average, 13 wt% ZnS. The phase relationships, very low solid solubilities of zinc sulphide in the liquid mixtures of both Cu2S-FeS-ZnS and Cu2S-PbS-ZnS systems, coupled with the high Raoultian Activity Coefficient of ZnS as well as the high vapour pressure of zinc over matte all favour the partitioning of zinc metal into the vapour phase. This new process is cost effective and bypassesthe expensive and tedious conventionaltechnique of zinc production involving oxidationof the sulphide ore by roasting followed bya reduction process to extract the zinc. Theresults indicate that a new zinc smelting technologyusing the Warner Process would bemore efficient and preferable over the traditionalmethods of zinc extraction."

Jan 1, 2002