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By R. M. S. Häggblad

The article deals with stabilisation and regeneration of Ce02 and Ce02/Zr02 based Pt water gas shift catalysts, subject to high initial deactivation. The reaction gas species effect on the catalyst deactivation was investigated by H2-TPR. Activity measurements enabled the effect of different promoters, some added to the Ce02 based catalysts and some to the Ce02/Zr02 based Pt catalysts, to be investigated. The catalysts were also characterised by BET and CO-TPR. Deactivated catalysts activity was restored by using various regeneration methods. Of the two selected carriers the Ce02/Zr02 based Pt catalyst showed the highest resilience to deactivation. For the two different carriers, Ce02 and Ce02/Zr02, Wand Re were the best promoters when the catalyst was subject to deactivation. Experiments with Hr TPR indicate a fast initial change in the platinum oxides concentration and composition. The CO-TPR was used to make conclusions about the various regeneration effects of water and oxygen on the catalyst. Finally it is suggested that not one deactivation mechanism is possible and which mechanism that dominates is dependant on the catalyst and the reaction gas composition.

Jan 1, 2005

By G. Beckstead, L. Gormely, R. Zimmer, K. Hanneman, B. Nethery

As part of the EIS and permitting activities for the Pogo Mine in Alaska, a risk assessment study for the water management plan was carried out. The basis for the study was a site water volume and contaminant balance model. Probabilistic modeling was carried out using the @Risk Monte Carlo simulation package to investigate the frequency, quantity, and quality of discharges under varying assumptions. The results were used in discussions with regulatory officials as part of the permitting process for the project. The simulation allows probabilistic modeling of key environmental parameters based on input frequency distributions involving both quality and quantity of flow. When combined with predictions of water treatment plant capacities and removal efficiency, this was very useful for defining the likelihood of important regulatory outcomes. Based on the model, certain project modifications were made. Using the simulation as a basis, ongoing dialog with regulators led to consensus that all potential risks have been considered and mitigated for the Pogo Mine according to their likelihood and severity, and that regulatory requirements would be achieved. The paper describes the model and some of the applications for which it was used.

Jan 1, 2005

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By H. A. Hamza, J. Visman

"This is a report on the combined application of ""long-chain"" flocculants and classifier cyclones in the field of slimes treatment, with emphasis on the simultaneous thickening and clarifying of industrial effluents, at low cost. The principle of the process described below involves: (1) the formation of small floes of relatively great strength, by sequential dispersion and conditioning, with average floe size of about 1501 microns; (2) the floes being of sufficient strength to withstand the shearing forces operating within a cyclone and consequently behaving as solid particles with an equivalent diameter (Stokes) that exceeds the size cutpoint of the classifier cyclone; (3) the removal of flocculated solids by means of a classifier cyclone the size cutpoint of which permits effective separation of these solids from the water. Results of test work to date indicate that a broader use of cyclones in industry is possible with the above types of flocculants because the submicron particles and colloidal material are readily collected and clear water is produced, with the attendant advantages of compact construction and low cost that are characteristic of centrifugal separation. The process generally permits classifier cyclones of medium throughput capacity (e.g. 12-in. diam.) to be used for clarifying effluents that contain minus 10-micron particles."

Jan 1, 1973

Reaction between xanthate ions in solution and oxidized compounds present on the surface of galena to form lead xanthate is considered to be a side reaction not contributing to flotation, although accounting for some consumption of reagent. The direct reaction of lead sulphide with xanthate and oxygen to form lead xanthate is the most significant to flotation. Coadsorntion of dixanthogen is also involved. Previous work has shown lead recovery in lead rougher flotation to be a function of m [H+] where: m = concentration of xanthate in solution rHl = hydrogen ion concentration. A plausible explanation for this relationship is suggest-ed. Likewise, the experimental findings that the amount of xanthate adsorbed under certain conditions is a function of m'[H+] are explained in terms of reaction between xanthate ions and soluble basic lead salts such as PbO.PbS04? It is also shown that m[H+] should have a constant value in lead cleaners operating at a higher pH than the roughers. This conclusion is confirmed by plant data, and the value of the constant agrees well with the calculated value. The finding is useful in mill control.

Jan 1, 1965

By T. L. McCall

AUTHENTIC records show that coal mining in Cape Breton dates from the year 1720, when the French military authorities obtained coal from what is now known as the Blockhouse seam, in the Morien district, for use at Louisburg, where the fortress, now of such historic interest, was being built. Thereafter, coal was mined more or less continuously, and although, for many years, in a very haphazard way, there was, on the whole, a steady growth towards a better regulation of the industry, culminating in the year 1825 with the arrival of the General Mining Association in Nova Scotia. This Company, more generally known as the G.M.A., had acquired extensive tracts in Brazil and Colombia and had also purchased the mining rights for the whole of Nova Scotia-excepting such areas as had been previously leased-the attraction being the rich veins of copper currently reported as occurring in the Province. These fabulous copper veins, upon examination, failed to materialize, but the engineer sent out to report on them returned with such good accounts of the coalfields he had seen that steps were taken immediately to investigate them. From that rime onward, the history of coal mining in Nova Scotia is one of progress and achievement. One of the first acts of the G.M.A. was to acquire the areas already leased to other concerns and develop these in a masterly fashion, employing the best machinery and talent available at that time. Such dominant control over the minerals of the Province, although it led to orderly development in the several coalfields, also, later on, resulted in restricting operations in the various coal centres to such an extent that a determined effort was put forward by the people of Nova Scotia to end such a state of affairs. Consequently, in 1857, the original lease of the G.M.A. was abrogated, the Company, however, being allowed to retain certain areas in the districts it had already developed. This opened the way for the formation of other coal-mining companies, and numbers of these immediately sprang into existence in the various coal-mining centres. In 1893, the Dominion Coal Company, Limited, was formed by the amalgamation of seven companies operating in the neighbourhood of Glace Bay, in Cape Breton. Later, in 1910, the Dominion Iron & Steel Company, Limited, obtained control of the Cumberland Railway & Coal Company, which had been formed in 1884 to acquire the rights of the two companies working in the Cumberland County coalfield.

Jan 1, 1936

By M. J. Young, C. A. Aird

"The Gem molybdenum prospect is situated at the head-waters of Clear creek, between the Fraser river and Harrison lake, about 30 miles north of• Harrison Hot Springs, B.C. Clear creek follows a deeply eroded fault zone southwesterly through the center of the claim group. Elevations range from 2,000 feet in the creek bed up the steep slopes flanking the creek to a height of 5,500 feet. The property lies within an area underlain by schists and gneisses which strike from north to west in a broad fold plunging steeply to the northeast. This metamorphic complex has been invaded by numerous bodies of grano-diorite, much of which is gneissic. A granite plug, roughly 2,400 by 4,000 feet in size, has intruded this broad fold just west of Clear creek and encloses a circular breccia pipe 1,500 feet in diameter. In the breccia pipe, fragments of metamorphic rocks, granite and quartz monzonite porphyry are firmly cemented in a matrix of quartz monzonite porphyry. All the above rocks are cut by numerous fractures filled by vuggy quartz veins, many of which contain molybdenite. Attentien was first drawn to the area by a quartz vein, 18 inches in width, known as the Gem vein, which consists of several laminated bands of quartz and molybdenite. Since 1964, exploration efforts have been directed toward attempting to outline a large, low-grade type of molybdenum deposit."

Jan 1, 1969

By Henry C. Knight

A number of improvements in the techniques of budgetary control have been developed in the 1970's. The most significant of these is zero-base budgeting. This procedure is a marked improvement, because it overcomes some of the key weaknesses inherent in most traditional approaches to budgeting. It incorporates techniques and disciplines which improve the quality of both the budgeting effort itself and the documents that most senior managers will need to evaluate. The end result is a budget that establishes and improves cost effectiveness. This budget is based on resource allocations using cost-benefit criteria and on a system of prioritization for making funding choices. Zero-base budgeting is applied only to costs and expenses that are not conducive to control using industrial engineered standards. Therefore, the benefits attributed to zero-base budgeting will only hold true for administrative, selling, exploration, safety, fire protection and overhead, and other indirect types of costs and expenses. It is in this context that the question of its attractiveness for the mining industry is dealt with.

Jan 1, 1978

By Nader Golchinfar

The V-shaped breakout zones around excavation boundary have been captured by a variety of numerical methods such as FEM and DEM methods and failure criteria such as linear Mohr-Coulomb and non-linear Hoek-Brown failure criteria. Diederichs (2007) used Hoek-Brown parameters in his spalling parameter approach; however, it is convenient to use the Mohr-Coulomb failure criterion in numerical modeling because the material parameters can easily be determined from triaxial tests. It is shown in this study that when peak and residual strength parameters as well as dilation angle are properly defined, the brittle Mohr-Coulomb failure criterion can be used to model depth of failure near underground excavations satisfactorily.

Jun 1, 2012

By G. Whittle, R. Peevers, P. Moryoussef

Enterprise optimization is a relatively new optimization approach to mine planning used to jointly consider all aspects of a mining operation affecting the mine planning process and related valuation. In this paper, it is applied at SEMAFO's Mana operations in Burkina Faso, consisting of several open pits and a proposed underground mine. The surface-minable ore is relatively shallow, and the pits are long and linear. The underground operations, as currently envisioned, will consist of a stoping operation accessed by two ramps from the surface. Power is a concern at this property due to local power being produced largely by diesel generators, and it has become one of the key optimization constraints. Other important parameters are the mining and processing rates, underground configuration and cutover elevation. Enterprise optimization was found to improve net present value for the Mana Operations property by simultaneously optimizing multiple parameters and constraints to arrive at an optimal pit and mining phase design, optimal cut-off grades over time, and optimal ore feed based on ore hardness, power constraints, and head wades. Reserves were expanded several times over the course of the study to improve the valuation of the mining operation and put SEMAFO in its present enviable position of ongoing reserve increases.

Jan 1, 2011

By J. C. Hawkins

Determining moisture content and rate of flow of a solid product make measurement and control of dryers unusually difficult. This paper de-scribes a method of accomplishing this with readily made air-temperature measurements. The system can cope with changes in feed moisture and feed rate. It does not measure solids temperature. The system's application to several typical rotary dryers is described, and control schemes using feedforward techniques are explained.

Jan 1, 1971

By M. Nzotta, L. Teng, S. Seetharaman, A. Chychko

The objective of the present work is to optimize the EAF practice towards Mo alloying with maximum retention of the alloying element in molten steel. During Mo additions, there were significant losses to the dust (ca 7 %) and to the slag phase (ca 2 %), which had serious economic and environmental impacts. The present work was aimed at designing a suitable Mo precursor, an alternative to ferromolybdenum, as the Mo source and a process sequence for optimal retention of Mo in the steel. The design of the Mo source should be in such a way that low cost raw materials such as MoO3 concentrate have to be used, stable during the addition so that the vapour phase losses as MoO3 are kept minimum and the dissolution of the precursor in molten steel is easy without loss to the slag phase. After thermodynamic considerations, three precursor materials were chosen, viz. CaMoO4, MgMoO4 and Fe2MoO4. Synthetic mixtures of the component oxides in each case as well as pure MoO3 were investigated by TGA and high temperature XRD in order to find out the temperature range in which the compounds were formed. Experiments were also conducted separately where the evolved gases were analyzed. All the three precursors were formed easily and the loss of MoO3 to the vapour phase was found to be extremely low. Addition of the oxide mixtures to steel melts were conducted in three different scales, viz. 16 g, 500 g and 3 tons (induction furnacle). Initial experiments showed that MgMoO4 was not suitable since the Mo yield in the steel melt was not very high. Fe2MoO4 was found to perform best, the Mo yield reaching 98 %. Further trials were conducted in the 65 ton Electric Arc Furnace (EAF) at Uddeholms AB in Hagfors. Mixtures of mill scale, MoO3 and carbon in suitable proportions were added in a pre-determined addition sequence. It was found that, in the actual practice, the Mo yield reached 99 %, equaling in performance the addition of ferromolybdenum. The process offers an effective use of cheaper raw materials and very high Mo yield avoiding a pre-treatment step like the production of ferromolybdenum. This is both cost effective and environmentally advantageous. The process has been patented and is being currently implemented at Uddeholms AB, Hagfors, Sweden.

Jan 1, 2011

By Paul B. Batten

Shutdown is a generic term for what may be called an Outage, Turn Around (TAR) or Overhaul etc. Running a plant shutdown well has always been key to the financial contribution of a mine. However, something important has changed. The post pandemic reality is that it is harder to retain workers and many of those near retirement just didn’t come back to work. This is creating a shortage of experienced people and a workforce that changes employers easily. We are seeing the impact of this manifested in the erosion of established maintenance and supply chain processes that now struggle to yield the plant runtime that could once be taken for granted. The scope, cost and duration of a shutdown varies widely depending on the nature of the work and the equipment being renewed. The PM of an electric shovel might require a week of downtime and cost $100,000. A gold plant may need to go down for 3 days when its time to change mill liners and cost $500,000. A turnaround in a refinery can take more than a month and cost multi millions. Despite the huge differences.

Jan 1, 2023

By D. P. Goodall

THE development of the oil and gas resources of Western Canada is not, as many suppose, a new industry. For more than half a century an intensive search for these valuable products of nature extended from near the western edge of the Precambrian Shield to the Pacific coast, and from the International boundary north to the Arctic circle. The chief centre of interest to the oil prospector has, however, always lain in that region lying east of the first range of the Rocky mountains and confined largely within the boundaries of the Province of Alberta. Although there are many geological problems yet to be worked out in this Province, the oil-well driller has helped in no small way in determining sub-surface conditions and distribution of rock formations. The chief geological conditions as they affect the drilling of wells are generally re-cognized, and for this purpose the Province may be partitioned into three main divisions: first, the disturbed belt or foothills region extending along the eastern edge of the Rocky mountains; second, the Alberta geosyncline, a broad trough lying to the east of and parallel to the disturbed belt and from which the formations rise eastward to level off and form, third, the plains ? ? region, extending over the rest of the Province. A relatively small area in the northeastern part of the Province is underlain with Precambrian rocks and may be excluded from this classification, as it is of no interest to the oil prospector. The foothills, or disturbed belt, has presented the greatest difficulty to drilling, though it has produced the largest yield of oil within the Province to date. Within the foothills belt, the rock formations consist largely of hard shales interspersed with layers of abrasive sandstones, which wear out drilling bits at an alarming rate. The strata, in most flaces, dip steeply and are cut by numerous thrust faults. Although some o the faults have great displacements, their presence may easily be overlooked or the extent of the fault misinterpreted. Many a prospect well has been located on what appeared to be a suitable geological structure only to find, after drilling through a normal succession of rocks for 4,000 feet or more, that the drill had passed through a major fault plane to a younger formation than that in which drilling was started. Only a repetition of formations already drilled could be expected at greater depths.

Jan 1, 1942

By S. Xu

Magnesium alloy AM50 is of interest to automotive cradle application because of it excellent castability and good ductility. In this work, microstructure and mechanical properties of both low pressure die cast (LPDC) and high pressure die cast (HPDC) AM50 test bars are characterized. Microstructure was examined using optical microscope, scanning electron microscope (SEM) and transmission electron microscope (TEM). Phase identifications were performed using energy dispersive x-ray spectrometer (EDS) and TEM diffraction. It has been found that LPDC produces much coarser microstructure than HPDC. At the same time, the HPDC samples are more heterogeneous in microstructure and composition close to grain boundaries. Particles with various dimensions and morphologies of two different intermetallic phases, Mg17A112 and A18Mn5, were found in all the samples. Mechanical tests were performed under conditions similar to those related to an engine cradle application. LPDC samples show lower strength but better creep resistance than HPDC mainly due to the difference in grain sizes and grain boundary microstructure between LPDC and HPDC. Creep curves are well described by the empirical Andrade equation. Tensile-compressive yield and creep asymmetries were found in AM50, i.e. better deformation resistance in tension than in compression. The average yield asymmetry ratio for all the samples is 0.87. Microstructural examinations on the samples tested in tension, compression and creep showed that the deformation mechanisms in AM50 were slip plus twining at temperatures up to 125°C. The examinations indicate the important role of twining in the asymmetry phenomenon. The creep results indicate that dynamic precipitation of the Mg17A112 phase during testing is not the mechanism directly responsible for the creep asymmetry in AM50.

Jan 1, 2004

By Greg Yuriy

This paper discusses research carried out by the Laurentian University Mining Automation Laboratory (LUMAL) in the field of discrete-event simulation of mine equipment systems and reliability assessment of these machinery using genetic algorithms. The AutoMod simulation package, from Brooks-PRI Automation Inc., is used in this research. It is a 3-D discrete-event simulation/animation software tool for creating realistic depictions of manufacturing and materials handling systems. Discrete-event simulation involves modeling of real-life systems based on variables and events which occur or change at distinct points in time. In our case, a two level, multi-drift sublevel stoping model was created in AutoMod for the simulation of the equipment fleet employed in the development cycle (drilling, explosives loading, blasting, materials hauling, ground support) of a typical underground mine in the nickel mining region of Sudbury in Ontario, Canada. The equipment primarily considered in the simulation is Load-Haul-Dump (LHD) vehicles (scooptrams), drills, explosives-loaders and roof bolters. The purpose of the simulation study is to assess the impact of equipment failures to mine?s production throughput. In more detail, using Mean Time Between Failures (MTBF) data of scooptrams derived from a reliability assessment model based on genetic algorithms, LHD failures are incorporated into the simulation model. These failures cause production interruptions to the development cycle and consequently loss of hauling capacity. This paper will indicate the significance of equipment failures to a mine?s production and suggest a methodology based on the combination of discrete-event simulation and a predictive reliability assessment model using genetic algorithms for the study and analysis of mine equipment systems.

May 1, 2003

By E. E. Mason

THE Myrtle group of mining claims is situated on Barkerville mountain in the Cariboo mining district of British Columbia, west of the old mining town of Barkerville. An 1,800-foot adit, known as the Shamrock tunnel, was driven in 1935-36 from the Barkerville road and in the general direction of the Myrtle group. It was proposed to enlarge this adit to more convenient section, extend it 2,500 feet int0 Myrtle ground, and from there drive a main entry 3,000 feet along the length of the group. Several laterals were also to be driven off this main entry as part of the tunnel schedule. It was thus originally proposed to drive 5,500 feet of new adit and 1,800 feet of laterals, a total of 7,300 feet of new work. Work was commenced with a bulldozer on April 21st, 1941, cutting a bench on the hillside for a plant site. The power plant was ready for operation on August 8th. Slashing and re-timbering of the old adit rook longer than was expected. It was found that 57 per cent of the length required timbering, chiefly by fore-poling, and there was also trouble in several sections with swelling ground. First round in the new face was taken on September 17th, when a 2-shift daily schedule was commenced. Due to delays in delivery of electrical equipment, it was not possible to add the third shift until November 14th. From then on, a 3-shift daily schedule was maintained with the exception of holidays and fortnightly change Sundays until August 1st, 1942, when shortage of labour caused the dropping of a shift. All work was suspended on August 14th. The ground through which the tunnel passed was such that the driving was often interrupted by the need of protective timber at the face. Further, crews were continuously employed timbering behind the face, and in maintenance of timbered sections in swelling ground. Roughly 980 feet of the new workings are now timbered, about 21 per cent of the total.

Jan 1, 1942

By R. G. S. Mussi

An inclined cooling plate is utilized as a modification in the compocasting process of magnesium alloy and the mechanical properties of the composites obtained are studied in this work. Based on crystal separation theory, molten AZ91D is poured onto an inclined plate in order to produce solidification nuclei inside the fluid metal, and is mechanically stirred while reinforcement is added. Particulate SiC was utilized as reinforcement in quantities varying from 0 to 15%vol. Dispersion of the reinforcement was observed by macro and microstructure analysis. SiC was properly mixed into matrix until 15%vol., and Vickers hardness tests were carried out for the composites produced. Results obtained for hardness were shown to increase with reinforcement addition and comparable to those of traditional compocasting. Utilization of Inclined Cooling Plate produced good inclusion and homogenization of SiC through an AZ91D matrix, at lower temperatures and shorter times than traditional compocasting.

Jan 1, 2006

By W. A. Gow, H. H. McGreedy

It is believed that many of the problems encountered in the operation of gold cyanidation plants are difficult to resolve due to the lack of sufficient and reliable in-formation regarding the variations and actual values of operating variables at any given time. The application of instruments to monitor the more important variables in the cyanidation process should result in more efficient plant operation and a better understanding of the process. The use of pH and conductivity sensing devices for alkalinity measurements, a monitor to determine the dissolved oxygen content of plant solutions, a continuous cyanide titrator and sonic control of grinding circuits are discussed. Although the discussion is oriented toward the cyanide process, much of the paper is applicable to other ore treatment operations.

Jan 1, 1966