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By Zygmunt Wegrzyk

Poland is rich in hard and brown coal reserves, which have become the most important, and steadily developing, primary source of energy. With 192.6 mill. t of hard coal production and 40 mill. t of exports in 1978, Poland is fourth and second in the world respectively. The paper discusses the various mining methods adopted in the country's history of mining. Particular emphasis is placed on longwails, their mechanization and equipment assembled in the form of fully mechanized face complexes suited for varied geological conditions. Measures to improve the recovery ratio of coal resources are dealt with. investment efforts undertaken in the coal industry are outlined. An account is given of the ever improving techno-economic results of coal mining. The country also exports a wide range of mining equipment and transfers its well-founded technical know-how to others. There are strong cooperative links with many foreign partners.

Jan 1, 1979

By Marsh A. Cooper

THE THEME of my remarks provides a great deal of latitude. I shall therefore take advantage of the scope it offers to look at our industry across a broad spectrum. My observations reflect a Canadian mining man's varied career as a geologist, mine operator, geological consult ant and company executive in Canada and overseas ... under differing cultures, business environments and political jurisdictions. I was fortunate to come into this industry in the mid-1930's when it was characterized by great enthusiasm, drive and resourcefulness. It was the beginning of a burgeoning era of some 30 years' duration in which the individualist, the entrepreneur and the builder found ample room for expression. As I contemplate the environment in which we now have to operate and try to perceive what lies ahead, I find myself deeply disturbed. Something serious has happened to this industry along the way. It appears that our very success has been the source of our undoing. I believe it is useful to summarize our industry's basic strength at home as a take-off point f or assessing its position in world terms. I hope that I can focus on some of the things that, in my view, must be done for this industry and by this industry to restore Canada's historic role in the world mining community. The Canadian mineral industry provides 140,000 jobs. It pays the second -highest average weekly wages and salaries among the country's major industries. The output per employee in the mining industry is estimated at about three times that for the economy as a whole.

Jan 1, 1977

By V. Chatain

The environmental assessment of historical mining sites contaminated with various inorganic species, as also the determination of remediation targets require a better knowledge of pollutant-bearing phases. The objective of this paper was to investigate the operational fractionation of arsenic (As) in an As contaminated (ca. 3 wt%) soil collected from a gold mining site in France, where mining activities and smelting processes of gold ores took place until 2004. Single and sequential chemical extraction procedures were performed to evaluate the potential mobility of As according to the fractions to which it was associated in the contaminated soil, and also the part of As sorbed onto soil particles. These procedures used provided information on the nature of As fixation processes in the mining soil studied. Results showed that As appeared mainly sorbed (ca. 72%) with iron on the soil particles, in particular amorphous iron oxyhydroxides. These results confirmed a potential risk of arsenic mobilization under acidic and/or reducing conditions, which frequently occur in mining environment. This research evidenced the importance of the knowledge of As-bearing phases to better predict the mobility of this pollutant and in turn improve the management of As contaminated sites.

Aug 1, 2013

By J. P. Morris, J. T. Novak, E. A. Sarver

"A variety of reagents are utilized in coal preparation, but aside from performing their desired function relatively little is known about the behavior of these reagents within the processing circuits. Where exactly do reagents go once dosed? In this paper, we present preliminary results of partitioning studies on frother (i.e., MIBC) and collector (i.e., diesel) chemicals commonly used in coal flotation, and examine implications for water management (e.g., in closed-loop systems). Additionally, we discuss the usefulness of such data in predicting environmental transport and fate of chemicals – which is currently a top priority for industry.INTRODUCTIONThe purpose of coal preparation is to upgrade mined coal into more valuable products. Since coal is primarily used as a fuel source for electricity generation, product specifications are typically contracted to minimize unwanted constituents that detract from the overall heat value (e.g., ash and moisture) or that add to environmental pollution or other problems like corrosion at a power plant (e.g., sulfur) (Pitt & Millward, 1979). Failure to meet specifications results in a financial penalty for the coal producer (Szwilski, 1986), and thus preparation processes have evolved to simultaneously optimize recovery of valuable “clean” coal with rejection of mineral matter and moisture. In addition to advancements in equipment and circuitry, development and application of various chemical reagents has dramatically improved the performance of coal preparation processes.Contemporary preparation plants typically include multiple circuits that can be categorized by the size of particles they process: coarse, intermediate, and fine/ultra-fine (Figure 1). Coarse and intermediate circuits generally rely on size classification and gravity separations (e.g., dense-media cyclones), and do not require significant chemical reagents. However, fine and ultra-fine circuits often use froth flotation to separate coal from impurities, which requires chemical additives (Table 1). The primary additives include collectors, which coat the surface of the coal particles to render them (more) hydrophobic and thus more likely to attach to air bubbles and float; and frothers, which aid in the formation and stability of the froth that will accumulate the floated coal particles. Modifiers are also commonly added to flotation circuits to regulate pH in instances where coal or impurity characteristics may change water chemistries (Laskowski, 2001). Following flotation, coagulants and flocculants are often utilized in solid-liquid separations (i.e., dewatering or clarification) for coal products, and for tailings slurries prior to their disposal in impoundments. Coagulants function via double-layer compression1 to bring colloidal particles together, while flocculants promote bridging between the grouped colloids – and the combined result is enhanced sedimentation (Wills, 2006). Defoaming or anti-foaming agents may also be required to avoid fouling of dewatering operations."

Jan 1, 2012

By David Morrison

Our present longwall problems in Cape Breton can be grouped under five main classifications. These are: (1) Roof control on the face and on the main roadways leading thereto. (2) Transportation of coal along face and levels. (3) Mechanical loading at the face. (4) Safe method of conducting and applying power at the working faces. (5) Dust nuisance. The usual layout for longwall operation in Cape Breton is to have three, and sometimes four, faces in line with each other, the length of face being from 400 feet to 500 feet (see Figure 1), and producing between 425 and 500 tons per face. Each wall is serviced by a well constructed roadway for transportation of coal, men, and materials, and is operated as an independent unit. Each wall works under a regular cycle of operations: first, cutting and boring; second, drawing hardwood chocks, building midwalls, and shifting panlines; and third, loading. The present method of roof control and operation of longwall faces has developed through trial and error since the commencement of longwall miring in Cape Breton. The basic method of roof control in all longwalls in Cape Breton is: rigid support of the roof in the immediate vicinity of the working faces by hardwood blocks, as shown in Figure 2, accompanied by a cushion support furnished by continuous midwalls, 12 feet wide, constructed of stone obtained from the waste and spaced at 50-foot centres. These midwalls are kept forward to within 4 feet to 10 feet of the working face and allow a gradual subsidence of overhead strata, thus preventing any sudden break at the working face.

Jan 1, 1947

By B. Drew, K. Budna, C. Wenzl, D. Gregurek, A. Spanring

"The metallurgy of nickel and cobalt and of copper is closely interlinked when processing sulfidic Ni-Co ores and Cu-Co ores. The respective furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear mode. This paper evaluates the common refractory wear mechanisms, namely infiltration, spalling and chemical attack by various slag systems, as well as sulfur attack, as observed when processing primary sulfidic ores. All these wear parameters, which are discussed in this paper, lead to a severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” is an important prerequisite for the refractory producer. Based on such research results, combined with specific process knowledge, appropriate brick lining solutions for nickel and cobalt processing furnaces can be recommended.INTRODUCTION The metallurgical production of cobalt and nickel and of copper is closely interlinked to the mineralogy of the respective ores: cobalt is found in African Cu-Co ores as well as in Co-rich nickel ores (laterites and sulfides). Also, Co-bearing secondary raw materials contain the mentioned elements in different contents. In pyrometallurgical processing of sulfidic ores, cobalt is generally recovered as a by-product during the production of copper and nickel, whereas it is normally not recovered separately during the processing of nickel laterites but remains in the FeNi product. Besides various hydrometallurgical production routes, the pyrometallurgical processes involved comprise smelting (i.e., production of a Cu-Ni-Co-Fe matte in electric or flash furnaces), converting and refining (i.e. removal of Fe and S as well as other elements from matte by oxidation). The ongoing trend to use higher oxygen enrichment in process air enables higher intensity processes but also increases the oxidation potential in the vessel. Therefore, during smelting and especially during the oxidative treatment in converting and refining, some amounts of valuable metals are also transferred to the slag in their oxides form. A subsequent slag treatment is then applied for recovering valuable metals from the slag, namely allowing an economic material stream handling and minimizing metal losses. This is often done in a slag reduction furnace. Additionally, copper and nickel are very good collectors for precious metals and platinum group metals (PGMs) - therefore, depending on the content of these metals, an additional refining process is used to recover these valuable metals from the matte or metal phase (Elvers et al., 1997; Davenport et al., 2002; Crundwell et al., 2011)."

Jan 1, 2017

By Brien A. Perry, Art Wiebert

"Many organizations which have implemented Total Quality Management (TQM) are finding that the process has either stalled or is not working so well as originally envisioned. This can be particularly evident in an engineering environment where the uniqueness of engineers and their particular culture has not been adequately considered. Winning the commitment of a highly educated group ojprojemnnJJ1s to the TQM concepts, which are often initially 5W2 as too simplistic poses special challenges.Successful TQM implementations are found among technical groups where employees have significant input into creating the new work culture, feel empowered to make changes and are well trained in teamwork. A coach who is knowledgeable in implementation problems can, when working closely with the technical teams, help them circumvent obstacles and guide them successfully through the difficult early phases. The remaining key ingredient for success is supportive management which leads the change and is both informed and appreciative of the accomplishment being made.This Paper is based on first-hand experience with common problems and results encountered in implementing TQM in an engineering environment. Described in the paper are ways of avoiding these problems through awareness of the unique nature of engineering groups, implementation planning, just-in-time training and coaching people in the TQM process. The paper concludes with a focus on the opportunities and results from a successful implementation. These opportunities and results include the benefits each engineer can realize through process thinking, empowerment and teamwork."

Jan 1, 1995

By Dean McDonald

The Committee Bay Greenstone Belt extends over 300km and is one of the largest unexplored greenstone belts in North America with excellent gold and diamond potential. Committee Bay Resources Limited holds over 550,000 acres of land with prospective geology in the Committee Bay area southwest of Melville Peninsula, Nunavut. Committee Bay is a typical Archean greenstone belt comparable to the Yellowknife, Red Lake, Kirkland Lake and other prolific gold belts. Drilling during 2003 at Committee Bay resulted in: 1) the discovery of high-grade gold-bearing quartz veins with silicification and sulphidation at Three Bluffs, and 2) the continuation of high-grade gold mineralization in the hinge area of the iron formation at Inuk. Gold mineralization at Three Bluffs is identified in iron formation and adjacent sediments and has been traced by drilling for over 700m. The Three Bluffs iron formation is open to depth and along strike where is has been traced on surface for over 6km. In January 2004 Committee Bay and joint venture partner Gold Field?s announced a $7.1 million exploration program for the Committee Bay project in 2004. A total of 8,000m in exploration drilling has been approved for the expansion of the Three Bluffs to the resource stage and drilling of at least five new target areas. Additional mapping, sampling and geophysics will be used to identify new gold targets along the very prospective Committee Bay belt.

May 1, 2004

By Carlos Rebolledo, Nelson Parra

Arsenic is an unresolved problem in the mining industry considering the fact that most of the new copper deposits have high arsenic contents; stricter environmental restrictions for handling, transporting and processing complex materials are expected and stable abatement of arsenic is not extensively applied. In 2018 Chile produced 24.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly associated with production of concentrates that will also contain more arsenic. China has set an import benchmark of maximum 0.5% for arsenic content in copper concentrates and this value is expected to be more restrictive in the future. On the first day of 2018 China banned the importation of scrap. Blending practice has been a business option, but it is not sustainable in the future, as “normal” copper concentrates become less and less clean. By the end of 2018, Chile formulated new regulations, increasing the capture of SO2 and arsenic to 95%. In order to comply with these regulations Chilean smelters had to make large invest large amounts of money. Disposing of arsenic as a stable residue is a pending issue. EcoMetales is a 100% subsidiary of Codelco and provides the mining industry with environmental solutions. It has a plant near Calama in Chile that treats flue dust from smelters, refinery effluents and acid solutions from acid plants. EcoMetales is fully committed to contributing to the solution to the arsenic problem. Currently we are developing four main projects: 1) Concentrates treatment. A PLCC project considering the treatment of 200 ktpy of copper concentrates with arsenic from the northern district of Codelco; 2) EPAS DET project considering the treatment of 700 m3/d of weak acid solution with arsenic from the of El Teniente devision of the Codelco acid plant; 3) Borras project, considering the recovery of valuable metals (Cu, Ag, Ge, Pb) from the flue dust leaching plant; 4) Tailings project, considering the recovery of metal values from tailings. The purpose of this work is to present the trends and treatment processes for arsenic handling in the copper mining industry with a focus on the scorodite process. INTRODUCTION Between 2000 and 2015 the global copper concentrates production has grown from approximately eleven to fifteen million metric tons per year. Chile produced 26.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly as a result of the production of concentrates (Figure 1)

Jan 1, 2019

By J. W. Matousek

Tonnage oxygen plays a critical role in the primary production of two of the most important industrial metals - copper and iron - and minute quantities of oxygen play equally critical roles in determining the properties of the market products. For refined copper, oxygen in the final metal is balanced between maximizing electrical conductivity, neutralizing the effects of harmful impurities, and ensuring that the metal takes on the desired "set" during casting - the surface texture and physical properties required for subsequent rolling and drawing. For refined iron, oxygen must be removed to minimize reaction with carbon during cooling from the molten state with the generation of CO and CO2 - leading to a loss of carbon and the creation of "blow-holes" in the solid ingots and the potential for defects in rolled and forged products. This paper reviews the thermodynamics of oxygen in molten copper and iron at the levels of primary interest to production metallurgists.

Jan 1, 2014

By M. Eikerling

The full competition between mass transport and reaction in PEMFC unfolds in cathode catalyst layers (CCLs). Recently developed models provide vital insights into effects of thickness and composition on effectiveness of catalyst utilization and performance. However, the CCL's key function in liquid water removal is rather unexplored. Studies of water balance in PEMFCs focus mostly on other cell components. Notwithstanding this prioritization, a simple calculation shows that the CCL is the PEMFC's favourite medium for conversion of liquid water into vapor. Porous structure and wetting properties steer the interplay of evaporation, transport and reaction. A model will be presented, that links pore space morphology, composition, distributed properties (concentrations, pressures, reaction rates, potential) with global performance (critical phenomena). It reveals how problems of flooding in the fuel cell could be mitigated by properly adjusting catalyst layer structure and operation conditions and under which conditions all liquid water arriving in the CCL would leave it as water vapour through the CCL/GDL interface. Results for a simple variant of the model emphasize the role of the CCL as a watershed for the whole cell.

Jan 1, 2005

By F. H. Edmunds

LLOYDMINSTER is the centre of a well developed agricultural area, lying on the Alberta-Saskatchewan interprovincial boundary in Township Fifty. The surrounding country is gently undulating, without any notable topographic features, but twenty-two miles to the north the North Saskatchewan river, and thirty miles to the south the Battle river, have cut deep valleys. In the spring of 1934, a wild-cat well (Lloydminster Gas Company's No. 1 well) was successful in striking a large flow of gas at a depth o 1,974 ? feet. The gas was piped into the town, a short distance south, and Lloyd-minster became the first Saskatchewan town to be served with natural gas. Following this discovery, other wells were sunk and, up to the present, thirteen wells have been drilled m what is here designated the Lloydminster area. Ten of these wells are in Saskatchewan and three in Alberta. Seven were successful in obtaining gas, three oil, and three have been unsuccessful. The area tested by this drilling is about eight thousand acres, six thousand of which can be considered as proved gas or oil land. To the south and west of Lloydminster, in the Province of Alberta, there are several areas in which oil and gas have been discovered. The Wainwright field lies nearly fifty miles to the southwest; Battleview, where recently gas has been discovered, is thirty miles west-southwest; and the Ribstone area is about thirty miles south and a little west. At Ribstone, a number of wells were drilled some years ago and there is a small production of oil. The data relating to the wells in the Lloydminster area that are recorded in this paper are taken from the records of the several companies operating in the field. The names of these companies are given on the map and on the type stratigraphic section (Figures 1 and 2). The author wishes to record his appreciation to Mr. R. H. Shaw and Mr. 0. C. Yates, both of Lloyd-minster, for much valuable information; also to Mr. E. Swain, of the Department of Natural Resources, Regina, with whom the writer has visited the field on several occasions, and who, by his enthusiasm and encouragement, has done much to forward the development of the area. The well samples were examined at Ottawa by officers of the Borings Division of the Geological Survey of Canada, who also made the interpretations of the logs. Frequent references will be made to the work of Dr. G. S. Hume, of the Geological Survey, and the writer would like to pay tribute here to his work.

Jan 1, 1940

By Sylvie Poirier

This paper focuses on new developments regarding thermal rock fragmentation applications. The technology consists in a strong burner powered by diesel fuel and air. The thermal reaction, which is created, allows for the enlargement of 125-mm to 450-mm holes by breaking the rock in a spalling effect. It has been used for over 30 years in Russian open pit mining. Following an agreement between Dynamitage T.C.G. Inc. and the owner of the technology, major improvements have been brought to this technology, allowing for the fabrication of a prototype suitable for the Canadian industry. In Russia and Ukraine, thermal rock fragmentation is actually used to drill large diameter holes in surface mining. Upon having acquired a better knowledge of this technology, it seems that it presents a great potential for selective mining in narrow-vein operations, for either surface or underground mining. Rocmec International Inc., a subsidiary of Dynamitage T.C.G. Inc., and Natural Resources Canada are technical partners in the evaluation of the operational parameters and environmental aspects, such as gas, heat, dust and fog emissions. Furthermore, Canada Economic Development is a financial partner in this project. This paper presents the technology and its history. It also reports on the changes brought to the equipment to adapt it to North American environments. A summary of the tests realized since 1995 is provided, along with the main conclusions obtained. The anticipated applications for the use of this technology in both surface and underground environments are described, such as open pit mining, bulk sampling and narrow-vein ore extraction. An estimate showing a comparison between the thermal fragmentation mining concept and the long-hole mining method is presented and, finally, the future developments planned are listed.

May 1, 2002

By F. Kitzinger

Electromagnetic testing of wire rope has become more and more reliable over the past two decades. This improvement is partly a result of an unprecedented progress of electronic technology, which permitted the development of a new breed of testing instruments. There are two basic methods for the electromagnetic testing of wire ropes, the AC method and the DC method. Both methods rely on magnetic field disturbance caused by mechanical anomalies in the rope structure. The wire rope under test is passed through a magnetic excitation field, which can be a weak alternating field or a strong static field. Because the alternating field is produced by an alternating current, these instruments are of the AC type(l). In the early days of ND-testing, strong permanent magnets were not yet available; therefore, the static magnetic field was produced electromagnetically with direct current. Instruments based on static excitation are still called DC instruments(2), even though the field is now produced by a permanent magnet. Both these methods have certain characteristic features. The AC method can detect loss of metallic area caused by corrosion or other effects, whereas localized faults such as broken wires are better detected by the DC instruments . The basic principles of the wire rope testers have remained unchanged over the years and the improvements present in the new instruments usually reside in the signal processing and recording sections. The Instrumentation Department of the Noranda Research Centre* has been involved in a four-year development program which resulted in a new type of wire rope tester, the Magnographv** . This new instrument in many ways represents a considerable departure from the traditional wire rope testers. The Magnograph has already been patented in Canada and the U.S.A.(3), and patent applications are pending in other countries.

Jan 1, 1979

By J. Bigu, M. G. Grenier

"Dust size distribution and aerosol size distribution measurements have been carried out in several Canadian underground uranium mines. In addition, dust samples have been analyzed for long-lived radioactive products of the U-238 and Th-232 natural decay chains using ex-spectroscopy and -y-spectroscopy techniques.From the data collected one may summarize: (a) most airborne particulates are of size below I u-m and 50% by mass are found above 1 u-m; (b) dust clouds are bimodal; (c) preferential deposition of radon (thoron) daughters takes place on airborne particulates in the sub -micron range at about 0.1 u-m; (d) deposition of radon (thoron) daughters is proportional to particle surface area; and (e) ex-spectroscopy and -y-spectroscopy of dust samples reveals the presence of U-238, Ra-226 and some of their short-lived and long-lived decay products.IntroductionExtended inhalation of airborne radioisotopes poses a potential health problem to occupational workers. Because of this, monitoring of radiation and dust levels for dose exposure calculation purposes is not only recommended but in most cases mandatory.CANMET (Energy, Mines a nd Resources Canada) has long since been engaged in a comprehensive monitoring program aimed at determining dust concentrations in the respirable size range, aerosol concentration in the sub-micron range, and in the radioactivity associated with these particulates in underground uranium mines. Measurements have been carried-out with gravimetric dust samplers, dust size selectors (including a horizontal elutriator , a fineparticle spectrometer and Nuclepore* filters of different pore sizes) and a condensation nucleus counter(1 – 6). Inactive and active working sites have been monitored according to some typical mining operations. A summary of these data has been given elsewhere(3- 5)."

Jan 1, 1984

By Douglas C. Fraser

"Geophysical data are often presented on maps, sections or profiles with minimal data processing. A common example is magnetic data, in which the diurnal-free raw readings are merely contoured on a map. Other examples include profile presentation of VLF-EM data, IP pseudo-sections and airborne EM anomalies which may be shown on a map with only the measured amplitudes indicated.In recent years, efforts have been directed to the portraying of data in more useful forms. A number of algorithms (i.e., manipulative procedures and equations) have proven to contribute significantly to the usefulness of geophysical data. Some can be applied manually; others are sufficiently complicated to require a computer. Some merely alter the data to a more useful geometric form without altering the units. Others yield quantitative estimates of source body parameters such as conductivity and shape. Several examples follow:1. A simple algorithm is in common use which transforms noisy non-contourable VLF-EM data into less noisy contourable data. The input is the dip angle in degrees or per cent and the output is also in these same units.2. A simple algorithm has recently been developed which allows multi-level dipole-dipole IP data to be contoured on a map. Again, the units are not altered.3. A relatively complicated algorithm is in common use which transforms non-contourable height-sensitive helicopter EM data into contourable resistivity data,4. An algorithm has been recently developed which transforms non-contourable height-sensitive EM data into contourable weight per cent magnetite.The purpose of all the above techniques is to present the data in a simplified form. This, in turn, allows an easier assimilation by the user of much of the information content of the data."

Jan 1, 1981

By Y. Guglielmi, C. Gout, P. Henry, P. Dick, C. Nussbaum

For a decade, observations and experiments conducted in underground environments worldwide (mines, underground research laboratories - URL) made it possible to bridge the scale gap between laboratory scale and large scale faults. Indeed, underground rock laboratories allow developing decameter scale relatively well constrained experiments at the smallest distance from the hypocenters. URL’s experiments allowed developing new monitoring technologies coupling pressure-strain-seismic measurements and reproducing complete earthquakes sequences analogous to natural ones. They also allowed exploring past movements of faults and sometimes also paleofluids in three dimensions and characterizing different fault architectures and hydromechanical properties in unaltered conditions. This is particularly important in the study of faults affecting clay formations which could not be observed at the Earth’s surface because of the high alteration. Here we show how examples from the Mont Terri (Switzerland) and Tournemire (France) The URLs may help in (i) defining the concepts of fault architecture in shales, (ii) estimating fault hydromechanical properties from field decameter scale experiments. Some key results are that faults which are critically stressed or at the rupture limit can reactivate for stresses variations within the range of those produced by shallow underground excavations, and that slight micrometer-to-millimeter scale reactivations may lead to large factor-of-10-to-1000 permeability increases. Such promising results show that URL’s experiments may bring new insights on some key processes that control the relations between fault stability and permeability evolutions in very permeable layers.

Jan 1, 2015

By T. Melfi, M. James

Attaining required mechanical properties in welds made using the double submerged arc welding (DSAW) process is difficult, and it is becoming more difficult as the strength level of the base materials continues to increase. Producing weld metal with adequate mechanical properties involves factors that are often overlooked and not taken into consideration. Not least amongst these problems is simply finding information to use in selecting the appropriate flux/wire combination. Most of the available data on flux/wire combinations provided by consumables manufacturers is generated using the multiple pass welding procedures required for classification per specifications such as AWS A5.17 and A5.23. This data really gives no insight into the properties that can be expected in a DSAW application. Also, base plate composition plays a very significant role because of the fact that base plate dilution can be as high as 70% in DSAW welds. This means that if any elements are present in the base metal that are deleterious to mechanical properties, they will also be present in significant quantities in the weld deposit. Some of these elements can decrease toughness and increase hardness (increased hardness is a concern if the pipe is intended for sour service). Some of these problems can be mitigated by proper selection of welding consumables. Selection of proper welding consumables means selecting an electrode that provides the appropriate alloying elements to obtain the desired level of impact toughness while also keeping the hardness within any specified limits. In order to attain the necessary impact toughness, selection of a flux with an appropriate composition (in terms of its basicity and its ability to control the nitrogen content of the weld deposit) is required. As with all welding processes, the mechanical properties of DSAW welds are also highly dependent on the welding procedures. This work clarifies how to select appropriate consumables to meet a given set of requirements, and also how to achieve the optimum mechanical properties from those consumables.

Jan 1, 2005

By F. G. Smith

Abstract Laboratory methods are now in use whereby the temperature and pressure during the crystallization of hydrothermal minerals can be determined. The techniques include the use of the decrepitation method of studying liquid inclusions, and electrical measurements of pyrite. The determinations are sufficiently accurate that the data can be used in solving a variety of ore deposition problems. Within the last year, several new laboratory techniques have been developed in the Geochemical Laboratory of the Department of Geological Sciences, University of Toronto. The results of several tests of ore by these methods have proved to be useful in treating some problems which previously were considered unsolvable. It is now possible to determine the temperature of deposition of most of the minerals in a hydrothermal ore deposit, also the depth below the surface during deposition. Measurements can also be made of the reopening history of a complex ore. The temperature-pressure determinations depend upon the fact that minerals deposited from a hydrothermal solution always trap a small amount of the solution at the time of crystallization. The solution, being predominantly composed of water, has a density which depends upon the temperature and the pressure prevailing during crystallization. After ore deposition is complete, erosion and isostatic uplift finally exhumes the vein. During this slow fall in temperature and pressure, the solution contracts and a gas bubble appears. If the trapped solution in the mineral is examined, the gas-liquid ratio records the density of the solution at the time the mineral was deposited (except for a slight change in the volume of the mineral). The thermal expansion and compressibility of water and water solutions are known to a sufficient degree that, if the gas /liquid ratio can be determined, the temperature-pressure relations during deposition can be calculated.

Jan 1, 1949

By M. Mirnezami, D. Lascelles, J. A. Finch, E. El-Ammouri

"In a previous publication, the depressant action of Mg above pH 10 on Cu-activated sphalerite was described (Lascelles et al., 2001). In the present communication, a second role, aggregation is introduced.Aggregation (i.e., the tendency of particles to cluster) is measured using settling rate and turbidity converted to an aggregation index (AI) where 0 corresponds to dispersed and 1 to aggregated. Surveys of Cu and Zn flotation stages at four concentrators showed the A1 increased significantly above pH 9. The metal ions identified in the process waters, principally Ca and Mg, were tested to determine which might be responsible. The presence of Mg was found to be the most important, 50 ppm Mg having a greater impact than 500 ppm Ca fkom pH 9 to 1 1. In one plant, poor repeatability in A1 was suspected to be related to varying Mg levels; doping with Mg significantly increased AI.In both aggregation and depression, therefore, the common feature is the impact of Mg at pH > 9. Over this pH range Mg forms a range of hydroxy species, including Mg(OH)2 precipitates. Suggested aggregation and depression mechanisms associated with these precipitates are introduced. Possible problems and opportunities arising from the findings are discussed.INTRODUCTIONProcess waters in flotation circuits contain a variety of metal ions that may introduce unwanted activation or depression. Two common metal ions are calcium and magnesium. Typical concentrations are in the range 50 ppm Mg and 500 ppm Ca (Marticorena et al., 1994, Basilio et al., 1996, Negeri et al., 1997, Nesset et al., 1998)."

Jan 1, 2002