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By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

By Ye Chen, Jianhua Chen, Xianhao Long, Qingxia Liu, Zhenghe Xu

"It is crucial to understand the mechanism of the collector interacting with the mineral surface in the presence of water molecules, which could influence the relaxation and electronic properties of sulphide mineral surface due to the proximity effect for narrow band gap of semiconductors. The adsorptions of three typical collector molecules (xanthate, dithiocarbamate and dithiophosphate) on the sulphide mineral surfaces in the absence and presence of water molecule have been simulated by density-functional theory (DFT). The calculated results show that the adsorptions of collectors on clean mineral surface in vacuum are not in agreement with the observed flotation behaviours. The presence of water molecules has a great influence on the adsorption of collectors. The analysis of density of states of the mineral surface atom suggests that the adsorption of water molecules could influence the electronic properties of mineral surface and consequently influence the adsorption between the surface and the collector molecule.INTRODUCTIONIn the separation of multi-metal sulphide ores, the selectivity of a collector is a key factor for the efficient recovery of the aimed mineral. Xanthate, dithiocarbamate (DTC) and dithiophosphate (DTP) are the most common collectors used in the flotation of sulfide minerals. Generally, xanthate exhibits powerful collecting property but lack of selectivity. While dithiophosphate and dithiocarbamate show the good selectivity in the lead and copper sulphide mineral flotation. The mechanisms of these collectors interacting with the sulphide mineral had been attracted many attentions and several mechanism based on experimental results had been reported (Chander & Fuerstenau, 1974; Fuerstenau, 1990; Raju & Forsling, 1991; Crozier, 1991; Bradshaw, Cruywagen & O’Connor, 1995; Guler, Hicyilmaz, Gokagac & Emekci, 2006). However, the micro-mechanisms of the selectivity of these three thiol collectors on different sulphide mineral surfaces are not fully understood."

Jan 1, 2016

By J. Lee, K. B. Min, J. Rutqvist

Shear slip of fractures in fractured rock masses is a critical issue for many geological engineering applications, such as the design of underground nuclear waste repositories, enhanced geothermal systems (EGS), and geosequestration of CO2. This paper presents new development of the TOUGH-UDEC simulator for analysis of coupled thermal-hydraulic-mechanical (THM) processes in fractured porous media. As an alternative to developing a single coupled THM code in discontinuum, two existing wellestablished codes, namely TOUGH2 and UDEC, are coupled to cover coupled THM analysis of multiphase fluid flow, heat transfer, and deformation in fractured porous media. TOUGH2 is widely used for modeling heat transfer and multiphase, multicomponent fluid flow, and UDEC is a well-known discrete element code for rock mechanics, which have been verified and used by many groups all over the world. Although a sequential coupling of two codes is less efficient than having a single code in principal, a big advantage with coupling of TOUGH2 and UDEC is that both codes are well tested and widely applied in their respective fields. When linking two codes, the coupled equations cannot be solved simultaneously; they should be solved sequentially, with coupling parameters passed to each equation at specific intervals. After solving thermal-hydraulic equations through the TOUGH2 model, pressure (P) and temperature (T) information is delivered to UDEC model. Pressure information is directly stored at the center of each UDEC zone and domain, however, temperature information is interpolated from zone-centers to the corners nodes. After solving the mechanical equation through the UDEC model—considering new pressure and temperature—calculated fracture apertures are converted to equivalent permeability and porosity for TOUGH2 flow analysis. The solution was calculated by iteratively following an explicit sequence for numerical efficiency. Verification examples are presented to demonstrate the capabilities of the coupled TOUGH-UDEC simulator.

Jan 1, 2015

By N. A. P. Kiran Kumar

The Zr-Nb alloys are reported to be showing superior resistance to corrosion and substantially lower hydrogen pickup when compared with zircaloys. In the present study zircaloy-4 and Zr-1Nb (E110) alloys were hydride using high pressure hydrogen gas furnace at a pressure of 20 MPa. Thermal cycling was done on the samples at a temperature of 3500C for 10 cycles with 5h soaking time at 3500C per each cycle. The Microstructural observations on zircaloy-4 samples show long and interlinked hydride like chain, oriented along the circumferential direction. Whereas in Zr-1Nb, short hydrides were observed with hydride platelets not showing interlinked chain like structure. The hydrides in Zr-1Nb were observed to be not showing particularly orientation along the circumferential directions. Electron backscatter diffraction was use to understand the hydride precipitation and their orientation in Zircaloy-4 and E110 alloy.

Aug 1, 2010

By Y. Konishi

This paper reviews the mechanism and kinetics of bioleaching of chalcopyrite by the thermophilic archae Acidianus brierleyi in batch and continuous-flow reactors. Rate data for the batch bioleaching of chalcopyrite concentrate were collected to clarify mechanism of the chalcopyrite bioleaching with A. brierleyi. The chalcopyrite leaching was markedly accelerated in the presence of A. brierleyi, and greater than 90% copper leaching was achieved within 10 days. Chalcopyrite leaching took place predominantly as a result of direct attack by adsorbed bacteria on the sulfide surface, the chemical leaching with ferric iron being insignificant. Batch rate data collected under a variety of operating variables were analyzed with our batch bioleaching model, in order to estimate microbial kinetic and stoichiometric parameters for the microbial growth on chalcopyrite. The batch model and the estimated parameter values were used to find optimum operating conditions. Moreover, the batch model was extended to describe the bioleaching in continuous-flow stirred tank reactors. Simulations based on the continuous reactor model and the estimated parameter values were used to predict the leaching fraction as a function of the number of reactors connected in series.

Jan 1, 2007

By A. J. Russell

"This paper investigates why it is critical for a mine to accurately determine thermal rock properties and virgin rock temperatures. Theoretical simulations of deep mining production zones have demonstrated that thermal conductivity (k), virgin rock temperatures and specific heat (cp) significantly impact rock heat predictions which can be the dominant component of a mine’s heat load. Natural variability in these factors showed that realistic errors can have a significant effect on mine heat loads. This can ultimately affect miner safety and introduces risk to the viability and sustainability of a project. INTRODUCTION Accurate heat load determinations are critical to ensure that underground working conditions are maintained within legislated and mine specific parameters to safeguard the safety and productivity of employees. Underpredicting mine heat loads will result in hot underground conditions, which risk the health and safety of employees, reduce the productivity of employees or stop production if legislated temperatures in working areas are exceeded. Overestimating mine heat loads will result in increased capital and operating costs reducing the viability of the project. Over- or under- predicting the heat load for a project will increase the project risk. Heat sources in a mine can broadly be broken into two categories. These two categories are defined by Hemp and Rawlins (2014) as natural and artificial heat sources. Those sources which depend on the size, location and depth of the mining areas are defined as natural heat sources, whereas those heat sources which are a result of the actual mining activities are defined as artificial heat sources. Autocompression, or the conversion of potential energy, to enthalpy is an important consideration when determining the air temperature in the mine and its interaction with natural and artificial heat sources. It is documented by Jones (1985) and Hemp and Rawlins (2014), that the heat flow from rock in deep mines can dominate other heat sources; information from BBE’s archives show that this is between 40% and 60% of the total heat load. They also point out the importance of accurately measuring both the thermal rock properties and virgin rock temperatures (VRTs) for determining and planning the ventilation and refrigeration requirements for a mine. Both of these texts cite multiple methods for calculating the heat-flux and ultimately the heat load for the different working areas in a mine. All of these methods demonstrate that the heat flux and heat load will increase proportionally with increased thermal conductivity (k), specific heat (cp) of the rock or mineral, and VRT depending the area of the mine or mining method."

Jan 1, 2019

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By R. I. Grauch, Michael D. Glascock, Chen Nansheng, Jr Coveney, James B. Murowchick

"Unusually rich molybdenum ores (cutoff grade = 4.10/0 Mo) hosted by Lower Cambrian black shales have been mined since 1985 near Zunyi in the province of Guizhou in China. Similar ores were once worked for Mo and Ni near Dayong in the province of Hunan. In both mining areas, mineralization occurs in Lower Cambrian black shale (Niutitang Formation and stratigraphic equivalents) as a single sulfide bed or lens with exposed thicknesses up to 15 cm and reported thicknesses up to 35 cm. In addition to high Mo values (4% to 7%), ore samples contain up to 7% Ni, 2% Zn, 2.5% As, and several hundred ppb Au and Pt-group elements, but the precious metals have never been recovered from the ores. Sporadic occurrences of Mo-Ni sulfide ore beds are found in at least five provinces stretching approximately 1600 Ian from Yunnan to Zhejiang. None of the Mo-Ni ore-bed occurrences has any obvious connection with mafic or ultramafic source rocks. Similar occurrences containing elevated values for Ni, Mo, and PGE exist in Devonian black shale in the Yukon. Future exploration for Pt, Au, Mo, and Ni deposits should consider this previously unknown type of sediment-hosted mineral deposit.Sommaire - Des minerais anormalement riches en molybdène (teneur-limite = 4.1% Mo) provenant de schistes argileux noirs du Cambrien Inferieur ont été exploites depuis 1985 près de Zunyi dans la province de Guizhou en Chine. Des minerais semblables ont déjà été traire pour Mo et Ni près de Dayong dans la province de Hunan. Dans ces deux régions minières, la minéralisation se présente dans le schiste argileux noir du Cambrien Inferieur (Formation Niutitang et équivalents stratigraphiques) sous forme de couche ou lentille unique de sulfures avec des épaisseurs exposées de plus de 15 cm et des épaisseurs rapport6es de plus de 35 cm. En plus des fortes teneurs en Mo (4%-7%), des échantillons du minerai contiennent jusqu’ à 7% de Ni, 2% de Zn, 2.5% d'As, et plusieurs centaines de ppb d'or et d'éléments du groupe du platine; toutefois, les métaux précieux n'ont jamais été récupérés des minerais. Des présences sporadiques sous forme de couches de minerai sulfure de Mo-Ni se retrouvent dans pas moins de cinq provinces s'etendant sur 1600 km de Yunnan a Zhijiang. Aucune de ces présences de minerais, sous forme de couches, ne semble associée a des roches du type mafique ou ultramafique. Des présences similaires contenant des teneurs élevées en Ni, Mo et EOP se retrouvent dans le schiste argileux noir Devonien du Yukon. L'exploration future pour des gisements de Pt, Au, Mo et Ni doit prendre en considération ce type de gisement encore inconnu précédemment."

Jan 1, 1992

By Michael Loken, April Montera

"The process of blending consistent and predictable feed for the roasters is critical to optimizing product quality and controlling production costs. To assist in this process, Online PGNAA Slurry Analyzers have been installed and evaluated at a Sudbury Ontario smelter. They are used to measure 100% of the full process stream to obtain elemental composition data in real time. This paper explains the application details at Sudbury and the benefits achieved from their Full Stream, Elemental Slurry Analyzers.INTRODUCTIONSudbury Integrated Nickel Operations (Sudbury INO), a Glencore Company consists of two underground nickel/copper mines in Sudbury, Nickel Rim South and, Fraser, along with the Strathcona mill and the Sudbury smelter. The facilities are spread throughout the 60 kilometer-long, oval-shaped geological formation known as the Sudbury Basin (Figure 1). The company has been mining nickel-copper ores in the Sudbury area since 1929. Nickel and copper are the primary focus of operations at Nickel Rim South and Fraser. Other base metals such as cobalt and precious metals are also produced."

Jan 1, 2016

By D. Runnels, Daniel Roy, Ricardo Esteban, J. Torrealba-Vargas

"An intuitive way to reduce power consumption in grinding operations is to feed the grinding circuit with finer feed by enhancing blasting and fragmentation control. The optimization of blasting with the objective of minimizing power consumption in grinding is not new.The study was based on a Canadian mine that processes a very hard ore. BBA conducted blasting/fragmentation and grinding circuit surveys in 2014. The results of the exercise were used to develop a base case model to simulate the effect of blasting in the operation on the grinding circuit. Tools for fragmentation simulations, particle size measurement and crushing/grinding simulations were used with the objective of reducing the OPEX costs including power consumption.The paper describes the steps involved in the model optimization as well as an economical evaluation of the OPEX savings.INTRODUCTIONIn 2014 BBA was retained by one of its clients to conduct a crushing and grinding survey. The objective of the survey was to update the grinding circuit model with production data and also to develop a tool to investigate opportunities for process improvement.A second phase of the study involved the development of drilling and blasting and crushing models. The models were used to diagnose the operations and to investigate opportunities for process improvement.The objective of the present study is to describe the approach and to identify potential improvements to overall mine site operating costs by better integrating mining and milling operating costs with blasting and grinding models."

Jan 1, 2016

By Jian Li, V. Y. Gertsman, David C. Katz, M. Elboujdaini

Analysis of stress corrosion cracking (SCC) usually involves high-end analytical tools including scanning electron microscope (SEM) and analytical transmission electron microscope (TEM). In recent years, focused ion beam microscope (FIB) has found many applications in materials science fields. In this study, high-resolution FIB images have shown details of crack morphology and a plan-view TEM specimen containing the selected crack-tip was successfully prepared. The preparation of cross-sectioned samples containing crack tips was of paramount importance for subsequent TEM analyses.

Jan 1, 2004

By Gema Ribeiro Olivo

The hydrothermal Au-Pd deposits are hosted by the jacutinga in the Lake Superior-type iron-formation of the Itabira Group, Minas Supergroup. Jacutinga is a highly sheared, metamorphosed, hydrothermally altered iron-formation composed of hematite, magnetite, quartz, talc and phlogopite (Cauê) or muscovite (Conceição) and minor tourmaline, palladian gold, arsenopalladinite, mertierite II and palladeisite (hydrothermal) and native gold, native palladium Pd-Cu-oxides, and kaolinite (weathering products). The highest concentrations of Pd-Au occur in quartz and hematite veins parallel to the S1 foliation (Corpo Y, CorpoX, Aba Leste and Central orebodies, at Cauê and a single orebody at Conceição) or parallel to the S2 foliation (Aba Norte). The average ore grade is 30-40 g/t Au+Pd. The characteristics of the Au-Pd ore favor an epigenetic model for gold and palladium concentration in the iron-formation. During the D1 deformation and peak metamorphism, the oxiziding, acid and hot hydrothermal fluids transported Au and Pd preferentially as chloride complexes. The reaction of the fluid with the dolomitic carbonate (the probably protolith of the jacutinga) would have dissolved carbonate and K-feldspar to form muscovite or phlogopite and tourmaline, resulting in an increase in solution pH and a decrease of Cl concentration and subsequent deposition of gold and palladium minerals.

May 1, 2003

By R. Roufail

"Energy consumption in stirred mills has been studied, in the last couple of decades, on a macro scale. Effective operation and meeting particle size required for downstream operations used to be the main objectives behind energy utilization of stirred mills. In this paper, three energy terms are defined to assist in understanding the breakage mechanism for various types of minerals versus mill operation. The types of minerals studied had diverse physical and mechanical properties that are summarized as specific gravity, hardness and crystal structure. The minerals utilized in this study were quartz and galena. The effect of quartz and galena mix has been addressed as well as Lead-Zinc ore sample from SAG mill discharge. The energy input to the mill is function of the agitator speed, therefore three agitator speeds were evaluated, 1000, 1500 and 2000 RPM, respectively. The energy terms studied are specific energy (kWhr/ton). Effective energy is the ratio between net energy and total energy consumed by the mill. Last type of energy is the specific breakage energy, which is the net energy consumed by the mill per one-micron breakage. Results showed that specific energy and specific breakage rate are functions of mineral type, while effective energy is only function of mill input power (agitator speed).INTRODUCTIONGrinding is the largest energy consuming component of a mineral processing operation and typically consumes about 50% of the total energy used at a mining operation (Botin, 2009). Over the last two decades, stirred mills have been extensively utilized in mineral processing operations due to increased mineralogical complexity of ore bodies. Stirred mills grind particles to less than 10 µm by applying a high power intensity. The technology has been the focus of several research studies to investigate mill energy and grinding mechanisms. Becker, et. al. (2001) studied the relationship between different types of energy including input energy, specific energy, volume/mass specific energies, to stress intensity and final product particle size. Other studies such as by Kwade (1999), Kwade and Schwedes (2002), Blecher et al (1996), Partyka and Yan (2007), Stender et al (2004), focused on mill design and/or stress intensity distribution. Peukert (2004) studied the effect of mechanical properties of the grinding media and ground material on the comminution process."

Jan 1, 2016

By J. D. T. Steyl

Anglo American Corporation and the University of British Columbia have developed a medium-temperature oxygen pressure leaching process for the extraction of copper from chalcopyrite concentrates in an acid-sulphate system (AAC/UBC process). Leaching is performed at 150°C and surfactants are added to disperse molten elemental sulphur from the unreacted sulphide surface to prevent liquid sulphur occlusion. Copper extractions of over 95% and elemental sulphur yields of around 60% were observed over a 2-hour average residence time in a continuous pilot autoclave. Sporadic blockages occurring under continuous conditions were found to be caused by the accumulation of molten elemental sulphur mixed with unreacted sulphide mineral. A batch programme of experimentation was undertaken to establish the reason for this phenomenon. Batch experiments were conducted at low pulp densities on concentrate samples with narrow size distributions and at similar solution compositions to those experienced in the pilot autoclave. The overall rate of chalcopyrite oxidation was shown, under approximately constant solution composition, to be a strong function of the total available mineral surface area. Initial copper extraction rates followed the shrinking particle kinetic model under intrinsic surface control. Deviation from shrinking particle kinetics was however observed after a certain oxidation time. Secondary electron images identified small (typically less than 20 µm) sulphur conglomerates at the point of deviation, which 'collected' unreacted chalcopyrite mineral particles and lowered the total mineral surface area available for oxidation. These sulphur clusters are thought to be the precursor for blockages experienced in the continuous pilot autoclave. These results emphasised the importance of fine grinding (P80 5-20 µm) and suggest that shorter residence times may minimise the formation of sulphur conglomerates in a continuous autoclave operating at medium temperature.

Jan 1, 2004

By Shigeomi Nishigaki

This paper presents quantitative indexes to evaluate operator?s bearing, difficulty in a task, and machine operability when an operator remotely controls a backhoe, and reports the use cases. The quantitative indexes would give her/him the opportunity to reflect on her/his works, and enable us to gain in-depth insight into the teleoperation, and furthermore give us with promising hints to improve it.

Aug 1, 2013

By Akihiko Nishiyama

Unmanned construction technology used for remote control operation of construction machines has some problems to solve compared with manned operation of construction machines, such as fatigue due to long-term operation or decreases in operational efficiency. To solve these problems, we recorded the viewpoints of operators in both manned and remote control operation and analyzed the differences. This paper reports on our discussion of improving the operability of remote control operation based on the analysis results.

Aug 1, 2013

By M. H. Leite, R. Corthésy, D. E. Gill

"La connaissance des contraintes naturelles qui prévalent dans les massifs rocheux est un prérequis indispensable pour la conception sécuritaire et économique des excavations comme on en retrouve dans les exploitations minières souterraines. Certains chercheurs se sont attardés à colliger les résultats de mesures de ces contraintes et les ont utilisés pour produire des modèles de prédiction basés sur leur traitement statistique. Ces modèles de prédiction sont très populaires auprès des exploitants miniers puisqu’ils permettent, du moins dans les étapes préliminaires de design, d’obtenir de façon s’apéconomique mais approximative, une partie des paramètres dont ils ont besoin. Dans le cadre d’un projet initié en 1994 avec la collaboration de l’IRSST, il a été décidé de produire un modèle de prédiction englobant une partie de la zone périphérique de la faille de Cadillac, soit une zone plus restreinte que le Bouclier Canadien utilisé jusqu’ici comme région pour l’élaboration de tels modèles. Pour produire ce modèle de nouvelles données obtenues avec une technique permettant d’exercer un excellent contrôle de qualité ont été ajoutées à celles déjà disponibles. Une telle régionalisation des données de base permet d’obtenir un modèle où les intensités et les orientations des contraintes principales sont beaucoup moins dispersées que ce que rapportent les modèles publiés jusqu’à ce jour. Enfin, il est démontré que le modèle proposé pour la région étudiée est en toute probabilité plus sécuritaire que les modèles plus généraux publiés à ce jour. Knowledge of the in situ state of stress existing in a rock mass is essential to the safe and economical design of underground mining excavations. Prediction models have been published, based on the statistical treatment of stress measurement results. Such prediction models are very popular among mine operators because they allow them, at least at a preliminary design stage, to economically obtain part of the information needed, even if this information is approximative. In 1994, a research project financed by IRSST was initiated aiming to produce a prediction model that would comprise a peripheral zone around the Cadillac fault. This region is more confined than the Canadian Shield on which the existing prediction models have been based up to now. In order to produce such a model, existing stress measurement results have been used in conjunction with new stress measurements that have been performed based on a technique which allows full control of the quality of the measurements. Restricting the data upon which the model is based to a more specific region gives a model in which the intensities and the orientations of principal stresses are far less scattered than the results published to date. Finally, it is shown that the proposed model is probably safer for the studied region than the models previously published."

Jan 1, 1998

By Z. F. Zhou, X. Y. Zhou, V. G. Papangelakis, Z. D. Jankovic, S. M. Ulyanov, S. N. Lvov

Recently developed flow-through electrochemical techniques (1,2) were employed for measuring pH in high concentration aqueous solutions and geothermal brines. The pH values of (1) 5.0 mol kg-1 NaCl + x mol kg-1 HCl, (2) 3.0 mol kg-1 of NaCl + 0.5 mol kg -1 of KCl + 1.0 mol kg-1 of CaCl2 + x mol kg-1 HCl (x < 0.1 mol kg-1), and (3) mixtures of Al2(SO4)3-H2SO4-H2O, MgSO4-H2SO4-H2O, and NiSO4-H2SO4-H2O solutions have been measured at temperatures from 100 to 280°C. The obtained experimental data and their thermodynamic analysis demonstrated that the electrochemical system can be used for on-line pH monitoring of high concentration aqueous solutions with an accuracy of ±0.1-0.3 pH units over a wide range of temperatures. Greater deviation exists in real laterite leach solution measurements due to in situ precipitation of Na-alunite. The system is excellent for research and process development work. Further work is needed to ensure robust operation under pressure leach conditions of laterites.

Jan 1, 2004

By Q. Zhang

The necessary capability of the gravity transportation pipeline system for cemented coal gangue backfilling at the Suncun Coal Mine, China, is about 74.4 m3?h-1 according to mining production and working times in the mine. It is estimated that the working velocity and maximum pipe length-backfill depth ratio of the backfill system are 3.82m?s-1 and 5.4, respectively and that the probable backfill capability of the system is 110.18m3?h-1. Results of hydraulic calculations for the backfill transportation system show that the designed backfill system is reliable in flowability and sufficient for backfill capability needs.

May 1, 2007

By R. J. Enkin

Modern mineral exploration depends on multidisciplinary 3-dimensional integration of geological and geophysical data. Identification of the geological sources of geophysical anomalies requires knowledge of the physical properties fingerprint of rock types, formations and their alteration products. Understanding how and why rock physical properties vary within the Earth&apos;s subsurface ensures that appropriate geophysical exploration methods can be chosen, and allows for more efficient and effective surveys to be designed. Physical properties knowledge is integral to geophysical modeling - measured data or values estimated based on geological understanding are used to produce realistic forward calculations and to constrain inversion models. Mira Geoscience and the Geological Survey of Canada, in collaboration with industry and academia, are building a Rock Properties Database System (rpds.mirageoscience.com). It compiles the most valuable physical properties for mineral exploration (density, porosity, magnetic susceptibility and remanence, electrical resistivity and chargeability) linked with location and lithological metadata. A critical knowledge gap, addressed in this study, concerns the dependence of physical properties on alteration and mineralization processes. We report on the results of a collaborative University of British Columbia - Geoscience British Columbia project, ?Integrated Geological & Geophysical Porphyry Models: Adding Value to Geoscience BC Geophysical Data?. As part of the QUEST and QUEST-West geophysical initiatives, Geoscience BC focused detailed geophysical surveys on a suite of six known porphyry deposits: Mount Milligan, Endako, Huckleberry, Bell, Granisle, and Morrison. Physical properties for a set of 269 samples of characteristic host rocks and their altered equivalents were measured. The causes of physical properties variations were investigated through their correlations with ore and alteration mineralogy determined from thin-section observations and X-ray diffraction analyses. Physical properties of variably altered host-rocks and intrusive rocks vary significantly between different BC porphyry deposits. No specific unifying geophysical model exists that can be uniformly applied during exploration. Knowledge of local background geology and local physical properties variations is necessary as host-rocks and intrusive rock compositions vary depending on magmatic affinities, and alteration styles will vary reflecting host-rock compositions, crustal depth and influence of meteoric water. A district-scale exploration strategy requires location of intrusive bodies, which are commonly magnetic, resistive and low in density. Correlations should not be expected between density and magnetic susceptibility, because alteration may lead to magnetite destruction or to secondary magnetite development. Deposit-scale ground geophysics might image potassic alteration zones that can be magnetic in both alkalic and calcalkalic systems. Low magnetic susceptibilities, resistivities and densities might aid in locating the typically more porous phyllic and argillic zones. All geophysical data must be interpreted with background knowledge of local rock types and in light of the expected deposit model and associated magmatic and hydrothermal processes. The most effective means to building physical properties knowledge prior to geophysical investigation remains collecting rock physical properties measurements. The cost of rock properties data collection is low, relative to the overall costs of running a mineral exploration program, and can provide an important framework for design of geophysical surveys, survey method selection, geophysical modelling, and data interpretation.

Aug 1, 2013