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By M. Melashvili

"The SART Process was introduced to the gold mining industry in the late 1990s and several commercial plants were built over the following 10 to 15 years. Most of these plants have operated well and enjoyed plant performance in line with expectations based on the underlying chemistry of the process. However, two of the plants have consistently suffered from high reagent consumption and poor product quality, which has motivated a re-examination of the process fundamentals.The primary product in the SART Process is synthetic chalcocite, Cu2S, and the stoichiometric requirement for sulphide addition is therefore 0.5 moles per mole of copper in solution. It is shown here that when sulphide is added in excess of this amount (generally with the express purpose of lowering residual copper in solution) it not only fails in its intended purpose, but can have a negative impact on the settling and filtration characteristics of the copper sulphide product, as well as the final product quality. Moreover, these problems are exacerbated the higher the selected operating pH in the pH 3 to 5 range, and the longer the residence time of slurry in this pH range.Freshly precipitated copper sulphide compounds are known to be very fine and slimy, with poor settling and filtration characteristics. It is therefore important to engineer the SART Process in such a way as to encourage growth in the average particle size of the precipitate crystals. This was the rationale for recycling a portion of the thickener underflow to the primary reactor when the SART Process was developed. However, the theory of crystallization predicts that compounds of extremely low solubility, such as chalcocite (Cu2S: KSP = 10-48), are unlikely to experience growth in crystal particle size through heterogeneous nucleation and are more likely to grow through aggregation. On this basis, the SART practice of recycling a portion of thickener underflow to the primary reactor in the commercial plants is unlikely to lead to crystal growth via nucleation, and could in fact promote breakage of the aggregates that formed in the thickener. Recycling thickener underflow could therefore have the opposite of the desired outcome. The result of testwork that is reported here lends credence to this theory and questions the wisdom of recycling in the SART process."

Jan 1, 2016

By D. O. Downing

"The 1990s saw enormous changes in the Canadian coal industry and the future promises to be no less turbulent. While the markets served by Canadian coal producers have changed and buying practices continue to evolve, the coal mining, or supply side, has also changed remarkably in response and now provides the basis for an interesting industry story.The dynamic situation in coal mining has led to some surprising outcomes and seemingly contradictory developments. This paper outlines the changes that have occurred, and which are still unfolding in Canadian coal mining, firstly, in terms of mining technology and productivity, secondly, in terms of corporate divestments, acquisitions and bankruptcies, and finally, in terms of resource development. The paper also outlines some plausible futures for the industry looking ahead."

Jan 1, 2002

By R. C. A. Thurston

"The lack of notch ductility in structural steel in general, and in ship plate in particular, has been the object of widespread attention in the metallurgical world since the spectacular collapse of the ill-fated S.S. Schenectady in 1943. Numerous investigations have been carried out, many new tests have been developed, and a vast amount of useful data has been published, with the result that our knowledge is now far more advanced than it was at the time of this disaster. Interest has focused largely on the medium strength steels, and the various factors which cause a normally ductile steel to behave in a brittle manner in the presence of a notch and at relatively .low temperatures have been thoroughly studied.The literature available on high-tensile steels, however, is less extensive and the present paper is intended to supplement this information. Notch toughness tests have been carried out, at the request of the R.C.N., on a high-tensile manganese steel in the form of commercial ship plate. One of the newer tests, the tear test, and the Charpy V-notch impact test, were used to examine the characteristics of plate for the construction of an ice-breaker. About 250 plates, mainly in the thickness range from 11,4 in. to 1 % in., were tested. An an-alysis of the results obtained is presented, certain aspects of the tear test are discussed, and the correlation between the two types of test is studied. On the basis of information available from casualty ships, the plates, with few exceptions, were considered to be satisfactory."

Jan 1, 1959

By K. R. Barnard, K. D. Marte, T. V. Gamarano

"The first commercial scale application of CSIRO’s direct solvent extraction (DSX) technology has been in operation at the Boleo project in Mexico since December, 2015. In this application, DSX is a synergistic solvent extraction system consisting of the extractants LIX 63 and Versatic 10 for recovery of cobalt and zinc from a solution background of manganese, magnesium, and calcium. Key operating parameters such as metal extraction, phase disengagement and extractant stability are summarized and discussed in this paper.INTRODUCTION Commissioning of the Boleo processing plant, located on Mexico’s Baja peninsula, began with the copper circuit starting in late 2014, with first copper cathode production achieved in January, 2015. The cobalt and zinc circuits began commissioning in December, 2015 with first zinc sulphate monohydrate (ZSM) and cobalt cathode production achieved in February and April, 2016 respectively. The Boleo project flow sheet and development has been described in detail in previous publications (Dreisinger, et al. 2005; Dreisinger, Baxter, & Molnar, 2006; Dreisinger, et al. 2008; Dreisinger, et al. 2009) and is summarized schematically in Figure 1. Boleo is a mixed oxide/sulphide Cu-Co-Zn-Mn high clay deposit that is processed in a whole ore, atmospheric, oxidative and reductive, sulphuric acid/seawater leach. Copper is recovered as cathode by conventional solvent extraction and electrowinning. Cobalt and zinc are recovered, from a solution background of manganese, magnesium, and calcium, by CSIRO’s synergistic solvent extraction technology Direct Solvent Extraction (DSX). Cobalt and zinc are bulk stripped from the DSX circuit and then further purified by phosphinic acid solvent extraction to produce zinc sulphate monohydrate granules via spray dried granulation and cobalt cathode rounds via divided cell electrowinning."

Jan 1, 2017

By T. P. Riordon

"Major swings in the silver price since 1979, along with the ever constant fight to maintain ore reserves has forced United Keno Hill Mines Limited through several unique series of events in order to survive in the 80s.This paper is specifically meant to be a description of safety and productivity improvements achieved to ensure the survival of a silver mining community ill the Yukon. There are, however, other events and conditions that must be described to complete the story and this paper attempts to do that as well IntroductionUnited Keno Hill Mines Limited, a subsidiary of Falconbridge Limited, is the only silver producer in the Yukon. Operations are located in north central Yukon, in and around the small town of Elsa, latitude 62.5 °, about 275 road miles from Whitehorse. The Arctic Circle is about 185 miles due north of the town.Temperatures in 1986 ranged from a high of 28.5°C in July to a low of -37.0°C in November, however, much lower temperatures have been recorded in previous years. Due to the mountainous terrain the town of Elsa is completely in the shade from mid-November until early February, a period of about 12 weeks.The Elsa area, as is most of the north, is considered semiarid with an average precipitation level of about 15 inches. Vegetation, however, is quite abundant though slightly dwarfed at the townsite elevation of 3200 feet above sea level: Many of our operating and exploration portals as well as our open pits are above the tree line. Permafrost in the area has been recorded up to 400 feet below the surface."

Jan 1, 1988

By D. A. Riva

"The Line Creek Project is located in southeastern British Columbia, approximately 25 kilometres north of Sparwood. The design is to produce a total of2.7 million tonnes of coal annually. This is made up of1.4million tonnes of thermal coal and 1.3 million tonnes of metallurgical coal.Construction commenced in the spring of 1980 and mining operations began in July 1981. The thermal processing plant, maintenance and dry facilities, as well as extensive road and bridge construction, were completed in early 1982. A collective agreement was signed with the International Union of Operating Engineers, Local 115, in June 1981.The first unit train left Line Creek on February 18, 1982 with a load of thermal coal bound for the Ssangyong Corporation in Southern Korea. It was the start of a ten-year contract to supply 350,000 tonnes annually to fire their cement kilns. Additional contracts for 750,000 tonnes will fuel the boilers of Korea Electric Company's San Chon Po and Go-Jeong power stations. Metallurgical coal shipments are scheduled to leave the Roberts Bank port in Vancouver in April 1983.Tracking an introductory presentation given at the 1981 CIM Annual General Meeting in Calgary, this paper highlights the salient developments by which ""The Line Creek Project"" has progressed during the past year to the"" Line Creek Operation"". Line Creek has com e on stream as scheduled and will meet all contractual commitments pertaining to timing, volumes and quality for thermal coal. The first train load left the plant in mid-February, and the first boat load to Korea departed Roberts Bank in mid-April. Metallurgical coal deliveries will commence in April 1983."

Jan 1, 1982

By K. K. Panthi, P. K. Shrestha

"Displacement of rock mass around a tunnel opening varies according to the rock mass properties, insitu stress conditions and applied support in the tunnel. Such displacement is also altered by presence of bands of rock mass that differ in properties. This paper focuses on the deformation behavior of rock mass around tunnel openings at four tunnel sections in Kaligandaki headrace tunnel where extensive instrumentation was done. Based on the actually measured tunnel displacement records and actually measured support pressure; back analysis has been done to estimate rock mass properties and insitu stresses. Numerical analysis has been done to analyze and assess the deformation behavior of the rock mass around the tunnel sections.INTRODUCTION Instrumentation and monitoring of tunnel convergences have significant importance in evaluation of tunnel stability. One of the key aspects of monitored data is that early convergences can be used in estimation of long term convergence. In addition, these data can also be used in evaluation of rock mass parameters and in-situ stresses around the tunnel. Convergence around a tunnel periphery may vary according to rock mass quality. Presence of bands of different rock mass may hinder the displacement pattern in the tunnel. Particularly, displacement characteristic of tunnel periphery in schistose, foliated and deformed rock mass is altered by presence of bands of comparatively stronger rock mass, e.g., quartz veins or presence of shear seams or faults. Similar observations were also recorded in monitored tunnel sections in Kaligandaki headrace tunnel, located in the Nepal Himalayas. Extensive monitoring was done by installing multiple point borehole extensometers (MPBX) at three different locations of the tunnel periphery at four different tunnel sections. In addition, convergence measurements by tape extensometers and installation of pressure cells to record support pressures were also carried out at each of the tunnel sections. Observations showed that the tunnel convergences varied according to rock mass quality, in-situ stress and effective support pressure.Rock mass parameters and stresses have significant role in the extent of tunnel deformation, but these parameters are often unknown or difficult to predict. Back analysis based on actual tunnel displacement records and known support pressure is believed to be an important method in such endeavor. This paper performs back analysis to evaluate rock mass parameters and discusses correlation of rock mass behavior with tunnel deformation and applied support. For this purpose, the rock mass parameters are estimated from actual tunnel displacement records, mapped rock mass quality records and laboratory tested data. Then, numerical modelling is conducted to correlate post peak behavior of the rock mass with actual tunnel displacement."

Jan 1, 2015

By E. A. Rychkun

"For the last 700years of recorded economic history, man has been subjected to alternating inflationary and deflationary patterns. Through this period of time, a severe deflationary pattern has developed approximately every 55 years, creating 12recordable occurrences. Through the last two centuries, this severe deflationary phenomenon has come to be known as a depression. As these depressions have repeated themselves regularly, they are cyclic. This in turn leads to the question of whether the 13th cycle will also repeat itself in the form of a depression. As this cycle is now 51 years old, we must consider the possibility at about 1984.In analyzing a 700-year record of consumer prices in Southern England, the 55-year cycle appears to vary in shape and intensity. This varying phenomenon is due to the effect of longer cycles upon which each one ""rides "". Because each cycle effectively rides on the next largest, which in turn rides on the next largest and so on, the combined measured effect of all cycles together at any point in time is always unique. This means that anyone cycle can never repeat itself in an exact identical manner. The combined effect therefore is what we observe in the form of prices and, as cycles interact, variations in deflation are produced . The ""science"" of economics attempts to quantify and develop theory on situations which are never identical and hence can be conservatively classified as a useless predictive tool.This means that more unconventional approaches may be required to predict our economic future. In looking at previous depression cycles, it is possible to recognize similarities in human behaviour patterns and hence the resulting economic movements. These behaviour patterns create major events or influencing factors which set the scene for a major deflationary condition. The way in which these factors occur, however, is not predictable. As more and more of these similar events are identified in each cycle, we can increase our confidence on the probability of the last event occurring (a depression). By also unravelling the set of larger cycles, we can determine the potential combined effect at any point in the future.This paper presents a system of cycles ranging from 800 years to 3 years which appear to operate in our economic system. By so doing, a long-term projection into the next century can be made. Finally, the paper deals with the main controlling similarities within the depression cycle, to show that a comparison with our current cycle implies that a major deflationary collapse in the mid 1980's is virtualy inevitable."

Jan 1, 1980

By Richard Cyr, Peter Larsen, William Quesnel

"The need to continually improve efficiency and lower costs in mining operations is of paramount importance to all concerned in the industry. Mining operations are constantly testing new methods and equipment in order to lower costs and improve productivity. Equipment suppliers strive to fulfill the demands of the mines through improved design and innovative ideas for productivity increases. In some cases, however, an increase in productivity does not require new equipment design, but rather the application of an existing mining method into different operating parameters. Such is the case in applying longhole methods to narrow vein ore deposits.Bulk mining methods have long been recognized as efficient, low-cost alternatives in narrow vein operations. Typically, shrinkage and some cut-and-fill methods are employed. The shortfall of these methods is the tendency to be labour intensive. The demand for miners skilled in these methods far outweighs their availability. Consequently, labour-efficient methods have to be employed to fill the void. The application of longhole drilling techniques to narrow vein deposits is one such method.IntroductionPercussion longhole drilling evolved in Canada in the early 1940s. Prior to percussion drilling, blast holes were drilled using diamond drill equipment. Jack Gardner, of Gardner Steel, began testing with carbide percussion bits and extension drill steel in applications where diamond drills had been previously employed. Percussion drilling equipment proved to be considerably more productive and cost-efficient. The experiment eventually led to the replacement of diamond drills in this application.Over the years, the percussion methods were improved, with particular emphasis on the equipment used. Rifle bar rotation machines evolved to independent rotation. Bar and arm set ups evolved into self-contained mobile drill carriers that increased productivity while reducing the physical labour. The introduction of hydraulics further improved efficiency and production figures. Today, it is not uncommon to see fully computerized jumbos in production longhole drilling applications. These machines represent the ""state-of-the-art"" in longhole drilling equipment.Production longhole drilling is considered to be one of the most efficient bulk mining methods in use today. Production statistics normally exhibit low-cost, efficient ore extraction. As a rule, longhole (blasthole) methods are associated with substantial ore deposits. These methods have exhibited high production figures and low mining costs.Over the past decade, long hole methods have been applied to several narrow vein deposits. These applications have proven that, given the right parameters, longhole methods will produce the same advantages in narrow vein deposits as are seen in more conventional applications."

Jan 1, 1990

By C. Pawlik, R. T. Jones

Cobalt occurs together with copper in the southern African copper belt, and a large portion of this cobalt ends up in copper smelting slags, mostly dissolved in oxide form. It is possible to achieve high recoveries of cobalt by reductive smelting of the copper slags, using some form of carbon as a reducing agent in an electric furnace. For example, a 40 MW DC arc furnace was operated at Chambishi Metals in Zambia from 2001 to 2008, and demonstrated cobalt recoveries of around 80% from slag to an iron-rich alloy containing copper and cobalt. The alloy was atomized prior to leaching. With the recent increase in demand for cobalt (and the resulting high metal prices), there has been increasing interest in this process route. There is also an alternative hydrometallurgical process for recovering the valuable metals from the slag. The choice between these process options requires a trade-off between capital and operating cost and environmental acceptability. This paper examines the potential for cobalt recovery from slags, and outlines various process options. INTRODUCTION Cobalt has had a number of important uses in society since antiquity, and its principal use has changed dramatically over time. Since at least 2250 BC, cobalt-based pigments (cobalt blue) have been widely used to colour manufactured goods such as glass and pottery. Later, cobalt became known for its magnetic and wear-resistant properties and high-strength alloys, and most of the cobalt produced was consumed in the production of cobalt-based superalloys. The greatest recent growth in cobalt demand is due to it being essential to the rechargeable lithium-ion batteries used in consumer electronic devices and increasingly to drive electric vehicles. Cobalt is usually produced as a by-product of copper or nickel. The copper belt in the Democratic Republic of the Congo (DRC) and Zambia supplies most of the world's cobalt production. In 2018, the DRC was expected to produce 90 000 tons of the world total of 140 000 tons of cobalt (Shedd, 2019). This paper focuses on the southern African copper industry, and specifically the cobalt that is able to be produced as a co-product from this. A BRIEF HISTORY OF SOUTHERN AFRICAN COPPER SMELTING Copper deposits in South Africa have been documented since at least 1685, when the Cape governor, Simon van der Stel, ‘discovered’ the 'Copper Mountain' at Springbok. South Africa's first public commercial mining company (imaginatively called the 'South African Mining Company') was established in Cape Town in 1846, to exploit the rich copper resources that were believed to exist in Namaqualand.

Jan 1, 2019

By J. J. Taute, O. S. Tinkler, G. Zárate, K. C. Sole, J. Steeples

Global practice in copper solvent extraction is reviewed, based on individual plant operating data for 2018. The survey respondents account for almost 40% of global copper cathode production by solvent extraction and electrowinning. Regional trends in operating conditions, as related to the prevailing ore mineralogy, leaching processes, and life of mine are evaluated. The adoption and expansion of this technology in the African Copperbelt and Asia are assessed, together with the associated challenges of specific orebody characteristics. Trends in feed and electrolyte compositions and flow rates, and extractant and diluent selection, together with their impact on copper recovery are reviewed. The evolution of equipment design and associated ancillary processes are discussed, and new projects identified. INTRODUCTION Continuing from similar surveys carried out in 1997, 1999, 2003, 2007, and 2013 (Robinson, Davenport, & Jenkins, 1997; Jenkins, Davenport, Kennedy, & Robinson, 1999; Robinson, Sandoval, & Cook, 2003; Robinson, Moats, Davenport, Karcas, Demetrio, & Domic, 2007; Sole, Zarate, Steeples, Tinkler, & Robinson, 2013), global operating practice in copper solvent extraction (SX) in 2018 is reviewed. Contributing operations include established sites in the USA (8), Chile (9), Peru (2), Spain (1), Mexico (2), and Australia (2), as well as newer operations in Africa (7) and Asia (3). This survey represents 2018 copper cathode production of 1.91 Mt, or about 43% of world production by solvent extraction combined with electrowinning (SX–EW). Trends in operating conditions and performance, as well as equipment design and process technology choices are analysed. The significant expansion in production in the African Copper Belt is also discussed. There are currently about 130 operations worldwide producing some 4.6 Mt copper by SX–EW; of these, about half produced more than 10 000 t/a. Figure 1 shows global copper production by country. As it has for several decades, Chile remains dominant, with 36% of global production of cathode copper. Since 2005, the Democratic Republic of Congo (DRC) has increased production year on year, and now represents 23% of the global total (International Copper Study Group, 2017; Statistica, 2018). Copper production in Asia has grown significantly in the past decade, particularly since the ramp-up of Wanbao in Myanmar. There used to be numerous small copper SX plants in China (Schlesinger, King, Sole, & Davenport, 2011), although most of these have now shut down and Chinese production is lower than it was five years ago. The most important trend, however, is the rise of Chinese-owned mining companies, particularly in Central Africa, but also around the world more generally.

Jan 1, 2019

By Gabriel Zarate

"Los Bronces had two ROM dump leach operations designated Leach I and Leach II. Leach I was commissioned in 1998 and stopped in 2014 due to the mine requirements. Leach II plant, commissioned in early 2002, was built to treat around 700 million tons of marginal ROM ore averaging 0.45 % total copper. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides.The original electrowinning plant design capacity for copper production was nominal 19,500 tonnes per year at a current density of 276 A/m2 and a current efficiency of 92%. Presently, Los Bronces San Francisco plant typically operates at current densities between 390 and 440 A/m2, much higher than the average in the industry, with current efficiencies around 93% and a maximum copper cathodes production of 37,200 tonnes per year.In order to accomplish these achievements, a number of modifications in the process conditions, in the cell hardware and in the operational procedures have been implemented. In the first case, the specific flowrate, copper concentration and temperature of the electrolyte were modified to accommodate the operational requirements facilitating the increased current density. Associated with the cell hardware, a six cells expansion was added, upgraded equipotential inner cell busbars were installed and the cross section of the cathode hanger bars was enlarged for increased current carrying capacity. Documented operational procedures like short circuit detection and cathode weight control were improved.The modifications implemented and the results obtained are discussed in this paper.INTRODUCTIONLos Bronces Division of Anglo American Chile is located up in the Andes Mountains, northeast of Santiago. It had two cathode plants, Los Bronces at an altitude of 3500 meters above sea level (m.a.s.l.) commissioned in 1998 and closed in 2014 and San Francisco at an altitude of 2800 m.a.s.l. and in operation since 2002.The process is leaching run off mine (ROM) low grade copper sulphide ore in dumps. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides. The average grade is 0.45% total copper (Cut).At Los Bronces dump, Leach I plant, the pregnant leach solution (PLS) was collected and stored in an underground reservoir. From there, it was fed to a solvent extraction plant with a series-parallel configuration in two extraction stages and one stripping stage. The electrolyte produced was fed to the electrowinning plant having 30 cells and 60 cathodes per cell. Maximum capacity of this plant was 12,000 tonnes per year (tpy)."

Jan 1, 2016

By G. Castillo, G. Thies, C. Bissue

"Newmont’s Phoenix mine began gold production in 2006 and has since experienced difficulties in reaching design throughput due to variability in ore hardness. In 2010, a debottlenecking study was conducted, generating multiple options to increase throughput of the existing Phoenix Mill through a series of phased expansions. An option was selected in early 2011 to increase the current concentrator capacity by approximately 25% through two phases. The first phase of the project was the installation of a secondary crushing and screening circuit in order to reduce SAG feed size from a P80 of 6 inches to 2 inches. The second phase focuses on downstream unit operations in the concentrator aiming to relieve existing bottlenecks such as flotation. This paper analyzes the design, commissioning, and operation of a recently installed SAG Pre-crush circuit (Phase 1). The design discussion will focus on concept development, flowsheet design, design criteria, process models, design limitations, and control philosophy. Discussion on the integration of operating data and flowsheet into design during engineering will be presented. Actual operating data of major equipment is gathered from the commissioning and operation of the circuit and compared to the initial design models. Conclusions will be drawn on equipment design factors used during engineering, and the success of model integration into operation. The paper concludes on the successes of the project and where improvements can be made during design.INTRODUCTIONThe Phoenix mine is located within 25 miles of the town of Battle Mountain, Nevada. The mill processes copper, silver, and gold ore. Production started in 2006 and has since struggled to reach the designed tonnage of 33,600 stpd due to the variability in ore hardness. In production year 2010-2011, the Phoenix mill average daily throughput of 33,000 stpd. In 2008, a larger primary crusher (FLS 60/89 gyratory crusher) was installed to operate in parallel with the originally supplied primary crusher (Metso 50/65 gyratory crusher), in order to provide additional capacity upfront in the circuit so that the primary crushing circuit could keep up with the mill.In 2010, a mill debottlenecking study was completed to assess the various options that could be implemented to increase the current mill capacity. The study was completed in late 2010 and contained four tonnages that Phoenix could achieve through various expansion scenarios. A single option was selected in early 2011 to increase the mill capacity from 33,000 stpd to 48,000 stpd. The selected option looked at a four phased expansion that would increase the capacity of the Phoenix mill and address the mill’s current bottlenecks:"

Jan 1, 2013

By G. S. Hume

In the transformation of carbonaceous materials, such as peat, to coals of various grades, the changes are known to be both physical and chemical and the grade of coal finally produced depends on the stage to which alteration proceeded. Those changes, which are frequently spoken of as the results of metamorphism, are due to pressure with accompanying heat and, according to the amount of metamorphism to which the sediments with the included carbonaceous beds have been subjected, there is a gradation from peat to anthracite coal, and even to graphite. The improvement in the quality of the coal as a result of metamorphism is due to an increase of the carbon content of the coal and a corresponding loss of the volatile materials. This rise in the quality of the coal according to the degree of metamorphism is well illustrated by the coals of western Canada. In the Plains area, where the deformation and the attendant metamorphism of the sediments is comparatively small, the coals are lignites, whereas in the mountains, where deformation has been severe, the coals are semi-anthracites. Sub-bituminous and bituminous coals occur in the intervening areas. The same general relationship between the quality of the coal and the degree of metamorphism holds true for the Appalachian basin of the United States, where there is a progressive improvement in the quality of the coals from west to east, that is, from an area of comparatively slight metamorphism to an area of marked deformation in the Appalachian Mountain region. But while it is true that this relationship holds in a general way, it has been found that the improvement in the quality of the coal is not always uniformly progressive, and there may be local variations such that an area containing coal with a carbon content indicating low or medium metamorphism may be surrounded by areas in which the coals are of higher grade. These local variations in many cases can be explained, and they in no way detract from the general rule that, in a region exhibiting a progressive betterment in the quality of the coal from an area of low metamorphism to one of more marked deformation, the quality of the coal, i.e., the amount of fixed carbon in the coal, may be taken as an index of the degree of metamorphism of the coal as well as of the sediments in which it occurs, It has been pointed out (') that certain coals, such as cannels, are unreliable indicators of the varying degree of metamorphism because of the nature of the material from which such coal was derived. Such coals, however, are not known in western Canada and their behaviour need not here be discussed.

Jan 1, 1927

By Antonio Laguna

During the past few years, synthetic efforts have been addressed to the synthesis of polymeric materials with optical or semiconducting properties or even with capabilities to act as sensors for volatile organic compounds (1). The most recent studies have been concerned with the synthesis of heterometallic systems with short metal-metal interactions and the determination of their optical properties. These complexes are undoubtly interesting from a theoretical viewpoint and include an emerging class of luminescent materials, in which the observed luminescence results mainly from the interactions among the different metal centers, as well as the environments of these atoms. The understanding of the photophysics and photochemistry of these products could permit the design of complexes with appropriate metals and ligands chosen for individual applications. Following a synthetic strategy consisting on reactions between acid heterometal complexes and basic gold precursors we have succeded in synthesizing supramolecular assemblies formed via acid-base stacking, which display tunable luminescence or selective and reversible sensitivity to Vapour Organic Compounds (VOC?s) (2-5). In this sense, in accord with previous Mössbauer studies carried out in the gold precursor complex [AuR2]- (R = C6F5), the basic properties of this and related materials have been employed as building blocks of supramolecular assemblies in their reactions with complexes in wich the metallic centers act as lewis acids as, for instance, Tl(I) or Ag(I) (6). For instance, in the case of silver, by reacting equimolecular quantities of [NBu4][Au(C6F5)2] with AgClO4, in acetone, a solid of stoichiometry [Au2Ag2(C6F5)4(OCMe2)2]n is obtained. The polymeric nature of this material in solid state is confirmed through X-ray analyses (figure 1). It consists of polymeric chains formed by repetition of Au2Ag2 moieties linked through short gold-gold interactions. Nevertheless, in solution, the nature of this polymeric materials was still a matter of controversy and, in this case, the optical properties have been shown as useful tools in order to obtain information. Thus, while dilute acetone solutions of this complex give a emission coming from pentafluorphenyl localized ??* excited states, in accord with the presence of isolated tetranuclear Au2Ag2 units, when the measurements are done at different and higher concentrations, a band that does not obey the Lambert-Beer law appears. This deviation is consistent with molecular aggregation in solution of these units through gold-gold interactions, and a clear correlation between the emssion wavelength and the structure in the solid state and in solution is shown (figure 2). DFT calculations accord with the observed experimental behaviour and show the nature of the orbitals involved in each transition.

Oct 1, 2003

By A. Mukherjee, C. Kelly, B. Markovich, G. E. Agar, G. E. Robertson, F. Khan, B. Shea

"Laboratory batch flotation tests were performed on a sample of bulk slow cooled converter matte (Cu:Ni = I) to optimize the time in each of the separation stages. Numerical simulations were carried out to estimate a continuous circuit material balance for the conditions selected. An experimental simulation of a continuous circuit (locked cycle test) readily came to steady state and there was reasonable agreement between the numerical and experimental results. The use of nitrogen as the flotation gas and the addition of collector to the grinding mill minimized the oxidation of chalcocite, which has previously resulted in increasing circulating loads, and led to a stable circuit with very low weights in the recycle streams.IntroductionINCO Limited developed a flotation process for separating the components of copper-nickel matte [Sproule, Harcourt and Rose 1945; Sproule, Harcourt and Renzoni 1960] in 1945 to replace the Orford process and continues to use the flotation process in almost the original mode to this day. Initially the matte processed was the result of smelting a nickel concentrate that analyzed about 12% nickel and 2% copper and all of the recycle material that was generated in the smelting process. The matte generated analyzed about 25% copper and 53% nickel, roughly 2: 1 nickel to copper. This matte was blown in Pierce-Smith converters to be sulfur deficient in order to produce a metallic phase that collected the precious metals contained in the smelter feed [Wilson and Stratton-Crawley 1991]. This process continued with little change until 1994 when the separation of chalcopyrite from pentlandite in the Copper Cliff mill was discontinued after 63 years of operation. As a consequence of the elimination of the primary separation of chalcopyrite from pentlandite in the milling process a bulk concentrate was produced for smelting. Bulk concentrate smelting came into practice in 1994 as part of the initiative to meet government legislation that restricted the emission of sulfur dioxide to the atmosphere. Previously, the copper concentrate was smelted in an INCO oxygen flash furnace which resulted in the capture of a high strength sulfur dioxide stream from which liquid sulfur dioxide was produced. Nickel concentrate was smelted in reverberatory furnaces that produced low strength sulfur dioxide gases which were difficult to treat. The action taken by INCO to meet the environmental constraints was to smelt a bulk concentrate in oxygen flash furnaces which would produce gases suitable for the production of liquid sulfur dioxide and another stream that was high enough in sulfur dioxide to be readily converted to sulfuric acid [Bell et al 1990]. The end result of this decision was that all the copper-nickel separation would be done in the matte separation plant."

Jan 1, 1996

By R M. Ennis, J. C. Botham

This paper is one of a series pre-pared to study the role of fuels and reductants in metallurgical processes, especially from the viewpoint of Canadian requirements. The object of these studies is to provide a reason-ably authoritative interpretation on the interrelation of fuels in light of the considerable changes that have taken place in the Canadian energy field during the past few years. Previous papers in this group have dealt with the problem generally, and specifically in terms of the development of the iron and steel industry of Western Canada. These latter papers, presented at the Symposium on Iron and Steel in Western Canada held in Edmonton, Alberta, on September 8-9, 1959, surveyed the ferrous processes of interest for use in Wes tern Canada, especially with regard to solid fuel requirements. At that time it was evident that there was a need for a similar study of the fuels aspect of the non-ferrous metals industry.

Jan 1, 1961

By P. Talonen

Since the last Iron Control in Hydrometallurgy Symposium in Montreal in 1996, the Kokkola zinc plant has increased its capacity from 175,000 t/y to 280,000 t/y by installing an atmospheric concentrate leaching process, which has also affected iron control in the leaching circuit. Major changes have been made at the jarosite residue pond; a subterranean plastic wall reinforced with bentonite and cement has been built around the pond. A new water collecting system that is used for groundwater level control in the pond area was installed. With these two investments in the pond area, it is now possible to prevent any seepage flow from the pond into the surrounding environment. Water pumped from the residue pond is treated in the water treatment plant. This paper describes the behavior of iron in Kokkola's current leaching processes. The treatment of the jarosite, the improvements to the residue pond and the water treatment process are also described.

Jan 1, 2006

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By H. A. Steane

THIS PAPER describes the re-grind section in the 2,000-ton per day, lead-zinc flotation mill of Canadian Exploration Limited, near Salmo, B.C. There are two re-grind units in operation, one in the lead circuit, and one in the zinc circuit. In each unit, the rougher concentrate is re-ground ahead of the cleaning circuit. These re-grind units have made valuable improvements in the concentrate grade, and with no loss in recovery by over-grinding galena or sphalerite. Since the initial installation of this re-grind section, the plant throughput has been increased gradually from 1,600 tons to 2,000 tons per twenty-four hours, and, as shown by the screen analysis of mill tailing, a coarser overall grind has been accepted, from 55 per cent to 45 per ?cent minus 200 mesh. There has been no increase in grinding capacity, but two mills have been taken from the main grinding circuit and used for the re-grind circuit.

Jan 1, 1958