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By Richard Hurteau

Design and validation of an integrated guidance system for articulated ground vehicles is investigated. The development of an autonomous industrial vehicle must take into the account the specific geometry of these vehicles; they can be composed of a tractor with 1 or 2 trailers or of articulated type like LHD. Moreover the tractor-trailers type vehicles can have on-axle hitch configuration or positive/negative off axle configuration. The path-tracking of a tractor-trailer vehicle in restricted space is presented and discussed in this paper. Recent results obtained in simulation and validated by experimentation are also presented. These studies can lead to better ways of maneuvering an articulated vehicle in a restricted space or automatically executing of docking and parking maneuvers

May 1, 2002

By EJ. Reichhardf

The Molopo Farms Complex is a major, layered ultramafic/mafic, early Proterowic intrusion which is totally covered by sediments of the Karoo and Kalahari Fonnations and situated in southern Botswana and northeastern South Africa. The approximately 3000 m thick, generally fine- to medium-grained ultramafic and mafic cumulates are intrusive into equivalents of Thmsvaal Supergroup sediments and lavas. Multiphase defonnation resulted in tilting and segmentation of the Complex into individual tectonic blocks. Sr isotopes document at least two chemically distinct parental liquids which interacted in a complex manner to form an approximately 1000 m thick rhythmically layered succession which straddles the ultramafic/mafic boundary. Repeated mixing resulted in a complex cryptic layering pattern and numerous sulfide-enriched layers which contain significant PGE+Au concentrations.

Jan 1, 1994

By A. E. M. Warner, A. Vahed, P. J. Mackey

In the decade 2002 to 2012 some 6.7 million tonnes of new copper concentrate production capacity was brought on line, corresponding to 2 million tonnes of contained copper. This increase in concentrate supply necessitated the commissioning of a number of new copper smelters as well as the modernization and/or expansion of existing plants to meet the demand. This paper gives an overview of the copper extractive industry, reviews recent copper production trends and changes in the copper industry, including an examination of pyrometallurgical and hydrometallurgical technology developments. WorleyParsons has supported a number of the projects involved in these developments and this role is briefly discussed. The paper introduces a number of ideas related to possible future directions of the copper industry.

Jan 1, 2014

By Erin N. Legault-Seguin

The Lac des Iles Mine (LDI) is located approximately 100 km northwest of Thunder Bay, ON. The mine has been in operation since 1993. The initial mine production was 2,300 mtpd and increased to 15,000 mtpd following a mine expansion project that was completed in 2001. Effective Oct. 29, 2008, LDI was shut-down under care and maintenance due to low metal prices. Prior to shutting down, LDI was the only primary PGM deposit in operation in Canada and of the few found globally. The complex geology and physical properties of the deposit causes several challenges for the concentrator. This paper will discuss the solutions to the main challenges of attaining nameplate tonnage and achieve satisfactory Pd recovery and concentrate grades.

May 1, 2009

By G. Stafford Whitby

N ATURAL gas is found in several provinces of Canada, particularly Ontario, New Brunswick, and Alberta. The largest producer is Alberta, and there the most important field is the Turner Valley, where some low-gravity crude oil and naphtha are associated with the gas. Last year there was produced from the Turner Valley field an average of 3,462 barrels, or about 450 tons, of oil a day. The gas flow from the wells in this field bears such a high ratio to the oil which comes from them that, despite the enforcement of a measure of conservation, it amounted to the vast quantity of 6,000 tons a day, or more than 2,000,000 tons a year. Prior to the application of any conservation measures, the gas flow was at one time of the order of 12,000 tons a day. The heat content of one ton of the gas is almost equal to that of two tons of coal. A certain amount, say, 10 per cent," of the gas is used in Calgary and surrounding towns and in re-pressuring the Bow Island gas field, but the greater part of it goes to waste. What are the possibilities of making use of this waste gas, in whole or part? The possibilities of using it profitably as fuel for domestic and industrial purposes have undoubtedly been carefully considered by the Company which now distributes a part of the gas to cities and towns in Alberta. But the relative sparness of the population and the cost of pipe lines makes such possibilities strictly limited. There are, however, distinct possibilities of making use of at !east a part of the gas for the production of a variety of chemical products and of liquid motor fuel. The present paper is devoted to outlining some of these possibilities. About three-quarters (by weight) of the Turner Valley waste gas consists of methane, the lightest and, chemically speaking, the simplest of hydrocarbon gases. The remaining quarter consists of heavier hydrocarbon gases-ethane, propane, and butane. Formerly, naphtha was separated from the well gas by a simple process of self-refrigeration. The gas coming from the wells at a pressure of, say, 1,200 to 1,800 lb., was passed through simple cylindrical vessels fitted with baffles and known as 'separators'. The pressure was allowed to drop to, say, 300 lb. in the separators, and the cooling effect secured by this expansion brought about separation of the naphtha. The naphtha thus obtained was 'wild', that is, it had a high vapour pressure owing to the presence in it of dissolved and liquefied gas. In order to reduce the vapour pressure to a level at which the naphtha could be shipped, this gas was removed either by distilling it out through a 'stabilizing' column or, according to the practice at many wells, merely by allowing the naphtha to 'weather' in open tanks (heated by coils if necessary) until the gas had been driven off in to the air.

Jan 1, 1936

By Z. Q. Liu, J. M. Du

"On the basis of analyzing current design and applications, the structure form, working loads and design principles of shaft sinking headframe are summarized in this paper. To overcome the insufficient bearing capacity and geometry size of the finalized shaft sinking headframe in China, a series of new large shaft sinking headframe were developed under vertical shaft construction conditions of maximum net diameter of 12.0 m and maximum depth of 1200 m. The new series shaft sinking headframe include two sets (with single sheave platform and double sheave platform), three dimensions (optimum shaft diameter <8.0 m, 8.0-10.0 m, and 10.0-12.0 m, respectively) for each set, and has innovation and optimization on structure of the sheave wheel platform (MU type) and bracing frame (REN and ZHONG type). The largest new shaft sinking headframe can arrange up to 4 hoisting equipment simultaneously and has bearing capacity more than 10000 kN. Two of the new shaft sinking headframe were successfully applied in practical engineering, such as the Hulusu auxiliary shaft, the Dahaize 1# auxiliary shaftand Sishanling auxiliary shaft. These applications showed that the new shaft sinking headframe has sufficient bearing capacity and reliable applicability. The new shaft sinking headframe could provide an effective guarantee for safety and efficiency sinking of deep-large shaft in the future.INTRODUCTIONShaft sinking headframe is one of the basic shaft sinking structures and it is mainly for hanging hoisting containers and sinking facilities in sinking a vertical shaft (Yu & Shi, 1991; Wang, Jing, & Liu, 2007). Currently, 7 types of steel pipe sinking headframe are used in China, which are mainly finalized by the Ministry of Coal Industry of China (Wang, 1988). As shown in Table 1, V-type is the largest of them and it is only suitable for sinking shaft of diameter less than 8 m and depth less than 1 000 m(Yang, 1982). However, with the increase of mining depth and scale of mineral resources in China, the diameter and depth of newly built vertical shaft are increasing continuously (Xie, Zhou, Xue, Wang, Zhang, & Gao, 2012; Qi & Pu, 2013). At present, the maximum net diameter of vertical shaft is close to 12 m, and the maximum depth is more than 1600 m (Yang & Chen, 2015; Xu, Yang, Liu, & Qin, 2015). The shaft sinking headframe has become the main restrictive factor for the development of sinking equipment, such as the height of muck discharging platform cannot meet the usage requirement of hydraulic umbrella driller, the size of sheave wheel platform is difficult to arrange the increasing hoisting and suspension equipment, the bearing capacity is insufficient to meet the needs of multiple hoisting loads in sinking a deep-large shaft, etc. Therefore, development of new shaft sinking headframe for deep-large shaft (>1000 m in depth and 8~12 m in diameter) is urgently required for China and also the whole world."

Jan 1, 2019

By James D. Bliss, David M. Sutphin

"On the basis of differences derived from genetic, descriptive, and grade-tonnage data, graphite deposits are classified here into three deposit types: disseminated flake, amorphous (microcrystalline), or graphite veins. Descriptive models have been constructed for each of these deposit types, and grade-tonnage models are constructed for disseminated flake and amorphous deposit types. Grade and tonnage data are used also to construct grade-tonnage models that assist in predicting the size and grade of undiscovered graphite deposits. The median tonnage and carbon grade of disseminated flake deposits are 240 000 tonnes and 9% carbon and for amorphous deposits, 130 000 tonnes and 40% carbon. The differences in grade between disseminated flake and amorphous deposit types are statistically significant, whereas the differences in amount of contained carbon are not .IntroductionIndustrial minerals, including mineral construction materials such as sand, gravel, and crushed stone, have historically exceeded metals in global production value. Today, industrial minerals are being used in new and sophisticated ways in response to the late 1980s emerging information- and service-based economies&apos; requirements for less metal and more industrial minerals . Natural graphite is an example of one such mine ral that has been known since ancient times, and is now finding new applications. Graphite was first used as an industrial mineral in Bavaria in 1400 A.D. where it was an important component of crucibles. Traditionally, natural graphite has been used in heavy industries. New applications, such as development of carbon-magnesite bricks a decade ago and the current advancement of alumina/graphite refractories, are increasing its graphite use. Other new uses for natural graphite, such as the use of graphite powder as a thermal blanket for the continuous casting o f steel (Northern Miner, 1987) and the addition of expanded graphite to polyurethane foam where it acts as a flame retardant (Industrial Minerals, 1987), are increasing the demand for this mineral. To meet future demand for graphite and other industrial minerals, knowledge of the characteristics of the deposit types in which they are found is important. A further look at the deposit types for graphite and at construction of descriptive and grade-tonnage models is warranted .The graphite industry recognizes three basic types of graphite , distinguished primarily on the basis of grain size: crystalline flake, lump and chip, and amorphous. These naturally occurring forms of graphite are products of metamorphism and are found in schists of various types, gneisses, and marbles. Temperatures of at [east 400°C are thought to be required for graphite formation (Landis, 1971). Synthetic graphite, also known as artificial or manufactured graphite, is a man-made carbon product and offers higher purity and lower crystallinity than natural graphite. Several authors have written about graphite&apos;s unique physical and chemical properties and the uses for individual types of graphite (Krauss et 01., 1988; Graffin, 1983; and Harben and Bate s, 1984)."

Jan 1, 1990

By G. Chung, W. Petruk, D. Doyle

"A series of tests was conducted on Carol Lake iron ore, which contains about 38 wt % hematite and 19 wt % magnetite, to establish a flowsheet for high weight yield by spirals. A pilot plant was run in parallel with the IOC concentrator to simultaneously test two flowsheets on the same feed material. The IOC concentrator processes the ore by treating it directly in a spiral circuit, whereas the pilot plant used a laconite flowsheet which had a low intensity magnetic separator (LIMS) at the front of the circuit. The LIMS produced a non-magnetic (hematite-rich) product and a magnetic (magnetite-rich) product prior to treating the ore in two separate spiral circuits. The results from about 150 tests were evaluated by chemical assays and materials balancing techniques, and a selected test was evaluated by the image analysis and materials balancing technique.The image analysis and materials balancing evaluation showed that a higher hematite recovery was obtained by the hematite spiral circuit than by the IOC concentrator spiral circuit, and a slightly lower magnetite recovery by the magnetite spiral circuit than by the IOC concentrator spiral circuit. Furthermore the hematite recovery by hematite spirals was higher than the magnetite recovery by magnetite spirals. The better hematite recovery was achieved because a higher liberation is obtained for hematite than for magnetite, and the hematite in the Carol Lake ore has a narrower grain size range than magnetite. Consequently, better spiral control can be maintained when processing a hematite-rich spiral feed, than when processing a magnetite-rich spiral feed. Since the feed to the IOC concentrator spiral is a mixture of hematite and magnetite, an intermediate hematite recovery is obtained by the IOC concentrator. INTRODUCTIONA study of characteristics that affect recoveries of hematite and magnetite from the Carol Lake ores of the Iron Ore Company of Canada (IOC), was carried out in connection with a project on designing a flowsheet for maximum weight yields. A pilot plant using a taconite flowsheet was run in parallel with the existing IOC concentrator which uses a classical iron ore flowsheet. About 150 tests were run to compare iron recoveries and weight yields by the spirals in the two flowsheets. Better iron recoveries were indicated for the taconite flowsheet, but the results were not consistent and the reasons for the observed differences were not apparent. The material from one test (Test 61), which gave better iron recoveries for the taconite flowsheet, was evaluated by the image analysis and materials balancing technique. A suite of samples was taken from 5 points in the IOC concentrator and from 8 points in a pilot plant (taconite flowsheet). The samples were analyzed to compare the behaviours of the Carol Lake hematite and magnetite in the spirals of the two flowsheets. The results provided a sound basis for further tests in designing a high weight yield flow sheet."

Jan 1, 1993

By T. Fliß

The protection of natural resources is of essential importance in times of rapidly increasing populations and resulting shortage of agricultural land. Soil and groundwater resources play a central role for the production of food or feed of any kind. The intensive agricultural and environmentally friendly use of these resources must ensure sufficient income and sustainability of life for future generations. Mining projects often represent a particularly deep intervention into ecosystems due to their size as well as the most expensive treatment processes. Conventional mines comprising of shafts and developed mining fields require the stockpiling of waste rock and in particular to potash mining, the discharge of brines from raw salt processing. In contrast, mining operations based on the solution mining method can be operated without major environmental impacts and lower security risks. While the solution mining for the production of rock salt finds application since more than 500 years, exist a procedure to produce potash using solution mining only since the 1980&apos;s. For solution mining drill holes are used to exploit the potash, launched from the surface into the deposit. The exploitation of the raw material occurs by the dissolution of the potash injecting solvents and creating so-called brine caverns. Currently, a number of mining projects in Carnallite deposits by the solution mining method are in progress around the world. Often these projects are located in sensitive ecosystems. K-UTEC project and support actual a solution mining operation of a Carnallite deposit for a Chinese customer in South-East Asia. This work comprises a comprehensive geological and geomechanical modeling as well as stability analyses. Furthermore the cavern design and brine field layout as well as the planning of the brine processing and the plant design. The present paper introduces this project as a case study. The application of a special solution mining procedure and processing design ensures an emission-free mining operation (Zero Disposal Plant). The emission-free operation is achieved by utilizing the full extent of the caverns to dispose the liquid solutions from processing. The presentation of principal salt processing and technical equipment will be rounded by information about the geology of the deposit. Since the deposit includes a number of sensitive minerals, such as Tachyhydrite and Bischofite the presentation comprise a lot of interesting items with special view at the brine field operation. K-UTEC designed and delivered a special blanket measuring system and a well cement according the request of the customer. K-UTEC, a research and engineering company with more than 60 years of experience in the sector of potash and rock salt mining, developed the world&apos;s first solution mining operation for Carnallite in Germany more than 30 years ago. In recent times K-UTEC served in different solution mining projects worldwide, with special view at the environmental impact, as well as the optimal utilization of the deposits.

Aug 1, 2013

By Mauricio Olivares

About Largest combined Phosphate and Potash company in the world Corporate headquarters in Plymouth, Minnesota Publicly traded on NYSE under MOS

Aug 1, 2013

By T. C. Murphy, W. Taciuk

In 1966, the Iron Ore Company of Canada commissioned a wet magnetic scavanging plant for the recovery of fine magnetite values p.resent in spiral tailings discharged from a spiral gravity separation process. The plant includes dewatering, grinding, classification, thickening, mini-wedge screening, and primary, secondary and tertiary wet magnetic separation stages. The source of feed varies in quantity and quality, so the original design included variable operational procedures to deal with these conditions.

Jan 1, 1972

By G. A. Moruzi

Two sulphide dust secondacy explosions have occurred in the mines of the SUdbury operations of Falconbridge Ltd. during the past 18 months. 'Ihe main similarity between the occurrences is that they both happened in vertical crater retreat blasthole stopes. A relatively high p:,v.tier factor was noted in both instances. other details are enumerated and examined, as well as some results of tests done by Noranda Research on company ore samples.

May 11, 1988

By D. G. Minnes

Talc has been mined at Madoc since 1896, the oldest mine in continuous operation in Canada. Canada Talc Industries Limited operates the Henderson and Conley deposits by underground methods. A newly discovered East zone is being de veloped by open pit. The raw Henderson talc is a foliated talc schist of high purity and whiteness; Conley talc is a white talcose dolomite. Products are used primarily as fillers in paints, plastics and rubber.

Jan 1, 1984

By D. J. Kemp

The 20th century saw changes in the mining and metallurgical industry not only technically but also in social and environmental expectations. As projects continue to become larger their visibility raises concerns among many groups. For mining companies, transparency, openness, and early engagement of all parties are fundamental to assure success. An equally important task is to anticipate the standards that will be required to meet society’s expectations in the 21st century.

Jan 1, 2005

By Peter D. Cunningham

At Vale Inco in Sudbury, underground mobile equipment production and maintenance data is presently collected manually from paper slips. This paper reviews a pilot project that developed a system to electronically collect that data. The benefits and improvements in data accuracy, timeliness and reduction in collection effort, will be discussed. Technological issues that arose from the use of WiFi, RFID (Radio Frequency Identification) and the IREDES mine data equipment standard are also discussed.

Oct 1, 2009

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

"For the Kazchrome DC Ferrochrome plant, SMS-group specifically designed an electrode column that would minimize downtime. Special features include the possibility for on load electrode jointing, on load slipping, and back-slipping. Electrode consumption is strongly related to furnace load and impedance, and is very low at high loads, which makes the graphite electrode an alternative to consider even in AC applications. The electrode could also be applied in other DC applications, as for example TiO2 slag, the novel Conroast process, or (twin) DC FeNi furnaces, and could possibly be installed during bigger shut downs. This paper will describe some of the design considerations and operational performance data on this novel column in the FeCr industry that could also be of interest for the FeNi or PGM industry if these would continue to develop towards DC technology.INTRODUCTION Every DC furnace has a cathode and an anode. The anode applied is commonly known as the Concast design, though the original design was by ABB who handed it over to Concast, subsidiary of the SMS-group. Some well-known DC furnaces outside the steel industry where the Concast bottom has been installed are listed in Table 1 as well as a few other key design features.Sidewall cooling and some other data have been left out for reasons of space, and being a lesser relevant design feature to this paper. HES stands for Hollow Electrode System, in which feed is charged through an electrode. Table 1 is built up chronologically according to first start-up date. Below comments are given to briefly explain some of the columns in Table 1: •,“Arm” in the “Cathode” column means that the design of the cathode holding and regulating mechanism consists of an electrode arm as depicted in Figure 1. •,Charging is relevant as some operations started with HES charging, whereas recently most new operations have started without HES but only charging chutes, of which at least some are close to the electrode and possibly others installed closer to the sidewall. •,“Dome” in the “Roof” column means that the design of the roof involves a center piece that can be exchanged if worn. •,The optimal roof design still seems to be a topic of debate, where no design is without problems."

Jan 1, 2017

By M. A. Roche

The property of the Hudson Bay Mining & Smelting Company, Limited is located at Flin Flon lake, 85 miles northwest of The Pas, Manitoba, on the Manitoba-Saskatchewan boundary. The area is at latitude North 54°, and is approximately 1,000 feet above sea level. The ore-body occurs in amygdaloidal greenstones, which are to be referred to the earliest basic volcanic flows in the district. It was discovered in an outcrop on a point of land jutting into Flin Flon lake, and subsequent diamond drilling proved that it extends under the lake both to the north and south of the point of discovery. After the taking of soundings from the ice during the winter months, it was estimated that l,000,000 tons of overburden, mainly mud and clay, would have to be removed to expose the underlying ore. Flat diamond-drill holes indicated that the ore-body was separated into more or less independent lenses by horses of unmineralized greenstone, and that in places the overall width, including horses of waste, reached 450 feet. These several] conditions were the main factors influencing the management in their decision to adopt an open-cut method for the mining of the upper portion of the ore-body. Before it was possible to commence stripping operations, it was necessary to dam-off the eastern portion of Flin Flon lake, instal pumps, and de-water the dammed-off area. Dams for this purpose were constructed of mine waste rock and clay filler from nearby hillsides. Material for the bottoms of the dams was taken across Flin Flon lake in hopper-bottom barges. Trestles were then built on the dam bottoms and dams were complete by the time trackage was available. De-watering commenced in April, 1930, and was completed by the latter part of May of the same year. Estimated pump output for the period was roughly four billion gallons. Two Morris 10-inch dredging pumps were used, direct-connected to 250 h.p. electric motors. Individual pump capacity was rated at 3,000 g.p.m. against a 150-foot head. Average head for the operation was 50 feet, which increased the total output considerably. The pumps were mounted on floating barges in cribbings of piling driven at the lowest points in the lake bottom.

Jan 1, 1933

By J. R. Dinn

On the afternoon of Saturday, June 23rd last; there was an unusual occurrence at the surface plant of the Dominion Coal Company&apos;s Caledorria mine, Glace Bay, which operates on the Phalen seam, here lying at a depth of 170 feet from the surface. On that day, the writer, who was attending a business conference in the General Office about a mile distant from the Colliery, received a telephone call to the effect that there was a strong odour of gasoline or kerosene in the wash-house and lamp-house of the Colliery, and that the attendants in both the wash-house and the lamp-house had become ill and had had to be sent home. Instructions were given at once to cut off the electric current, and to close all doors to prevent access to the building. When the writer arrived at the plant and questioned the workmen, he was led to the belief that the gasoline tank in the lamp-house (used in connection with flame safety lamps) had leaked and that the gas, having volatilized, had displaced sufficient oxygen to cause the trouble. Emphasis was being placed on the kerosene, or, as some said, the gasoline, odour. In the lamp-house, there is a small shuttered window which opens on a corridor. Here the workmen receive their lamps from the lamp attendant. An examiner, with a flame safety-lamp, proceeded to test the atmosphere within the building by passing his lamp through the open window, since, if the trouble was due to volatilized gasoline, a gas cap would be shown on the flame of the safety-lamp. After holding the lamp for a few seconds inside of the window, he withdrew it and remarked, "There&apos;s no gas cap" . Almost immediately the lamp fell from his hand and he dropped unconscious to the floor of the corridor. The writer, who was standing beside him, felt no ill effects and removed him at once from the corridor. Steps were immediately taken to revive him ( artificial respiration) , and in about ten minutes he became conscious and was breathing naturally. In making the examination, his head was not inside the window, but in line with the frame of it. It was apparent that some gas more deadly than the hydrocarbons from gasoline was present.

Jan 1, 1934

By Michel Aubertin

Mining activities can produce large volumes of waste rock, which are typically deposited in piles on the soil surface, above the water table. Such piles can cover areas of several tens of hectares and can reach over a hundred meters in height. For hard rock mines, the waste rock grain size can vary from silty particles to metre-scale blocks. The internal structure of a pile constructed on a relatively flat surface typically includes two main zones. The first zone corresponds to the heart of the pile, and is formed by several sub-horizontal stratifications (with dense and loose layers) due to the heavy mine equipment traffic which induces local compaction and degradation of the waste rock. The second zone corresponds to regions where waste rocks are deposited by push-dumping or end-dumping close to the external flank of the pile, inducing grain size segregation along the slope. Depending on the deposition sequence, grain size distribution and bench height, a gradation may then be observed, with coarser particles (with cobbles and blocks) near the base and finer particles near the crest, together with inclined stratifications due to the advance of the deposition face. These internal features affect the distribution and flow of water (and air) in the pile. To assess the internal distribution of material properties within the pile, a combination of several tools is usually required which can provide information on the hydrogeological and geochemical characteristics of the waste rock. In this regard, geophysical tools are very interesting because they can lead to a threedimensional mapping of property variations. The information gathered from a combination of appropriately selected techniques can be used to construct numerical models to further study unsaturated water flow and reactive transport. Such simulations help better understand the pile response in its actual and future states, which in turn provides input to adjust the deposition sequence, to plan for closure, and to select an in situ groundwater monitoring strategy. The presentation will give an overview of techniques that have been developed to characterise material properties in the laboratory and in the field, and to obtain a general picture of a pile?s internal structure. Additional results on unsaturated reactive transport modelling will also be shown to illustrate how the internal pile structure may influence its hydro-geochemical and environmental response.

Nov 1, 2008

By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988