Search Documents

By Hua-Zhong Yu

Gold is one of the most widely used substrate materials for self-assembly. Self-assembled monolayers (SAMs) prepared from alkanethiols and their derivatives on gold are the most reliable and well-studied systems to date, which have attracted much attention because of interest in two-dimensional molecular assemblies, and of their potential applications in molecular devices, sensors, and functionalized interfaces. Gold electrodes are also very important in microelectronics and electroanalytical chemistry. This work reports the characterization of a new type of gold substrates for self-assembly. The gold substrates are constructed from recordable compact disks (R-CDs) with simple and straightforward wet-chemical treatment, and can be made at desired sizes and shapes that satisfy different experimental needs. In particular, an easy, inexpensive, and reproducible method to prepare self-assembled monolayers (SAMs) on CD-R gold substrates after removing the protective polymer films with concentrated nitric acid was described.

Oct 1, 2003

By K. Meyer, M. E. Goddfellow

"At Teck-Corona Operating Corporation's David Bell Mine, a water quality management strategy is employed to produce both a chemically and biologically clean effluent prior to discharge to the environment.The strategy includes operating methods to minimize contaminants leaving the concentrator and an effluent treatment plant for cyanide, antimony, and heavy metal removal of concentrator, mine and site waste streams.Concentrator practices, the effluent treatment plant, process chemistry and the present day performance of the water quality management strategy are reviewed.INTRODUCTIONThe David Bell Mine is located in the Hernia gold camp 35 km east of Marathon, Ontario. The concentrator has a design throughput of 1,000 tonnes per day. ROM ore (-6"") is ground in a semi-autogenous mill followed by a ball mill, thickener, leaching, and carbon-in-pulp gold recovery unit operations. The concentrator flow sheet is shown in Figure 1."

Jan 1, 1991

By A. Singh

Two alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho have been processed by direct extrusion at 300°C and 200/230°C to produce various microstructures containing icosahedral quasicrystalline phase with different grain sizes. The alloys were mechanically tested in tension and compression. The mechanical properties were related to the grain size and microstructures studied by transmission electron microscopy. The extruded alloys showed a mixture of nano-sized icosahedral and monoclinic Mg4Zn7 phase, as well as icosahedral phase particles a few hundred nanometers in size distributed in the matrix. Coarse icosahedral phase particles several micron in size also remained after extrusion. The alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho extruded at the same temperature of 300°C produced very different grain sizes of 15 and 3 µm, respectively. The alloy Mg96.9Zn2.7Ho0.4 extruded at 200°C and Mg93Zn6Ho extruded at 230°C produced grain sizes of 0.7 µm and 1.5 µm, respectively. Both the alloys showed yield stresses of about 300 MPa in both tension and compression with elongations of about 18%. Hall-Petch parameters are calculated for the alloys.

Jan 1, 2006

By K. D. Peaslee

Slag splashing is an important development that has dramatically improved BOF vessel campaign life and reduced operating costs. This paper highlights research from physical modeling work using a 1/8-scale room temperature model BOF and slag characterization studies from several plants in North America and China. In the model studies, gas flow rate during blow and viscosity of the liquid were found to be two of the most important factors to changing the overall rate of liquid splashed onto the vessel sidewalls. When the flow rate was increased or viscosity decreased, the lower regions of the walls were splashed at a much greater rate. It was also shown that by changing the lance height, more liquid was deposited in the upper regions of the vessel at the expense of lower regions. Reducing the number of nozzles was found to be the most effective method of selectively coating a particular vertical section of the wall. Studies of BOF's using slag splashing in North America and China showed a difference in the melting characteristics of the final slag. Generally, slag splashing is successful when the melting point of the slag is 220-270°C below the tap temperature to maintain a balance between fluidity and refractoriness.

Jan 1, 2004

By A. S. H. Kabir

Due to the high specific strength and excellent corrosion resistance, Ti-6A1-4V has been widely applied in aerospace industries. In this study, the welding performance of 3.2-mm and 5.1-mm thick Ti¬6A1-4V sheets was studied using a 4 kW continuous wave Nd: YAG laser. It is found that the use of filler wire, matching the parent metal composition, can bridge the joint gap and produce full penetrated welds up to a width of 0.6 mm without cracking. The laser welds were characterized in terms of the bead geometry, defects, microstructures, and hardness. With increasing joint gap, the percent porosity area increased, reaching just over 1% of the fusion zone area at a gap width of 0.6 mm for the 3.2 mm and 5.1 mm thick sheets. The maximum underfill depth in the Ti-6A1-4V laser welds was about 5% or 7% of the sheet thickness for the 3.2-mm and 5.2-mm thick materials, respectively, meeting the AWS D17-1 specification. The microindentation hardness was maximum in the fusion zone and sharply decreased through the heat affected zone until reaching the base metal value.

Jan 1, 2011

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

By M. S. Badollet

"IntroductionASBESTOS FLOATS may be defined briefly as blends of air-borne particles of fibrous asbestos and dusts produced during the milling stages and collected by Cottrell precipitators, dust sheds, or bag-houses.The various grades of asbestos floats on the market contain fibrous asbestos particles ranging in length from microscopic to approximately 1/4-inch. The fines or dusts present in the floats are from 40 microns to 2 microns or less in cross-section.Airborne asbestos particles are of diverse length because they are collected at numerous places in the mill. There are: (1) dusts removed from dry rock storage bins, (2) dusts removed from rock and fiber screens, (3) particles from the tops of collectors, and (4) fines removed by suction from the processing equipment. Sometimes the airborne particles are kept segregated, so that there is a partial separation by gravity. This is accomplished by a series of dust chambers enclosed in a long, rectangular building. The longest and heaviest particles fall nearest to the air flow entrance, the smallest at a point farthest away and nearest the exit. Sometimes the air from the dust chamber building is passed through a series of bag-houses or electric :precipitators ,to collect the extremely fine particles which normally escape to the atmosphere."

Jan 1, 1952

By C. Holmes, T. Holmes

Engineered-in material handling problems are responsible for significant unrealized value in mineral processing plants. At the root, is a lack of awareness and understanding of bulk material handling science and how important it is, especially in early design stages. Mineral processes add value to mined raw feedstock through physical and chemical transformations in unit operations, but only if the material can flow through them. Essentially, each unit operation receives a unique feedstock and produces a unique product to be collected, transported, and fed into the next unit operation. Such material-handling systems can only be expected to achieve design throughput if the system equipment is designed to the materials’ characteristics, over their full range of conditions. This requires quantification of flow properties to support the necessary customized equipment designs. Too often, assumptions or “library values” of a material’s properties are used as the basis for flow modelling and conceptual, and sometimes even detailed, design. This is especially true for hazardous materials like uranium ore, for which the additional precautions, costs, and time necessary for safe handling are often used to rationalize postponing or even bypassing testing. The surprises that often transpire in the wake of insufficient material handling consideration can have acute and costly effects. Fortunately, there is a better way.

Jan 1, 2020

By A. del Campo A.

The roast segregation process, which was patented in 1974, makes use of a set of chemical reactions that are different from the traditional sequential oxidation of iron and copper sulfides used by all modem pyrometallurgical processes to treat copper concentrates. It allows metallic copper to be obtained via sublimation of copper chloride at temperatures in the range of 700-800 OC. In addition it avoids melting the concentrate, doesn't require transferring molten materials, doesn't need flux addition and allows nearly all of the sulphur to be removed in one stage as a high-S02 gas stream. Most importantly, it allows a decrease in the use of energy to approximately 6 million BTU/ton of anodes. This represents a saving of approximately 40%, compared to the potential of the most advanced processes presently used. Such a promising process has been waiting for its first industrial application for more than 30 years. This article examines the technical difficulties that have delayed application of the roast segregation process to beneficiate copper concentrates. Special emphasis is made on material handling aspects, discussing the possibility of using a well designed mass flow silo as the main processing vessel to carry out the segregation stage. Cu2007

Jan 1, 2007

By F. Richards

"The property of the Cariboo Gold Quartz Mining Company; Limited; is in the Wells-Barkerville district of Cariboo mining division. It consists of a group of 106 Crown granted mineral claims and fractions; and extends for over 6 miles along what is termed the Barkerville gold belt. The main portal and mine camp are half a mile south of Wells; which lies at the northeast end of Jack of Clubs lake and is reached by a 55-mile motor road from Quesnel; the northern terminus of the Pacific Great Eastern railway.Gold-bearing quartz veins were discovered on the surface in various parts of the property by different prospectors as far back as 1877, but the work that led to the formation of the present company was performed by Al Sanders in the year 1926. Sanders dug trenches and drove small adits on quartz veins containing gold above what is now known as the Sanders zone. Very little underground work has been done beneath the earliest known discovery-the B.C. vein. The Cariboo Gold Quartz Mining Company was formed in the autumn of 1926. The total production of gold from its beginning in 1933 to the end of 1944 has been as follows:"

Jan 1, 1954

By J. H. Brown

"THE need for continuing education has been recognized only in fairly recent years as a major concern of the engineering profession. Formerly, it was acknowledged that engineers were required, at least informally, to follow the professional literature and to give some attention to new technical and technological developments. However, those relaxed days, when progress could be followed in a casual or incidental evening of reading, have disappeared in these days of mushrooming information. The engineer is now in the position of the man trying to control the flow from a fire hydrant with a child's pail. Our problem is that of developing an effective flow system -be it trough, hose, pipe or a bigger pail.The first step in achieving an effective means for continuing the education process is to realize that the need for the system is really an outgrowth of an increasingly sophisticated society. It is merely one more symptom of that society; others would• include the facts that new engineering graduates are more highly trained than those of several years ago, that graduate schools are now the norm and that even some fairly recent technologies are becoming outdated. There-fore, let us examine the education-al systems from which the bulk of the increasing sophistication has grown."

Jan 1, 1966

By E. L. Warburton

Before entering into a discussion of wet washing, it will be advisable to consider the various phases and conditions sur- rounding the problem of cleaning coal from the Corbin mines. Corbin is located in the south-east part of British Columbia in the Crowsnest Pass district, about 35 miles north of the International boundary and about three miles west of the Flat-head Range of the Rocky Mountains. It is reached by a rail-way, about thirteen miles long, from McGillivray, B.C., a point on the Crowsnest branch of the Canadian Pacific rail-way, owned and operated by the Eastern British Columbia Railway Company, a subsidiary company of Corbin Coals, Limited. The coal is assumed to occur here, as principally elsewhere in the Rockies, in the Kootenai series of the Lower Cretaceous, but owing to the disturbed condition of the surrounding country and, therefore, the magnitude of the geological study involved, this has never been definitely worked out. The coal is of the usual Crowsnest high-grade steam-coal, containing from 9 to 12 per cent. of ash, but appears to have 4 to 5 per cent. less volatile combustible matter than other coals being mined in this district, a representative analysis being about as follows:

Jan 1, 1924

By Premil Agarwal, Alok R. Patnaik, Pulak Dhar, Prakash C. Patnaik

In this study, a physics based model has been presented, considering the growth of the thermally grown oxide (TGO) layer on the bond coating of a thermal barrier coating. Using diffusion equations, a model has been developed to physically describe the oxidation process. The mathematical equations representing the diffusion formulations have been solved numerically. The computed results show the depletion of Al in the bond coating as it diffuses both towards the super-alloy substrate and towards the TGO produced in between the bond coating and the ceramic TBC top layer.

Jan 1, 2004

By J. H. Bernard, K. Zak

Abstract- The three traditional types of Variscan vein Pb-Zn-(Ag) mineralization recognized in the Bohemian massif from historic paragenetic studies are confirmed by modern metallogenic studies. Stable C, S, and 0 isotope data, as well as Pb and Sr isotopic ratios of the deposits, indicate a predominantly crustal origin of the constituents in all three types. Although the data also suggest differences in temperature and pressure of formation, and the oxidation conditions and nature of the hydrothermal fluids, nonetheless they are consistent with prevailing metallogenic classifications of the vein mineralization.

Jan 1, 1992

By L. Contretras

This study has as an objective to analyze and to propose actions to improve the quantity and quality of the graduate education in the area of mining industry, specifically of mining engineers, metallurgists, geologists, to satisfy the expectations of professionals in the mining industry. Included are an analysis of the present scenario and the future demands in countries like Chile and proposed plans for the Establishment of Educational Initiatives, country policies and market forecast, vis-a-vis the experience of Australia, South Africa, United Kingdom, Canada and the United States of America.

Jan 1, 2007

By J. H. Bernard, K. Žák

The three traditional types of Variscan vein Pb-Zn-(Ag) mineralization recognized in the Bohemian massif from historic paragenetic studies are confinned by modem metallogenic studies. Stable C, S, and O isotope data, as well as Pb and Sr isotopic ratios of the deposits, indicate a predominantly crustal origin of the constituents in all three types. Although the data also suggest differences in temperature and pressure of formation, and the oxidation conditions and nature of the hydrothermal fluids, nonetheless they are consistent with prevailing metallogenic classifications of the vein mineralization

Jan 1, 1992

The PEMAC Commitment to World Class Industry in Canada The Plant Engineering and Maintenance Association of Canada PEMAC is a national, not-for-profit industry and technical association for plant and facility maintenance, engineering and physical asset management practitioners and professionals. Founded mid 80?s in the last century PEMAC is a knowledge based organization that focuses on sharing knowledge with our members and the profession. We provide education and professional development programs and certification for maintenance practitioners and professionals. We develop, produce and participate in conferences, seminars and trade shows.

May 1, 2008

By H. Vermette, J. Demers, R. Leclerc, P. Bergeron, P. Hudon, A. Lessard

The Arvida Smelter marked its 80th anniversary in 2006. Arvida currently operates 6 potrooms equipped with prebaked side-feeding pots producing 160 000t of aluminum per year, requiring the supply of 300 000t of alumina per year. In the past, to ensure reliable alumina supplies to the pots, especially in winter, a safety stock of alumina was kept inside the plant. The improved reliability of shipping on the Saguenay River has cut the need for such a stock. However, the stoppage of 8 Soderbergtechnology potrooms, starting in the 1980s up to 2003, generated alumina from the cleaning of pot pits, totaling 18000t and leading to the building-up of a significant alumina stock again. Concerns over working conditions, effect on potroom operations, and dust emissions prevented Arvida from tackling effectively this impressive alumina stock. Yet the increasing cost of alumina has created a strong motivation to use the stored alumina. In 2004 Arvida launched a project to recycle the stored alumina. This 4-year project aimed at clearing the alumina stock without affecting the operation of the smelter. It involved changing work organization, improving equipment and controlling the effect of the recycled alumina on the smelting process and working conditions.

Jan 1, 2006

By Lanny Pasternak

"This article is directed at plant production, engineering and maintenance personnel. Seldom does any industrial operation take the time to study the costs involved in the generation of what is probably their most expensive plant utility energy source.IntroductionIn the typical industrial plant in Canada, a 200 hp, 900 cfm, air compressor costs about $60,000* per year to operate (Fig. 1). In 1989 when BC Hydro embarked on their industrial energy management program Airflow Energy Ltd. were asked to spearhead the “Efficiency Compressed Air” portion of that program with a mandate to perform onsite overview surveys and physical hands-on testing of some 300 selected industrial plants throughout British Columbia for compressor efficiencies and wasteful air leaks (Fig. 2). The program duration lasted until 1995, during which time a tremendous amount of data were amassed relating to equipment types, clients’ operating habits, end-use applications and operating costs.During the past six years, Airflow Energy also performed somewhat similar surveys but on a smaller scale in Alberta, Ontario, the United States and the Republic of China. It was no surprise to find some inherent equipment concerns related to efficiency as well as neglected energy wasteful air leaks, so British Columbia was not alone and the problems appear somewhat universal."

Jan 1, 1996

By Stephen B. Hearn

The SLon Vertical Ring and Pulsating High Gradient Magnetic Separator was developed to overcome multiple disadvantages associated with traditional horizontal type Wet High Intensity Magnetic Separators (WHIMS) which have been in service for many decades for recovering iron ore and other minerals. Proven successful, with hundreds of units now upgrading low-grade iron ores and maximizing recovery of fines throughout China, the technology is now being tested in the Western world. This paper will discuss the drawbacks of traditional WHIMS, explain the operation of the SLon, and illustrate its practical use in processing hematite ores.

May 1, 2007