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By Richard Klimpel

"Over the last 15 years, there has been a number of plant scale sulfide mineral flotation tests organized by this author specifically aimed at understanding how flotation rate varies with reagent type and dosage. With regard to the Interaction of collector dosage, particle size, and frother type, the eight specific trends listed in the paper (Illustrated with data from two specific case studies) are qualitatively the same for almost all plants studied in some depth. The Interaction of flotation rate K and equilibrium (Infinite time) recovery R in the plant has been denoted as the R/K trade-off. The effect of collector dosage on the rate of flotation of specific particle size intervals is particularly interesting and once understood, is quite useful In understanding how industrial flotation plants respond to changing reagent type and dosage. The location and magnitude of the R/K trade-off can be different for various ores and various plant configurations, but the RIK trade-off is almost always present. The purpose of this paper is to clearly describe and illustrate the nature of this very Important flotation system Interaction so that operating engineers have a starting reference point for beginning successful plant Improvement studiesIntroductionIt is well recognized by industrial froth flotation plant operators that improving existing sulfide circuit performance is often difficult due to the self-compensating systems nature of the froth flotation system, e.g. Klimpel (1988, 1989, 1995). Extensive plant testing with existing and new reagents by this author throughout the world has clearly shown that one of the more important self-compensating mechanisms is the Interaction between collector dosage, frother type, and particle size. The term self-compensation in flotation simply means that as the plant operator consistently changes one parameter in the same direction, the nature of the froth flotation system Is such that the circuit will eventually begin to resist this controlled parameter change by automatic (uncontrolled) changes In other parameters and the overall circuit performance will go through a maximum or minimum (hence causing the operator to stop the parameter change)."

Jan 1, 1997

Block caving is an underground mining method for the profitable extraction of massive, low-grade orebodies. Lately, it has become the mining method of choice, for many mining companies, because of depleted high-grade orebodies, and declining metal market prices. Block cave mining, however, still faces several challenges. Lack of access to the cave remains a major issue in understanding the rockmass response to mining for method optimisation. Improving our understanding of the rockmass response to caving will lead to safer and more productive operations. Combining large datasets from multiple sources with virtual reality scientific visualisation (VRSV) is a viable alternative to understanding complex cave behaviour without access to the cave. This is achieved using immersive environments with the ability to view complex multi-dimensional data (beyond 3D) graphically. VRSV offers a unique platform where it becomes possible to immerse the multi-disciplinary experts, and/or management team, in a virtual mine environment for quick decision making and fast resolution to conflicting conclusions. The underground mining system is complex due to multiple interrelating factors such as geology, excavation geometries, stress and time. Block caving is even more complex than most underground mining methods due to the network of tunnels required, and the use of induced stress, among others. As a consequence of the complexity in the block caving environment, it is vital that the mining system is analysed holistically, as a system, rather than optimizing individual factors one at a time. This paper presents a customised software module developed for use in the Advanced Visualisation Interactive Environment (AVIE) at The University of New South Wales (UNSW), Australia, to enable VRSV investigation into block cave mining systems (BCMS). This approach has the potential to provide a better understanding of the effect of time in in rock engineering, which has proven to be an important factor in hard rock mines (Ma & Daemen, 2006; Malan et al., 1997; Suorineni, 2010) but never validated. This work back analyses the early undercutting phase of a case study block caving operation with the view to understanding time/sequence effects. There is evidence that heterogeneous rockmass time-dependent behaviour governs the seismic response of the rockmass following undercut developments.

Jan 1, 2015

By Tim Hughes, Steve Gannon, Jennifer Abols

"In the past year, two very innovative gold ore processing plants have been designed, built and commissioned by Gekko Systems Pty Ltd. The first plant in Vietnam utilizes conventional crushing and ball milling followed by gravity concentration (Inline Pressure Jig (IPJ) and Falcon concentrator), flotation, intensive leaching (GFIL), the first industrial scale use of AuRIX®1001 ion exchange resin and a cyanide destruction circuit. The second plant, in Australia, uses a 3 stage crushing circuit to crush the gold ore to minus 1mm, followed by gravity concentration utilising a rougher, scavenger, cleaner circuit of IPJ’s and a Falcon concentrator. A direct smeltable gold concentrate is produced as well as a lower grade concentrate for future intensive leaching or sale. Both plants were designed and built within very tight time frames and budgetary constraints. The experience gained during the plants’ design, commissioning and operation are discussed.INTRODUCTIONGekko Systems (Gekko) is a leader in the development of innovative technology for gravity recovery and intensive cyanidation. It provides low cost and metallurgically optimal solutions for its customers. It has also led the trend away from whole ore cyanidation (CIP/CIL) towards gravity/intensive cyanidation (GIL) and gravity/flotation/intensive cyanidation (GFIL) plants. These types of plants offer low capital costs, low environmental impact and maximum return to investors (Rob J Longley et al, 2002). Key to this type of flowsheet is the application of a continuous concentrate unit, such as the InLine Pressure Jig (IPJ), which is designed to produce high gold gravity recoveries at a coarse grind (Sandy Gray, 2003). When combined with other gravity devices, and/or flotation, and intensive cyanidation, using the Gekko InLine Leach Reactor (ILR), very high overall recoveries can be achieved.In 2004, Gekko launched a new range of products called Gekko Modular Systems. The idea was to provide off the shelf, complete solutions for the separation and recovery of complex and free gold as well as the pre-concentration of diamonds. A series of modules were designed that incorporated Gekko manufactured as well as outsourced equipment. Gekko now offers modules ranging from feeding and conveying to crushing, gravity recovery, flotation, intensive cyanidation, refining and detox (see Figure 1)."

Jan 1, 2007

By J. C. O'Rourke

"Gibraltar Mines Ltd. has been operating its open pit copper mine for fifteen years. In that time, over 140 million tons of waste and low-grade material has been placed on the mine waste dumps. Laboratory and in situ testing indicated that enough leachable copper was recoverable from the dumps to justify a leaching operation which would include the construction of a solvent extraction-electro winning plant. The plant, which was commissioned in October 1986, was designed to process 3000 USGPM of dilute copper solution to produce 5000 tons per year of high-quality cathode copper.This paper deals with the start-up and initial year of operation of this plant. The three areas: leaching, solvent extraction, and electrowinning are presented with emphasis on the innovations which were made to help overcome the problems unique to the Gibraltar operation.The Leaching CircuitThe mine waste dumps are leached to produce a pregnant copper solution as feed to the SX-EW plant. To achieve this the dumps are sprinkled with a mildly acidic solution which percolates through the dumps. In travelling through the dumps the solution contacts the surfaces of the liberated copper minerals and dissolves the soluble copper into the form of copper sulphate. The leaching reaction is achieved by a combination of bacterial action to oxidize the sulphides and solubilization of the copper into the acid solution.For the bacterial action to occur the dumps must be near the ideal pH of 1.9 to 2.1 and the necessary elements of the reaction must be present. Because a bacterial reaction is involved there is a lag time between the time when the conditions for bacterial growth are achieved and when the bacteria are in their active growth phase. Laboratory leaching tests with Gibraltar ore indicated that bacterial action takes two to three months to reach its maximum rate (Fig. I).The expected lag time for the planned rate of bacterial leaching prompted Gibraltar to start irrigating the dumps in late June 1986 for a plant start in early fall. The lag time proved to be longer than expected and the dumps took until November to start producing copper at the expected rate (Fig. 2)."

Jan 1, 1988

By Gerhard Heinrich

"The composition and the possible utilization of a slag sample from a nickel smelter operation in the Sudbury district were investigated. The sample containing 0.136% Ni, 0.10% Co and 0.29% Cu could be characterized as a fayalit e slag with a sulphide bearing glass matrix. While the fayalite contains most of the Co, Ni is enriched within both sulphides and fayalite. Cu is only present in higher amounts in sulphides or metallic droplets. This, as well as the small grain sizes of the mineral phases, inhibits significant enrichment by mechanical methods. However preconcentration is possible by means of magnetic separation. An effective hydro metallurgical approach proved to be oxygen pressure leaching with sulphuric acid. Accordingly, the method proposed for processing the investigated slags is to combine the normal utilization as coarse construction material with pressure leaching of the fines and the ground upgraded magnetic fraction. Besides the recovery of base metals, the leaching process yields fine-grained residues, which, after addition of CaD, will set to a cement-like material, or can be used as a pozzolanic cement colour. INTRODUCTIONDuring the pyro metallurgical processing of nickel ores, the valuable metals nickel, cobalt and copper are enriched within the sulphide matte, similar to the smelting of copper ores. The resulting waste materials are slags, which may still contain valuable metal contents of up to 0.5% or above . These contents are close to the cut-off grades of some nickel-cop per-cobalt deposits. The methods that are used to recover copper from slags comprise in general further pyro metallurgical treatment, often after enrichment by flotation. Another area of application for such slags is their use as construction material. However, this might cause environmental problems if nickel containing dusts are produced.Based on one example, the characerization and a possible way of complete utilization of nickel smelter slag s as construction materials in combination with partial base metal recovery are described in this paper. The investigated slag sample was obtained from a dump site in the Sudbury district, Ontario. Detailed test series for process optimization were not possible during this study due to the limited available sample size."

Jan 1, 1989

By David J. McDougall

"IntroductionThe production of pig iron, wrought iron bars and castings in Quebec during the 18th and 19th centuries has been so closely identified by historians with the Forges du St. Maurice on the St. Maurice River a few miles north of Trois Rivières (Three Rivers), that one is sometimes left with the impression that it was the only iron works that ever operated in the province. There were however, about twelve others, one of which was so completely re-built that it should probably be considered as a separate entity. All but two were constructed after the midpoint of the 1800s, coinciding with the growing Canadian demand for ""charcoal pig"" for railway car wheels and castings for industry, and about half of them were technically, if not economically, successful. The misconception about the Forges du St. Maurice may have come about either because of its long history of somewhat less than continuous production over a century and a half, or a tendency of Quebec historians to concentrate on events in the French-Canadian rather than the English-Canadian milieu, but whatever the reason, the other Quebec iron work s have been generally ignored. All but one of the Quebec blast furnaces could be described as ""preindustrial"" with capacities ranging between three and ten tons per day, the exception being the Radnor furnace built in 1892 with a maximum production of about 35 tons per day and an alleged capacity of 50 tons per day.Until a railway network was completed in the 1880s, the location of all the Quebec iron works except the Grantham Iron works was dictated by close proximity to adequate ore reserves because horse transport was of little use beyond a ten-mile radius. The other essentials of forest resources (mainly soft woods) for charcoal, limestone for flux and water power, were generally available except within a few miles on either side of the St. Lawrence river. Among the dozen iron works established in Quebec between 1732 and 1880, seven used bog iron ore in charcoal-fired furnaces."

Jan 1, 1983

By B. K. Gorain, A. W. Stradling

"The traditional metallurgical scale-up techniques for flotation plants are based on lumped flotation rate constants, dimensionless hydrodynamic numbers and the use of safety factors. Once the plant has been designed, the flotation principles that govern scale-up play almost no role in the optimization of the circuit to meet its metallurgical targets. This deficiency can potentially lead to a plant design incapable of meeting its targets, especially when circuits incorporate large flotation cells. This paper demonstrates the application of the k = PSbRf model in providing a suitable framework for flotation modelling, scale-up and circuit optimization, thus presenting an integrated approach to the problem. Studies were conducted at Teck Cominco’s Red Dog concentrator to characterize cell hydrodynamics, gas dispersion properties, froth flow behaviour, entrainment and ore floatability to obtain the key data necessary to develop a model for the flotation circuit. The findings of these studies are presented in this paper, which provide valuable insights into the modelling and optimization of the Red Dog flotation circuit. IntroductionThe traditional methodology for flotation scale-up and plant design is based on the ruleof- thumb with safety factors and dimensionless hydrodynamic group similitude considerations. With the recent trend toward larger flotation cells with volumes of 150 m3 and greater in concentrators, the problem of scale-up has become even more acute. The scale-up factors that may have been tolerated on smaller cells are not applicable to larger cells. The transportation of froth in these large cells adds further complexity to the problem. Arbiter et al. (1980) foresaw this problem and pointed out that if scale-up were attempted by rule-ofthumb and trial-and-error, the probability of failure would then increase with scale. This problem is confounded by the fact that the design and scale-up considerations used for a new flotation circuit play almost no role in optimization of the circuit to meet its metallurgical target. This results in a plant design, which may be incapable of meeting its metallurgical targets. There have been several instances where new concentrators have required significant circuit modifications and additional capacity to achieve design targets."

Jan 1, 2003

By w. w. Milde

"Since its startup in 1975, the Rabbit Lake mill has been modified (0 process both increased tonnage and higher grade ore. Ore initially came from the Rabbit Lake pit . In 1985, a major mill expansion was commissioned to allow treatment of B-zone pit ore, which is mineralogically and metallurgically different fromRabbit Lake pit ore.Mill modifications, and the changing ore characteristics and processing targets which made them necessary, are described. Mill LocationThe mill complex, shown in Figure I, comprised of milling facilities, acid plant, power generation , warehouse and administration offices, is located approximately 1.5 Ian south of the Rabbit Lake pit, and about 8 Ian southwest of the B-zone open pit mine.Original Milling CircuitOre feed to the mill commenced June 10, 1975. The mill was designed to process 1500 tonnes per day , 483 000 tonnes per year with an average grade of O.44OJo Ups and an annual production of 2000 tonnes UPs' Run-of-mine ore was dumped directly onto a 60 em square opening grizzly. Oversize was broken with an Ingersoll-Rand hydrauli c rock breaker. Minus 60 cm ore was fed to a 6 m diameter by 1.8 m long Hardinge semi-autogenous (SAG) grate discharge mill. Mill discharge was screened over a Tyler double-deck vibrating screen, with screen oversize returned to the SAG mill feed chute via conveyor belt. Screen undersize (minus 2.4 mm) was pumped to 51 cm diameter Krebs cyclones in closed circuit with the SAG mill. Cyclone overflow (about 50% minus 74 micron) was thickened to 55% solids in a 30 m diameter neutral thickener .Thickened pulp was stored in two mechanically-agitated wood stave tanks (5.5 m diameter by 6 m high), to which sulphuric acid was added to obtain a pH range of 1.5 to 2.0. The fmalleaching was carried out in five more identical tanks. Sulphuric acid and sodium chlorate were used to maintain a pH of 1.5 and a terminal emf of -450 to -500 mV. Steam sparge was utilized to obtain a temperature of 45°C."

Jan 1, 1989

By Tim J. Carew, Dennis C. Martin

"One approach to stabilization of rock slopes is to place a buttress at the toe of the slope to provide additional resisting forces and increase the length and strength properties along the failure surface. This paper describes the rock mechanics and mine planning aspects of incorporating a buttress of intact rock in the lower part of the slope as part of the slope design for the south wall of the final pit at Cassiar Mine. Stability analysis techniques and results are described. Analyses results have indicated that, in order to maintain steep over-all slopes in the final pit, a buttress of intact rock shoud be incorporated into the lower section of the slope until late in mine life. The effect of the buttress is to flatten the slope and reduce the slope height thereby improving slope stability. The mining plans would be such that the buttress would be mined out during the last four months of mining when the consequences of instability would be least severe.IntroductionThe concept of using a buttress to stabilize slopes has been used in mining and civil engineering construction in may locations (Richards and Stimpson, 1977). Most buttresses involve placement of coarse rock fill timber cribs or other material as a load at the toe of an already unstable slope to provide forces which resist failure by counteracting driving forces and increasing the length and strength of the failure path.This paper describes the geotechnical and mine planning aspects of incorporating a buttress of intact rock in the design of the south wall of Cassiar Mine. The effect of an intact rock buttress is to flatten the slope and reduce the slope height, thereby improving slope stability. No actual construction is required other than normal excavation of the slope. The ""mine plans would be such that the buttress would be mined out at the end of mine life when the impact of instability would be less severe and additional ore might possibly be recovered from the slopes. Mining of the buttress could induce instability at the very end of mine life at a time when maximum ore extraction has been achieved."

Jan 1, 1986

By J. W. Jefferies

"Plant availability up 13%, production output up 40%, tons per employee up 15% and labor turnover down 52%. One mine manager states these were direct spin offs from the work being done to qualify for a safety award in the program known as the ""IMSRS 11 over a three-year period of time. ""Of Course"", stated this manager, ""these were in addition to an 87% reduction in our disabling injusry frequency rate.”Officially known as the International Mine Safety Rating System or the Five Star Mine Safety Rating, a new approach to mine safety is being used with enthusiasm by a significant number of mines in Canada, the U.S., Australia, Chile, Indonesia, the Philippines and South Africa. Significant results are coming into the International Loos Control Institute from over 125 mines from these countries.The program is built around a mine safety audit system that gives positive recognition to a mine at 5-step intervals along the way, (a star with each step attained). The Institute has licensed auditors in locations in Canada and the U.S. available to audit.It is believed the success of this program is the result of the premise upon which the program is based. The results being achieved are due to the concept that a modern, well-managed mine safety program maintains the basic foundation of a complete management system. When properly implemented, it reinforces those factors common to production, quality and safety. (Attitude - skill - knowledge - fitness - structure - machine - equipment - materials and processes). The IMSRS contains elements that reinforce all these factors. It uniquely treats safety as part of the ""right way"" to do the job and not just the ""safe way"" as a distinctly separate entity. Mines using this program now recognize that many of the older safety techniques were not necessarily the right way or the most efficient way to do things. It appears that this new approach to mine safety is a new avenue for the attainment of management's real goals for being in business, and at the same time achieves optimum support for the important target of safety and health for the mine worker."

Jan 1, 1983

By John Oxenford

There are currently two operators producing oil from the surface-mineable portions of Alberta?s oil sands (Syncrude Canada Ltd. and Suncor Inc.) and two other companies are proposing to enter the industry (Albian Sands in 2002 and True North in 2004). Tailings from the two current oil sands plants contain approximately 220 000 tonnes per year of recoverable TiO2 and approximately 80 000 tonnes per year of recoverable zircon. This represents approximately 6% of the world?s TiO 2 consumption and approximately 9% of the world?s zircon production. With the commissioning of plants by Albian Sands and True North, and the announced expansion of plants by Syncrude and Suncor, it is expected that these tonnages could quadruple in the next ten years. All of these operators have at least 50 years of reserves even at these expanded production rates. The occurrence of heavy minerals in Alberta?s oil sands has long been known and is well documented in the literature. There have been a number of attempts to produce market-grade products from this resource and the results of this work have been quite mixed. Typically, researchers have used the normal mineral dressing techniques of the industry and have found the mineral assemblage does not respond to these techniques all that well. This has led to the widelyheld suspicion that there must be some difficult metallurgical problems associated with this resource. There are three main problem areas that have created difficulties for previous researchers: 1) The bitumen coating on the sand grains; 2) Secondary mineralization such as pyrite, siderite and calcite 3) A high proportion of aluminosilicates (approximately 25%) that have the same gravity, electrostatic and magnetic properties as other minerals in the heavy mineral suite. Recent work by Lakefield Research shows that these problems can be largely overcome with some novel approaches. The bitumen can be removed by washing with a solvent in the presence of a demulsifier. The pyrite can be removed by flotation. And the titanium and zircon minerals can be separated by selective flotation followed by conventional electrostatic and magnetic separation.

May 1, 2001

By J. C. O'Rourke

"Gibraltar Mines Ltd. has been operating its open pit copper mine for fifteen years. In that time over 140 million tons of waste and low grade material has been placed on the mine waste dumps. Laboratory and in-situ testing indicated that enough leachable copper was recoverable from the dumps to justify a leaching operation which would include the construction of a solvent extraction-electrowinning plant. The plant, which was commissioned in October, 1984 was designed to process 3,000 usgpm of dilute copper solution to produce 5,000 tons per year of high quality cathode copper.This paper deals with the start up and initial year of operation of Gibraltar's SX-EW plant. The three areas: leaching solvent extraction and electrowinning are presented with emphasis on the innovations which were made to help overcome the problems unique to die Gibraltar operation.THE LEACHING CIRCUITThe mines waste dumps are leached to produce a pregnant copper solution as feed to the SX-EW plant. To achieve this the dumps are sprinkled with a mildly acidic solution which percolates through the dump. In travelling through the dumps the solution contacts the surfaces of the liberated copper minerals and disolves the soluble copper into the form of copper sulphate. The leaching reaction is achieved by a combination of bacterial action to oxidize the suphides and solublization of the copper into the acid solution.For the bacterial action to occur the dumps must be at or near the ideal pH of 1.9 - 2.1 and the necessary elements of the reaction must be present. Because a bacterial reaction is involved there is a lag time between the time when the conditions for bacterial growth are achieved and when the bacteria are in their active growth phase. Laboratory tests with Gibraltar ore indicated that bacterial action takes two to three months to reach its maximum rate. See figure 1.The expected lag time for the planned rate of bacterial leaching prompted Gibraltar to start irrigating the dumps in late June 1986 for a plant start up in early fall. The lag time proved to be longer than expected and the dumps took until November to start producing copper at the expected rate. See figure 2."

Jan 1, 1988

By L. J. Surges, C. Bazin, D. Hodouin

"A kinetic model was developed for the conditioning and flotation processes of an industrial lead concentrate dezincing circuit. The models were incorporated into a flowsheet simulator. Simulation results demonstrate the advantages of split conditioning of coarse and fine particles and the potential of this approach for the production of the heuristics required for the development of intelligent control strategies.The conditioning model relates the proportions of activated and hydrophobic surfaces and residual reagent concentrations to activator and collector reagent flowrates. The model accounts for the solids and water flowrates, and for the solids grade and size distribution. The flotation model uses the predicted proportion of hydrophobic mineral surface, the aeration rate and the froth depth to estimate cell, bank and circuit performances. IntroductionFlotation has been the object of modelling and simulation studies for more than two decades. The process is usually modelled as a kinetic one in which the particle flotation rate constants are key parameters. Rate constants are related to the operating variables (pH, reagent flowrates, aeration rate, etc), however these relationships are seldom established in the literature.In spite of the large amount of literature on flotation modelling and simulation, few papers deal with the interaction between flotation rate constants and operating variables. This important gap, which was identified in the early seventies by Woodburn (l970), still exists. One of the first attempts to include operating conditions in a flotation simulator was made by King (l973), who explicitly introduced the aeration rate into an air bubble loading model. Lynch et al. (1981) used an empirical model to relate the proportion of slow floating particles to the ratio of collector per ton of ore. Such empirical relationships are difficult to calibrate and cumbersome to use when an activator and a collector are added to slurries in which particle size distribution and surface characteristics are changing. Eascur and Herbst (l982) relate in a fundamental way the mineral flotation rate constants to the aeration rate, froth depth, agitation and frother concentration, however the model does not account for reagent flowrates. Niemi et al. (1982) have proposed a model for the conditioning of minerals and included it into a conventional flotation simulator."

Jan 1, 1988

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract—Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O signature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract-Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O sig- nature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By J. Ling, J. Xiao, A. R. Laplante

"The most challenging gold gravity separations occur when gangue has a high s.g., gold is fine, or a combination thereof This paper examines such separations, and evaluates the performance of a 3-in Knelson Concentrator at various rotation speeds, a 4-in SuperBowl, and a laboratory Mozley Multi-Gravity Separator (MGS). Synthetic feeds, primary cyclone underflows and flash flotation concentrates are tested.It is concluded that higher rotation speed are mostly useful for very fine (< 3 7 µm) gold recovery, with potential loss of recovery in the 37-212 µm range. This problem is traced to the collapse of the flowing film at higher Gs, which hinders the percolation of particles of intermediate size. Increasing fluidization water flow can alleviate this problem, but the recovery of very fine particle then drops. The MGS does not operate with the same principles, and can achieve good to very good recoveries of very fine to fine gold particles, but the unit has a high cost to capacity ratio, and there is no evidence yet that it can yield smeltable concentrate grade or a concentrate that can be upgraded with a shaking table.IntroductionThis presentation is a sequel to similar CMP presentations of the past eight years; all focused on practical aspects of gold recovery. The first hard rock application of the Knelson Concentrator (Laplante et al, 1990), studies of the grinding and classification behaviour of gold and other malleable metals (Banisi et al, 1991; Laplante et al, 1995), the development of a 3-in Knelson based methodology to study gold gravity circuits (Laplante and Shu, 1992), a comparison of the Knelson and Falcon (Laplante, Laplante et al, 1993), the presentation of a test to determine the amount of gravity recoverable gold, or GRG (Laplante et al, 1996), and the use of synthetic materials, in particular tungsten, to mimic gold (Laplante et al, 1995) were presented. A summary of many practical implication of the McGill research was presented in 1994 (Laplante). Whereas gold gravity recovery was less popular and largely jig-based (in North America) at the beginning of the eighties, many gold plants now incorporate a gravity circuit, and the Knelson Concentrator is the most commonly used unit."

Jan 1, 1998

By W. Díaz, R. A. Parra, L. E. Arias, C. A. Toro, M. Marin, E. Balladares, V. Parra, G. Reyes, S. N. Torres, D. Sbarbaro

This work presents visible-near infrared (VIS-NIR) spectroscopy measurements, and signal analytical techniques to characterize minerals and relevant pyrometallurgical process variables for the copper extractive industry. Data signal processing techniques such as baseline correction and numerical analysis are used to estimate the continuous and discontinuous spectral components. Such spectral components are used to estimate the process temperature, and patterns such as the integrated radiation. Also, metal combustion emissivity calculation are depicted. Our findings suggest that VIS-NIR spectroscopy may be a suitable technique to assess the process condition state, appearing as an interesting sensing alternative. INTRODUCTION Although the flash smelting process is one key stage in the copper extractive industry, representing about 40% of copper matte production worldwide (Cantallopts, 2017), few attention is dedicated to develop sensing solutions to assess process variables, such as mineralogical composition and temperature, in the feeding and bleeding stages, compared to the steel industry (Strakowski, et al., 2014). In this process and other industries, e.g. the thermoelectric power generation one, combustion and particularly the generated flame are the production chain’s heart. Since the flame is a highly radiative emitting process where chemical and physical transformations take place, many works had been dedicated to characterize the combustion state by sensing its radiation using optical and photonic technologies (Ballester & García-Armingol, 2010). In this context, this work aims to contribute with visible-near infrared (VIS-NIR) spectroscopy and pyrometry techniques to retrieve relevant information from a laboratory scale flash smelting process. On the other hand, since photonic instrumentation allow us to perform contactless measurements of emitted, absorbed, transmitted or scattered radiation, it appears as a suitable technique for sensing process properties in harsh environments, e.g. high temperature processes. One of these techniques is the Visible- Near Infrared (VIS-NIR) spectroscopy, which provides information about the spectral radiation intensity distribution, in this work, the emitted flame’s radiation. It is well known in combustion research that the spectral emission from a flame is composed by a black body continuous radiation background, molecular emissions, elemental emissions and additive noise features (Arias et al., 2011). To make sense of such information signal processing techniques are needed, here we propose to analyse the continuous and discontinuous spectral components separately.

Jan 1, 2019

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019

By Liu Yulin, Zhao Yi, Tan Qi, Liu Lei

"Hydrotalcite is one kind of layered double hydroxides, and has special crystal chemical characteristics. Due to its good thermal stability, hydrotalcite used as the PVC heat stablier has attracted scientists’ attention. In this study, nano-hydrotalcite was synthesized by the method of mechanochemistry/crystallization, using brucite, Al(OH)3 and Na2CO3 as raw materials, and added into PVC to investigate the effect of hydrotalcite on thermal stability of composites. The synthesis mechanism was suggested by virtue of XRD, FE-SEM, FT-IR. It has been indicated that at the first of dry milling process, the parical sizes of brucite and Al(OH)3 decrease, while specific surface areas of them increase by the action of mechanical force, until produced amorphous particles. In the process of wet milling, metal ions in the amorphous body, which has high surface energy, can easily react with H2O, and produce the precursor of Mg6Al2(OH)18•4.5H2O, which has the same crystal structure as hydrotalcite. Under the hydrothermal condition, anions of OH- in the interlamination of precursor are exchanged by CO32- in the solution and nano-hydrotalcite is generated at last. The thermal stability was characterized by Congo red method. The results have revealed that hydrotalcite is one kind of long-term heat stabilizer, and residual stability time increase with the rise of added hydrotalcite amounts.INTRODUCTIONHydrotalcite, one kind of anionic clays, has been attracted a great interest for researchers because of their unexpected physical and chemical properties. The general formula is Mg6Al2(OH)16CO3·4H2O, where Mg2+ and Al3+ occupy octahedral positions in the brucite-like layers, and CO32- is an interlayer anion (Hoyo, 2007). Hydrotalcite is widely used in the fields of chemical engineering, materials engineering, environmental protection, medicine, and so forth, owing to its unique capability of adsorbability, ion exchange and thermal stability (Rozov, Berner, & Taviot-Gueho, 2010; Iwasaki, Yoshii, & Nakamura, 2012; Ay, Zümreoglu-Karan, & Temel, 2011; Cavani, Trifiro, & Vaccari, 1991; Li & Duan, 2005; Lin, Wang, & Evans, 2006). As a result, the study on synthesis and application of hydrotalcite has received considerable attentions."

Jan 1, 2016

By C. B. Webber, L. S. Diaz

"The paper presents the approach taken by Craigmont Mines to grinding circuit control. A detailed description is given of a fully automatic control system which bases its control actions on the continuous measurement of particle size in the cyclone overflow stream. The control system holds a specified particle size in the cyclone overflow, and grinds rod mi 11 ore feed at increased rates. The principles of operation of the system used for continuous measurement of particle size are described, end the improvements in mill throughput and copper recovery over several months of continuous operation are presented.INTRODUCTION Craigmont Mines Limited is located in the south-western interior region of the province of British Columbia, approximately 230 road miles north-east of Vancouver, and ten miles west of the town of Merritt. A moderate climate, good roads and service facilities provided by the Canadian Pacific Railway, Inland Natural Gas Company, and the B.C. Hydro and Power Authority, have provided a very favorable mine and plant site.The preliminary metallurgical design of the Craigmont mill was based on the test results of samples obtained from the original 2500' level drift during 1959. Pilot plant runs and other research testing for design pur¬poses were conducted at the Canadian Exploration Ltd. Laboratory, at Salmo, B.C. The design flowsheet was altered in progressive stages from 2,000 to 3,000, and finally 4,000 tons per day as the ore reserves became better defined. Construction work on the 2,400' level mill site commenced in late 1960. The official opening of Craigntnt Mines Limited took place on September 15, 1961, a little over two years from the time of the metallurgical assessment of the original ore samples.Mill throughput to date has varied widely both on a daily and a monthly basis, due to the varying hardness of the mine ores. The grindability af the ore appears to be related to the oxide iron content, which varies from lows of 9% to highs of 20%. Daily tonnage has ranged from 5,000 tons per day with 10% iron in the feed, to 6,000 tons per day with 20% iron feeds."

Jan 1, 1973