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By George Hope, Dave Green, Jacques McMullen

The Est Malartic mill has been treating massive sulphide, copper/gold ore from the Bousquet 2 mine since 1989. The need to minimize copper content in flotation tails which are leached for gold recovery and to produce a saleable copper concentrate led to the evaluation of Conventional, Column and HG flotation methods. The HG method was preferred and two full-scale cells were installed and operated over a two-year span. In 1992, it was decided to expand the mill capacity from 1500 tpd to 2500 tpd. A total of nine additional HG Tank Cells were installed to provide additional roughing and cleaning capacity. The expanded plant has been operating since June 1993.

Jan 1, 1994

By J. H. Baek, D. W. Lee, B. K. Kim

Nanostructured Cu-Al203 composite powders were synthesized by thermochemical process for an electrode application. The synthesis procedures are 1) preparation of precursor powder by spray drying of solution made from copper and aluminum nitrates, 2) heat treatments to evaporate volatile components in the precursor powder and synthesis of nanostructured CuO+Al2O3, and 3) CuO reduction by hydrogen into Cu. The suggested procedures stimulated the formation of the gamma-Al2O3. The mean particle size of the final composite powders was 20nm, and the electrical conductivity and hardness in the hot-extruded bulk were competitive with Cu/Al2O3 composite by the conventional internal oxidation process.

Jan 1, 2004

By E. Kordzadeh, M. Reza Bateni, M. Karaminezhaad, A. Moeini

A series of austenitic heat resistant Fe-Ni-Cr-Al alloys with different nickel contents have been investigated at 1100 ° C and 25, 50, 50,100 hours in S/0 bearing atmospheres. Before sulphidation test, the specimens were annealed in argon at 1250 °C for 8 hrs. Weight changes were measured using an automatic thermo gravimetric analyzer and corrosion products were analyzed by scanning electro microscope (SEM), energy dispersive X-ray spectrometry (EDAX), X-ray diffraction and optical microscope. The results showed that sulphidation resistance decreased with increasing nickel content. Internal sulphidation controlled by gaseous transport through cracks and pores and the formation of internal sulphide increased when liquid sulphides formed on the surface.

Jan 1, 2004

By A. Cadieux, J. -B. Pineault, C. Allaire

The temperature measurement of the molten metal in the aluminum transformation process is of prime importance. This is particularly the case for aluminum treatment furnaces, such as holding and melting furnaces. Such reverberatory type of furnaces involve a thermal gradient across the metal line which limits the life of conventional thermocouple protective ceramic shields, due to the action of locally induced thermal stresses. This paper presents a novel thermocouple assembly using a composite refractory protective shield allowing long term resistance to such above conditions. Example of results obtained from various tests in aluminum holding furnaces are presented. The results confirm the superiority of the novel thermocouple assembly, as compared to conventional thermocouple units.

Jan 1, 2004

By Y. Turen, Y. Karakas, E. Candan, C. Sahinturk

In this study, wettability between sprayable tundish lining (MgO) and molten steel was investigated by using sessile drop method. Content of glass fiber (SiO2) in the MgO varied between 0 to 8 wt% whereas mean particle sizes of the MgO were 25, 75, 150 and 300µm. Experimental results revealed that contact angle (0) of sessile drop on the MgO was not altered by the addition of glass fiber up to 1 wt.% whereas above 2 wt.% addition decreased the 0 considerably. Contact angle, 0, increased considerably with increasing MgO particle size. SEM analysis showed deposition of glass phase was present at the interface as the finer MgO particles were used.

Jan 1, 2004

By J. Bouchard, A. Desbiens, M. Maldonado, R. del Villar

ABSTRACT: Despite many years of practical applications in mineral processing plants, the potential of column flotation has still not been fully exploited. The challenge in measuring some key variables is certainly an important contributing factor to this situation. Reliable online measurement of variables, such as the froth depth, bias, gas hold-up, frother concentration, bubble surface area flux, and bubble size distribution, provides opportunities for the application of various advanced control strategies and real-time optimization based on an economic criterion. For several years, Université Laval’sLaboratoire d’observation et d’optimisation des procédés researchers have been working on these opportunities. This paper describes the most recent advances and current research trends.

Jan 1, 2011

By Tomoya Kawasaki, Tatsuya Motomura, Yutaka Yasuda

Saganoseki Smelter, one of the largest copper producers in Japan, currently operates a single flash smelting furnace to produce 450,000 tons of new copper annually. The smelter used to employ two flash furnaces, and integrated the two into one in 1996. Since then, various improvements to its facilities and technologies have been made to increase productivity. To upgrade the operation efficiency, "stability" was considered a key issue, and the measures were taken to increase the operation and facility reliability. Currently, the furnace is running at a feed rate of 215 DMT/h, while the furnace utilization has been maintained at 97%. This paper outlines recent improvements that have made to increase furnace productivity and efficiency.

Jan 1, 2014

By K. Tsuchihashi, A. Kishimoto, T. Uda, Y. Kado, S. Maruyama

We recently proposed a continuous production process for titanium metal with some experimental results. In the process, titanium tetrachloride is reduced by Mg in the presences of Bi to form a Bi-Ti alloy at 900ºC. At this temperature, the obtained alloy is liquid and allows for the continuous removal of product and heat from the reaction vessel. The obtained Bi-Ti alloy was vacuum-distilled at 1000ºC for 24 hr, and 98 at % (92 wt %) titanium, which was easily crashed to powder, was obtained. Bi solvent was selected because of the highest titanium solubility at 900ºC and the moderate vapor pressure among the candidate metals (Bi, Sn, Pb, Zn, and Sb).

Jan 1, 2014

By Jean-Luc Collins

"The paper deals with the impact of fleet imbalance on a deterministic evaluation of shovel fleet productive capacity. It shows that if the fleet imbalance is overlooked, then estimated fleet productive capacity will be overrated.The paper shows that fleet imbalance inflates utilization, and care must be taken when using such statistics which are derived from reported field-equipment-hours. It shows that the utilization must be deflated by a factor called 'balancing efficiency"" in order to estimate shovel productive capacity correctly. The paper also shows how fleet imbalance can be controlled by managing idle time or downtime in an actual operation.The technique used for measuring the balancing efficiency factor is based on statistical analysis of equipment utilization."

Jan 1, 1980

By D. Moffat

Rio Algom Limited has mined uranium at Elliot Lake, Ontario for 20 years. The production of this energy-generating element results in the need to dispose of low-level radioactive solid wastes and liquid effluents. Because of the wet-temperate climate at Elliot Lake, the liquid effluents are of particular importance. Radium-226 is the isotope which requires most attention, and the current practice for its control is by addition of barium chloride and retention of the resultant precipitates in large settling ponds. Analyses of typical effluents and waste streams are discussed and typical levels of radium-226, thorium-230, thorium-232, thorium-228, lead-2iO, polonium-2iO, and uranium isotopes are presented.

Jan 1, 1979

By Robert White

?Introduction of BMS?Paste fill generalities?Development through paste?Development through rock fill?Conclusion ?Brunswick mine is operated by Xstrata. The mine has been in operation since 1964 and produces around 10 000 tons per day of ore containing (in order) zinc, lead and silver? The ore body consists of close to ten sub-parallel massive sulfide lenses. The length of the ore body is 1200 m with a width of up to 200 m. From the surface, the ore body extends to a depth to 1200m ?There is 100 km of active drifts for a total 400 km ?The mine is divided by 7 levels and 23 actives sub levels

Feb 1, 2008

By K. Horikawa, S. Kitahata, H. Kobayashi

"It has been clarified that the Al-5%Mg alloys containing 200 mass ppm of sodium showed grain boundary (GB) fracture, even when tested at room temperature, as well as at high temperatures (~500°C). SEM/EDX study revealed that the GB fracture was associated with the segregation of sodium on grain boundaries of the Al-Mg base alloys. Differential scanning calorimetry (DSC) revealed that the GB fracture at room temperature of Al-Mg alloys was caused by sodium segregation in the solid state. It was also shown that the tendency of the GB fracture strongly depended on the heat treatment; the alloys after the solution heat treatment showed severe GB fracture compared with the alloys after the homogenizing treatment. Moreover, it was shown that the GB fracture at room temperature by sodium segregation was suppressed by the addition of bismuth or indium. The suppression of the GB fracture by the additional elements was believed to be the scavenging effects by forming the sodium bearing compounds in grains.INTRODUCTIONIt is widely known that Al-Mg base alloys containing high amount of magnesium(~5 mass%)show better workability at room temperature, while that the alloys show grain boundary (GB) embrittlement at higher temperatures ranging from 200 to 500°C, depending on grain size(Otsuka, 1984), sodium impurity level(Ransley, 1959, Okada, 1997, Horikawa, 2001)and testing strain rate(Yamada, 2012). In the case of coarse-grained Al-5%Mg alloys (~300 ?m), 2 mass ppm of sodium causes severe GB fracture around 300°C, however, the Al-5%Mg-2ppm alloy does not show GB fracture at room temperature. It has also been shown that the GB embrittlement caused by 2ppm of sodium was suppressed by the additional elements, such as bismuth (Talbot, 1995), antimony (Ueda, 1997) and indium (Horikawa, 2012). Basedon these facts, we have concluded that the GB embrittlement at higher temperatures of Al-Mg alloys is attributed to the synergy effects of GB segregation of atomic sodium and GB sliding. For the GB embrittlement mechanism of Al-Mg alloys, involvement of low melting point metallic phases has been pointed out (Lynch, 2002),since the GB embrittlement appeared only at high temperatures. Up to date, the effects of high amount of sodium addition more than 2 ppm on GB fracture were not fully investigated in Al-Mg alloys. In the present study, the effect of 100 ppm ordered sodium impurity on GB fracture of Al-5%Mg alloys was examined, together with the effect of another additional elements."

Jan 1, 2017

By Alan A. Barton

Introduction The Little Long Lac mine is situated in the Thunder Bay mining district, township of Errington, Ontario. The mine is located on the south side of the most westerly bay of Little Long Lac. The property consists of 36 claims, which comprise some 1,400 acres. This group of claims was staked in August, 1932, by Tony Oklend and Tom Johnson, and, after surface sampling, was optioned by the present controlling interests, who diamond-drilled it during the winter of 1932-33. In early spring, a small steam-driven plant was installed, and shaft sinking commenced on June 1st, 1933. During the summer, all supplies are transported to the mine from Hardrock station, at mileage 18 on the Canadian National Railway line from Longlac to Port Arthur. At Hardrock, which is seven miles from the mine, the railway skirts a bay of Little Long Lac, and supplies are loaded directly from railway cars to scows. Two scows are used, of 30-and 45-ton capacity, respectively. A 36-ft. pointer, powered by a 35 h.p. engine, is used as a tug. A good winter-road has been cut out from Geraldton to the mine, for winter transportation. Geraldton is about two miles north of the mine, and is also located on the Canadian National railway. A hard-surface road is now being constructed for summer as well as winter use. Geology The Little Long Lac gold area covers the northern limits of a large synclinal structure, the contact of the Keewatin flows and sediments, striking about twenty degrees north of west, with the dip of the sediments varying from eighty degrees north to seventy degrees south, the average being around eighty degrees south. The vein worked by Little Long Lac Gold Mines occurs in massive sedimentary rock of about the composition of arkosic or quartzitic greywacke, and consists of a shear-zone up to fifteen feet in width, striking N.75°E. and dipping steeply to the south, which has been filled by numerous narrow, parallel quartz veins and. veinlets. These are well mineralized. with arsenopyrite, pyrite, and some chalcopyrite and stibnite, and carry considerable quantities of visible gold. They show more than one age of quartz deposition, the quartz being fractured and re-cemented. The arkosic rocks separating the veins and veinlets are also slightly mineralized with pyrite. Work to date has indicated the probability that the vein-shear is controlled by local drag-folding.

Jan 1, 1935

By Phil A. Keele

"IntroductionGeneralThe Genesee Coal Mine is a joint venture of Fording Coal Limited and the city of Edmonton. The mine supplies thermal coal to the Genesee Generating Station operated by Edmonton Power and is located approximately 75 km southwest of Edmonton (Fig. I).Under the terms of the joint venture agreement, Fording Coal Limited has designed and developed the Genesee Coal Mine. Fording also operates the mine which has a minimum economic life of thirty-five years. Mine development started in the spring of 1987 with the construction of the dragline erection pad and mine service complex. Major development of mining areas was carried out in 1988 with the construction of haul roads, powerlines, topsoil recovery, etc. Mining officially commenced on December 14,1988.The mine produces 1.6 million tonnes of coal per year and employs 65 people. MiningGround conditions have turned out to be very poor, as expected with the majority of the overburden in the first few years a soft lacustrine clay with minor amounts of fine-grained glacial till. To compound matters, what was expected to be a relatively uniform coal subcrop turned out to be a very irregular erosional contact.The coal mined at Genesee is a sub-bituminous Class B thermal coal with approximately 16070 ash, 21% moisture, 8300 Btu/lb and 0.27% sulphur on an as-mined basis.The primary piece of mining equipment used at the Genesee Coal Mine is a M8200 walking dragline. It has an effective operating radius of 100.6 m, a 50.5 m3 bucket, and weighs approximately 3860 tonnes yielding a ground pressure of III KN/m2•Figure 2 illustrates schematically the single pass mining sequence presently employed at the Genesee Coal Mine. The M8200 is used to lift all coal out of the cut, the coal being placed in stockpiles on the prepared pad .This method maximizes coal recovery under the conditions where spoil failures due to poor material would otherwise put men and equipment at risk. The coal is subsequently loaded by the coal shovel operating on the same bench as the M8200 dragline and delivered to the plant as required.All mined areas, as required under Alberta Legislation, are to be returned to an agricultural land capability equal to or better than that which existed prior to mining. Reclamation activities, as a result, are an important and integral part of the mining process. A complete list of the primary mining equipment deployed at the Genesee Operations appears in Table I."

Jan 1, 1994

By Masahiro Eguchi, Giuseppe Granata, Chiharu Tokoro, Hiroki Fukuda, Yuichiro Toba, Shungo Hobo

"Currently, large amounts of wastewater containing boron are discharged from industries like coal-fired power plants. Although coagulation-sedimentation is widely employed for their treatment, only a little consideration has been given to its mechanism. An additional problem is that the produced sludge has poor solid-liquid separation. This study is focusing on coagulation-sedimentation using magnesium, examining the mechanism and improving the solid-liquid separation. First, the co-precipitation with magnesium hydroxide was conducted against high-concentration boron wastewater with 500 mg/dm3as B. Second, in order to improve the solid-liquid separation by maintaining high reactivity, low-crystalline magnesium oxide was synthesized from magnesium carbonate by calcination at 400–700°C. It was tested as an adsorbent of boron and compared to co-precipitation with magnesium hydroxide. Co-precipitation showed high removal capacity. X-ray diffraction (XRD) of the sludge revealed the presence of other compounds besides magnesium hydroxide. This result suggests that other processes play a role other than simple adsorption on to magnesium hydroxide, and provides a plausible explanation for the observed high separability. As for the adsorption, the synthesized magnesium oxide immobilized as much or more amount of boron than co-precipitation. Furthermore, the results of fourier transform infrared spectroscopy (FT-IR) suggested the residual magnesium carbonate improved solid-liquid separability due to its poor solubility.INTRODUCTIONBoron is used in various industrial applications. In glass industry, the addition of a little amount of boron into glass products can enhance heat-resistance and chemical-resistance. Semi-conductor industry also employs boron as dopant for silicon. From these industries, large amounts of wastewater containing boron have been discharged. Additionally, coal-fired power plants have been recently discharging highly concentrated boron wastewater because the amount of boron contained in coal has been increasing due to a gradual decrease of the quality of coal. Since boron is partially proved to be toxic for animals, plants, and human beings (WHO, 1998),the guideline of the World Health Organization limit the boron concentration in drinking water to 2.4 mg/dm3(WHO, 2009).Because boron does not precipitate from solutions by simply changing the pH, the removal could be carried by operations such as adsorption or ion exchange. However, since ion exchange is an expensive operation with relatively low capacity, it is not suitable to treat the large amounts of wastewater produced by heavy industries like the coal-fired power plants. Therefore, coagulation-sedimentation method is still widely used as a suitable alternative way."

Jan 1, 2017

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By Michael McClintock, Bern Klein

"The high pressure grinding roll (HPGR) is a relatively new comminution technology that is gaining popularity for providing energy efficient solution to hard rock mining operations. A significant barrier to increased adoption of HPGRs is the present requirement for large amounts (excess of 2 tonnes) of sample for pilot testing, which may not be possible for most early stage projects. Three methodologies have been developed at NBK Institute of Mining Engineering at the University of British Columbia that may be used for sizing design optimization of HPGR circuits. All three methodologies use a MTS pistonpress to simulate HPGR comminution. These tests are capable of providing information regarding energy consumption, energy breakage relationship, reduction ratio, and product size distributions. In a period of slow economic development, these methodologies are critical to allow the industry to cost effectively understand the operational benefits of HPGR implementation. This paper examines previous test work done at UBC, as well as the development of an HPGR and piston press database for use in sizing and budgeting of HPGR circuits.INTRODUCTIONCurrently, the mining industry faces several challenges due to falling commodity prices and escalating costs. This has applied pressure for operations and projects to reduce costs and improve project economics. In addition engineering and metallurgical budgets have shrunk as companies try to conserve cash. Improvements and optimization of milling and comminution circuits is one area project economics may be significantly improved. By considering alternative comminution technologies such as the high pressure grinding roll (HPGR), energy operating costs may be greatly lowered. Many have begun to implement HPGR crushing as an alternative to semi-autogenous grinding (SAG) mills, including KGHM and, Sierra Gorda, and Freeport Mc-MoRan’s Cerro Verde operation. However, implementing new technology for companies with little or no HPGR experience may not be practical. An operator must consider both feasibility and economics of a circuit. Currently, consideration of the HPGR requires expensive pilot scale testing for which large sample sizes are needed. In addition, few laboratories are equipped for running pilot scale HPGR test programs. Furthermore, the results of pilot HPGR testing are dependent on the quality of the sample, which cannot represent variations across a deposit. In contrast, ball mills and SAG mills can be sized using the Bond Mill Work Indexes that require a small amount of sample which enable a number of different geological blocks to be tested to allow engineers to have a complete understanding of how the comminution circuit will perform for the life of mine."

Jan 1, 2016

By A. Nielsen

"The Polaris mining operation (Fig. I) is located on Little Cornwallis Island in the Canadian Arctic, an area with a very limited shipping season and a hostile climate. The operation consists of the underground works, barge-mounted concentrator facilities, concentrate storage and shipping facilities, a personnel accommodation complex and an airstrip.The electrical energy for the operation is provided by four 2.3 MW diesel-generators installed on the barge. The power is distributed through a 4.16 KV system connected directly to the generators and to the large motors. All other loads are supplied at 600 V or 120 V.The power plant has been designed as a Total Energy System with maximum energy efficiency and thus designed for maximum heat recovery. The waste heat recovered on a year 'round basis is expected to be sufficient for the process heating and drying as well as the space heating for offices and accommodations. The engine cooling system consists of two glycol-water loops, a "" cold"" loop for charge air and lube oil cooling and a ""warm"" loop for jacket water cooling. Each loop is complete with heat exchangers f or heat recovery and out-door forced air radiators to dispose of excess heat. A water loop in the concentrator area transfers the heat from the jacket water loop and the exhaust gas boiler to the space heating equipment, the process and the heating system for the accommodations. Part of the exhaust gas is diverted to the concentrate dryers.IntroductionThe Polaris Mine is a highly mechanized, trackless mine with access through a decline. Drill equipment is electrically powered to minimize fumes and heat. Dry development and production drilling eliminates the need for an underground water supply system.The concentrator, power generators, work shops and auxiliary facilities are located on a barge which is beached in a prepared berth on the shore of Crozier Strait. Oil storage tanks, concentrate storage and accommodation buildings are built on shore. The concentrate storage building ha s a 12-month capacity and is fed from the concentrator by a conveyor system.The accommodation building houses up to 240 people, includes administration office, dining and recreation facilities. The complex is housed in on e interconnected building with public use areas alternating with accommodation units.At full production annual concentrate shipments will amount to about 220,000 wet tonnes. This will be accommodated by about 8 shipments during the regular shipping period-August 15 to October 15. Re-supply of general cargo and fuel will be carried out annually in about 3 shipments within the same period."

Jan 1, 1984

By D. Stüben, G. P. Glasby

"Abstract - Shallow submarine hydrothermal fluids from Paleohori Bay off the Greek Island of Milos have been investigated in detail. The extensive gas and warm (max. 93°C) water vents are enriched in major components such as C1-, Na+, Si, Ca2+, Mn, PO4 3-, NH4 +, K+, Sr2+, H2S and CH4 and depleted in Mg2+, O2 and SO4 2- relative to ambient seawater. Based on zero-Mg calculations, it is deduced that the submarine vent fluids are related to the geothermal reservoir beneath Milos which has a similar chemical composition. Fluid samples from each vent in Paleohori Bay represent a mixture of hydrothermal end-member fluids derived from the upper and deeper geothermal reservoir systems of Milos, a mantle-derived source, a high-chloride fluid resulting from phase separation of geo thermal fluids and a steam-heated CO2-rich meteoric water. Résumé - À l’île de Milos dans la mer d’Égée, des fluides sous-marins hydrothermaux en eau profonde ont été récherchés en détail près de la baie de Paleohori. Les larges émanations de gaz et d’eau chaude (temperature maximale: 93°C) sont enrichies en constituants principaux tels que de Cl-, Na+, Si, Ca2+, Mn, PO4 3-, NH4+, K+, Si, Sr2+, H2S et CH4 et appauvries en Mg2+, O2, SO4 2- comparé à l’eau de mer environnante. Selon le calcul du zéro-Mg, nous en déduisons que les fluides sous-marins hydrothermaux sont dérivés du réservoir géothermal sous l’île de Milos car leur composition chimique est la même. Les prélèvements des fluides de chaque source hydrothermale représentent un mélange de fluides hydrothermaux dérivés des réservoirs géothermaux supérieur et inférieur, d’une source dérivée du manteau, d’un fluide très enrichi en chlorure produit par la séparation des phases et de l’eau météorique enrichie en CO2 et chauffée par la vapeur."

Jan 1, 1999

By K. Hasselwander, K. Knabel

"A significant area of Outotec’s business involves fluidized bed roasting. With several decades of experience, more than 300 reference plants and strong R&D capabilities, the company provides several industries with optimum processing solutions. Applications include oxidation and sulfation of sulfides found in copper, pyrite and zinc concentrates. Gold production and de-arsenifying roasting are also within this scope. This paper describes the latest furnace developments and includes novel trends. Moreover, hot and wet gas cleaning systems are examined focusing on unit operations related to the removal of components such as dust, SO2 for sulfuric acid production, fumes, halides, Hg, hydrocarbons, nitrous oxides and metals.INTRODUCTIONGenerally, when defining roasting processes, it can be stated that the respective primary pyrometallurgical reaction is exothermic, of gas-solid nature and relates to a value solid product. These processes are a key focus within Outotec’s scope and include: (i) dead roasting (ii) sulfating roasting (iii) partial de-arsenifying roasting and (iv) two-stage, de-arsenifying roasting.Dead roasting involves the oxidation of a given sulfide, thus allowing for a subsequent leaching process, and has been applied to producing ZnO. Dead roasting of pyrite has also been extensively utilized with a primary goal of producing sulfuric acid. In contrast, sulfating roasting involves converting a sulfide to its sulfate, enabling a selective sulfation of components, such as Cu or Co, and their separation from ferrous components during leaching (produced sulfates are soluble). Partial roasting involves partially oxidating the metal sulfide to its oxide with the simultaneous production of gaseous As4O6, which is handled during gas cleaning. The solid product, containing hardly any As, is rich in S and can be fed to a respective smelter (e.g. in the case of Cu). Alternatively, if the production of oxide is required, a dead roasting step is added after the partial roasting step, with the overall process considered as two-stage roasting."

Jan 1, 2012