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By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005

By M. Özer, F. Boylu, G. Önal

In this study, the fine coal waste subjected to the experiments is taken from the waste stockpile of Soma Coal Plant. The possibilities of its evaluation and the production of clean coal were investigated. For this purpose, Reichert Coal Spiral and Shaking Table are used. The minus 1 mm coal waste includes 60.43% ash and 50% minus 38 micron material by weight. The microscopic observations of the screen fractions were shown that the clay minerals are in fine sizes and the coarser size fractions contain silica and carbonate minerals as ash forming materials. The tests were conducted after desliming. The commercial grade clean coal product containing 29-35% ash with a calorific value of 3800-4200 kcal/kg (15.91-17.58 MJ/kg) was obtained by gravity methods.

Jan 1, 2004

By Robert C. Lo

As tailings dams grow in physical size, their impact on public safety and the environment also increases in severity. Over the last three decades, tailings dam engineering has evolved from largely "trial-and-error" methods to a mature, multi-disciplinary engineering endeavour. This paper reviews the current practice of tailings disposal, and the evolution of tailings dam engineering. Key factors affecting dam integrity and examples of dam failures are then highlighted. Finally, the paper reviews some of the recent trends that lead to new challenges to the mining industry. These challenges include: coping with heightened public concern about dam safety; balancing potential conflict between seismic and environmental requirements; and addressing issues introduced by globalization of the mining industry. Institutional responses and technological tools available to meet these challenges are also outlined.

May 1, 2001

By M. Solomon

Abstract -Giant, sediment-hosted lead-zinc deposits in northern Australia formed during development of Mid-Proterozoic extensional basins that overlie Lower Proterozoic basement. The basement in the Mount Isa area, exposed by folding and faulting, contains fractionated, high-heat-producing granites. These granites generate heat at a rate of about 6 ?Wm-3, probably sufficient to form giant lead-zinc deposits either by (a) driving episodic convection of saline basement and basin fluids for periods of 105 to 106 years at temperatures of about 230°C, or (b) heating basin fluids moving under the influence of topographic relief or fault movement. The presence or absence of such granites may form a vital component of the genetic model. Ore-forming fluid flow was probably initiated by continent-scale, extensional basin fracturing.

Jan 1, 1992

By K. Shitogiden, Y. Samada, T. Miki

Steelmaking slag contains nutrition such as Si, P and Fe for acceleration of phytoplankton growth. Phytoplankton can fixate carbon dioxide more than any other species on earth. Hence, suppression of CO2 can be achieved by applying the potential of steelmaking slag as the nutrition for their propagation. When it is considered to supply nutrition from steelmaking slag to seawater, we must avoid dissolution of hazardous elements or change of pH of seawater by steelmaking slag addition into seawater. The protection against dissolution of fluorine into artificial seawater has been studied based on dissolution behavior of steelmaking slag and synthesized substances into artificial seawater in the present work. The dissolution mechanism of fluorine from steelmaking slag and buffering action of pH change are discussed by using stability diagram in seawater.

Jan 1, 2004

By J. W. Matousek

"Computer modeling of smelting processes requires internally consistent equations for calculating the compositions of mattes and slags. That is, the sum of the calculated assays must total 100%. One set of equations that satisfies this requirement for copper produced under oxidizing conditions (pSO2>one atmosphere pressure) is given by the following:%[Fe] = 62.0 – 0.775%[Cu]%[S] = 28.0 – 0.00125%[Cu]2%[O] = 10.0 – 0.225%[Cu] + 0.00125 %[Cu]2Mattes containing nickel in appreciable quantities do not have the defined “white metal” end point of approximately 80 percent copper and 20 percent sulphur that is found in the copper system during the converting process. The above equations, however, are readily extended to nickel and nickel/copper mattes for any desired end product composition."

Jan 1, 1996

By M. Solomon

Giant, sediment-hosted lead-zinc deposits in northern Australia fonned during development of Mid-Proterozoic extensional basins that overlie Lower Proterozoic basement. The basement in the Mount Isa area, exposed by folding and faulting, contains fractionated, high-heat-producing granites. These granites generate heat at a rate of about 6",Wm-3, probably sufficient to fonn giant lead-zinc deposits either by (a) driving episodic convection of saline basement and basin fluids for periods of IOS to 106 years at temperatures of about 230°C, or (b) heating basin fluids moving under the influence of topographic relief or fault movement. The presence or absence of such granites may form a vital component of the genetic model. Ore-fonning fluid flow was probably initiated by continent-scale, extensional basin fracturing.

Jan 1, 1992

By Seongki Lee

The purpose of this paper is to propose the real-time facility management system framework based on Building Information Model (BIM) and Web of Things. Latest IT such as BIM is rapidly spreading to architecture, civil engineering, engineering and maintenance with the aim of simplifying complex system in buildings and facilities, minimizing operation cost, providing high value services and advancing facility management. In particular, BIM-based management framework design to assist the development of sensor information operation system, which adds convenience to facility maintenance and management, has emerged as a key issue. To this end, this paper proposed conceptual framework for data warehouse, web service and interface that make up real-time facility management system. The paper also produced conceptual methodology on CoRE-based web service platform, mobile device, BIM and WSN mapping.

Aug 1, 2013

By A. E. Reschke

Optimized mine planning of the Leeville Gold Mine, Nevada, necessitated the requirement for an average of 2540 tpd of high quality cemented rockfill (CRF) in primary stoping blocks and underhand cut and fill workings. To meet this requirement, a number of innovative design features were incorporated into the overall batching plant design. Foremost is the use of a dedicated skip to transfer crushed aggregate from surface down through the ventilation shaft to twin underground storage silos. Also, the use of a high shear colloidal mixer on surface to pre-slurry a cement/flyash binder with pipeline delivery to one of two separate underground CRF mixing stations was incorporated. Finally, the binder and aggregate are combined in a 9 m3 twin shaft compulsory type mixer before loading into teleram trucks for placement.

May 1, 2007

By Joseph Carlston

With environmental regulations continuing to restrict the discharge of phosphorus from wastewater treatment facilities, traditional methods of phosphorus removal are proving inadequate. To achieve the phosphorus control necessary, a new coagulant used for phosphorus removal, cerium chloride, has been studied in several municipal and industrial wastewater treatment facilities that must meet a phosphorus discharge limit of 0.5 mg/L or lower. These studies demonstrated the high phosphorus removal capabilities of cerium chloride, with the results illustrating the ability for cerium chloride to reduce phosphorus to low concentrations in the effluent using a lower volume of product as compared to traditional coagulants, such as ferric chloride. This reduction is due to the unique ability of cerium chloride to remove phosphorus as cerium phosphate, whereas iron- and aluminum-based coagulants rely on adsorption and co-precipitation.

Jan 1, 2014

By N. Plint, M. Potgieter

The Anglo Platinum Mogalakwena North concentrator was one of the first three hard rock mineral processing applications to utilise a HPGR circuit in preference to a SAG milling circuit. This was driven by the extreme competence of the ore that had given rise to throughput issues on the original South Plant. Despite more than adequate capacity and performance of the individual comminution units, the circuit has struggled to obtain full design capacity. A thorough review of the integrated performance of the circuit revealed a wide range of bottlenecks and underutilised parts of the circuit arising from design issues. Interestingly, the major opportunities lie in materials handling issues and mismatch of loads about the circuit. This paper presents the high-level outcomes and the associated opportunities, and is pertinent to all HPGR circuit designs.

Jan 1, 2012

By Mike McKevitt

We are trying to promote a concept and a change in management?s approach to the iterative process of grade control. This is important as grade control must routinely try and achieve the long term objectives set by the mine plan ??BackgroundBackground ??Factors contributing to variation from planFactors plan ??Basis of OptimisationBasis Optimisation ??Ore Block Optimisation processOre process ??Operating mine examplesOperating examples ??Chain of Mining. ??Intention is to highlight the need for repeatable and consistent materialand material-type classification to remain consistent with the Life of Mine Plan ??We can drill another hole or reWe re-optimise a plan, but once excavated, the final decision has been made ??The grade control decision is the last decision made in the resource exploitation sequence.

May 1, 2009

"Many underground mines are achieving extended life and optimizing existing facilities by mining at greater depths. The challenges to do this require a sound engineering approach to mine design and mine services, as well as ingenuity in safety design. The social consequence is full utilization of existing infrastructure.Accessing ores at depths of 2000 m to 3000 m requires exceptional hoisting design. May’s theme issue includes a paper that examines a case study of one such hoisting plant, with emphasis on the hoist rope selection at Agnico-Eagle’s Penna shaft. The paper also describes the process whereby consultation with provincial safety authorities resulted in a revised safety factor suited to the hoist. Another paper examines the challenges of ventilating mechanized mines to 3000 m, including air cooling and dilution of diesel exhaust emissions. Vent system designs are discussed, using sound engineering design, and proven technology that minimizes emissions to achieve cost efficiencies. The paper suggests design based on process and ventilation simulators to obtain realistic economic data at the design stage. Increased ground pressures present unique challenges for production and safety. While this is not confined to deep mining, one paper examines rock pressures and seismic events at the Brunswick mine, for which experience may be applied at depth. It describes seismic monitoring as a predictive tool in a real mine situation, and how it is used to improve overall recoveries and maintain worker safety."

Jan 1, 2004

By David D. Davidson

Commodities remain hot for the time being, but for how much longer? The bulls point to global economic growth lead by China?s insatiable demand for raw materials. To further emphasis the bullish view they point to the emergence of India for follow through demand. The bears remain convinced China?s growth is unsustainable and with higher interest rates and high oil prices, the United States economy is poised to slow. Both groups can make a convincing argument and both will be proven right in the fullness of time. Profitability and balance sheet strength for the mining industry has rarely been better. Is this a time to be bold or cautious? In this paper, the author will address the dilemma facing today?s management as they pursue growth and try to minimize risk.

Apr 1, 2005

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By A. A. Wessels, D. P. Allison

"Mine hoists are built to handle a certain nameplate capacity; they are specified and designed according to the required duty. However, as production capacity increases in other parts of an operation, the hoist capacity can become the critical constraint. Such a situation occurred at Lundin Mining’s Neves-Corvo operation. This paper examines how each component of the existing hoisting system was examined and optimized. Through a combination of engineering study and hoist simulations, the annual hoisting capacity was improved by 24% through increases in payload capacity and available hoisting time combined with a reduction in cycle time, while no changes were made to the hoist motor, drum or headframe. The additional payload capacity was achieved by reducing the mass of the hoist ropes and skips, and improving load monitoring systems. The cycle time was reduced through the shortening of the creep distances and increased availability through the installation of a shaft collar safety platform, alternative guide rope bushes, and superior liners for both the skips and underground measuring flasks. Enhanced cooling of the hoist electrical system was also incorporated to increase hoist availability by reducing downtime during hot summer months. The changes will increase the capacity from the current 4.5 mega tonnes per annum (Mtpa) to a planned 5.6 Mtpa and are being implemented over a 2-year period whilst maintaining the mine production during the upgrade work. INTRODUCTION Neves-Corvo Mine Neves-Corvo is primarily a copper and zinc mine producing copper, zinc and lead concentrates. The operation is owned and operated by Somincor, the Portuguese subsidiary of Lundin Mining. Located in the Alentejo district of southern Portugal, the operation is situated approximately 15 km southeast of the town of Castro Verde, where summer temperatures can reach as high as 45ºC, and approximately 220 km southeast of Lisbon. The principal means of mine access is via a ramp from surface, with the vertical shaft used to hoist ore and waste from the 700 m level, while conveyors descend from the 700 m level to transport ore and waste up from the deeper levels of the mine. The mine is highly mechanized and several different stoping methods are employed, with the most significant being bench-and-fill and drift-and-fill. The Neves-Corvo mine currently exploits five orebodies: Neves, Corvo, Graça, Zambujal and Lombador for copper and zinc-lead ores which are processed in one of two plants. All the orebodies are currently exploited over their full elevation with the exception of Lombador which is only mined down to the 220 m level, approximately the top 50% of the orebody, known as Lombador Phase 1."

Jan 1, 2019

By K. Chomyn, R. Veenstra, P. Zangeneh, Hatch Ltd., C. Van der Woude, H. Ghorbani

"The furnace is the heart of smelting operations, and therefore the performance, reliability, and campaign life of the furnace are critical considerations. Furnace refractory is exposed to high temperatures and other harsh operating conditions causing brick erosion, crushing, and cracking, typically limiting the furnace campaign life and requiring costly furnace shut-downs for refractory re-lining. Despite extensive study, the in-service thermal / mechanical stresses in these complex refractory systems are not generally well understood. Hatch has developed a thermal-mechanical finite element analysis (FEA) based furnace refractory modeling approach that allows for the quantification of refractory movements, load distribution, and thermal / mechanical stresses.Due to the complexity of the refractory system, a range of models are used to identify and assess damage mechanisms and design improvements, including: 2D models, to capture expansion and movement of individual bricks, changes to load paths, and thermal stresses; and 3D models, to include the effect of differential expansion between bricks in each course, and assess overall load distributions. The 2D and 3D analyses include the effect of nonlinear temperature-dependent properties, thermal expansion, movement of individual bricks with frictional contacts (i.e., gaps can open, bricks can slide), and brick tensile or compressive failure. Both as-built and damaged conditions can be investigated (e.g., after bath zone brick erosion), for circular and rectangular furnaces. 3D models also include papering and brick joint & interface action.Analyses using these models have shown the importance of thermal stresses, papering, and geometry / arrangement of individual bricks. Results have been used to identify and assess damage mechanisms, showing good alignment with furnace autopsy observations. By using this FEA-based approach to quantify the refractory design, the risk of damage can be significantly reduced, low-cost design changes can be identified, and the furnace campaign life can be extended.INTRODUCTIONThe furnace is the heart of smelting operations and therefore the performance, reliability, and campaign life of the furnace are critical to the success of the smelting operation. Furnaces are inherently exposed to high temperatures, often in excess of 1600°C (Holappa, 2004), and furnace operating power has progressively increased over time (Voermann, Gerritsen, Candy, Stober, & Matyas, 2004). The refractory system must withstand high temperature, high heat flux, and other harsh operating conditions. These conditions are particularly significant for the furnace hearth, and can lead to damage including brick erosion due to molten material flows, crushing due to thermal expansion loads, and cracking due to severe thermal gradients within the bricks. Refractory damage typically limits the furnace campaign life, requiring costly furnace shut-downs for refractory re-lining (repair or replacement). In some cases the refractory may lose integrity causing damage to nearby equipment and harm to personnel."

Jan 1, 2016

By Gonzalo Díaz, Diego Mesa, Willy Kracht

"It is well known that frothers affect the amount of water that is transferred to the froth, which has an effect on both the froth stability and the water recovery. On the other hand, since non-selective recovery by entrainment is directly related to water recovery, it can be said that frothers have an indirect effect on flotation selectivity. Recent research on this subject has shown that the non-selective recovery by entrainment, which is characterized by the entrainment factor, is frother dependent. In other words, the entrainment factor is not unique, but depends on frother type.Having different entrainment factors implies that for the same water recovery, the amount of undesired particles reporting to the concentrate may vary if one changes the frother type, which suggests, as a possible explanation, that it is not only the amount of water in the froth what is affected by frother type, but also the froth structure.The purpose of the current work is to study the effect of frother type on foam structure (two phase froth). A quasi-2D cell operated with a slot sparger was used to study the foam structure in the presence of three different frothers: Methyl Isobutyl Carbinol (MIBC), OrePrep®549, and Octanol at the same gas flow rate and reagent dosage. The foam structure was studied using image analysis, and an algorithm based on textural analysis was developed to classify the foams. The results show that it is possible to classify foams according to the frother used, which proves that frothers have an effect on the foam structure.INTRODUCTIONFrothers are usually dosed paying attention to froth stability, condition that is commonly estimated by sight, according to the operator's criteria and experience. This happens because there is not an established procedure or technique for frother characterization, generating qualitative descriptions such as “powerful” or “selective” frothers, which lack of scientific thoroughness and remain under subjective factors. Nevertheless, several works have been done in this line of research. Moyo et al. (2007) classified frothers based on their water-carrying capacity, proving that this characteristic is related with gas holdup and frother type. Previously, Trahar (1981) had related water recovery and gangue particles recovery, defining the entrainment value (ENT). Nowadays it is known that entrainment affects both hydrophilic and hydrophobic because it is not a selective process. In the last decade some studies (for example the one of Konopacka and Drzymala (2010)) delved into different entrainment behaviours dependent mainly on the flotation type (batch or continuous, agitated or columnar, etc.), but there were no studies on the effect of frother type regarding entrainment, since Rahal et al. (2001) argued that the ENT factor was independent of the frother type and concentration, and froth height."

Jan 1, 2016

By S. Kodama, G. Sasaki, K. Matsugi, K. Sugio, Y. B. Choi

"Pure aluminum (Al) matrix composites with changing the volume fraction of TiB2 particle content from 10 to 30% was fabricated by spark plasma sintering (SPS) process. Then the microstructure, density, dispersibility and thermal conductivity of the composites was estimated. As increasing TiB2 content, the dispersibility of particles and the density of the composites degraded slightly. And, the effect of the dispersibility of TiB2 particles on the thermal conductivity was quite little. The thermal conductivity of the composites was less than the theoretical value calculated by Maxwell-Eucken equation considering the effect of the density. It is due the influence of the interface heat transfer rate, because these composites have many small sized particles and have high interface density.INTRODUCTION Recently, metal matrix composites (MMCs) have been used widely in electric / electronic components, architectural materials, transportation equipment, aerospace and a precision instruments, because it’s superior properties have been greatly watched. Demand of MMC for industrial use has been increasing gradually. Furthermore, multifunction properties are required for the composites strongly. By integrating the dissimilar materials, the composites have various properties that we cannot get from monolithic materials. On the other hand, the response to the thermal management is required for materials, recently, and the need for the structural material controlling the thermal conductivity has been increasing. Especially, superior thermal conductivity and good mechanical properties from room temperature to high temperature are required for heat sink and heat exchanger at the same time. In late years, a study on the composites combining carbon materials and aluminum and copper has been developing, and actually the composites with high thermal conductivity which is not provided in the conventional materials is developed. On the other hand, non-oxide ceramics particles such as SiC and AlN, TiB2 have good thermal conductivity. Particularly, as TiB2 has good electrical conductivity, TiB2 containing MMCs is expected as innovative materials used as electric/ electronic components. Furthermore, as TiB2 has low density, high melting point, low thermal expansion and good deformation resistance, the development of high performance composites with multi-functional properties is expected. As thermal conductivity of pure Al and TiB2 are 225 and 66.4 W/mK, respectively, it is expected that the degradation of thermal conductivity by adding dispersant in Al matrix is suppressed. The authors have carried out a thermal conductivity, electrical conductivity, mechanical properties of 20 vol.% TiB2 dispersed Al composites (Sugio, 2016, Sasaki, 2016). In this study, the influence of quantity of addition of TiB2 on microstructure, thermal conductivity was studied minutely."

Jan 1, 2018

By G. M. Ritcey, A. W. Ashbrook

"This paper summarizes the optimum leach conditions for each Of several cobalt-containing arsenical feed materials, describes the solution treatment prior to purification of cobalt recovery, and discusses the plant operation on one feed as well as the treatment of effluents.IntroductionDuring the period 1962-1964, when the demand for uranium was low, Eldorado Mining and Refining Limited (Eldorado Nuclear Limited) made a decision to undertake a three-year diversification program. One area chosen in this program was that concerned with the processing of cobalt-nickel materials. Many such materials were evaluated over the three-year period, ranging from tailings, residues, ores, concentrates and speiss to metal scrap. Cobalt feed materials, on which much of the effort was concentrated, were those containing arsenic together with other metals such as silver, copper, nickel and iron. This paper describes the treatment of arsenic-bearing feed materials (ranging from 0.3 to 570/0 As) and the subsequent purification stages required before the separation and recovery of high-purity cobalt. Because of the current interest in treating cobalt ores, it seemed appropriate that the information on the treatment of various cobalt feeds should now be made available . Although a large amount of data were generated during the research and process development program, a complete scientific correlation and understanding could not be achieved. Nevertheless, the data may provide a guide to others involved in processing not only cobalt, but other arsenical ores."

Jan 1, 1981