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By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By R. C. Reed, L. T. Wu, H. C. Harada, K. Kawagish, R. T. Wu

Oxidation of pure metals is a chemical reaction in which the metal loses one or more electrons, such that the atom of the metal changes from the neutral state to a positively charge ion and reacts with oxygen to form an oxide of the metal. The oxide can form as a protective and adherent scale that slows down further oxidation, or may spall off repeatedly, exposing fresh metal surface to react with oxygen. In multi-component alloy systems such as typical high temperature NiCrAlY bond coats, more than one oxidation mechanism may take place at once and thus, complicates the study of oxidation. To better understand the competition between formations of oxides of different compositions, a thermodynamic assessment is carried out to study the oxidation mechanism of a Ni-27Cr-9Al (at %) ternary alloy. Based on the assessment, it is demonstrated that the layering of different oxides can be determined, with the most stable oxide (alumina) existing directly above the metal-oxide interface and the least stable oxide (nickel oxide) locating on the outer most layer. A comparison between the calculated results and previously published experimental observations shows excellent agreement.

Jan 1, 2010

By R. A. Sullivan

I T IS one of the unwritten policies at Preston Mines that we examine closely any method or tool that will help us in our constant battle against rising costs. It is our personal conviction that most work methods can be improved. Therefore even though the job went well yesterday, it does not necessarily follow that it should be done by the same method today. With the arrival of the natural gas pipe line in the Porcupine area it was obvious that we would have to take a good look at the possibilities of using this source of fuel for plant heating. • Steam presently generated at Preston is for heating purposes only, no process steam being required. Prior to the fall of 1960, the heating plant consisted of two low pressure, coal-fired, fire-tube boilers, operating at an approximate pressure of 14 pounds per square inch. These boilers were underfed by stokers and could be operated either singly or together. ~o. 1 unit was a horizontal return tubular boiler, registered at 100 h.p. No. 2 unit was a fire-box boiler, registered at 75 h.p.

Jan 1, 1962

The uphole bench extraction strategy at EKJV Management Pty Ltd?s Raleigh Mine, requires simultaneous horizontal and vertical exposure of paste filled stopes. In order to prevent excessive ore dilution, the paste fill must be of sufficient strength to prevent failure during exposure. A numerical modelling methodology has been developed to accurately simulate the initial stress distribution within paste filled stopes, together with the strain-softening loading response of paste fill material. Due to the narrow orebody width and high deformation behaviour of the host rock mass, high closure strains are likely to cause a stiff, brittle fill material to undergo crushing failure upon exposure. The stability of paste fill exposures at the Raleigh Mine was determined by conducting a series of three-dimensional numerical models that incorporate the extraction, filling and exposure sequence of paste filled stopes. Stability charts for 2.5 m and 3.5 m wide simultaneous horizontal and vertical exposures have been derived based upon the numerical modelling results. Implementation of the stability charts has proved successful in limiting the amount of ore dilution from paste fill and provides a basis to optimize paste fill cementation and stability throughout the life of the mine.

May 1, 2007

By Paul Ransom

Sullivan Production and Present Value ? Mined 150 million tonnes ? 6.0% Pb, 5.5% Zn, 2 opt Ag, + Sn, Cd, In ? May 2006 Value + US$43 Billion ? 50% of metal from first 37% (55MT) of tons ? True original size ~ 110-120 Mt @ 17%Pb+Zn ? 30MT unconsolidated fill + HW cave

May 1, 2006

By Alfredo Bambaren

First Encounters between Communities and Mining 1. Importance, meaning and process 2. Antamina?s study case 3. ?Self-organization? theory (NLP) 4. The story we tell, the values we live 1. Importance, Meaning and Process ? First encounter stays in mind as a model. ? First encounter means foundation. ? First encounter builds the story.

May 1, 2010

By B. M. Coombes

The McCracken and Stacey (1989) method of assessing geotechnical risk for largediameter raisebored shafts has been the basis for most Australian pre-construction raisebore investigations for the past 20 years. At the time of its publication, the McCracken and Stacey (M&S) Method did not include a database of raisebore diameter and rock mass conditions versus actual performance. It did, however, provide a chart that quantified geotechnical risk in terms of proposed shaft diameter and the raisebore rock quality index, QR. Two parameters, RQD/Jn and Jr/Ja were identified as being critical to raisebore stability, but the contribution of these to overall raisebore stability was not quantified. Peck and Lee (2008) published a database of raisebore performance from Australian case histories. Raisebore diameter and ground conditions, in terms of a Lower Bound QR value, were presented for 50 cases versus raisebore performance. This paper updates the database with further case histories and corrected SRF values. This paper further evaluates the reasons for the variable raisebore performance for similar RSR values. For all case histories, three parameters, RQD/Jn, Jr/Ja and Jw/SRF are investigated to assess their influence on raisebore performance.

May 1, 2011

By Claude Deveau

"With ever decreasing feed grades, finer mineralogy and increased demand for product, it became obvious that a major step in equipment performance was required to reduce operating costs and increase production. Offsite testwork indicated that a Centrifugal separator was capable of recovering fine tantalum and that the newly developed C Series Falcon concentrator would be capable of replacing many pieces of aging equipment and provide improved performance. Further investigation led to the rental and the purchase of a Falcon C20 concentrator followed by a C10 to maximize circuit performance.Falcon Concentrators Inc’ s practice of working with the customer mirrors Tantalum Mining Corporation of Canada’s (Tanco) philosophy of continuous product development. This synergy honed valve design for continuous operation in a highly abrasive ore environment.Tanco has recently purchased two more Falcon concentrators for the recovery of additional tantalum from its spodumene circuit. These new units have additional user friendly operating features partially based on developments made at Tanco.The Falcon C Series units have enabled Tanco to maximize recovery of tantalum that was otherwise lost while using the original conventional gravity circuit."

Jan 1, 2000

"THE OTTAWA BRANCH, CIM, each year holds a symposium on a subject of topical interest. The symposium this year was on Canada's Offshore Mineral Resources, at which papers were presented by: Dr. Donald G. Crosby, chief, Resource Administration Di-vision, Department of Energy, Mines and Resources, Ottawa; John A. Beesley, head, Legal Division, Department of External Affairs, Ottawa; and David W. Smith, man-ager, offshore exploration and production, Shell Canada Limited, Calgary. Because of the interest which this topic holds for our members, and because of the wealth and significance of information presented, the three papers -representing the first comprehensive review of our offshore resources -are reproduced herewith. The opening remarks of the Chairman, Dr. F. K. North, Professor of Geology, Carleton University, are also recorded, together with a few of the questions asked by the large attending audience. The symposium was held February 13th, and was organized by Dr. W. M. Tupper, chairman of the Branch Program Commit-tee. Differences in the extent of the continental shelf will be noted in the papers. These differences are related to slightly different definitions of the continental shelf by the authors."

Jan 1, 1969

Polymer electrolyte membrane (PEM) fuel cell has increasingly become the potential choice of zero-emission power source for portable, mobile and stationary co¬generation applications. However, technical barriers need to be overcome before its widespread commercialization; cost reduction and performance improvement including reliability are the two key areas, that can be realized through better cell/stack design and improved understanding of the transport processes occurring inside the individual cells and stacks. In this presentation, we will provide an overview of various cell/stack models that are available in the literature, their strength and weakness, and then present a comprehensive multi-species, multi-phase and multi-dimensional formulation of a single PEM fuel cell, with consistent and systematic formulation for all the regions involved, including the solid bipolar plates, gas flow channels, the electrode backing layers, the catalyst layers and the electrolyte membrane. Such a detailed approach allows us to extract sufficient information to the analysis of a stack of PEM fuel cells. Stack model will be presented that investigates the various stack designs and flow configurations, and the optimal stack design based on the present study will be described. Also some innovative cell/stack designs will be featured.

Jan 1, 2005

By Aimee Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario, using bacterial metabolic processes are used to enhance the solubilization of the metal(s) of interest. The cost effectiveness of bio-mining in Elliot Lake depends on the bacterially-influenced dissolution metals of economic importance, as well as on the ability to suppress microbiological activity following the release to solution of the economically important elements. This poster provides an overview of elemental recovery results and release kinetics for more than 50 elements. The data is obtained using a combination of advanced spectroscopic tools (ICPAES and ICP-MS) to analyze solutions obtained from a series of environmentally controlled biologically mediated uranium ore extraction experiments. The focus will be on rare earth elements, potential environmentally toxic elements, and metals of economic importance. Furthermore, the importance of these findings will be put into an economic and geologic context for the re-development of the mining industry of the Elliot Lake Camp.

Aug 1, 2010

By M. Kinne

Catalyst preparation/ characterization Slightly modified DP (~Schumacher et al. Catal. Lett. 89, 109, 2003) CeO2 HAS 15 from Rhodia calcined in air for~ 2h BET: ~188m2/g, particles size: 5.7nm (TEM, XRD) + HAuCl4 at pH of 6.5-7, (>95% of the Au was deposited) ? Au/CeO2 (2.6wt% Au, ICP-AES) A new conditioning procedure was applied, including heating at low temperature in N2 and H2/N2 mixtures) Patent DE 10205873A1. Very small Au particles <2nm, for CO oxidation catalyst as Au/TiO2, Au/Fe2O3, and Au/Co2O3 Here Au particles size <3.5nm (XRD) Summary ? CO is nearly exclusively adsorbed on the Au particles ? Positive reaction orders of 0.5 are found for CO and H2O ? Ea= 40kJ/mol ? The catalyst is very active and stable ? During WGS reaction huge amounts of formates are formed and cover the surface ? The activity of the catalyst seems to be correlated with the formate species.

Oct 1, 2003

By L. Xia, B. Hart, K. Douglas1, S. C. Chelgani

Development work to optimize a flotation flowsheet for rare earth element (REE) recovery is underway. The original approach used alkyl phosphates and phosphoric acid ester as collectors to concentrate REE minerals. To improve REE recovery, hydroxamates as alternative collectors were investigated. In this paper, micro flotation of REE minerals using salicylic, benzoyl and naphthoyl hydroxamates is reported. Unlike phosphonic collectors, slime removal does not show a significant effect on REE recovery when using hydroxamates as collectors. Among the three hydoxamates, the grade of La, Ce, and Nd for concentrates produced by salicylic hydroxamate is the highest. The recovery response with naphthoyl hydroxamate is similar to that of salicylic hydroxamate; good grades for La, Ce, and Nd, less effective for Nb, Y, and Zr. The data indicated an affinity by salicylic and naphthoyl hydroxamtes for LREE over the HREE minerals. In comparison, benzoyl hydroxamate indicated an affinity for Nb, Y, and Zr. Temperature effects on REE recovery were also studied. The grade and recovery of REEs generated by flotation using a mix of salicylic and benzoyl hydroxamates at room temperature was almost identical or even better relative to the recovery using naphthoyl hydroxamates at elevated temperature.

Jan 1, 2014

By W. K. Chan, R. Lahaie

"The Suncor Oil Sands Mine located north of Fort McMurray, Alberta, produces about 80000 m&apos; per day of tailings waste which must be disposed of economically in an environmentally acceptable manner. To date, this has been accomplished by impounding the high water content tailings wastes behind large dykes, many of which approach 100 m in height .The dykes are constructed using suitable overburden material stripped prior to the mining of the oil sands feed and/ or the coarse sandy fraction of the tailings waste itself. Although the above is common practice at many mining operations, the large volumes handled and the resultant costs require designs to be meticulously fine-tuned toward the optimum. As a result, considerable effort is expended on planning, designing and construction, and performance monitoring. The lack of precedent experience (Suncor pioneered oil sands mining), coupled with the realities of long, harsh winters and a variety of troublesome site conditions and construction materials, has led to some very unique dyke construction.This paper overviews current tailings disposal plans as welt as some of the key issues related to the design, construction and performance of these large dykes."

Jan 1, 1988

By K. Murase

Potentiostatic electrodeposition behavior of dendritic copper from acidic copper(I) chloride (cuprous chloride) baths containing sodium chloride and sodium bromide was investigated. The morphology, or appearance, of copper dendrite and the sodium content in the dendrite as an impurity were both influenced by deposition potential (0 to ?150 mV vs. SHE) and bath temperature (R.T. to 60 C), while the current efficiency for the deposition was 99% or more irrespective of the deposition conditions examined. The bath pH did not affect the deposition behavior in the pH range of 0 to 2. Bath temperature was found to be the most important factor influencing the deposition current. The current density of the dendrite deposition on a titanium cathode was lower than that onto a copper cathode with the same substrate surface area. The reproducibility of the current for the dendrite deposition was poorer when an as-polished titanium cathode was used, although it was improved by surface treatment of the cathode with an HF-HNO3-H3PO4 solution before electrodeposition. The deposition behaviors were discussed with the potential-pH diagram of the Cu-Cl-H2O system.

Jan 1, 2007

By George McIsaac

This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development and mining method. Based on practical considerations, maximum rates are set for each zone?s development and production capacity. As for the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum number of development metres per day is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Furthermore, the fixed cost of operating the mine is taken into consideration whenever mining activities take place. Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analysed. What-if scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan.

May 1, 2003

By H. Saari, M. Pates, P. C. Patnaik, A. Merati

Single crystal nickel-base superalloys such as PWA1484 exhibit superior performance compared to conventional superalloys, and are used extensively in turbine blade applications requiring good high temperature properties. The life of these blades is typically limited by cracks and erosion. Due to the high cost of these blades, welding techniques are being considered to weld/repair worn components, extending their useful lives and delaying the need for expensive replacement components. However, the sensitivities for solidification cracking and post weld heat treatment cracking are relatively high in these alloys. Electron beam (EB) welding can deliver concentrated heat sources and has the potential to address these issues. Numerous welding trials and structural tests must be conducted to identify the optimum method and welding parameters. Weldability is studied over a range of material conditions, welding parameters, and directions. The influence of welding parameters on the fusion zone microstructure and resultant weldability is investigated using combination of microscopic examination and micro-hardness testing. This paper summarizes some of the results of a feasibility study conducted to understand the effects of welding parameters on localized microstructural features, cracking sensitivity, and mechanical properties of autogenously EB welded coupons of single crystal PWA1484.

Jan 1, 2004

By Steve R. McCutcheon, Cees R. Van Staal, John P. Langton, Leslie R. Fyffe

Abstract -The volcanic-dominated Tetagouche Group in northern New Brunswick contains numerous massive-sulfide deposits and intimately associated metalliferous sediments. The massive sulfides are generally hosted by Llanvirnian-Llandeilian volcaniclastic sedimentary rocks of the Nepisiguit Falls, Patrick Brook, and Boucher Brook formations. These formations are intercalated or closely associated with rhyolitic-dacitic flows and/or domes, and minor continental tholeiites of the Flat Landing Brook Formation. Pyroclastic rocks are relatively scarce in the silicic volcanic complex. Tuffites and epiclastic sandstones, of the Nepisiguit Falls and Patrick Brook formations, respective­ ly, generally occur along the fringes of the silicic volcanic complex. The flows and tuffites are intruded by quartz- and feldspar-phyric rhyolite (porphyry) dykes, sills, and domes. Although the volume of the silicic volcanic complex is large, evidence for a previously proposed collapsed-caldera model is lacking. On the basis of host-rock type and stratigraphic position, the sediment-hosted massive sulfides have been divided into three groups: the Brunswick-, Caribou- and Halfmile Lake-type deposits. Syngenetic feeder pipes and asociated alteration zones are generally not present beneath the Caribou- and the Halfmile Lake-type deposits and, if present at all, are poorly developed underneath the Brunswick-type.

Jan 1, 1992

"This document establishes standards and guidelines for scientific and technical disclosure by Issuers listed on the TSX Venture Exchange on their mineral properties. It incorporates and expands upon the minimum standards prescribed by Securities Laws and applies to all oral statements and written disclosure made by an Issuer or on behalf of an Issuer involving mineral properties.1. Introduction1.1 General(a) This Appendix establishes standards and guidelines for scientific and technical disclosure by Issuers on mineral properties. These standards and guidelines should be applied prudently and with common sense by those Issuers in conjmction with the applicable requirements of section 1.2.(b) This Appendix incorporates and expands upon the minimum standards prescribed by Securities Laws and applies to all oral statements and -written disclosure made by an Issuer or on behalf of an Issuer involving mineral properties.(c) This Appendix is not intended to be exhaustive or all-encompassing and greater detail may be appropriate and required in certain situations. Issuers are encouraged to contact Exchange technical staff where they are not certain about the requirement for disclosure on mineral properties."

Jan 1, 2003

By J. Mosher, G. Banini, J. Hollow, A. Villanueva

Prior to installation of High Pressure Grinding Rolls (HPGR) at PT Freeport Indonesia (PT-FI) a series of laboratory tests were carried out to determine the design parameters and also determine key performance indicators (KPIs) for the industrial unit. The design parameters derived from the lab test work were then scaled up to estimate the industrial capacity of the HPGRs to be installed. These parameters include specific power draw, specific throughput, and specific force, rolls speed, product size distribution and wear rate of the rolls. This paper compares the performance of the scale-up procedure against the installed industrial size HPGR. Overall, the specific throughput of the industrial size HPGR is higher by a minimum of 30% compared to the expected scale-up value. As a result of the high specific throughput, the specific power draw and grind sizes are below the scale-up expectations in the commercial application. The impact of these factors also contribute to a lower than expected wear rate on the industrial rolls. Installed rolls achieved a service life in excess of 18,500 hours relative to the target of 6,850 hours predicted from the laboratory testing.

Jan 1, 2012