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By Andreea Catalina Gluhoi

The oxidation of propylene and methane has been investigated over two series of Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 catalysts (M, MI, MII =Li, Rb, Mg, Mn, Ce, Zr). Whereas the effect of the presence of MOx or MOI x/MOII x on the oxidation of methane is relatively small, a large enhancement in activity is observed for propylene oxidation. Synergistic effects have been observed by combining ceria or a transition metal oxide (high oxygen storage capacity) with an (earth) alkali metal oxide.

Oct 1, 2003

By Emile D. L. Rienks

We have studied the interaction of NO with the quasi-hexagonally reconstructed Au(100) surface. Using variable temperature scanning tunneling microscopy we have observed formation of the unreconstructed phase of Au(100) after NO exposure. This NO adsorption induced phase transition is observed in a window of temperatures around 170 K. Under the same conditions, CO and O2 cannot drive the phase transition, suggesting weaker interaction. Thermal desorption spectroscopy experiments provide an estimate for the strength of NO chemisorption on Au(100) of 57 ± 4 kJ mol-1.

Oct 1, 2003

Abstract - A method to extract certain types of error variance information from paired data is presented, which constitutes an important tool for the calibration of Gy’s formula for variance predictions in the sampling of broken ores. The research summarized here complements publications by others on geochemical precision. The model and method proposed for treating duplicate data provide a practical means of deriving separate estimates of the purely analytical and aliquot sampling variances, from a unique set of duplicate assays, and, hence, proposes a new avenue for estimating effective mineral grain size.

Jan 1, 1998

By Melissa Whellams

?? What is a social risk assessment (SRA)? ?? Why do a SRA? ?? When do you do a SRA? ?? How do you do a SRA? What is a social risk assessment? ?? SIA vs. SRA ? SIAs determine how a company?s project will affect social/cultural conditions in a region ? SRAs determine how social/cultural conditions will affect the risk profile of a company?s project Social risk context includes: ? review of human rights record ? analysis of conflict situation ? analysis of political climate ? stakeholder identification ? stakeholder concern/interest identification ? And so on?

May 1, 2008

By R. D. Brown

This article summarizes some of the principal features of the taxation of industrial mineral mining in Canada. Where the rules applicable to such operations differ from those pertaining to the production and processing of precious and base meta s (non-industrial minerals), the two sets of rules are compared. If a conclusion could be drawn from such an over-all comparison, it may be that the total tax burden on an industrial mineral mine can be considerably more onerous than on both base meta mining operations and manufacturing profits.

Jan 1, 1979

By Belinda Campbell

Tools for Consistency 1. GIS Web Site 2. National Project Management System 3. Site Grouping Approach (721 PIDs) 4. Mine Reclamation Standing Offer Agreements ?Contracting tool 5. Remedial Objectives Guidance Document Background ?CBDC (now ECBC) is a Federal Crown Corporation and falls under federal jurisdiction. ?When it stopped mining coal, CBDC turned its attention to cleaning up and closing out its industrial sites. ?Public Works and Government Services Canada is common service provider to the GoC. ?Expertise in environmental, engineering, IT, project management, communications, GIS, real property management.

May 1, 2011

By Ann Bigué

Outline of Presentation 1. Impacts and Benefits Agreements Defined 2. Elements that determine the content of an IBA: ? the nature of the project ? the identity of Aboriginal communities affected by the project ? the legal environment 3. Content of Impacts and Benefits Agreements Impacts and Benefits Agreements Defined Have emerged in response to effects of major mining projects located on or close to Aboriginal lands and close to Aboriginal communities Are negotiated between the mining project proponent and one or more Aboriginal groups May include government May be known under other names

May 1, 2004

By K. Schimann, H. D. Knipping, J. P. Fouques

"RESUMELe gisement d 'uranium de Cigar Lake, dans la région de l'Athabasca au nord du Saskatchewan, fut découvert en mai 1981 par Cogema Canada Ltée, opérant pour Ie compte de la ""Waterbury Lake Joint Venture"".Le corps minéralisé. qui est dépourvu de toute expression directe en surface, est situé a la discordance entre les met sédiments du wottaston Group (Protérozoïque inférieur ou Aphébien) et les grès de l 'Athabasca (Protérozoïque moyen ou Hélikien), à une profondeur de 410 a450 m.Fin 1984, Ie gisement était reconnu par 105 sondages minéralisés repartis sur une longueur de 1800 m, pour une largeur comprise entre 25 et 105 m. 11 se présente sous forme d’une lentille aplatie de 5 a30 m de puissance, et montre une remarquable continuité d'ensemble. Une ride ou bombement topographique de la discordance est associée au gisement surtoute sa longueur.A l'échelle régionale, le corps minéralisé à est associe à un corridor structural d’orientation est-ouest, a l'intérieur duquel des facies particuliers aténdance blast mylonitique sont développes dans les formations métapolitiques agraphite du socle métamorphique. Il est entouré par un halo d'altération très important, caractériser Ie développement de minéraux argileux alumino-magnesiens (illite-chlorite).La minéralisation est située, pour la plus grande part, dans les grès d'Athabasca, et se compose essentiellement d'uraninite et de sulfo-arseniures de nickel et de cobalt,De nombreux levés géochimiques et géophysiques ont été effectues dans la région de Cigar Lake. Aucune anomalie ne peut être associée directement au corps minéralise, mais la combinaison des données en provenance de plusieurs sources s’est révélée fort utile au niveau de l’interprétation géologique régionale et de la définition des cibles de sondages a l'intérieur des zones reconnues favorables.Le gisement de Cigar Lake présente de nombreuses analogies avec plusieurs des gites classiques de la région de l'Athabasca; il est caractérise en particulier par l'intensité des phénomènes d’altération et la présence de minéralisations extrêmementriches.En 1984, les réserves géologiques globales estimées par géostatistique sur I ‘amas minéralise principal s 'élevaient a 110 000 tonnes d'uranium, aune teneur moyenne de 12.2%, avec une précision de 25% à l'intervalle de confiance de 95%.ABSTRACTThe Cigar Lake uranium deposit, in the Athabasca area of North Saskatchewan, was discovered in May 1981 by Cogema Canada LId., as operator of the Waterbury Lake Joint Venture. The deposit, which is devoid of direct surface expression, is located at the unconformity between the Lower Proterozoic (Aphebian) Wollaston Group meta-sediments and the Middle Proterozoic (Helikian) Athabasca sands tone, at a depth of 410 m to 450 m below surf ace.AI the end of 1984, the deposit had been defined by 105 mineralized holes over a length of 1800 m and a width of between 25 m and 105 m. It has the shape of a flat-lying lens 5 m to 30 m thick and shows a remarkable longitudinal and latera continuity from the information obtained to date. A well-defined bulge of the unconformity underlies the mineralized zone over its entire length.The deposit appears to be controlled by an east-west-trending structure within which a particular rock facies (""augen gneiss"") has developed in the graphitic metapelites of the Wollaston Group. It is surrounded by a strong alteration halo affecting both sandstone and basement, characterized by extensive development of Mg-A I rich clay minerals (illite-chlorite).The mineralization is hosted principally by the Athabasca sandstone, and consists mainly of uraninite and sulfo-arsenides of nickel and cobalt.Numerous geochemical and geophysical surveys have been carried out in the Cigar Lake area, and no specific geochemical or geophysical anomaly can be directly associated with the mineralized body, although there may be locally a good coincidence. However, a combination of several methods proved extre"

Jan 1, 1986

By M. J. Michaud, M. J. Lavigne

"Abstract - North American Palladium Ltd. operates its Lac des Iles open pit palladium mine 85 km north of the city of Thunder Bay, Ontario. The Roby Zone deposit occurs within the mafic/ultramafic Lac des Iles Intrusive Complex (LDI-IC), which was created by multiple pulses of magma of varying composition within several closely spaced chambers. Chaotic lithological distribution, the presence of magmatic breccias, and the rarity of rhythmic layering suggest a dynamic intrusive environment with disruptive magma pulses. As of December 31, 2001, measured and indicated resources for the 950 m long by 815 m wide Roby Zone deposit totalled 159 Mt grading 1.55 g/t Pd, 0.17 g/t Pt, 0.12 g/t Au, 0.05% Cu, and 0.05% Ni at a palladium cut-off grade of 0.7 g/t. The Roby Zone contains an additional 73 Mt of inferred resources at similar grades.The Roby Zone is dominated by varitextured gabbro containing pipes and pods of breccia, and large blocks (~60 m across) of varying lithology. Mineralization at Lac des Iles occurs as: (1) a PGEand base metal-rich magmatic matrix of breccia (breccia ore); (2) mineralized dikes or sills (gabbronorite in North Roby ore); (3) lower-grade mineralization in varitextured units that are host to the distinctive breccia ore and envelope the North Roby ore; and (4) high-grade mineralization associated with strong silicate alteration exemplified by high-grade ore.The close spatial association of the mineralized breccias with both varitextured units and silicate alteration leads to an interpretation that the energetic magma that created breccia was charged with a dissolved fluid, and that this deuteric fluid exsolved at high temperatures to migrate through crystal mush, enhancing crystallization along its pathways, resulting in variable grain size. This transformation occurred at high temperature and produced sulfide-poor, varitextured gabbro-hosted mineralization exemplified by some of the mineralization in the North Roby Zone, and also found throughout the Roby Zone. The association of hydrous silicate alteration with mineralization can be explained by continuing fluid migration during cooling and continued metal transport. Résumé - North American Palladium Ltd. opère la mine à ciel ouvert de Lac des Iles située à 85 km au nord de Thunder Bay, Ontario. Le gisement Roby Zone est encaissé dans le complexe mafique/ultramafique de Lac des Iles (LDI-IC), lequel représente une intrusion polyphasée créée par plusieurs pulses magmatiques de différente composition à l’intérieur de chambres magmatiques fermés. La distribution chaotique des lithologies, la présence de brèches magmatiques, et la quasi-absence de litage rythmique suggèrent un environnement magmatique dynamique perturbé par l’introduction de nouveau magma. Au 31 décembre 2001, les ressources mesurées et indiquées s’élevaient à 159 millions de tonnes titrant 1,55 g/t Pd, 0,17 g/t Pt, 0,12 g/t Au, 0,05% Cu, et 0,05% Ni, pour une teneur de coupure de 0,7 g/t Pd. De plus, la Roby Zone contient 73 millions de tonnes de ressources inférées à une teneur similaire.La Roby Zone est principalement encaissée dans un gabbro de texture hétérogène (varitextured) caractérisé par des cheminées et des lentilles de brèches et des énormes blocs (environ 60 m de diamètre) de plusieurs lithologies. Au Lac des Iles, la minéralisation en EGP et en métaux de base se retrouve dans la matrice magmatique de brèches (breccia ore), dans des dykes ou des sills minéralisés (gabbronorite dans la zone North Roby ore), comme minerai de basse teneur encaissant le minerai de brèche (breccia ore) et enveloppant la zone North Roby. Du minerai de haute teneur est également associé avec une forte altération en silicates dans la zone high-grade ore.L’étroite association spatiale entre les brèches minéralisées et les unités de texture variée (varitextured) et l’altération en silicate suggère que le magma énergique qui a causé la bréchification était chargé de fluides. Ces fluides deutérique"

Jan 1, 2001

By The Mill Staff

Professor H.E.T. Haultain: Table 4, on page 131 of this paper, gives the assays of sized mill products. I am sure that there are many others besides myself who would be very interested to learn how the sizes 0-3 and 3-13 microns were obtained. * * * Mr. Del Davis, Mill Superintendent, Flin Flon Concentrator, on behalf of the authors of the paper, has kindly sent us the following information in reply to Professor Haultain's enquiry. Sub-Sieve Sizing by Sedimentation Procedure (As used by R. J. Digney & J. E. Ryan, 1940) Fractionation of Sub-Sieve Sizes General Method: A 1,050-gram sample of the material was pulped to 3 liters; 10 c.c. of sodium silicate and 0.2 grams of Na2C03 was added and thorough agitation given for two hours previous to settling. The material was assumed to consist wholly of particles of the same density as the most abundant particles. The time required for a particle of the upper limit of the lowest size-range to be separated, to fall a specified distance was calculated according to Stokes Law. The pulp was poured into the settling apparatus and, when the calculated time had elapsed, the suspended material was drained. The settled sediments and the process repeated until no more suspended material was obtained. The next larger size fraction was obtained in a similar manner, using the settled sediments which had been stripped of all smaller sizes as above. The fractions were arbitrarily set at 0-3, 3-13, 13-23, 23-33, and 33-43 microns (43 microns = 325 mesh).

Jan 1, 1946

By F. Liu, S. Rezaei, M. Muinonen, M. Barati, V. L. Lakshmanan, S. Marcuson

Canadian nickel-copper ore deposits have been a major source of nickel, copper, cobalt and precious metals for more than 100 years. The two main minerals of interest, pentlandite (Pn, (Ni,Fe)9S8) and chalcopyrite (Cp, CuFeS2), are usually accompanied by large quantities of pyrrhotite (Po, Fe1-xS). Until the 1950s, Po containing small amounts of nickel was routinely smelted as part of the valuable Ni concentrate. The rapid growth in Ni demand following the Second World War created impetus to treat the Po separately. This action would liberate a valuable smelting capacity for higher value Pn, allow for recovery of Ni locked in Po, convert the Fe to iron oxide or metallic iron pellets, and recover S as sulphuric acid or elemental sulphur. The roasting process also has the potential to produce energy due to the highly exothermic oxidation of Po. The Ni industry would then have a “waste-free” process. Both Inco (now Vale) and Falconbridge (now Glencore) developed processes and built large industrial plants for this purpose that operated with some success. But technical issues and tenuous economics were continual challenges. By the early 1980s these industrial operations were closed. Sophisticated froth flotation methods of rejecting Po were developed, and Po containing up to 1% Ni became a waste material reporting to the tailings stream. As part of a major study on possible processing methods of Po for both value recovery and waste remediation, this paper presents a historical perspective on Canadian Po tailings with regards to their generation, inventory, value, and attempts to process them.

Jan 1, 2017

"These guidelines set out information on timely disclosure of news releases which are intended to provide, existing shareholders and potential investors, factual information on which a reasoned investment decision can be made.Consider the problems and concerns raised by the following hypothetical news releases:Natural Resource Company""The Company has recently optioned a large and exciting gold property near the ""XXX"" gold discovery area. In describing the property, the Company's independent consultant has said: ""The favourable location of, and some of the results of prior work done on the property give the Company a worthwhile mineral exploration opportunity .... "". The Company proposes to expeditiously conduct a sizeable exploration program on the property as soon as the appropriate financing has been arranged.""Non-Resource Company""Based on discussions with several European countries, the Company anticipates that it will have orders to ship over 200,000 crates of widgets to those European countries over the next two years. These orders, which considerably exceed the Company's forecasts for the first year, represent a projected profit to the Company in excess of $1,000,000 over the next five year period.""GuidelinesTimely disclosure news releases are intended to provide, to both existing shareholders and potential investors, factual information on which a reasoned investment decision can be made. National Instrument 43-101 Standards of Disclosure for Mineral Projects provides requirements for disclosure of a scientific or technical nature for a mineral resource company.The examples do not provide sufficient detail and are misleading because material information is omitted. The following guidelines should be observed when preparing a news release:"

Jan 1, 2003

By K. Wongpreedee

Recovery and recrystallization of Au wire can degrade strength and alter conductivity properties during exposure to elevated temperature. Au Deformation Processed Metal Metal Composites (Au DMMC's) are being developed for electronic applications requiring high conductivity and high strength. This paper discusses the relationships between microstructure, strength, and resistivity of Au DMMC's. It also presents the results of a recent study on the elevated temperature stability of Au DMMC's of several compositions. Au-7 vol %Ag, Au-14 vol %Ag, and Au-vol 7%Pt DMMC samples were prepared by a powder metallurgy technique. All specimens were processed into wire by extrusion, swaging, and drawing. The smallest final diameter of these wires was 120 ?m. Thermal stability was analyzed by electrical resistivity measurements to determine the relation between transformation rates and time at elevated temperature. The extensive deformation used to produce these composites reshaped the initially equi-axed powder into filaments that are 30 to 100 nm in diameter and 16 to 180 mm in length. The small filament diameter confers high strength on the composite. The high conductivity can be explained by electrons flowing parallel to the filamentary microstructure aligned with the wire axis. Using the Avrami and Arrhenius equation relationships, it is possible to predict the times and temperatures needed to achieve various degrees of homogenization. The Au DMMC's were found to have good thermal stability compared to conventional coldworked Au interconnection wires. Although these composites will revert to solid solutions if exposed to high temperatures for prolonged time periods, their relative stability is sufficient to allow them to maintain their twophase microstructure during the anticipated lifetime temperature profiles of many products.

Oct 1, 2003

By B. Van den Bogaert, K. Binnemans, T. Van Gerven

Europium is one of the most critical rare-earth elements due to the limited supply of this element combined with a high demand for red lamp phosphors. Therefore, the recycling of europium from end-oflife lamp phosphors has become increasingly important. Photochemical reduction of europium(III) to europium(II) and subsequent removal from rare-earth mixtures by precipitation as EuSO4 is a very selective and efficient method to recover europium from binary europium/yttrium solutions. It is shown that full separation of europium and yttrium is feasible from laboratory prepared non-equimolar Eu/Y mixtures up to a ratio of 1/20, which reflect the composition of red lamp phosphors. Optimal conditions were determined at pH 4 with isopropanol as a radical scavenger, which is a less harmful and toxic compound than the commonly used formic acid scavenger. Europium removal efficiencies of more than 95% were achieved, with a purity of 98.5% of the EuSO4 precipitate. The irradiance of the used light source, expressed in mW/cm2, has a large impact on the illumination time needed to remove europium from the solution. It is observed that higher irradiance results in a shorter induction time, i.e. a period during which virtually no europium is removed, and a faster removal rate once the induction time has passed. The photochemical separation technique was applied to recover europium from leached industrial red lamp phosphor (YOX) powder, with a Eu/Y ratio of 1/30. Europium recovery of 50% was reached with a purity of 96%, proving the feasibility of this method for the recycling of europium from end-of-life lamp phosphors.

Jan 1, 2016

By R. Siwik, N. K. Davé

"The national reactive tailings (RATS) program is a co-operative industry-government effort to develop practical techniques for closure of reactive tailings areas. This paper summarizes the RATS program objectives and areas of research, and details the Noranda/CANMET project on the Waite Amulet tailings.Geophysical and biohydrogeochemical investigations were carried out at an inactive copper-zinc mine tailings site, Waite Amulet, in Noranda, Quebec. Geophysical investigations consisted of seismic, electromagnetic conductivity and electrical resistivity surveys to determine the thickness of the layers above bedrock and to map conductivity variations within the tailings and the immediate outlying area. Biohydrogeochemical investigations consisted of installing multilevel piezometer nests to determine groundwater flow patterns and porewater chemistry, obtaining solid core samples and characterizing for physical, chemical and mineralogical parameters, and iron oxidizing and sulphate reducing bacterial counts.The geophysical survey indicated a bedrock ridge extending under the tailings from the northeastern outcrop which may act as a porewater boundary layer. The survey also indicated a 2 to 20 m clay layer underlying the main tailings dam. Preliminary results of the saturated zone porewater chemistry have indicated three major zones of high electrical conductivity varying between 1,000 to 12,000 µs and pH between 3.4 to 8. Lower pH and high metal and sulphate concentrations were obtained in a shallow zone near the water table. With depth, the concentration of metal and sulphate ions decreased and pH increased below the water table. The underlying clay layer is relatively impervious -and most of the seepage from the tailings is probably exiting from the sides of the impoundment dam."

Jan 1, 1987

By M. L. Jeremic

"The syngenetic and epigenetic mechanics of sedimentation and deformation of coal seams resulted in various types of internal structure, as listed below:TYPE I-massive structure with evenly distributed coal constituencies of integrated mechanical properties.TYPE II-broad-banded structure, with bright and dull coal bands of differential mechanical properties.TYPE III-heterogeneous structure, with sheared coal bands and partings of sectional mechanical properties.TYPE IV-contortional structure, with refolded coal layers and deteriorated mechanical properties.TYPE V-porous structure of orogenically crushed and pulverized coal, with disintegrated mechanical properties.The study suggests criteria for the estimation of coal seam internal structure (gamma-gamma density log and cracks density log), which might be related to the evaluation of strata stability and coal mineability.IntroductionIt is common knowledge that coal seams have various internal structures due to different syngenetic and epigenetic events. Investigations of the internal structure of coal seams have been carried out in the coal fields of Western Canada, as follows: geological field studies of coal-bearing strata;?,geophysical borehole surveying studies;?,geological borehole logging and crack density;?,underground phenomenological studies of mine structure;?,chemical coal analysis; and?,mechanical testing of coal samples.These investigations eliminated a large number of criteria previously established for the estimation of coal seam internal structure and indicated that, from an engineering point of view, only two of them are sufficient:(I) density of seam profile (inferred from gamma-gamma log);(2) density of crack s (inferred from geological log).On the basis of these criteria, five main structural types of coal seams have been classified, which might be related to mechanics of deformation and ' failure of mine structures."

Jan 1, 1982

By Gordon Sparks, Lyle Kajner

"An often over-looked component in the assessed value of a mining property is the value derived from the ability of the operator to limit financial losses during adverse economic times (i.e. low market price, high energy prices, etc.) by suspending operations. Overlooking the value of this type of operating flexibility when conducting mine investment analysis may negatively bias the risk profile for the investment by over estimating the investment's downside potential, thereby effectively undervaluing the investment. This paper illustrates the nature of the value of operating flexibility and discusses how it may be explicitly quantified within the context of conducting stochastic mine investment analysis. IntroductionMining properties are evaluated using an array of techniques ranging from simplistic non-discounted payback calculation s to sophisticated, discounted-stochastic simulation. Stochastic simulation analysis is perhaps the most robust mine investment analysis technique as it not only provides an estimate of the expected value of the property, but also quantifies the associated risks (for examples of stochastic mine investment analysis, see: Billingsley and Yaychuk, 1986; Gentry and O'Neil, 1984; Munro, 1977; or Harris, 1970).The quantification of risk is important as it provides the necessary yardstick required to allocate the corporation's resources efficiently. Resources are said to be allocated efficiently when the corporation's expected long-term financial reward is maximized while at the same time minimizing its risk (see Hertz, 1968; or Markowitz, 1952 for in depth discussions on efficiency as it relates to investment policy). The efficient allocation of resources should be the objective of any rational corporation. Therefore, rational corporations should employ stochastic evaluation techniques when screening their investments."

Jan 1, 1992

By J. Kronsteiner, E. Kabliman

"In the present work, we developed a Smart Process Control Toolkit (SProC) as a single simulation environment for the modelling of materials microstructure and its interaction with the local microchemistry during manufacturing of semi-finished products. This toolkit supports the data communication between sub-sequent processing steps such as casting, homogenization, pre-heating to deformation, etc. The thermo-kinetical simulation software MatCalc of MatCalc Engineering© GmbH was used for modelling of precipitation kinetics, such as formation of primary and secondary phases and their evolution. An import/export functionality of the precipitation distribution after each processing step was implemented to follow the parameter history. For the evolution of the local microstructure, a Mean Dislocation Density based Model (MD2M) was used. This model consists of two parts: (1) Flow Stress Model for calculation of the total strength during the deformation and (2) Static Recrystallization Model for account of the recrystallization and grain growth after the deformation. Validation was done by a comparison of experimental and simulated hot compression tests of a conventional AA2024 alloy.INTRODUCTION Optimization of a semi-finished products quality, elimination of typical production issues and cost savings are of a great demand for supply industries. However, it is currently not feasible to investigate the whole manufacturing process in detail at an industrial level. Concerning the processing parameters, one must understand the correlation mechanisms between macroscopic properties and microscopic material behavior. Numerical simulations, which could reproduce the real processing conditions on the one hand, and employ a physically based modelling on the other, are thus attracting a lot of attention and their power is no longer under the question. It is well known that e.g. the total strength of the material depends directly on distribution of precipitation particles and mean grain size. In order to follow their evolution during the manufacturing process beginning from casting to the final semi-finished product, and thus be able to control the process, one should use the techniques which would at the same time reproduce experimental processing conditions of real size objects (e.g. sheet, extrusions, etc.) and account for the evolution of a local microstructure and its interaction with the microchemistry. A commonly used approach is to implement a model which would describe the evolution of microstructure based on a dislocation density approach into a user defined material subroutine of some finite element solver. There is, however, also an influence of the manufacturing process by e.g. the evolution of a local microchemistry (formation, transformation and dissolution of the precipitation particles) on the microstructure and thus the macroscopic material behavior. Thus, a method is needed to follow the variable history through the simulation of the whole production chain."

Jan 1, 2018

By André Chagnon, Yvon Héroux

"Résumé - Cette étude porte sur l'altération de la matière organique et des argiles dans les boues carbonatés dévoniennes du faciès ""F"" de la Formation de Pine Point et ses équivalents stratigraphiques la Formation d'Evie et l'unité bitumineuse de la base de la Formation de Horn River. La matière organique se compose principalement de bitume solide et de quelques fragments de fossiles (organo­ clastes). La majorité des échantillons ne renferment que de l'illite et des interstratifiées illite/smectite.Si on compare les températures d'homogénéïsation (Th = l00°C) des inclusions fluides de la sphalérite et des dolomites associées à la minéralisation aux températures estimées à partir de la réflec­ tance de la collinite (84°C à ll7°C), l'on ne peut pas conclure à la présence d'une anomalie ther­ mique dans le district minier de Pine Point. De plus, la réflectance des organoclastes n'est pas plus élevée dans le district minier de Pine Point que dans les localités plus éloignées des gîtes. L'analyse des minéraux argileux conduit à la même conclusion : aucune anomalie thermique n'est décelable dans les unités échantillonnées à l'intérieur du district minier de Pine Point quelque soit l'indicateur utilisé.La kaolinite et la matière organique altérée, affichant des valeurs anomales de sa réflectance, se trouve essentiellement en présence de soufre et de sulfures. Cela suggère une origine authigène de la kaolinite et une altération de la matière organique reliées au phénomènes de minéralisation.Abstract- The alteration of organic matter and clays is studied in the Devonian Pine Point Formation carbonate muds, ""F"" facies, and its lateral equivalents the Evie Formation and the biturninous unit at the base of the Horn River Formation. The organic matter is mainly composed of solid bitumen with few fossil fragments (organoclasts). Most samples contain only illite and mixed layer illite/smectite.If we compare the Th(l00°C) from fluid inclusions of sphalerite and dolomites associated with mineralization to the temperatures calculated from the reflectanœ (Ro) of the collinite (84°C to 117°C), we cannot detect a thermal anomaly in the Pine Point mining district. This result is based on the reflectance values of organoclasts from the mining district that are not higher than those reflectance values measured on organic matter (OM) away from the ore deposit. A similar conclusion is reached from the clay study: none of the parameters used allow us to identify a thermal anomaly in the samples from the mining district.The kaolinite and the altered OM showing anomalous Ro values mainly occur with sulfides and sulfur. This association suggests an authigenic origin for the kaolinite and an alteration of the OM due to the mineralization events."

Jan 1, 1994

By André Chagnon, Héroux. Yvon

"Résumé - Cette étude porte sur l'altération de la matière organique et des argiles dans les boues carbonatés dévoniennes du facies ""F' de la Formation de Pine Point et ses équivalents stratigraphiques la Formation d'Evie et l'unité bitumineuse de la base de la Fonnation de Hom River. La matière organique se compose principalement de bituré solide et de quelques fragments de fossiles (organaclastes). La majorité des échantillons ne renfement que de l'illite et des inter-stratifiées illite/smectite.Si on compare les températures d'homogénéisation (Th = 100°C) des inclusions fluides de la sphalérite et des dolomites associées a la minéralisation aux températures estimées à partir de la réflectance de la collinite (84°C à 117°C), l'on ne peut pas conclure à la présence d'une anomalie thermique dans le district minier de Pine Point. De plus, la réflectance des organoclastes n'est pas plus élevée dans le district minier de Pine Point que dans les localités plus éloignées des gites. L'analyse des minéraux argileux conduit à la même conclusion: aucune anomalie thermique n'est décelable dans les unités échantillonnées à l'intérieur du district minier de Pine Point quelque soit l'indicateur utilisé.La kaolinite et la matière organique altérée, affichant des valeurs anomales de sa réflectance, se trouve essentiellement en présence de soufre et de sulfures. Cela suggère une origine authigène de la kaolinite et une altération de la matière organique reliées au phénomènes de minéralisation.Abstract - The alteration of organic matter and clays is studied in the Devonian Pine Point Formation carbonate muds, ""F"" facies, and its lateral equivalents the Evie Formation and the bituminous unit at the base of the Hom River Formation. The organic matter is mainly composed of solid bitumen with few fossil fragments (organoclasts). Most samples contain only illite and mixed layer illite/smectite.If we compare the Th (100°C) from fluid inclusions of sphalerite and dolomites associated with mineralization to the temperatures calculated from the reflectance (Ro) of the collinite (84°C to 117°C), we cannot detect a thermal anomaly in the Pine Point mining district. This result is based on the reflectance values of organoclasts from the mining district that are not higher than those reflectance values measured on organic matter (OM) away from the ore deposit. A similar conclusion is reached from the clay study: none of the parameters used allow us to identify a thermal anomaly in the samples from the mining district.The kaolinite and the altered OM showing anomalous Ro values mainly occur with sulfides and sulfur. This association suggests an authigenic origin for the kaolinite and an alteration of the OM due to the mineralization events."

Jan 1, 1994