Search Documents

By Peter Claus

In the last years, supported gold catalysts with particle sizes smaller than 10 nm have attracted a lot of attention. While gold bulk metal is rather inert in chemical reactions and, thus, is of low interest for catalysis, highly dispersed gold particles supported on oxides as TiO2 or ZrO2 show surprisingly high activities in some reactions important for the chemical industry. The oxidation of carbon monoxide at low temperatures is mainly used as model reaction to study the unusual properties of gold catalysts [1]. On the other hand, to evaluate the catalytic potential of gold, other chemical reactions which allow to control also the selectivity have to be considered. The selective hydrogenation of ???-unsaturated aldehydes to allylic alcohols is of both commercial relevance (e.g. in fine chemical and pharmaceutical intermediate production) and specific scientific interest [2]. Note that thermodynamics favors hydrogenation of the C=C over the C=O group (stronger negative free reaction enthalpy of 35 kJ/mol), and for kinetic reasons the C=C bond is more reactive than the C=O group. Thus, in the presence of most of the conventional hydrogenation catalysts, based on Pt, Rh or Pd, -unsaturated aldehydes such as acrolein and crotonaldehyde are hydrogenated predominantly to the saturated aldehydes and only to a minor extent to unsaturated alcohols. Therefore, it is desirable to find catalysts which are able to control the intramolecular selectivity by hydrogenation preferentially the C=O group while keeping the olefinic double bond intact (Fig. 1).

Oct 1, 2003

By E. R. Packer

"The mill of Anaconda Britannia Mines is located on the eastern shore of Howe Sound, approximately 32 miles north of Vancouver, British Columbia. The mill has a daily capacity of 3400 to 3500 tons and at the present is treating chalcopyrite-pyrite ore from which only the copper mineral is concentrated. For a clear conception of concentrate filtering and shipping practice at Britannia perhaps a bit of past history should be related.For many years the mill concentrated copper and zinc minerals and intermittently a pyrite concentrate was produced. It was general practice to ship copper concentrate by towed barge down Howe Sound, across Juan de Fuca Strait and thence down Puget Sound to Asarco's smelter at Tacoma, Washington. Zinc concentrate was loaded in hopper bottom rail gondolas spotted on rail barges and towed to rail heads in Vancouver, thence by rail to Anaconda Reduction Works in Great Falls, Montana. Most of the pyrite produced was shipped by ocean freighters to Japan and Taiwan with an occasional barge load of 2000 to 4000 tons to nearby customers in Vancouver and the state of Washington.In recent years, because of smelter shut-downs for one reason or another, mostly strikes, a considerable amount of copper concentrates has been shipped by ocean freight to Japan and in 1971 several lots were loaded in gondola cars and shipped by rail to the Anaconda smelter in Anaconda, Montana, because Asarco's smelter was forced by municipal and state anti-pollution laws to limit the amount of S02 emission from the smelter stacks. Zinc concentrate production was halted in the early part of 1Y70 because of zinc depletion in the ores and pyrite production was stopped in May, 1971, because of a lack of markets.Filter equipment in the Britannia mill consists of conventional disc vacuum filters and reciprocating vacuum pumps. The copper concentrate filter was installed in 1923 as a 6 x 8'6"" American disc type manufactured by United Filter Corporation, The zinc concentrate filter, now converted as a spare for copper concentrates, is also a 6 x 8'611 American disc manufactured by Traylor Engineering and Manufacturing Company and was installed the same year. Formerly, there were, in addition, two 4 x 6' disc filters for pyrite and two 6 x 6' disc filters to de-water bulk flotation concentrates ahead of the regrind mills. Installed vacuum pumps were two Ingersoll Rand 22"" x 811 and one 22"" x 9"". One of the smaller machines has since been scrapped.At the time of the writer's transfer to Britannia in 1965, the entire filter system was operating as a unit using two vacuum pumps and a common filtrate tank with a 2"" SRL filtrate pump for five operating filters. The regrind and pyrite filters were in continuous operation and the co11p('r concentrate filter alternated with the zinc concentrate filter because both copper and zinc concentrates were transp0rted to storage by the same conveyor belt."

Jan 1, 1972

By Maureen E. Lipkewich

Education builds long term awareness, acceptance and support for responsible mineral resource development. The MABC Education Program is an award winning education partnership with British Columbia classroom teachers that has helped over 5400 teachers with resources and other learning opportunities. Each year, thousands of students begin, and continue, to learn about our modern mineral industry as a result of this teacher-written program. The CIM network has an integral role in the future of mineral education in today?s classrooms in Canada and programs of this caliber are vital to our future. The industry needs help in raising awareness of the benefits of modern mining and teachers need help in acquiring that information.

May 1, 2002

By G G. Suffel

T HESE remarks on the occurrence of strata-bound massive sulphide deposits are submitted be-cause the writer recently visited the principal Cyprus deposits (in January, 1965) and has also a back-ground of many years spent largely in detailed observation and map-ping of the Horne and Amulet ore-bodies, now largely inaccessible. They are particularly related to the Symposium papers (September Bulletin) by Hutchinson and by Roscoe. Some comments are offered on the cupriferous pyrite deposits of Cyprus. As the writer is currently reviewing the published literature on the related deposits in Turkey, a brief account of some characteristic Anatolian sulphide occurrences is given. The discussion is closed with some thoughts on the relationship between these Mediterranean sulphide deposits and those of northwestern Quebec and the Superior province in general. The geology of Cyprus, as it relates to the sulphide deposits, is well summarized by Hutchinson (1965). After visiting Mavrovouni, Skouriotissa and Limni and after much thought on the possible ge-nesis of these ores, it seems quite logical to me that he is right. They are indeed closely related to late-stage submarine volcanism.

Jan 1, 1965

By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By E. Lee Cameron

The old mine workings on four barite-fluorite veins of the Lake Ainslie district, Nova Scotia, were opened recently and channel sampled. The samples were then forwarded to the Ore Dressing Laboratories, Bureau of Mines, Ottawa, for chemical analyses. Following the analyses, the sample rejects were combined to form bulk samples, representing ore from each vein, for small-scale batch test work. Tonnage samples from the veins, for pilot mill testing, were submitted when requested by the Bureau. The results of the analyses on the channel samples showed that there are two grades of ore in the di strict, represented, for test purposes, by the Trout River vein and Johnson vein ores. Small-scale and pilot-plant test work was undertaken on both these ores. The Trout River ore is amenable co concentration but, because of the high-barite-co-fluorite-co-calcite ratio, a fluorite concentrate was not obtainable from the Johnson vein ore as received. However, Johnson ore blended in a 1 :1 ratio with Trout River ore gave a mill feed that was readily concentrated. The test work on these ores showed that the following concentrates are obtainable : (a) A barite concentrate, with a recovery of 85 to 95 per cent of the available barite, analysing 93 co 96 per cent BaS04, 4 co 6 per cent CaF,, and 0.5 co 2 per cent CaCO3. (b) A fluorite concentrate, with a recovery of 80 co 85 per cent of the available fluorite, analysing 94 to 97 per cent CaF, , 1 to 3 per cent BaSO., and 1 to 3 per cent CaCO3

Jan 1, 1945

By E. Roman, M. Brissette

"For its end of life, Kemess Mine processed its difficult-to-treat hypogene ore from the east pit, which is a lower grade copper and higher pyrite content gold ore. Metallurgical testwork showed that improvement was possible with finer grinding. In July 2010, small grinding media were introduced into the regrind mill resulting to a nearly 50% decrease of the power draw with a finer grind, an increase of 1.1% in the final copper grade, an increase of 1.2% in copper and 2.9% in gold recoveries at the cleaners. The overall recoveries of copper and gold increased by 0.6% and 1.3% respectively.INTRODUCTION Kemess Mine was located at 430 km North West of Prince George in North Central British Colombia. Its production started in May 1998 by Royal Oak Mines and was acquired by Northgate Exploration in 2000. Kemess reached its end of life production with its last of production on March 9th, 2011. The concentrator nominal capacity was 56,000 TPD consisting of a primary gyratory crusher feeding two identical conventional SAB circuits totalizing 35,840 kW available for grinding. Rougher flotation consists of four parallel rows of eight 130 m³ tank cells to produce a concentrate of 2% Cu and 6 gr/t Au which was pumped to a 5 m x 10.8 m regrind ball mill. The regrind installed power was 4,480 kW to generate a final grind of 80% passing 40 microns. This product fed the two stage cleaner flotation circuit, first stage being two parallel rows conventional 17 m³ Denver cells and second stage, two 3.3 m x 11.0 m flotation columns in series, designed and constructed by Kemess, to produce a 22% copper concentrate grade. The cleaner flotation middlings were returned back to the regrind mill (Froehling, Mohns, Roman & Grady, 2005; Froehling, Mohns, Rajwani & Fullam, 2007). The large copper-gold porphyry deposit was composed of 15% of oxidized supergene and leach cap ore and 85% of hypogene ore having three major alteration zones, mainly characterized by their sulphur/sulphide content. Chalcopyrite is the main copper mineral species with minor bornite. Gold was mainly present as free gold or electrum. The first alteration zone consisted of a phyllic alteration characterized by moderate and intense sericite alteration which had the highest mill throughput and twice the mine grade when in contact with the supergene horizon. The second zone consisted of a potassic alteration characterized by more competent groundmass and moderate to intense quartz stockwork which had a slightly lower mill throughput. Finally, a third alteration found beneath and on the east side of the deposit having almost no quartz stockwork and hardened groundmass, sulphide content is two to four times more. This zone had the lower mill throughput with significant drop in the mine average gold and copper grade. Through its mine life, the average life of mine copper head grade was 0.21% Cu and 0.64 gr/t Au. Head grades began to decrease from 2008 to be substantially lower in 2011 as shown in Table 1."

Jan 1, 2012

By Andrew Chapman

The scope of the SA (Situational Awareness) working group is to analyze the effectiveness of information delivery systems in mining equipment and develop a unified display design, to mitigate against the proliferation of screens within equipment cabs. This working group comprises a variety of stakeholders representing a cross-section of relevant mining and mining-related organizations. This stakeholder network will help guide the direction of the working group towards a common, mutually beneficial end. For now, the focus is on shovel displays; however it should be noted that this work is expected to form the foundation for similar work with other equipment in the future.

Aug 1, 2013

By G. Kipouros, M. Dadvand, A. Dadvand

"A novel methodology was developed to obtain a 3D porous layer with a high aspect ratio of porosity on a titanium electrode. The porous structure allowed more active material such as hydrous ruthenium oxide to be accommodated during the fabrication of the supercapacitor, resulting in an exceptionally high capacitance per surface area. The electrode demonstrated a remarkably high capacitance of 4,800 mF/cm2. The porous layer was composed of functionalized nanoparticles of TiO2 organized in a perfect 3D hexagonal close-packed array that resulted in a highly porous 3D structure. The layer was used as a template to electrolessly deposit a thin layer of silver prior to the electrodeposition of active material. KEYWORDS Capacitance, Porous, Ruthenium, Silver, Supercapacitor, Titanium RÉSUMÉ Une méthodologie innovante a été mise au point afin d’obtenir une couche poreuse tridimensionnelle (3D) affichant un rapport d’aspect élevé en termes de porosité sur une électrode en titane. La structure poreuse permet d’utiliser une matière plus active telle que l’oxyde de ruthénium hydraté durant la fabrication du supercondensateur, ce qui se traduit par une capacité exceptionnellement élevée par surface active. L’électrode affichait une capacité remarquablement élevée de 4 800 mF/cm2. La couche poreuse était composée de nanoparticules fonctionnalisées de dioxyde de titane (TiO2) organisées dans un arrangement regroupé parfaitement hexagonal en 3D, qui a engendré une structure en 3D hautement poreuse. Cette couche a servi de modèle pour le dépôt autocatalytique d’une fine couche d’argent avant l’électrodéposition de la matière active. MOTS CLÉS argent, capacité, poreux, ruthénium, supercondensateur, titaneINTRODUCTION There is a growing demand for integrating compact energy storage elements into electronic circuits due to the miniaturization of electronic circuits, sensors, and actuators, and the increasing importance of portable and wear-able devices incorporating more advanced electronic technologies that operate in controlled or uncontrolled environments to gather, process, store, and communicate information (Deng, Ji, Chen, & Banks, 2011; Beidaghi & Wang, 2012; Chen, Ramachandran, Mani, & Saraswathi, 2014). The manufacturing of compact energy storage elements needs to be compatible with the electronic circuit microfabrication processes. Recently, interest in integrating miniaturized supercapacitors into electronic circuits has increased due to their high charge–discharge rate and long operating life; however, ultra-high power miniaturized supercapacitors suffer from low energy density, hence requiring significant enhancement in their energy density for various applications (Deng et al., 2011; Beidaghi & Wang, 2012; Chen et al., 2014)."

Jan 1, 2019

By Robert G. Boutilier

So far, most social performance monitoring systems have not gone beyond listing the impacts on various stakeholders. Executives have had to rely on intuition to devise interventions that would improve the impacts. This paper describes a survey process, known as the Stakeholder 360 (S360), which eliminates much of the guesswork. The paper reviews key studies showing that raising the levels of communication, trust, and common vision among stakeholders leads to the acquisition of the resources needed to improve the socio-economic situation. Therefore, the Stakeholder 360 measures the levels of these three factors in the relationships between a company and its stakeholders, and among the stakeholders themselves. In a validation study at a gold mine in rural Papua New Guinea, the S360 produced a socio-political ?roadmap? that showed management and stakeholders alike which relationships need more communication, trust, or common goals/vision. Management used the findings to create alliances that helped the government move forward on a regulatory regime for the mine closure. The community used the findings to focus its planning for life after the closure. An S360 survey conducted six months later revealed a decline in dependence on the mine and an overall increase in levels of mutual understanding.

May 1, 2002

By X. Louw

"This paper examines the change in surface properties of the Polyurea used on spirals at different operational times: unused spiral, 28 months in operation and 58 months in operation. This is being done to investigate the alleged statement that spirals have a decrease in spiral separation efficiency after a certain period of operational time. Observing the surface characteristics under 1.5x and 36x magnification it can be concluded that the surface roughness decreases with increased operational time. This may be explained by a decrease in air inclusions and streak lines as the spiral surface wears. Decreased surface roughness should in theory have a beneficial effect on spiral separation performance. This leads to the conclusion that if a decrease in spiral separation performance is observed after a certain period of operation, it can’t be attributed to the change in surface properties. Uneven wear of the spiral surface, material creep or application of force to the spiral will change the profile of the spiral and could cause an adverse effect on spiral separation performance. The metallurgical test work showed that the best results are obtained at 30 - 35% solids by mass in the spiral feed. The iron recovery was significantly higher in the new spiral in comparison to the 2012 and 2010 spirals. The mass yield to concentrate in the new spiral was approximately three times more than for the older spirals. In conclusion, the yield combined with the grade, which equals the recovery was the best for the new spiral.IntroductionAn investigation was launched to research the common belief that spirals experience a decrease in efficiency, and therefore recovery, after a certain period of operation (a period of seven years has been used in the industry). The properties of the spiral that may have an effect on the efficiency are:"

Jan 1, 2017

By W. R. McClelland

GOLD-BEARING ores, representing many types, are found widely distributed through the Province of British Columbia. They range from those which by their nature may be considered as complex, to those whose mineral characteristics are simple. Those in which the gold is associated with metallic sulphides provide particular milling and metallurgical problems, the solution of which involves not only detailed laboratory investigation but also a careful consideration of economic factors. The location of an ore-body may have a deciding influence on the adoption of a method for the metallurgical treatment. Whether the ore should be treated with the object of recovering the gold as bullion or as a shipping concentrate is often dependent on such topographical considerations as the position of the mine at or near tidewater or within a reasonable overland distance of a smelter. British Columbia is fortunate in having the Trail smelter situated in the southern part of the Province, and the smelter at Tacoma, Washington, is accessible for coastwise traffic. Both of these provide a ready market for most types of gold-bearing concentrate. In order that the results obtained by laboratory tests may give a fair indication of what should follow in mill operation, it is essential that the test sample should represent as closely as possible in mineralogical character and in grade the ore that eventually will constitute the feed to the mill. In the early stages of mine development this consideration is sometimes overlooked and samples of a much higher grade than would be representative of run-of-mine ore are submitted. Flotation tests on such a sample of ore high in sulphides may show a low ratio of concentration, bu.t if the actual run-of-mine ore is lower in sulphides the mill operation will reveal a much higher ratio. The recommendations for treatment based on the results of laboratory tests may have been against concentration, when in actual operation this would be the most suitable method of treatment. Recommendations based on laboratory tests are necessarily from the results of work carried out on the sample submitted, modified only by such other economic or topographical information as may be known to the investigator. This paper deals with a few of the gold ores found in the six mining districts of British Columbia and is based on investigations made in the Ore Dressing and Metallurgical Laboratories of the Mines Branch, Department of Mines, Ottawa.

Jan 1, 1937

By Philippe Angers

This article analyzes the social acceptability process of a mining project located in an existing city. It will explore how the principles of sustainable development have been integrated in the project of the Canadian Malartic open pit mine held by the Osisko Mining Corporation, and the corporate social responsibility (CSR) initiatives proposed to strengthen the social acceptability of the project. This mine is located on the ancient south quarter of Malartic and has required the displacement of hundred of houses and five institutions. The location and the inherent social impacts generated by the relocation of the citizens of the south quarter makes this case particularly interesting to understand social dynamics in an era of environmental consciousness. These major constraints of the mine generate high expectations within the urban population with regard to the social and economic benefits it will receive from the project. In a context where society demands higher CSR from the corporation, Osisko is closely followed regarding their actions toward the sustainable development principles to see if they respect the environment and the desires of the community. From the beginning, the company had to be a model of sustainable development in various aspects reflected by the manifold interest of the population. To understand the endeavor made by the company to fulfill the demand of CSR, we will analyze how the company understood sustainable development principles and what CSR initiatives Osisko company put forward. We will explore the involvement of the company in various social aspects like employment, employee satisfaction, and the level of commitment to non-discrimination policy in employment, notably with the native populations. We will also take a closer look at the relationship built by the company with the community and the level of commitment with the various stakeholders of the community. In this way, we will be able to seize the level of involvement of the company in the fulfillment of the principles of sustainable development toward a higher CSR, and to specify the trajectory adopted to build social acceptance.

Aug 1, 2013

By Michael P. Amsden

"THE ECSTALL CONCENTRATOR is situated adjacent to Highway 101 and the Ontario Northland Railroad, 15 miles east of Timmins, Ontario. Ore is delivered to the concentrator by rail from the mine, which is 17 miles northwest of the plant. Power and fuel are obtained from the hydro and natural gas lines which pass close to the plant site. Water is obtained from the Frederickhouse River, 6 miles east of the concentrator. The main concentrator building is a large structure 500 by 640 feet by 90 feet high and contains facilities for fine crushing, crushed ore storage, grinding, flotation, tin recovery, concentrate handling and reagent handling. Located in the same building are the machine shop, warehouse, metallurgical laboratory, pilot plant, men's change room, sample preparation area and an assay laboratory. The general concentrator layout is shown in Figure 47. Originally designed to handle 9,000 tons per day, the concentrator now treats 10,000 tons per day. Two different ore types are processed by selective flotation in three individual circuits to recover copper, lead and zinc concentrates. In 1973, another circuit was added to recover pyrite and tin concentrates from the combined zinc tailings of the three main circuits."

Jan 1, 1974

By R. L. Bailey

"The Acheson D-3 Pool was discovered in August 1950, and contains 88 producing oil wells on 40 acre spacing. Initial oil-in-place was 118 million stock tank barrels and initial well potentials averaged 2,000 barrels per day.In early 1956 studies of hydraulic interference between the Acheson and Leduc D-3 Pools were conducted on the Carter Petroleum Reservoir Analyzer. These studies indicated that the natural water drive to Acheson would be incapable of replacing reasonable withdrawal rates over the life of the pool. To avoid shrinkage losses a scheme of pressure maintenance by water• injection was therefore instituted in March 1957.This pressure maintenance scheme is notable because pressure is being effectively maintained by high volume injection through one well located on the flank of the pool. Close control on reservoir behaviour is maintained by regular bottom-hole pres-sure surveys and observation of water cuts on producing wells. No evidence of pressure gradients or channelling of the injected water has been observed to date, and the water-oil contact has remained level over the whole field. It is possible to control the average reservoir pressure within very close limits by varying the rate of fresh water injection.Ultimate recovery estimated from the rise of the oil-water contact and calculated water influx to December 31, 1958, is 335 barrels per acre foot, or a total of 91.4 million barrels from the pool. This compares to 217 barrels Per acre foot or a total of 59.4 million barrels indicated from laboratory test data."

Jan 1, 1961

By R. H. Sheaphim

THE RECENT and continuing activity in the Boundary district, British Columbia, makes the publication of this paper timely. The following description and discussions are based on two years' experience in the district as Field Manager and Geologist for Attwood Copper Mines, Limited. The Attwood project was organized by Dr. D. F. Kidd to re-examine the Boundary mining camp. Thanks are due to Dr. Kidd, both for his intelligent guidance during the project and for his permission to publish this paper. Much of the data and many of the interpretations presented are credited to the work of, and to discussion with, Dr. W. H. White, Consultant Geologist, who worked for two field seasons on the project. However, the author assumes the responsibility for this presentation. Dr. C. D. A. Dahlstrom worked with the author during the latter stages of the project. His assistance and advice are gratefully acknowledged.

Jan 1, 1956

By J. A. Hansuld

"THIS SESSION marks something of a milestone in that it is, as far as I know, the first session at a CIM Annual Meeting devoted entirely to exploration geochemistry. This is an indication of the general acceptance and widespread recognition by industry of geochemistry in mineral exploration. As a first, I hope it proves sufficiently successful and interesting that geochemical exploration sessions will become a routine part of future CIM annual meetings. The greater use and acceptance of geochemistry has resulted in many investigations and advances, especially in areas such as the Canadian Shield. For a first session on geochemistry, the meeting in Quebec suggested an ideal opportunity to assess these advances and report on the current application of geochemistry in the Shield. The theme of the session is ""Geochemical Exploration in the Canadian Shield - The State of the Art."" A series of six papers will be presented dealing with the various dispersion media - rocks, heavy minerals, ""soils"", lake sediments, waters and vegetation. As a background to the individual presentations, I would like to take a few minutes to briefly trace the history of the use of geochemistry in the Canadian Shield."

Jan 1, 1971

By H. H. Wang

Construction safety documents regulate significant safety actions and requirements by which construction workers or employees should abide in order to secure them from occupational hazard events. Therefore, facilitating faster identification of applicable safety requirements from the documents has become an important topic in the construction safety domain. To address the need in this regard, tools and techniques have been developed and research efforts have been made. One of the research efforts is to utilize ontology, a knowledge representation and reasoning approach, as the methodology to achieve the goal of identifying applicable safety requirements. In such ontology-based researches, the development and construction of the safety concept ontology is an essential task as the concepts and the relationships between the concepts both representing key safety knowledge need to be carefully identified. In this paper, the author focuses on the safety documents without predefined concept structure and aims to address the concept and relationship identification difficulties. Specifically, the author leverages the Formal Concept Analysis (FCA) methodology, a theory of data analysis that identifies conceptual structures among data sets, to mine and analyze the documents in order to discover safety concept structure and to further assist the development of the concept ontology for the construction safety documents. The author expects the application of FCA to construction safety domain can eventually benefit the ontology-based approaches for identification of applicable safety requirements.

Aug 1, 2013

By J. Doucet, C. Price

In an industrial setting, operational changes are continually introduced, driven by new technologies or changing economics. Because of day-to-day variability, quantifying the impact of these changes based on metallurgical performance requires long trial periods to achieve statistically significant results. Tools and techniques developed by the mineral processing group at McGill University have allowed for direct measurement of process variables (e.g., bubble size, gas and solid holdup). Two case studies are described where direct measurement techniques were used to evaluate: a) a new rotor stator mechanism; and b ), the introduction of a new frother type. Application of these methods has accelerated the evaluation of process changes and improved confidence in results.

Jan 1, 2009

By Q. Shi, Q. Feng

"The influence mechanism of chlorite on the flotation of pyrrhotite was investigated through flotation tests, Zeta potential measurements, optical microscope photos, solution ion measurements and absorption measurements. It is observed that, the addition of chlorite influences the flotation of pyrrhotite seriously. The IEP (isoelectric point) of pyrrhotite and chlorite is 7.6 and 4.3 respectively, in the condition of slight alkalinity, both pyrrhotite and chlorite are negatively charged, and the hetero-aggregation will not occur. With the existence of oxygen in solution, the iron ions are dissolved from pyrrhotite surface because of the oxidation of pyrrhotite during pulp conditioning. The dissolved iron ions adsorb onto the surface of chlorite in the forms of iron hydroxyl and iron hydroxide, and the adsorption results in the opposite charge of chlorite surface. As a result, the hetero-aggregation between pyrrhotite and chlorite occurs. The adsorption of chlorite changes the surface property of pyrrhotite and restricts the adsorption of amyl xanthate onto pyrrhotite surface, and then decreases the flotability of pyrrhotite.INTRODUCTIONIn sulfide ores processing, magnesium silicate bearing gangue minerals often report to the concentrate causing downstream processing problems as well as increased smelting costs. Talc,chlorite and serpentine are gangue minerals commonly encountered in complex sulfide ores (Engel, Middlebrook, & Jameson, 1997; Pietrobon et al., 1997; Witney & Yan, 1997; Chen, Grano, Sobieraj, & Ralston, 1999a, 1999b; Bremmell, Fornasiero & Ralston, 2005; Senior & Thomas, 2005; Wang, Somasundaran, & Nagaraj, 2005; WieseHarris & Bradshaw, 2007). All of them are characterized with uniform crystal structures consisting of silicon-oxygen tetrahedron and magnesium-oxygen octahedron. The magnesium-oxygen octahedron layers are broken during the liberation of serpentine to expose the magnesium-oxygen bonds with strong ionicity and hydration, which results in natural hydrophilicity of serpentine. In water, the hydroxyl on serpentine surface ruptures and dissolves into the aqueous phase while the Mg2+ remains, resulting in surface positive charge (Tao, 2012). As serpentine has a positive potential at alkaline condition, it is therefore likely that it will attach through electrostatic attraction to the negatively charged mineral surface and reduce both the flotation rate and recovery of target minerals (Lu et al., 2011). For talc, characterized as good natural hydrophobicity, the liberation comes from the interlaminar fracture to remain molecular bonds on surface with weak hydration. Being naturally hydrophobic, talc easily reports to flotation concentrates, thus reducing concentrate grade (Shortridge, Harris, Bradshaw, & Koopal, 2000; Beattie, Huynh, Kaggwa, & Ralston, 2006). Meanwhile, both molecular bonds and magnesium-oxygen bonds are exposed on chlorite surface when liberation occurs, resulting in moderate natural hydrophobicity between serpentine and talc (Tao, 2012). And thus the mechanisms of influence of chlorite on sulfide ores are more difficult to study."

Jan 1, 2016