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By P. -Q. Wu

A modified electrochemical noise (EN) technique has been applied to monitor corrosion wear of TiN-coated ASP23 steel and TiN-coated AISI 316 stainless steel sliding against corundum in 0.5 M H2SO4. Experimental results show that the EN technique can sensitively detect potential and current variations during a corrosion-wear process. Corrosion-wear mechanisms of TiN coatings depend on their substrate properties. If the substrate is passive, such as AISI 316 stainless steel, the potential and current variations reflect the properties of the coating. Depassivation and repassivation alternately take place on the tribo-activated wear area during the steady-state phase. If the substrate is active, such as ASP23 tool steel, the electrochemical noise is dominated by dissolution of the substrate at the pinholes and the hydrogen evolution all over the exposed surface.

Jan 1, 2005

By C. Schlumberger

INTRODUCTION The object of the present paper is to discuss, from a geological point of view, the practical results obtained by the authors with the method of the 'resistivity map of the subsoil' in the study of various mining problems. Some of the studies described date from 1920, 1922, and 1923. They are, therefore, quite old, at least as far as geophysical research is concerned (1). Others, on the contrary, are very recent (2). We shall deal only very briefly with the theoretical and technical sides of the processes employed. This paper has, essentially, a practical purpose, and it has seemed unnecessary to enter into a detailed discussion of the methods. Such a discussion cannot be presented without introducing ,quite. Complex considerations both of mathematics and experimental physics, which interest only the geophysicist: whose work is highly specialized.

Jan 1, 1931

The recovery of fine hydrophilic gangue in flotation is related to the recovery of water. Water is carried by bubbles as a film and wake into the froth. The amount carried (entrained) depends on bubble size, gas rate and the subject of this paper, frother type. To isolate the effect of frother type from that of bubble size and gas rate, gas holdup is used as the correlating variable. Measurements were made using a bubble column (no solids) operated continuously with the overflow recycled. Continuous operation meant some foam depth was required to ensure only entrained water is recovered. Using an automatically controlled 7cm foam depth the overflow rate of water is used as a measure of 'water carrying rate'. It is shown that the common frothers can be grouped into four families based on the water carrying rate-gas holdup relationship.

Jan 1, 2006

By R. O. Suzuki, S. Natsui, R. Nashimoto, T. Kumagai, T. Kikuchi, H. Takai

A newly developed computational fluid dynamics model based on a multi-phase particle simulation is presented for predicting the entrainment behavior of liquid metal into slag due to rising single bubble. By comparing results calculated using this model against experimental data, it was found that the transient behavior of bubbles and the two immiscible liquids can be accurately estimated by this method. The rupturing of the thin water film surrounding the bubble was less reliably predicted, but this 3-dimensional unsteady numerical model still nevertheless provides valuable new information for directly predicting the change in the liquid-liquid interface over time. This model predicted the Young-Laplace pressure, and the interface shape was simulated with volume conservation using this model as opposed to the conventional particle method. This simulation model can calculate both of dispersed phase and continuous phase seamlessly.

Jan 1, 2015

By Q. G. Reynolds, R. T. Jones

The choice of furnace design parameters has a marked effect on the integrity of the furnace that is constructed. The design methodology for DC arc furnaces typically begins with the chemical reactions and feed materials that define the process. The specific energy requirement of the process, and the feedrates of the raw materials largely determine the power requirement for the furnace. A chosen value for the 'power intensity' sets the diameter of the furnace. Justification is provided for why this is a good choice of scale-up parameter. Equations are presented to quantify the resulting trade-off between thermal efficiency and the degree of error that can be tolerated in the balance between power and feedrate. This improved understanding should provide a better rationale for selecting an appropriate power intensity (or furnace diameter) for future furnaces.

Jan 1, 2015

By R Zavadil, S Kuyucak, F Fazeli

Proton exchange membrane (PEM) fuel cells generate electricity by reacting hydrogen and oxygen. A thin, bipolar electrode material provides a medium for electron exchange with the electrolyte, alternately serving as anode at the hydrogen-rich side and cathode at the oxygen-rich side. Stainless steels have sufficient corrosion resistance to qualify as bipolar plate materials. However, the protective chromite layer increases the contact resistance, the battery’s internal resistance; and thus, decreases the electrical efficiency of the fuel cell. A heat-treatment is proposed and investigated via simulation by ThermoCalc / Dictra and experimentally, to generate a sufficient quantity of conducting surface carbides that breach the protective layer. Once carbide growth is arrested, a subsequent heat-treatment is also needed at a higher temperature to restore the corrosion resistance by filling-in the Cr-depleted layer (sensitization) around the carbide particles.

Jan 1, 2014

By B. Jin

Removal of fluoride and chloride by alkaline washing from direct lead smelting dust which originated from an Ausmelt furnace is reported. The results show that the fluoride removal efficiency increases with an increase of alkaline concentration, alkaline washing temperature and time. The L/S ratio has little effect on fluoride and chloride removal efficiency. A new flow sheet for removal of fluoride and chloride from the dust was successfully proposed according to the results. Fluoride and chloride removal efficiencies are more than 53.68% and 63.18% respectively using the flow sheet under the optimum parameters of temperature 338 K, L/S ratio 3:1 and alkaline washing time of 1.5 h. The contents of fluoride and chloride in the alkaline washing residues can meet the standard of zinc purity as hydrometallurgical materials for zinc processing.

Jan 1, 2014

By M. T. Ho, D. E. Wiley

The iron and steel industry accounts for almost 5 % of the total world CO2 emissions. Optimisation of the steelmaking process has led to significant reductions in the energy intensity to the point where it is now close to the thermodynamic limit. Further reductions are not likely to be achieved with efficiency improvement alone and will require the development of novel or breakthrough technologies. This paper will show the costs of implementing CO2 capture at direct atmospheric emission points for a number of iron and steel production processes. These include a conventional process, top gas recycling processes, the Corex and Hismelt smelt reduction processes and the Midrex direct reduction process. Depending on the point source emission, costs of capture with existing chemical absorption technology at iron and steel plants can be similar to capturing CO2 at pulverised coal fired power plants.

Jan 1, 2015

By J. S. Stachulak, K. A. Mackinnon

This paper deals with specifying and evaluating fans for mine ventilation projects. Topics such as fan and equipment design life, operating points, and operating conditions are discussed. Common operating problems, such as vibration, parallel operation, mechanical failure, erosion, corrosion, and deficient fan performance are covered. Apart from identifying the potential operating problems, likely causes and suggested remedies are given. Fan type, fan accessories, and likely system effects and fan testing are discussed. Suggestions on what should be covered when evaluating different fan options and proposals and suggestions on the verification of supplier claims and guarantees, including cost of operation, the evaluation of initial capital cost, estimate on maintenance costs, and likely replacement expenditure over the life of the fans. In addition, fan reliability, operational flexibility, suggested construction details and fan vendor past history and experience are reviewed.

Jan 1, 2004

By Bassam Kattaa

"Abstract - A heavy mineral survey of beach and dune sands including geochemical analysis for trace elements was undertaken to evaluate the economic potential of the sands and to understand the nature and distribution of the heavy minerals relative to potential source rocks. Results indicate that heavy minerals are generally derived from outcropping volcanic rocks that comprise a proportion of the hinterland in the south part of our survey area. The most abundant minerals are magnetite and pyroxene. The morphologies of the heavy mineral grains are angular to subangular, suggesting that they were transported short distances from the source rocks. Factors controlling heavy mineral distributions include wave and wind action, proximity to provenance, the fluvial drainage network, and longshore currrents.The most economically important mineral is ilmenite. Zircon and rutile concentrations are relatively minor and thus have lower economic potential."

Jan 1, 2002

By I. Colquhoun

Current practice tends towards "integrity as an afterthought". That is, integrity is treated as an isolated aspect of operations and maintenance. In fact, this works quite well. But it would work so much better and with less uncertainty if integrity management measures were introduced at the design phase and addressed the entire life-cycle of the pipeline asset. The talk will address the measures and metrics that can be implemented on a new pipeline during design to optimize integrity and deliver a comprehensive operating manual and integrity management program for the pipeline system. This deliverable should describe the risks to be assessed and monitored, and the actions to be taken to control these risk adequately. Properly executed, integrity by design will provide a good working estimate of the life-cycle integrity management costs and maximize system reliability.

Jan 1, 2005

By Frank S. Palkovits

Over the past 30 years, underground paste backfill systems have been implemented across the globe in many configurations, each with a primary focus of providing high quality backfill to enhance mine operations. However, a number of key design drivers are not always well understood within design engineering firms that occasionally undertake this work, leaving opportunities on the table. Perhaps not always obvious to those newly embracing paste technology, identifying key drivers and opportunities attainable through a paste backfill system is generally not straightforward, requiring innovative approaches to securing higher productivity, availability, performance, maintainability, and operator health and safety. This paper describes a number of applications and audits of paste backfill systems for several challenging mine operations. Key challenges include iterative design aspects of availability of good backfill materials, plant location and configuration, general arrangement, and binder receiving/storage systems.

Oct 1, 2010

By J. E. Dutrizac

A pyritic Zn-Pb-Cu ore waspercolation leached with acidified ferric sulphate solutions; zinc and copper were leached, lead was oxidized, but not dissolved, and pyrtte was essentially unattacked. High zinc extractions were achieved after a few months leaching, and substantial zinc solution concentrations could be produced by recycle of the oxidized solution. The leaching rate was generally controlled by the transport of the ferric sulphate oxidant. Zinc extractions increased with increasingferric ion concentration or flow rate, but were essentially independent of the concentrations of sulphuric acid, ferrous sulphate, cupric sulphate or chloride ion. The leaching rates were insensitive to the height of the ore column once a minimum height had been exceeded (0.8-1.0 m). Elemental sulphur was the principal sulphidic reaction product, but variations in the ratio of sulphur to sulphate produced anomalous temperature effects.

Jan 1, 1979

By B. Farabi Khoshmehr

In the present study the effect of Silicate Sodium oxidation agent concentration and Plasma Electrolytic Oxidation (PEO) treatment time were investigated on properties of oxide layer on Aluminum alloy. The phase composition and surface morphology of PEO films were evaluated through x-ray diffraction (XRD) and scanning electron microscopy (SEM). Pin on Plate abrasive machine were used to investigate of were resistance of coating. The results showed that oxide layer which formed on Aluminum surface consist of high temperature a- Al?O? and ?- Al?O? phases. The diffraction peak intensity and percentage of these phases were increased by increasing silicate sodium concentration. Microscopic studies revealed a porous surface for PEO coating. This was affected by silicate sodium concentration and oxidation time. The wear test results showed that the weight loss of PEO coating was reduced due to improvement of their wear resistance.

Oct 1, 2011

By M. X. Yao, C. D. Opris, P. C. Patnaik, R. Liu, X. J. Wu

Two cobalt-based superalloys, Stellite 694 and Stellite 712, were functionally graded with reinforcement of titanium-carbide particle for high-temperature wear/corrosion applications. The designed composite specimens were fabricated using powder metallurgy (P/M) technique, combined with hot isostatic pressing (HIP). Calorimetric effects of the alloy powders were investigated using the differential scanning calorimetry (DSC) technique, which provided the basis of the sintering cycles designed. The phases present in the microstructures of the materials were analyzed using SEM and X-ray diffraction. The wear resistance of the materials was evaluated on a pin-on-disc tribometer. It was demonstrated that adding titanium-carbide particles to the alloys has increased significantly their wear resistance. It was also found that the HIP process had improved the density of the sintered specimens and thus enhanced their wear resistance.

Jan 1, 2004

By Robert J. McCarthy

There are two things on everyone's lips when mining folks gather these days - one is the exciting business opportunities that now exist for mine development and expansion, and the other is the dire shortage of human resources needed to design, manage, and even operate the mines. Years of stagnant industry growth, limited employment opportunities, and unwarranted perceptions of remote and harsh working conditions have caused mining to be a less than desirable career choice. Attrition and reduced entry to the workforce has resulted in shortages for not only mining professionals, but also skilled trades people and operators. Consequently, to survive, let alone grow, mining companies, suppliers, and educators are all pursuing innovative solutions with technology, inter-industry recruiting, centralized services, and strategic partnerships. This paper describes some of these initiatives and proposes others, now that the people are gone!

May 1, 2008

By A. Morales

Flue dusts from a copper smelting furnace (continuous furnace), have been extensively characterized. The main phases detected have been cuprospinel, anhydrous copper sulfate (chalcocyanite), lead sulfate (anglesite) and arsenic oxides (claudetite and arsenolite). As minor phases, zinc sulfate (zincosite) and several copper or copper/iron sulfides were detected (digenite, anilite, bornite, cubanite), and also a copper oxide (tenorite). The suspension of this material in water leads to the partial dissolution of copper and zinc (chalcocyanite and zincosite) and arsenic oxides. The hydrocyclone classification of the residue makes it possible to obtain two fractions: a copper-rich coarse fraction and an arsenic-rich fine fraction. The coarse fraction can be recycled to the smelting furnace and the fine fraction can be mixed with wastewater sludge from a paper factory, to make both residues inert before disposing them to landfill.

Jan 1, 2007

By M. Reza Bateni, M. Zandrahimi, J. A. Szpunar

Titanium aluminides and nickel aluminides offer the potentials, as coating materials, for high temperature and aerospace applications. In this research, attempt has been made to develop Al-Ti and Ni-Al intermetallic compound coatings on the surface of Inconel 738. The coatings applied through pack cementation and simultaneous diffusion annealing processes. Scanning-electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX) and grazing angle X-ray diffraction were used for evaluating of coating structure. It was demonstrated that the pack cementation technique could be used to develop TiAl3 and AlNi intermetallic compounds coating on Inconel 738 substrate. When pack cementation technique is based on a halide-activated pack with aluminum and titanium powders, the coating consists of TiAl3 intermetallic compound phase. Whereas, by pack aluminization of Inconel 738, the coating consists of AlNi intermetallic compound phase.

Jan 1, 2004

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By M. Bueno

Between 1993 and 2003, a series of AG and SAG mill pilot plant trials were conducted using Hardinge Ical pilot plant scale SAG mills on numerous ore samples and ranging across a wide variety of operating conditions. The data from these tests were used to evaluate the design of SAG and AG mill circuits for over a dozen projects, of which about half were eventually constructed and commissioned. The data were also used in the development of SAG mill modelling, scale-up and simulation procedures by several consultants who had access to part of the data set. Recently, we have had the opportunity to bring this data together and further analyse the consolidated dataset. This paper reports on the outcomes of this analysis that has identified the impacts of different AG/SAG circuit flowsheets and operating conditions on energy efficiency and operating cost.

Jan 1, 2012