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A key point in the manufacture of cemented backfill is the dewatering and settlement of the total tailings product. A new technology characterized by rapid non-mechanical settlement of total tailings has been developed based on a large number of laboratory and field tests, where dynamic settlement and continual slurry preparation of total tailings in a vertical sand silo are realized by the addition of an effective flocculating agent named NPA. It has been shown that the sedimentation velocity of the interface between total tailings and water after NPA was added is 10 to 20 times higher than that without any flocculating agent, that the mass fraction of sand slurry deposited at the bottom of the vertical sand silo reaches 70%, and that the solid particle content in effluent waste water meets national water quality standards. The simple devices used to add flocculants have little deleterious effects on the current preparation tank and have been tested in an industrial environment. The processing cost of total tailings by the new technology is only 10% to 20% of that required for mechanical settlement.

May 1, 2007

By N. Hmidi, T. Yalcin, M. Papadakis, B. Hilscher

Mill tailings, containing iron sulphides in particular, pose an environmental concern since they constitute a potential source of acid mine drainage which can damage vegetation, harm soil and living organisms, and contaminate groundwaters. Proper disposal of acid generating tailings is therefore an important issue that must be addressed and resolved in a satisfactory manner. Placer Dome Canada operates a 4000 t/d gold cyanidation facility at Musselwhite mine, in northwestern Ontario, where the mill tailings have been classified as acid generating. This study was conducted to explore the effectiveness of froth flotation in removing the sulphide minerals from these tailings and producing a low-sulphur, non-acid generating material that could serve as a capping material for previously deposited tailings. Laboratory semi-batch flotation tests were carried out in accordance with an experimental design procedure, and a computer simulation program was developed to facilitate the evaluation of flotation performance. In this investigation, pH, collector concentration, and airflow rate were considered as the relevant flotation variables, and their effects were examined both experimentally and by simulation. Results have demonstrated that flotation can successfully desulphurize the Musselwhite mine tailings and render them non-acid generating.

Jan 1, 2004

By Ian R. Muirhead

Over the past year or so, a number of mining companies have been meeting to examine the role of research in surface mining and, in particular, how to establish a collaborative research effort for the surface mining industry. A review has been completed which has identified the topics that are of interest to the surface mining companies for undertaking collaborative research. This has identified key subject areas such as Operations & Equipment; Maintenance; Environment & Reclamation; and Stability. Specific research projects for the initial research effort have been selected which include Wireless Data Communications, Analysis and Management; Application of GPS in Mining; and Tires for Heavy Haulers. In addition, attention has also been focussed on finding a suitable low cost, but effective, organization to coordinate and manage the collaborative research. The recently formed CONRAD Organization (Canadian Oilsands Network for Research and Development) appears to be a suitable candidate and discussions are ongoing with that group. This paper provides a summary of the review of surface mining research needs and of the status of the establishment of a collaborative research body for surface mining.

Jan 1, 1996

By Shae K. Kim

The aim of this study is to manufacture magnesium alloys with alkaline earth metal oxides (BeO, CaO, MgO or SrO) additions with the objectives of (1) ensuring safety during processing and applications by raising the ignition temperature and reducing oxidation, (2) protecting the environment by reducing or eliminating use of protective gases, (3) maintaining or improving elevated temperature properties with lower amount of Ca or Sr or rare earth metals when compared with conventionally developed high-temperature magnesium alloys, (4) developing cleaner strip casting and continuous casting processes without hot tearing and (5) obtaining all of these objectives without sacrificing mechanical properties or increasing the cost of magnesium alloys.

Jan 1, 2006

By M. Drozd, M. Somppi, Z. Yamak

"Granular activated carbon is widely used in the gold mining industry for gold extraction from aurocyanide-containing slurry. The extraction process can employ carbon as part of the gold recovery operation for various circuit designs including carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) circuits. However, various qualities of activated carbon exist and the durability of the material can change significantly from source to source. Handling this expensive reagent can pose challenges when fine carbon losses occur in the CIP, CIC, and CIL circuits. Additionally, any gold that is adsorbed to these carbon fines can also be lost by various mechanisms including carbon attrition and fracturing, inefficient coarse-fine separation, and poor carbon fines capture. With the above in mind, a series of tests were conducted to investigate standardizing simple laboratory methods for testing carbon quality. A standard procedure beyond or enhancing ASTM methods can serve as additional starting points for evaluating carbon specific to the gold industry. The investigation focused on size distribution, flatness, wet attrition resistance, surface area, gold kinetics, and gold loading. The final results provided information to generate an equation for ranking carbon samples to plant performance.IntroductionActivated carbon for use in gold extraction is amongst the most commonly found processes in modern gold-milling plants. Although gold losses are inevitable in the milling process, operators often focus on the importance of maximizing gold recovery. One focus area that is important in gold recovery is optimizing the use of activated carbon and examining potential changes to realize improved economics for carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes."

Jan 1, 2017

By K. Adham

Iron chloride pyrohydrolysis (ICP) is used as an efficient way to fix iron as an oxide, for sale as a by-product or for safe disposal. Iron chloride is reacted with water at elevated temperatures to yield iron oxide and hydrogen chloride. Both the steel industry and synthetic rutile producers make extensive use of ICP. Two technologies are available for ICP: fluidized bed (FB) and spray roaster (SR). Both technologies are energy intensive. Here, fluid beds and spray roasters are compared with respect to their fuel and electrical energy consumptions. Roaster size and oxide product characteristics are also considered. Process models are prepared, using the METSIM® software, and specific energy consumptions are compared. The results will help the industry decide which technology best suits its goals and at what energy cost.

Jan 1, 2006

By Lori Kormos, Jhonny Carrión De la Cruz, Dominic Fragomeni, Elizabeth Whiteman, Jorge Oliveira

"Process diagnosis, flowsheet design and optimisation are most effectively and efficiently achieved through the use of metallurgical testwork combined with more modern quantitative mineralogical techniques. Integration of the mineralogical data in testwork programs provides a resolution that cannot be obtained from assays alone and can direct the flow of work to result in optimized conditions more quickly than would otherwise be possible. At Xstrata Process Support (XPS), QEMSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) and EPMA (Electron Probe Micro Analyser) information can be employed to diagnose specific issues in a plant or lab scale test and are routinely combined with other metallurgical data sets to benchmark performance, design and optimise flowsheets. Representative sampling protocols for ore bodies or test products, the use of geometallurgical unit classification and high confidence metallurgical test programs are key components of the strategy. Two case studies from Xstrata Zinc’s Antamina Mine and Concentrator in Perú, and Xstrata Nickel’s Nickel Rim South Mine in Sudbury are described to show how the use of quantitative mineralogy were used to diagnose a plant issue and how the data can be integrated into metallurgical programs to assist mineral processing engineers to design and optimise flowsheets.INTRODUCTIONOver the past decade, there has been a shift away from metallurgical testing that employs only chemical assays to quantify performance; the use of empirical observation in order to optimise a flowsheet; and the extraction of bulk samples for testing or piloting. The integration of geological information into the planning and execution of testwork programs including the use of quantitative mineralogy has improved the overall quality and predictability of metallurgical programs. At the same time, improvements to metallurgical testwork protocols such as rigorous statistical assessment of results, the use of factorially designed experimental strategies (DOE), and replicate flotation with appropriate quality controls, has improved the confidence level in these results.Process diagnosis, which utilizes quantitative mineralogy, can clearly define the root cause of the metallurgical issue. Whether used on its own to diagnose an issue or in combination with other metallurgical testwork, the use of mineralogical data has become the standard in the mining industry."

Jan 1, 2010

By C. P. Patel

"The Sturgeon Lake Joint Venture volcanic massive sulpide deposit was discovered in 1970. Milling was started by Falconbridge Copper Ltd. at Sturgeon Lake in September 1974. The Sturgeon Lake pit and mill are located 88 kilometers by road northeast of Ignace, Ontario. IgnE1ce is a town of some 2800 people located on the Trans-Canada Highway, 241 kilometers west-northwest of Thunder Bay. The mill is treating an average of 1100 TPD producing separate concentrates of copper, lead and zinc. Initially, difficulties were experienced in achieving accept-able concentrate grades and recoveries but these were eventually overcome. This presentation describes current metallurgical strategy as practiced at the Sturgeon Lake mill.But first, a few words about the type of ore being treated. In geological terms the ore is classified into two main categories. They are the massive sulphides with underlying zones of stringer sulphides as illustrated in Fig. 1. The plan view is shown in Fig. 2. The areas of East-limb and North-limb are as shown. These last two ores have suffered enough alteration to cause problems during treatment. The massive sulphides consist of chalcopyrite, sphalerite, galena, tetrahedrite and small amounts of pyrrhotite among other gangue materials. The stringer ore is comprised of predominantly chalcopyrite intrusions into rhyolite and has lesser amounts of sphalerite and tetrahedrite. At present we are treating a predetermined blend of massive and stringer ores from zones that have been metallurgically tested to ensure compatibility with current treatment procedure in the plant. Ore responding to this treatment is classified as normal ore while the ore proving incompatible is classified as north-limb ore or east-limb ore."

Jan 1, 1980

By M. Churchill, V. R. Degner

"Over the past two decades, declining ore body grades, increased operating costs and increased construction costs have provided an incentive for the development of progressively larger flotation machines. As a consequence, the 60 to 100 cubic foot flotation machine of the l950's and l960's is being rapidly replaced by large volume machines, with a resulting improvement in the flotation machine specific capacity (TPH processed per square foot floor space), specific power (HP per TPH processed) and process control simplicity. The recent development, and satisfactory plant evaluation, of the WEMCO 1000 cubic foot flotation machine provides the means by which further economic and operating advantages may be incorporated in high tonnage mill applications.The systematic development of the large 1000 cubic foot flotation machine, and its subsequent performance evaluation in beneficiating metalliferous ores (copper, zinc and iron) will be reviewed in this paper and recently completed plant results will also be provided."

Jan 1, 1982

By Ilpo O. Auranen

Background: Mines of today are moving ever increasing tonnages of rock. The new ore bodies tend be of lower grade and located deeper in the earth?s crust. The industry?s focus to overcome this ?deeper but poorer? ore problem has traditionally been to lower the costs by increasing the scale of mining. This has resulted in an ever increasing size of mining equipment like drills, loading shovels, dump trucks. The main focus has been in reducing the cost per ton of mining. This cost focus has often resulted in increased waste rock dilution and more ore losses. From costs to value: Waste rock dilution means waste rock in the concentrator feed. It?s value in open pit mining is equal to the value of ore it replaces. In underground mining, waste rock dilution?s value is equal to the value of ore it replaces added to the costs of mining it. It is commonly accepted that waste rock dilution in open pit mining ranges between 5 and 20% and in underground mining between 5 and 40 % . In a typical large open pit mine ore value is from 20 to 60 USD per ton and mining costs are 1 to 3 USD per ton. One percentage point reduction in waste rock dilution represents savings corresponding to about 20% of total mining operation costs. The difficulty of reducing waste rock dilution comes from the complicated nature of the ores. Accurate ore waste-border detection has not been possible due to excessive costs. Core drilling combined with geochemical lab analysis is the most accurate method for locating ore waste borders. However, it is also expensive and time consuming, which is why it is often combined with somewhat lower cost methods like sampling drill cuttings from blasting drill holes or from reverse circulation drills and analyzing them in a laboratory. The main drawback with these methods, in addition high costs, lies in the sampling accuracy and in the quality control of the whole process when a large number of samples have to be handled manually. In every mine it is possible to halve waste rock dilution by using new on-line analysis technology .

Oct 1, 2009

By V. Lakshmanan, Dan Mackie, J. Melnbardis

"Crystalline Flake Graphite is a strategic mineral. Since 1954 nearly all North American consumption has been imported from offshore. The Bouthillier Project in Quebec, Canada, is Orrwell Energy's bid to enter the market, with plans to begin production of a 500 TPD operation in 1984.Milling of flake graphite is considered easy, yet more problems have been encountered in flowsheet and plant design than in most other minerals. A fresh approach to existing technology was taken, giving results that are highly satisfactory. The key to graphite liberation without flake deterioration is found to be in autogeneous grinding. In addition to producing marketable coarse graphite by such autogeneous grinding, flotation and tabling, super purity fines can be produced using repeated regrinding, elutriation and flotation. This paper discusses the design of a 500 TPD plant based upon the results obtained from bench and pilot plant studies. INTROOUCTIONWhen the Black Oonald mine at Calabogie Ontario ceased production in 1954 nearly all North American crystalline flake graphite had to be imported from offshore. Orebodies in the United States were too small or too low in grade to be exploited economically.The Houthillier Township near Mont Laurier in Quebec (Figure 1) was a known graphite-bearing area The Orrwell property in that area was delineated in 1957 Some test work including minor footage of diamond drilling was carried out by Italia Copper and the MHM Syndicate prior to 1981 when Orrwell acquired the property"

Jan 1, 1984

By I. Dimitrov, S. R. McCutcheon

"Industrial-grade limestone is found in both the Lower Silurian La Vieille Formation and Upper Silurian LaPlante Formation of the Chaleurs Group in northern New Brunswick. Currently, between 150 000 and 200 000 tonnes of limestone are produced per year from the proximal facies of the LaPlante Formation at the Sormany quarry of Elmtree Resources Ltd., located west of Bathurst.The proximal facies of the LaPlante Formation was deposited on the margins of tectonically uplifted Ordovician terranes. This facies comprises stromatoporoidal-algal bindstone intercalated with wackestone, packstone, and floatstone in variable proportions. The distal facies comprises calcareous shale and minor limestone deposited deeper offshore.Folding and faulting related to Middle Devonian Acadian tectonism have caused an increase in the apparent thickness of the limestone sequences, especially adjacent to the regional Rocky Brook-Millstream fault. Structural and stratigraphic observations indicate that some of the limestone bodies in the area have been tectonically displaced from their site of deposition.A variety of prospecting techniques was used to locate new limestone resources, including geological mapping, airborne and ground electromagnetic surveys, and satellite remote sensing. Clastic rock units above and below the LaPlante Formation have distinctive properties that help to trace the intervening limestone along strike. Because of water-saturated glacial cover, thick vegetation, and the small size of targets, airborne geophysical methods did not prove effective in delineating limestone beds, but aeromagnetic surveys helped map the underlying clastic unit. The remote-sensing data and especially high-resolution digital elevation models helped in identification of karst topography related to limestone."

Jan 1, 2007

By C. Doucet

Since 2001, CANMET Mining and Mineral Sciences Laboratories (MMSL) have worked with Falconbridge Ltd. (now Xstrata Nickel) to evaluate trends in the strength development and water retention properties of a novel backfill material for underground mining, called gelfill. Between 2004 and 2006, extensive laboratory tests were undertaken under the leadership of the Deep Mining Research Consortium (DMRC). This paper compares results obtained from samples circulated through a mini-flow loop and a simple mixer. Although many parameters were studied over the last five (5) years, this paper focuses on the investigation of the effect of the mixing method, sequence and time, and the curing environment on strength development and water retention of gelfill. It was found that binder should be added as a powder to the mix in the mini-flow loop, and that mixing slurry in the mini-flow loop as opposed to the mixer generally yielded higher strengths. The practical implications of these observations are the subject of an on-going underground trial that will compare laboratory and in situ properties of regular slurry fill with gelfill.

May 1, 2007

By Cz. Mora, A. Pawelczyk, D. Hreniak, P. Nowak, A. Dyonizy, S. Strek, W. Strek, K. Grabas, A. Ostrowski

Globalization and a growing demand for limited raw material resources have forced changes in the approach to the supply chain. This is particularly true in the case of rare earths, which are regarded as one of the most important development indicators of modern technologies. To ensure a secure supply of commodities, the European economies have been prompted to investigate REE recovery from sources which until recently, for technical or economic reasons, were considered not sufficiently attractive. An interesting example is apatite phosphogypsum waste dumps. The REE content in these waste dumps averages around 0.5-1 %. One of the most important phosphogypsum locations in Poland is the Lower Silesia region where a phosphoric acid Chemical Plant "Wizów" operated for several dozen years. In this work, rare earths are leached from the phosphogypsum crystalline structure by a chemical treatment and can then be separated into individual chemical compounds. The technology used in these recovery tests, matches up to a coherent European raw materials policy supporting effective management of resources and promoting waste materials recycling.

Jan 1, 2014

By Kosuke Hosoda, Shuji Owada, Hiroyuki Tokuichi, Hirobumi Ohta, Chiharu Tokoro, Moto-o Sato, Katsushi Okumura, Hiroto Ogawa, Hideaki Umezawa

The Japanese government enforced the "Small Domestic Appliances (SDAs) Recycling Law" in 2013. The law targets metals such as Ta, Nd, Dy, Co, and W to be recycled. Considerable amounts of these minor rare metals are mounted on printed circuit boards (PCBs) of the SDAs and/or e-scrap (electric and electronic scraps). Although precious metals and copper can be recovered from the e-scrap in non-ferrous metals smelters, most of the minor rare metals report to the slag in these smelters in non-recoverable forms. These metals are often used in particular types of devices, and therefore it is possible to concentrate them by separating such devices before feeding to the smelters. In previous work we developed technology for "Device Separation" to concentrate several minor rare metals, but some problems remained, such as how to remove the PCBs from e-scrap bodies, and how to detach devices from PCBs after their removal from escrap bodies. This paper proposes a two-stage crushing process in which, firstly, PCBs are removed from the e-scrap body with various crushers, and secondly, devices are detached from the PCBs involving the application of elevated temperatures. It was found that in the first stage, crushers with physically flexible rotating media such as chains, which provide high collision probability with the sample and consume relatively low energy, can quite effectively separate the PCBs from the e-scrap bodies non-destructively. In the second stage, heating was found to be remarkably effective in helping to detach mounted devices from PCBs, also non-destructively. This paper will also discuss the detailed mechanism of the heating effect on the detachment of devices from PCBs.

Jan 1, 2014

By S. Rivard

"This paper demonstrates the selection of grinding circuit technology for a number of recent projects including discussion of the key drivers and the role of energy efficiency. Decreasing head grades combined with a strong and sustained increase in operating costs has forced miners to examine increased project size, increased equipment capacity and efficiency improvements in order to reduce their unit operating costs and improve overall project economics. Comminution energy consumption, safety and capital cost considerations play a critical role in the success of projects. This paper presents some key guidelines for a successful and cost effective comminution circuit design and includes a case study on three projects, outlining the issues and the drivers which led to the ultimate circuit selection and the critical role that energy efficiency played.IntroductionComminution circuits for minerals processing are selected based on their suitability and efficiency in reducing run-of-mine ore to the desired feed size for the downstream process. The input material (ore) properties and downstream process requirements are the key determinants and there are standard approaches for each circumstance.The minerals processing industry has been a fast adaptor of efficiency improvements based on increasing capacity of equipment (e.g. trucks, crushers, mills, pumps) but less successful in adapting radically new technologies that disrupt incumbent flowsheets or processes.The installed power of grinding mills has increased linearly over the past 25 years (Meka & Lane, 2010) and pumps and classification equipment have kept pace. The autogenous grinding (AG) and semi- autogenous grinding (SAG) mills displaced stage crushing as a dominant method of coarse rock breakage in many applications causing crusher manufactures to increase the capacity of cone crushers to meet the competitive demand.Examples of new comminution technology in the 20th and 21st centuries are the development and adoption of cyclone classification in the 1940s (Newtech, 2016), AG milling in the late 1950s, vertical grinding mills in the 1980s, high pressure grinding rolls (HPGRs) also in the 1980s and ultrafine milling technology in the 1990s (Meka & Lane, 2010)."

Jan 1, 2017

By Peter Makuvise, Alain M. Bantshi

"The Mazowe Gold Mine is managed by Metallon Gold (Zimbabwe) and is situated in the west-central part of the Harare greenstone belt. Orebodies here generally comprise shear zones which are in-filled with gold-bearing sulphides and quartz. The mineralised zones are up to 1 m in width, have average grades of 4 to 5 g/t, and mostly dip between 10º and 60º to the north.Mazowe Mine is one of the oldest mines in Zimbabwe, and exploration and development in this region dates back to 1890, with over 1.4 million ounces of gold produced to date. Mazowe mine comprises two underground operations, Mazowe and the BSV sections. Ore is processed in a single plant which consists of conventional crushing and milling and carbon-in-leach facility.Baldmin Projects was awarded the contract for the design, construction and commissioning of the 60,000 tonnes per month plant at Mazowe mine in 2014 for the processing of sand and slimes tailings from previous operations at Mazowe mine. The average grade of the tailings is 1.1 g/t. The plant consists of feed preparation, grinding, flotation, thickening of flotation concentrate, and carbon in leach (CIL). A pump station for hydraulic mining of the slimes tailings dam also part of the plant.Key features of the Mazowe sands Plant are described and include:• Hydraulic mining of gold tailings dump.• Feed preparation section that includes a (W x L) 2.4 m wide x 4.8 m trash screen, 250 m3 surge tank, a cluster cyclones with 2 x 500 mm diam. Cyclone.• Comminution circuit designed for a bond work index range of 10-12 kwh/tonne. comminution circuit is constituted with 3 ball mills, 1.83 m diam. X 6.71 m Long, 280 kW.• Flotation circuit comprising rougher bank, scavenger bank and cleaner bank. Rougher Scavenger bank is constituted of 6 x 6m3 flotation cells and 3 x 30 m3 flotation cells and the cleaner is constituted of 3 x 6 m3 flotation cells.• Concentrate Thickening with 6 m diam. Thickener.• Concentrate CIL (carbon in leaching): CIL circuit is comprised of 7 tanks with 2 leach tanks and 5 Carbon in leach."

Jan 1, 2017

By P. P. Andrieux

The recovery of the Zone G crown pillar, located between the bottom of the open pit and the top of the underground workings at the Raglan Katinniq Mine in Nunavik, started in the summer of 2008 and should be completed by the end of 2009. This article describes the rock mechanics-based approach implemented to design the recovery of this valuable block of ore. The stereophotography-based ShapeMetriX3D technique was first used to provide a comprehensive assessment of the various joint sets that comprised the pillar. Then, the statistical distributions obtained for the dip, dip direction, spacing and persistence of these sets were used in conjunction with the geometry of the large-scale faults present in the area to build and run a series of explicit rigid numerical models. Each of these models had a slightly different jointing geometry, randomly constructed from these statistical distributions. Incorporating in a properly formulated numerical model the variability of some of the input parameters has allowed the engineering team to assess in a rational and reliable manner the likelihood of success of the proposed mining method and sequence.

May 1, 2009

By J. E. Nesset

"Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right ‘strength’ is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry will also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.INTRODUCTIONFrothers perform various functions in flotation but the primary ones are control of bubble size in the pulp zone and stabilization of the froth zone. Laskowski (2003) was among the first to try to capture both roles in characterizing frothers in order to provide a basis for frother selection for a given duty, as well as to explore the link between function and frother chemistry (structure). The method he used requires bubble size data and a frothing index; the procedure has been simplified by Cappuccitti and Finch (2008) using gas hold-up to substitute for bubble size, and froth height (without overflow) as the froth stability metric. The gas hold-up/froth height relationship will be referred to as ‘hydrodynamic characterization’. Essentially, the gas hold-up parameter reflects the sum of the hydrodynamic conditions in the pulp phase (water in this case), i.e. the effect of bubble size plus the apparent impact of the water surrounding the bubble due to the frother (Finch, Nesset and Acuna, 2008). Similarly, the stable froth height parameter reflects the sum of hydrodynamic conditions in the froth, i.e. the effect of bubble size undergoing coalescence plus the influence of the water in the lamellae and Plateau borders between bubbles. It could be argued that the gas hold-up/froth height relationship is a superior one to simple bubble size/froth index for discerning differences in frother behaviour"

Jan 1, 2010

By John Wilson

"The Rietveld numerical method was used to calculate the relative abundances of phases in both synthetic binary mixtures and synthetic and natural ores, using X-ray diffraction data. The results were compared with those of image analysis and a chemical method. The ranges of the relative errors were estimated. The Rietveld method is found to be acceptable for determining the abundances of major and minor phases and the amorphous component of partially crystalline samples. In complex mixtures, where there are several trace phases (~<2 wt%) present, the technique becomes less accurate. It is most useful as an alternative technique to image analysis when sample preparation is problematic or sample particle sizes are sub-micron. It is a manual method which requires user input during the fitting process, but is both simpler and faster than image analysis due to the reduced set up time and sample preparation required. It is now implemented at CANMET as a technique for quantitative analysis.INTRODUCTIONUntil recently, the Applied Mineralogy group at CANMET used only image analysis and chemical techniques to determine phase quantities. An effort to develop quantitative X-ray diffraction (XRD) has been on-going for several years. Initially, the reference intensity ratio (RIR) method with external standards was tried with some success (Szymanski and Petruk, 1989). The main difficulty with this technique was finding adequate standard material for each phase present in the sample. This shortcoming made the method ultimately impractical, given the wide variety of materials which come to the laboratory for analysis.The Rietveld refinement method of quantitative XRD (Hill et al 1993, Mumme et al 1996), in contrast, requires no standards and requires minimal sample preparation and therefore a more rapid turnaround compared to image analysis. The Rietveld method also has advantages over image analysis in that it can identify and quantify polymorphs, ultra fine materials and many types of hydroxide products. As well, it is useful for analyzing materials such as bauxite or talc, which do not polish well enough for making mounts of the quality required for image analysis. To quantify amorphous material and phases which are present in amounts below the detection limit of XRD, the addition of a standard material is still required. However, in such cases only one standard is needed, which is alumina."

Jan 1, 2003