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By Lewis Finch

Oil and .gas reservoirs exist under pressure within the pore spaces of rock structures or traps. Wells are drilled to produce these reservoirs. Under primary operation, the natural energy of expanding fluids in and adjacent to the reservoir forces or drives oil and gas to the wells. There are three basic sources of energy: dissolved gas, water, and gas cap. Typical recovery by primary methods is only 10 to 25 per cent of the oil in place for the dissolved gas drive but is generally higher for the others. Secondary recovery involves the injection of water or gas to supplement natural energy, thereby increasing recovery over that obtainable by primary operation alone. In many cases ultimate recovery with secondary methods is 1.2 to 2.0 times the expected primary recovery. The type programme adaptable in a field depends on its 'primary performance and on certain reservoir characteristics. In the United States, application of secondary recovery methods is becoming increasingly important. About 22 per cent of United States oil production now comes from fields in which injection projects are operating. In 1953, nearly 1.4 million barrels of oil daily came from such fields, more than double the amount in the early 40's. Ultimate primary recovery from known pools is estimated at roughly 73 billion barrels. Secondary recovery projects already in operation will increase this to almost 80 billion, an increase of almost 10 per cent. Unitized secondary recovery projects have been very successful. From unitized projects alone, industry reserves of oil in the United States have been increased by 3 1/2 billion barrels. In Canada, secondary recovery has not been so wide spread mainly because D-3 reef reservoirs which have held the major reserves are under water drive. However, appreciable amounts of water are being injected in the Redwater D-3, Leduc D-2 and Joarcum Viking reservoirs, and gas in the Golden Spike D-3. In both countries, possible achievements in increased recovery through secondary recovery methods now in use and by new ones which may be developed through research and field trial are a challenge to the scientist and the industry.

Jan 1, 1956

By P. Clinton Milne

Uranium mines in Washington State include the producing Midnite and Sherwood mines and several mined-out deposits, the most productive of which was the Daybreak mine. The Midnite mine is generally classified as a hydrothermal deposit consisting of tabular orebodies in Precambrian pelitic and calcareous metasedimentary host rocks. The host rocks occur as roof pendants in a Cretaceous porphyritic quartz monzonite intrusive; the quartz monzonite averages 12 ppm U308 The uranium deposit appears to have undergone a complex genesis, involving a series of depositional and enrichment stages. The Sherwood uranium deposit, approximately 4 miles south of the Midnite mine, occurs near the bottom of a basal Late Cretaceous to Paleocene arkosic conglomerate. The conglomerate lies nonconformably on the porphyritic quartz monzonite that is associated with the Midnite deposit. The Sherwood and Midnite uranium deposits may have had a similar genetic history linked by a common uraniferous pluton source, ground-water action, and/or leaching of uranium-rich ash flows from now-eroded, overlying, Eocene volcanics. The Daybreak deposit, in northeastern Spokane County, consists entirely of secondary uranium mineralization (metaautunite) in a quartz monzonite pluton. Mineralization is confined to a low-angle fault zone and is most highly concentrated at the intersection of primary and secondary shears. Both hydrothermal and ground-water origins are feasible. Besides the Midnite-Sherwood area, 14 other areas in the western Okanogan Highlands physiographic province and Cascades region have favourable characteristics for uranium potential. Criteria include the existence of uranium occurrences, Tertiary basin sediments with intercalated volcanic and volcaniclastic rocks, favourable geochemical data, alkaline plutons associated with uranium occurrences or borders of Tertiary basins, and structural controls.

Jan 1, 1979

By Engineering Staff

In 1958, the Iron Ore Company of Canada decided to proceed with the Carol Project. The ore deposits in the area are part of the highly metamorphosed southern zone of the Labrador Trough. They lie along the shore of W a bush lake, in the western part of Newfoundland-Labrador, 190 miles north of Sept-Iles. The project is designed to mine, by open-pit methods, 17,200,000 long tons of crude ore, grading 37 per cent iron, per year. This ore will be beneficiated to produce 7,000,000 long tons of concentrate, grading 66 per cent iron, of which 5,500,000 long tons will be pelletized. Production is scheduled to commence this summer. Initially, ore will be taken from 45-foot benches in the Smallwood mine, using jet-piercing production drills and large-scale blasting with "slurry" explosives. Four 13-yard electric shovels will muck the broken ore into 100-ton trailer trucks. The trailers will be hauled to two 2,000-ton loading pockets, which feed the ore into 100-ton railcars. Four ore trains, each comprised

Jan 1, 1962

By Donald S. Macdonald

"I AM thankful for this opportunity to address the Toronto Branch of The Canadian Institute of Mining and Metallurgy. The Members of your Institute can have a great influence on the direction in which the mineral policies of Canada will evolve, and to assure that optimum benefits from our country's vast mineral resources will accrue to the nation as a whole and to all its citizens. Today, I want to: (1) offer an outlook on the mineral industry for 1973; (2) talk briefly about the role of minerals in the total economy; and (3) outline some of our thinking with respect to a national minerals policy for Canada."

Jan 1, 1973

By S. Khoshkhooei

In this research, the effects of rare earth elements addition on thermal fatigue behaviors of AZ91 alloy were studied. Repeated heating and cooling cycles were applied on the samples at 170°C and 210 °C to develop thermal fatigue cracks, Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy (SEM) as well as energy dispersive X-ray spectroscopy (EDS), Thermal fatigue behaviors were improved successively by addition of up to 2-wt% RE, This improvement is attributed to consummation of the aluminum of the melt by precipitation of the needle shape Al 11 RE3 phases, This process reduces the volume of Mg17Al12 phases and consequently decreases the brittle Mg/Mg17Al12 interfaces which are the main reason of weak thermal properties of the alloy at rather high temperatures, Further additions of RE, however, reduced the thermal shock resistance of samples by increasing in the mean length of the brittle needle shape phases.

Jan 1, 2005

By J. E. Dutrizac, J. B. Sunstrum

Until relatively recent times, virtually all gold was recovered by gravity and/ or amalgamation methods. Although such techniques are very effective on coarse gold, they become increasingly less useful for finer grains especially when the gold is partly enclosed in rock matrix. Throughout the nineteenth century a number of bonanza gold fields were found in the United States, South Africa, Australia and Canada. In every case the abundant supply of gold nuggets and coarse alluvial gold soon gave way to hard rock mining with its inevitable losses of fine gold in the stamp mill tailings. Continuing efforts to develop new technologies capable of dissolving gold from finely ground ore were eventually successful first with chlorination (the Plattner process) and subsequently with cyanidation. Even before the nineteenth century, however, European chemists such as Scheele and Berthollet were aware that gold could be readily dissolved in an excess of free cyanide(1). As early as 1840, a patent was issued to the Elkington brothers for the dissolution of pure gold in cyanide solution and its subsequent plating onto various metals, with or without an applied electrical current. In 1846, Elsner showed that oxygen was also required to solubilize gold or silver in cyanide media(1). Despite the fact that much work was done on the reaction of cyanide solutions with gold, a viable leaching process for gold ores did not quickly emerge although cyanide solutions were used to enhance amalgamation from the 1860s onward. Major problems were associated with the use of concentrated cyanide solutions; the costs of cyanide were excessive and it was difficult to recover gold from the concentrated media.

Jan 1, 1999

By A. Jain

During sheet forming, metal experiences not only multi-axial load, it also undergoes strain path changes. For example, metal in the flange region may be drawn, may bend and unbend through a bead, before bending around a die radius, etc. Compression data were obtained from AZ31 sheet after pre-straining in compression along an orthogonal direction. The compression directions correspond to the sheet product (rolling-RD, transverse-TD, and normal-ND) directions. Three cases are examined: slip dominated deformation (ND) followed by twin dominated (RD or TD) deformation, twin dominated (RD or TD) followed by de-twinning (ND), and twin dominated (e.g. RD) followed by cross-twinning or secondary twinning (e.g. TD). Slip induced pre-straining simply hardens the material, while twin dominated pre-straining alters the texture allowing the material to either de-twin or re-twin upon changing the strain path. Polycrystal plasticity modeling has been used to predict qualitative features of the flow curves during strain path changes.

Jan 1, 2006

By Douglas M. Smith, G. A. Maki

"The initial development of the massive potash deposits of the prairie evaporite formation took place over a decade ending in 1970. The potash mining and refining facility near Rocanvi11e, Saskatchewan was the 1ast of ten mines to come into production during that era. This operation, known as Sylvite of Canada Ltd., was designed to produce 1. 2 million short tons per year of KCl product in granular, coarse, standard and special standard grades.In 1977 the parent company, Hudson Bay Mining and Smelting, sold the Sylvite property to the Potash Corporation of Saskatchewan. Shortly thereafter PCS slated its new Rocanville Division for a two phase program of expansion. The first phase, completed in the spring of 1979, was relatively small, involving mill debottlenecking and additional equipment in the compaction circuit and the product and ore storage areas. The second phase was a major undertaking which included additional mining equipment and a new 300 STPH milling circuit. This work was completed during the fall of 1981 and has increased the Rocanville Division's nameplate capacity to two million STPY.Thickening equipment operating in the Saskatchewan potash industry is generally situated within the main refinery building or a separate insulated and heated structure due to the harsh winter climate and the need to closely control plant brine temperatures to ensure good flotation circuit performance. Since these thickeners process large volumes of slurries, conventional basin type designs tend to be large, ranging up to 150 feet in diameter or more. As part of the general effort to minimize capital costs, the potash industry has begun investigating the use of alternate high capacity, compact thickener designs. In this regard, PCS Rocanville undertook a program in 1978 to evaluate a Lamella™ Thickener and one other type of 'High Rate' thickener* as alternatives to a conventional design for the phase two expansion project."

Jan 1, 1983

By R. W. Brock

This subject is too broad and comprehensive to be dealt with adequately and authoritatively in this paper. It calls for the knowledge and experience of many men, but the results from such collaborative effort would be of great value, particularly if similar reports of the principal mining districts of the world were made on a standardized basis so that conditions everywhere might be directly and accurately compared. In considering conditions affecting mining in British Columbia, unfavourable as well as favourable factors must be taken into account. The unfavourable are apt to loom large and to be exaggerated rather than minimized; for it is human nature to see the blackness of the cloud rather than the silver lining; to think that one's own undertaking is beset with peculiar difficulties, and to attribute lack of greater success to out-side causes rather than to personal shortcomings. It should be recognized, however, that there is no country where the conditions for mining are ideal. The ideal mining country is the product of imagination, invested with every favourable condition found anywhere, but with none of the unfavourable conditions that are always present in reality. So if British Columbia has some handicaps to the industry, it is in good company. What is important is that the advantages compensate for the disadvantages, that the balance will compare favorably with that of competing states, for mining, like every other industry is competitive, and the cost of one's product must have a definite relationship to its price in the world's market.

Jan 1, 1924

By Joanna LaForte

"IntroductionIn respect to The Human Dimension by M. Phyllis Bray, this author's impression is that research on long distance commuting (LDC) is long overdue. This type of mining is not new to many workers, especially those from areas such as the Maritimes, who have had to look for work away from their families for at least a decade. Perhaps to the industry the over-all set-up is new, but to workers who have faced mine shut-downs in their areas finding a job was the main objective and if the security of long-term employment was evident, then the families might join them later. This was the situation with which the writer' s family was faced.LDC LifestyleBeing the wife of an underground miner, the author has personally experienced this lifestyle for almost 10 years, and has never experienced accommodation in a company town. The first five years of marriage were spent in a small rural municipality within 50 miles of the worksite, but the town had industry separate from mining and was not affected by the mine shut-down.Since her LDC lifestyle began her family has been pretty much city-based, out-of-province commuters with two children and a third to arrive some years later. She therefore lived a fairly normal married life with a husband home daily. The author has experienced life with a husband who worked away for five-day stretches and then drove long distances to be home weekends or the portion of time left over from driving and fatigue. She has done the 3D-days in/l4-days out routine, and for approximately the past four years has been existing on a two-weeks in/two-weeks out ritual .The author does not agree that the ""bottom line is that mining families go where the jobs are"" . The miners go where the jobs are and the families fend for themselves with the assistance of the pay cheque making it home each pay period.Perhaps because there are many personal frustrations with this type of lifestyle, perceptions may be inaccurate. Having only dealt with underground operations, there may be gross differences between the pressures and demands of other forms of mining."

Jan 1, 1991

By Jas. E. Thomson

PUBLIC attention was first attracted to the Crow River area of north-western Ontario by the discovery of gold in 1928. The first three discoveries were eventually developed into Central Patricia, Pickle Crow, and Albany River mines. In 1929, preliminary developments were carried out at the Howell vein on N.A.M.E. (later Pickle Crow) claims, and in 1929 and 1930 surface and underground work indicated an ore-body at Central Patricia mine. However, due to the financial depression and the distance of these properties from the railway, it was not until 1934 and 1935 that, benefitted by the revaluation of gold, the real potentialities of these two properties began to be realized. Their immediate success led to a resumption of activity on neighbouring properties throughout the area in 1936 and 1937. Preliminary prospecting in the earlier period had been limited by the scarcity of rock exposures in the country. The procedure in the recent programme of intensive exploration has been along similar lines at most properties and has consisted lf detailed geological mapping accompanied by geophysical surveys and followed by systematic drilling of favourable zones. The present importance of the camp may be judged by the fact that, in 1937, Central Patricia and Pickle Crow mines together produced bullion valued at $3,662,953, and paid $1,450,000 in dividends. In addition, there were pro-mising gold developments at Albany River mine. During the past two seasons, the Geological Branch of the Ontario Department of Mines has been making a fairly detailed study of the geology and mineral deposits in the Crow River area. It is the purpose of this paper to present a brief statement of some of the structural features of these deposits; a summary of other geological information essential for the understanding of the main topic is included. A more detailed report on the area will be published shortly by the Ontario Department of Mines. It is impossible to make full acknowledgment here for all help received, for the writer is in-debted to the management, staff, and consultants of every Company in the camp for generous co-operation in the field and for information, plans, maps, and records placed at his disposal. Reports and articles on properties in the area have been written by Hurst (1), Cormie (2), Reid (3), and the staff of Pickle Crow Gold Mines ( 4).

Jan 1, 1938

By A. Bauer

This paper describes the trends in recent years in explosives formulated to produce larger blast-hole spacings and over-all lower drilling and blasting costs in hard formations. A consideration of current rotary drilling costs per ft of hole and per ton of muck versus hole diameter indicates that it is now possible that we shall see much further use of lower-energy-content, lower-cost slurries and dry mixes, and larger-diameter and, in many instances, cheaper blast holes. These will be drilled on current or slightly larger blast patterns to yield the same energy input per ton of rock and similar fragmentation at lower costs.

Jan 1, 1968

By A. Hayatdavoudi, K. G. Sawant, F. Boukadi

"In this work, we found that contact between shale and water results in development of micro fractures. Based on results of experiments on Pierre shale, we conclude that appearance of micro fractures begin with saturation of capillaries, ionic and diffusive transport of water into the shale clays and once capillaries are saturated, the cause of micro fracture propagation is the conversion of ionic activity/exchange to excess pressure that did not exist before fracking. Based on these findings, the spread of micro fractures appear to be a time-dependent phenomenon which has not been addressed in the existing macro/micro fracture models.INTRODUCTIONShale has often been involved as a hazard in drilling operations. This hazard can be defined as “destabilization” of shale. When contacted with water-based drilling fluids, some shales readily swell and sometimes, cause the wellbore to cave-in, slough, wash-out, close, and pack-off, impeding the drilling by sticking the drill-pipe. However, once drilling reaches the desired depth or length, the casing is set, cemented, and perforated, and then actually we wish to initiate fractures and destabilize the shale formation, using hydraulic fracturing.Clays constitute a major portion of minerals in shale. These clays contain a large amount of free energy which is the main factor for “slick” water adsorption/absorption. In fact, the reason for using “surfactants” in hydraulic fracturing fluids is to make the penetration of the fluid into the capillaries much easier, thus water meets with less resistance to enter the small capillaries. Also, the result of high capillary suction pressure is due to small Angstrom size capillaries, smaller pores and presence of ions and hydrateable metal atoms. The free energy is thus, related to all the above mentioned and other affects. Capillary pressure, osmotic pressure and other pressures are responsible for creating the micro-fractures in shale, thus, increasing the network of micro-fractures which leads to more gas production. The objective of this study is to evaluate the pressures of the individual ions which are released by the diffusing “slick” water into shale. These pressures would be added to the above mentioned capillary pressure, osmotic pressure, bacterially-induced pressures, chemically-induced reaction pressure, pressure due to exchangeable ion-transport, pressure due to release of free energy of solvation and eventually to the pore pressure as suggested by Terzaghi’s equation."

Jan 1, 2015

By M. R. Hudec, M. A. Nikolinakou, P. B. Flemings

"We model the shale response to the large deformations associated with salt bodies, and we identify the implications of the stress changes for hydrocarbon exploration. We employ both the static and evolutionary approach, and show that while the static one can model actual geologic geometries, only the evolutionary approach can provide a detailed description of the stress history of shales, which is essential for predicting stress, porosity, and pore pressure and, more generally, for understanding Earth processes related to salt-hydrocarbon systems.INTRODUCTIONDuring the last two decades, understanding the stress, material behavior, and pore pressure in shales around salt bodies has become increasingly important. The energy industry routinely drills near salt (Beltrão, Sombra, Lage, Fagundes Netto, & Henriques, 2009; Meyer, Zarra, Rains, Meltz, & Hall, 2005; Seymour, Rae, Peden, & Ormston, 1993), because a significant number of hydrocarbon reservoirs around the world are found in layers dipping away from salt diapirs.Salt is a viscous material that cannot sustain deviatoric stresses. Under differential loading it flows, changes shape, and eventually relaxes to an isostatic stress state (Urai & Spiers, 2007). Therefore, emplacement of a salt body and its viscous relaxation process may cause significant deformation of the surrounding sediments, perturb their state of stress and create local overpressures (Dusseault, Maury, Sanfilippo, & Santarelli, 2004; Seymour et al., 1993). As a result, drilling near salt is particularly challenging, and problems leading to additional expense or even abandonment are common (Bradley, 1978; Dusseault et al., 2004; Meyer et al., 2005; Seymour et al., 1993; Willson et al., 2003).Historically, salt and the evolution of its cross section to the present day geometry have been studied using kinematic restorations (Rowan & Ratliff, 2012). This approach aims to explain the present geologic section through a sequence of plausible past sections; however, it does not model the constitutive response of the wall rocks, hence it cannot provide any prediction on their state of stress. Similarly, largestrain numerical studies (Albertz & Beaumont, 2010; Chemia, Schmeling, & Koyi, 2009; Goteti, Ings, & Beaumont, 2012; Gradmann, Beaumont, & Albertz, 2009) have focused on the rheological evolution of salt systems without modeling the geomechanical response of the sediments."

Jan 1, 2015

By G M. Thorpe

This paper discusses mine research at Inco, giving specific examples of research projects which illustrate the approach to mining problems. The first example covers the development of a new mining method, "undercut and fill," which was originated for mining badly broken-up pillars, but which is now rapidly replacing the square set method of pillar recovery. In the new method, ore is extracted in a series of successive horizontal cuts, progressing downward, a cut being completely mined and filled before the cut below is started. In the second example, improvements to the "cut and fill" method of mining are discussed. These improvements are the result of improved techniques and improved equipment, etc., with, in many cases, the former being made possible by the latter. The advances made have permitted the use of the "cut and fill" method at much greater depths than before. The third example is presented to illustrate research undertaken to obtain the earliest maximum advantage of the introduction of a new piece of equipment or material. For this purpose, the development of the "Under-ground use of AN /FO Blasting Agent " has been selected. Work on this project started in May, 1960, at a time when there was very little in-formation regarding the potentialities of AN /FO for underground blasting, either primary or secondary. By the end of 1961, AN /FO made up 64 per cent of the explosives used under-ground at Inco mines.

Jan 1, 1963

By Vu Van Dong

Resource estimation is the science of determining the amount and quality of a given material in the ground that has the potential to be mined at a profit. This is because during this time computers have become more widely available and more powerful and software packages have become more comprehensive and user friendly. Over the past three years The Mining Geology Company with the support from Vinacomin Group has developed the Coal Geological Modelling and Reserve Estimation ? VMG system. The VMG system enables the geological and mining engineer to start at the reserve estimation for the mine design and planning. The VMG system enables the national and international standards (NI43-101, CIM-Canada; SAMREC Code, Africa, and JORC Code, Australia) and user friendly with menu driven thereby permitting the engineer with minimal computer training to rapidly learn and utilize the system. Geological and mining data input through digitized map files and drill-holes information files stored in the database that is an integral part of the VMG system with the main function for collection, validation, and recording, storing and processing of data will include both ?primary? (observation and measurement) and ?interpreted? data. It is recommend that data be stored digitally, using a documented, standard format and a reliable storage medium that allows for easy and complete retrieval of the data. The coal reserve estimation through standard polygon methods with the increased use of these mathematical techniques (geometrical modelling, geostatistical method, least square method, ?) over the last ten years corresponds, to some degree, to a decrease in both the amount of the coal deposit mapping and, in particular, coal seam structural interpretation and modelling, and permit rapidly evaluation of coal seam and overburden quality and quantity. The understanding of the relationship between the coal mineralization of interest and the likely related complicate geological processes and structure that govern its emplacement and geometry within the geological framework is essential to the establishment of the geological controls for coal mineralization. System outputs includes: drillholes summary reports, stratigraphy, cross-sections, isopach maps, structure, contour maps, premining and post mining topography maps, and 3D perspective view on coal seam structure.

Oct 1, 2009

By Glenn K. Nolan

"Today, more than any other time in recent history, aboriginal communities are looking for ways to be understood as more resource development companies continue to explore and develop Canada's vast resource potential.Recent Supreme Court rulings have affirmed the need to engage aboriginal communities early on in resource development projects. There are many conflicting ideas on how, who, and when to engage. Given the large number of communities and varied cultures, each resource development company must equip itself with a better understanding of the people they are planning to work with.The lecture will begin with a basic historical perspective on treaties and the various societies across Canada. We will also explore the current situation many communities find themselves in today. Building a meaningful relationship with a community is the foundation for a lasting partnership. Every community is unique and every approach to engage communities must be just as unique. The lecture will outline some basic steps that can lead to a better relationship building process between the communities and companies."

Jan 1, 2008

"Increasing demand for timely and accurate information about flotation plant performance requires metal accountants to increase the scope and reporting frequency of plant production. This trend has brought in-process inventory estimation at the forefront of metal accounting issues. Such significant in-process inventories can be locked in diverse process equipment (bins, holding tanks, flotation cells, thickeners, pipeline, etc.) or in stockpiles (ore, concentrates, tailings, etc.). Practice has shown that boldly ignoring these in-process inventories or the errors associated with their estimation lead to unreliable metal balances thereby creating confusion in plant production planning and operational performance assessment. To this extent, the characteristics (physical bounds, spatial heterogeneity and residence time) as well as the available measurements (volume, density, humidity, mass, composition, etc.) of each unit/section found in a generic flotation plant are jointly reviewed with respect to the particular metal accounting issues they present. The daily and monthly metal accounting tasks are then reviewed together with possible methods for obtaining reliable inventory estimates including different procedures for end-of month reconciliation.INTRODUCTION Most of the cost reduction initiatives of the mining industry aim at improving capital efficiency and asset utilization. Among the possible paths through which these goals can be achieved are mine-to-metal optimization, real-time plantwide process control (Hodouin, 2011) and knowledge sharing databases (Bascur & Linares, 2006). However, the successful implementation and subsequent monitoring will ineluctably results in an increased demand for timely and accurate information. This more than often requires metal accountants to increase the scope and reporting frequency of plant metal production. A striking example of such scope expansion is the Minas-Rio iron ore project in Brazil (Anglo American, 2013) having a pipeline route of 525 km between the concentrator and the concentrate shipping area. Several other mining companies have also set an increased frequency for their key performance indicators thereby shrinking the metal accounting period from monthly to weekly and daily. Those concurrent trends have brought in-process inventory estimation at the forefront of metal accounting issues. Indeed, as illustrated in Figure 1, improving trading reactivity requires improvements in production planning which strongly impacts the requirements for reliable metallurgical accounting. Furthermore, practice has shown that boldly ignoring significant in-process inventories or the errors associated with their estimation can lead to unreliable metal balances. In other words, since metal balances are the cornerstones of metal accounting, some of the risks associated with important business decisions are linked to errors associated with in-process inventory measurements."

Jan 1, 2014

By U. Erb, L. Monaco

"Electrodeposited nanomaterials are increasingly implemented in advanced industrial applications in the aerospace, automotive, defence, electronic and energy sectors due to their outstanding physical, chemical and mechanical properties, including increased strength and wear resistance, and superb magnetic properties. As with the development of any class of new materials, the corrosion behaviour of these electrodeposits requires considerable attention. This presentation reviews major developments in the understanding of the corrosion behaviour of nanocrystalline metals, alloys and metal-matrix composites over the last 20 years, with emphasis on how their intrinsically high density of intercrystalline defects does not compromise their corrosion resistance as initially expected.INTRODUCTIONOver the past 20 years there have been considerable advances in the understanding of the corrosion behaviour of nanocrystalline metals, alloys and metal-matrix composites. In this paper, the corrosion properties of nanocrystalline nickel, cobalt, zinc, and copper and some of their alloys are reviewed with emphasis on how a reduction in grain size affects their corrosion behaviour in different environments.It is possible to synthesize nanocrystalline material with microstructural refinement down to the range of 1 to 100 nm using a large number of processing methods. There are five basic synthesis methods that can be used to classify the different techniques: vapor-phase processing, liquid-phase processing, solid-phase processing, chemical synthesis, and electrochemical synthesis. Depending on the synthesis method, different microstructures (equiaxed, textured), shapes, and forms (films, particles, bulk material) may be produced. In addition, other factors may be introduced (eg. residual porosity or amorphous phases), aside from microstructural refinement, which can contribute to the observed properties (Erb, 2010). In order to interpret and categorize the resulting microstructures, a dimensional structure modulation scheme was introduced by Siegel (1996) in which zero-dimensional nanomaterials refer to individual particles, clusters, etc. One-dimensionality results from a layered (less than 100 nm thick) structure. Two-dimensional nanomaterials are thin, layered structures containing grains (less than 100 nm) within each layer. Finally, three-dimensional nanomaterials are bulk structures with an average grain size less than 100 nm."

Jan 1, 2012

By Richard J. Wardle, Ambrose F. Howse

The industrial minerals industry in Newfoundland and Labrador is a significant contributor to the provincial economy. The variety ofcommodities produced reflects the diverse geological environment from which they come. A highlight of the past decade has been the continuing development of dimension stone quarries, with producers now active in anorthosite, gabbro, granite and sandstone. Other dimension stone prospects have been identified and are in various stages of assessment and development. Western Newfoundland hosts a large resource of limestone, dolomite and marble. It provides raw material for industries that produce Portland cement, agricultural limestone and aggregate, as well as chemical-grade limestone and dolomite products. In western Labrador, dolomitic marble is quarried for use in the production of self-fluxing iron ore pellets. The recent opening of a new gypsum quarry at Fischells Brook signalled the beginning of a new era in the commercial production ofgypsum, a commodity which the province has produced since the 1950s. Hopefully it will emulate the nearby Flat Bay Quarry (now closed) which was a long-time exporter to markets along the U.S. eastern seaboard, in addition to supplying local demands. Oil production and continuing exploration in the Newfoundland offshore has renewed interest in local barite deposits for potential use in drilling fluids. Already there has been some production from the Collier Point deposit, and at Buchans, an existing plant is being refurbished to recover barite from a large tailings pond. Emerging new industries include the development of an antimony mine in central Newfoundland, the development of silica deposits near Labrador City for silicon metal production, and reactivation of the St. Lawrence fluorspar mine. The province has many deposits with development potential such as rare metals at Strange Lake, white marble at Roddickton and salt deposits near St. George's Bay region.

Jan 1, 2001