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By H. Tan

The effect of carbonaceous matter on gold extraction was investigated in cyanide systems with pure gold as well as pre-robbing sulfide gold ores. Auger studies demonstrated that the carbonaceous matter preferentially smeared on iron sulfide rather than aluminosilicate surfaces during wet or dry grinding. During mechanically mixed leaching, coating of sulfides and silicates and stripping of carbonaceous matter occurred simultaneously. TEM and XPS studies indicated preferential coating in the form of elemental (graphitic) carbon at the edges and the defect sites of particles. Interestingly, carbonaceous matter extracted from the gold ore was predominantly graphite and not preg-robbing in a solution with a high KCN concentration. However, the carbonaceous coating had a significantly detrimental effect on gold dissolution when gold was pre-ground with the gold ore. Artificial coating on gold surfaces with the natural carbonaceous matter from the ore was also found to substantially retard gold dissolution. With the addition of the natural carbonaceous matter from the gold ore, gold extraction from two non preg-robbing sulfide gold ores was inhibited owing to carbonaceous coating. The presence of carbonaceous matter significantly reduced the current density for gold oxidation and increased the current density for pyrite oxidation. This could explain the fact that carbonaceous coating hindered gold dissolution while enhanced sulfide preg-robbing.

Jan 1, 2005

By A. Alfantazi, M. Mahon

The current efficiency in zinc electrowinning is a key indicator of the performance in a cell house. This is typically measured by comparing the weight of the cathode to the electric current applied over the deposition period. This calculation can be cumbersome because the deposition history of each pulled set of cathodes will be unique. It will depend on the applied current and electrolyte conditions from onset of deposition until the cathode is removed and stripped. Not accounting for these can introduce errors to the calculated current efficiency. To track this history and reconcile the current efficiency, a time based computer process simulation was made of an industrial cell house. Two months of hourly recorded measurements from the cell house were input to the simulation, including current to the cell houses, concentrations, flow rate, and temperature of the purified leach solution. The simulation’s predictions of the concentration of zinc in the circulated, spent, and returned electrolyte all showed good agreement with the industrial data over the two months giving a validated zinc balance. The simulation was then tuned to predict the instantaneous current efficiency for all times, as well as the expected masses for the deposits given their deposition history.

Jan 1, 2014

By R. Spring

"Soft-sensors are a computer software alternative to inadequate hardware instrumentation. Filters are averaging methods that reduce the noise in any sensor's signal. This paper introduces these topics and places them in a mineral processing context using then-product formula.Soft SensorsAs their name implies, ""soft-sensors"" are computer programs that estimate values for process variables (Tham, 1991). This approach is useful when the appropriate hardware sensor does not exist, is deficient, supplies only infrequent values, etc. For example, in mineral concentrators the traditional magnetic flowmeter/ nuclear density gauge instrumentation for measuring slurry flows costs $5,000 or more per flow and requires frequent maintenance. However, metal assays are commonly available from online X-ray fluorescence analyzers and application of the n-product formula (Taggart, 1945) to these assays conveniently provides software estimates of the flowrates (albeit only when the circuit is in steady-state).Soft-sensors are used by inferential controllers that base their control actions on the process values ""inferred"" by the soft-sensor. Such was the case at Brenda Mines where the rod mill feed tonnage controller used an inferred value of the cyclone overflow particle size (Bradburn, 1976). It was also the case at Brunswick Mining where reagent controllers adjusted reagent addition rates throughout the plant according to the various ore flowrates inferred by an expert system (Spring, 1991). A unique feature of the expert system soft-sensor was its dynamic flow models which compensated for residence times, material transport lags, etc. Thus the soft-sensor values were valid under both steady-state and nonsteady- state conditions."

Jan 1, 1992

By Philip M. J. Gray

"The real cost of conversion from ore to semi-fabricated non-ferrous metals has been increasing for many years. Consumer resistance and improved knowledge and techniques now available justify investment in revolutionary as well as evolutionary methods of extraction. Metallurgical factors in current practice which preordain high production costs are identified as: smelters' demand for clean minerals, use of processes with low intensity of working per unit of reactor volume, use of low-velocity reactions, use of long reactor retention times relative to the speed of reactions, dilution of values in solution and commitment to electric power as a source of energy.Six new types of flowsheet are proposed for processing from ore to metal, composed of steps which are economic to construct and maintain and making maximum direct use of fossil fuel and the energy content of minerals. The basic knowledge and technology for developing these flowsheets exists. It is very tentatively suggested that these routes might reduce the capital and production cost for conversion of ore to metal by 30-50%."

Jan 1, 1980

By R. G. Zaripova, N. D. Ryan, H. J. McQueen

The austenitic and ferritic stainless steels do not undergo any phase transformation that induces very fine grains in the product through thermomechanical processing as practiced in most other steels. Considerable grain refinement can be achieved by intense multistage deformation descending through warm to cold working; notably multi-axial forging of bulk material can attain high strains with diminished risk of cracking. Hot working to improve ductility yields finer grain sizes as the T is reduced and strain rate E raised; increased strain has limited effect due to the steady state regime. Ferritic steels develop subgrains with size diminishing as E rises and T falls with the advantage of retained strain hardening; recrystallization delivers grains several times the cell size. In austenitic steels, dynamic recrystallization (DRX) provides finer grains at higher E and lower T with a lower limit due to intergranular cracking. The DRX grains contain a strengthening substructure that can easily be retained by quenching; if static recrystallization is allowed to occur the grain size rises markedly. Multistage rolling with diminishing T is able to provide grain refinement to the same degree as straining at the finishing T yet provides better ductility. grains on recrystallization. As a result of the strain induced transformation to martensite, small subzero deformations of austenitic or duplex steels produce very high dislocation densities that yield marked grain refinement when they revert upon reheating.

Jan 1, 2004

By O. Zach, K. Gamweger

"The Process of gas purging in molten Aluminium has been an industrial practise for many years. The melting of alloying elements and their rapid distribution in the bath is very important. To improve the mixing and homogenisation process, at RHI NON FERROUS METALS ENGENEERING GMBH a lot of CFD calculations were done. The so developed new ""purging program"" was tested at Alumino Catalan S.A., Spain. The results of the testtrials were very satisfactory and corresponds very well with the calculated data."

Jan 1, 2004

By R. Roufail

Mineral liberation is accomplished by comminution and is the first step towards achieving successful downstream processes such as flotation or leaching. In metal mining, one of the most effective comminution methods that is used to grind particles below 10 microns is stirred milling. In this paper the study of particle breakage mode vs. mill operating parameters is addressed. Stirred mills' grinding action is mainly attrition, but operation can be manipulated to include breakage by compression or impact loading. Macro and micro analysis of particle breakage and grinding mechanisms are correlated. Macro analyses convey information that relates grinding mechanism to particle size and shape. It is speculated that the breakage mechanism in the horizontal stirred mills is massive fracture for the coarsest particles and attrition (abrasion) close to the grinding limit where the size reduction ratio approaches 1.0. For micro analysis, the particle breakage mode has a direct impact on fracture type either transgranular or intergranular. Intergranular particle breakage leads to higher mineral liberation compared to transgranular breakage. Similar minerals would have more homogeneous properties that convey a stronger bond compared to dissimilar, heterogeneous mineral bonds. Transgranular fracture requires higher energy than inter granular fracture; trans granular fracture toughness of pure single phase mineral is about 10-14 % higher than the intergranular fracture toughness. This communication presents the results of an investigation to assess how operating conditions can affect trans- vs. inter-granular breakage.

Jan 1, 2009

By M. Sabau

The Electrowinning Plant at INCO's Copper Cliff Nickel Refinery is a precious metals upgrading plant. The feed to the plant contains copper, nickel, cobalt, iron, significant amounts of precious metals and some impurities. Copper is the most abundant element in the feed. This paper describes the major equipment and process changes over the last twenty years, geared to improve the tankhouse operation, workroom environment and recovery of copper from the acidic solution. Copper is plated on to titanium blanks using explosion-bonded crossrods, animal glue as a levelling agent, and an organic surfactant for mist control. The installation of the stripping machine in 2001 required a number of changes: cathode and anode contacts were redesigned, flat bus bars were replaced with dog-bone type, spacer boards for cathodes and anodes were installed, longer anodes started to be used, and the plating cycle was extended from seven to fourteen days. A number of initiatives for improvement are being carried out. Explosion-bonded crossrods are being replaced with titanium-clad crossrods. The plan for the near future is to increase copper production by increasing current efficiency and current density. The possibility of lowering the iron concentration in electrolyte and changing the acid mist control method is being investigated.

Jan 1, 2007

By Juan Pablo Vielma

In this work we study how to incorporate risk control to the generation of ultimate pits when orebodies are modeled through a finite number of conditional simulations. To control risk we consider a chance constraint on the value of the ultimate pit. We incorporate this measure into the generation of ultimate pits by solving a stochastic programming version of the ultimate pit problem. We compare this stochastic programming problem to previous approaches such as generating the ultimate pit for each simulation and the hybrid pit approach introduced by Whittle and Bozorgebrahimi. We also study the effect of using different number of simulations in the generation and evaluation of ultimate pits.

Oct 1, 2009

By David Morley

This paper considers the ideal truck-excavator combination, defined as the combination resulting in the lowest direct unit cost, in consideration of multiple haul scenarios characterized by different haul distances, material and equipment availability. Through the application of Monte Carlo simulation, selected for its unique ability to handle the uncertainty of activity durations, the ?four to six passes? loading rule is shown to not correlate with the selection of the minimum cost fleet. Additionally, through the results of the simulation it is determined that the haul truck capacity has a greater effect on the overall efficiency of the system than does the excavator capacity. As a result, in order to arrive at efficient operations, the entire earthmoving system must be viewed as whole, namely, considering haulers together with excavators, as opposed to the popular method of first selecting a loading unit and then selecting a hauler obeying the ?four to six passes? loading rule. Furthermore, truck utilization and excavator utilization exhibit an inverse relationship and neither directly correlates with the overall efficiency of the earthmoving operation. The following conclusions are drawn: first, with limited financial resources, it is more valuable to increase hauling unit size before increasing loading unit size and second, predefined rules or generalizations, not based on evidence, potentially eliminate optimal truck excavator combinations from being considered.

Aug 1, 2013

By A. Alfantazi

Recently, titanium and its alloys have been the materials of choice for the liner and internal components of autoclaves used to extract Ni and Co from laterite ores. There have been many corrosion incidents ranging from localized attacks due to scale formation or welding, to damage caused by pockets of concentrated acid. Most of the literature focuses on methods to avoid the corrosion altogether. Little has been published to increase awareness of the chemistry at these conditions. For this paper, a literature review of the thermodynamics of titanium was undertaken to decipher the slew of information available. E-pH diagrams were constructed from select data and compared with the results of electrochemical experiments. Since nickel laterite leaching takes place in sulphuric acid, and in many cases chloride concentrations are very high, the Ti-H2O, Ti-Cl--H2O and Ti-SO4---H2O systems were considered.

Jan 1, 2004

By A. Pranowo, G. R. F. Alvear F., N. Aslin, M. S. Moats

"The toxicity of arsenic is well known and documented; however, the presence of arsenic in copper electrorefining anodes and electrolytes is critically necessary to produce high-quality cathode. Arsenic as well as antimony and bismuth concentrations vary relative to their concentration in the anode copper received from the smelter. The behaviour and benefits of arsenic in copper electrorefining and the detrimental effects of antimony and bismuth on cathode quality and tankhouse performance are discussed. This will include the minimization and mitigation of problems associated with arsenic, antimony, and bismuth—including cathode contamination, floating slimes, scaling, and anode passivation.RÉSUMÉ La toxicité de l’arsenic est bien connue et documentée; toutefois, la présence d’arsenic dans les anodes de l’électroaffinage du cuivre et dans les électrolytes est d’une nécessité critique pour produire une cathode de grande qualité. Les concentrations en arsenic, ainsi qu’en antimoine et en bismuth varient selon leur concentration dans l’anode de cuivre reçue de la fonderie. Le comportement et les avantages de l’arsenic dans l’électroaffinage du cuivre et les effets indésirables de l’antimoine et du bismuth sur la qualité de la cathode et le rendement des cuves d’électrolyse sont discutés. On traite aussi de la minimisation et de l’atténuation des problèmes associés à l’arsenic, l’antimoine et le bismuth – incluant la contamination de la cathode, les schlamms flottants, l’entartage et la passivation de l’anode."

Jan 1, 2016

By L. C. So, S. Faucher, S. Mostaghel, D. Sauter, S. -Y. Oh, S. K. Lee

"Molten material from pyrometallurgical furnaces is tapped at high temperature, carrying a large amount of heat. Traditional handling methods of slow air cooling or water granulation do not allow for the recovery of heat from slag and matte. Furthermore, water granulation adds an inherent safety risk of explosions. Recently, there have been numerous studies into processes attempting to recover waste heat. However, most of them have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple dry atomization system that allows for heat recovery while eliminating the use of water. Comparisons of pilot and commercialized dry atomization and heat recovery technologies will be presented and challenges of these technologies will be highlighted.INTRODUCTION Slag has traditionally been regarded as an undesired waste product from smelting operations with slag management focused on removal and disposal of “waste”. Over 500 million tonnes of slag are produced per year, carrying with it ~220 TWh of energy (Barati, Esfahani, & Utigard, 2011). Depending on the process, the energy content of slag ranges from 10-90% of the total energy input (Barati, 2011, Rodd, 2010). There has therefore been great interest in recovering energy from slag. Slag handling methods can broadly be classified into three categories: (1) dumping and slow cooling, (2) wet granulation and (3) dry granulation. As discussed below, only dry granulation routes are amenable to heat recovery. Slag dumping involves the slow cooling of molten material and crushing of the resulting solid. In this process, slag is dumped on the ground directly from furnaces or transferred to slag pots that are moved by rail or haulers and then dumped on the ground. The molten material is left to cool and solidify until it can be broken and handled by heavy machinery."

Jan 1, 2017

By J. M. Menacho

As usually occurs in technological development, heap leaching knowledge has been built upon two parallel lanes, theory developed on fundamentals but relatively far from industrial applications, and operational know-how generated from empirical trial and error. As a contribution to close the gap between the above-mentioned lanes, the De Re Metallica process consulting group has been developing and applying fundamentalsbased modeling tools for industrial process design and process optimization of existing plants over the last ten years. As result, a library of models is now available with application to the whole production chain from blasting to electro winning. This presentation is centered in heap leaching and several real case studies are developed, showing how paradigms are broken when fundamentals are applied. Cu2007 - Volume IV (Book 1) The John E. Dutrizac International Symposium on Copper Hydrometallurgy Edited by P.A. Riveros, D.G. Dixon, D.B. Dreisinger, M.J. Collins Toronto, Canada,

Jan 1, 2007

By S. Joshi, E. Asselin

An electrochemical quartz crystal microbalance (EQCM) was used to study the leaching of pure gold in deaerated 1 M Na2S solution. Multiple cyclic voltammograms were measured between -0.76 and 1.242 V (SHE) at 20 mV/sec and 2 mV/sec and the frequency shift of the quartz crystal was simultaneously measured. Both the forward and reverse scans showed oxidation occurred between -0.40 to 0.20V. The frequency shift increased during both the forward and reverse scans in the potential range of -0.40 to -0.06 V indicating electrode mass decreased. Since at -0.40 to 0.20 V oxidation peaks were also observed, part of the oxidation was due to oxidation of gold. Eh-pH diagrams were constructed and showed soluble Au(I)-S(IV) species formed between -0.30 and 0.10 V (SHE). Atomic absorption spectroscopy of the test solutions and the mass change recorded by EQCM both showed about 0.015 mg of gold leached. Since the majority of the frequency shift increase corresponding to gold oxidation occurred at -0.40 to -0.06 V during multiple cyclic voltammogram measurement, the total leaching of gold could be approximated to occur at this potential interval to give a leaching rate of ca. 6.4x10-5 mg/s-cm2.

Jan 1, 2011

By A. Fawcett, B. C. Dyer

Abstract - The basis of the tomographic velocity imaging technique is briefly described and an application of the method to detect and image a cross-section through a chromite pod is presented. Using the chromite application as an example, the relative costs of tomographic data acquisition and processing are compared with those of diamond drilling to obtain similar resolution. A number of different tomographic survey configurations and the potential role of the method in surface and underground exploration are discussed.

Jan 1, 1994

By Scott D. Long

"Abstract-Grass roots exploration has an emphasis on good precision at low (sub-economic) concentrations of an element, in order to identify "anomalies" which may lead to drilling targets. Although it is wise to have well-defined quality controls in place during early stage sampling, the control procedures at this stage tend to be rudimentary. When a deposit warrants detailed delineation, the need for accurate geological characterization and assaying of ore-grade rock must be supported by appropriate quality control procedures.As a project returns more promising results, and the likelihood of the project warranting a prefeasibility study increases, it is time to tighten quality assurance requirements and quality control protocols. Delays in instituting adequate quality control and verification procedures may lead to costly remedial actions that can also delay completion of the prefeasibility or feasibility study. Sometimes, as a project matures, the quality control and quality assurance aspects fail to keep pace with the changing nature of the work: an increasing emphasis on precise and accurate assaying of oregrade rock.A resource model is like a house of cards. The foundation of the house is the geological observations, the sampling methods and the geological interpretations performed upon those samples. Upon the sampling, which includes all the sub-sampling steps of sample preparation, rest the assay results. The quality of the assays can be no better than the quality of the sampling. Good assaying technique will preserve all biases and imprecisions introduced during sampling and sample preparation; it cannot remove them. If the sub-samples and/or assays are bad and must be redone, all the succeeding levels of the house of cards must also be rebuilt, or at least patched up.From geological observations, a geological interpretation is built, the quality of which is critical to the construction of an acceptable resource model. Geological elements are difficult to assess, and are not discussed here; they are dependent upon the expertise of the geologists involved. Geological knowledge contributes essential quality control elements to resource/reserve determinations (Sinclair and Postolski, 1999; Postolski and Sinclair, 1999).This paper consists of five sections: (1) overview of quality control protocols, (2) maintaining quality control of databases, (3) quality control of drill sampling, (4) optimizing crushing and grinding requirements, and (5) quality control of assay data acquisition."

Jan 1, 1998

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By Patricia Dillon

EHS Management Standards Communication and Reporting (8) ! Establish processes for internal and external communications ! Designate responsibilities for communication with COI ! Report as defined by senior management ! Report annually to employees, shareholders, COI on EHS and social performance Community Rights and Public Consultation (9) !Identify COI?s and establish process to hear concerns !Acknowledge and respond to complaints !Support local communities !Plan for closure and conduct public consultation !New projects include identification of COI?s, concerns to be considered in design

May 1, 2004