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Fault detection and identification are major challenges in process engineering and manufacturing and the key component of abnormal event management systems. Timely detection, diagnosis and rectification of abnormal or faulty process conditions can lead to savings of billions of dollars in equipment damage and lost productivity, not to mention the prevention of injury and loss of human life associated with industrial accidents. A major contributing factor to current losses in industry is the reliance on human operators to interpret high-frequency samples from hundreds or thousands of variables simultaneously. As a result, the automation of fault detection and diagnosis is seen as crucial to the successful implementation of abnormal event management, the need for which is becoming all the more urgent given the increased complexity associated with modem industrial plants. In this paper, a methodology for process monitoring that uses support vector methods to extract nonlinear features from data is discussed and applied in the diagnostic monitoring of an industrial liquid-liquid extraction column.

Jan 1, 2005

By Christopher W. N. Anderson

Induced hyperaccumulation of gold by plants was first reported in 1998 by researchers from Massey University in New Zealand who proposed the idea of mining gold using plants (phytomining). Since that time research has been conducted to understand the conditions under which plants can be made to take up economic amounts of the metal. One key focus has been on the geochemistry of gold-rich soils, leading to a diagnostic test that can predict how suitable a particular soil might be to gold phytomining. Field trials have been conducted at several locations around the world in collaboration with industry partners. A Decision Support System has been developed to assist in the design and management of phytomining operations, and economic modeling has been carried out to set targets levels for phytomining technology. Novel studies are now examining the form of gold in plants. Research suggests that plants may store gold as discrete metallic nanoparticles in leaf and stem tissues, an observation that may lead to new ways to recover the metal from harvested biomass.

Oct 1, 2003

By Thomas Clark

This report presents a review of the distribution and exploration potential of platinum-group elements (PGE) in Québec; it is based on published and unpublished analytical data. This qualitative evaluation of the PGE potential, whether in PGE-dominant deposits or in Ni-Cu-dominant deposits with co-product PGE, is based on interelement ratios such as Ni/Pd, Cu/Ir, Cu/Pt, and Cu/Pd. Good PGE targets, i.e., deposits associated with magmas fertile in PGE, are identified. Less favorable PGE targets, i.e., deposits associated with PGE-depleted magmas, are also mentioned. The importance of exploring for deposits similar to those at lac des Îles and East Bull Lake (Ontario) is emphasized.

May 1, 2001

By H. E. Lake

VERY EARLY in the initial stages of underground development work at Eldorado's Beaverlodge operation, the decision was made to use mill tailings as a backfill product. Mining and milling commenced in June, 1953, using locally available sand as backfill, while test work and installation of a plant was carried out to prepare ?and deliver the tailings to the mining areas. The first use of tailings was made in February, 1954, a sandslime separation being carried out with hydraulic cyclones. To date (January. 1956), approximately l 40,000 tons of fill have been used in the stoping areas, providing very effective support in a 50 deg. Vein system of cut-and-fill mining. The recoverable portion of the mill tailings amounts to 40 to 45 per cent, which has resulted in a product giving a percolation rate of 6 to 10 inches per hour. Owing to the fact that Eldorado has milled from 15 to 2 5 per cent more ore than it has mined, through the purchase of custom ore, the degree of control on the sand-slime separation has not been as critical as it might normally be when the filling operation must depend only on the tailings from ore mined. A description of the conditions involved and of the plant as finally installed is given below. It might be mentioned here that, with the impending increase in milling capacity from 700 tons to 2,000 tons p.er day, the present plant will be considerably altered within the ensuing year to handle the increased tonnage and distribution.

Jan 1, 1956

By Ralph Harris, Javier Jara

"Oxygen is essential in gold cyanidation. It is supplied to the leaching media by sparging oxygen or compressed air into the cyanidation tank. The rate of oxygen transfer is critical to achieve the desired oxygen concentration in solution.The performance of a novel device for gas sparging recently developed at McGill University is compared to the mass transfer characteristics of the two spargers most used in the gold industry: the four lance configuration and the inverted cone. The distribution of gas and the kinetics of oxygen desorption of the three types of spargers was studied in a 140 litre tank. The oxygen dissolution of the new device is three to five times faster than the other spargers. This could increase the leaching rate and/or decrease the cyanide and oxygen consumption.IntroductionIn hydrometallurgical processing, it is often necessary to bubble gas through a pulp to carry out the wanted reactions. The gas can act to agitate the pulp and it can also supply reactant. The rates of the reactions which require a reactant supplied by the gas are often dependent on the rates of mass transfer from the gas to the solution.A common example of this is gold cyanidation which requires oxygen for gold dissolution. Since the gold containing slurry is rich in other oxygen consuming substances (sulphide like pyrrhotite), it is important to provide enough oxygen to allow complete gold dissolution within the residence time of the cyanidation reactors. It has been demonstrated that the rate of gold dissolution is directly proportional to the dissolved oxygen concentration of the pulp which in turn is proportional to the oxygen partial pressure in the bubble 1 2 3. Improving the rate of mass transfer of oxygen increases the dissolved oxygen concentration of the slurry and therefore improves the rate of the reaction.The rate of mass transfer from a bubble to its surrounding solution increases with decreasing bubble size and increasing gas bubble residence time which in turn increases with decreasing bubble size. The generation and dispersion of small bubbles is thus critical to achieving high rates of mass transfer. Different configurations and devices used to inject gas have different effects on the bubble size and the residence time, influencing the overall rate of mass transfer. Therefore better mass transfer can be achieved by adopting a more efficient method.The methods tested in this report are the four lance configuration (wall spargers), the inverted cone and a new device, designated HCD. The wall spargers and the inverted cone are used widely in the industry today."

Jan 1, 1994

By Eiichi Sato, Koichi Kitazono, Hiroshi Masuda, Kenta Higane

"The present study investigated the low-temperature creep mechanisms in ultrafine-grained (UFG) aluminum manufactured by accumulative roll bonding. UFG aluminum with grain size 0.39 µm showed steady state creep even at room temperature under low stresses as confirmed by the creep curves in the strain rate–strain plot. The low-temperature behavior was divided into four regions by three distinctive stresses, sI, sII and sIII: sI (=45 MPa) is denoted as the micro-yielding stress with which dislocations start movement, sII (=85 MPa) the dislocation-multiplication stress above which dislocations multiply with creep deformation, and sIII (=171 MPa) the conventional yield stress above which macroscopic plastic strain is generated. During low-temperature creep, below sI, negligible plastic strain is generated. Between sI and sII, creep deformation with stress exponent 2.5 occurred, which is accommodated by dislocation absorption into grain boundary and grain boundary sliding, similarly to the low-temperature creep of HCP metals. Between sII and sIII, creep deformation with stress exponent 7.0 occurred, whose mechanism is similar to the low-temperature creep of coarse-grained aluminum. Above sIII, power-law breakdown occurred.INTRODUCTIONIt is well understood that the creep deformation brings about at high homologous temperatures (T/Tm) of >0.4, where Tmis the melting point, with diffusion processes. Recently, the importance of aluminum is increasing for cryogenic temperature parts such as a metallic liner or a cap in high pressure-hydrogen vessels, and the presence of creep behavior in aluminum at room temperature has become recognized (Matsunaga, 2013;Kassner, 2015).In HCP metals and alloys, especially intitanium, steady-state creep behavior appears at room temperature with apparent activation energy of1/10 of that for self-diffusion(Neeraj, 2000; Matsunaga, 2009).On the other hand, Kassner (2015) claims that aluminum shows creep behavior at room temperature with apparent activation energy of 4/5of that forself-diffusion, but never reaches the steady state. We should note that it is derived from the data obtained from short-term creep tests of few hour, and Matsunaga (2013) already claimed the presence of steady state in room temperature creep in aluminum with activation energy of 1/5of that for self-diffusion.The mechanisms for low temperature creep are considered different between HCP and FCC metals: in HCP metals, grain boundary sliding is observed and is thought to accommodate piled-up dislocations at grain boundaries through absorbing them. The so-called slip-induced grain boundary sliding occurs with low number of activated slip systems(Matsunaga,2009).On the other hand, in FCC metals, many activated slip systems bring about work hardening with dislocation cell structure formation. In the initial stage of creep, it results in primary creep (Kassner, 2015), but Matsunaga (2013) claimed that once the annihilating of a cross-slipped dislocation to another reaches balance, steady state is established. It has been, however, strongly required to show more convincing experimental verification for the presence of steady state in FCC metals at low temperature."

Jan 1, 2018

By Elbasher M. E. Ahmed, Indresan Govender

"A mechanistic model of axial charge segregation in rotating drums is presented. We show that granular material composed of different frictional properties diffuse into axial bands as a consequence of concentration fluctuations in the free surface layer that is caused by friction-limited mobility. A Bagnoldian stress assumption ensures an asymmetric free surface profile thereby providing the essential ingredients for the evolution of axial bands and the subsequent band coarsening observed in the literature. The formulation is sensitive to the boundary conditions of tumbling mills, including particle size and density, mill speed, inter-particle bulk friction, end wall friction and drum geometry (length and diameter).INTRODUCTIONA mechanism to fully describe the axial segregation of charge in a rotating drum remains elusive to the mineral processing industry. With regard to low aspect ratio mills (like ball mills), current thinking favours the use of closed circuit mills with correspondingly low residence times to offset the completely random contact probabilities between particles and balls (Wills & Napier-Munn, 2006). Conical end caps are argued to exploit the centrifugal force to achieve a regular gradation of ball size along the mill with larger sizes at the feed end and smaller ones closer to the discharge. However; segregation along the length has been observed in the absence of conical end caps (Oyama, 1939; Levine, 1999): In these investigations, sufficient differences in the particle’s mechanical properties (particle size, density, shape, surface roughness) was enough to successfully achieve axial segregation. Figure 1 shows the segregation of a bimodal distribution (by size) into bands of larger (darker colour) and smaller (lighter colour) particles."

Jan 1, 2016

By Victor Rudenno

"Previous methods have employed statistical analysis to model future mineral resources. The method presented in this paper uses Zipj's Law to determine the size and grade of tin deposits still to be discovered. The law is applied independently to both known deposit tonnage and grades. A probability distribution for both 'tonnage and grade is computed/or those deposits still to be located and then, by applying a correlation between tonnage and grade, a distribution of the probability of metal content discovery is obtained.By considering an economic cut-off in metal contained in a deposit, the probability of economic success for the next tin discovery is computed, both for a world discovery and for the special case of Tasmania, Australia. The results indicate a probability of 11-37% on a world-wide basis and 18% chance of economic success in Tasmania.IntroductionIn the past , most attempts to determine the probability of success in finding an economic mineral deposit have relied on the accumulation of statistical data. These data are then used to predict a suitable frequency distribution to assess the probability of finding a deposit of a given size and grade (Singer,1975).The method not only relies on one having sufficient data, but also on the assumption that the data are not biased and that the distribution (usually log-normal) is a correct one. The method presented in this paper, to analyze tin deposits, uses Zipf's Law, which has been recently applied to oil, uranium, lead-zinc and gold deposits by Folinsbee (1977) and to Western Australian gold deposits by Rowlands and Sampey (1977). Tapp and Koniuszko (1978) have applied Zipf's Law to mineral distribution patterns in the Northern Australian orogenic provinces, which has enabled them to make predictions with a relatively small data source."

Jan 1, 1981

By J. M. Livingstone

"This paper covers some of the problems confronted by Canada's railways in moving bulk materials from their source to the dock-site. The ""cost center"" concept is presented, and hypothetical examples of its use given. Also discussed are systems design, the unit train and pipelines.INTRODUCTIONCANADA LIVES BY RER EXPORTS and the Port of Vancouver by the exports of the Mountain and Prairie Empire at her back. The most recent estimates of off-shore shipments of bulk from the Port of Vancouver rise to 35.8 million shipping tons in 1985 and deep-sea general cargo estimates, in and out, are estimated at 7.6 million shipping tons for the same year. This compares to 7.67 and 2.87 million shipping tons, respectively, in 1965."

Jan 1, 1968

By P. L. Wright

"This is a brief history of the development of the mining project, with a description of the proven geology. The paper describes how the experiences gained progressively demanded change in the mine design. The equipment used is described, together with methods of working. Interesting facts have been proved regarding gas emissions and roof. supi;iort. The. working cycles evolved are completely flexible m operation and lend themselves to maximum utilization of the most productive units. The two underground mines are compared, showing the variance in conditions already experienced. Programs currently in operation to improve standards and production are: the training of miners, maintenance men and officials; experiments in floor consolidation and continuing roof support trials; and the effect of comparative stability of working crews on the performance of the operation."

Jan 1, 1973

By D. J. Lloyd

"Bending is involved in the forming of many sheet parts and it is important to understand the phenomena involved. In this paper the basic equations describing bending on a global scale are compared with strain measurements of bent sheet. The development of strain on a local, microstructural scale is also investigated, as is the general aspects of plasticity and the failure process. It is shown that the global equations can be used to estimate the strains involved and the local strains can be attributed to various aspects of the plasticity. The bendability can be related to the fracture strain of the sheet and the ability of a sheet alloy to accommodate the necessary bending to form the part can be assessed.INTRODUCTION The ability of a sheet alloy to undergo bending without failure is an important capability in the forming of many parts and it is useful to be able to assess the bendability of an alloy during its development. The basic mechanics of bending were developed in the 1950s (Lubhan & Sachs, 1950; Hoffman & Sachs, 1953). When a sheet is bent the upper bend surface is in tension, the lower surface in compression and at some point within the sheet there is a plane of zero strain which is referred to as the neutral axis. For sheet exhibiting limited plasticity the neutral axis is static and occurs at the mid-point of the sheet thickness but for sheet exhibiting extensive plasticity the neutral axis progresses deeper in to the sheet as bending progresses. This results in two expressions for the maximum strain at the upper bend surface depending on the motion of the neutral axis. For Al alloys such as AA6111, AA6016 and the like extensive plasticity occurs and the neutral axis is expected to move during bending. However, very few studies have examined how the neutral axis motion and the strains develop, compared with the mechanics analysis. Geist and Parker (1984) used hardness measurements to investigate neutral axis motion but these experiments did not have the resolution necessary to compare the results with experiment but did indicate neutral axis motion. To understand the nature of plasticity and failure during bending it is important to know the extent of neutral axis motion, the scale of strain gradients developed through the sheet and the maximum strains occurring at the bend surface, finally comparing experimental results with the theoretical predictions. The influence of microstructure on the evolution of strain and failure can then be considered in the context of these parameters. Recently, bending in some automotive Al alloys has been reported mainly from the microstructural perspective (Lloyd, 2000, Lloyd et al., 2002, Mattei et al., 2013) and FEM studies have also investigated the development of plasticity under bending, demonstrating the tendency for strain localization (Becker, 1992, Shi et al., 2014)."

Jan 1, 2018

By Marcel Laflamme

Underground mine workers are continuously exposed to many sources of noise and vibration in carrying out their tasks. Even though the vibration and sound level of some mining equipment is documented, it was found that this information is not readily available for many pieces of equipment and that it is not considered when choosing equipment or planning tasks. As well, health problems related to vibration and noise are among the main causes of work-related compensations in mines. Considering those facts and although no Canadian regulations could force employers to limit the exposure of their workers to vibration, the Société de recherche et développement minier (SOREDEM) decided to address the problem by including vibration among their research priorities. In order to characterize noise and vibration sources of different mining equipment used for underground mining, the authors have performed a study in 8 different mines in Québec on 28 different mining equipments. The paper will present the procedure that was followed to select the list of equipment to be evaluated and the low cost acquisition system developed to perform multichannel time domain acquisition in harsh environments. It will also present the results obtained for the noise level produced by the equipment as well as for the hand-arm and whole-body vibration exposures.

Aug 1, 2013

By S. Z. R. Pinkney

Positron Emission Tomography (PET) is a medical technique that produces three dimensional images of the body, commonly to aid diagnosis and treatment of tumours. PET has been developed by the University of Birmingham in order to track particles in an opaque system which is known as Positron Emission Particle Tracking (PEPT). The object to be tracked is irradiated. As the radionuclide decays positrons are produced; when these collide with electrons a pair of concurrent parallel back-to-back gamma waves are emitted and detected, from which the position of the object can be calculated. Stirred media mills are used for particle size reduction. The mill is usually operated at high solids loading with grinding media and has a polyurethane or polyurethane-lined steel pot and is thus opaque. For this study grinding media has been directly irradiated and tracked using the PET camera during the grind. The stirred media mill can be divided into cells of equal volume known as voxels. The fraction of the total time the irradiated media spend in each voxel can be shown in an occupancy diagram. The mean velocity and kinetic energy of the media for each voxel are calculated and also plotted. In occupancy and kinetic energy plots colour indicates the value of the voxel, in dimensionless time and Joules respectively. The arrow in velocity plots shows direction and length of arrow indicates magnitude of the mean velocity for the voxel. From these diagrams and further data analysis a detailed understanding of the flow patterns, media behaviour and high energy areas of the mill can be developed. Variables considered were the tip speed of the impeller and density of the grinding media. It was found that the grinder has three distinct regions: above, at and below the impeller with each region having its own flow patterns and velocity and kinetic energy profiles. These are different for each variable and so are used to characterise the grind. Tip speed and density of the grinding media were shown to both affect the velocity of the media and the proportion of time spent in the each region of the grinder.

Aug 1, 2013

By A. O. Orumwense

Mill circumferential speed, the number of passes of pulp through the grinding chamber, media type, size and filling ratio were investigated in an attempt to determine how to effectively grind copper concentrates in a stirred mill. The stirred mill product fineness was enhanced to some extent by decreasing media size, high media filling, and an increased number of passes of the pulp through the grinding chamber. Shape also plays a major role in grinding media effectiveness, with spherically shaped media producing a finer size. The fineness of the product increases with increasing power consumption but the method of energy transfer is very important in energy utilization. The effect of the mill parameters on copper flotation was evaluated. Copper recovery was influenced by grinding media size, mill speed and the number of pulp passes through the grinding chamber.

Jan 1, 2006

By S. Banisi, J. Marois, A. R. Laplante

"This paper compares the behaviour of gold and ore in the grinding circuit of Hemlo Mines Ltd. Particular attention is given to grinding kinetics, classification behaviour, and liberation. For grinding kinetics, laboratory grinding of gold flakes and silica, 840 µm to 1200 µm in size (14/20 mesh), was also performed to provide a standard for comparison and to study in a controlled environment the mechanisms of breakage, folding , smearing and impacting.Grinding kinetics were characterized at laboratory scale with breakage and selection functions. The breakage function showed that 75% of gold disappearing from the 840 µm to 1200 µm class reported to the 600 µm to 840 µm; this figure is much higher than for silica (46%) or most other minerals, and implies that comparatively fewer fine fragments are produced from the breakage of gold flakes, on account of gold's malleability. The selection function of silica was four times that of gold. At plant scale, the ratio of the selection function of ore and gold increased from 6 for at 50 urn to JOO pm to 20 at 500 um to 1000µm.Observation of original flakes and their fragments with the scanning electron microscope showed that the main mechanism of ""grinding"" from the 840 µm to 1200 µm to the 600 µm to 840 µm class was folding rather than actual breakage. This was confirmed by a measure of individual flake weight. The postulated breakage cycle is that relatively globular flakes become increasingly serrated through grinding; they can then regain their original shape through folding and reflattening into cylindrical and spherical shapes, as the majority does; however, some fragments will at this point undergo actual breakage. Photograhic evidence is presented to support the proposed mechanisms.Smearing of gold unto silica was observed when silica was ground after a gold, and embedding of silica into gold flakes when gold was ground after a silica. Both mechanisms occur whenever gold and harder minerals are jointly ground, and result in ""unliberation"" of gold. It is postulated that smearing of gold onto other minerals plays an important role in explaining how gravity recovery can increase over-all gold metallurgy, especially when used ahead of flotation.Classification of gold in the primary hydro cyclones takes place at a much finer cut-size than ore, 20 µm vs 57 µm. This and the slower grinding kinetics result in high gold circulating loads in the primary loop, 6700%, and a gold content in the primary cyclone underflow (PCUF) is twenty-four times that of the ore. The gold size distribution for primary cyclone overflow is much finer than that of the ore, although they are essentially similar in the PCUF.Liberation, or more accurately ""gravity recoverability"", was assessed with a 7.5 cm (3 in.) Knelson concentrator. It varied between the thirties for the primary mill discharge and two cyclone overflows, to highs of 89% and 92% for the PCUF and secondary mill discharge."

Jan 1, 1991

By H. K. Olsen, B. Thomassen, H. K. Schønwandt, L. Grahl-Madsen, H. Stendal

Abstract-The central part of the early Proterozoic Ketilidian orogen in South Greenland consists of an I-type granitoid batholith transected by four regional NE-SW-trending shear zones. The batholith was probably emplaced during subduction, from the south toward the Archaean craton in the north, in a sinistral transpressional system. A regional sediment sampling program covering 5000 km2 shows a close connection between a gold-mineralized trend and one of the major shear zones within the epizonal facies of the batholith. The gold mineralization is not directly related to the major shear zones, but occurs in quartz-veined and silicified second-order structures. High-grade (up to 114 ppm Au over 6 m) low-tonnage mineralization is found within these second-order structures cutting both amphibolites and granitoids. The mineralization is characterized by negligible or small alteration halos. Gold is associated with various element combinations of enhanced As-Bi-W- Cu, which indicate that the mineralization is mesothermal in origin.

Jan 1, 1995

By Mahmoud Shakeri1

Various types of thin-walled structures have been frequently used as energy absorbers to mitigate the adverse effects of impact and hence protect the vehicle structure under consideration when subjected to different loading conditions. Compression tubular structures that buckle in a progressive manner, can be used to advantage, providing inexpensive and versatile, but nevertheless weight and stroke efficient energy absorbers. In this paper quasi-static nonlinear finite element simulations are performed to study the effects of number of corners of the cross-section, wall thickness, plastic hardening rate of material, foam-filler and load angle on deformation mode and mean crushing force of tube. Crush strength increases as the number of corners of the cross-section increases, though it almost saturates for the number of corners beyond 11. Higher plastic hardening rate stabilizes the collapse pattern. Foam-filled tubes seem to have higher critical load angles in oblique loading and display a more stable and gradual decrease in mean load over the transition region. Substantial decrease in the initial peak load and dynamic load at any a given deflection was observed as the load angle increases. The investigation of bitubal arrangements and Multi-cell tubes reveals that these may be preferable to monotubal specimens due to the presence of the inner profiles. In addition, a comparison is conducted between the numerical and experimental results of the mean forces of some special angle elements. Good agreement is obtained.

Oct 1, 2011

By T. R. Yu, D. B. Counter

"In an effort to increase productivity, the use of fly ash as a binder for consolidated backfill was studied. From laboratory and underground tests f or its cementitious properties and environmental effects, it was found that a portion of Portland cement could be replaced by the same amount of type ""C"" fly ash to produce an acceptable consolidated rockfill product for use at Kidd Creek.The environmental concerns in terms of dust control and emanation of radon gas were unfounded from measurements. The dust count was comparable to the use of Portland cement only, or with ground blast furnace slag, and the radiation readings were low, averaging one-seventh the regulation level.Since May 1984, a total of over 100 000tonnes of fly ash has been consumed as a binder blended with Portland cement, producing over four million tonnes of consolidated rockfill. To date, the fill in the stopes has performed very satisfactorily, while yielding considerable cost savings.IntroductionThe Kidd Creek minesite, located 27 km north of the city centre of Timmins, Ontario, produces 4.5 million tonnes of base metal sulphide ore annually. The mining method for both No. I and No .2 mines is mainly sub-level blasthole stoping with delayed backfilling.No. 1 mine was developed with a shaft to a depth of 930 m in 1973 to recover the ore between the floor of the open pit at the 216 m horizon, and the 792 m horizon. Stopes are normally 18 m wide, 22 m to 65 m long, with heights varying from 90 m to 135 m. Vertical rib pillars between stopes are typically 24 m wide and sill pillars are 30 m thick.Pillar recovery is implemented after the consolidated rockfill placed in the mined stopes has cured for a period of at least three months. This allows a maximum recovery of the ore with a minimum of dilution, while also maintaining safe working conditions.No. 2 mine was developed from a second shaft, sunk to a depth of 1530 m in 1978, for the recovery of ore beneath the No. I mine. Sub-level stoping in No .2 mine is similar to No.1 mine in methodology, yet differs in sequencing, as no rib pillars are left."

Jan 1, 1988

By E. Mataradze

Statistics shows that the majority of accidents with fatal outcome are caused by methane and/or coal dust explosion. This leads to assume that contemporary counter-explosion systems of various designs cannot be considered effective. Considering the growing threat of methane explosion in the coming years along with the development of deeper levels, the improvement of a system for protecting people in underground opening appears urgent. This paper presents the results of the testing of the Automatic System from Methane Explosion in Coal Mines. The protective system consists of: i) a wireless device for the detection of explosions and activation of a protective system, and ii) an absorber with a pyrotechnic device ensuring the discharge of dispersed water. The protective system, at the command of the initiation signal, produces tailored dispersing water mist with droplet sizes in the range of 25?400 ?m along selected tunnel sections.

Aug 1, 2013

By So-Yeong Lee, Moosang Lee, Seung Hwan Ahn, Ho-Sang Sohn, Jongshin Chang

It is necessary to understand the characteristics, phase changes and chemical reactions of flue dusts introduced from a furnace to an off-gas line in order to achieve the stable operation and the improvement. This study is to develop the dust reaction model for chemical reactions of dusts in an uptake shaft of smelting furnace and a waste heat boiler. Phase equilibria and reaction paths in this system were determined by thermodynamic calculation with experimental and industrial data. The oxidation reaction rate of dusts was determined by the gas film mass transfer controlling. And the sulfation reaction rate was evaluated by the unreacted shrinking core model. Kinetic parameters were estimated by reference data including industrial ones. The present study with the developed model shows various effects of temperatures, dust particle sizes, and O2 gas partial pressures on dust reactions. INTRODUCTION The flue dusts from a copper smelting furnace move along a furnace off-gas stream into an uptake shaft and a waste heat boiler (WHB) and electrostatic precipitator(s). It is necessary to control the dust quality in order to stabilize the operation because the sticking behaviors differ depending on the phase of dusts. Phase changes of dusts are caused by chemical reactions at given conditions such as temperature and partial pressure of gases. Therefore, it is required to understand the phase changes and chemical reactions of dusts in order to perform the improvement and stable operation. The present study carried out the investigation to understand their fundamental knowledge. Especially, this study was focused on the kinetics of chemical reactions of flue dusts, developed the model. In particular, the scope of development and utilization of the model was defined as the uptake shaft of the Mitsubishi S furnace and the S-WHB radiation section in the Onsan smelter. Information needed for the modeling work referred to data from these processes.

Jan 1, 2019