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By Ki-Bok Min, Seokwon Jeon, Seung-Beum Choi, Taehyun Kim

"In order to investigate anisotropic characteristics of Boryeong shale in Korea, which clearly shows transverse isotropy, a series of experimental tests were carried out. Using Brazilian test, five elastic constants and tensile strength of the shale were evaluated. Elastic constants were determined by iterative procedure and in order to perform this procedure, constitutive model was modified to fit the experimental condition. The anisotropic ratios of elastic constants were evaluated and the applicability of the methodology was assessed. Apparent Brazilian tensile strength profile was investigated and the ratio of the maximum to minimum tensile strength was estimated. Results showed that the tested rock type had low to moderate anisotropic characteristics.INTRODUCTIONMechanical, thermal and hydraulic characteristics of many rocks vary according to direction, which is known as inherent anisotropy, and it is originated from stratified and/or foliated structure of intact rock and discontinuity of rock mass. Anisotropy is one of the long standing issues of rock mechanics field and it has to be taken into account in several engineering fields such as civil, mining and petroleum engineering. An anisotropic medium has 21 independent elastic constants without any assumption of symmetry. If a material has any symmetry, the number of elastic constants required to define its behavior reduces and eventually two constants are necessary if it has complete symmetry, which is known as isotropy. An anisotropic medium that has remarkable planar structure due to its stratification and foliation such as bedding is often called as a transversely isotropic medium. Transversely isotropic model is frequently adopted in many applications especially for sedimentary rock formation and five elastic constants are required to establish the constitutive model."

Jan 1, 2015

By Seong-Taek Lim

Recently, 7xxx aluminum alloys have been evolved into new variants for thick semiproducts which have low amount of 2nd phases and low quench sensitivity. Commercial 7xxx alloys, especially in the thick forgings made of big ingots, often entail microstructural inhomogeneities and concurrent poor mechanical properties due to limited heating ranges and slower quench cooling. In this study, high strength aluminum alloy 7175 and 7050 are adjusted as an attempt to control the equilibrium phases (M-, T- and S-phase) to have optimum microstructure for the thick forging applications. The effects of the relative content of (Zn, Mg, Cu) on the evolutions of the coarse equilibrium phases, hardening response and resultant mechanical properties are investigated. Equilibrium phases (M,T,S) are evolved depending on the constitutional effect, primarily the change of Zn:Mg ratio, and cooling rate following solutionizing. The formation of the T- and S-phases is effectively controlled, and M-phases are homogeneously precipitated in the adjusted (dilute and high Zn:Mg ratio) alloys. It provides extended heating range and lower quench sensitivity than conventional alloys. The attempts ensure the microstructural homogeneity and improved properties, and is expected to be uniquely applicable in 7xxx thick forgings.

Jan 1, 2004

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By R. W. Zeindler, D. A. Fawcett

"A summary is presented of the report completed by the Coal Mining Research Centre in 1980. This report was of a cross-pit conveyor system applied as an auxiliary mining complement to the major stripping unit, a dragline. The purpose of the CMRC report was to evaluate selective mining and replacement of the upper horizons of the strata as an aid in reclamation. These strata were the topsoil, subsoil and glacial till.Past utilization of cross-pit conveyor systems and related engineering studies were assessed. The parameters of the study were based on the mining and geological conditions of the Alberta prairie coal mines. The principal excavator for stripping was a dragline. Excavation of the upper horizons was done by a bucket-wheel excavator discharging onto the crosspit conveyor. Alternative equipment applications were economically compared. Four cases or geological sections were evaluated in detail. The economics of the alternative mining systems for each of the cases were determined. In all instances, the most economical solution was a tandem system utilizing a dragline with a bucket-wheel excavator/ cross-pit conveyor system."

Jan 1, 1981

By Georges Houlachi, Raynald Labrecque, Jean-Noël Cloutier

"Electrodialysis (ED) is an electro-membrane technology based on electrochemical process using electrical energy for the production of chemicals. The process can be used for concentrating, extracting, separating products, modifying molecules, purifying solutions, pH adjustment and regenerating salts into their base and acid. This paper reviews the principle of ED, present some of the different options and discuss applications that are relevant to the hydrometallurgy and mining industries for the treatment of effluents focusing on recovery of chemicals (acid and metals) and recycling of water minimizing the environmental footprint.INTRODUCTIONElectrodialysis (ED) is usually defined as an electrochemical separation process in which electrically charged membranes and an electrical potential difference are used to separate ionic species from an aqueous solution and other uncharged components [1]. ED technology consists of an electro-membrane technology based on an electrochemical process using electrical energy for the production of chemicals. It is a method combining electrolysis and dialysis was proposed for the first time in 1890 by Maigrot and Sabates [2]. In the late 1930s Teorell, Meyer and Sievers discussed membrane phenomena, revealed membrane potential, electric conductivity, transport number [3]. Meyers and Strauss introduced a multi-compartment ED apparatus consisting of two electrodes and a stack of ion-exchange membranes between them [1]. They succeeded to double the concentration of a KCL solution [3- Tarleton]. In general, ED consumes less energy than electrolysis to perform salt splitting. In that regard, one can expect an energy reduction of about 30% [4–5]. ED offers a great versatility in the domain of separation processes. Indeed, it can be used for concentrating, extracting, separating products, purifying by desalination, pH adjustment and regenerating a salt to acid and base components. This paper reviews the principle of ED, presents various options available and discusses potential applications relevant to the mining and metallurgy industries with economics of some successful industrial applications."

Jan 1, 2016

By F. R. Ploeger, J. H. Crocket

"IntroductionRocks in the Kirkland Lake district form part of the Timiskaming Group, a south-facing homoclinal sequence of wackes, conglomerate, trachytic flows and pyroclastic rocks and syenitic intrusive rocks. Hewitt (1963) indicates that the thickest section, about 5 km, of the Timiskaming Group rocks is attained in Lebel Township. Several writers (Thomson, 1948; Hewitt, 1963; Hyde, 1978; Jensen, 1978; and Downes, 1979) have observed that the Timiskaming Group unconformably overlies the Keewatin volcanics, particularly along the northern contact. Recent work by Downes (1979) in McGarry and McVittie townships to the east of Kirkland Lake has shown that much of what had formerly been classified as Timiskaming actually belongs to an older group of rocks, the Larder Lake Group (Jensen 1978).General GeologyA series of fluviatile, braided-stream sedimentary rocks (Hyde, 1978) form the oldest of the three major rock suites at Kirkland Lake. Conglomerates constitute a large proportion of these sedimentary rocks and typically contain a large percentage of a variety of locally derived alkalic rock clasts as well as the distinctive red jasper iron-formation pebbles (Fig. 1a). The associated wacke units can be massive to finely bedded and are interbedded with the conglomerate. They also contain a large alkalic tuffaceous component.Interbedded with these sedimentary rocks are alkalic extrusive rocks, including tuffs, agglomerates, breccias and flows, which represent episodes of fissure and explosive crater eruption (Cooke and Moorhouse, 1969). The tuffs, although dominantly alkalic in composition, are commonly reworked and contain sedimentary features such as graded bedding, scouring and crossbedding (Fig. 1 b). The trachytic flows are massive to porphyritic and outcrop mainly east of Kirkland Lake in the adjoining townships. Altered leucitic porphyritic flows, locally referred to as red and green spotted trachytes, commonly occur."

Jan 1, 1982

By S. Jayasekera, A. M. T. S. Bandara, J. Kyle, E. Koenigsberger, L. Koenigsberger

The extraction of rare earth oxides from fluoroapatite rich phosphate concentrates often involves a weak acid leach of fluoroapatite and a sulphuric acid bake of the leach residue followed by water leach and precipitation to obtain an intermediate product. The main aim of this study was to determine and rationalize the solubility of rare earth metal ions in synthetic solutions representing various process liquors at the temperatures 40, 60 and 80oC. The liquors contained different acid and metal ion concentrations with respect to sulphuric acid, phosphoric acid and sulphate salts of sodium, magnesium, aluminium, potassium, calcium and iron(III). A solid of mixed rare earth carbonates was used as the source of rare earth metal ions. The solubility tests and characterization of solids using XRD were conducted at Murdoch University laboratories as part of the process development for the Arafura Resources Nolans rare earth project. The composition of initial carbonate solids and the solids and solutions formed after saturation were analysed for rare earth and other elements at TSW Analytical Laboratories in Perth using ICP-MS and ICP-OES. The precipitated solid in sodium-rich acidic sulphate solutions is the double salt NaRE(SO4)2 based on the solid assays. However, in acidic solutions free of sodium or of low concentrations of sodium the precipitated solid appears to be RE2(SO4)3.

Jan 1, 2014

By J. J. Barakso, S. J. Horsky, H. V. Warren

"A review of past and present biogeochemical studies is given. Early and more recent analytical procedures are described and compared. Tables 1-5 give silver concentrations in various organs of some plant species at different localities. Table 6 and conclusions provide guidelines for exploring for silver using biogeochemistry.IntroductionBiogeochemistry has been shown to be a useful tool in the search for gold deposits, especially those of the disseminated type (Warren and Barakso 1982). The purpose of this paper is to demonstrate that biogeochemistry can also be of assistance in searching for silver concentrations buried by as much as twenty feet of overburden without inflicting any damage on the environment."

Jan 1, 1984

By C. H. Bertoni

"The Superior Province of the Canadian Shield is the largest gold producing area within Archean greenstone rocks in the world, with total production of over 140 million ounces of gold. One hundred and fifty-five mines have individually produced more than 8,000 ounces, although only a relatively limited number of deposits (33) produced more than one million ounces of gold. The output from these 33 deposits accounts, however, for 85% of total gold production. The majority of grades (68%) ranges between 0.10 and 0.30 ounce per ton, and there is no linear relationship between grade and tonnage.Development of new gold mines reflects the history of gold prices. However, the response to the latest increase in gold prices was not as marked. It is concluded that gold deposits are becoming increasingly more difficult to find and new exploration techniques are urgently required.IntroductionWith most of its production coming out of the Superior Province, the Canadian Shield is the largest producer of gold from Archean greenstone rock s in the world. In total gold production, the Superior Province is surpassed only by the paleo-placers of Witwatersrand and the placers of the USSR (Anhaeusser, 1976). There has been no attempt so far to compile the historical production of the Province as a whole in a single document. The aim of this work is to fill this gap, not only for the convenience of having a complete list of gold producers, but, more importantly, as a basis on which to study the tonnage and grade characteristics of these deposits."

Jan 1, 1983

By Oscar F. Tangel

This paper outlines Canada's current status in world iron ore markets, and evaluates the prospects for the future. Estimates for the production, export and consumption of iron ore are given. Canada's major market will continue to be the United States, with the European Common Market countries, Japan and the United Kingdom also forming important outlets. The advantages held by Canada's major competitors in these latter three market areas are briefly discussed.

Jan 1, 1966

By A. Warczok

The mechanisms and kinetics of copper oxidation and reduction have been investigated in small scale thermal gravimetric experiments as well as in laboratory pilot scale, packed bed reactors. With blister copper flowing gravitationally down through a packed bed of ceramic particles, counter-current to low oxygen containing combustion gases, the rate of oxidation was found to be very high due to the large surface area created. Similarly, reduction by flowing copper through a packed bed of charcoal lead to rapid de-oxidation. Based on these laboratory measurements, fundamental rate data have been obtained. Modeling of industrial sized packed bed reactors using the laboratory results, opened up the possibilities of developing a new, very intensive, continuous process for copper fire refining. The developed mathematical model together with a computer process simulator, allowed for the design of the industrial-pilot installation to be built and tested at the ENAMI Paipote smelter in Chile.

Jan 1, 2007

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

By M. Abumiya, N. Onodera

Stabilization of arsenic via the precipitation of large-sized scorodite (FeAsO4·2H2O) particles usually involves the use of expensive autoclave systems operated under high temperature and pressure conditions. Alternatively, DOWA developed a novel scorodite synthesis process (DMSP®) wherein the Fe(II) ions in solution containing As(V) ions were oxidized by O2 gas under atmospheric pressure. In this process, crystalline scorodite particles were formed via the formation of a gel-like precursor containing Fe(II). Based on this concept, in this study, we have demonstrated the synthesis of scorodite particles by the addition of Fe(III)-containing solution to the experimental solution containing Fe(II) and As(V) ions, without the O2 gas oxidation process. Ferric sulfate (Fe2(SO4)3) was used as the source of Fe(III) ions. Results indicate the precipitation of scorodite particles, comparable to that of the O2 gas oxidation method.

Jan 1, 2014

By T H. Clark, R P. Doig, V. A. Saull, R B. Butler

Terrestrial heat flow has been determined for four boreholes in the Montreal area. The mean value of the results (uncorrected for glacial effects) is 0.790 ± 0.053 x 10-6 cal/ cm2/sec (95 per cent confidence limits). Thermal gradients were determined using a thermistor probe and d-c bridge, and also by a new method using a probe-contained phase-shift oscillator, the output frequency of the oscillator being a function of probe temperature. Thermal conductivity determinations were made on core from the boreholes, using a divided bar apparatus. INTRODUCTION T HIS paper concerns the terrestrial heat flow in the St. Lawrence lowland of Quebec, as determined from measurements on four of the numerous boreholes drilled in this region for gas and oil. The work has been supported by Geological Survey of Canada Re-search Grant 3-58, awarded to T. H. Clark and V. A. Saull. This sup-port is hereby gratefully acknowledged.

Jan 1, 1962

By L. C. Bird, A. I. A. Salama, M. W. Mikhail

"A program of sampling in Canadian washeries was carried out by the Coal Research Laboratory (CRL) over a period of two years to evaluate the performance of various density separators in these operations(1). Operating data on quality and recovery of products, separation efficiencies and cutpoints for each separator type are compared with data predicted using computer models developed from previously existing data.The Heavy Medium Cyclone (HMC), Heavy Medium Bath (HMB) and jig models give predictions of recoveries and qualities of products for sizes coarser than 10mm with absolute value of error mean less than 7 per cent, whereas predictions of the Water Only Cyclone (WOC) model for -10mmfine coal are with absolute value of error mean less than 8 per cent. Although less accurate for -10 mm fine coal, the HMC and jig models produce predictions of recoveries with absolute value of error mean less than 2 per cent and quality of products predictions with absolute value of error mean less than 28per cent which are generally acceptable because more liberation in the fine fractions appears to compensate for any difference in the accuracy of separation, resulting in good prediction of the clean product. However, ash content of the actual fine refuse was lower than predicted. The difference is attributed to the highly friable nature of Canadian coals which tends to cause an excessive loss of coal fines to the fine refuse.A comparison study based on quality and recovery of products is made between the Dutch State Mines (DSM) models and the recently modified models, both produced comparable predictions."

Jan 1, 1985

By C. Desmeules

"Carbon addition in the oxide pelletizing process is a big concern at the Sidbec-Normines pelletizing plant since 1976.Laboratory pot-grate testing carried out before the initial start-up of the Port-Cartier plant indicated that the nominal pelletizing grate capacity could be increased by fifteen per cent with a suitable carbon addition. Also an improved induration cycle offered the possibility of a significant energy reduction within the process with no adverse effect on pellet quality. A one-month plant scale program duplicated the lab test results and confirmed the anticipated cost saving by using these techniques. Since March 1980, Sidbec-Normines used coke addition as a current operation.This paper reviews briefly earlier laboratory and in-plant test work carried out to investigate the effects of adding carbon materials to the Fire Lake hematite concentrate, and presents operation techniques and plant results of carbon addition in the Port -Cattier pellet plant.IntroductionThe Sidbec-Normines pelletizing plant at Port-Cartier, Quebec, is designed to produce six million ton s per year of oxide pellet s. It is a Dravo-built two-line plant; one line to produce three million s tons per year of blast furnace grade pellets averaging 5.5 per cent silica, and another line of three million ton s to produce direct reduction grade pellets of about 2.0 percent silica.The laboratory pot-grate test program was conducted in 1977 at the British Steel Corporation Research Laboratories in England, with the assistance of J .E. Appleby, consultant to British Steel Corporation (overseas services) Limited.The purpose of that test program was to determine the optimum energy saving cycle and to study the physical and metallurgical effects on blast furnace and direct reduction pellets."

Jan 1, 1983

By S. Masambi, S. M. Bradshaw, C. Dorfling

The presence of iron in base metal leach solutions complicates nickel and copper recovery processes. Leach solutions are commonly purified by precipitating iron as hematite, jarosite or goethite. Fast oxidation of ferrous to ferric is an important step to remove iron by precipitation at low pH values. This study reviews the ferrous oxidation mechanism and reaction rates in chloride media using molecular oxygen. This work contributes to the development of a better understanding of iron precipitation processing steps, which continues to be an important matter in hydrometallurgy. The specific objectives were to investigate (1) the effect of key process variables (acid concentration, copper concentration, and temperature) on the rate and extent of ferrous oxidation by dissolved oxygen and (2) the oxidation mechanism by varying chloride and hydrogen ion concentrations separately. Batch oxidation tests were performed using synthetic chloride solutions containing 45 g/L Fe and 3 g/L Ni at 50 and 80°C, dissolved Cu concentrations (0.3 to 3 g/L) and HCl concentrations (2 to 4.6 M). Regression analysis indicated that the significance of the effect of different variables on the extent of oxidation achieved after five hours decreased in the following order: HCl concentration > Cu concentration > temperature. Increasing the HCl concentration from 4 M to 4.6 M caused the degree of oxidation achieved after two hours to increase from 58.3% to 98.1%. The catalytic effect of dissolved copper on ferrous oxidation was more significant at low acid concentrations. Experimental data suggest that rapid oxidation of ferrous is possible at high HCl concentrations for two main reasons. First, the formation of ferrous chloride complexes allows ferrous oxidation to proceed without the formation of superoxide as an intermediate product (the rate limiting step in dilute acid solutions). Second, the formation of ferric chloride complexes stabilises the oxidation product.

Jan 1, 2016

By J. Schick, V. Granger

Nowadays, all French former uranium mining sites are remediated and redeveloped. If needed, mining waters containing radium have to be treated before discharged into the environment. Classical radium treatment consists in a (Ba,Ra)SO4 salt precipitation and radium monitoring was carried out using a time-consuming analysis called emanometry. Three zeolite samples have been tested to remove 226Ra from mining water. In batch experiment, radium was totally (R=100%) and quickly removed after 2 minutes contact time. Continuous sorption experiments were carried out through a vertical column at lab scale. Chabazite is the most efficient zeolite with an 226Ra activity below 0.2 Bq/L until 60000 Bed Volume. Chabazite is always efficient although radium content in material reaches 150 Bq/g. 226Ra uptake was also tested at semi-industrial scale on a pilot plant. More than 3000 m3 were successfully treated with a radium content below 0.1 Bq/L. The environmental impact assessment of Ra-chabazite was characterized by using batch leaching tests made according to the NF EN 12457-2 standard as applied on all wastes. Ra-chabazite stability is excellent during this test: radium leaching is very low, less than 0.005%. A new 226Ra measurement method was developed by ICP-MS for a better analysis reactivity. This new method was carried out in a couple of minutes with a lower sample volume than emanometry. The validation was performed according to the French NF T90-210 standard for the calibration function definition, the limit of quantification, the accuracy and the interferences.

Jan 1, 2020

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By D. Fredlund

The decommissioning of uranium tailings facilities often requires the design of a suitable cover system. In northern climatic environments there is a portion each year that can be considered to be ?inactive? while the remainder of the year can be considered to be ?active?. There are numerous engineering design assumptions required when analyzing both the ?active? and the ?inactive? portions of the year. Cover systems are subjected to complex boundary conditions and nonlinear unsaturated soil properties. The proposed paper describes the steps necessary for the preparation and the analysis of a multi-year climatic database for the design of a cover system in northern environments. The paper also explains how climate can be classified and how observed variations from one year to the next can be taken into consideration in cover design. The results of climatic records at two different sites are used to illustrate conditions that need to be taken into consideration when designing soil cover systems.

Aug 1, 2010