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By Teresa Sikora

For over 40 years the Institute of Innovative Technology EMAG has specialized in the development of systems and equipment for laboratory and on-line monitoring of coal quality parameters, as well as the implementation of these systems and devices in mines and power stations. Some of these systems, based on advanced radiation detection techniques such as ?-ray backscattering (ALFA-06 and ALFA -06/T systems) or dual energy ?-ray transmission measurement (ALFA-06/2E ash meter), and also the ALFA-06/3E system applying microwave technology for the measurement of moisture, have had numerous applications in Poland. At present, over 100 systems and devices are used in Polish hard and brown coal mines. For over 10 years, EMAG has been specializing in the development of systems and devices, based on natural gamma measurement technology. An on-line ash meter, RODOS and RODOS Ex, based on measurement of natural gamma radioactivity of coal, has been developed and put into operation. This technique has been also used in developing the portable ash meter WALKER and laboratory analyzer GAMMA NATURA. The paper briefly presents features of the above-mentioned devices, their limits and their obtained accuracy, but in particular refers to the laboratory analyzer, GAMMA NATURA, as the first such device in the world, and presents the results of ash and moisture content measurement in hard, brown coals and potassium salts. The possible applications and advantages of the device in coal mines are discussed. The paper also presents the implementation results of the portable ash meter, WALKER, and the on-line ash meter, RODOS, that is used underground in coal mines.

Aug 1, 2013

By S. Shairp

Copper is an impurity as well as a necessary reagent in the processing of zinc sulfide concentrate at Hudson Bay Mining & Smelting Co., Limited's (HBMS) zinc pressure leach plant. Copper is present in the zinc concentrate as chalcopyrite, which consumes reagents necessary for zinc leaching. A small percentage of copper precipitates in the autoclaves, discharge lines, and flash tanks, requiring maintenance of the equipment and disposal of the solids. Copper also precipitates in the neutralization stages and is removed to low levels in a specific copper removal stage of purification. Yet some copper, as copper sulfate, is required, along with potassium antimony tartrate, in the final purification stage to improve cobalt removal from the zinc sulfate solution prior to electrowinning. The behaviour of copper experienced at HBMS's zinc pressure leach plant is discussed.

Jan 1, 2008

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By E. Rezaei

Glue is an animal protein that is used with other organic agent such as thiourea, in copper electrorefining. The concentration of glue has to be controlled carefully, because the electro-deposition process is often very sensitive to small fluctuation in the operating variable. This additive (glue) prevents rough and nodular copper cathode deposits. The nodular deposits may grow causing short circuits, which results in losses in production. Addition agents are effective in controlling metal growth; they modify the normal nucleation and lattice growth steps and refine the grain structure. In this research glue concentration was determined in an industrial copper electrolysis plant. A non-linear model with high capability was constructed and after optimizing its parameters, the accuracy and precision of the model were evaluated. For determination of glue concentration, electrochemical voltammograms in optimum condition (Differential pulse voltammetry technique, Hpulse=50 my, scan rate=10 mv/s) were plotted. Some information from voltammograms was transferred to the model as inputs and the calibrated model analyzed the information and the glue concentration was determined with high precision and accuracy. In this way there is no need to separate or add agents to remove interferences. This method has been successfully applied at Sarcheshmeh copper complex.

Jan 1, 2007

INTINERARY ?What is SRI? ? How do we define good corporate social and environmental performance in the mining and petroleum industries? ? Why should you care? MJRA Inc. ? Established in 1992 ? Canadian Social Investment Database (CSID) launched in 1993 ? Jantzi Social Index launched in January 2000 ? created in 2000 SRI is ?the incorporation of social and environmental parameters into the investment decision making process.

May 1, 2002

By J. Lui

Inco Copper Cliff Smelter commissioned two new Inco flash furnaces in 1991/1993 as part of its S02 abatement program. Each flash furnace is equipped with a fluid bed dryer. The ~ 12 wt% water content in the concentrate filter cake, flux, reverts and sludge is removed in the fluid bed dryer. The dry solids are discharged from the dryer together with exhaust gases into the baghouses where they are separated. The dry solids are transferred to four storage bins. In September 2003, for the first time since startup in 1991/1993, a large amount of elemental sulfur accumulation was discovered on the walls, roofs and floors of the outlet side of the baghouse chambers. Several baghouse fires were experienced during cleaning and conducting maintenance work in the elemental sulfur contaminated baghouses. Laboratory scale test work at the Inco research lab was conducted to understand the mechanism. A plant solution to minimize elemental sulfur formation was implemented with success. This paper summarizes the efforts to understand and minimize elemental sulfur formation in the baghouse chambers.

Jan 1, 2007

By Daniel Gendron, Luc Morin

"Concentrate sampling is a growing concern in the world's mining and smelting industry. The main modes of transportation for concentrate to the smelter are by truck or rail car in a bulk form, thereby limiting access to sample extraction equipment. In many cases, concentrate is shipped to a smelter by several suppliers therefore requiring individual manipulation of different customer samples in a safe and reliable manner. The Heath & Sherwood Bulk Product Sampler offers this feature as well as an economical and effortless way of obtaining samples in rail cars or truck boxes.In 1994, Noranda Metallurgie in Rouyn-Noranda, Québec purchased a self contained Bulk Product Sampler to extract samples directly from inside rail cars before unloading the concentrate. After testing and comparing the results with the conventional sampling method, the bulk product sampler proved to be a practical and advantageous solution for concentrate sampling both for the customer and smelter. Since its installation at the Horne smelter in Rouyn-Noranda, the Bulk Product Sampler has been steadily used on rail cars which contain concentrates from around the world."

Jan 1, 1996

By V. Pouyafar

Semi-Solid metal alloys, as used in SSM processing, have a special microstructure of globular solid particles suspended in a liquid matrix, which makes them behave differently in forming processes. The sensitivity of semi-solid slurries to temperature variations and their history and rate dependant behavior, make process design and control difficult. Precise selection of the process parameters is necessary in part production. Therefore, a numerical analysis and simulation of the process can be a valuable tool in process design. In this work we proposed a structural dependent model to account for the thixotropic behavior of semi-solid metals. The parameters of the model were then determined using rheometery tests. The results show a good agreement between the model and the experiments.

Oct 1, 2011

By Libao Zhu, David J. Williams, Nazife Erarslan

"Statistics show that the drawbell in underground mines is usually subjected to significant damage by impact loading due to falling ore. Drawbell damage causes a large quantity of residual ore to remain on the drawbell, thus leading to a huge waste of ore resources. In this study, the Cavity Monitoring System (CMS) and Surpac software were employed to visualize the 3-D damage. Also, the Discrete Element Method (DEM) was employed to perform simulations of the falling ore to investigate the damage evolution of drawbells under repeated ore impact and obtain the dynamic damage accumulation mechanism. The reason of drawbell damage was found due to the micro-shear cracks. The numerical simulations of a drawbell damage process under repeated impact loading showed the main failure type was shear failure and this type damage was found increasing with more ore falling. INTRODUCTIONDrawbells are an important part of underground mines and play a significant role in ore recovery in terms of safety, economy and efficiency (Brunton et al., 2010; Hustrulid & Bullock, 2001; Trueman et al., 2002). In most cases, blasted ore is gravitated along the drawbell and finally arrives at the footwall of the drawpoint. However, some of the blasted oversize ore blocks clog the drawbell road and those ore pieces are called hang ups (Penswick, 1997). However, any damage on a drawbell is believed to be the reason for these hang-ups. In the literature, researchers have reported that the stability of the draw-point is influenced by the stress distribution above and near the drawbell (Butcher, 1999; Neverov & Neverov, 2013). Much research in the literature has been done on draw-points in underground mines. In fact, rockfalls cause very serious damage on a small impact area in a very short time (Volkwein et al., 2011). Hoek (2000) pointed out that the blasted ore causes progressive ravelling and even collapse of the drawpoint, thus the ore in the stope is abandoned. In this paper, the Cavity Monitoring System (CMS) was employed to obtain the damage profile of a drawbell due to the impact of rockfalls and to confirm the residual blocking ore on the damaged drawbell. Then, the drawbell damage evolution due to repeated falling ore was simulated by the Discrete Element Method (DEM)."

Jan 1, 2015

By R. C. Hartviksen

"The Drumbo Mine is a new gypsum mine located at exit No. 32 of Highway 401 between Woodstock and Kitchener, Ontario. The flat-lying 6-foot (1.8-metre) bed of gypsum is near the base of the Silurian Salina Formation, about 380 feet (116 metres) below surface. The mine is owned and operated by Westroc Industries Limited. A shaft, 12.5 feet (3.81 metres) in diameter, was drilled and then lined with a liner-sinking technique new to this continent. The shaft was completed in the fall of 1977. Gypsum production was started in December 1978, employing a conventional room - and - pillar method of mining.Historical BackgroundA brief mention of gypsum in the Drumbo area is included in a survey of the Ontario gypsum industry by Guillet. This occurrence was discovered in 1958 when National Gypsum conducted some widespread diamond drilling. Western Gypsum Products Limited acquired leases in 1960 and concentrated a drilling program in Blenheim Township near the village of Drumbo; 79 holes were drilled in an area of 1900 acres (770 hectares). Mining rights were then acquired for 170 0acres (690 hectares). A test shaft, 44 inches (1.1 metres) in diameter, was drilled to obtain a 50-ton (45-tonne) bulk sample. This opening will be used as an emergency escape way and for ventilation.Westroc Industries Limited, a wholly owned subsidiary of BPB Industries, has its head office at Mississauga, Ontario and operates gypsum board plants at Mississauga, Vancouver, Calgary, Winnipeg and Montreal. Other gypsum mines are at Windermere, B.C. and Amaranth, Manitoba."

Jan 1, 1983

By A. Montini, M. H. Moys

"A conductivity probe mounted in the shell of the mill has been used to measure the behaviour of the load in the mill as a function of operating variables. It was found that certain properties of the conductivity signal correlate strongly with the per cent solids of the slurry passing through the mill; in particular the angular location ?D of the shoulder of the load is an increasing function of the per cent solids. A method for measuring the viscosity of the pulp discharging from the mill has also been developed. The use of the measurements in mill control is illustrated by simulating various control strategies for open circuit milling. It is shown that the use of ?D allows very tight but imprecise control of the slurry rheology in the mill, while the use of viscosity is subject to severe limitations in speed of response. A cascade control system involving both measurements provides adequate control of slurry rheology within the mill. Applications to closed circuit milling are discussed.IntroductionMultivariable control of milling circuits continues to receive a lot of attention in the literature. Hulbert and co-workers and Niemi, et al. have described the use of Inverse Nyquist Array (INA) techniques while Herbst has recently described the use of Optimal Control. It is significant that in neither of these three projects was any variable associated with the grinding mill itself (e.g. power or properties of the mill discharge) used in the control strategy. Pauw, et al.do, however, use mill power in their multivariable peak-seeking controller for pebble-mill control. Little work has been published on the use of measurements of the properties of the slurry being discharged from grinding mills, in spite of the fact that milling efficiency is known to be strongly affected by slurry rheology».Moys has recently developed a technique for measuring the dynamic behaviour of the load in the grinding mill. This method involves the monitoring of the response of a conductivity probe mounted in the shell of the mill which gives a measurement of the orientation of the load inside the mill. It was found that the load behaviour was strongly influenced by slurry rheology. In this project a technique was also developed for the measurement of the viscosity of the slurry in the mill discharge. It was, thus, decided that it would be worth investigating the use of these measurements in mill control schemes since direct control of the slurry rheology in the mill must inevitably increase the efficiency and productivity of the grinding circuit as a whole.This will be done by using the dynamic responses measured by Moys and Montini to simulate the behaviour of an open circuit ball mill. While the control of open circuit mills is of little interest, this simulation provides a simple but powerful demonstration of the advantage provided by these measurements, advantages which should apply to closed circuit operation of any mill type (including autogenous milling). Investigations into multivariable control of a closed circuit ball mill are currently nearing completion and will be published soon."

Jan 1, 1987

By Jaime Meléndez Martínez

Recent interest in unconventional reservoirs motivates our work in laboratory measurements of seismic anisotropy. Seismic anisotropy is the variation in speed of a wave as a function of its direction of propagation. Analyzing anisotropy in unconventional reservoirs is important since anisotropy leads, for example, to differential stresses upon loading and could affect hydraulic stimulation (Reinicke et al., 2010, Zimmermann and Reinicke, 2009); in this sense, laboratory measurements are an important tool to study seismic anisotropy at small scales which can aid in the characterization of larger formations. The purpose of this work is to describe the laboratory methodology used to simultaneously measure ultrasonic P and S-waves in three different directions from a single core sample. Elastic anisotropy of a Proterozoic sedimentary rock from south-west Alberta is investigated. In metamorphic rocks seismic anisotropy is caused by preferred mineralogical alignment or foliation. Assuming a transversally isotropic medium, arrays of compressional and shear piezoelectric ceramic transducers were mounted on a sample trimmed from a core to measure travel times of ultrasonic P-waves and S-waves as a function of confining pressure at directions perpendicular, parallel, and oblique to the plane of foliation (bedding). Results show strong anisotropy agreeing with the assumption of a transversely isotropic medium. Dependence of travel times and hysteresis effects can be observed when pressurizing and depressurizing.

Jun 1, 2012

By S. Eckert, M. Reuter, D. Obiso, S. Kriebitzsch, M. Akashi

The present paper focuses the application of CFD techniques to investigate the Top-Submerged- Lance (TSL) gas injection in liquid metal. Previous works of the authors have shown that up- and down- scaling procedures based on the modified Froude number have some shortcomings, as this approach does not take into account the interfacial and viscous forces. Indeed, surface tension and dynamic viscosity of the smelting slags (σ = 0.4-0.5 N/m, μ = 0.2 Pa·s) are higher than the operating fluids that have been used in literature (water, paraffin oil) to study TSL injection in down-scaled furnaces. In order to get closer to real systems, the authors study the TSL injection of Argon in a liquid metal. An experimental campaign was carried out in the X-ray lab at Helmholtz-Zentrum Dresden-Rossendorf (HZDR), where the eutectic alloy GaInSn was used as liquid phase. The alloy is liquid at room temperature, and X-Ray imaging is used to picture the multiphase flow in a quasi-2D vessel. The aim of the present work is to demonstrate the applicability of CFD techniques to model multiphase flows involving liquid metals, and validate the model using the data produced at HZDR. The commercial software ANSYS Fluent® was used together with the Volume of Fluid model to directly resolve the gas-liquid interphase. Some features of the flow, such as the void fraction distribution and bubble detachment frequency are tracked with CFD and compared to the experimental data. INTRODUCTION In the last thirty years the TSL smelting technology has increasingly been used for industrial non- ferrous smelting processes and is now one of the significant pyrometallurgical processes. Developed in the early 1970’s at CSIRO, the furnace is nowadays commercialized in different market sectors, including copper and lead smelting, zinc fuming, waste treatment and slag recovery (Floyd, 2005). Despite the wide application of these reactors in the pyrometallurgical market, some aspects of the process are still not fully clarified, since in-situ measurements and optical accesses are prohibitive because of the high temperatures and aggressive conditions. Phenomena such as the bubbling regime, the slag solidification and the submerged combustion still need a deeper scientific investigation to obtain a better understanding of the process.

Jan 1, 2019

By Theophile Yameogo

Much has been said about the methodology of geomechanical design in underground excavations. However, the geological, hydrogeological and geotechnical complexities encountered at the production horizons in the Athabasca Basin commanded for a novel approach in the geomechanical assessment and design of underground openings. Rock mechanics engineers at Cameco McArthur River have been able to establish a practical methodology that goes beyond known conceptual approaches. In this paper, the author describes the original challenges and unique approach in the geomechanical assessment for drifts and chambers development. The example of the successful development of the 510-8225N Chamber will also be presented.

Aug 1, 2010

By I. M. Santos Moraes

The control of minor impurities (mainly As, Sb and Bi) in copper refineries has been a great challenge. Caraiba Metais' copper refinery produces a very high quality copper, registered in LME as grade A, and recognized as amongst the top ten in the copper world. At Caraiba's Tankhouse Bi and Sb are controlled by means of electrolyte bleed-stream removal after partial decopperizing in a set of electro-winning cells (liberators). Another way of reducing the Sb and Bi content in the electrolyte is by means of the arsenate precipitation chemistry. It is well known that the use of high arsenic concentrations in copper refinery electrolyte has the advantage of causing most of the bismuth and antimony to report in the anode slimes. However, the use of such mechanism of control may contribute to other undesired problems such as antimony and bismuth precipitation in the bulk of the electrolyte, what may cause severe contamination problems. This paper describes a period when some cathode contamination with Sb occurred at Caraiba Metais' Copper Refinery. It also presents an analysis of several process parameters related to the problem, the possible causes for the contaminations as well as the actions taken to correct the problem.

Jan 1, 2007

By G. V. Theja, V. B. Maji

Large infrastructure projects like tunnel excavations, underground constructions face innumerable risks. For successful completion of these projects, it is essential that we foresee and understand risks that could occur during different phases of the project. One of the risks affecting underground excavation projects is the inaccurate performance prediction of TBMs. As this could severely affect the project, resulting in lower advance rates and could also result in changing the excavation machine or method, due to difficulties in excavation, thereby increasing the overall cost of tunnelling. This makes performance prediction of the TBMs as one of the crucial aspects in tunnelling, as a precise estimation of its performance is required for planning and estimation of time and cost of the tunnelling projects. This performance prediction of TBM is a challenging geotechnical problem that is intricate and complex in nature, this is possibly due to the fact that TBM performance prediction involves understanding the rock fragmentation process in wide range from micro-scale (i.e. the interaction of surface of rock material and cutter tip) to macro-scale (including the interaction of rock mass and TBM). Thus in order for the performance prediction model to be efficient, parameters of both TBM specifications and ground conditions have to be considered. Various models have been proposed by researchers since the early phases of TBM application, these studies resulted in the development and improvement of numerous penetration prediction models. Most of these models consider the geotechnical parameters that are input to the model to be consistent along the TBM drive and neglect the uncertainties in parameters that occur. And so to improve the predictive capability of these models and to incorporate the above uncertainties, the penetration rate is modeled as a stochastic variable depending on the geotechnical and TBM parameters, its statistical distribution is determined and is used to characterize the penetration rate instead.

Jan 1, 2015

By P. V. Barr, Y. -H. Li, A. P. Watkinson

Subsequent to a campaign of pilot-kiln trials of firing bio-oil and natural gas, scale-up to commercial lime kilns was made using an in-house mathematical kiln model. Both dry limestone and lime mud kilns of 3.5 m OD. by 100 m length were used for bio¬oil firing simulations. Comparisons were made against natural gas firing on the basis of specific firing rate, off-gas volume, energy consumption and overall lime quality. Model simulation results indicate that conversion from natural gas to bio-oil with no productivity loss will increase energy comsumption by about 7.5% and total off-gas volume by about 8%. Alternatively, a 6% decrease in productivity would be expected if off-gas volume is maintained constant. The calculations are sensitive to deviations in the lower heating value (LHV) used in the simulations. A 5% increase in the LHV of the bio-oil, which could result from a 3% decrease in the moisture content, reduces the energy penalty to 2% coupled with a slight reduction in off-gas volume.

Jan 1, 2004

By Hans Lundberg

An electric survey from a 'plane flown over the ground is much faster and cheaper than an electric survey carried out on the ground. The results are obtained as continuous recordings that are resolvable into both a depth expression and a conductivity effect, so that the indications are easier to evaluate, as well as to correlate from one flown line to the other. The prospecting technique adopted in our electric airborne surveys may be brie fly described as follows: A loop of many turns of insulated copper cable is fastened around the fuselage of the 'plane and connected to a generator supplying a few ampere alternating current, usually of a frequency less than 1,000 cycles per second. Just as the current in the primary coil of a common transformer will induce current in the secondary coil when shorted, the alternating magnetic field from this primary current now induces alternating current in electric conductors that happen to be located in the vicinity of the path over which the 'plane is flown. This induced secondary current in each conductive section of the ground causes, in turn, an alternating magnetic field, secondary field, which disturbs or dampens the normal alternating magnetic field from the primary loop flown by the 'plane. These secondary fields are then picked up and recorded by the help of detecting solenoids, amplifiers, and recorders carried in the 'plane. By closer study of such a secondary field it is possible to localize the secondary current causing it and, thereby, the conducting body that contains the secondary current. In the 'plane are continuously recorded, besides the amplitude or intensity of the field, also the phase, which is a measure of how much the recorded secondary field is out of step with the primary field.

Jan 1, 1950

"The pressure leaching of alkali-pretreated limonitic laterite ore in nitric acid was studied. The optimal leaching conditions are as follows: leaching temperature of 458 K, initial nitric acid of 2.44 mol/L, leaching time of 60 min, liquid to solid ratio of 2:1 mL/g, agitation speed of 500 RPM. Under the above conditions, the extraction of nickel and cobalt can be achieved as approximate 95% and 80% respectively while that of iron is as lower as 1%. The leaching residue containing 70% of iron in the form of hematite and trace amount of chromium is suitable as the raw material for iron-making. The nitric acid in the leaching solution can be regenerated and further recycled to leach. INTRODUCTIONIt has been estimated that 60%-70% of the world land-based nickel resources presented in nickel laterites containing 130 million tons of nickel although these only accounted for about 42% of the world nickel production (Sudol, 2005; Luo et al., 2010). The nickel resource of laterite has not yet been fully utilized. Due to the increasing global demand of nickel and the declining global reserves of nickel sulphides, there is an increasing focus on the processing of the huge reserves of laterite ores today. Nickel laterite ores can be simply divided into two types, namely, silicate-rich and limonite. The former can be treated effectively by pyrometallurgical process in which the ferronickel product or nickel/iron sulphide matte is produced (Monhemius, 1987). The limonitic laterite is rich in iron in the form of goethite which is the main nickel-bearing mineral and usually contains cobalt associated with a manganese phase (Chang et al., 2010; Georgiou and Papangelakis, 2004). The limonitic laterite is usually processed by hydrometallurgical methods, such as atmosphere acid leaching (AL) (Xu et al., 2005; McDonald and Whittington, 2008), high pressure acid leaching (HPAL) (Chou et al., 1977; Georgiou and Papangelakis, 1998; Rubisov et al., 2000; Whittington and Muir, 2000) and reductive roasting-ammonia leaching (Caron Process) (Whittington and Muir, 2000; Valix and Cheung, 2002). The AL process can proceed at lower temperature, thus the operation costs may be very low. But two biggest problems associate with the AL process, namely, the slow rates of nickel extraction and potentially the significant amount of impurities such as iron and aluminum in the leaching solutions, which hampers the wide application of the AL process. The Caron Process uses the pyrometallurgical and hydrometallurgical methods together to obtain the metallic values, but the overall metal recovery is relatively low, especially for cobalt. In recent years, the environment-friendly process of HPAL has become increasingly important because it is most suitable for low-grade ores and leads to high extraction of the valuables. However, the HPAL process needs a much higher temperature and pressure (503-533 K, 4-5 MPa) to maintain a relatively fast leaching rates, which results in higher operation costs. Moreover, another serious problem of scale formation in autoclaves occurs in the HPAL process, for example, in Moa Bay, up to 20 cm scale may build up resulting in 5 days descale downtime per month. In addition, the iron residues cannot be utilized for ironmaking due to the presence of high content chromium (Ema and Harada, 1987; Owada and Harada, 1987; Takagi and Furui, 1987)."

Jan 1, 2012