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By A. P. Yovanovic, P. Bonadia, M. N. Moraes, C. F. Matos

"The magnesite flotation operation of Magnesita Refractories, in Brumado – Brazil, has four parallel ball mills working in closed circuit with hydrocyclones to grind the ore for the reverse flotation of silicates in mechanical cells. The modification proposed here opens the circuit for three of the ball mills so that their products are collected together to feed a high frequency screen. The oversize of the screen feeds the fourth ball mill in closed circuit for secondary comminution. The product reports to dewatering and flotation. The undersize undergoes desliming and subsequent flotation operation. According to pilot tests performed, the modification on the magnesite flotation operation will promote a 20% increase in the productivity, 8.5% increase in mass recovery and a 26% reduction in water consumption. The gains are due to the fact that the silicates in the feed are concentrated in the smaller particles (<100µm) with over grinding in the existing closed comminution circuit, making it impossible to take advantage of this natural selectivity. The combination of open circuit, more selective milling, and the high frequency screen, ensures high efficiency particle size classification. This renders the process more effective, both to the screen undersize with its high contents of silicates and fines, and to the screen oversize, which is almost without fines and has a higher magnesite grade. This situation allows for the setting of specific parameters for the flotation of both the primary milling undersize and the secondary milling product.INTRODUCTIONMagnesita Refractories, with its operations site in Brumado, is the largest producer of high purity dead burned magnesia (DBM) in Latin America. The magnesite ore is extracted from an open pit mine, named Pomba, after which it is crushed and handpicked. Due to the presence of disseminated silicate the ore has to be ground and concentrated by means of reverse flotation, before feeding the high temperature kilns for sintering and conversion to DBM.The magnesite flotation unit has an impact crusher to reduce the size of the feeding ore, which is transported to the mills by conveyor belts. The milling operation is composed of four ball mills in closed circuit with hydrocyclones. The closed circuit generates a high circulating load with excess fines, which is detrimental to the selectivity of the desliming and flotation operations, reducing both mass andmetallurgical recovery.In the current scenario, the capacity of the flotation plant is insufficient to meet the demand of the DBM kilns, forcing the operation to work with high purity ores in order to attain the highest possible mass recovery in the concentration process. This is not an ideal situation as it requires the mining site to work with higher stripping ratios.The objective of this work was to improve the magnesite flotation unity to increase its productivity. After a detailed analysis, the milling was identified as the limiting process, which made the authors to focus on this operation."

Jan 1, 2016

By Gerhard Melcher, Hermann Hilbrans, Michael Gamroth

"IntroductionSeveral new smelting processes have been proposed and developed during the last 20 years. This has been true, in particular, for copper smelting technology. The important impulses for the advances in this field have been the recent demands regarding the environmental protection, energy saving and improved utilization of the metals contents of deposits, in particular that of complex raw materials.The methods developed more recently for pursuing these objectives have been outlined in several papers. In some of them the advantages and drawbacks of certain developments have been stressed. These documents are of great importance for assessing the different processes. The following paper tries to explain some details of the cyclone smelting process taking into consideration a few of these well-known presentations. The effectiveness of operation of the cyclone smelting process indicates that this process presents a significant achievement when compared with other conventional methods.The application of the CONTOP smelting cyclone range s beyond the field of copper metallurgy or the smelting of sulphide concentrates with the aid of oxygen. The research work carried out in the pilot plant of KHD Humboldt Wedag AG in Cologne-Porz also includes the recovery of the metal contents of intermediate products and processing of smelter residues which have to be converted in a disposable stat e, free of environmental pollution. This paper explains a few examples in this regard."

Jan 1, 1987

By Chun-Sheng Liao, Chun-Hua Yan, Sheng Wu, Fu-Xiang Cheng

"INTRODUCTIONChina is providing more than 90% of the rare earth products consumed in the whole world. Acidic extractants are commonly used in the extraction separation of rare earths. Saponification of the acidic extractants by basic substances is usually necessary for the purpose of increasing and stabilizing their extraction capacity, and meanwhile inorganic acids are required for both scrubbing and stripping. Thus acids and bases are the main consumed chemicals, and the resulting salts are the main pollutants generated by rare earth separation processes. Currently, due to increasing environmental concerns in China, rare earth solvent extraction separation techniques are being developed to reduce both consumption and emission of chemicals, which is driving the developments on both theories and processes for solvent extraction separations.In the 1970s Prof. Xu et al. developed the Theory of Countercurrent Extraction (Xu, Li, & Yian, 1985). In recent years, the development of novel processes for rare earth separation has moved beyond the earlier theory. One rare earth separation process, the so-called hyperlink process, has been developed in the past decade and proven in industrial practice to dramatically reduce both the consumption and emission of chemicals during multi-component solvent extraction separations, and therefore is now widely used in the Chinese rare earth separation industry (Liao, Wu, Cheng, Wang, Liu, Zhang, & Yan, 2013). The present article will give a brief review of the development of the theory of the hyperlink processes, and the hyperlink separation flowsheets for typical rare earth mines in China designed using the theory.HYPERLINK PROCESSES (LIAO et al., 2013)A flowsheet of multiple-component separation consists of a couple of separation units. The units of a conventional flowsheet separately consume chemicals for saponification and scrubbing and discharge wastewater with resulting salts. In contrast, the separation units in a hyperlink process are hyperlinked and thereby the chemical demands of the whole flowsheet are decreased. For a feed containing t components of A1, A2, …, and At, it has been proved in theory that the separation mode of (AtAt-1…A2)/(At-1At-2…A1) is preferred in a single separation unit. The hyperlinking between separation units can have two forms. The link between two units locating at a same separation level, such as between (A4A3)/(A3A2) and (A3A2)/(A2A1), is known as horizontal hyperlinking. The link between two units located on different levels, such as between (A4A3A2)/(A3A2A1) and (A3A2)/(A2A1), is known as vertical hyperlinking. Both the hyperlinking forms have been proven to save chemical usage and consequently to lower the pollution emissions in industrial practices as well as in theory."

Jan 1, 2016

By C. Sui, J. E. Nesset, M. Li, J. Y. Kim, S. L. Chryssoulis

"A plant study of zinc rougher flotation at Brunswick Mining was conducted using lime, soda ash and a combination of both as the pH modifiers in order to establish the effects on sphalerite and pyrite kinetics and mineral selectivity. The plant sampling and analysis was augmented by surface analysis using TOF-LIMS, SEM and XPS as well as fundamental precipitation and surface-charge studies in the sphalerite Ca/C03/S04 system.The results revealed the important role of carbonate ions in cleaning the sphalerite surface for effective activation by CuS04 to occur, and the beneficial role of combined soda ash and lime in increasing pyrite and galena depression.1.0 IntroductionThe studies reported in this paper were initiated as part of an investigation into the causes of a particularly pronounced seasonal deterioration in metallurgical performance at the Brunswick Mining concentrator during the summer of 1995. The concentrator treats a complex base metal ore having a typical feed composition of 9.0% Zn, 3.5% Pb, 0.4% Cu and 100g/t Ag at a current throughput of 9,000 TPD, although at the time of the problem in 1995, the average production rate was closer to 10,500 TPD. Zinc, lead, copper and bulk (zinc-lead) concentrates are produced with overall metal recoveries of 86% zinc, 63% lead, 60% copper and 60% silver; results which are typical of the lower recoveries associated with fine-grained, highly complex VMS and SEDEX type deposits. The main economic minerals of interest are an iron-containing (7% Fe) sphalerite, galena and chalcopyrite with the main diluent (about 60% wt) being pyrite.Figure 1 shows a simplified flowsheet of the Brunswick milling circuit while the seasonal decrease in summer metallurgy in 1995 is illustrated in Figure 2. Of significance is the rapid drop in copper and lead recovery in June while there is an apparent delay until late August-September before the zinc deterioration reaches its lowest point. A more typical seasonal effect within the experience of the authors is the reverse of the Brunswick situation, namely an improvement in summer performance thought to be associated with improved differential flotation kinetics during warmer weather leading to better mineral selectivity. The historical Brunswick experience was particularly severe during the summer of 1995 with estimated incremental losses of $10 Million for this period. The potential of the very significant economic benefits to be gained from understanding and hopefully improving the annual drop in performance led to an investigation involving the minesite metallurgical group, the Noranda Technology Centre (NTC) as well as researchers in Professor Jim Finch's group at McGill and the surface analytical services and interpretive skills of AMTEL."

Jan 1, 1998

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, A. M. Elmahdy, Keiko Sasaki

"Seawater has been reported to depress molybdenite in a copper-molybdenum (Cu-Mo) flotation process at high pH due to the precipitation of Mg(OH)2. Meanwhile, to improve mineral recoveries, collectors are usually added into the flotation cells, thus adding the complexity to the mechanism of bubble-particle interactions involved in Cu-Mo flotation. Therefore, understanding the interaction mechanism in seawater flotation and in the presence of collectors is important to explain the minerals depression. The present work investigated the effect of kerosene on the bubble collision and attachment to pure chalcopyrite and molybdenite surfaces in MgCl2 solution as one of the seawater major components at pH 6 and 11. Mineral surfaces were characterized using atomic force microscopy (AFM). In addition, minerals floatability in the same system were tested in a column flotation. The study of bubble-particle interactions shows that following several collisions, bubble could displace the intervening liquid layer on the mineral surfaces, forming a three-phase contact (TPC). A TPC formed more rapidly in the presence of emulsified kerosene in a 0.01 M MgCl2 solution at pH 6 for both minerals. The reason is kerosene increased the surfaces hydrophobicity and destabilized the intervening liquid layer on the surfaces. Moreover, the average time required to form a TPC was shorter on molybdenite surface. This can be attributed to the effect of adsorbed kerosene on molybdenite surface and molybdenite surface roughness.INTRODUCTIONIn froth flotation, bubbles are used to separate hydrophobic mineral particles from hydrophilic particles. In this process, bubble-particle interactions (i.e., collisions, attachment, and detachment) are crucial with regard to mineral recoveries. The effectiveness of froth flotation depends on the formation of stable aggregates between the hydrophobic particles and the bubbles, allowing the bubble to carry the particles to the froth layer. To form such aggregates, the bubbles and particles must collide, and the intervening liquid layer must be drained below the liquid layer critical thickness, forming a stable threephase contact (TPC) (Ralston & Dukhin, 1999). Particles detachment may take place if the particles still have sufficient kinetic energy and the TPC is not formed. Previous studies of bubble-particle interaction in electrolyte solutions have been conducted using atomic force microscopy (AFM) (Assemi, Nguyen, & Miller, 2008), and by approaching the bubble using mica plate (Pushkarova & Horn, 2008), however, these studies did not focus on the bubble-particle collisions. Bubble collisions and attachment to hydrophobic (Teflon) and hydrophilic (glass) surfaces in a a-terpineol solution have been investigated by Krasowka et al. (2003)."

Jan 1, 2016

By M. J. Nicol, T. Moyo

Ammoniacal solutions are an effective lixiviant for the oxidative dissolution of some mineral sulphides. A detailed study of the anodic dissolution of chalcopyrite in ammonium sulphate-ammonium hydroxide solutions has been carried out using cyclic voltammetry, chrono-amperometry and rest potential measurements. The role of the copper(II)/copper(I) redox couple in the oxidation process has been evaluated. Rest potentials have been found not to be affected by oxygen but to increase with an increase in initial copper(II) concentration. Pseudo-steady-state anodic current densities measured in the absence of copper(II) ions at the rest potentials obtained in the presence of copper(II) ions increase with increasing concentration of copper(II) ions, confirming the positive effect of copper(II) ions on the rate of dissolution of the mineral. Cyclic voltametric and chrono-amperometric data show that in the absence of initial copper(II) ions, the rate of dissolution in the presence of dissolved oxygen is significantly lower. These results confirm that the effective oxidant for the mineral under the conditions of the study is copper(II) and not dissolved oxygen. Coulometric measurements have been used to establish the stoichiometry of the anodic reaction at different potentials.

Jan 1, 2014

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By D. T. Smith, S. J. Strohmayr

Originally developed as a step change in ultrafine grinding efficiency, the IsaMill™ has made inroads into conventional ball mill and tower mill mainstream grinding duties during the last 5 years - beginning with the Anglo Platinum mainstream grinding projects in South Africa. At the 2006 SAG Conference, plant testwork on the incorporation of IsaMill™ technology into the McArthur River (Northern Territory, Australia) Pb/Zn primary grinding circuit was reported. The IsaMill™ has now become an integral component of that circuit, treating up to 1mm top size feed and directly producing P80 45 µm rougher flotation feed. Two 1.1 MW IsaMills™ are now used in this duty contributing to a 27% increase in overall plant throughput and a reduction in rougher feed size distribution. In this paper, we report on the current state of development and performance of the IsaMill™ in the primary grinding duty at McArthur River and also consider future directions.

Jan 1, 2012

By A. Blackmore, A. Lamoureux, J. Woloshyn

This paper provides an overview of recent applications of Computational Fluid Dynamics (CFD) to combustion related fugitive emissions problems. The aim is to illustrate the capabilities and discuss the present limitations in this field. Examples include design of retrofitted NOx reduction technology in a kiln and in a boiler, and the prediction of pollutants such as SO2 and metallurgical dust emanating from a copper flash smelting furnace. It is demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause problems and testing solutions, and for concurrently assessing emissions reduction and process impact. In addition, the value of CFD for demonstrating due diligence for regulatory compliance is discussed.

Jan 1, 2015

By I. Paredes, R. Díaz, H. Henao

Smelting of copper concentrate generates a significant amount of dusts which are collected in electrostatic precipitators. This material, which is a complex oxide of Cu, Fe, S, As, Sb, Bi and others, is difficult to recirculate into the smelting process due to the reported high concentration of arsenic. However, the dust also has concentration of copper above 10wt %, aside from reported contents of silver corresponding as much as 25wt% of the total inventories of this element in the smelters. Thus, it is of economic and environmental interest the development of a process able to reduce the concentration of arsenic in the dust and produce a material suitable to be recirculated into the smelting process. The present experimental work shows the results of a process of dust sulfidization-oxidition able to remove more than 65wt% of the arsenic present. INTRODUCTION Copper sulfide deposits worldwide exhibit increasing concentrations of arsenic. One case of interest would be the copper ores from the northern zone of Chile, which report high concentrations of enargite (Cu3AsS4) (Revista química, 2015) (Latinominería, 2014). The obtained concentrate from this ore is treated in a Fluidized Bed Roaster, producing calcines with low concentration of arsenic (<0.5 wt% As). This material is suitable to be treated in a Flash Furnace. At the roasting process, the arsenic is volatilized and then precipitated as fine particles of complex oxides. Most of this particulate material is removed from the gas stream through a device called Electrostatic Precipitator (Minería chilena, 2014). The experimental results reported in the literature indicate that arsenic present in these particulate materials (or dusts) cannot be eliminated in oxidizing atmospheres (air) or with inert gases (N2) in a Fluidized Bed Roaster even at temperatures as high as 700°C. There is also information that even the recovery of valuable metals from the dust is difficult through hydrometallurgical processes (private communication). This is how in some foundries these dusts are considered environmental liabilities. Regarding the decomposition of enargite (Cu3AsS4) in neutral atmosphere, it is reported in the literature (Padilla, 2001) that the main chemical reactions are:

Jan 1, 2019

By Carricajo T., S. Nazari

This paper discusses a unique dynamic solution for optimizing comminution area in real time. The proposed technology is a combination of model predictive controller, optimization methods and real-time digital twin for mineral processing. For grinding area, the ultimate goal of an effective control strategy is to maximize the mineral processing, reduce energy consumption and stabilized size classification. To have a continuous and effective comminution operation, a reliable control system that minimizes the need for human intervention is necessary. The implemented advanced control strategy for comminution area consists of two layers in hierarchical structure. The lower layer objective is to stabilize the process stabilization using model based predictive controller (MPC) technique. The unique MPC used in this layer is called BrainWave™ chosen for its robustness, convergence and delay handling; furthermore, the developed platform offers stable and repeatable solution and has short implementation time. The upper layer is a supervisory control, which sends the preferred process operation points to the lower layer to drive the process towards optimal performance. The goal of this layer is to optimize the process targets, as well as making decision. To increase process performance, automatic ore characteristic adaptations are implemented in this layer. A digital twin of comminution area is built in the second layer that runs amongst the process in parallel. By communicating, the process data in real time, a virtual densitometer is built that is being used in our advance process control strategy. Our control strategy has been developed, tested and implemented in various areas of a copper concentration plant. The targets for implementing advance process control are usually increased throughput, decrease energy consumption and variability reduction in particle size distribution. Overall, the results showed in different mine sites are increase throughput between 2 and 5%, specific energy consumption reduction about 15% and process variability reduction up to 60%. In this paper we discuss the results of the recent implementation of this technology on Minera Los Pelambres, Minera Collahuasi and CAP Minería. Their concentrator plants have installed control systems with the most updates optimization features, for SAG mill, ball mills and thickeners.

Jan 1, 2019

By Azadeh Riahi

The main goal of this paper is to investigate the effects of permeability anisotropy in Large Open Pit (LOP) mines for problems that exhibit homogeneous anisotropic characteristics. The most important effect of the groundwater flow in open pit mines is on the stability of the pit slopes. This study will investigate the effects of having increased permeability in both horizontal and vertical directions on three aspects of LOP behavior, location of phreatic surface, pore pressure distribution and stability of slopes. The hydromechanical coupling is simulated using a one-way coupling approach. The Shear Strength Reduction method (SSR) is applied to assess the stability of slopes. The studies performed in this paper suggest that anisotropy in permeability leads to a significantly different regime of pore pressure dissipation depending on two aspects, ratio of anisotropy and the relative magnitude of permeability to simulated time. As a result, variation in safety factors and the location and depth of the failure surface must be expected.

Jun 1, 2012

By L. A. Homeniuk, R. Bonnar

"The Athabasca Basin has been the scene of an intense exploration effort since the late 1960s, resulting in the establishment of this area as one of the major uranium districts in the world.The A thabasca Group is of Helikian age and unconformably overlies metamorphic rocks of Aphebian and Archean age. Most of the known uranium deposits have a close spatial relationship with the unconformity, graphitic meta-sediments, major northeast-trending structures and the basin edge. It should be noted that, in regard to the latter, some of the Cluff Lake deposits are exceptions.The pre-Helikian rocks underlying the Athabasca Group have been divided into six Iithostructural domains. The known uranium deposits are concentrated in the Wollaston and Mudjatik domains in the southeastern portion of the basin.The orebodies typically have a narrow high-grade portion below the unconformity and a broader, lower-grade disseminated zone in the overlying sandstone. Over-all grades average over 1% U3O8 and our estimate of known reserves totals more than 400 million pounds of contained U3O8. Some of the deposits have high concentrations of other metals, including nickel, arsenic, cobalt and gold. Ubiquitous chlorite and clay alteration is characteristic of the orebodies.Other Proterozoic basins in Canada of similar ages and having analogous geological settings to the Athabasca have received far less attention. Although little of the known uranium mineralization in these basins is related to the Helikian unconformity, there may be an exploration potential for deposits similar to those of the Athabasca basin.IntroductionThe Athabasca sedimentary basin is located within the Churchill Structural Province of the Canadian Shield in Northern Saskatchewan. The basin is elliptically shaped and is approximately 800,000 square kilometres in area.The objective of this paper is to summarize the various elements in the genesis of the unconformity-type uranium deposits of the Athabasca Basin and to evaluate the comparative potential of other Proterozoic basins to host similar unconformity-type deposits."

Jan 1, 1982

By S. Downing, T. Grammatikopoulos, N. Hoffmann, C. Gunning

"Most deposits display a high degree of geological and mineralogical complexity that can affect metallurgical processing. Therefore, the proper characterization of the ore and gangue minerals requires a multi disciplinary approach combining geology, mineralogy, geochemistry and processing. However, mineralogy to a large extent informs the metallurgical process. Automated methods can be used throughout the mining chain from advanced exploration through to production.In this presentation we discuss actual case studies where automated mineralogy has been applied in a geometallurgical framework at a pre-feasibility to feasibility level. These include examples from a strongly serpentinized magmatic Ni deposit (Dumont) and a magmatic Cu-Ni deposit (Maturi). Mineral speciation and ratios, e.g., chalcopyrite, cubanite, and pentlandite/pyrrhotite are critical to model the Cu-Ni magmatic deposit. In the serpentinized Ni ore, automated mineralogy is used to speciate the Ni minerals into sulphides, alloys and refractory Ni in the silicate matrix.The mineralogical results are linked to the metallurgical test work in order to model the geometallurgical domains. These case studies will illustrate how mineral quantification and improved understanding of inherent mineralogical parameters in relation to metallurgy reduce technical risk in both exploration and flowsheet development.INTRODUCTIONGeometallurgy is a cross-discipline approach combining geology, metallurgy and mine planning (e.g., Dunham et al., 2011). It is aimed to improve the understanding of geological, mineralogical and metallurgical parameters of an ore. Informational gaps among the different disciplines are often apparent. Automated mineralogy is shown in many studies (e.g., Eppinger et al., 2013, Philander and Rozendaal, 2013) to constitute the link between geology and metallurgy. The geometallurgical approach can provide specific data to geology, mining and mineral processing development and plant operations. The scope of the automated mineralogy is to illustrate how mineral quantification can improve the understanding of inherent mineralogical parameters in relation to metallurgy, and reduce the technical risk in both exploration and flowsheet development."

Jan 1, 2016

By P. Mottahed, E. K. S. Passaris, J. Q. Ran

"The jointed roof of underground mine openings in stratified rock can be analyzed in terms of a voussoir beam. Because of the essential indeterminacy of the structure, previous attempts of theoretically solving the equilibrium equation have been unsuccessful. Numericalanalysisby the finite element method taking the geometrical and joint non-linearity into consideration combined with the experimental method has been adopted to study the performance isopara of the voussoir beam. Deformation and failure mechanism is analyzed in relation to the failure modes. Equations are proposed to estimate the elastic buckling strength and the crushing strength of the voussoir beam and to verify the failure mode of shear sliding. For application of the mechanism of the voussoir beam in mining operations, methods are described to predict the stability of a jointed roof and to design the dimensions of mining openings.IntroductionThe roof stability of an underground mine opening has direct effects on the selection of support methods, opening dimensions and, more importantly, on the safety of mining personnel. The prediction of the roof stability can be of importance in the design of a mining method and in mining operations. The jointed roof of mine openings in stratified rock can be stable under transverse load depending on the roof geometry and properties of the roof material and joints. The stability of this type of roof can be analyzed in terms of a voussoir beam which was introduced by Evans (1941) to study the strength of underground strata. Brady and Brown (1985) analyzed the voussoir beam and suggested that the mechanism of the voussoir beam could be used in the design of underground mine openings in stratified rock instead of the traditional continuous beam theory."

Jan 1, 1993

By P. H. J. Mercier, M. Couillard

Aberration-corrected scanning transmission electron microscopy (STEM) allows for the nano-scale exploration of materials at unprecedented resolution and sensitivity. In this paper, we combine this approach with electron energy-loss spectroscopy (EELS) and energy dispersive X-ray spectroscopy (EDX) to analyze the carbon distribution in residual solids found in solvent-diluted bitumen product extracted from Alberta oil sands. Major components of these contaminant solids are ultrafine clays. Biwettable clays have been associated with the formation of solid-stabilized water-in-oil emulsion, which are known to increase the content of both water and mineral solids in the final bitumen product. We demonstrate that the residual solids present in bitumen product contain carbon intermixed with mineral particles of various size and shape. By probing the carbon content at the nanometer scale with the high chemical sensitivity of EELS, we provide direct evidence of carbon intermixing with clay platelets. This clay-organic association at the nanometer-scale will contribute to the biwettable, hydrophobic character of the platelets, and will therefore play a crucial role in the bitumen extraction process

Jan 1, 2014

By David A. Grieve, David E. Pearson

"A rank-map of Crowsnest coalfield, showing the distribution of the bituminous coal measures and the locations of major structures, has been produced from vitrinite reflectance measurements on over600coal samples. The timing of coalification in relation to these major structures has also been determined.In the west-central portion of the coalfield a complete stratigraphic succession of coal measures which rides on major thrust surf aces is all of high-volatile bituminous rank, but despite the structural discordance no break in rank is discernible across these structures. The thrust faults therefore predate much of the coalification.Three major valleys expose cross sections of the folded coal measures and in each an increase invitrinite reflectance is demonstrable as individual seams are traced from ridge crest to valley floor. Thus, in these sections, a significant amount of coalification post-dates folding. The proportion of this post-folding coalification is found to increase toward the south of the coalfield.A late gravity-fault, exposed along the east crop of the coalfield, places high-volatile coal-bearing successions in contact with low-volatile coal and demonstrably is a reactivated thrust fault. Coalification at this locality occurred between these two different ages of faulting.The variations in rank and the subtleties of the coalification pattern have, together with systematic changes in the maceral composition of coal seams, had a profound effect on coal quality in the coalfield. Coking coals with a variety of properties occur together with some coals that have no caking capacity."

Jan 1, 1985

By U. Caliskan, S. Miskovic

Gravity separation is a technique that depends on the difference in density of minerals for their separation. Although this method is one of the oldest separation techniques, it is still preferred in the industry because of its low capital and operating cost while it is environmental-friendly. In this paper, we present a new numerical methodology that can be used to investigate dynamics of dense slurry flows in gravity separation systems. A simple channel with a set of riffles is selected as a test platform in order to observe the effect of the riffle shape on segregation profile of particles with different densities. It is believed that the riffle shape would affect the slurry flow and possibly cause one class of particles to segregate within the riffle zone. The turbulence, as a disturbance effect within the riffle zone, causes heavy particles to displace the light, that is, the heavy particles will be trapped in riffles, while the lighter particles are carried by water to the end of the channel, which is an example to uninterrupted suspension. MP-PIC model in OpenFOAM is used to study the effect of riffle shape and slurry percentage of solids in this simple gravity separator on particle segregation profile of four discrete mineral density classes, which are Quartz/Clay (SG 2.6), Pyrite (SG 4.2), Chalcopyrite (SG 5.1), and Gold (SG 19.32). Gold particles are found to be readily captured and retained in the riffles because of their high density, while particles with the intermediate densities are more influenced by the flow. The developed model framework has been proven robust and capable of providing physical results even for the flows with a very high percentage of solids, characteristic for mineral processing operations. INTRODUCTION Gravity-based ore concentration techniques make use of differences in density of minerals within an ore to enable separation of valuables from the gangue. As some of the oldest techniques used for ore beneficiation, they are known to offer a range of benefits such as low specific energy consumption and low capital and operating costs (Burt, 1999; Falconer, 2003; Holland-Batt, 1998), however, they suffer from low selectivity, poor separation efficiency, and low capacity. Gravity separation techniques are common practices in the mining industry and are employed widely for the precious mineral concentration, iron ore recovery and coal preparation (Kroll-Rabotin, Bourgeois, & Climent, 2013; Laplante & Spiller, 2002; Williams, 1997). For example, gravity separation systems are highly applicable for precious metal enrichment operations by being included in primary grinding circuits, shaking table tailing separation, pre-concentration of leach feed and flotation concentrate enrichment for both flash and conventional flotation purposes (Burt, 1999; Falconer, 2003; Holland-Batt, 1998; Laplante & Spiller, 2002; McAlister, 1992). Gravity separation can be employed in the copper processing circuits by being integrated into the pre-flotation circuit to capture the gravity recoverable gold (GRG) and any free copper aiming to enhance the gold and copper recovery of the plant. When native copper and GRGs are present in the deposit, this integration not only facilitates plant overall performance via removal of the valuables early in the circuit, but it also reduces downstream operational expenditures due to less retention time of coarser copper particles in the system.

Jan 1, 2019

By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By Jan Kvinge, Aina Opsal Bakke, Yanjun Li, Jan-Ove Løland, Svein Jørgensen

"Compound casting is a very attractive approach to reduce the weight of components for some specific applications while keep both the functional and the mechanical property requirements. In this work, Al-7Si-Mg alloy /copper compound castings were produced through a low pressure die casting process. To reduce the oxide present in the interface, flux coating of the copper pipes was tested. The interface layer formed between the two alloys was investigated using Optical Microscopy (OM), Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS). Vickers Micro-hardness was also measured across the interface. Results showed that the flux coating prevented the formation of the metallic bond between copper and aluminum. Instead, high concentrations of potassium, magnesium and fluoride, coinciding with formation of KMgF3 and MgF2, were detected in the interface. In the castings without surface treatment, a continuous metallurgical bond was achieved. In the bond layer, various Al-Cu intermetallic phases have been detected. In addition, formation of primary silicon particles in the reaction layer was observed in all castings. The mechanism for the formation of the intermetallic phases and the strength of the interface layer have been discussed.INTRODUCTION Recent development in the automotive industry has focused on producing lightweight components, which can reduce CO2 emission and increase the efficiency. Often, one material alone is not able to meet the requirements for a specific use. The need for lightweight bimetallic components has therefore increased. Aluminum-copper bimetallic components can be used in wires and bus bars where conductivity is an important factor (Lee, Bang, & Jung, 2005). Compared to Al-Cu alloys, Al-Cu bimetallic components can reduce both weight and cost without reducing electrical and thermal conductivity (Sheng, Yang, Xi, Lai, & Ye, 2011). A challenge is, however, that aluminum and copper have high affinity to each other, especially at elevated temperatures. This causes formation of brittle intermetallic phases with high electric resistance (Liu, Wang, Sui, Wang, & Wenjiang, 2016). In addition, both metals are subjected to oxide formation on the surface. Copper is especially exposed to oxidation at elevated temperatures (Pinnel, Tompkins, & Heath, 1979), while a thermodynamically stable oxide layer will spontaneously form on the aluminum surface (Papis, Loeffler, & Uggowitzer, 2009). Oxides are known to be passive substrates, which will reduce wettability and will thus prevent the formation of metallic bonding between aluminum and copper (Papis, Hallstedt, Löffler, & Uggowitzer, 2008)."

Jan 1, 2018