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By John Battista

Uranium mining in Australia has a chequered history. This paper reviews the development of the Australian uranium mining industry from the 1930?s to the present day. It outlines the geology of the various deposits and the mining and metallurgical techniques used to extract the uranium. The industry is profoundly affected by government policies and the paper considers the roles of the Federal, State and local governments. The influence of public opinion on nuclear issues and the effects current and historical policies of various governments have had on uranium mining are outlined. Despite heavy restrictions placed on it, Australia?s uranium mining industry has maintained its place as one of the world?s largest producers. This paper also provides an outline of where the industry in Australia may be headed in future.

Aug 1, 2010

By J. Fixter, P. Prangnell, Z. Pinter, E. Eimer, B. Chehab

"High deposition rate Wire and Arc Additive Manufacture (WAAM) can provide benefits to the aerospace industry, including a reduction in lead time, reduced material waste and, through higher solidification rates, refinement of the as-built microstructure relative to a cast material. However, candidate 2xxx series high strength alloys for this process normally require a solution treatment, which is problematic for large near-net-shape components, and age hardening to achieve maximum mechanical properties. With each layer being subject to multiple thermal cycles, exploiting the thermal conditions in the WAAM process to avoid post-build solution treatment is therefore of interest. A solutionisation model has been developed for the WAAM process, based on diffusion controlled dissolution using DICTRA, which was validated through thermal simulations combined with 2D and 3D image analysis. The model has subsequently been used to simulate the solutionisation behavior during a typical WAAM thermal cycle and to explore what could theoretically be achieved by, for example, refining the starting microstructure.INTRODUCTION There is currently great interest in exploiting additive manufacturing (AM) in the aerospace sector due to several benefits it can potentially provide; including reduced material waste, shorter product lead times and greater design freedom (Herzog, Seyda, Wycisk, & Emmelmann, 2016). However, with aluminium alloys the material properties obtained are generally inferior to those of conventional high-strength wrought products; therefore more research is required to explore the potential for exploiting the unique process conditions in AM to improve the as-deposited microstructure. A range of AM techniques are now available (Debroy et al., 2018), which differ in terms of the feedstock type and power source and it is necessary to match the appropriate technology to a particular application. This generally requires a compromise between the build rate and shape resolution. Wire and plasma-arc additive manufacturing involves using an electric arc to melt wire onto a substrate, and fabricates a part by building up overlapping layers of deposited weld beads (Addison et al., 2015; Williams et al., 2015). The benefits of this process over other AM methods are the much higher deposition rates (e.g. kg’s/hour) achievable and lower capital equipment costs relative to powder bed techniques, which makes it suitable for large scale applications. However, limitations include a lower part complexity, lower solidification rates and a greater need for post-process machining (Frazier, 2014)."

Jan 1, 2018

By S. Vaidya, R. C. McKellar, N. K. Sinha

Nominally [001]-oriented nickel-base single crystal (SX) superalloy CMSX-10 was investigated at 900°C under constant load, equivalent to an initial stress of 700 MPa, for creep strains from 7% to fracture strain (18.2%). The cross-sectional dimensions of initially uniform cylindrical specimens were measured along their entire length after the tests. The cross-section changed from circular to near elliptical shape. The anisotropic deformation, measured in terms of eccentricity, increased with the increasing strain level, but for a given strain level, it remained constant along the entire length of the initially uniform gauge section. The results are discussed in terms of diameter, eccentricity, area, local stress and microstructural observations. The most striking observation was the fact that all the specimens displayed a yoke-like shape, or the reduction of cross sectional area, at two locations within the originally uniform gauge section. Such observations have not been reported in the literature for single crystal superalloys.

Jan 1, 2006

By M. S. Moats, F. Elnathan

"The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.INTRODUCTIONCatalytic titanium anodes (CTAs) were developed in the 1960’s to replace graphite anodes in chlor-alkali cells. CTAs exhibited much better dimensional stability than graphite leading to lower operating potentials by promoting smaller electrode gaps and better operational efficiencies as they had to be replaced less often. CTAs are simply Ti substrates coated with precious metal oxides (such as IrO2 and RuO2) mixed with other components (such as TiO2 and TasO5) (Trasatti, 2000).CTAs are used in many other electrochemical industries, including water disinfection, wastewater treatment, cathodic protection and metal plating. RuO2 based coatings are typically used for chlorine evolution. IrO2 based coatings are for the most part utilized for oxygen evolution (Comninellis & Nerini, 1991; Forti, Olive, & De Andrade, 2001; Kotz, Stucki & Carcer, 1991; Trasatti & Lodi, 1981)"

Jan 1, 2016

By M. N. Vu, G. Armand, A. Noiret, D. Seyedi

Extensive experimental observations have been performed around drifts and shafts at the Meuse Haute-Marne (North-Eastern France) Underground Research Laboratory (URL) to assess the extent and pattern of the induced fracture networks in Callovo-Oxfordian claystone. Two types of fractures can be distinguished, namely; shear (mode II) and extension unloading (mode I) fractures. The main goal of the present paper is to provide insights on the extent of damaged zone around the drifts by numerical simulations. A two-step approach is considered. First, 2D elastic calculations are performed for simulating the excavation of a drift following the direction of the major in situ horizontal stress. The evolution of the stress and strain tensors around drifts are calculated by applying an elliptic convergence function on the drift wall. Two failure criteria are then verified for the induced damage. An equivalent strain and an elastic energy based damage criteria are considered. The obtained results show that the employed simplified approach provides rather good results for the extent of the damaged zone for drifts parallel to major horizontal stress. However, post-processing elastic results leads to overestimating the vertical extent of the damage zone and underestimating its lateral extent, where the in situ stress state is quasi-isotropic in a section of drift. Nevertheless, the obtained results show that an energy based damage criterion could be considered as a potential way for reproducing the extent of the damaged zones if a convergence function can be defined for the drift.

Jan 1, 2015

By P. Marcotte, G. LeBlanc, S. Ouellette, J. Boutin

"To characterize noise and vibration sources of different types of mining equipment used in underground mining, the authors performed a study in eight Quebec mines on 28 pieces of equipment. This paper presents the procedure followed to select the equipment to be evaluated, and the low-cost acquisition system developed to perform multichannel time-domain data acquisition in harsh environments. It also presents the results obtained for the noise level produced by the equipment and for handarm and whole-body vibration exposures.RÉSUMÉ Dans le but de caractériser les sources de bruits et de vibrations de divers équipements miniers utilisés sous terre, les auteurs ont étudié 28 équipements dans huit mines du Québec. L’article présente la procédure suivie pour choisir les équipements à évaluer ainsi qu’un système multicanal à faible coût développé pour acquérir des données dans des environnements difficiles. Il présente aussi les résultats obtenus pour les niveaux de bruit produit par les équipements et pour les expositions main-bras et du corps entier aux vibrations."

Jan 1, 2015

By Ahmad Ghahremaninezhad, Noelene Ahern, Yeonuk Choi

Arsenic (As) is a toxic element and is a major contaminant in the extraction processes of some metals (e.g. gold and copper). Due to the toxicity of arsenic species, its removal from As-containing streams from extractive metallurgy processes and safe disposal is absolutely necessary. For nearly complete removal of waste arsenic species from metallurgical process streams, it is required to have arsenic in its pentavalent state (As5+ species). This study presents an oxidation process for arsenic species with air or oxygen gas as oxidant. Activated carbon (AC) or other carbon based materials are used to catalyse the oxidation reaction. Air or oxygen gas is the only consumed reagent which makes the economy of the process very attractive. The oxidation reaction can be carried out at ambient conditions (room temperature and atmospheric pressure) in less than 24 hours.

Jan 1, 2014

By G. T. Lapidus, O. J. Solis-Marcial

Currently, ores with high-grades of copper oxides and secondary sulfides have become increasingly scarce, which has encouraged industry to look for alternative raw materials to obtain copper. The problem is that primary sulfides are difficult to dissolve at near ambient conditions. Proposed hydrometallurgical processes have not been implemented beyond a pilot or demonstration scale. One of the principal disadvantages is that the majority of these processes are not viable with ores that contain less than 4% copper. One of the more recently proposed techniques involves the use of organic solvents in the dissolution of copper concentrates with a chalcopyrite content of between 20 and 30%, which has shown high efficiency. The present research explores the ability of this process to leach copper from low grade chalcopyritic ores (<4% Cu) at different temperatures ranging from 20 to 50°C. It was found that depending on the temperature, high percentages of copper were extracted in 40 to 100 minutes, using different oxidants. Additionally, distinct leaching behavior was observed with each oxidizing agent. In some cases, the extraction kinetics adjusted to the diffusion controlled shrinking core model.

Jan 1, 2014

By Matthew Violot

Vale Canada?s Birchtree Mine, located in Thompson Manitoba, has been experiencing problems with hanging wall / footwall dilution, as well as sloughing off of adjacent stopes and temporary stope block backs. Birchtree Mine is interested in determining how time affects the stability of their open stope blocks. Many factors simultaneously influence open stope stability (rock mass quality, joint condition, stress condition). This makes it challenging to determine the influence of a single parameter such as exposure time or stand-up time. This study focuses on determining the effect of exposure time on open stope dilution and combines stress analysis and empirical based approaches.

Jun 1, 2012

By T. C. Chudy, C. C. Hamilton, G. R. Lane

The selection and provision of mineralogical services to assist in developing a GeoMetallurgical program for a Cu Porphyry Mine in South America is covered in this paper and presentation. The objectives of the study were to provide a rapid mineralogical scoping protocol to support and confirm results of sequential Cu leach data and to provide detailed mineralogical analysis of four composites and products on which locked cycle test-work were performed. Results showed good reconciliation was achieved between measured chalcopyrite and secondary Cu mineral contents with leach data using a linear intercept mineralogical procedure by TIMA (Tescan Integrated Mineral Analyser), as well as a generally positive correlation between pyrite and Cu-sulphide grain size. Size-by-size analysis of Composite feeds and test products was used to outline comparisons between feeds on a mineralogical basis and provide liberation and association data with which to diagnose and better explain performance. Identifying key mineralogical drivers to Cu recovery and concentrate grades using these results, a greater understanding of the role of chalcocite and pyrite on metallurgical performance was established. INTRODUCTION As a global supply of copper, porphyry copper deposits are typically very large, often in excess of a billion tons of ore (Keeney, Walters, & Kojovic, 2011; McMillan & Panteleyev, 1980) with grades typically between 0.2 and 1.2% Cu, and up to 2% Cu in places. They are also a source of gold. The complexity of copper porphyries arises from their classically zoned nature, the type of host rock, as well as whether or not they have been overprinted by oxidation, weathering and supergene enrichment (Sillitoe, 2011). Zones of alteration and other geological attributes give rise to varied mineralogy, ore mineral textures and material properties, all of which result in different processing characteristics. Due to the interdependencies of geological and processing characteristics, it is vital to study links between the geology at the macro-scale and mineralogical features down to millimeter and micrometer scale (mineral content and texture) and their influences on mineral processing behaviour (Cropp, Goodall, & Bradshaw, 2013). The growing field of GeoMetallurgy aims to provide an Orebody Knowledge framework by which to gather such information as it pertains to: (1) Understanding and predicting likely flotation response; (2) Guiding relevant test work to investigate and validate links, interdependencies, theories and data interpretation/evaluation; (3) Populate a block model with relevant information and; (4) Implement and refine the model for ongoing optimization and control. Specific questions addressed by using mineralogy often include flotation diagnostics as aids to interpretation, causes of dilution and losses to tailings, as well as guidance to sampling for test work (Cropp et al., 2013).

Jan 1, 2019

By F. Vasilikou

Commercial deployment of Carbon Capture Utilization and Storage (CCUS) requires field testing of a scale that can stress the geologic reservoirs. One such reservoir of interest consists of unminable coal seams that exhibit favorable characteristics and depositional environments and lower pressure and temperature than other, deeper, reservoirs. Such conditions can reduce compression costs while utilizing the action of adsorption that offers a more effective carbon dioxide (CO2) bonding than free storage or solution. To ensure the success of such tests, a number of parameters should be accurately determined, such as the seam geometry and stratigraphy, coal porosity and permeability parameters as well as optimum injection conditions. In essence the CO2 injection model should be calibrated for the reservoir characteristics using all available data. History matching calibrations are based on gas and water production from existing wells prior to injection. This paper will present reservoir models that were developed for a pilot--scale 907 tonnes (1000 tons) CO2 injection test that was performed in 2009 through one legacy coalbed methane production well in Russell County, Virginia, USA. The model incorporates a number of individual coal seams about 0.3 m (1ft) in thickness located at depths ranging from 300 to 700 m (1,000 to 2,200 feet). Model calibration was performed through history matching to prior production data, and subsequently the model was utilized to develop different injection scenarios. The developed model was used after injection to calculate CO2 plume distribution patterns that were monitored at the injection test. The paper will present model data and assumptions with a special emphasis on the effect of hydraulic fractures and the skin factor to the coalbed methane (CBM) production model.

Aug 1, 2013

By B. A. Watters, G. A. Parslow, F. H. Mcdougall

Carbonate-rich rocks occur at several localities within the Flin Flon volcanic sequence of the eastern Amisk Lake area. The rocks occur in two areas: as a group of small occurrences on islands within Amisk Lake and as two much larger linear belts running parallel to the regional structure east of Amisk Lake. Mineralogically, the rocks consist of talc and Ca-poor ankerite with occasional graphite. Segregation of these minerals and colour variation impart a well-defined planar fabric to the rocks and where the units are fairly continuous (e.g. Mosher Lake), their trend and attitude suggests a concordant relationship to the volcanics. Major and trace analysis of22 samples confirms the presence of two types, with one type being represented in each of the two areas. Most of the elements studied can be used to characterize the two groups, but three elements in particular give a clear separation: Mg, AI and Ni. Recalculation of the major element analyses, on a water and carbonate-f ree basis, indicates that one group (large concordant bodies with high MgO, high Ni and low AI20.J is altered ultrabasic material of peridotitic or dunitic composition. Because no relict igneous material is observed, and the contacts are apparently very sharp, it is possible that the hydration-carbonization process occurred simultaneously with intrusion, .in a closed system. The other group (small occurrences with relatively low MgO, low Ni and high AI203J represents alteration of basaltic rocks. AIthough some analyses suggest the introduction of calcium, as carbonate, along with the volatiles, the major oxides have remained remarkably stable during the alteration process(es).

Jan 1, 1981

By D. J. Scarpato

"Slope construction in shale can present some interesting challenges for geotechnical design engineers and contractors alike. There are challenges that can be expected and designed-for; however, all too frequently, such challenges manifest themselves as “surprises” in the field. Common constructability challenges can include those such as drill hole deviation during drilling for controlled blasting; and, excavation slope instability arising from inconsistent perimeter control drilling. Drill hole deviation results from the cumulative effects from both drilling mechanics and rock mass conditions. Once a hole has initiated the deviation trajectory, it is difficult to rectify drill steel position. Although such challenges are not necessarily unique to shale, they are often exacerbated by weak, weathered and transversely isotropic nature of bedrock conditions. All too often, the working assumption is that shale is “soft” and easily excavatable; however, this blanket assumption can prove to be costly. This paper is intended to provide design professionals and contractors with the practical considerations needed to avoid the “surprises” associated with drill hole deviation, and minimize the potential for costly claims.INTRODUCTIONFor all the slopes that have been excavated worldwide, and for such advancements in excavation technology and field characterization, one might be tempted to believe that the industry almost has slope development down to a science. This is frequently not the case, especially for weak/weathered and anisotropic bedrock. Excavation contractors are still pushed to the limits of what their technology can achieve, and engineers are all too often called to the field during construction, to make potentially risky onthe- fly decisions relative to excavatability, short and long-term slope stability, and project safety. Although there have been a host of other research papers and journal articles that have been written on the subject of deviation over the past 30 years (Brown, Geen, Sinha, 1981), the problems associated with drill hole deviation are still all too frequent. This fact is especially true for civil engineering surface excavations in bedrock."

Jan 1, 2015

By Simon B. Blancher, Malo Rousseau, Renato Contessotto, Thomas Wallmach

The Manganese division of the ERAMET group extracts manganese ore in Gabon and produces manganese alloys for the steel industry. ERAMET has an economic interest to maximize the ore throughput without reducing the lifetime of its manganese mines. This can be achieved by means of research and development leading to innovative ore beneficiation processes. For this purpose, the ERAMET research center has designed and constructed a new pilot plant for ore beneficiation by physical separation processes. This pilot facility was erected within an infrastructural and synergetic framework, including competencies in hydrometallurgy, pyrometallurgy, numerical modelling, analyses and mineral characterization that provide ideal research conditions. After laboratory scale tests, a pilot operation of beneficiation of low grade Mn ore (around 35% Mn) was carried out by jigging of the 1-10 mm fraction. This gravity separation process exploits density differences between the various Mn-bearing minerals such as pyrolusite and lithiophorite as well as gangue minerals such as silicates and iron-hydroxides. Enrichment leads to the production of a marketable product associated with a high mass recovery (53% for the jigging step). However, 20% of pyrolusite and 30% of lithiophorite are lost in the waste. Mineral characterization has shown microtextural complexities, but grinding the ore to approach the liberation mesh was not an option due to commercially defined constraints given by the ferro-alloy industry. Recovery of the Mn-bearing minerals or adjustments of the feed grain size (6.3-10 mm) are two potential areas of process improvements identified by means of Qemscan® mineral characterization. This paper details the process tested on a pilot scale (0.5 t/h), which has led to a significant increase in the beneficiation of a low grade Mn ore.

Jan 1, 2016

By Stephen G. Hardcastle

Worldwide, metal mines are going deeper. For example in Canada there are six such mechanized mines planning production at 3000m (10,000?). Working at such depths challenges all aspects of mining including the provision of ventilation to supply an equitable working climate for personnel and machinery. This paper explores the overall challenges of supplying ventilation in Canada?s deepest mines and how the volumes required could be minimized. This is essential because it must be remembered that ventilation and refrigeration are not only costly items to supply, but the magnitude of their cost is also very sensitive to the volume supplied. For ventilation this is obvious because of the cubic relationship between volume and cost. In deep mines, the main function of ventilation is the removal of heat transferred from the strata and generated by the mining machinery, and the air volumes supplied are designed accordingly. The second consideration is the removal of other pollutants that could be harmful to humans such as diesel and explosive fumes. However, the need for ventilation at its present design levels could be reduced. This paper discusses the implications of such technologies as: teleremote mining and alternatives to diesel equipment on the magnitude of the volume supplied; ventilation-on-demand which recognizes ventilation as a costly and limited resource; plus other aspects, such as the benefits of controlled recirculation, local cooling, and heat rejection back to the strata to gain further advantage from new developments. Furthermore, this paper advances the need to be able to design ventilation systems more cost effectively and how such new advances as process simulators can be used in conjunction with ventilation simulators to explore the diverse options that could affect the air volumes required and provide more realistic economic data upon which to base design decisions.

May 1, 2003

By H. Saari, D. Y. Seo, J. Beddoes, T. R. Bieler

Prior work on effects of lamellar orientation on creep rates and other mechanical properties have shown that having lamellae parallel to the tensile axis provides optimal creep resistance and good strength. Consequently, a directional solidification system was used to examine the effect of solidification rate on the development of crystals with lamellae parallel to the growth direction. The nominal chemical composition of TiAl ingots was Ti-46A1-2Mo-2Nb (at%) and the ingots were 20 mm in diameter and 180 mm long. The master alloy bars were placed in a high purity yttria mold on a copper chill plate and raised into the hot zone of a Bridgman furnace. The alloys were melted and then directionally solidified at withdrawal rates of 4, 8, and 12 mm/min. As-cast specimens were sectioned at positions of 4, 22, 66, 111, and 155 mm from the bottom of the ingot to evaluate microstructure and crystallographic texture as a function of distance from the bottom of the ingot. The directionally solidified microstructure consists of continuous columnar grains with fully lamellar structure, a network morphology of primary 13, yttria particles, and interlocked columnar boundaries. For all three ingots, the texture at 4 mm shows many peaks, with isolated strong peaks, and a slight tendency toward <111> plane normals within about 20° of the cylindrical axis. At 155 mm, all specimens showed substantially stronger clustering of <111> orientations near the cylinder axis, with the strongest clustering of poles occurring for the 8 and 12 mm/min specimens. Analysis of diffraction peaks indicates that strongly compressive residual stresses in the radial direction are present in the casting. The combined microscopy and texture analysis provides more complete understanding of the processes of directional solidification of TiAl alloys.

Jan 1, 2004

By S. N. Yu

Tele-operation manipulators applied in this paper are systems for the remote handling and management of pyroprocessing related facilities in an Argon cell of the KAERI (Korea Atomic Energy Research Institute). Generally, these kinds of systems are composed of a master-slave system and its peripherals installed along the wall of the cell, with the master transmitting the user?s own motion to the gripper directly. This study introduced various considerations and modifications to improve the remote handling performance. The analysis of an operator&apos;s ability using his/her own upper arm motion range while manipulating the MSM, and considerations of its manipulation margin and the related tool modifications are also included. Finally, the test results of several remote handling tasks are presented, and an adequate operation strategy for the tele-operation system of hot-cell type facilities is proposed.

Aug 1, 2013

By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By G. Bylapudi, K. Mondal, J. Hirschi

ABSTRACT: Rock bolts are the main form of defence against rock falls in mines. Conditions under-ground are conducive to corrosion. A perception exists about American coal mines that bolt corrosion is not an issue, especially when bolts are fully grouted. This perception is not necessarily accurate due to the formation of micro-cracks as the resin sets and to subsequent rock movement that breaks the resin column’s continuity. Corrosion should be considered when designing rock bolt support in long-term excavations. This paper explores the problem of corrosion, outlines a method to determine the corrosion potential of bolts, and suggests ways to mitigate such effects.

Jan 1, 2010

The uranium ore processed by the McClean Lake Operation is co-mineralized with niccolite, rammelsbergite and gersdorffite (nickel arsenides). During the strong acid leach process, the majority of the reduced arsenic is oxidized and liberated into the lixiviant solution as As+5. Following uranium extraction, the residual raffinate solution, enriched in As+5, reports to the tailings preparation process. In this process, Fe+3 is first added and mixed with raffinate (pH~1) to achieve a Fe+3/Astotal molar ratio of at least 3. This is followed by two stages of neutralization, using slaked lime to achieve a solution pH of 4, and approximately 7.5, respectively. Synchrotron based x-ray absorption techniques (XANES, EXAFS) applied to neutralized raffinate solids and tailings samples collected from the tailings management facility provide evidence that arsenic has been precipitated as a poorly crystalline form of the mineral scorodite (FeAsO4?2H2O).

Aug 1, 2010