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By Lesley Hymers

First Nations Natural Resources Youth Employment Program PDAC Mining Matters ? Charitable organization ? Provide education to students, teachers, and the public about rocks, minerals, metals, and mining ? Provide current information and offer exceptional educational resources that meet provincial Earth science and geography curriculum expectations First Nations Natural Resources Youth Employment Program ? Provide instructional development workshops for educators who are teaching Earth science and geography ? Since 1994, reached more than 400,000 students, teachers, industry representatives, and members of the public

May 1, 2009

By G. Roy

Interest in metal-hydrogen systems can be manifold. Small amounts of hydrogen adsorbed by elemental metals and alloys usually result in strong changes in the physical and mechanical properties of engineering materials. Overwhelmingly, these changes, viz. hydrogen embrittlement, are considered deleterious with respect to structural performance of engineering materials. However, the changes, often studied by metallurgists and metal physicists, can present new possibilities and applications. A prominent example is the recent interest in safe, solid-state hydrogen storage in metallic lattices. In a new laboratory in MTL, Ottawa, a study has been initiated to investigate the effect of "micro- and macro- alloying" of Al and Mg powders with hydrogen (in high-energy mechanical alloying mills) on plastic deformation in metal and metal hydride structures. It is anticipated that high-rate impacting and subsequent grain refinement in the mill will have an effect on hydrogen storage capacity in lightweight magnesium and aluminum alloys. First examination of the state-of-stress by X-ray diffraction in high-rate milled, nanostructured pure aluminum, aluminum milled with a solid surfactant, and aluminum or magnesium alloy milled with hydride and/or gas hydrogen will be presented.

Jan 1, 2005

By K. M. Wild, C. D. Martin, F. Amann

"Argillaceous rock formations, in particular clay shales, are notorious for creating challenges in rock engineering. Due to their generally low hydraulic conductivity and their complete saturation in their natural state at depth, the behavior of clay shales is usually characterized by a strong hydro-mechanical coupling.This paper presents typical pore pressure responses monitored in different underground rock laboratories and explores alternative ways for their interpretation. The underpinning processes and their relevance are identified based on analytical and conceptual numerical models. Pore pressure monitoring data from Opalinus clay at the Mont Terri Underground laboratory, the Boom Clay at the Mol facility and the Callovo-Oxfordian clay in the Meuse/Haute–Marne URL show a similar pore-pressure response associated with stress changes accompanying tunnel construction although the tunnels were built in different rock types, at different locations, and under different in-situ conditions.The numerical analyses in this study shows that the pore pressure response around an excavation in low permeable clay shales may have different explanations. Pore pressure drops observed in the tunnel near field can theoretically be explained by both, a pure elastic response in an isotropic or anisotropic rock mass with an anisotropic stress state, or a inelastic response and related dilatancy. However, a comparison between the numerical models and the in-situ measurements revealed that the latter is more likely. This conclusion is justified by the observation that pore pressure drops occur significantly ahead of the tunnel face which is not the case in elastic numerical simulations. Pore pressure measurements in the far field, where failure processes are unlikely to occur, can only partly be explained by a linear poroelastic models. The introduction of an anisotropic material plays a key role in reproducing the responses, conceptually."

Jan 1, 2015

By Doris Stüben, Geoffrey P. Glasby, Akira Usui, Jörg-Detlef Eckhardt, Bruce W. Mountain, Zsolt Berner

"Abstract - Twenty-seven marine Mn and Fe deposits chosen for their diverse origins have been analyzed for five platinum-group elements (PGE). The PGE display their highest concentrations in hydrogenous Mn crusts and nodules, lesser concentrations in diagenetic nodules and two to three orders of magnitude lower concentrations in hydrothermal Mn and Fe crusts. This difference of behavior reflects the well-known fractionation of Mn and Fe from the other transition elements, rare earth elements (REE) and PGE in hydrothermal Mn and Fe crusts. Pt, Ru, Rh, and Ir show a close geochemical coherence in these deposits and are differentiated from Pd which shows a negative anomaly with respect to the other PGE in hydrogenous and diagenetic Mn deposits. Pd is less depleted than the other PGE and the Pd anomaly much less pronounced in the hydrothermal Mn and Fe crusts relative to the hydrogenous and diagenetic Mn deposits.Stability field diagrams show no evidence for the oxidation of Pt to the tetravalent state in seawater as suggested by some authors. Rather, Pt appears to be present in seawater as Pt(OH)2 0. Adsorption of Pt(OH)2 0 onto the surface of Mn and Fe oxyhydroxide minerals may explain the enrichment of Pt in marine Mn deposits. However, Pt metal is the thermodynamically stable solid phase of Pt under seawater conditions and reduction of Pt(OH)2 0 to Pt metal, particularly in the vicinity of the oxygen minimum zone, is possible, although the high Ce/La ratios of the Co-rich Mn crusts do not support this hypothesis. Pt, Ru, Rh, and Ir display their maximum concentrations in the Corich Mn crusts. This may reflect, among other things, the low growth rates of these deposits. The stability field diagram of Pd shows that Pd is undersaturated in seawater and occurs in seawater dominantly as PdCl4 2- and anionic mixed-hydroxide-chloride complexes. This would explain the anomalous position of Pd among the PGE with respect to its uptake into marine Mn deposits. A study of inter-element associations indicates that the incorporation of the PGE from meteoritic dust plays only a minor role in the uptake of these elements into marine Mn deposits. The PGE remain the most poorly studied group of elements in marine Mn deposits. The data presented here emphasize the need for the establishment of a more comprehensive database of the PGE in marine Mn deposits in order to understand more fully their uptake into marine Mn deposits and their pathways through the oceans."

Jan 1, 1999

Drilling is a common process in mining and petroleum engineering applications which have different objectives. For example, drilling deep boreholes in tight gas formations and gas shales is becoming more popular in the oil and gas industry. By contrast, drilling deep small sized holes for mineral exploration in hard rocks is performed to obtain samples for grade analysis purposes. In both applications optimising the drilling process includes using the most effective operating parameters such as rotation speed and weight-on-bit in order to maximise the rate of penetration. Obtaining the optimum drilling parameters requires sensitivity analysis over a range of data, which would be costly and time consuming during real field operations. Therefore, conducting several experimental simulations in the lab would be very beneficial before field operations begin. A drilling rig was designed and developed to simulate various drilling scenarios. The rig works in conjunction with an existing true triaxial stress cell (TTSC) which is in use for different petroleum related applications. The rig allows drilling into a cubic rock sample of up to 300 mm size. Three independent stresses can be applied to the sample to simulate real in-situ field stress conditions while the sample may be saturated with fluid. A significant feature of the rig is its ultra-high speed rotation which can rotate up to 8000 rpm: this is to simulate hard rock drilling for mineral exploration applications where large weight-onbit could damage the bit cutters. With the proposed design, a drilling fluid of any type can be circulated in the simulated borehole similar to the real situation, to study its effect on drilling performance. The TTSC drilling lid is equipped with torque and drag measurement systems which are two important drilling parameters to be recorded during drilling operation. It is believed that this new drilling rig will open opportunities for performing major new applied research in the area of more efficient drilling in both oil and gas bearing formations and mineral exploration applications.

Aug 1, 2013

By D. Kalumba, S. Jjuuko

"Thin Spray-on Liners resist relative small deformations (< 1 mm) between rock blocks or fragments in terms of a combination of shear, adhesive and tensile-bond strengths. Shear-bond strength addresses the ability of a thin liner to resist stresses that act parallel to the rock-liner interface. Therefore quantification of shear-bond strength is essential in the formulation of design standards and requirements for Thin Spray-on Liners. In this paper Thin Spray-on Liner support mechanisms are reviewed. In addition previous methods of Thin Spray-on Liner shear-bond testing are discussed. The paper also explains the research being carried out at the University of Cape Town to investigate the effect of different parameters on the shear-bond strength.INTRODUCTIONRock surface support is widely used to combat rockfalls and resulting injuries and fatalities in the vicinity of active faces (Potvin, 2002), where workers spend most of their time (Adams & Baker, 2002; Potvin, 2002; Lacerda, 2004). The conventional (traditional) surface support systems in underground rock support include passive methods such as mesh and lacing and active methods such as shotcrete. However, rockfall sources between 1990 and 2000 in Nevada gold mines showed a steady increase in rockfall injury associated with mesh support as shown in Figure 1 (Lacerda, 2004). The conventional methods also negatively impact the mining operations with regards to costs, logistics and mining cycle times due to large material volumes (Tannant, 2001; Ozturk & Tannant, 2010; Ferreira, 2012). Therefore, these systems need to be substituted, with enhanced methods, in order to realize the business target of the mining industry of providing the planned return on investment made without harm and within budget."

Jan 1, 2015

By D. A. MacFadyen, J. J. Brummer, C. C. Pegg

"The first record of a kimberlite found in Canada (1946) was the identification of thin dykes intersected while drilling for gold in Michaud Township, Ontario.Sampling of the Munro Esker (1964) in the Kirkland Lake area, Ontario, by the Geological Survey of Canada identified the occurrence of detrital grains of pyrope garnets along a length of 35 km of the 113 km tested. A search for the source of the garnets resulted in the identification (1968) of a narrow subsurface kimberlite dyke in the Upper Canada Mine. This discovery resulted in a staking rush. Unfortunately, subsequent work did not identify the source of the kimberlite indicator minerals.During 1978 the Ontario Geological Survey started a multi-discipline study of 29 townships (2560 krn2) in the Kirkland Lake area, to encourage exploration for gold, base metals, and kimberlites. Back-hoe sampling (1979 to 1982), where the overburden was thin, and reverse circulation drilling, in areas of thicker drift, yielded samples of the till. These were analyzed for several elements and a mineralogical identification of the heavy minerals was completed. Pyrope and chrome diopside grains were identified.Studies of the Pleistocene geology indicated only the most recent direction (167 degrees) of ice advance (Matheson) and the associated deposits, out of a possible three advances known to occur in the general region straddling the Ontario-Quebec boundary, is present in the immediate area of Kirkland Lake. Contouring the distribution of pyrope grains (1990) showed a concentration centered over an area of 616 km2 extending down-ice from Gauthier Township. This included a smaller area containing chrome diopside grains. Kimberlite boulders were identified (1981) in gravel pits on the Munro and Misema River Eskers located within this anomalous area. The next step would be to use the airborne geophysical data to locate the kimberlite pipes which yielded the indicator minerals and boulders. The source area is likely to be in the northern half of the Ontario Geological Survey study area."

Jan 1, 1992

By O. A. Ojo, D. L. Chen, N. Zhou, J. Q. Zhang, A. K. Khan

Dual phase (DP) steels are designed to consist of hard martensite dispersed in a relatively soft ferrite matrix, which offers a favorable combination of high strength with good deformability. Fiber laser welding (FLW) is becoming increasingly important for joining advanced materials due to its flexibility and deep penetration. In this study, the microstructure of a dual phase steel, DP980, welded by FLW technique was carefully analysed. Gleeble thermo-mechanical simulation coupled with analytical transmission electron microscopy (TEM) revealed that the FLW process produced significant microstructural changes in a narrow heat affected zone (HAZ) and fusion zone (FZ), which can result in dramatic changes in mechanical properties. This is reflected in the micro-hardness profile obtained across the welded material. The salient phase transitions induced by the FLW, including the formation of new martensite grains in the upper-critical HAZ and FZ, are discussed.

Jan 1, 2014

By Daan Maijer, Wade Marquardt, Robert MacKay, Steven Cockcroft, Farzaneh Farhang Mehr

"To comply with the new Corporate Average Fuel Economy (CAFE) standards, the automotive industry is aiming to reduce weight and increase the power and efficiency of small displacement engines through the application of forced induction technologies. As an example, there are now several 2.0 litre turbocharged engines in production, producing in excess of 240 hp. To meet the need for improved fatigue properties in the engine blocks used in these high-output engines, a new water-cooled chill technology is under exploration at UBC in partnership with General Motors and Nemak. A series of experimental techniques were used to assess the capability of the new chill to extract heat from an A319 casting in the vicinity of the main bearing bulk head. The results show that this method has the potential to achieve a reduction in secondary dendrite arm spacing thus meeting the new microstructural specifications for these engines.INTRODUCTION The automotive industry is working to meet the stricter efficiency requirements laid out within the CAFE (Corporate Average Fuel Economy) regulations (Bastani, 2012; Cole, 1995; Mackay, 2011; Miller, 2000), while at the same time not sacrificing performance. One approach is to increase the use of lightweight materials, which leads to a decrease in the overall vehicle weight and fuel consumption (Cole, 1995; Mackay, 2011; Miller, 2000). Other approaches include smaller displacement engines and gas-electric hybrid drivetrains. However, one trend that is becoming clear, is a greater emphasis on force induction gasoline engines. This allows for weight reduction to be achieved with smaller displacement engines without sacrificing performance. One consequence of this approach is that the engine block materials are subject to higher in-service thermal and mechanical cyclic loads (Cole, 1995; Miller, 2011; Heysler, 2001) The fatigue properties of an alloy are strongly affected by a number of the, as-cast, microstructure features including, Secondary Dendrite Arm Spacing (SDAS), porosity and eutectic lamella spacing (including intermetallic ß-Al5FeSi platelets) (Mackay, 2010a; Mackay, 2010b; Viet-Duc, 2015; Casellas, 2005). It is generally accepted they can act as fatigue initiation sites and that a reduction in their size will result in an improvement in fatigue performance. For a given alloy chemistry, one of the key parameters affecting the length scale of all three is cooling rate (Mackay, 2000)."

Jan 1, 2017

By Bryon Bisiaux, Walter Valery, Sonny Mwansa, George Amonoo, Adrian Dance

"Newmont Ghana Gold Limited’s Ahafo operation have been working with Metso Process Technology & Innovation (PTI) since early 2009 to increase mill throughput from a combination of controlled blasting practices and optimised primary crusher and grinding circuit conditions. For such Mineto-Mill projects, PTI’s methodology is termed Process Integration & Optimisation (PIO).Ahafo operate a SAG mill, ball mill and pebble crusher (SABC) circuit that processes a range of primary ore of varying hardness from different pits which is blended with soft oxide material. The PTI study focussed on ball mill limited material from the Apensu open pit.Following a benchmarking study of all blasting, crushing and grinding practices in January 2009, PTI recommended changes in both blasting and crushing conditions in order to generate a finer feed size to the SAG mill. Additional operating changes in the grinding circuit were recommended.A series of trials were conducted in November 2009 where three blasts were fired using a different blast design (hole diameter and explosive type) in the same area of the Apensu pit as the benchmarked material in January 2009. Top and bottom benches (or flitches) from each blast were sent exclusively to the grinding circuit and the material was tracked using PTI’s SmartTag™ system.The results from the six trials showed a significant increase in primary ore throughput at a reduced blend of oxide material. Ahafo have since standardised on these modified blasting conditions for all Apensu ore zones and have been able to sustain higher throughput compared to historical performance on similar material.This paper summarises the phases of the PIO project, the changes made in operating practices and the outcomes of the blasting trials that validated the predicted increase in mill throughput."

Jan 1, 2012

By J. J. Benitez

MIBC (methyl-isobuthyl carbinol) was previously shown to enhance significantly sylvite flotation when used at the stage of preparation of amine dispersions. In this paper Atomic Force Microscopy (AFM) is used to study the effect of MIBC on deposition of octadecylamine (ODA) on the surface of mica. The AFM images indicate that amino terminated, and therefore hydrophilic, deposits of ODA are observed on the mica surface in the ODA dispersions free of MIBC. In the presence of MIBC a methyl terminated (hydrophobic) monolayer is obtained on the mica surface. The transition between the monolayer and bilayer phases is due to the presence of MIBC. Experiments carried out in distilled water reproduced the results obtained from the brine. Working in pure water instead of brine simplifies the preparation conditions and the analysis by AFM.

Jan 1, 2006

By David Deglon, Martin Harris, Mehdi Safari

"This study investigates the effect of energy/power input on the flotation of a platinum ore in a pilot-scale oscillating grid flotation cell. Oscillating grids generate near ideal hydrodynamic environments, characterised by turbulence which is relatively homogeneous and isotropic. Secondary rougher feed and primary cleaner tail streams were floated in a pilot-scale oscillating grid flotation cell at power inputs from 0 to 2.5 W/kg, using 0.50 and 1.50 mm bubbles. From this study one may conclude that the effect of energy/power input on the flotation rate is strongly dependent on the particle and bubble size. Flotation rates generally increase with increasing particle size and decreasing bubble size. Increasing energy input generally leads to an increase in the flotation rate for finer particles and an optimum flotation rate for intermediate & coarse particles. Optimum conditions for intermediate/coarse platinum ore particles are using small bubbles at low energy inputs, or large bubbles at higher energy inputs. These results suggest that higher energy inputs are generally beneficial for the flotation of platinum ores as these consist predominantly of finer particles (-75 µm) and most industrial flotation applications operate with larger bubbles (1.0-2.0 mm).INTRODUCTIONThere is a considerable body of experimental and theoretical evidence to suggest that energy/power input plays an important role in flotation kinetics, particularly in the finer particle sizes where flotation efficiency is poor (Deglon, 2005). A number of excellent studies into the effect of energy on flotation kinetics have been carried out in impeller stirred cells (Ahmed and Jameson, 1985; Deglon, 2002; Pyke et al., 2003; Newell and Grano, 2006). Investigations using this type of cell have a number of limitations. The impeller influences particle suspension, bubble break-up and agitation in the cell. In addition, turbulence is highly inhomogeneous and anisotropic, with power intensities near the impeller orders of magnitude higher than those found elsewhere in the cell (Deglon, 1998; Koh and Schwarz, 2003; Schubert, 1999, 2008). These limitations have resulted in the development of novel cells for the investigation of energy input."

Jan 1, 2016

By M. Sukhram

In the year 1992, T.A. Utigard published a paper titled "The measurement of the heat-transfer coefficient between high temperature liquids and solid surfaces." In that work, he instrumented an agglomerate of materials with thermocouples to infer the heat transfer coefficient of a high temperature liquid on a solid. The purpose of that research was to help in the design and operation of metallurgical reactors. Since that time there have been many researchers that have worked to characterize heat, mass, and momentum transfer phenomena in high temperature metallurgical processing operations. This paper presents results from the author’s experience with instrumenting thermocouples in copper elements coated with carbon to infer velocity of high temperature liquid metals. It also presents a methodology to determine velocity of a high temperature liquid by inferring the local heat transfer coefficient at a solid-liquid interface

Jan 1, 2015

By Geir M. Haarberg

Electrochemical techniques, mainly linear sweep voltammetry and potential step chronoamperometry, were used to study the behaviour of dissolved phosphorus species in cryolite-alumina melts, The presence of AIPO4 or Na3PO4 gave rise to voltammetric current waves due to electrode reactions involving phosphorus species at potentials where dissolved alumina is stable in cryolite melts, Diffusion kinetics for dissolved P(V) species were studied, Data from industrial cells were used to determine mass balances for phosphorus, For cells being fed with secondary alumina, more phosphorus tends to end up in the produced metal, Laboratory experiments to study the effect of phosphorus in the bath on the current efficiency for aluminium were also carried out.

Jan 1, 2004

By M J. Daniel

Comminution is the science of size reduction of brittle materials. It is integral to mineral extraction and is one of the most energy intensive processes in the mining industry. There are a number of tests used to quantify the strength of ore, which are then used to size the AG / SAG mill in circuit design. The calculated energy utilized for breakage in these devices is based on the assumptions that the materials treated are of average shape and that the processing equipment is designed to break the ore as efficiently as possible under the given operating conditions. In drop weight tests, it was found that shape significantly influences the measured rock strength. Controlled experiments with variations in blends of rock shape show that mill throughput increases with the addition of weaker shaped rocks.

Jan 1, 2012

By M. Al-Hilal, G. Rajja, A. Al-Ali, Y. Jubeli

Abstract -A radiometric survey was carried out over clastic sediments in the immediate vicinity of some phosphatic sediments of Cretaceous age in the Wadi Qasser Al-Hallabat basin of central Syria. The objective was to explore for uranium and to define its dispersion pattern. This was based on ground radiometric surveys and geological studies. All ground surveys (using radon emanometry, track etching, gamma-ray survey and geochemistry) gave similar results, outlining the locations of the radioactive phosphatic formations in the basin, and indicating the dispersion pattern of uranium in the clastic sediments in the surrounding area. The dispersal of uranium from upper Cretaceous phosphatic formation occurs by mechanical weathering and chemical leaching by oxidizing surface waters. A rough estimate is that about one-third of the original uranium content of the Cretaceous sediments has been dispersed. Mechanical erosion is responsible for the main part of this released uranium, which now occurs in Recent sediments. However, the occurrences of spotty secondary U mineralization indicates that another small part of the available uranium must have been chemically leached out by the prevailing oxidizing waters, forming minor surficial minerals.

Jan 1, 1998

"Sedimented hydrothermal precipitates of silica, now fine-grained quartz, are described from a Pb-Zn-bearing vein system. Their discrimination from the wall-accreted fine-grained quartz that is common in the shallow parts of epithermal systems is discussed. Local fine-grained (<0.3 mm) quartz accumulations occur in a suite of veins with otherwise normal drusiform and crustified infills. This sediment may fill the vein above chokes in steep segments (axial plugs), or form continuous layers within the footwall material where the vein is inclined at low to moderate angles. Pads of fine-grained sediment are deposited on the upwards-facing surfaces of wall-rock clasts and of drusiform crystals growing from the vein walls. The asymmetry of these deposits differentiates them from the more common symmetrical, crustified walllining deposits of fine-grained quartz and opaline silica, and requires a gravity-controlled, sedimentary depositional mechanism.Thin section examination shows that much of the fine-grained quartz is present as elongate prisms. The prism habit was present soon after deposition, but it is not possible to identify unequivocally the original sedimented grains. Sedimentation of vein- and wall-rock-derived detritus is also recognized. Deposition of the fine-grained sediment accompanies normal in situ drusiform growth of quartz and other vein minerals. The mammilated and spherulitic textures associated with accretion of amorphous quartz are entirely absent from the Tyndrum veins with sedimented materials. The literature on modern hydrothermal waters and physical chemistry of silica precipitation shows that precipitates of silica suspended in hydrothermal fluids are amorphous and derived from colloidal silica. It is argued that much of the suspended silica was present as quartz at the time of deposition or was converted from amorphous silica almost immediately after deposition.Hydrothermal sediments and their distribution potentially provide information on flow directions and velocity in veins. Plugs of sediment obstruct vertical flow and lead to local flows with large horizontal components. It is shown that sedimentation features occur in other deposits and can involve other minerals. If the features seen here can be scaled up to the size of major veins, they may result in up and downdip variations in mineral assemblages and abundances, which may affect grade."

Jan 1, 2007

By A. Koster, V. Maurel, S. Dezecot, Szmytka. F.

The aim of this work is to clarify the role of microstructure heterogeneity in the initiation and growth of cracks in a lost foam cast A319 for low cycle fatigue (LCF) loading condition. Because 2D analysis fail to establish the scenario of damage events, this study is based on 3D in situ analysis using synchrotron X-ray tomography during LCF test performed at 200°C. If X-ray tomography is now an established technique to study damage development in 3D, its application for relatively high temperature cyclic tests has never been done so far. Initial 3D observations of damage show that the cracks that lead to fracture initiate near large pores and propagate into the hard particles 3D network of the eutectic regions.

Jan 1, 2015

By J. G. Pharoah

Over the last two decades a variety of models for solid oxide fuel cells (SOFCs) have emerged ranging from one dimensional (1-D) to 3-D models, from steady-state to transient models; single- and half-cell and entire stack models. A majority of these models have focused either on the transport processes or on the chemical/electrochemical processes. The approach taken by our research group is to develop a comprehensive SOFC model framework based on the considerations of detailed electrochemical reaction mechanism and by accounting for complex transport processes occurring in the porous media at the micro-scale level. In this paper, we review the state-of-the-art in SOFC modeling and identify the existing gaps that need to be filled in.

Jan 1, 2005

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016