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By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By A. M. Salomon de Friedberg

With respect to impurities, HBM&S' copper smelter, located in Flin Flon, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Flon is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&S' metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.

Jun 1, 1993

The process of gold recovery by gravity concentration is incorporated in the metal recovery flowsheet at seven Newmont Mining Corporation owned mining operations in Australia, North America and Africa. In 2009 gold recovered by gravity processing was equivalent to nine percent of Newmont's total gold sales of 5.3 million ounces. This paper will discuss these applications in detail including a review of plant flowsheets and presentation of recent operating results. Operating performance will be discussed with reference to ore characterisation procedures, interpretation of results, design considerations and optimisation practices as they relate to the recovery of gold by gravity concentration.

Jan 1, 2011

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013

By Robert D. Irvine

"Enhanced concern for protection of the environment and attendant actions by environ-mental regulatory authorities in support of this concern are influencing, to varying degrees, the demand and supply of a range of industrial minerals in a number of jurisdictions. These influences take a variety of forms.In this paper, the author seeks to delineate certain broad trends which are occurring relative to industrial minerals and the environment and then, through a series of examples, to outline opportunities, developments, and impacts respecting a number of industrial minerals produced and consumed in Canada and the United States."

Jan 1, 1996

By N. Shi, T. G. Joseph

ABSTRACTA series of algorithms were developed to perform geometric and kinematic analyses of cable shovel dipper-ground interactions for a given set of mining face conditions. The routines examine and analyze (a) the position of the dipper in relation to the shovel; (b) the dipper in relation to the face conditions; (c) the dipper position in relation to possible interference or collision with crawler tracks during digging cycles; and (d) kinematic and geometric considerations with respect to any point on the dip-per as it conducts a duty cycle. In all cases, field measurement verifcation provided good agreement(within 4% variance).

Jan 1, 2011

By J. Hall Carpenter

"Wet concentration has, in the history of ore dressing, been the primary treatment method following crushing, grinding and sizing, when these have been necessary. The evolution of new methods of gravity concentration has been comparatively slow.Today, the most significant and sophisticated of the new types of gravity concentrators is, no doubt, the cone concentrator developed by Ernst Reichert of Mineral Deposits Pty. Limited in Southport, Australia. These units have now had some years of use in the field, are becoming one of the standard tools of the industry and their metallurgical results, as outlined in this paper, are out-standing."

Jan 1, 1966

By C. Hu

A MOS capacitor hydrogen sensor array is reported for hydrogen gas distribution mapping. Si(100) was used as substrate for film deposition. After silicon oxide growing on the silicon surface with dry thermal oxidation, palladium film was sputtered on silicon oxide as hydrogen-sensitive gate material in MOS structure. The 3x3 sensor array was patterned on silicon substrate and packaged in one chip. Sensors' response was test with impedance analyzer. The sensors in array were calibrated in the hydrogen concentration range from 10ppm to 10000ppm. The 2D hydrogen concentration distribution was obtained with the calibrated sensor array.

Jan 1, 2005

Recently, renewed interest in the recovery of uranium from leach solutions has necessitated a re-examination of the hydrometallurgy methods used for uranium in the 1960?s to 1970?s. A synthesizing overview of the lessons learned in those decades together with examination of recent developments in this area is warranted. This paper considers uranium recovery chemistry from acid and alkali leach solutions using solvent extraction and resin ion exchange, and provides information on circuit selection and configuration, equipment selection and design, as well as operational considerations. The unique thermodynamics of uranium solvent extraction are also presented and discussed.

Aug 1, 2010

By Edouard Asselin, Tasawar Javed

This study was conducted as a part of ongoing work to characterize sulphide concentrate leach residues generated under CESL (Cominco Engineering Services Limited) and Vale pilot and demonstration plant medium temperature (150 °C) process conditions. Three different samples were analyzed. Derivative samples were prepared by extracting gypsum, sulphur and amorphous/poorly crystalline iron oxyhydroxide phases from the leach residues. Thermal behavior of the samples was studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) in the temperature range 25 to 800 °C in both air and nitrogen atmospheres, with XRD analyses both before and after heating. Thermal transformation temperatures for different iron oxides/oxyhydroxides present in hydrometallurgical leach residues vary over a wide range which suggests the variable crystallinity of the phases. Raman spectroscopic analysis was carried out to help identify the type of iron phases in the residues. Furthermore, hydroxylamine hydrochloride (HaHC) and oxalate extractions were used to compare the fractionation of the amorphous/poorly crystalline iron phases in the residues. Given the compositions of the residues, any thermal events in the temperature range of 200 °C to 480 °C were attributed to amorphous/poorly crystalline iron phases.

Jan 1, 2014

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By J. Chenier, M. Boissoneault, D. Ducharme, R. Schonewille

The operation of Falconbridge's Sudbury nickel smelter has undergone significant change since the production was consolidated to a single electric furnace in 1994. In the late 1990's a capital program of about $100 MM (Cdn) was undertaken to expand and modernize the smelter. This project, known as Smelter 2000, was mainly driven by the need to process the new concentrate produced at Falconbridge's Raglan operation in northern Quebec. Included in the scope of the project was the installation of dry concentrate handling facilities, modifications to the roaster feed preparation system, installation of a matte granulation system and modification of one of the converters. Improvements to in-plant hygiene were also an important part of the Smelter 2000 project. Over the past 5 years much has been learned about the challenges in treating two significantly different concentrates. More recently, the introduction of a third concentrate from Falconbridge's new Montcalm operation near Timmins, Ontario has added another dimension to the operation. This paper will describe how the main challenges from the past 7 years have been overcome and discuss the path forward for the Sudbury Smelter Business Unit.

Jan 1, 2005

By Timothy W. Ellis, Abbas H. Mirza, R. David Prengaman

Recycled lead, i.e. material produced by the recycling of lead-acid batteries, has become the primary source of lead in much of the world. This has been important to the recycled lead industry as other uses have dwindled, e.g. lead based pigments, chemicals, fuel additives, solders and CRT glasses. Presently, battery manufacturing accounts for greater than 85% of lead consumption worldwide while recycled lead accounts for approximately the same market share of lead supply. Battery manufacturing and production of recycled lead are intimately coupled. In 2007, of all the industrial base metals, lead from lead-acid batteries had the highest recycling rate in North America at greater than 95%. In this paper we will review some of the processes and technologies used in a modern lead acid battery recycling facility, and how recycled lead has become the material of choice for battery construction through the development of a recovery and refining process that exceeds the industry requirements. We will also briefly review an advanced air emissions treatment system in a modern lead recycling plant that demonstrates the feasibility of a new maximum available control technology (MACT) for secondary lead smelters.

Jan 1, 2011

By V. I. Lakshmanan

Recycling helps to save energy and is good for the environment. It is also important for preserving the limited natural resources. In addition, recycling creates economic benefits and frees up space at the landfill sites. Process Research Ortech Inc. (PRO) has conducted extensive testwork in the area of waste processing and recycling. A process was developed for the recovery of Zinc from galvanized steel by alkaline leaching followed by solvent extraction and electrowinning. Extensive testwork has been conducted at PRO to obtain a useful by-product from rice husk. Rice husk was combusted in a gas/solid reactor to obtain an environmentally acceptable amorphous silica ash suitable for use in high strength concrete. In another development, vanadium was recovered from fly ash by separating carbon first, followed by alkaline pressure leaching, solvent extraction and precipitation. PRO has also developed an environment friendly process for treatment of industrial wastewater for its reuse to obtain zero or minimal effluent discharge. In this paper, four case studies related to recycling of zinc scrap, controlled combustion of rice husk, processing of fly ash, and reuse of waste water will be discussed.

Jan 1, 2011

By S. Khallouk, J. Zollinger, J. R. Kennedy, E. Bouzy, B. Rouat, D. Daloz

Titanium aluminides recently replaced Ni-based superalloys as turbine blades in the last LP stage of aircraft engines. To extend their range of use at higher temperature their properties need to be improved, either by alloying or processing. An efficient solution is to reduce the grain size during the solidification process. In the first part of the paper, an overview is given on the possibilities for grain refinement of such alloys, based on literature data and new results. The most efficient grain refinement is obtained with boron addition which leads to boride formations that are detrimental for in-use properties of turbine blades. In this work, the use of the high grain refinement potency of inoculation with non-brittle particles has been used by developing new refractory-based inoculants. The effect of one of these inoculants on grain refinement of an as-cast structure in a Ti-46Al is presented; resulting in a reduction of the grain size by a factor of 3.While less efficient compared to the potency of boron containing alloys, the grain refinement is effective and does not introduce any embrittling particles.

Jan 1, 2015

By Mary A. Wells, Amir Hadadzadeh, Mark A. Whitney, Stephen F. Corbin

In an effort to produce less expensive titanium sheet via roll compaction, the room temperature compaction behavior of titanium sponge granules (99.9% pure, Alfa Aesar) was studied under uniaxial die compaction. The titanium sponge granules were irregularly shaped, with a high degree of porosity, having a maximum particle size of 3mm. Manual die compaction was conducted using a Carver hand press, in a hardened tool steel die with 12.61 mm inner diameter. Uniaxial die compaction in a hardened tool steel die with 9.50 mm inner diameter was also performed using a Gleeble® 3500 thermal-mechanical simulation testing system which allowed for controlled deformation rates. Compaction behavior of the titanium sponge was studied using well-established compaction equations (Heckel, Panelli-Filho and Ge), and it was observed that compaction rate influences the room temperature compaction behavior of this material. The Heckel analysis of the titanium sponge showed that the behavior of the material could be analyzed in two compaction pressure regimes. In the low pressure regime (<100 MPa) the granules exhibited high compressibility, while; in the high pressure regime (>100 MPa) lower compressibility of the titanium sponge was observed.

Jan 1, 2015

By A. M. Hadian

The use of dolomite refractories in steel making and cement industries has advantages over other basic products particularly in countries where this type of refractories is produced. Due to existence of high-quality dolomite deposits in many regions of Iran, there is a good potential for producing dolomite refractories in the country. This study focuses on the effect of such additives as iron oxide and alumina on hydration resistance and density of Iranian dolomite. It was found that addition of Fe2O3 is more effective than Al2O3 on increasing density as well as resistance to hydration of dolomite.

Jan 1, 2004

By P. W. Waggitt

ABSTRACT From approximately 1986 until 2000, uranium production was at a historic low. In 2003, uranium mineral exploration surged, despite the global financial crisis; however, the shortage and aging of qualified and experienced operators and regulators might soon become a constraint to this upsurge. This is true for all types of engineers, geologists, other scientists, tradespeople, and technicians. The situation raises questions about how the global mining industry in general and the uranium sector in particular will cope with future staffing needs. In this paper, the author examines the current situation and describes how some organizations are seeking possible solutions.

Jan 1, 2014

By Alessandro Navarra

Discrete event simulation provides a computational framework in which the use of smelting equipment can be analyzed and optimized, leading to the development of alternative modes of operation. Much of the complexity of copper and nickel smelters is centered on the converter aisle. These converters operate in parallel, produce batches, and set the tempo for the downstream operations. In practice, smelter staff schedule daily operations to coordinate the smelting furnaces and converters with downstream operations. Thus, a realistic simulation of smelter operations, over hundreds of days, should incorporate converter scheduling algorithms as presented in this paper.

Jan 1, 2014

By H. Gharahbagheri, S. Shafiei Zadeh, H. Hassan Nejad, Reza Roostaazad

In this paper, dissolution of vanadium from mining residue, in which vanadium is associated intimately with magnetite ore, was investigated via both bacterial ( aerobic and anaerobic) and fungal activity. Although bacterial activity was tangible, it could not reduce and dissolve vanadium in both aerobic and anaerobic experiments. However, in fungal leaching, after 30 days about 36.9% and 29.7% of vanadium was dissolved for a pulp density of 10 and 30 g/l, respectively. At the end, the concentration of metabolites usually produced by fungal activity was optimized and oxalic acid was chosen as the main agent for the leaching process.

Jan 1, 2014