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By M. V. Rowley, D. D. Warkentin

With high commodity prices, tightening operating budgets and increasing disposal costs, there is an increasing interest in processing municipal waste streams, such as the ash derived from combustion processes. This paper describes laboratory development work for a process to recover metal values from the finer fractions of these wastes. The work was initially aimed at recovery of copper and the removal of lead and other heavy metals from the ash residue, but results showed gold and silver recovery to be an important objective as well. The process uses gravity and flotation as the principal separation steps, with gold recovery occurring mainly in the flotation stage. The particle size range and chemistry of the ash presented numerous challenges to developing a suitable flotation method, but an effective flowsheet was developed by separating the ash into a fine fraction and a separate slime fraction, each with a unique flotation strategy. Specialized conditioning stages and careful reagent selection have resulted in effective gold and silver recovery from a range of ash types and sources. The work has resulted in a patent being issued for a process based on this novel approach to the treatment of combustion wastes.

Jan 1, 2017

"Syncrude Canada Ltd. operates one of the largest surface mines in the world. The mining operation has two distinct phases: (1) the removal of the overburden, utilizing trucks and shovels; and (2) the mining of oilsand with drag lines and bucketwheels. Both phases combined move approximately 330 000 BCM per day.In support of current production demands and to provide a contingent oi/sand source, Syncrude has developed an Auxiliary Production System (APS) supported by the truck and shovel operation. This system utilizes oilsand sources within the existing mine area on an as-needed basis.The recent increased capabilities of the processing plant to handle a larger volume of oilsand has increased the reliance of the APS system. To facilitate the increased capacity, an auxiliary mine was developed external to the Base Mine operation with a production capacity of4.7 MBCM of oilsand per year.Development of the Northwest Auxiliary Pit began in January 1990, with the first cubic metre of oilsand taken to the plant in June, 1990. The Auxiliary Pit, as designed, has a total ore reserve of 68 MBCM of oi/sand."

Jan 1, 1993

By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

By Karen M. Moffitt

Developments in mining methods and rates have led to an increase in the frequency and size of waste dump failures that have not been adequately predicted or explained in terms of conventional slope stability analysis. Monitoring data and visual observations suggest a unique mode of failure responsible for large runout events. A numerical model has been developed to capture commonly observed patterns of deformation, and investigate the formation of the ensuing failure mechanism. The analyses have yielded a good correlation with observed field behaviour and have provided significant insight into the coincident stresses and deformations within the dump. Results indicate that while creep effects in the waste dump could have a significant effect on the magnitudes of displacement, the overall dump stability is governed by the strength of the foundation soils underlying the toe region. Consideration of both the stress and velocity fields leads to factors of safety for various dump heights and foundation slopes that are considerably less than predicted from limit equilibrium analysis. The results suggest that conventional limit equilibrium analysis techniques may not be adequate when assessing the stability and design of waste dumps on steeply sloping terrain.

May 1, 2001

By Shugang Li

Coal and coal-bed methane are valuable energy resources. If they can be extracted simultaneously and safely, the triple purposes of mine safety production, new energy resource supply and environmental protection can be fulfilled. After mining, the mining induced fissure distribution feature and methane delivery behavior in overlying strata were closely related to the relieved methane degasification. Using physical simulation and numerical simulation, it was explained that the distribution feature of mining induced fissure was the Elliptic Paraboloid Zone (EPZ) in three-dimensional space. Based on the key stratum theory, the types, parameters, characteristics and dynamic evolution behavior of the mining induced fissure EPZ were analyzed. Applying environmental fluid mechanics and the mass transfer theory, the relieved methane floating-diffusion equation of the EPZ was established, and the corresponding transport process was analyzed. Using the field practice of relieved methane degasification in Tianchi Coal Mine, it explained that the mining induced fissure EPZ was the storage and delivery area of relieved methane. The degasification effect will thus be useful if the drainage system is laid in the EPZ. Such studies can provide the theoretical basis and technical support for the safe simultaneous extraction of coal and methane.

Aug 1, 2013

By D. A. Akinlade, N. L. Richards, D. C. Murray, W. F. Caley

To investigate the effect of adding Ti to a Ni-Cr-Fe powder metallurgy alloy, a thermodynamic software package was used to predict the phase transformations that occurred during thermal processing. Specifically, the effect of adding 3w/o Ti to a 6w/o Al modified ternary Ni-Cr-Fe alloy (the quaternary) was simulated and the phase transformations that might occur in the material on sintering were obtained using the thermodynamic modeling tool. These predictions were subsequently compared with experimental results obtained by X-ray diffraction and metallography. For comparison, selected compacts were prepared containing only the ternary + 3w/o Ti (no Al). Based upon compressibility curves, the optimum pressure for producing the new Ti compacts was 500 MPa vs 600 MPa for the quaternary composition with Ti. In each case, hardness of the base alloy was enhanced by the Ti addition whereas the residual porosity remained relatively constant at about 19%. Finally, although SEM/EDS failed to confirm the presence of Ti in the gamma prime intermetallic, XRD spectra showed a shift in lattice parameter on addition of Ti, suggesting that the intermetallic was of the form Ni3(Al,Ti).

Jan 1, 2010

By A. Warczokand

The cleaning of copper smelting slag requires magnetite and cuprous oxide reduction. The slag reduction with coke, injected coal powder or bunker oil is strongly endothermic and requires heat generation by fuel combustion or the use of electric energy. The reduction of fayalitic slag with calcium carbide is slightly exothermic and the formed calcium silicate modifies the slag. Thus, the additional energy is required only for covering furnace heat losses. Results of crucible scale tests showed the rate of slag reduction approximately five times higher in comparison of the slag reduction with coke under the same conditions. It seems that the effect of exothermic reaction and slag modification with CaO at the reaction interface results in very high rate of slag reduction. Industrial scale tests carried out in the Anglo-American Chagres Smelter demonstrated the possibilities of effective reduction and cleaning of the slags from a flash smelter and Peirce-Smith converters in a Teniente Slag Cleaning Furnace. The slag reduction was carried out without any reductant or stirring gas injection, simply by calcium carbide charging through a furnace mouth, and was very fast.

Jan 1, 2007

By P. Au, P. Patnaik, H. Saari, D. Y. Seo, S. Bulmer

Ti-48Al-2Cr-2Nb-xW (where x = 0, 0.5, and 1 at. %) powders were consolidated by hot isostatic pressing (HIP). The consolidated samples were solution heat treated above the a-transus followed by stepped cooling to room temperature. Selected samples were subsequently aged at 950 °C for up to 72 hours. The post-heat treatment microstructure was examined by optical and electron microscopy. It was found that increasing holding time above the a-transus generated a more homogenous microstructure. Utilizing the stepped cooling sequence, especially with a transition temperature of 1270 °C, massively transformed gamma (Ym) was diminished. Aging caused coarsening of the fully lamellar microstructure in the 0%W and 0.5%W samples while almost no coarsening occurred in the 1 % W sample. Precipitates began to form during aging in samples containing W. The precipitates at the lamellar interfaces are fine and have a needle like shape, while precipitates at the lamellar grain boundaries are coarse and circular in shape. The size and number of the precipitates depend on aging time and the level ofW content.

Jan 1, 2006

By The Staff

"SummaryDetermination of uranium in ores may be made by measurement of their radioactivity.The method most commonly used is that of measuring beta radiations with the tray-type beta counter. This will give an accurate uranium determination provided the sample does not contain thurium and that the beta and gamma activities have not been disturbed from their natural state of equilibrium. Such a loss of equilibrium will result from mining the ore or from the weathering of the surface rock.A method is described which eliminates errors due to loss of equilibrium. The beta and gamma activities are measured simultaneously in one simple operation. This method is recommended for assaying samples of products from milling operations and its use is limited only by the presence of thorium in a ratio greater than one part of thorium to twenty parts of uranium.A third method is recommended for the analysis of exploration samples and diamond drill cores, which may be assayed in the uncrushed state.Rapid determinations of a large number of samples is possible with the pressure ionization chamber, which is sensitive to gamma activity."

Jan 1, 1950

By S. Usui, Y. Shinohara, C. Tokoro, K. Horiuchi, S. Owada

Process optimization of heating and physical separation for Cobalt (Co) recycling from spent lithium ion battery (LIB) was investigated. LiCoO2 in spent LIB was transformed to LixCoO2 which was more easily decomposed than LiCoO2 by heating. Coexisting materials of aluminum and carbon, and sealed atmosphere of the LIB promoted LixCoO2 decomposition. In an atmosphere of Argon, 95 % of LixCoO2 in the spent LIB was decomposed to 76 % of Co oxide and 19 % of Co metal in 10 min at 823 K; a lower temperature than the theoretical value for LiCoO2. The Co oxide and Co metal exhibited magnetic properties and could be recovered by wet magnetic separation. Furthermore, slow heating was effective for grain growth of Co oxide and Co metal. At 2 K/min rate of heating, average grain size of Co oxide and Co metal were 239 µm and 28 µm respectively, whereas at 30 K/min they were 190 µm and 15 µm respectively. Therefore, separation efficiency for Co recovery by wet magnetic separation was increased when spent LIB was slowly heated at 2 K/min.

Jan 1, 2015

By Si Qin

Unknown goafs and roadways of abandoned coalmines can be a great water inrush hazard for coalmine workers. Consequently, advance detection of such hazards is of great importance. By detonating seismic charges in underground coal seams, we can collect seismic data using a surface survey line, which is located across the ground projection of the underground shot point. This experiment was conducted in a coalmine in Shaanxi Province, China. After surface elevation compensation and travel time adjustments, we accurately determined the position of the goaf boundary along the survey line based on the wave velocity anomaly on the seismic record. Then we used a scattered wave imaging technique to enhance the energy of the scattered waves that are generated when the coal seam roof slide wave (refracted wave when the incident angle bigger than the critical angle) hits the roadway, thus confirming location of a geological discontinuity (roadway). This experiment shows that the coalmine ground seismic method, employing an underground explosive charge and a surface seismic array, has the ability to detect an abandoned roadway and goaf in advance of coal mining, thus can improve worker safety.

Aug 1, 2013

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale (MD/FE) method has been used to study dislocation generation and plastic deformation during a nanoindentation process which is physically associated with the generation of heat within the specimen and as a consequence with a temperature rise. Two different techniques are applied to study the temperature effect on the nanoindention process. In the first technique, a global Nose-Hoover thermostat is applied to the entire atomistic region to keep temperature constant during simulation (finite temperature approach). In the second method, the thermostat is applied only on a damping region along the MD/FE interface. Both techniques are able to effectively and efficiently absorb high frequency reflected waves from atomistic/continuum interface. The temperature profile of the atomistic region beneath the indenter is reported and discussed at four different initial substrate temperatures for both techniques. The loaddisplacement (load/unload) curves for different temperature-controlling techniques are compared and discussed. The nucleation and propagation of dislocations in the atomistic region are investigated for both techniques. Correlations between the observed features in the load-displacement curves with the motion and pile-up of dislocations are reported as a function of temperature.

Jan 1, 2006

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By P. Patnaik, F. Cuneo, D. M. Wang

Microwave (MW) energy has been used widely for several decades for communications, food processing, wood drying, vulcanization of rubber and medical therapy. Recently, this technology was found to be capable of successfully sintering ceramic and metallic powder materials, with the advantages of reducing soaking times and sintering temperatures. Unlike conventional heating, MW radiation works through the absorption of the microwave energy by a material placed in an electromagnetic field within the microwave cavity. A far more efficient heating process is produced due to the unique ability of microwaves in selectively heating a pecific part of the material with desirable dielectrical properties. This exploratory research was initiated with the objective of locally sintering the thermal barrier coating of gas turbine components using MW radiation. This novel technique may allow repairing of the component without subjecting the entire piece to unnecessary elevated temperatures and reduction of process time and cost. Y ttria stabilized zirconia was used in this study and sintering was conducted using a multimodal 1.2 kW microwave facility. Three configurations of heating setup were experimented and the preliminary results will be discussed in this paper.

Jan 1, 2006

By T. Shariff

Titanium alloys have found increasingly wide range of applications in aerospace, chemical, medical, sporting, power generation, oil and gas extraction industries mainly due to the low density, high mechanical property characteristics, biocompatibility, and excellent corrosion resistance. In the manufacturing routes of their finished products, welding has been a key technique used and always been a main concern requiring the stringent compliance to the well defined process. Conventionally, gas tungstenarc (TIG), gas metal-arc (MG), plasma arc, and electron beam welding processes have been used to weld titanium alloys. Nowadays, laser beam welding has provided great challenging applications for titanium alloys due to the low and precise heat input, deep and narrow fusion zone, small heataffected zone, low thermal distortion and high productivity. At the NRC Institute for Aerospace Research, some R&D work has been undertaken for titanium alloys using laser beam welding process. These investigations have mainly concentrated on optimizing the welding process as well as understanding the fundamental process-structure-property relationships. In this invited keynote presentation, the research progresses obtained and the main issues encountered in laser welding of titanium alloys will be briefly summarized.

Jan 1, 2011

By T. Yalcin

"This paper describes a process that can provide high rates of dewatering and that has the potential of bringing significant savings in tailing disposal costs. It involves a three-stage, closed-circuit operation employing a hydrocyclone, a settling cone and a thickener. The mill tailing, with adjusted pulp density, is first fed to the hydrocyclone. The underflow from the hydrocyclone goes to the settling cone for further dewatering. The overflows from the hydrocyclone and the settling cone are sent to a thickener which, with the addition of a flocculant, gives a clear liquid effluent and a dilute underflow which is recycled back to the hydrocyclone. The underflow of the settling cone is a material with as high as 78% pulp density and is suitable for direct disposal or for use as mine backfill.INTRODUCTIONDewatering is an essential process for the disposal of mill tailings and forms an additional cost item in milling operations. Cost-cutting measures are therefore desirable in this area as in any other stage of milling. One way of achieving this is through increased rate of dewatering which would require smaller dewatering units with correspondingly lower capital and operating costs."

Jan 1, 1987

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007

By S. F. Dudka, T. Dang, M. L. Wong

Abstract - The Nui Phao W-F-Cu-Au-Bi deposit is located in one of the poorest regions of northern Vietnam. The deposit is currently undergoing a pre-feasibility study by Tiberon Minerals Ltd., with a view to developing what would be the largest WO3 mine and one of the five largest fluorite mines in the world. The project is being planned in close compliance with World Bank and national guidelines for environmental and social protection. Development of the mine is anticipated to bring the following benefits: remediation of serious pre-existing environmental conditions (natural and anthropogenic heavy metal contamination and acid rock drainage); provision of employment and training, and thereby wealth, to local communities; significant tax and royalty payments to government, which will be reinvested as social spending; and development of municipal and industrial infrastructure to build sustainable post-mining communities. The role of governments at all levels is critical in guiding and facilitating this process. This paper was written prior to development of the mine, and relays the intentions of the developers. Future studies will be needed to evaluate the degree of attainment of sustainable development objectives, both during mine operation and after closure.

Jan 1, 2003

By T. Macpherson

ABSTRACT: Drawing on past research experience with sprayable polymer mine support agents (TSLs), Spray On Plastics Ltd. has developed a TSL ground support system called RockWeb. Using a relatively new polyurea polymer technology, RockWeb has been engineered to solve problems encountered underground with polyurethane liners by incorporating rapid curing, moisture insensitivity and superior physical performance. RockWeb possesses a unique, patented ability to be sprayed in a ?cobweb? like consistency allowing the applicator to span fissures in the rock, ensuring no initial defects in the liner, and maintaining design thickness over highly irregular surfaces. This ability, coupled with the high strength and elasticity of polyurea, allows RockWeb to mitigate rock movement through yielding, while maintaining intimate surface confinement. RockWeb provides reduction in logistics through the transport of 1/25 of the material quantities required for shotcrete, rapid deployment rates of as little as 30 minutes per round, and immediate return to the work area. This paper will discuss the technology and advantages of RockWeb as well as opportunities for overall mining cycle cost reduction. The safety benefits, as well as health and environmental considerations regarding application of isocyanate-based liners will also be discussed.

May 1, 2009