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By Gae On Kim, Ki Baik Kim, Suk Hoon Kang, Tae Kyu Kim, Sanghoon Noh

"Advanced radiation resistant oxide dispersion strengthened steel (ARROS) is being developed as a fuel cladding tube material for future nuclear reactor system applications. The research activities consist of advanced radiation resistant ODS steel development and fabrication technology development of ODS steel structural components. One candidate material with a chemical composition of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3and was selected as representative materials, and this material was named as the advanced radiation resistant ODS steel (ARROSTM).On the basis of this ODS steel composition, an optimized fabrication process of structural components such as plates, sheets and tubes has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. These R&D activities are expected to contribute to the realization of ODS materials in the future.INTRODUCTIONA sodium-cooled fast reactor (SFR) is being developed at the Korea Atomic Energy Research Institute (KAERI) with a view to economics, safety, reliability, and sustainability. The prototype Gen-IV SFR with a capacity of 150 MWe is under design, and this prototype reactor is scheduled to operate from 2028. For a commercial SFR system application, it is necessary to develop an advanced structural material having both high creep strength and irradiation resistance at high temperatures (Jeong, 2014). Oxide dispersion strengthened (ODS)steel is one of the most promising structural materials because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperatures under a neutron irradiation environment for a prolonged operating period(Kim, 2016). As the first step, several batches of ODS steel were designed and the candidate samples with a 2 kg scale each were fabricated by mechanical alloying, hot isostatic pressing and hot rolling processes. The mechanical properties of these samples were evaluated. Up to now, two candidate materials with chemical compositions of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3 was selected as representative materials, and these materials were named as the advanced radiation resistant ODS steel (ARROSTM).The next step was to optimize the fabrication process of the ARROS compositions for in-core structural components such as the fuel cladding tubes of a SFR. An optimized fabrication process of fuel cladding tube with a composition of ARROS has been established through various process conditions in mechanical alloying, hot consolidation, hot/cold working and heat treatment processes. Joining technologies of the ODS steel tubes is being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. It is expected that the development of ARROS will contribute to the realization of a commercial SFR with high economics and sufficient safety in the future. In this paper, the study of fabrication process of ARROS structural components is introduced."

Jan 1, 2017

By P. J. Deveaux, M. J. Kreczmer

The Tartan Lake deposit 12 km northeast of Flin Flon, Manitoba, was discovered in March of 1984 during the investigation of a VLF anomaly. The discovery hole intersected 16.83 metres averaging 21 gm Au/tonne. Since then, 99 holes, over 21,000 metres, have been drilled outlining 419,491 tonnes grading 11.79 gm Au/tonne in a di stinct group of mineralized lenses referred to as the Main Zone. Three other mineralized zones are known on the property but no reserves have been allowed for these, the South , East and Base Line zones. The Main Zone consists of seven parallel, east-west striking, quartz lenses. The lenses dip steeply to the north and plunge steeply west to northwest. Lens number l strikes for 160m and extends vertically to the 90m level. Within th is lens there is a 60m interval of low grade materi al. Lens number 2 is located about 5-l0m within the foo twall of Lens number I. Near surface this lens stri kes for 40m, at 200m level the strike length increases to 200 m. To date the deepest mineralization on Lens 2 has been intersected at a vert ical depth of 527m. Five smaller lenses are located in the foo twall of Lens 2 , containing gold va lues similar to the two main lenses but erratically distributed. The South Zone, located 100m south of the Main Zone, strikes east-west fo r l00m above the 100m level. The East Zone, found 230m east of the Main Zone, strikes fo r 80m and may possibly be an ex tension of the South Zone. The Base Line Zone is located 275m south of the Main Zone. Sporadic, but very significant gold intersections have been obta ined1n all three zones. Gold-bearing quartz-ca rbonate tourmaline veins are generally confined to a silicous crystal tu ff hori zon. The crystal tuff exhi bits fi ve distinct types of alteration: silicification, sericitization, ca rbonati zation, chlorit ization and pyritization. Silicification has resulted in a perasive addition of silica and the generation of multiple quartz veins. Sericiti zation is restricted to the crystal tuff. All rock units are pervasively carbonatized . Ankerite is abundant in the quartz veins and within the shear zones, particul arly those located along the chilled margin of a nearby gabbro-diorite intrusion. Chloritization is widely spread th roughout the rock units, while pyritization fo rms a broad alteration halo associated with the orebody. Sulphide accesso ry minerals associated with the gold , whi ch fo r the most part appears to be free, are chalcopyrite and pyrite. Generally, the higher grade gold values are related to an increased content of sulphides in the qua rtz veins. The average sulphide content in the deposit is less than 5 %.

Jan 1, 1986

By J. G. Kelly

"IntroductionOver the past twenty-five years of improvements to scooptrams In the Ontario Division of Inco Ltd., records indicate that on average, an 8 yard capacity machine at 80% availability will load, haul and dump about 100TPH from an average stoping area. This, essentially, means that Inco mines are limited to 2000 TPD as an approximate maximum production cap per minute. Some of the improvements made to scooptrams over this period have been:• dry disc and oil immersed brakes on larger loaders;• to replace air over hydraulic systems;• modulated shift transmissions;• greater breakout and tramming capacities by using larger engines and buckets;• operators' compartments have been enlarged and better seats,• joystick controls and air-conditioned cabs have been utilized'• major cost savings have been realized through tire maintenance improvements; and• major savings, safety improvements and increased ore recovery by using remote controls.After reciting the improvements listed above, and the list is by no means exhaustive, it is quite obvious that scooptrams are a mature product and that major design or performance improvements will not occur in the futre. Any futher improvements will be incremental in nature. Loading, hauling, and dumping with scooptrams is a batch process and as such is limited in its total output.Continuous Load/Crush/Convey Systems:In order to improve productivity, a radical new system was required. The target was 2000 tons per shift. In 1984, to meet the goal, Inco acquired the rights to a contiunous loader from Canadian Mine Services. Inco made modifications to the original prototype machine, such as: (I) conversion from rail mounted to crawlers for increased mobility; (2) a hydraulic cooling system was added; (3) flight bars were changed from cast to forged; (4) motor horsepower increased to 200 hp from 150 hp. Emerging from these modifications came a machine known as the CL-looo Oscilloader (Fig. 1).The CL-looo Oscilloader is an electric hydraulic 35-ton machine which is crawler mounted and has a drawbar pull of 30 tons. It has an adjustable frequency, oscillating lip which simulates the digging action of a manual .shovel. This action agitates and lifts the muckpile enough to allow it to settle by gravity onto the chain and flight conveyor table which then removes the ore to the tail end for discharge into either a crusher, a conveyor, a truck, or a combination of these.Late in 1985, six oscilloaders were fabricated and put into Inco mines for field trials. At Creighton Mine some early field trials were conducted with a rail mounted continuous loader loading directly into 140 cu.ft. Granby cars. Much of the field testing was in VRM drawpoints with the Oscilloader loading into 20-ton trucks or into Teletrams . At Levack Mine, by puttmg the truck on remote control, it was possible to have the operator run the Oscilloader and load his own truck (Fig. 2). At McCreedy West Mine, Copper Cliff North Mine, and Copper Cliff South Mine, the Oscilloaders discharged directly into 26-ton trucks."

Jan 1, 1988

By F. Musuka, D. Jenkins, A. Keyes

BHP Olympic Dam operates a Direct-to-Blister copper flash smelting Furnace (DBF) and an Electric Slag Cleaning Furnace (ESCF). Tapping blister copper from these furnaces via tapholes is a routine task carried out by trained personnel. Blister tapping is a high-risk activity with personnel operating in close proximity to molten metal. BHP’s risk management framework has identified taphole integrity as key to managing the potential for loss of molten metal containment and molten metal – water steam explosion, both of which have the potential to cause multiple fatalities. As part of the focus on managing this risk, since 2017, a dedicated Taphole Development Team has been embedded in the operation to run an accelerated improvement program focused on safely and sustainably embedding an improved taphole design with greater integrity. The program of works includes selecting and testing of new materials as well as improving operating discipline by collaborating with tapping personnel to convert their knowledge into codified condition monitoring and operating strategies. Computational fluid dynamics (CFD) is being used to derive critical risk controls, and to develop live-alerts to infer excessive refractory insert wear. To date, improving DBF blister taphole mudgun clay has led to more consistent drilling depths and subsequently reduced oxygen lancing requirements, resulting in improvements in taphole insert service life. On the ESCF, insert performance testing and development of a new taphole condition monitoring strategy, is being used to increase taphole insert tonnages to more sustainable levels. Operations personnel have been closely involved in different phases of the change management, this has led to standardization of tapping practices for both furnaces, and improved ownership of the proposed changes. The paper discusses the maturity in taphole integrity risk management as a result of recent and ongoing developments. It then provides an overview of future taphole developments proposed at Olympic Dam. INTRODUCTION Tapping operations at Olympic Dam and learning from significant events The Direct-to-Blister furnace (DBF) at Olympic Dam was built with a conventional design blister taphole, which was designed for manual oxygen lancing and clay stopper bar plugging tapping operations (Campbell, 2005). Manual tapping is a high-risk activity, where personnel work in close proximity to molten metal, and molten metal personal protective clothing and equipment must be used. Opening tapholes by oxygen lancing is a skilled activity and unintentional damage to the taphole inserts can occur. Since 2008, a Mudgun and Drill unit has been developed and trialled and is now in use on the DBF blister tapholes, to remove personnel from the line of fire when opening and closing tapholes. This has the additional benefit of reducing lancing damage to taphole inserts. A new taphole design labelled the Modular Blister Taphole (MBTH) was developed at Olympic Dam for the Mudgun and Drill operation. The intent of the design was for mudgun clay to fill the entire tapping channel when plugging after a tap. The drill would then drill through this clay plug to open the taphole.

Jan 1, 2019

The Cadia mine is shifting from the open pit operation to the Cadia East underground block cave. The resulting increase in milled tonnes and the decrease in fines production through shifting to block caving require an increase of over 25% in installed power. This expansion is being accomplished via the installation of up-front crushing and HPGR milling of the ore, with the SAG mill receiving a secondary crushed feed. This design, criteria and rationale for selection is presented. Over the coming years, the mine will further expand capacity. The target is to accomplish this with minimal addition of installed power or use of fresh water. This presents a challenge that epitomizes the future constraints on our resource dependent and intensive industry. The approach and proposed options to this longer-term expansion are also presented.

Jan 1, 2012

By A. Zarei-Hanzaki, O. Golmahalleh, S. M. H. Hosseini, H. Azizi-Alizamini

The main importance of acicular ferrite microstructures arises from their desired combination of mechanical properties in comparison with the bainite and ferrite-pearlite microstructures. Several factors affect the microstructural transition from bainite microstructure into the acicular ferrite one. As is well established any factor corrupting the prior austenitc grain boundaries nucleation potential, such as the thin layer of allotriomorph ferrite and the austenitc deformation inhomogenities may promote the acicular ferrite formation instead of bainite. Accordingly, this study deals with the effects of the aforementioned features on the acicular ferrite formation in low carbon microalloyed steel. The results indicate that the formation of strain-induced ferrite at the prior austenite grain boundaries accompanied by deformation inhomogenities in the austenite grains change the effectiveness of allotriomorph ferrite on acicular ferrite formation from active to inert one.

Jan 1, 2004

By M. Boher, J. Lehmann, M. C. Kaerlé

"In the production of high quality steel, the understanding of the interactions between liquid steel and refractories and of their effect on steel purity and cleanness are becoming more and more important.An experimental study has been per-formed in order to estimate the importance of the reaction between a MgO-based tundish refractory and an Al-killed steel. The results show a pollution of the liquid steel:•the silicon content of the liquid steel increases due to the reduction of the silica of the refractory by the aluminum contained in the steel; and•a reoxidation of the steel occurs and the formation of an oxide layer on the refracto-ry, mainly composed of spinel crystals and of Ca-aluminates is observed.The transfer mechanisms of the various elements are analyzed."

Jan 1, 1997

By J. Lee

A monolithic caisson is one of the major structural components commonly used in the construction of docks, breakwaters, and container terminal quay walls. Since the structure of monolithic caissons is typical and somewhat simple, its design process is also typical and repetitive, but still time consuming. To reduce the total time and enhance productivity, we developed a parametric model in Revit to automatically generate a 3D model of a monolithic caisson. It is designed to generate the Revit model of a caisson with concrete body and reinforcing bars. The size of caisson, the number of reinforcing bars, and the space between reinforcing bars are automatically changed when users update parameters. This paper presents how we developed this parametric family in Revit for monolithic caisson design and how it would enhance its design process.

Aug 1, 2013

By I. C. Edwards, D. C. Smith

THE milling plant of Bicroft Uranium Mines Limited at Ban-croft, Ontario, was one of the first in Canada to employ ion excl1ange for the selecti1•e recovery of uranium from acid leach liquors. The ion ex-change circuit started operating early in November, 1956, and by June 1 I959, had handled more than two million tons of pregnant solution containing I,830,000 pounds of U3Os. Each column had been saturated and eluted about 430 times. The ion exchange columns are the conventional fixed bed type. Uranium is eluted from the resin with a sodium chloride-sulphuric acid solution and is precipitated continuous-ly with magnesia. After filtering and drying, the precipitate, or "yellow cake," is packaged in drums for shipment to the refinery.

Jan 1, 1962

By A. A. Shirzadi, E. R. Wallach

"Liquid gallium has been used successfully to modify/remove the surface oxides prior to diffusion bonding similar and dissimilar nickel-base superalloys. Using this approach, bonds in nickel-base superalloys with ""virtually invisible interfaces"" were produced, and the compositions in the bond region were very close to those of the bulk alloys. Room temperature tensile and bend tests showed no preferentially failure at the bond lines. Creep tests on samples made between two different Inconel alloys also showed failure away from the joint, i.e. in the parent metal of the Inconel alloy with lower creep resistance. The high temperature lifetimes of these samples were as long as those of the unbounded Inconel, confirming that the joining approach has no adverse effect on the nickel-base superalloys being joined."

Jan 1, 2006

By G. R. MANSON

The Brisco Barite Mine lies 70 km south-southeast of Golden, British Columbia. Barile mineralization occurs in a northstriking brecciation zone within Ordovician-Silurian Beaver/ oot dolomites and quartzites. Brecciation was caused by faulting related to the Mount Forster-Steamboat Fault. The main barite vein occupies a fault zone and is up to 12 m wide and over 250 m long. It is light grey to white, fine grained and compact; BaSO4 content is 9/. 70 per cent. Production started in 1945 and has continued to the present. Barile originally was removed from an open pit; later, an adit, begun in 1957, reached more than 240 m along the vein, 15 m below the pit floor. Today ore is hoisted from a decline resting some 37 m below the pit floor.

Jan 1, 1984

By S. D. Logan

This presentation describes a lightweight automobile body structure concept developed at DaimlerChrysler to support a high fuel-efficiency vehicle project. This body structure consisted primarily of large thin-wall magnesium castings and resulted in a more than 40% weight reduction with a minimal cost increase over a conventional steel structure while achieving significantly improved structural performance as evaluated through CAE simulations. One concept vehicle was built for the purpose of demonstrating concept feasibility. Several slides showing the prototype build process are presented. The presentation also describes several large thin-wall die casting body applications that are in current production or have been used in recent production automotive applications and identifies areas where further development could improve the chances of a magnesium intensive body structure becoming a production reality at a later time.

Jan 1, 2006

By K. Waters, A. Navarra, T. Grammatikopoulos

Strategic decisions to develop a mineral deposit are subject to geological uncertainty, due to the sparsity of drill core samples. The selection of metallurgical equipment is especially critical, since it restricts the processing options that are available to different ore blocks, even as the nature of the deposit is still highly uncertain. Current approaches for long-term mine planning are successful at addressing geological uncertainty, but do not adequately represent alternate modes of operation for the mineral processing plant, nor do they provide sufficient guidance for developing processing options. Nonetheless, recent developments in stochastic optimization and computer data structures have resulted in a framework that can integrate operational modes into strategic mine planning algorithms. A logical next step is to incorporate geometallurgical models that relate mineralogical features to plant performance, as described in this paper.

Jan 1, 2017

By J. L. Barton, R. A. Murray

"This paper looks at how Syncrude Canada Ltd. is utilizing the Conveyor Belt Monitoring technology developed and patented by the Australian CSIRO and licensed to Syncrude by Conveyor Belt Monitoring of North America, Inc. The technology involves magnetizing the steel cables in the conveyor belts and detecting the fields produced by breaks, gaps or cable ends using special sensors which feed the signals into a multi- channel recorder to provide permanent traces of the various events taking place in the steel cable belts.The data is analyzed and combined with existing belt audit programs, to assist in predicting belt life, change-out criteria and belt design, belt loading and construction. All of these applications of the CBM technology leads to better utilization of resources and forms an integral part of the conveying system reliability program."

Jan 1, 1992

By R. Ham-Su, J. P. Healey, S. P. Farrell, R. S. Underhill, M. A. Gharghouri, C. V. Hyatt, L. M. Cheng

Magnetic shape memory alloys (MSMA's) are a class of materials where magnetic energy can be converted into mechanical energy and vice versa. NiMnGa-based MSMA's have attained magnetic field induced strains up to approximately 10% and have a relatively wide operating temperature range, from well below 0°C to above RT, making them very attractive for a variety of applications. However, these materials also suffer from low toughness. Using these materials in a composite could mitigate this shortcoming, and also overcome limits imposed by inertia and eddy current losses. In this work, we describe the manufacture and characterization of such composites. Composites with 30% by volume MSMA were fabricated under a magnetic field resulting in anisotropic magnetic properties. Damping properties were evaluated by dynamic mechanical analysis.

Jan 1, 2004

By T. Velea

The most widespread methods for producing metallic copper are smelting of copper sulphide concentrates (which generates various types of polluting substances) and the hydrometallurgical route which consists of leaching in sulphate and chloride media (usually employing high temperature, high-pressure and special equipments). This paper presents a process, called VEPE, which consists of oxidizing copper sulphide concentrates in weak alkaline media (Na2C03 orland NaOH solutions), under low pressure and with air sparging. The oxidized concentrate contains less than 0.4% S. Copper is recovered from the oxidized concentrate by the standard leaching-solvent extraction-electrowinning route, with a total efficiency of 98% extraction. The proposed technology could represent a good opportunity to recover copper from sulphide concentrates in a clean, simple and profitable way.

Jan 1, 2007

By S. Orzecki

The KGHM Copper Refinery Plant, Glogów 1, has operated for 35 years and -increased its capacity almost ten times.Cathode quality, expressed in terms of the total impurity content, has undergone a five-fold improvement. The present refining capacity is equivalent to 240,000 metric tonnes of copper cathode, with a total impurity content of 20 ppm, inclusive of 10 ppm Ag. These accomplishments result from combined implementation of current technological progress in electrolytic refining and KGHM's own solutions applied to the Glogów Refinery. The quality improvement measures feature both lowering actual current density, despite an increase in nominal current density, and diminishing the role of non-ion mechanisms which transfer impurities to cathodes. The paper contains a detailed discussion of these issues and outlines possible measures aimed at further production and quality improvements.

Jan 1, 2007

By G. B. Harris

A process for the recovery of copper from the waste oxide copper of a mined-out sulphide orebody is described. Hydrometallurgical recovery of copper from this and similar wastes has been tried several times previously without success. Leaching is carried out by sulphuric acid in columns under conditions that minimise the iron content of the pregnant leach liquor, and copper is then recovered by ion exchange rather than the more conventional solvent extraction. The resin is stripped by spent electrolyte and copper is electrowon. Results are presented for testwork originally carried out in 1993, and repeated in 2006, and the novel aspects of the process, leaching and ion exchange, are discussed. Finally, preliminary order of magnitude capital and operating costs are given, demonstrating that the process is cost effective.

Jan 1, 2007

By Marta Polgari, Eva Surova, Bohumil Molak

Abstract -The Ûrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organic­ geochemical methods. Both depositionallocalities were affected by the Lower Jurassic Toarcian anoxic event. Ûrkút shales are rich in organic matter (av. 2.94 wt% total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (?0.2 wt% TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decom­ position of organic matter that also involved Mn reduction.

Jan 1, 1992

By Andreea Catalina Gluhoi

Oxidation and reduction reactions of N-containing molecules have been studied over different types of gold-based catalysts, Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 (M, MI, MII=Li, Rb, Mg, Ce, Zr, Mn, Cu) prepared by deposition precipitation with urea. In general, all the catalysts were already active at low temperatures. NH3 oxidation was effectively catalyzed by Au/CuO/Al2O3, a catalyst which also gives the highest yield in N2. NO reduction by H2 performed over gold-based catalysts produced N2O, N2 and NH3 and N2O reduction resulted in the formation of dinitrogen. For all the reactions, large synergistic effects have been obtained by addition of different kind of additives.

Oct 1, 2003