Search Documents

By J. Baumbach, H. Bombach, M. Stelter

"Today technical electro-refining processes for copper exclusively use sulfuric acid, for silver refining nitric acid electrolytes are used. Sulfuric acid is characterized by very good chemical and electrochemical stability, good conductivity and low cost. The disadvantages of sulfuric acid are the precipitation of fine-grained cathodes with smooth surfaces only by using additives like glue, thiourea and chloride. In case of silver the electrolyte is electrochemical unstable and bears the risk of the formation of toxic NOx when pH is too low. A second disadvantage is the form of electrodeposition of silver as dendrites with their removal from the bottom of the Möbius cells.This paper reports the results concerning the application of an alternative electrolyte in copper and silver electro-refining. At first the electrolyte was characterized by the determination of current density potential curves. Electrolysis experiments were performed in laboratory scale using technical anodes for copper and synthetic anodes for silver. During the copper tests the solubility of contaminations from the anodes and the amount and chemical composition of the anode slimes were determined. Moreover the influence of current density, electrolyte temperature and the effect of several additives on the precipitation and chemical purity of the cathodes were investigated. In all experiments cell voltage as well as anodic and cathodic polarization was measured and current efficiency and specific energy consumption were calculated. A comparison with the results with those of tests using conventional sulfuric acid electrolyte shows the advantages and disadvantages of both systems, additionally the technical application chances and limitations for the new electrolyte. This electrolyte enables the precipitation of smooth copper cathodes with low silver and sulfur concentrations even at lower temperatures without any additive. For silver refining the electrodeposition of compact silver sheets is possible, that can be stripped comparable to those in copper electro-refining."

Jan 1, 2016

By M. Imani, A. Fahimifar, A. H. Javid

"Current studies of bearing capacity for shallow foundations tend to rely on the hypothesis of an isolated footing. In practice a footing is never isolated; it is mostly in interaction with other footings. This paper focuses on a numerical study to evaluate the ultimate bearing capacity for two interfering strip footings resting on a rock mass in which the strength can be described by the generalised Hoek–Brown failure criterion. This criterion is applicable to intact rock or heavily jointed rock masses that can be considered homogeneous and isotropic.The material is assumed to exhibit perfect plasticity and obeys an associated flow rule. The effects of Hoek–Brown parameters including GSI, mi, and sci were studied and the corresponding results are presented. For different clear spacing (S) between the footings, values of the efficiency factor (?) were determined; where ? is defined as the ratio of the failure load for an interfering new footing of a given width (B) to that of a single isolated footing having the same width. The maximum value of (?) occurs at spaced between S/B = 0.5 to 1.0. The results have been compared with those available in the literature.INTRODUCTIONEvaluating the ultimate bearing capacity of rock masses is essential for important projects like dams and bridges. Closely spaced footings may occur on rock masses in the form of pier foundation and grillage footing. Close spacing lead to permit higher loads than can be bore by similar isolated footings. The ultimate bearing capacity of two interfering strip footings resting on cohesionless soil have been studied theoretically (Kumar, & Gosh, 2007; Kumar, & Kouzer, 2008; Stuart, 1962). Results revealed when two strip footings approached closely enough, failure zones affect each other and ultimate bearing capacity significantly increased."

Jan 1, 2015

"Decreasing gold-in-ore grades is one of the main drivers of poorer productivity and rapidly escalating unit costs. Grinding costs, water use and reagent consumption are all intimately related to the ore grade processed. Various pre-concentration technologies have been developed that can be applied at various stages of crushing prior to ore grinding. This paper will review the amenability of ores to coarse particle barren gangue rejection for fine crush sizes in the pumpable particle size range (i.e., particles between 5 mm and 0.3 mm in size). The liberation of oxide gangue achieved during crushing is evaluated by proxy using sink-float analysis and the deportments of gold, sulfur, and arsenic into sinks and floats are monitored. Amenability of gangue rejection by continuous gravity separation is evaluated after various crushing modes (vertical shaft impact crushing, cone crushing, and HPGR crushing). The potential to identify coarse particle mineral association and liberation using three-dimensional x-ray computed tomography will be discussed.INTRODUCTIONThe aim of research in this area is to explore some of the attributes which make some ores amenable to preconcentration, or rejection of a significant component of the feed mass to tailings at a coarse liberation size. Characteristics such as ore type, mineralogy, breakage pattern, particle shape, and liberation characteristics may need to be examined to identify amenability to pre-concentration amenability.It is intended to focus on continuous gangue rejection in the pumpable size range (0.3–5.0 mm) as this remains one of the key opportunities to reduce processing costs through a combination of techniques including screening (for mineral differentiation rather than size classification only) and gravity separation (using jigs). This is to be contrasted to conventional preconcentration as performed with automatic ore sorters."

Jan 1, 2016

By A. Trusiak

"Increasing energy costs in mineral processing is making it necessary for tighter controls over various parts of the concentrating process. Continuous monitoring and control of critical process streams can be easily performed by today's many computer systems. Indeed, the list of successful applications of computers to grinding and flotation control continues to grow. The day is rapidly approaching when the use of computers within concentrators for either process control or simply metallurgical accounting will no longer be a luxury, but a necessity. The benefits from such applications far out weight the initial investment.This paper describes the current application of a process control system at Brunswick Mining in north-eastern New Brunswick. Emphasis is placed on the control of a CuPb flotation circuit, and the benefits derived-from this control.No. 12 Cu-Pb Flotation: The complex nature of the Brunswick flotation process has been described else-where. 1,2,3 Four final concentrates are eventually produced, these being a Zn concentrate assaying 53% Zn, a 30% Pb concentrate, a 20% Cu concentrate, and a bulk Pb Zn concentrate assaying 35% Zn and 17% Pb. The Cu concentate, Pb concentrate, and bulk Pb Zn concentrate are all derived from a primary CuPb concentrate assaying 26% Pb, 11% Zn and 1.8% Cu.The No. 12 CuPb circuit produces approximately two thirds of the total primary CuPb concentrate. No. 12 ore, assaying 3.5% Pb, 9% Zn, 0.25% Cu and 100 g/tne silver, is ground in two parallel grinding circuits. Each line uses a 3.2 x 4.2 meter rod mill in closed circuit with two parallel 3.2 x 3.9 meter ball mills. Ball mill and rod mill discharges are classified in two stages of cycloning. The secondary cyclone overflow, or flotation feed, is controlled at 65% passing 37 microns."

Jan 1, 1981

By L. V. Kin, V. V. Lodeischikov, A. V. Byvaltsev, IRGIREDMET JSC, O. D. Khmelnitskaya, S. V. Petrov

"Irgiredmet Institute carried out the study on the development of gold recovery technology from refractory ore from a Russian deposit. The ore contained 1.1 g/t Au, 1.5% of pyrite and 2.4% of pyrrhotite. The recovery of gold achieved was 84.7% using gravity with generation of high grade recoverable gold concentrate and gravity middling. In the course of lime treatment, cyanidation of the middling followed by tailings detoxification the consumption of reagents was 13.0 kg/t CaO, 95 kg/t NaCN and 72 kg/t Ca(OCl)2 of the concentrate. This was capital intensive.In order to decrease the consumption of reagents, magnetic separation of the middling of the concentrates from gravity separation was added to this flow sheet. Pyrrotite recovered to magnetic fraction, which did not contain gold in accordance to this advanced flow sheet. The mass yield of pyrite goldbearing non-magnetic fraction decreased down to 1.5 times in relative to gravity middling. The slurry filtration prior to and after cyanidation allowed the organization of cyanide solution recycling.The results of pilot plant tests using the developed flow sheet showed that the content of pyrrhotite in the non-magnetic fraction decreased from 59.1% to 11.3%. The reagents consumption was 12 kg/t CaO, 3 kg/t NaCN and 16 kg/t Ca(OCl)2 of the pyrite concentrate. The total gold recovery using this flow sheet was 83.4%. Due to a decreased consumption of reagents, cost efficiency of the process was achieved. Based on the results of this research, a project design criteria was developed. A processing plant with the annual throughput of 2.6 million tonnes of ore is being designed."

Jan 1, 2016

By Chuanhui Cao, Shimei Liu, Xiaojing Li, Yueyuan Zhou

"Force analysis on weakly-magnetic particles and non-magnetic particles in magnetic field are presented, using a kind of permanent magnetic drum magnetic separator, which is designed with strong specific magnetic force and open magnetic system. Its surface peak intensity reaches to 1.0T, and the distribution density of capture line is 1.25×103/dm2. Qualitative analysis on the particles including its magnetic property, particle size, motion speed, magnetic field intensity, etc. is also presented to calculate the separating parameters for the drum separator. Experiment was conducted for the separation of fine weakly magnetic minerals for example ilmenite. The practicability to separate the minerals using separator designed with open magnetic system has been proved, providing an economic way for efficient separation of micro-fine weakly magnetic minerals and upgrading of non-metallic minerals. INTRODUCTIONMagnetic separation is a mineral processing method based on the differences of magnetic properties between minerals in inhomogeneous magnetic field (Sun, 2007). Currently for separation of micro-disseminated weakly magnetic iron ore, electromagnetic high intensity magnetic separators with closed structure of magnet system are often used. And for the separation of strongly magnetic minerals such as magnetite, low intensity drum magnetic separators with open magnet system are often used. In order to lower the operation costs and improve energy efficiency, it is important to develop efficient high intensity permanent magnetic separator with open magnet system, to some extent replacing high intensity electromagnetic separator.Oberteuffer (1974) discussed the magnetic force and competing forces in magnetic separators which compete with the magnetic forces and act on all of the particles which travel through the separator are those of gravity, hydrodynamic drag, fraction, and inertia in magnetic separation."

Jan 1, 2016

By C. Cano

One of the main concerns within the mining industry is to minimize the impact of tailing facilities to the environment and nearby communities. Since the implementation of the first thickened tailings disposal (TTD) methodology at Kidd Creek in 1964, the thickened tailing disposal has been growing alternative disposal technology to mitigate the environmental impacts. Technical investigations on the TTD technology have been studied in detail to counteract the increasing shortage of water resources. One of the benefits observed with TTD is its resistance to potential earthquakes, particularly in zones with high seismic activity (Los Andes). TTD technology optimizes the maximum possible density for the material and generates a negative internal pore pressure in the material due to the surface and sub-surface water evaporation. This internal pore pressure should be enough to resist the pores pressure to which tailings are subject due to an earthquake action. The objective of this study is to verify the Shrinking Limit (SL) of thickened tailings during initial deposition and in the long term and the ability of tailings deposited by TTD would resist liquefaction. Fresh tailings coming from a flotation process of a copper plant concentrator were used. The samples put under cyclical three-dimensional tests associated with maximum credible earthquake magnitude range of 7.0 8.0 to develop a curve for the safety factor v/s depth for dry densities related to the maximum density obtained at the SL. At a dry density of 1.65 t/m3 liquefaction did not occur at any depth. At 90 % of dry density of 1.51 t/m3, liquefaction did not occur at earthquake magnitudes of 7.0 or 7.5 nor at any depth but liquefaction occurred at magnitude 8.0 between 0 m and 14.5 m; below 14.5 m, liquefaction does not occur.

Jan 1, 2007

During industrial copper electrowinning, a fraction of the electrolyte becomes entrained with the oxygen gas bubbles that are evolved at the anodes. The fraction of entrained bubbles increases from the bottom of the anode to the top, resulting in a bubble distribution that appears as an inverted wedge between the cathode and anode. Since the bubbles act as insulating spheres, electrolyte resistance increases from the bottom of the electrodes to the top resulting in correspondingly higher local current densities and uneven copper growth along the cathode. To counter-act the inherent tendency toward excessive copper growth near the bottom of the cathodes, the use of tapered anodes was examined. The potential improvement in cathode current distribution was evaluated by comparing the primary current distributions for 2-D computer models of a copper electrowinning cell with plate shaped anodes against one with tapered anodes.

Jan 1, 2007

By T. Takahashi, K. Oyamada, Y. Miyata, T. Isoo

The carbonation reaction of steelmaking slag has been known for many years. However, the size of blocks manufactured from this by-product material has been limited due to the difficulty of achieving a uniform reaction throughout the block. Using newly developed conditions, large porous slag blocks (1.0 x 1.0 x 0.5 m) were produced by car¬bonation of steelmaking slag with the optimum amount of water and supplying CO2 deep into slag powder compacted in molds. The development of these blocks has great poten-tial to solve the problem of slag utilization, for example, by recycling slag in large car¬bonated blocks for artificial fish reefs and seaweed cultivation beds. This paper de¬scribes the carbonation reaction, the new process for producing large slag blocks, and the utilization of blocks in past and recent years.

Jan 1, 2004

By S. K. Sadrnezhaad, B. Hashemi, Z. A. Nemati, Z. Moghimi

Based on the kinetics relationships of a solid - gas model, a software was developed for the prediction of oxidation. Preliminary prediction of oxidation by the software and experimental results of MgO-C refractories were studied and compared. By using the obtained data from this approach, the effective diffusion coefficient, intermolecular diffusion coefficient and diffusion activation energy in the MgO-C refractories, containing various amount of graphite were obtained at different temperatures. First of all, the prediction by the software was very compatible with experimental results, for different oxidation mechanisms in the MgO-C refractories. The results showed that pore diffusion is the predominant oxidation mechanism in this system. The results indicated that when graphite content was above 10wt%, the intermolecular diffusion coefficient was independent from graphite content, and it was closed to a constant value at each temperature.

Jan 1, 2004

By D. G. Dixon

A novel technology for leaching copper from primary copper concentrates has been developed at UBC. This patented technology takes advantage of the galvanic couple between pyrite and chalcopyrite to ensure rapid and complete oxidation of chalcopyrite under mild conditions in acidic iron sulfate solution, without the need for microbes, ultrafine grinding, or chemical additives such as chloride, nitrate, or surfactants. Copper recoveries of 98% or greater can be achieved at 80°C under atmospheric conditions in as little as 4 hours of residence time. The process is selective for chalcopyrite over pyrite, generates near-quantitative levels of elemental sulfur, and is fully compatible with conventional solvent extraction and electrowinning of LME Grade A copper cathodes. In this paper, the fundamentals of the Galvanox ? process are reviewed, and selected results of batch leaching tests on various concentrate samples are presented and discussed.

Jan 1, 2007

By Fengxiang He, T. Meadowcroft, Yanjun Zhang

Slag from the zinc fuming furnaces contains about 3 percent zinc and 0.1 percent lead. The paper outlines several experimental techniques for recovering these components from liquid fumer slag. The simplest method, remelting followed by a hold period, indicated that a substantial fraction of the metal values was recoverable as a result of fuming into the gas phase, presumable by reduction of the metal ions by divalent iron ions. Following on from this, slag samples were equilibrated with copper, chosen because the activity coefficients of zinc and lead in copper are very low. This improved metal recovery, with substantial amounts of lead and zinc reporting to the liquid copper as well as to the fume. Application of an electrical emf across the slag-metal interface, using a graphite anode and a liquid copper cathode, resulted in further gains in metal recovery.

Jan 1, 2004

By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By M. Silver, R. H. McCorkell

The effects of covering materials on radon emanations from uranium mine mill tailings were investigated. Granular materials with air in the spaces allow radon to pass freely. Moist covers of compost or soil decrease radon emanation from tailings. Water-saturated covers were more effective, and freezing the tailings with these covers further decreased radon escape. Water itself is a poor radon barrier probably due to circulation. Plants had no effect on radon emanation through soil. Although radon diffusion through water-saturated powders appears to be very slow and inefficient, about 25% of the radon escaping from the grains in water-saturated tailings diffuse to the surface and emanate when no cover is present. The radon escaping from tailings through covers of water-saturated compost or soil is no more than could be accounted for by radon produced in the covers themselves.

Jan 1, 1987

By Robert B. Parsons

"Originally intended to be implemented in 1977, but actually introduced effective May 6, 1974, the earned depletion regulations have been substantially refined and modified since their appearance on the Canadian tax scene, so that this important legislation now consists of a highly complicated set of rules which even the most astute follower of tax law has considerable difficulty sorting out!This month, Tax Notes attempts to cut through this bewildering array oj regulations, in reviewing the main features of the earned depletion allowance applicable to mining operations. Despite the phase-out of earned depletion allowances for most oil and gas operations as part of the federal government's new National Energy Program, earned depletion provisions are still alive and well for the mining sector, although they might well be slowly strangling to death in their own entanglement of complexity!"

Jan 1, 1981

By K-A. Adamson

If fuel cells and hydrogen are to become a mass market reality a substantial amount of further research and development needs to be undertaken. Work in hydrogen storage, production, the economics of all aspects of fuel cells and hydrogen, materials balances, and product integration are just a few of the areas that are under focus. Setting R&D targets, and providing R&D funding are therefore areas that are central to the long term development of the market, and areas in which a number of governments worldwide are highly active. Some governments, such as Japan and Korea, have set a number of very ambitious, highly focused, long term targets and are backing this up with substantial funding, others such as the EU are working on a more integrated approach, wrapping some fairly fundamental R&D into large integrated projects which run in combination with a number of other market aspects, such as public acceptance and roadmapping. The US is slightly different, in that although is has a number of long term programmes and targets, FreedomCar and SuperGen being just two, the levels of funding are set annually with the passing of each years Fiscal Budget. This paper takes three high profile regions and analyses the R&D targets and funding levels for fuel cells and hydrogen. Criteria that will be looked at include: Time frame of target(s), level of ambition, funding issues, including: Funding windows, levels available, funding barriers, overall programme goals. The added value to this paper is that it will provide a clearer picture of where each region is heading, what are its strengths and weaknesses, in terms of R&D and where there may be areas for potential international collaboration.

Jan 1, 2005

By D. P. Wilkinson

There are significant global environmental and supply issues with existing energy paths today . Global emission and fuel regulations, global fuel and power structure, energy security, and cost are driving new technology and non-conventional approaches . Fuel cells will play a significant role in the strategy to effect positive global change, increase fuel efficiency and decrease dependency on traditional fossil fuels. Fuel cells do not require recharging, just refuelling and a wide range of fuels are possible with hydrogen being the most desirable. Technical progress as well as investments in fuel cells for transportation, stationary, portable, and micro fuel cell applications have been dramatic in recent years. The present view is very optimistic for fuel cell power generation and the status is presently at the field trial level, or early commercialization stage, moving into volume commercialization. A number of demonstration programs are in progress worldwide such as the California Fuel Cell Partnership which involves original equipment manufacturers (OEMs), fuel providers, transit authorities, state and government bodies. Fuel cells and a hydrogen infrastructure are key to a long-term solution to global energy issues. Fuel cells will need to be competitive on an economic basis with the established and highly developed internal combustion engine and other forms of power generation There has been significant technical progress in a number of fuel cell areas including power density, transient / dynamic response, multiple fuels, cost potential, reliability and durability. However, significant technology gaps still remain today. This presentation will focus on the status and progress of the fuel cell today, current fuel cell research and development, the challenges going forward, and the future view of the fuel cell and it's impact on global energy issues.

Jan 1, 2005

By K. Feindel

The distribution of water in operating fuel cells must be carefully managed to optimize the performance, durability, and functionality of the system. For example, the ionic conductivity of polymer electrolyte membranes decreases as membrane hydration is reduced. Flooding at the cathode inhibits mass transport, and it can lead to failure of materials. Build up of liquid water in the gas flow channels of a fuel cell stack will create a non-uniform distribution of pressure drops across the individual cells. We will discuss the application of 1H NMR microscopy to investigate in situ the production and distribution of water throughout an operating H2/O2 polymer electrolyte membrane fuel cell. Polymer electrolyte direct methanol fuel cells posses high theoretical storage capacities as power systems for portable electronic devices. There are, however, two long-standing hurdles to development of practical methanol fuel cell systems. First, the electro oxidation of methanol at the anode of the fuel cell is poisoned by absorbed carbon monoxide, an intermediate in methanol electro oxidation. Second, methanol readily crosses over from the anode to the cathode of the fuel cell. This methanol crossover wastes fuel, and it poisons the electro reduction of oxygen at the cathode. We are investigating use of 2-propanol as an alternative to methanol as a fuel. 2-Propanol is less toxic than methanol, and it is less prone to crossover from the anode to the cathode. More significant, however, is that the electro oxidation of 2-propanol to acetone is faster than the electro oxidation of methanol because it avoids formation of adsorbed carbon monoxide. We will present active catalyst systems for the electro oxidation of 2¬propanol to acetone in fuel cells. We will also present methods to convert the resulting acetone back into 2-propanol, possibly leading towards rechargeable portable fuel cell systems.

Jan 1, 2005

By Peter J. Franklin

"Short-term mine planning of open pits is an activity that has historically been carried out by hand. Typically, the use of computers has played little part in this type of mine planning. This paper describes the objectives and the procedures involved in short-term mine planning, comments on the type of computer systems available, and describes in detail a computer-aided short-term planning and scheduling system known as STEPS.IntroductionThe mine planning department of any o pen-pit mining operation performs a wide variety of different tasks. However, their primary concern is the preparation of detailed long-and short-term mine plans. These mine plan s will define the long-term operating strategies and definitive everyday working plan s for the ongoing development of the open pit.In this day and age, when operating costs have spiralled upwards due to inflation , and product revenues have decreased due to depressed economies and poor markets, it is vitally important for all aspects of the mining operation, including mine planning, to be efficient and cost effective.There are numerous options available for planning engineers when generating a mine plan. A cost effective mine plan must investigate all these options and select the optimum. When using manual planning techniques, it is often impossible to evaluate all the available options. To do this, and to produce an optimum mine plan, a computer is required.This paper discusses mine planning, with emphasis toward the short-term plan and comments on how the processes may be computerized. It also describes in detail, a computer software system called STEPS, which has been designed as an interactive graphics, computer-aided short -term mine planning and scheduling tool."

Jan 1, 1985

By Richard S. Allen

"The casual visitor is not apt to think of the Adirondacks as a one-time hive of mining and manufacturing activity. However, where there are mountains there are usually minerals and northern New York State is no exception.The Adirondacks are a rocky shield, a great stone cap pulled down over what is now northern New York. The bedrock consists of layered metamorphic rocks which were once sandstones or limestones on the bottom of a shallow sea that covered the region 1000 million years ago. The highlands are composed for the most part of the igneous rock anorthosite. Ancient earth upheavals at temperatures of at least 750°C mixed molten masses of anorthosite and the minerals it contained with the older metamorphic rock, resulting in deposits of iron-titanium oxide s, red garnet and other valuable minerals. Of these, the most readily recognizable was iron.The first hint of the existence of iron ore in the Adirondack Lake Champlain region of upper New York State seems to have come from a Swedish naturalist, Peter Kalm (1716-1769), who travelled through French Canada and visited the military outpost of Fort St. Frederic in 1749. In July of that year, Kalm wrote:""Among the kinds of sand which are found on the shores of Lake Champlain; one is black and the other garnet-colored... and they sparkle when the sun shines. All the grains of this sand without exception are attracted to the magnet, the uppermost or black sand being about a quarter inch deep...""Concerned primarily with the fur trade, the officers and men who occupied this remote bastion of La Belle France were apparently unaware of the industrial and commercial possibilities beneath their feet. No deposit of iron was then known to exist any closer than the Three River s area in Lower Canada."

Jan 1, 1983