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By K. S. Raja, F. Battick, B. Pesic

"CeO2 doped with lower valence cations, such as Y3+, Sm3+, Gd3+ etc. is considered as electrolyte material for low temperature SOFC. Doping introduces additional oxygen vacancies and improves ionic conductivity. This work describes the preparation of yttria-calcia doped-ceria precursor material, its sintering in DC and AC field methods, and characterization of sintered electrolytes with respect to the ionic conductivity. Doped precursor materials were prepared by a controlled co-precipitation process. Sintering of prepared, pelletized particulates was carried out using three different methods such as: 1) conventional; 2) spark plasma sintering; and 3) an alternating current field at 1125°C (AC assisted sintering). The mechanism involved in the conductivity improvement as a function of defect density, grain boundary area and phase stability will be discussed. INTRODUCTIONThe performance of SOFCs depends highly on the properties of materials. Subtle variations in the composition, microstructure, or density of SOFC components can considerably alter the power output capabilities of fuel cells. Early SOFCs utilized zirconia based electrolytes but efforts in lowering the operating temperatures of SOFCs have prompted investigations into several other oxygen ion conductors – often modified with dopants to either promote the formation of oxygen vacancies or to stabilize a vacancy rich high temperature phase – such as bismuth oxide, lanthanum gallate, and ceria.The transport of oxygen ions through the electrolyte first begins with diffusion into the material. While this is generally a surface kinetics phenomenon, it is safe to say that it is highly dependent on oxygen pressure and vacancy gradients. The role of the cathode in SOFCs is to reduce oxygen at the electrolyte surface creating an O2– ion gradient which induces permeation into the material. Once inside and under the influence of a potential field, O2– ions migrate by a vacancy hopping mechanism, Catlow, C.R.A. (1990), effectively exchanging positions throughout the matrix until they reach the anode and react, thus leaving the matrix."

Jan 1, 2012

By Gang Mei, Nengxiong Xu, Yanlin Zhang

After open-pit mining finishes, an iron mine with steeply inclined ore-bodies will generally transform to underground mining. Non-pillar sublevel caving method, with horizontal slice mining from up to down, is commonly used for mining deep ore-bodies under the open-pit bottom. As horizontal slice mining proceeds, a gradually enlarging goaf will be formed under the open-pit bottom, the rocks surrounding the handing and heading sides of the goaf will collapse continuously, and then these results in rock-mass failure with large deformation and displacement in the open-pit slope. Based on FLAC3D, a modeling approach to predict pit slope deformation and failure induced by transitioning open-pit to underground mining is proposed in this paper. This method mainly consists of three procedures of modeling, i.e., mining modeling, landslide modeling, and filling modeling, of which landslide modeling is the core of the proposed approach. In the procedures of modeling with FLAC3D, iteration non-convergence is taken as a local failure criterion of pit slope. When iteration calculation cannot converge, the sliding modeling will start by deleting some elements with large displacements, and finish until convergence. Before modeling landslide, several displacement contours of rock-masses in the pit slope are searched out, and each contour is an approximate possible sliding surface of the open-pit slope. From these contours, the most proper one is selected as the slope sliding surface by using the iteration calculation convergence and minimum element deletion as the judgment condition. Landslide modeling is then realized by removing the elements outside the slope sliding surface. Finally, to demonstrate the effectiveness, the proposed approach is used to simulate the process of open-pit to underground mining at Yanqianshan Iron Mine, and to predict the deformation and failure characteristics of open-pit slope during underground mining. The case study results show that: the prediction of the slope stability determined by using our method is consistent with that calculated by using the limit equilibrium methods.

Jan 1, 2015

By J. A. Espinosa-Guillen, J. A. Lopez-Molina, S. García, J. A. Valencia-Quintanar

"The design and implementation of grouting treatments in rock masses are procedures that require continuous adjustment of parameters and criteria to optimize the results. In this proposal we describe a set of tools that enhance decision-making for this type of jobs particularly in dam projects. The methodology is focused on hydrogeological zoning of the site and its constant update combining engineer’s experience with artificial intelligence techniques to integrate the site knowledge; as well as the evaluation of grouting results for different scrutiny scales, with special attention on the relationship between water absorption and grout consumption. INTRODUCTIONSeveral methodologies for design, implementation and evaluation for grouting rock masses have been developed for the solution of specific problems and tested in diverse geological conditions. Each of these methodologies is focused on results evaluation for different scrutiny scales (Table 1) and is employed to assist decision-making before or during the grouting process.Some methods define specifications for grouting each stage of the borehole, making theoretical, semi empirical or experience-based considerations to define basic parameters as maximum pressure, maximum volume, grouting time, flow rate, etc. Ultimately each approach aim to optimize the injection process, adjusting volumes or the grouting time required to obtain satisfactory results, reducing risk of creating new flow paths or unnecessary grout travels, and enhancing the mixture properties to achieve adequate penetrability and long-term behaviour. Some of these criteria have been widely used in dam projects, for example the concept of Grouting Based on Facts to define the maximum pressure and volume (Ewert, 1997), the GIN method (Lombardi & Deere, 1993; El Tani, 2012), or the North American standards based on Apparent Lugeon measures (Naudts, 1995; Bruce 2011); on the other hand, there are relatively new criteria that have shown good results for dam grouting as the Aperture Control Method (Bonin et al., 2012; Carter et al., 2012) or the Real Time Grouting Control Method (Stille et al., 2012)."

Jan 1, 2015

By A. Perucho, J. P. Harrison, A. Bedi, L. Alejano, L. Lamas, A. Sofianos, A. M. Ferrero, R. Migliazza, R. Olsson, J-F. Mathier

"In 2010, the Eurocode for Geotechnical Design, EN-1997-1:2004 (CEN, 2004), informally known as Eurocode 7 or EC7, became the Reference Design Code (RDC) for geotechnical design – including rock engineering design – within the European Union (EU). EC7 is one standard within the comprehensive Structural Eurocode suite, which as a whole has been also adopted by a number of other countries beyond the EU. EC7 is thus becoming a key design standard for geotechnical engineering worldwide.As part of the Structural Eurocode suite, EC7 requires designs to adhere to the principles of Limit State Design. However, it is not clear that current rock engineering design practice can satisfy this requirement. In addition, evidence is accumulating that EC7 is currently difficult to apply to, and may even be inappropriate for, rock engineering design. These issues may be due to the fact that the development of EC7 to date took place without any formal input from the international rock mechanics and rock engineering community.In early 2011 under the auspices of CEN (Comité Européen de Normalisation / European Committee for Standardisation), EC7 entered a formal period of maintenance which was aimed at improving the applicability and ease-of-use of the Code. This maintenance cycle will conclude in 2020 with the publication of a revised version of EC7.This paper describes a number of critical aspects for rock engineering in the context of EC7, inparticular the following:– the history of the Structural Eurocodes and the concepts they embody;– the nature of Limit State Design and the challenges and opportunities it poses for rock engineering design;– the formal means by which the Structural Eurocode maintenance cycle proceeds;– the plans currently being developed for improving EC7 with regard to rock engineering design and construction;– the unique and vital opportunity for the entire international rock mechanics and rock engineering community to comment on the Code and make suggestions for its improvement."

Jan 1, 2015

By J. E. Dutrizac, R. J. C. MacDonald, J. B. O'Reilly

"Sometime around 3000 B.C., primitive metallurgists working in the mountainous regions of Asia Minor bordering on the Black Sea (Pontus) produced a soft, easily fused metal today known as lead. It appears certain that the first metal was made by reductive smelting of galena, but whether this recovery arose by the accidental inclusion of galena in the stones of a fire hearth or whether it occurred as a consequence of simple pyrometallurgical experiments on a series of interesting ""stones"" will likely never be known with certainty. The properties of galena, high metallic lustre, great density and facile cleavage, must have excited the ancients, and such ""stones"" would have been the object of primitive testing111 - Shortly after the discovery of lead, the ancients found that the controlled oxidation of this metal at elevated temperatures yielded smaller amounts of a more interesting material, silver. Again, it is uncertain if the production of silver by primitive cupellation techniques was the result of a fireside accident or the consequence of a deliberate experiment, but the important fact is that silver was produced shortly after the discovery of lead. The techniques for making lead and silver spread gradually throughout the entire civilized world, likely as a result of both technology diffusion and independent rediscovery. The physical properties of lead could not have been overly attractive to the ancients, but silver was a different matter altogether. The gleaming white lustre and relative immunity to oxidation quickly assigned silver to the precious materials category, a status it still enjoys. In early times, argentiferous galena was inevitably processed only for its silver values; lead was generally an unwanted byproduct and was frequently discarded as litharge (PbO) during the cupellation process. The silver was eagerly sought, however, and resulted in considerable mining activity culminating in the famous Athenian silver mines at Laurium at the southern end of the Athenian peninsula."

Jan 1, 1999

By H. Son

The three-dimensional (3D) reconstruction of as-built industrial plant models plays an important role in revamping planning, maintenance planning, and preparation for dismantling during the lifecycle of industrial plants. Recently, the 3D reconstruction of existing industrial plants was conducted using laserscan data to make surveying processes more efficient. However, the current 3D reconstruction process from laser-scan data is still limited due to the need for significant human assistance. Although a great deal of effort has been made to efficiently reconstruct 3D as-built industrial plant models, the presence of objects?such as equipment, pipelines, and valves of different sizes and shapes?in existing industrial plants significantly increases the complexity of laser-scan data and makes automating the reconstruction process more challenging in practice. The purpose of this study is to propose a knowledge-based approach for the 3D reconstruction of as-built industrial plant models from unstructured laser-scan data. First, pipelines were extracted from laser-scan data based on surface curvature information and knowledge about pipelines' sizes from existing piping and instrumentation diagrams (P&ID). Once entire pipelines were extracted, they were modeled based on skeleton features. Then, the remaining objects were clustered and grouped separately via the region grouping process. Afterward, clustered objects were retrieved and modeled based on global feature-based matching from the 3D database. Finally, the resulting model was checked to ensure that it was well-reconstructed according to the information regarding the relationships among objects abstracted from the existing P&ID. The preliminary results on actual industrial plants show that integrating knowledge into the reconstruction steps played an important role in the proposed approach and that this approach obtained accurate as-built industrial plant models from unstructured laser-scan data. The proposed approach could be successfully utilized to assist in many applications during the lifecycle of industrial plants.

Aug 1, 2013

By Muhammad Usman Siddiqui

Managing and analysing the vast amounts of data collected in a mining project effectively is crucial for enhancing the project's economic feasibility. The efficient utilization of this data is critical to minimising the time spent on projects and increasing project value. Process engineers can effectively integrate geometallurgical data into plant operations by employing analytical tools like Python, significantly optimizing the mine-to-mill process. This practical approach is a game-changer in the mining industry. Classifying a geomet dataset into units of similar characteristics (properties of the ore) is an important outcome of a geomet study. This approach simplifies data classification, allowing for class-by-class process modelling, which improves the decision-making process in mine planning and development. Classifying a geomet dataset involves using grade, lithology, and test work data (if available) to create blocks of similar characteristics, known as ‘geomet units.’ Compared to conventional methodologies, these units provide context and empirical evidence that can be more accurately mapped onto block-by-block process flowsheet development and net present value (NPV) estimation. This robust classification method reduces a project's technical risks and influences the initial mine planning sequence to maximise profitability. Defining robust geomet units with data sets with similar material is challenging due to the vast amounts of data available and the database's high heterogeneity. The methodology's purpose is to minimise time-consuming low-value-adding aspects of geometallurgy. The approach is different for a greenfield and a brownfield study, as all the valuable data in a brownfield process can be utilised to define the geomet units. Python has various libraries providing multiple machine-learning algorithms to assist in classification. The k-means algorithm is used for clustering, and the SHapley Additive exPlanations (SHAP) method is used to quantify the effect of each feature on the clustering results. However, even with automation, the methodology still requires a keen eye to account for the nuances that appear from project to project.

Oct 1, 2024

By Vladislava A. Ignatkina, Fillip O. Milovich, Vladimir A. Bocharov

"Complex research of flotation concentrates of monomineral fractions of chalcopyrite, sphalerite, galena, pyrite, pyrrhotite included methods of adsorption of collectors, surface compounds by IR ATR, and surface films of flotoreagents by TEM. They revealed that the proportion of the parts of thionocarbamate (TC) and dithiophosphate had an effect on the adsorption rate of the components of minerals, on the presence of characteristic bands, and, what is an important, visualized surface film of organic flotation reagents on the particles of concentrates by TEM. The predominance of thionocarbamate in a composition selectively increases the adsorption rate constant of the components and recovery of chalcopyrite compared with sphalerite and galena. The highest flotation rate using TC is characteristic for chalcopyrite (0.62 min- 1) in case of individual use, and it's in combination with butyl xanthate (25% butyl xanthate or 3:1) 0.89 min-1 too. We studied the ternary blend - dithiophosphate: thionocarbamates: butyl xanthate. The increase of the proportion of butyl xanthate in combination reduces the contrast of the flotation rate among all sulfides.Practice flotation of refractory sulfide copper-zinc ores of the Urals (content sulfide iron - 75- 95%) confirmed that the use of a combination of selective collectors increases selective recovery of copper sulfide minerals up to 50% at the first fraction that is the conditioned copper concentrate. New selective sulfhydryl collectors resulted in high levels of recovery of copper into a concentrate - more than 90% - against 70-72% (butyl xanthate) from copper-pyrite ore. Low floatability of iron sulfides has been obtained by selective sulfhydryl collectors. Using weak selective sulfhydryl collectors can reduce pH into collective or selective flotation from pH 10-10.5 to pH = 7.2-7.5, which improves the quality of individual concentrates of nonferrous metals and their recovery. The same is true for polymetalic sulfide ore. The volume of gold recovery also increased."

Jan 1, 2016

By T. A. Chepushtanova, I. U. Motovilov, V. A. Luganov, G. D. Guseynova

"Kazakhstan has significant reserves of oxidized nickel ore with low nickel content. Processing of such ores is effective via pyrometallurgical technologies such as smelting to ferronickel or matte with consecutive extraction of metals from melting products. There are also many options for direct hydrometallurgical processing. However, they do not provide high nickel recovery.We studied extraction of nickel and cobalt by using combined technology of low-grade ore processing from the Shevchenko Kazakhstan deposit, which includes smelting to poor matte followed by hydrometallurgical processing of the matte. The nickel content in the initial ore was 0.75–0.9%. Pyrite concentrate of Sokolov-Sarybai Kazakhstan deposit containing 0.17% cobalt and 0.06% nickel had been used as a sulphidizer at smelting.As a result of the study, we were able to extract up to 98% of the nickel and up to 80% of the available cobalt. Obtained matte contained 3.1% nickel, 0.29% cobalt, 71.6% iron and 24.3% sulfur. Matte leaching was carried out by hydrochloric acid. The iron content in the pregnant solution was 170–185 g/dm3. Nickel and cobalt precipitation from the pregnant solution was carried out by hydrogen sulfide. Initial matte or cast iron was used as neutralizers during the process. Practically complete precipitation of nickel was achieved at 3–5% excess of neutralizer at 333–343°K in 4 hours; up to 95% of cobalt precipitation was achieved in 50% excess of neutralizer at 363°K in 8 hours. The purified solution contained 200–600 mg/dm3 of nickel, 80-100 mg/dm3of cobalt and 175–185 g/dm3 of iron. The purified solution allows to obtain iron oxides by high-temperature hydrolysis, and to regenerate hydrochloric acid.As a result of non-ferrous metals precipitation we obtained sulfide concentrate with concentration of Ni up to 25% and concentration of Co up to 5.5%. The technology is recommended for semi-industrial testing."

Jan 1, 2016

By Z. Q. Yue

Many large rock avalanches and/or landslides have occurred in mountainous regions around the world. Their occurrences are normally rapid and unexpected, which can cause disasters. They have been investigated extensively by many researchers and engineers since the 1903 Frank Slide on Turtle Mountain, Alberta, Canada. They are one of the most peculiar phenomena because the rock debris of more than one million m3 can move over the horizontal distances exceeding those expected from conventional friction physics. This paper presents a gas cause hypothesis responsible for the large rock avalanches. It is the migration and expansion of a certain amount of highly pressurized and dense natural gas mass from deep geological grounds into the mountainous rock mass slopes. The natural gas with high pressure and density can escape from the deep geological ground and flow through faults, weak zones and/or porous channels into the rock mass forming a mountainous slope. The rock mass forming the slope has the high tensile and compressive strength and can resist the initial loading of the gas mass migrated into and stored in their voids, pores, holes, gaps, openings, apertures and cavities. With time, more and more gas mass from deep ground can migrate into and stored in the slope rock mass. Eventually, the peak equilibrium of forces and deformation reaches. The expanding power of the gas in the slope rock mass would instantly and rapidly break, erupt and/or explode them. The compressed and dense gas mass would mix, flow and expand together with the broken rock debris mass and continue offering their remaining expanding powers to the moving and sliding debris mass. As a result, the rock debris of large volume can reach the runout distances exceeding those expected from the conventional friction physics. The gas would escape into the sky and the solid rock debris would remain on the ground spreading over large ground area. The 1903 Frank Slide is examined to show this gas cause and mechanism in mountainous regions.

Jan 1, 2015

By Nicholas Bonderoff, Amily Xu

The evaluation of battery electric vehicles (BEVs) in underground mines involves comprehensive business case analysis beyond just the capital and operating costs of the equipment itself. BEVs demonstrate benefits from an EHS perspective, reduced mine ventilation costs, lower energy operating costs, reduced overall GHG emissions (dependent on the source of electricity), elimination of DPM, lower equipment maintenance costs, and reduced cooling requirements in deep mines. When including batteries and supporting infrastructure, BEV capital costs are approx. 80% greater than that of diesel equipment. The project economics are highly dependent on the cost of electricity and diesel fuel, and these can vary widely depending on the location of the mining operation. Battery charging and swapping methodologies must be evaluated as there are a variety of approaches that can be employed which vary by manufacturer and type of equipment. Careful consideration of the cycle times, charging methodologies, and location of the battery charging infrastructure is necessary. Specific operating conditions must also be taken into consideration. For example, the time for blast gases to clear will be increased by reducing ventilation flow, and the potential impact on production needs to be evaluated. Similarly, the electrical distribution system needs to be evaluated for peak loading conditions when BEVs are charging. Criteria including maintainability, reliability, commercial availability, and performance need to be evaluated. BEVs have fewer components than diesel equipment and this correlates to lower overall maintenance costs, however, BEVs require maintenance personnel with specific skill sets in order to maintain the equipment. Battery lifecycle costs need to be considered as battery replacement incurs significant capital expense. Some manufacturers offer services to offset these capital costs through usage agreements. Recycling and disposal of batteries at the end of their lifecycles also need to be considered. With the increased selection of BEV equipment that will be available in the next 2-4 years, 100% BEV adoption is also possible. We recommend a holistic approach when evaluating BEVs for underground mines. This will ensure that everything is considered in order to evaluate the full impact of BEV implementation.

Jan 1, 2023

By Michael T. G. Brown

Syncrude Canada Ltd. has recently completed construction of its ambitious tar-sand mining and processing facilities at Mildred Lake, Alberta. The Syncrude site is approximately 48 km (30 miles) north of Fort McMurray near the west shore of the Athabasca River. The Syncrude operation involves the open-pit mining of approximately 270,000 tonnes (300,000 tons) of tar sand daily using draglines and a conveyor system. Bitumen is extracted from the tar sand, upgraded to oil-gas and transported to refineries in Edmonton and other locations for final processing . The Beaver Creek Dam forms part of the mining facilities for the Syncrude tar-sand mining operation. Water from Beaver Creek is diverted from the open-pit mine site south to the Athabasca River via Ruth Lake and the Poplar Creek Dam. General site layout is shown on Figure I . Design of the dam was completed by R. M. Hardy and Associates Ltd. of Edmonton, Alberta (now Hardy Associates (1978) Ltd) . Construction was undertaken during the summers of 1974 and 1975 under the direction of Canadian Bechtel Limited, managing contractors for Syncrude Canada Ltd. Total length of the dam is approximately 2.8 km (1.7 miles), with a maximum height in the order of 16 m (50 ft) The Beaver Creek Dam is located in a broad, flat, poorly drained valley. About 50 per cent of the site is covered with treeless peat deposits, which ranged in thickness from in excess of 5 m (15 ft) at the east end of the dam to less than 1 m (3 ft) at the central portion. The peat deposits overlie Pleistocene meltwater sediments on top of clay/clay shales of the Clearwater Formation and the tar sands of the McMurray Formation. The peat deposits and high groundwater levels at the site combine to make the excavation and construction of a conventional rolled clay cutoff impractical. For these reasons, the slurry cutoff trench technique was utilized to produce an efficient and effective seepage cutoff under various sections of the Beaver Creek Dam .

Jan 1, 1979

By M. Jiang, X. Fan, W. X. Chen, Z. K. Guo, H. H. Zou

"Some improvements are carried out for elasto-plastic model by taking the shear dilation effects and relaxation effects of deep rocks into accounted. The high pressure equations of states with Mie-Grüneisen form are also introduced to describe the relation of pressure-volumetric strain. Numerical simulations of free field responses for deep underground explosions are conducted by using the user subroutines which compiled by means of the secondary development functions of LS-DYNA9703D codes. It is indicated that the dynamic responses of free field are well simulated based on this improved elasto-plastic model, and the analytical results are in good agreement with the data of U.S. Hardhat nuclear test.INTRODUCTIONDynamic behaviors of deep rocks for underground explosions are obviously different from that of shallow underground explosions and have aroused great attentions of international experts who work for rock engineering. The dynamic models of deep rocks could be roughly divided into classic elasto-plastic model and fracture damage model according to different theoretical foundation. M. E.Kipp and D. E.Grady et al. are the outstanding representatives who engaged in the researches of fracture damage mechanics. Researches of dynamic problems for geomaterials were carried out by C.C.Grigorian and the conclusion that incompressible elasto-plastic medium model could not be used to solve the problems of closed underground explosion was derived, and therefore C.C.Grigorian model was proposed. In this model, C.C.Grigorian assumed that the average hydrostatic pressures and the densities of medium had one to one relationship, and the path of loading or unloading is different from each other. For shear deformations, analytical solutions of the problems were derived according to the model which was slightly different from Prandtl-Reuss model, the constitutive equations were closed by Mises-Schleiher constitutive model. However, the analysis showed that there were two inadequacies in C.C.Grigorian model. Firstly, the shear dilation effects of fractured medium after wave front could not be considered. Secondly, the relaxation characteristics of the rocks in fractured region were not taken into account."

Jan 1, 2015

By D. Monder

Fuel cells are promising sources of electrical energy because of their exceptionally high efficiencies and low environmental emissions. Solid oxide fuel cells (SOFC) are high temperature, ceramic electrolyte cells, which unlike most other fuel cells, can work with a variety of fuels besides pure hydrogen, including hydrocarbons and hydrogen sulfide. In this presentation I present the models we have built for a single H2S fuelled SOFC. The goal is to model the electrochemical reaction coupled with mass transfer, fluid flow and current/voltage distribution in an yttria stabilized zirconia electrolyte fuel cell assembly operated between 750 and 850 °C. Two models of the above SOFC are discussed in this work, 1) an algebraic model derived by integrating a one-dimensional model along the thickness of the cell, and 2) a two-dimensional finite element axi-symmetric model. Important physical and kinetic parameters in the 1-D model are fitted using experimental data sets at three different temperatures and reasonable fits are obtained for the data sets at 800 °C and 850 °C. However, the third data set at 750 °C does not give a good fit using this model. We need to apply the curve-fitting to more data sets to investigate it further. The main conclusion that can be drawn from the present study is that the ohmic resistance of the cell is very high. Contact resistances are believed to be the reason behind this although there could be contributions from resistive interphases. The 2-D model also gives reasonable fits to data sets. One of the publications by the laboratory group doing the experimental work in our department presented very interesting data that shows the cell performance being a strong function of fuel flow-rate. We want to model this behaviour and will have to depend on the 2-D model as the 1-D model does not have flow-rates as parameters.

Jan 1, 2005

By D. Eriksen

Zero Emission Gas power, ZEG, is a novel concept where a high temperature solid oxide fuel cell (SOFC) is integrated with a reforming reactor producing hydrogen from natural gas through Sorption Enhanced Steam Methane Reforming (SESMR). The SOFC is used as a high temperature heat source for regeneration of the CO2-absorbent. Moreover, by using part of the produced hydrogen as fuel for the SOFC, the waste heat of the process is considerably reduced. Thus, the process has a very high thermal efficiency and produces both electricity and hydrogen from natural gas. In addition, a stream of pure CO2 is produced in the regeneration step and can be deposited or used commercially. Initial cost estimates indicate a cost of electricity and a cost of hydrogen well below today's prices. A small (1kWel + 1kW H2) demonstration set-up is under construction and experimental results and related research will be presented. This set-up comprises one 2.5kWth H2 SESMR-reactor (about 0.85 Nm3/h H2) operating batchwise with dolomite as the CO2-sorbent. The reactor developed is designed like a parallel plate heat exchanger where the mixture of sorbent and reforming catalyst is packed between the heat exchanging plates. The demonstration set-up includes a 1kW SOFC operating in a continuous mode. The set¬up will therefore demonstrate continuous simultaneous hydrogen- and electricity production, but cannot demonstrate simultanuous electricity- and CO2-production. The set?up is well equipped for on-line monitoring of gas composition, flows and temperatures. This important part of the demonstration set-up is developed and provided by Christian Michelsen Research (CMR). A minor part of the project is the development of a continuous circulating fluidized bed SESMR-reactor system and in another related project the focus is on the development of more suitable sorbents. In these two projects co-operation with University of British Columbia and Lousianna State University, respectively, is highly appreciated.

Jan 1, 2005

By B. R. Casement

"Managing safety on the basis of after-the-fact reaction to accidents, can never be more than partially successful. Injuries will occur as long as the underlying potential for them still exists. Unless unsafe actions and conditions are systematically decreased, no program can have more than a short-term success.The pro-active Bullmoose loss control process, instead, focusses on heightening awareness of work habits, to prevent incidents by reducing their potential.Any safety program will be doomed to failure if the development of safe work habits depends on the safety supervisor or a safety committee. At Bullmoose the focus is on the critical actions out of which losses emerge. The successful application of performance-related feedback is achieved by taking safety, health, and environmental concerns into consideration on every level, and, by doing the right thing in every job done.What is an Exceptional Loss Control Program?If an accident in an organization creates a flurry of interest, resulting in ""cracking down"" on violations for a short period of time then an ""exceptional"" loss control program exists. Unfortunately, exceptional here does not refer to the effectiveness of quality of the program but to the fact that the organization is managing loss control by exception. The degree of management attention in an ""exceptional"" safety program varies over a period of time, remaining low as long as the rate of losses stays within management's acceptable control limit (Fig. I). When the losses rise above this, management becomes motivated to begin ""exceptional"" efforts to manage losses. When the rate falls again to within the accepted limit, efforts to control losses take a back seat.Such a strategy guarantees that losses will be tolerated or ignored as long as the actual rate is below the acceptable limit. Simply to lower the limit would not reduce losses, but would result in an increased number of flurries of management attention to loss control. This ""on-again, off-again"" style of management teaches supervisors and others that basic loss control is not as important as are statistics."

Jan 1, 1993

"Projections of demand for Alberta coal indicate a quadrupling of current production rates to some 70 million tonnes/year by the end of the century. About half of this output-comprised of subbituminous coal-will be required within the province, primarily for generation of electric energy. The remainder-roughly 70 per cent high-volatile bituminous (hvb) steam coal and 30 per cent medium- or low-volatile bituminous (mvb/lvb) metallurgical coal-will be exported, principally to Pacific Rim and Western European countries. Direct employment in mining and coal processing is projected to increase from the present ca. 3000 to at least 12,000 persons.This paper presents separate forecasts for subbituminous, hvb and mvb/lvb coal production in the period 1982-2000; notes a number of possible developments that could substantially modify these forecasts; and briefly discusses attendant infrastructure requirements. Attention is drawn to potential shortages of qualified manpower and to threatening inadequacies of transportation facilities.IntroductionDespite the dislocations triggered by the 1973 'oil crisis', energy budgets of Western industrial countries are mostly still in the very early stages of the anticipated transition to greater reliance on coal. Shift s to coal are still more often only talked about than being implemented; and the public policies which are essential for timely development of facilities for producing, transporting and using coal are in many instances not yet even broadly formulated, let alone enunciated.In these circumstances, long-range projections of coal demand and supply-even if restricted to internal requirements- are subject to greater uncertainties than usually afflict such forecasts.On the demand side of the equation, these uncertainties arise ultimately from linkages between a need for coal and the availability and pricing of OPEC oil. The current surplus of oil on world markets, which has recently forced substantial reductions of posted prices, is undoubtedly a transient phenomenon that is unlikely to have any long-term impact."

Jan 1, 1982

By R. Gatzweiler

The Key Lake nickel-uranium deposits are situated within the Wollaston domain of the Churchill structural province. The host rocks of the two orebodies are of Aphebian and Helikian age. The orebodies occur mainly within a 5.2-km-Iong, northeast-trending zone which coincides with the intersection of the sub-Athabasca unconformity and a reverse fault striking east-northeast. The principal controls of mineralization are structural and lithostratigraphic (i.e., post-Athabasca faults, the sub-Athabasca unconformity and graphitic metapelites in the lower Aphebian, close to the Aphebian/Archean unconformity). Grades of up to 35% U3O8 and 20% Ni are recorded over intervals of up to 2 m. Some hypogene zonation exists and the nickel mineralization tends to underlie the high-grade uranium ore. The ore minerals include pitchblende, a-U307, coffinite, gersdorffite, millerite, niccolite, bravoite, zoisite, sericite, chlorite and kaolinite. The kaolinite is a post-ore, supergene alteration product. Chemical studies of the sub-Athabasca paleo weathering profile sho w that regolithization is characterized by depletion in Si02 and K20 and concomitant enrichment in Al203 and perhaps MgO. In the paleoweathering profile the ferromagnes ian minerals are chloritized, the Ksfeldspars sericitized and the plagioclase saussuritized. Preliminary geochronologic data from the ores reveal U/Pb ages of -1228 my, - 960 my and 89 my, and Rb /Sr data indicate basement ages of -1850 my and - 1372 my. Aphebian pelitic protoliths, carrying U and Ni, may have released some metals during post-Hudsonian weathering, and minor concentration in structural and geochemical traps may have taken place prior to the deposition of the Athabasca strata. However, it is felt that the bulk ofthe ore-grade mineralization wasgenerated after the deposition of the Athabasca formation and after faulting, probably during a major regional thermal/ intrusive episode of Grenvillian age. Several episodes of remobilization took place between 1228and 89 my ago.

Jan 1, 1979

By M. A. Bérubé, M. Choquette, P. W. Godbehere

"RESUMELa scorie produite par le procédé pyrométallurgique d'extraction Noranda contient environ5% de cuivre. Elle est traitée comme un minerai conventionnel de cuivre au concentrateur de Mines Noranda et les rejets de flottation présentent encore des teneurs souvent supérieures à 0.3% en cuivre. La scorie est principalement constituée de magnétite, de fayalite et d'un verre siliceux. Bien sûr, Ie cuivre y est majoritairement sous forme de sulfures et d'un peu de cuivre métallique. Le verre contient toutefois un peu de cuivre en solution, de 0.14 à 0.33% en moyenne, selon l’echantillon examine, ce qui représente à peine 1% de tout Ie cuivre de la scorie. Dans les rejets de flottation, cela justifie par contre de 15 à 25% des pertes totales en cuivre, Ie reste se retrouvant sous forme de tres petits globules de sulfures de cuivre ou de cuivre métallique, en moyenne de 2 à 3 micromètres de diamètre et bien emprisonnes dans Ie verre.SUMMARYThe slag produced by the Noranda continuous smelting process usually contains about 5% copper. It is processed as a conventional copper ore at the concentrator of Noranda Mines. The flotation tailings still often contain more than 0.3% Cu. The slag is mainly constituted by magnetite, fayalite and a siliceous glass. Evidently, the copper occurs mostly as sulphides and, to a lesser extent, as metallic copper. However the glass contains a small amount of this metal in solution, between 0.14 and 0.33% on an average, depending upon the investigated sample. This represents scarcely 1% of the total copper in the crude slag, but as much as 15 to 25% of this metal in the flotation tailings, in which the major part of the copper occurs as very small globules of copper sulphides or metallic copper with an average diameter of about 2 to 3 um and well-locked in the glass."

Jan 1, 1987

By J. F. Henderson, N. H. . C. Fraser

"Camlaren Mines, Limited, owns a group of claims near Gordon lake, in the Northwest Territories about 45 miles northeast of Yellowknife. The Hump vein on the property was explored continuously from the summer of 1937 to December, 1938, when all work was stopped. The two-compartment vertical shaft sunk near the vein is 380 feet deep and drifts and cross-cuts on the 200- and 350-foot levels total 2,241 feet . This exploration indicated 13,177 tons of ore with a gold content of between ½ and 1 ounce a ton1GEOLOGY AND STRUCTUREThe property is underlain by remarkably fresh greywacke and slate of the Early Precambrian Yellowknife group. The thickness of the b ~ds averages 1 to 2 feet, although that of the coarser greywacke may be 10 feet or more. Most of the greywacke beds show a gradation in grain from sandy at the base to slaty at the top. They are composed of chlorite, sericite; carbonate, and detrital quartz and feldspar grains.The structure of the greywacke and slate underlying a part of the property of Camlaren Mines, Limited, is shown in Fig. 1. The beds are isoclinally folded so that they dip at steep to vertical angles and at many places are overturned. The axes of the folds are 50 to several hundred feet apart, and generally plunge at angles of 45° or steeper. The beds along the axes of the folds generally meet to form a sharp V, and at the point of the V, or axial part of the fold, the beds are commonly ruptured . Minor faulting movements along the broken crests of the folds in many cases result in well-defined shear zones. Discontinuous quartz veins and irregular lens-like masses of quartz lying more or less parallel with the bedding are plentiful throughout the sediments, but tend to be concentrated along the ruptured and sheared, anticlinal and synclinal fold axes ( Fig. 1)."

Jan 1, 1954