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By K. Turgeon, D. Larivière, L. Whitty-Léveillé, J. -F. Boulanger, C. Bazin

"The processing of ore containing rare earth elements leads to the production of an impure solution of these elements. The separation of the rare earths from the impurities and the production of individual elements is usually carried out by solvent extraction. The effectiveness of the extraction conditions and of the reagents is generally tested in the laboratory. This paper deals with the processing of results from solvent extraction laboratory tests planned to generate data redundancy. A method is proposed to take advantage of the data redundancy by accounting for the pH variation during the extraction. The parallel processing of several tests also allows estimating the equilibrium constants for the extraction. The proposed method produces equilibrium constants that are more reproducible than values estimated using conventional approaches. The method is illustrated with solvent extraction tests conducted on synthetic solutions of rare earth elements.INTRODUCTIONThe processing of ores containing rare earth elements (REE) usually includes the production of a concentrate of the minerals carrying the REE. These minerals, for instance monazite and bastnäsite, contain the 14 elements from La to Lu plus yttrium and scandium. As an example monazite has the general formula of (La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy…Lu)PO4 with a typical lanthanum content of 20-26%, cerium content of 40-50%, praseodymium of 4-6%, neodymium of 16 to 20%, and decreasing concentrations of heavier elements (Gupta & Krishnamurthy, 2005). During the processing of a REE mineral, it is generally not possible to isolate and separate a single REE from all the rest. The mineral molecules need to be broken (usually via a heat treatment followed by leaching with a base and/or an acid) to produce an aqueous solution of the REE of the ore. After purification of the solution, the REE can be precipitated as a bulk concentrate and sold to a refinery that separates the REE into particular groups of REE such as the light versus heavy REE or into individual elements such as lanthanum, neodymium, or europium oxides to yield value-added products."

Jan 1, 2016

By A. Singh

"Flotation of fine (< 10 µm) minerals is a challenge exacerbated by the emerging practice of fine grinding flotation feed to better liberate targeted minerals; however, the ability of conventional flotation cells to float liberated fines remains questionable. The Gold Ore solution using Mach reactors was tested at Mintek, South Africa, and showed an ~180% increase in the Kelsall kfast factor, a projected recovery improvement of 4% for the Mach-reactor case, and final concentrate grade twice that of conventional flotation. Theory, pilot plant results, and key aspects of plant design, supplemented by operational plant observations after commissioning, are discussed.RÉSUMÉ Le procédé de flottation de minerais fins (< 10 µm) pose de grandes difficultés, lesquelles sont aggravées par la pratique émergente de l’alimentation du circuit de flottation avec des mailles de broyage très fines pour mieux libérer les minéraux ciblés ; la capacité des cellules de flottation classiques à flotter les fines de minerais libérées reste cependant discutable. La solution proposée par la société Gold Ore, qui utilise des réacteurs Mach, a été testée à Mintek, en Afrique du Sud ; elle affichait une augmentation d’environ 180 % du facteur kfast développé par M. Kelsall dans son modèle de flottation, une amélioration prévue de la récupération de 4 % dans le cas du réacteur Mach, et une teneur finale des concentrés deux fois plus importante que celle obtenue avec la flottation classique. Sont débattus dans cet article la théorie, les résultats générés par l’usine pilote ainsi que les principaux aspects de la conception de l’usine complétés par des observations relatives à l’usine en activité après sa mise en service."

Jan 1, 2018

By S. Harvey

The McArthur River deposit is a structurally-controlled unconformity-related uranium deposit. The mineralization is situated at the intersection of a pronounced fault zone, referred to as the P2 fault zone, and the unconformity between Paleoproterozoic Wollaston Group metasedimentary rock and Paleoproterozoic to Mesoproterozoic Athabasca Group. Mineralization is variably hosted within the Athabasca Group fault wedge and the faulted basement, consisting of twelve zones covering a strike length of 2,700 m. The main P2 fault zone consists of several reactivated foliation-parallel faults containing narrow seams of graphitic clay gouge that are separated by highly cleaved, graphitic wall rock. The mine grid east-dipping P2 fault zone is characterized by reverse offset of the unconformity surface. It varies from a single discrete fault to splay offsets consisting of two to three individual splays. The combined vertical offset along the P2 fault zone is a maximum of about 80 m. The fault has emplaced a wedge-shaped sequence of Wollaston Group metasedimentary rocks into the Athabasca Group. Foliation-oblique faults occur throughout the McArthur deposit trend. Steep east-northeast trending faults generally exhibit apparent oblique dextral sense of shear. Less common, and possibly conjugate, are steep faults trending east-southeast with an apparent sinistral sense of shear. Offsets are generally less than 10 m on these structures. South-trending and shallow west-dipping brittle faults with offsets less than 1 m are also observed while rare steep, north-trending faults are also noted locally and played a critical role in development of the Zone 2 basement-hosted mineralization.

Jan 1, 2020

By A. Saigal

A finite element analysis based investigation using DEFORM software was undertaken to model the extrusion of 15% alumina and 15% silicon carbide reinforced aluminum metal matrix composites. The study dealt with predicting the extrusion load as a function of ram displacement and initial billet temperature. The finite element simulation was also used to determine the maximum extrusion load, temperature distribution, maximum temperature, strain rate, velocity and stress distributions in the billet during the hot extrusion process. The constitutive equation used was of the type: Z = E exp(Q RT) = A{sinh(ao-)}" where Z is the Zener-Hollman parameter (temperature compensated strain rate), s is the strain rate, Q is the activation energy, R is the gas constant, T is the absolute temperature, a is the flow stress and A, a and n are constants. Based on the work of Davies et al and McQueen and Konopleva, the values of Q (KJ/mol), a (MPa-1), n and A for aluminum 6061 composites reinforced with 15% alumina and 15% silicon carbide used are 181, 0.024, 4.15 and 1.33x10&apos;2 and 233, 0.052, 2.60 and 1.26xl0&apos;4, respectively. Even though the individual parameters are quite different, it was found that the predicted maximum extrusion load, temperature distribution, maximum temperature, strain rate, velocity and stress distributions are quite similar and differ by no more than 1-2 percent between the two composites indicating that the deformation behavior is primarily controlled by the matrix material and is not a function of the type of reinforcing ceramic particulates.

Jan 1, 2004

By M. E. Holuszko

A research program has been carried out at the Mining Department of the University of British Columbia to study the effect of wettability of coal on its handleability and bulk density. The effect of moisture content on the bulk density of coal was found to be more pronounced for hydrophilic coals than for hydrophopbic ones. Altering wettability of coal surface leads to different effects of moisture on bulk density. The samples were studied at different fine fractions content, and it was shown that there was no effect of increased content of fines on the bulk density for hydrophobic coals, while for hydrophilic coals this effect was very significant. It was shown that the moisture content at which the lowest bulk density was reached coincides with the critical moisture content for studied samples, as determined from handleability tests using Durham Cone method. This critical moisture is the moisture content at which a sudden deterioration of coal handleability occurs. Based on the bulk density and handleability tests, the flow theory of moist coal is proposed.

Jan 1, 2006

By C. J. Hall

This paper presents a basic motive column analysis of natural ventilation and shaft resistance, using the density depth diagram. The method makes use of tables showing the state of the air as determined by thermodynamic analysis. Several theoretical examples are given.

Jan 1, 1968

By P. T. O'Kane

The PLATSOL® process, initially developed for the treatment of the NorthMet Cu/Ni/PGM concentrate, has seen over the recent years its applicability extended to include numerous other Cu/Ni concentrates of the same type, as well as other precious metals-containing feedstocks. However, several concentrates were found refractory to the typical PLATSOL® conditions, more particularly so the platinum. Attempts to extend those conditions, such as higher temperatures (250°C), longer retention time, increased oxidation conditions, higher chloride additions, were not successful. Detailed mineralogical investigation of those PLATSOL® leach residues indicated the main refractory mineral to be cooperite (PtS). Further metallurgical investigations showed that a thermal pre-treatment of the concentrate effectively unlocked the refractory platinum minerals for the subsequent leach. Temperatures between 400 and 750°C were tested, with the optimum being found around 650°C. The kinetics of the pre-treatment process were fast, and one hour at temperature proved sufficient. Under those conditions, PLATSOL® extractions were re-established around 95% for both platinum and palladium. From a mineralogical examination of the calcine, it was shown that the effect of the pre-treatment was to transform the cooperite and other refractory sulphides into metallic platinum and alloys, amenable to the PLATSOL®. The implications of the pre¬treatment step for the processing of PGM concentrates arc briefly discussed.

Jan 1, 2004

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By R. H. McMillan

A classification of important uranium deposits which utilizes both genetic and descriptive criteria is presented. The dual aspect is useful because, while the non-genetic nomenclature for the different deposit types is amenable to various interpretations, the critical characteristics of each deposit type can be analyzed to clarify various genetic points. Although the classification is intended primarily for Canadian uranium deposits, most of the important deposit types known elsewhere can be accommodated.

Jan 1, 1978

Slurry flow, including flow through the charge, through the discharge grates, along the pulp lifters and its discharge from the mill is an important contributor to the efficiency of the grinding process within a SAG mill. Poor transport of finer ground material can adversely affect grinding leading to excess energy consumption and over-grinding of fine material. This paper extends a 1-way coupled DEM-SPH method to three dimensions and applies it to a 1.8 m diameter by 0.6 m long AG/SAG pilot mill. This provides detailed information on the internal flow of slurry within a SAG mill, including the prediction of dry regions and of slurry pooling. Full 3D analysis also allows the pulp flow patterns into and out of the mill via pulp lifter chamber to be investigated.

Jan 1, 2012

By P. Ashtari

Influence of Sr and Mn single and combined additions on the modification of the Fe-containing intermetallic compounds and mechanical properties of Fe-rich AA319 aluminum alloys have been investigated, The microstructural features e,g, morphology of the Fe compounds and eutectic Si has been correlated to the mechanical properties, It was demonstrated that modification of the Fe compounds from the platelet ß-Al5FeSi to the Chinese script a-Al8Fe2Si compound improves the UTS and elongation of the alloys by 10.3% and 83.9%, respectively. Moreover, the simultaneous modification of the Fe compounds and eutectic Si increases the UTS and elongation of the alloys by 15,3% and 116,1%, respectively.

Jan 1, 2005

By Mehmet F. Tauer, Pierre Trudel

"The metamorphosed mineralized Archean Bourlamaque batholith, dated at 2710 +-54 Ma, is a homogeneous body, composed mainly of quartz diorite; it is cut by late dioritic, mafic and aplitic dykes, and contains metasomatized ultramafic xenoliths. A geochemical investigation confirms the calc-alkaline affinity of the batholith, and the REE profiles are similar (Lal Yb = 3.9 to 8.1) to those of the intermediate to felsic metavolcanic rocks at Val d&apos;Or into which the batholith was intruded and to those of the calc-alkaline members of the Blake River Group at Rouyn.Gold distribution within the batholith is heterogeneous and anomalous. Although the background Au content of the batholith is estimated to be 3.2 ppb Au by RNAA , the estimated median gold content of the batholith is 10 pp b (with P84 =32 and PI 6=3.1 ppb), much higher than that of ""normal"" granites (I to 5 ppb A u). The gold mineralization exhibits a close relationship with shear zones (e.g. Belmoral Mine) or with diorite dykes (e.g. Sullivan, Perron and Courvan mines).The following sequence of geological events is proposed: (I) pretectonic emplacement of the batholith, which is cogenetic with its volcanic host rocks; (2) regional metam orphism and deformation with localized shearing; and (3) hydrothermal alteration and quartz veining. We conclude that: (1) the Bourlamaque batholith is a gold-enriched intrusion, and (2) the determination of average gold content may be an effective method f or distinguishing ""sterile"" intrusions from those with potentials for gold mineralization.RESUMELe batholite archéen minéralise de Bourlamaque, daté de 2710+-54 Ma, est une intrusion homogène, constituée principalement de diorite quartzique, qui a été recoupée par des dykes tardifs de diorite, d&apos;aplite et de composition mafique. Il contient aussi des enclaves de roches ultramafiques metasomatisees. L &apos;étude géochimique confirme le caractère calco-alcalin du bath olite et les profits des ETR sont semblables (La/ Yb=3.9 a8.1) a ceux des volcanites intermédiaires afe tsiques de la région de Val d&apos;Or dans lesquelles le batholite fait intrusion et à ceux des unites calco-alcalines du Groupe de Blake Ri ver a Rouyn. La distribution de Au dans le batholite est à la fois anomale et hétérogène. Bien que le bruit de fond du batholite ait été estime à 3.2 ppb A u par AANR, sa médiane a été estimée a10 ppb Au (avec P84=32 et PI6= 3.1 ppb) , ce qui est nettement plus élevé que la valeur des roches granitoides ""normales"" donnée dans la littérature (1 a 5 ppb A u). Dans la batholite, la minéralisation aurifère est intimement associée aux zones de cisaillement (e.g. mine Belmoral) au aux dykes de diorite (e.g. mines Sullivan, Perron et Courvan).La séquence des évènements géologiques suivante est proposée: (1) emplacement pre-tectonique du batholite, lequel est cogenetique avec les roches volcaniques encaissantes; (2) deformation et metamorphisme regional avec des cisaillements tectoniques locaux; et (3) altération hydrothermale et développement des veines de quartz. Nous concluons que: (1) le batho lite de Bourlamaque est une intrusion enrichie en Au; (2) la determination de la teneur en Au peu être une méthode efficace pour distinguer les intrusions stériles de celles qui possèderaient un pot entiel pour des minéralisation s aurifères."

Jan 1, 1989

By Jianzhong Liu

Based on the characteristics of overburden rock strata movement, surface ground subsidence and casing deformation and failure, a tension-shear combination failure model of surface borehole was set up. The main controlling factors of the mining-induced deformation and failure of surface borehole were researched with this failure model and the limit analysis method. The mining methods and geology conditions mechanics action mechanism to surface borehole and its time ?space evaluation rule was found. The surface borehole deformation and fracture rule were advanced. It provides theoretical support to optimizing layout, structure type, security measure and local casing protection of surface borehole.

Aug 1, 2013

By A. Becker, C. Gauvreau, L. S. Collett

"A scale model was designed to simulate the airborne Barringer INPUT time domain electromagnetic system. The amplitude of the response to a vertical conductive dyke varies considerably with the conductor's thickness conductivity product (TCP). The response increases from a minimum detectable level at a TCP of about 2 mhos, rises to its maximum value at a dyke TCP of 15 mhos and then falls again so that conductors with a TCP exceeding 500 mhos would probably remain undetected. Measurements made with both standard receiver coil configurations (maximum or minimum coupled) indicate comparable effectiveness for both systems, either from the viewpoint of vertical conductor detection or from the viewpoint of discrimination against overburden anomalies."

Jan 1, 1972

By J. Budac, E. Krause, C. L. Stewart, D. Wrana, S. W. Laundry

"As part of an over-all arsenic management strategy, Inco has developed a novel process that converts a by-product high moisture copper/arsenic sulphide precipitate into a crystalline copper arsenate suitable for the manufacture of wood preservation chemicals.The copper/arsenic sulphide precipitate is atmospherically leached with oxygen and sulphuric acid, producing a crude (blue) copper arsenate precipitate, elemental sulphur, and a copper and nickel containing solution. The blue copper arsenate is dissolved with sulphuric acid, the molar Cu/As ratio is raised to 2, and a crystalline copper arsenate (olivenite) is precipitated by the addition of sodium carbonate. Dissolved copper is recovered using metallic nickel (or matte) and elemental sulphur, to produce a low-moisture (low-arsenic) precipitate suitable for standard nickel-copper processing.The process was successfully piloted at Inco&apos;s Manitoba Division between September 1990 and June 1991. The copper arsenate product typically analyzed 43% Cu and 25% As, and the moisture content was about 10%."

Jan 1, 1995

By G. W. Smith

"The adsorption of dehydroabietylamine acetate on quartz, hematite, rutile and baddeleyite has been deter-mined for concentrations ranging from 0.3 to 5,600 µ. moles/I and for pH values ranging from 2.5 to 10.5.The surface tension, UV and IR spectra, equivalent conductance and ion concentrations for dehydroabiety lamine acetate solutions have been determined.Contact-angle and flotability studies have established that good collection may be obtained with this amine but that selectivity depends on the suitable use of depressants for some of the minerals."

Jan 1, 1971

The article presents an outline of methods and certain results of laboratory tests, underground tests and model tests, aimed at assessing performance of a powered shield support on the floor of low strength parameters. The tests were conducted within the framework of GEOSOFT project co financed by Research Fund for Coal and Steel (RFCR-CT-2010-00001). The described research works were conducted by Central Mining Institute (Glówny Instytut Górnictwa), Janina coal mine and Becker-Warkop

Aug 1, 2013

By A. Rodriguez-Prado

"Magnetic fields affect the growth of cultured cells and plants; however, limited information exists about their effects on vegetation performing environmental remediation. Constructed wetland mesocosms treating hexavalent chromium (Cr(VI)) wastewater exposed to low-intensity magnetic fields (60 Hz, 56.5 × 10-6 Tesla) produced 100% more biomass than the unexposed control. Nonetheless, they removed only 43 ± 27% of Cr(VI), compared to 60 ± 21% for the control. A Cr(VI) reduction expression was developed as a function of the magnetic field. The design and operation of constructed wetlands to treat mining wastewater can be corrected for magnetic field effects.RÉSUMÉ Les champs magnétiques affectent la croissance des cellules et des plantes cultivées; toutefois, il existe peu d’information quant à leurs effets sur la végétation utilisée à des fins d’assainissement environnementale. Les mésocosmes des marais artificiels traitant des eaux usées, contenant du chrome hexavalent (Cr(VI)), exposés à des champs magnétiques de faible intensité (60 Hz, 56,5 × 10-6 Tesla) ont produit 100 % plus de biomasse que le contrôle non exposé. Néanmoins, ils n’ont enlevé que 43 ± 27 % du Cr(VI), comparativement à 60 ± 21 % pour le contrôle. Une expression de réduction du Cr(VI) a été développée en tant que fonction du champ magnétique. La conception et l’exploitation de marais artificiels pour traiter les eaux usées des mines peuvent être adaptées pour tenir compte des effets des champs magnétiques."

Jan 1, 2015

By Roméo Roussin

"The yearly production from the Asbestos Hill pit is 1,550,000 tons of asbestos ore, with a yield varying between 18 and 20 % . The orebody was exposed at the top of a hill, and initial production started without having to remove any overburden. The projected ratio of barren rock to ore, based on the present orebody, was 2 to 1. However, as it was necessary to push back the upper benches, this ratio has changed to 3 to 1. The final pit will be 2,300 feet long by 1,000 feet at the longest and widest points. The final depth will be 680 ft. A pit slope stability study was carried out and an average wall angle of 60-70 degrees must be maintained. Preshearing of final pit limits will produce good wall stability. Permanent access ramps will be 60 ft wide, with an 8 % maximum grade. Geological conditions and the low rock temperature are the major causes of the operation's drilling and blasting problems."

Jan 1, 1976