Search Documents

By R. Rumpold, J. Antrekowitsch

"The continued increase of the automobile production leads to a higher platinum, palladium and rhodium (PGM) demand. Due to the high value of the PGMs the recycle of these metals from automotive catalysts is of special interest. Pyrometallurgical processes, which are only focused on the PGMs, represent the state of the art of automotive catalysts recovery. However, hydrometallurgical recycling processes offer additional recovery of other valuable metals and compounds. The method presented in this paper is based on a combination of hydrochloric acid and hydrogen peroxide to dissolve the valuable metal fraction which can be precipitated afterwards.INTRODUCTIONPlatinum and the corresponding metals from the PGM group, especially palladium and rhodium are well known as catalytic active materials. They support chemical reactions which are inhibited. This effect is used to decrease the amount of harmful compounds like hydrocarbons, carbon monoxide or nitrogen oxides in automotive exhaust gases. The generation of these toxic substances is based on incomplete combustion, which in turn is caused by non-ideal conditions in the combustion chamber. Catalytic converters minimize the harmful compounds by supporting the following Reactions 1 – 3 (Votsmeier et al., 2009).CO + ½ O2 ? CO2 (1)CnHm + (n + ¼ m) O2 ? n CO2 + ½ m H2O (2)2 NO + 2 CO ? N2 + 2 CO2 (3)Platinum and palladium are very effective for the oxidation (Reactions 1 and 2), while rhodium supports the decomposition of nitrogen oxides by carbon monoxide (Votsmeier et al., 2009). The classical three way catalyst was a platinum – rhodium combination with a Pt:Rh ratio of 5:1 (Hagelüken et al., 2005). Today the platinum, palladium and rhodium ratio is highly variable and strongly depends on the engine type as well as on the car producer. Diesel engines are operated with a super stoichiometric air addition in comparison to spark ignition systems. Therefore the exhaust gas composition and off gas temperature is different. Based on the high oxygen amount, diesel engines produce less carbon monoxide and hydrocarbons but more nitrogen oxide in contrast to gasoline engines. This leads to various requirements for the catalytic converters."

Jan 1, 2012

By D. Bois, P. Keating, J. Lemieux, M. A. Vallée, M. Allard, R. S. Smith, L. Z. Cheng, M. Chouteau, D. K. Fountain

"Abstract -A test survey using the MEGATEMII airborne electromagnetic system was flown over the Iso and New Insco massive sulfide orebodies in the Rouyn-Noranda mining camp, Canada. The results were compared with data from historical systems (INPUT, DIGHEM) used to discover the deposits. The historical data show that the two deposits have comparable conductances. However, the modern MEGATEMII system reveals that the New Insco deposit has a much slower decay than the Iso deposit, and it is, therefore, interpreted to be more conductive. The MEGATEMII anomaly maps provide estimates of the location, depth, dip, and strike of the two deposits, information that was not available from the historical anomaly maps. The signal-to-noise ratio of the MEGATEMII data is greater than the historical data, yielding more sharply defined anomalies. The investigations also included a comparison between 90 Hz and 30 Hz MEGATEMII data. The 90 Hz data were found to be useful for mapping the less conductive parts of the Iso body, whereas the 30 Hz data demonstrated that the New Insco body is more conductive. Analysis of height attenuation data over the Iso body indicates that the body could be seen by the MEGATEMII system if it were buried an additional 230 m deeper (in highly resistive material). On the other hand, the INPUT system would detect the Iso body only if it were buried no deeper than an additional 60 m. Tests with the transmitter turned off showed that, for this flight, the MEGATEMII system noise levels on the processed data are about 300 pT/s. Sommaire - Dans le cadre d’un projet de recherche, un ensemble de levés d’essais électromagnétiques aéroportés employant le système de MEGATEMII a été effectué au dessus des dépôts d’Iso et de New Insco, Rouyn-Noranda, Canada. Les données ont été comparées avec les réponses des systèmes qui ont découvert ces deux dépôts (INPUT et DIGHEM). Les données antérieures montrent que le dépôt d’Iso a une conductance comparable à celle de New Insco. Cependant, les données de MEGATEMII démontrent que le dépôt de New Insco a une haute valeur de la constante de décroissance, ce qui reflète une plus forte conductivité. La carte d’anomalies de MEGATEMII indique la localisation, la profondeur, le pendage et l’orientation des deux dépôts, ce que la carte d’anomalies antérieure ne montrait pas. Le rapport de signal à bruit de MEGATEMII est plus grand que celui des données de INPUT et de DIGHEM; de plus, les pics sont mieux définis. Les tests ont également permis une comparaison entre les fréquences de base de 90 Hz et de 30 Hz. Les données de 90 Hz se sont montrées utiles pour cartographier la partie du dépôt Iso dont la conductivité est la plus faible, tandis que les données de 30 Hz montrent clairement que le dépôt de New Insco est plus conducteur. Les analyses de l’atténuation du signal avec la hauteur ont indiqué que le dépôt d’Iso pourrait être détecté par le système MEGATEMII s’il était enfoui à 230 m sous la surface (dans un milieu hautement résistant). D’autre part, le système INPUT pourrait seulement détecter le dépôt d’Iso s’l était situé à 60 m de profondeur. Les tests avec l’émetteur fermé démontrent que le niveau de bruit est des l’ordre de ±300 pT/s."

Jan 1, 2006

By D D. Deacon

A brief description is given of the requirements which No. 4 Shaft has been designed to meet and of the methods by which two-stage winding of rock has been accommodated in a single shaft sunk to a depth of 7,421 ft. This is followed by a consideration of the factors which led to the decision to sink the shaft as rapidly as possible. Introduction T HE No. 4 Shaft of Hartebeest-fontein Gold Mining Company, Ltd., has been sited to serve the deep southern area of the mine, some 1,500 claims in extent, between the elevations of 6,250 and 7,300 ft. below surface. From this area, some two-thirds of the mine production will ultimately be obtained. Above the 6,-250-ft. elevation, an existing shaft hoisting system, situated adjacent to the reduction plant, is of adequate capacity to cater for all ore hoisted to surface for milling. No. 4 Shaft will therefore be required to provide downcast ventilation of 1,000,000 c.f.m., together with surface hoisting facilities for men, material and development rock and underground hoisting

Jan 1, 1965

By J. Stiksma, R. Kalanchey, M. J. Collins, G. Owusu, R. Raudsepp, K. R. Buban, L. A. Barta, L. Masters

This paper describes the results of testwork for the treatment of Ambatovy laterite by an acid pressure leach process, with recovery of the soluble nickel and cobalt values as mixed sulphide intermediate by precipitation with hydrogen sulphide, and subsequent refining of the mixed sulphide to nickel and cobalt metals. These process development studies were carried out primarily in 2004, as part of a bankable feasibility study for the Ambatovy Nickel Project.

Jan 1, 2004

By Jun Xiao, Xiaodong Li, Chunming He, Daixiong Chen

"Benzohydroxamic acid with double dentate can react with copper to form cyclic hydroxyl oxime acid copper chelate, indicating a good selectivity for copper oxide minerals flotation, especially for malachite. The flotation results of the pure malachite mineral show a strong synergistic collecting effect between hydroximic acid and xanthate at a ratio of 3.5:1, achieving a malachite recovery of 95.5% when certain sodium sulphide is used as a sulphidizing agent in the optimal pH range. Thanks to the synergistic collecting effect, the flotation recovery of malachite of a real refractory ore flotation ,can reach over 92% under the optimum condition, a 12% higher than the recovery achieved with the conventional collectors. In industrial application, the flotation of the copper oxide minerals is improved , leading to a high efficiency utilization of copper oxide resources.INTRODUCTIONBeneficiation of copper oxide ore is one of the recognized challenges in mineral processing industry. Copper oxide ore is a vital component of copper resource in the world, which has abundant reserves. Majority of sulphide deposits has oxidized zone on the top, and some deposits are oxidized to become the large and medium-sized oxide deposits (Willam & Chavez, 2001). Most copper oxide ores have problems in processing such as high slime consumption, poor floatability, complex ore property and low flotation recovery, so it is of great significance in beneficiation of copper oxide ores to develop an efficient collector, especially for malachite (Fu & Gu, 1997; Wen, 2010; Riet, Kier & Elford, 1980). At present, sulphidization-xanthate flotation is the most important method for treating copper oxide ore. In recent years, due to the decreasing ore grade, the utilization of refractory copper oxide ore draws more and more attention (Zhou, 2003), except for sulphidization-xanthate method, chelating flotation method (Lu, 2009), chemical beneficiation method (Lenormed, Salman & Yoon, 1979), microwave radiation flotation method, hydrothermal sulphidization-flotation method (Mao, Wen & Fang, 2014) and ammonia leaching of sulphide precipitation-flotation method (Lekang, Stevik & Bomo, 2003) have occurred."

Jan 1, 2016

By E. Gallestey, D. Groenveld, F. Kolb, M. Rozou

"Recent copper price evolution pushes modern mining industry even harder to achieve highest production with maximum efficiency. Operations are bound by numerous contractual and environmental conditions that bring a high degree of complexity to both the operators controlling the process and the plant managers assessing the circuit’s potential and setting the production goals.Advanced process control (APC) for grinding is one important tool to operate this most energy intense area in an optimal way, finding the optimal trade-offs between highest throughput, energy efficiency and product quality based on variable ore properties, production targets and management priorities.ABB’s state of the art control and optimization software platform enables user to design a controller based on model predictive control (MPC). The paper and the presentation show the technology used and the results achieved through an APC controller installed in a pilot project in Aitik (Boliden SA), Sweden. Furthermore, possibilities to interconnect grinding with other areas as stockpile management and flotation with various interconnected APC controllers will be shown. Finally, an example of the return on investment and the payback times based on the increased throughput and better product quality will be presented.INTRODUCTIONDepending on the ore characteristics and the targeted plant capacity, the design of the grinding circuit may vary significantly. Typically, the circuit consists of several mills (rod, ball, SAG, AG) in series and/or parallel with a number of classifiers and sumps at appropriate locations (see Figure 1).The main goal of the grinding section is to reduce the ore particle size to a level that enables efficient separation between gangue and precious metals in the subsiding processing step. The trade-off between quality and quantity has to be made. At the same time, it is also crucial to execute this process at the lowest possible energy and grinding media consumption."

Jan 1, 2015

By J. T. Birkholzer, M. Rutenberg, K. -H. Lux, R. Wolters, J. Rutqvist, L. Blanco Martin

In this paper, we present numerical results corresponding to the Thermal Simulation for Drift Emplacement (TSDE) test, conducted in the Asse salt mine (Germany) between 1990 and 1999 to simulate reference repository conditions for spent nuclear fuel in rock salt. This test is of significant relevance for nuclear waste disposal in salt because extensive research and measurement programs were set up for the experiment. In our numerical study, we use two sequential simulators, TOUGH-FLAC and FLAC-TOUGH, and we investigate two-way coupled processes, focusing on thermo-mechanical analyses due to the main effect of heating. The two simulators used have recently been updated and are able to deal with large strains and creep processes. Moreover, specific constitutive relationships and coupling functions for rock salt and crushed salt under repository conditions are available. Within the framework of a benchmark exercise between Lawrence Berkeley National Laboratory and Clausthal University of Technology, the same scenario has been modeled in three dimensions using the two simulators mentioned. The main objective of the current, first stage of the benchmark is to evaluate the capabilities of these two simulators to predict relevant processes under repository conditions for high-level nuclear waste in saliniferous media. The comparison of the numerical predictions between them is very satisfactory, leading to a successful code-to-code verification. The comparison between measurements and numerical results shows that the most important processes are captured by the codes and constitutive models used. However, some differences exist between measurements and numerical results. These differences will be addressed in the next stage of the benchmark exercise, in which a parameter fitting effort will be undertaken. Overall, from the results obtained it can be concluded that TOUGH-FLAC and FLAC-TOUGH have the necessary capabilities to reproduce relevant processes under repository conditions for high-level nuclear waste in saliniferous formations.

Jan 1, 2015

By Terry Braden

"Meeting probable world mineral demand in the years ahead will almost certainly require an ability to economically treat lower grade and more complex ores. Achieving this will require extensive research and technical development across the full spectrum of mineral processing.For mid-sized or smaller companies the most effective way to participate in such extensive programs - and gain access to the technology required to stay competitive - may be through collaborative research.This paper explores the recent history of collaborative research in mineral processing and in particular its ability to attract world-class multi-institutional research teams with sufficient resources to make step-change advances. It chronicles the advances achieved, but also explores the research architecture and administrative structures required to deliver research outcomes and technology transfer mechanisms to a range of often disparate sponsoring companies.INTRODUCTIONIn medieval times the dream of alchemists was to turn base metals into gold. We modern alchemists, of course, don’t waste our time on that sort of foolishness: we turn base metals into dollars. When I see the profit reports filed by some companies recently, I can only conclude that a lot of those present today must be pretty good at this.But the fact that we are here at this conference reminds us that an alchemist’s work is never done; turning base metals into dollars is not a one-trick wonder but an art that we must extensively refine year after year if we are to survive in a competitive marketplace.It is not that demand for metals is likely to slow; most people seem to think that China, India, Brazil and other emerging economies are still at the lower end of their demand curve. They will need significantly larger volumes of metals in the years ahead. The challenge for us as processors is that to supply increasing tonnages of those metals profitably we will almost certainly need to process more complex or lower grade ores and probably to do so with reduced energy inputs."

Jan 1, 2009

By Alfred Guenkel, Kyle Marte, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985 (Borbely, Devuyst, Ettel, Mosoiu & Schitka, 1985). Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. Though it is possible to supply sulphur dioxide (SO2) in either gas or liquid form, the majority of these SO2/air operations use sulphite-based salts as the ‘SO2’ equivalent reducing agent. This is probably due to the lower capital cost, safety concerns with, and availability of liquid SO2. Sodium metabisulphite (SMBS) is commonly employed, and its cost is an order of magnitude higher than that of sulphur. The increased capital expenditures (CAPEX) for a sulphur-burning SO2 gas plant could have a pay-back of less than two years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas inventory. Furthermore, a SO2 gas plant will not trigger the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and Boleo).This paper discusses the different processes which require SO2 as a reducing agent and compares the capital and operational costs of a SO2 gas plant to conventional process alternatives using sulphite-based salts or liquid SO2.The heart of the SO2 gas plant is the sulphur furnace. The most economical way to produce SO2 is by combustion of sulphur in air producing up to 19.5 vol% SO2. Examples of large and small sulphur furnaces are discussed in terms of design, operation, and impacts on operational costs.The SO2 gas produced in a sulphur-burning plant has to be contacted with the liquor to be reduced. The choice of gas-liquid contacting device is important, and two contacting devices are discussed: 1) Gas sparging into the bottom of leach tanks (high, nearly constant, back pressure due to liquid head) and 2) absorption columns (low gas-side pressure drop)."

Jan 1, 2014

By F. J. Hrach, K. P. Flynn, P. J. Miranda

"ST Equipment & Technology, LLC (STET) has developed a processing system based on tribo-electrostatic belt separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to other electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the triboelectric belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (300 µm) particles with very high throughput. The high efficiency multi-stage separation through internal charging/recharging and recycle results in far superior separations that can be achieved with a conventional single-stage free-fall tribo-electrostatic separator. The triboelectric belt separator technology has been used to separate a wide range of materials including mixtures of glassy aluminosilicates/carbon, calcite/quartz, talc/magnesite, and barite/quartz. Separation results are presented for selected industrial mineral sources. An economic comparison of using the tribo-electrostatic belt separation versus conventional flotation for barite / quartz separation illustrates the advantages of dry processing for minerals.INTRODUCTIONThe lack of access to fresh water is becoming a major factor affecting the feasibility of mining projects around the world. According to Hubert Fleming, former global director for Hatch Water, “Of all the mining projects in the world that have either been stopped or slowed down over the past year, it has been, in almost 100% of the cases, a result of water, either directly or indirectly” (Blin et al., 2013). Dry mineral processing methods offer a solution to this looming problem."

Jan 1, 2016

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

"Previous studies on the effect of polytetrafluoroethylene addition during chalcopyrite leaching under conditions similar to those of the CESL process have reportedly resulted in complete leaching of the copper without the need for grinding of the flotation concentrate. However, these studies employed a pulp density of only 1% and finely sized PTFE particle that required the use of high impeller rotation rates that are not sustainable at an industrial scale. This paper explores the performance of 1/8” diameter balls of PTFE, that readily sink in the leach solution, on leaching performance at impeller rotation rates and ore pulp densities more typical of industrial practice. Possible routes for separation of the PTFE from the leach residues and their regeneration for recycling back to the leaching stage are also discussed.INTRODUCTIONChalcopyrite, CuFeS2, is the most important primary sulfide source of copper. While pyrometallurgical smelting of chalcopyrite remains the only widely accepted route for treating chalcopyrite concentrates, several medium temperature pressure oxidation processes are claimed to be economically feasible (Muir & McDonald, 2007). Among these, the CESL process has been extensively piloted and demonstrated at the prototype scale. The overall process chemistry of the CESL process may be summarized as follows (Marsden & Wilmot, 2007):4CuFeS2 + 5O2 + 4H2SO4 ? 4Cu2+ + 4SO4 2- + 2Fe2O3 + 8S0 + 4H2O (1)4CuFeS2 + 17O2 + 2H2SO4 ? 4Cu2+ + 10SO4 2- + 4Fe3+ + 2H2O (2)Though copper extractions of over 95 % are achieved, the CESL process requires extra grinding of the concentrate (Muir & McDonald, 2007). This is because leaching is conducted at temperatures around 150 °C, where the elemental sulfur produced is molten and grows thicker on the mineral’s surfaces as oxidation progresses, creating an increasingly large barrier for mass transport. In addition, the sulfur is sticky and tends to cause the mineral particles to agglomerate, effectively halting further oxidation of the particles that end up embedded within the agglomerates. Consumable surfactants, such as ligin sulfonate, have been shown to be effective at avoiding agglomeration, but they are not effective at removing sulfur from the minerals. Hence, their use does not obviate the need for fine grinding."

Jan 1, 2012

By X. Wu

Tunnel Boring Machines (TBMs) are widely used for tunneling in urban areas because of their high advance rate, precise as-built profile and minimal impact to buildings and traffic on the ground. For a tunnel built by a TBM, there are strict requirements on alignment control and safety. To meet these requirements, it is important to monitor the position of the TBM. In the current practice, the TBM position data, including advance distance and line and level deviations, are reported manually to the managers on a daily basis. To interpret and analyze the position data, the managers also need to refer to various construction drawings. This practice is untimely, inefficient, and error prone for decision making. To improve the current practice, an automatic approach for real-time as-built tunnel product modeling and visualization is proposed, based on TBM position and orientation data autonomously sourced from the Virtual Laser Target Board (VLTB) TBM Guidance System developed at University of Alberta. Related information of the tunnel project, such as the as-designed alignment, soil layers, the ground, existing utility lines, is also visualized together with the model of the as-built tunnel. The modeling algorithm is presented step by step. Its application in a real-life drainage tunnel project is discussed and limitations are also identified.

Aug 1, 2013

By K. Sun

The exothermic behavior of the intermetallic reactions inside an Al-Mn metallic powder compact and its assimilation fundamentals in molten aluminum were examined. In this study cylindrical compacts were manufactured and tested. The experimental work involved simultaneous temperature measurements of three thermocouples as well as detection of the apparent weight of the cylindrical specimen during its assimilation in liquid aluminum. The details of the intermetallic reactions prior to the compact complete disintegration were investigated by microscopically studying the morphology and local composition in a partially reacted compact. The variation of manganese concentration in the melt was determined by chemically analyzing the samples taken from the molten aluminum at specific time intervals. The exothermic reaction increases the compact&apos;s temperature above that of the liquid aluminum. In tandem with this exothermic reaction, the compact is suffering a swelling action. This swelling action disintegrates the cylindrical specimen, which is assimilated into the liquid aluminum. The intermetallic reactions proceed in a stepwise manner. Both the bath temperature and the compact composition impact on the exothermicity of the intermetallic reactions. However, when the amount of Mn in the compact is greater than 75-wt%, the maximum centerline temperature rise is slightly reduced as Mn amount increases.

Jan 1, 2004

By P. Leo

The Al-Zn-Mg alloys (e.g. 7004, 7020) are employed for land transport and architectural applications whereas the Al-Zn-Mg-Cu alloys (e.g. 7075, 7050) provide the high strength aircraft alloys. The Cu gives rise to suitably sized and distributed precipitation but causes high quench sensitivity. Their hot work processing also has marked differences; the Cu-free alloys have good extrudability whereas the Cu-bearing alloys have low extrudability and are difficult in rolling as well. The behaviors of the two classes are described in terms of flow stresses and ductility over 300 - 500°C, along with constitutive contrasts. The ductility of the alloys with Cu is much reduced above 400°C by precipitation of a phase at the grain boundaries that can be avoided by suitable heating schedules. The high strength alloys are subject to de-lamination corrosion of sheared edges due to severely pancaked grains; this can be alleviated by holding between passes, in mid-rolling schedule. In torsion tests at 10-1 to 10 s-1/ 250 - 500°C, the stresses (ductilities) at 300°C/ 1s-1 and activation energy Q for 7004 were 118 MPa (2) and 262 kJ/mol. The 7075 was tested after several pretreatments: completely over-aged (softened): 107 MPa (5), Q=150 kJ/mol; whereas, solution and quick cooling to testing caused extraordinarily high peaks related to dynamic precipitation resulting in 160 MPa (1.2), Q=300 kJ/mol.

Jan 1, 2011

By B. G. Cousins, L. Racine, R. S. MacPhail

"FLEX 31 is a chemically enhanced sodium isopropyl xanthate that has shown improved collection properties over SIPX for copper-bearing and copper-activated minerals. Characteristics such as improvement of recoveries with lower dosages and high pyrite and pyrrhotite rejection capabilities have all been exhibited by FLEX 31.The most improved results have been seen insphalerite flotation. Plant trial work carried out in the zinc circuit at the Louvicourt Concentratorin northern Quebec has produced data showing superior grade and recoveries from rougher concentrates that previously had not been attain-able with other reagents effectively. The improvement over SIPX adds up to an almost$1,000,000 annual improvement on the mine’s bottom line at present zinc prices.IntroductionSodium Isopropyl Xanthate (SIPX) is one of the most popular flotation chemicals on the market today. Somewhat more specific than amyl xanthates, SIPX is used in a variety of ores like copper/zinc, lead/zinc, arsenopyrite/pyrite, and many others (Melis et al., 1991). An investigation carried out by Tennants Research Technology Applications (TRTA), a division of Charles Tennant & Co. (Canada) Ltd., produced a chemically enhanced SIPX that has shown all the advantages of normal SIPX along with improved recoveries of copper and copper activated minerals. The new product has been named FLEX 31. Currently, FLEX 31 is manufactured at the Prospec Chemicals, another division of Charles Tennant & Co. (Canada) Ltd.A large amount of laboratory testing pro-grams have been carried out with FLEX 31 todate (MacPhail and Cousins, 1995; Cousins and MacPhail, 1996). One of the minerals that has a defnite affinity to improved fotation is sphalerite (ZnS). Once activated with copper sulphate, sphalerite has produced some of the most spectacular test work when FLEX 31 is compared directly to SIPX. Plant trials of FLEX31 at Aur Louvicourt Inc. carried out in 1995show that FLEX 31 is far superior to SIPX for activated sphalerite flotation."

Jan 1, 1997

"The successful commissioning and ramp up of the Albion Process™ at the GPM Gold Project relied on the successful scaling up of the process from batch and continuous pilot plant campaigns (Voigt et al., 2015). Critical information about reaction kinetics and residence time, grind size and pulp density were determined at the laboratory scale and successfully applied to the commercial scale. A limitation of small scale testwork, is that some parameters cannot be measured reliably and scaling up is a function of the physical size of the equipment which isn’t possible to test with laboratory scale equipment. Oxygen mass transfer rate is one such parameter since this is a complex interaction of many factors including slurry temperature, solution and slurry chemistry, slurry viscosity, agitator type, dimensions and power, oxygen bubble residence time, oxygen purity, tank geometry and oxygen injection technique. Oxygen generation represents an important operating cost for the Albion Process™. Pivotal to the Albion Process™ operating economically at atmospheric pressure is the capability to efficiently transfer oxygen while utilising as much oxygen injected to the process as possible. To respond to this Glencore Technology developed the HyperSpargeTM supersonic gas injector. This paper compares the HyperSparge™ against other sparging techniques to quantify the benefits of oxygen injection via a supersonic gas jet on scale up of the oxygen mass transfer system. The paper then examines plant survey data from the GPM Gold Project to demonstrate the very high oxygen utilisation that can be achieved with a correctly designed oxygen mass transfer system.INTRODUCTION One of the main challenges in chemical reactor design is the scale-up of processes from the laboratory to industrial scale. Processes which cannot be faithfully simulated with an experiment at the laboratory scale face challenges due to the physical dimensions and complexity of full scale operation. One example of this is the design of oxygen mass transfer systems in atmospheric oxidative leaching circuits such as the Albion Process™. A number of constraints associated with the use of laboratory scale equipment to design full scale circuits are involved in gas mass transfer processes in agitated slurries such as the Albion Process. Chiefly, typical laboratory and pilot size equipment lacks the required volume to provide useful design data without relying on empirical correlations: the specific agitator power input is artificially high, the bubble residence time in the vessel is artificially low, the oxygen partial pressure at the base of the vessel is artificially low and the oxygen delivery method may differ significantly to the industrial process. Further, the dynamic nature of the process introduces additional impacts on gas mass transfer, including the presence of solids, recycle streams and minor elements, plus the variances within the reality of a process plant such as disruptions or variance of feed quality."

Jan 1, 2017

By E. Engelbrecht

"A pressure non-oxidative leach is employed at Anglo American Platinum Base Metal Refiners to extract nickel from a slow cooled matte. The design base requires two 80 m3 autoclaves in parallel to achieve a nickel extraction of 60% at the nameplate capacity of 32.4 ktpa nickel plated. Isothermal modelling of mineralogical and chemical concentration profiles, through a reactive mass balance, permitted rate constant parameter estimation and selection of the most probable reaction pathway. The model was validated with plant data up to a capacity of 26 ktpa Ni plated and suggested by extrapolation that nameplate capacity may be viable through one 80 m3 autoclave.INTRODUCTION Anglo American Platinum Base Metal Refiners is situated on the outskirts of Rustenburg in the North-West province of South-Africa. The refinery produces nickel cathode, copper cathode, cobalt sulphate powder, covellite rich copper pressure leach residue and bulk sodium sulphate through an integrated circuit that refines slow cooled converter matte. The converter matte is milled, non-magnetics are separated as solid nickel copper matte (NCM), and the magnetics are leached yielding a pressure vessel liquor (PVL). The remaining solid platinum group metals (PGM) concentrate after leaching is sent for downstream processing in the Precious Metals Refinery (Hofirek & Kerfoot, 1992). The work presented here is applicable to the base metals refinery which receives the two base metals feed stocks NCM and PVL. In 2009 the capacity of the refinery was upgraded from 21 ktpa nickel cathode plated to 32.4 ktpa. This paper deals with evaluating the capacity of the pressurised non-oxidative nickel leach (NOX) process which accounts for at least 28% of the nickel leached from NCM by design. The NOX design base requires two 80 m3 autoclaves divided into four compartments operated in parallel at 155°C and 600kPa(g). Elevated temperature is required to speed up the leach kinetics of particularly nickel and iron which are trapped in slow leaching mineralogical phases namely millerite and bornite, (Dinham, 2006). The stated equivalent capacity for the NOX configuration was 32.9 ktpa nickel plated at first pass nickel and iron leach efficiencies of 60% and above 80% respectively and is a key step for the selective removal of iron (Bryson, Hofirek, Collins, Stiksma, & Bereaowsky, 2008)."

Jan 1, 2017

By Brian Danyliw

"Dust control is an increasingly important consideration for all mining operations from a health, safety, environmental and maintenance perspective. Modern mining operations incorporate a variety of mechanical dust control techniques into design however in many cases these engineered systems are unable to meet desired fugitive dust level targets. In these cases a variety of chemical dust suppression options are available to operators to assist in meeting their targets. This paper provides an overview of available chemistries, discussion of application techniques and equipment requirements and available performance monitoring technologies. This paper will also include a number of case histories discussing the treatment approach chosen, challenges encountered, chemical feed, storage and application equipment, monitoring techniques employed and results achieved.INTRODUCTIONDust FundamentalsFugitive dust by definition is an aerosol consisting of particulate matter suspended in a gaseous medium. Aerosols can include suspensions of particulate (solids) or sprays (liquids) or a mixture of both. Of particular concern from an occupational health and safety perspective are aerosols of particulate matter due to their involvement in classical occupations lung diseases such as silicosis, poisoning through chronic exposure to compounds such as lead and beryllium and expected involvement in more modern identified conditions such as cancer, asthma, and a host of other respiratory and non-respiratory conditions which may be caused or influenced through exposure to dust.According to the ""Glossary of Atmospheric Chemistry Terms"" (IUPAC, 1990), ""Dust: Small, dry, solid particles projected into the air by natural forces, such as wind, volcanic eruption, and by mechanical or man-made processes such as crushing, grinding, milling, drilling, demolition, shoveling, conveying, screening, bagging, and sweeping. Dust particles are usually in the size range from about 1 to 100 µm in diameter, and they settle slowly under the influence of gravity."" It should be noted that the behavior of particulates with respect to settling rate in air is a function of particle mass and shape and therefore the geometric size of the particle can be misleading. Occupational hygienists utilize the concept of particle aerodynamic diameter as a more representative reflection of particle size. Particle aerodynamic diameter, is defined as ""the diameter of a hypothetical sphere of density 1 g/cm3 having the same terminal settling velocity in calm air as the particle in question, regardless of its geometric size, shape and true density."" The expression of particle size as aerodynamic diameter allows for a more consistent understanding of particle behavior both from a settling perspective as well as from the perspective of how dust particles will behave in the respiratory tract. Figure 1 illustrates settling rates for particles of various aerodynamic diameters. The relationship between particle size and settling rate is important for understanding what size of particles must be addressed by dust control strategies as well as what particle sizes represent the most danger from an exposure and occupational health perspective."

Jan 1, 2015

By P. Karimi, G. Mollataheri, A. Amini, H. Abdollahi, A. Mirzaeian

"Chah-Palang tungsten deposit is one of the two tungsten indexes in Iran. Based on ore characterization techniques (including optical mineralogy and XRD analysis), quartz, chlorite, atacamite, azurite, malachite, ferberite, illite, goethite and calcite were distinguished as major minerals. The representative sample was analyzed qualitatively by using X-ray fluorescence and chemical assay. Results showed that grade of tungsten oxide and copper were 1.76 and 7%, respectively. Also precious metals such as gold with grade of 1 ppm was reported in the sample. By using the mineralogical studies on the prepared sample, the liberation degree of tungsten minerals in –0.6 mm size fraction was obtained 80%. Several tabling tests were carried out on the original sample which at the optimum conditions and as a result, the grade and recovery of tungsten in concentrate reached to proximately 23 and 59%, respectively. To increase the grade of tungsten in the final concentrate, acidic leaching were performed on the tabling concentrate and its appropriate results indicated that the grade of tungsten increased to 27%. Also more than 90% of copper was extracted as a byproduct in the fallowed process.INTRODUCTIONTungsten, a unique hard, heavy heat-resistant metal, is distributed erratically in economic concentrations throughout most continents, occurring mostly as small irregular deposits that are not readily adaptable to large-scale, low-cost mining methods. The diverse physical characteristics and mineral composition of tungsten ores also present problems in beneficiation, requiring complex hydro- and pyrometallurgical treatment to yield high-purity concentrates suitable for the production of ferro alloys, carbides and super alloys in the steel industry (Hausen, 1989; Kholmogorov & Kononova, 2005). Tungsten is most frequently used as tungsten monocarbide, which has hardness close to diamond, in cemented carbides. The most well-known use of tungsten is in lighting filaments, and other important applications include improving steel properties and use in tungsten alloys, electronics, and chemical products (Hausen, 1989; Kholmogorov & Kononova, 2005)."

Jan 1, 2016