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By S. Banisi, M. Poorkani, M. Farzaneh, M. Askari

"At the Sarcheshmeh copper mine 40,000 t of ore per day with an average grade of 0.9 % Cu is ground to 70% passing 75 microns. Grinding is effected in 8 parallel lines of 8 x 5 m ball mills in a closed circuit with cyclones. The make-up balls are 80-mm forged alloy steel balls and the average ball consumption is 750 gh of ore ground. In order to optimize ball size distribution inside the mill, based on the previous investigation instead of using only 80 mm make-up balls a combination of 80 and 60 mm (75% to 25% by weight) ball charge was used in one of the mills. To evaluate the performance of three ball types namely forged alloy steel balls (A), ductile cast iron (C), high chromium cast iron (D) and also a combined (80 and 60 mm) charge of forged alloy steel balls (B), four identical parallel mills were charged accordingly. These four mills were sampled during a period of six months. The amount of material finer than 75 microns of cyclone overflows was selected as a criterion for the performance evaluation. It was observed that in a mill with the combined make-up balls the amount of fine produced was 4% higher than the other mills. The consumption of ball types A, C and D were 730, 710 and 534 g/t, respectively. The results of laboratory flotation tests showed that due to an improvement in the production of fines an increase of 1.4% in the overall copper recovery is obtainable. Due to the promising results, the new make-up ball regime was implemented in all mills in the plant.INTRODUCTIONThe Sarcheshmeh copper ore body which may rank as third or fourth largest in the world contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybednite concentrate per year. After three stages of crushing, the ore with a F80 of 12.7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70% finer than 75 microns. The concentrate of the first stage of flotation is reground and the tailing constitutes the main component of the plant final tailings. A concentrate with an average grade of 31% Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type."

Jan 1, 2002

By J. H. Shillabeer

"Rational exploration requires the prior selection of areas possessing excellent geological potential and minimum hazards to commercial development . Within an over-all strategy of grass-roots exploration, two procedures for selecting areas for (i) coal and (ii) metals exploration are described. The procedures explicitly balance infrastructure requirements and environmental concerns for areas of geological merit not alienated in parks and reserves. Through consensus, priorities are attached to those areas meriting closer scrutiny and field reconnaissance.IntroductionMining companies need to know that having made a potentially economic discovery, they will be allowed to develop it with minimum delay and at reasonable cost. The environment for exploration in British Columbia is complex and recent experience suggests that conditions are not becoming any easier. Conflicts over land use issues, preservation and economic development are common. The high cost of exploration requires that the risks should be offset where possible by: (i) carefully selecting the areas in which to work (ii) conducting operations in a responsible manner, and (iii) working cooperatively with the community of interests. This paper concerns the first action: prior selection of areas.To aid exploration planning at Suncor, a procedure was developed to grade those areas of the province possessing favourable geology according to the ease with which a mine might be developed . This had to be done within the constraints of the company's over-all approach to exploration. This emphasizes ""grass-roots"" exploration of self-generated projects in British Columbia. In addition, having selected a favourable belt of rocks, it is intended to persevere there while steadily adding to the accumulated data base and local experience. Hence, it is intended to concentrate on an area. This implies a long-term commitment to an area which in turn increases the importance of the original selection.Suncor's search is directed to finding base and precious metals in intrusive and volcanic environments, and export quality coal."

Jan 1, 1985

By Akiyoshi Horiuchi, Manabu Kanno, Shigeki Sato, Taro Aichi

"AKITA ZINC Co., Ltd. (Iijima Zinc Refinery), jointly owned by DOWA METALS & MINING Co., Ltd.(DMM), has used the company’s own hematite process for iron control since the beginning of operations in 1971. The hematite process consists of reductive leaching with SO2 gas and iron removal in autoclaves by high temperature hydrolysis. This process enhances not only zinc recovery but also the recovery of gold, silver, copper, lead and rare metals, which is carried out at another DOWA metallurgical plant. All by-products produced in the hematite process are marketed and sold. This paper presents an overview of the hematite process and the recent process improvements made.INTRODUCTION DMM carries out mining and smelting activities for precious metals, PGMs, rare metals and base metals such as copper, lead and zinc. It owns KOSAKA SMELTING & REFINING, producing copper and lead, and the AKITA ZINC Co., Ltd. (AZC) in Akita Prefecture. DOWA is a specialized smelting company which has established a metallurgical complex for copper, lead and zinc, including a recycling business. AZC was established in 1971 at a production capacity of 72,000 t/y zinc; it is jointly owned by DMM and five other non-ferrous metal companies. AZC has increased its capacity continuously and now produces 210,000 t/y of zinc. Figure 1 shows the changes in zinc production and capacity at AZC."

Jan 1, 2016

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By Bevan. P. A.

The general location, topography and climate are discussed briefly, together with an historical record of the deposit. General geology, grade control and ore reserves are covered at some length, and reasons are given for the operation being placed on a salvage basis.

Jan 1, 1973

Slurry flow, including flow through the charge, through the discharge grates, along the pulp lifters and its discharge from the mill is an important contributor to the efficiency of the grinding process within a SAG mill. Poor transport of finer ground material can adversely affect grinding leading to excess energy consumption and over-grinding of fine material. This paper extends a 1-way coupled DEM-SPH method to three dimensions and applies it to a 1.8 m diameter by 0.6 m long AG/SAG pilot mill. This provides detailed information on the internal flow of slurry within a SAG mill, including the prediction of dry regions and of slurry pooling. Full 3D analysis also allows the pulp flow patterns into and out of the mill via pulp lifter chamber to be investigated.

Jan 1, 2012

By M. Lundström

The Outotec HydroCopper® process is a novel technology, developed and registered by Outotec Technology Oy, for leaching copper from chalcopyrite using cupric chloride solution. The leaching process is operated at atmospheric pressure in a stirred tank reactor, at temperatures near the boiling point of water and pH values between 1.5 and 2.5. During the leaching of chalcopyrite in cupric chloride solution, a reaction product layer forms on the mineral surface. In the present work, the formation and the composition of the reaction product layer was studied in an environment similar to that of the HydroCopper® process. The effect of the process parameters on the reaction product layer was investigated. Electrochemical measurements, including A.C. impedance spectroscopy and microscopic observations were carried out and an equivalent circuit was used to determine the surface parameters, such as the reaction product layer capacitance and the charge transfer resistance. The results suggest that, at low pH, a passivating sulfur-rich layer forms, whereas at high pH, a more porous iron-rich layer was detected. The values measured can give useful information for optimising the leaching parameters of the HydroCopper® process. Cu2007

Jan 1, 2007

By Thomas H. Heine

"The Rabbit Lake uranium deposit is located at 58° 11’00”N.. 103°42'36""W., close to the west side of Wollaston Lake, and approximately 800 km north of Saskatoon. The orebody is hosted by Aphebian Wollaston Group rocks, initially deposited as a series of shallow-water marine sediments consisting, in part, of carbonates and possible saliferous petites. Metamorphism during the Hudsonian Orogeny, peaking at about 1850 Ma, recrystallized the sediments to upper amphibolite grade paragneisses. This was accompanied by partial anatexis. The waning stages of Hudsonian orogenesis appear to be marked by minor granitic intrusive activity.The post-Hudsonian period was marked by a long interval of physical and chemical erosion, resulting in the unroofing of the Wollaston metamorphic complex. The entire region underwent extensive lateritic weathering under tropical to subtropical conditions. Carbonates were especially vulnerable and, in the Rabbit Lake area, suffered extensive solutioning with accompanying formation of collapse breccias. Old zones of weakness also underwent periodic reactivation.It was during this period that uranium was leached from the surrounding meta-sediments by oxidizing meteoric waters, and transported into the karsted and fractured rocks of the Rabbit Lake doline.Athabasca Group sediments eventually covered the deposit, their diagenesis taking place at about 200 °C and 900 bars. This allowed the partial to complete recrystallization of the initial mineralization, resulting in a minimum age of 1281 ± 11 Major ""first""-generation pitchblende. Periodic fault/fracture reactivation modified the hydrologic regime within the deposit, resulting in episodic mobilization and recrystallization of pitchblende and other uraniferous species. This is clearly shown in the open pit at the present time: uranium is being mobilized and recrystallized on damp pit walls as bayleyite and liebigite due to the modification of the hydrologic system by mining activities.The uranium mineralization occurs mainly as fracture fillings, coatings, and impregnations within breccia zones and intensely altered metasediments. Lesser mineralization is intimately associated with phyllosilicates which form the matrix of a carbonate-col/apse mega-breccia. The primary ore mineral is pitchblende, consisting of five generations, and from which a large suite of secondary uraniferous minerals have formed. On a gross scale the metal content of this deposit appears to be simple, consisting almost exclusively of U, but minor Ni, As, Cu, Se, Fe and Co are also present. The eastern limit of the mineralization is defined by a vertically-dipping microgranite dyke - breccia complex, containing high-grade uranium values. The orebody is truncated to the west and at depth by the Rabbit Lake reverse fault. Minor mineralization occurs as fracture fillings in unaltered plagioclasite in the footwall of the ore body. Precipitation of uranium from solution could have taken place by a number of processes. A mobile reductant (methane, carbon dioxide, etc.) may have been generated from graphite present in some of the host rocks of the orebody. Sulphides are also a common accessory and may have aided in the formation of a reducing environment. Phyllosilicates may have acted as adsorbants for uranium, allowing for its fixation. This metal has also been incorporated into the phyllosilicates themselves."

Jan 1, 1986

By Gregg S. Hill, Bert J. Huls

"This paper on coarse particle recovery (CPR) summarizes a process to capture coarse particles that are not recoverable by regular flotation. Several porphyry copper operations in the world operate analogous circuits that recover non-floated copper from tailings; however, the case presented here is unique in that extensive underlying test work has allowed us to elucidate some fundamental principles behind recovery enhancement. This paper discusses an overview of the flow sheet that is proposed to Minera Escondida Ltda., the nature of copper in the feed to the CPR circuit, and the various unit operations within the recovery circuit. Details of the technology behind each unit operation will be presented in later publications.INTRODUCTIONSince 1996 BHPBilliton and MEL (Minera Escondida Ltda.) have developed a process to recover copper from coarse particles in the rougher tailings. Copper recovery from fresh tailings is not new. Several operations in Chile, such as Chuquicamata, El Teniente (AMEC, 2003), Mantos Blancos and others have operated various forms of tailings circuits. Both Chuquicamata and El Teniente practice cascade flotation scalping off froth containing fine copper particles after allowing sufficient retention time, air inducement and, sometimes, additional reagent addition. Chuquicamata tailings are not segregated but floated in sequential cascade and conventional large cell arrangements. At the Valle Central operation of El Teniente a coarse fraction of mill tailings is ground and floated, with the rejects recombined with fine tailings and subjected to cascade flotation through a sequence of concrete launders as the tailings flow towards their final deposition area. Mantos Blancos cyclone the rougher tailings and blend the underflow with scavenger concentrate from elsewhere in the principal circuit prior to flotation in Wemco Cells. Kemess in BC, Canada operates a 160 m3 Outokumpu cell to reduce the tailings sulfur content (Rasmussen, et.al, 2004)."

Jan 1, 2005

In several European countries, including Russia, it has become economically attractive to utilize peat as a fuel for power generation, the production of metallurgical coke, the production of fuel briquettes for the domestic market and low-Btu gas. Although the economic base and availability of energy supplies in Europe is much different than it is in Canada, regional economics here may warrant the development of peat as an alternative source of energy. Canadian peatlands cover several thousands of square miles and have historically been considered as waste land. Now, with the increasing costs of other energy sources, it is apparent that fuel peat should be re-evaluated as a potential energy resource. A nation-wide inventory of peat deposits has been prepared and reserves evaluated for some of these areas where field surveys have been carried out. The paper describes alternative mining methods developed to meet some of the various conditions encountered on virgin peatland . These mining techniques are generally based on current peat technology exercised in other parts of the world and would be applicable in some of the peat regions of Canada. Cost estimates have been prepared for peat production in regions of Canada, and the socio-economic aspects of a large-scale fuel peat operation are discussed. Several potential utilization schemes have been described, with particular emphasis on electric power generation. The paper makes recommendations for steps to be taken in the development of a fuel peat industry in Canada.

Jan 1, 1978

By J. Beland

The Rimouski-Matapedia region is along the southwestern extension of the central Siluro-Devonian synclinorium of Gaspe Peninsula. As in Gaspe about 30,000 feet of Siluro-Devonian strata rest on a "basement" of tightly folded Ordovician rocks. The central synclinorium is divided up into two northeasterly trending belts each of which is characterized by distinctive lithologies and patterns of folding. The northwestern belt is gently to moderately folded and includes lithologies which point to a stable environment. The southeastern belt on the other hand is tightly folded and the lithologies indicate a less stable environment. A marked angular unconformity separates the basement from the Siluro-Devonian cover near the north-western margin of the northwestern belt. At the southeastern margin of the southeastern belt the relationship of cover to basement has not been as-certained because of a fault. The northwestern belt has several features significant in the search for petroleum; the Silurian strata are exposed in broad open anticlines

Jan 1, 1962

By Thomas J. Ferree

"IntroductionThe objective of this chapter is to provide important criteria relating to the operation and maintenance of spiral concentrators and Reichert cones, so that optimum performance can be achieved and maintained in a mill circuit. Little space will be devoted to the theory of the forces of separation or the technical details of the devices, as that in(ormation is available from other sources. The discussions in this chapter will be presented in a manner that should be interesting and useful to anyone who may be exposed to these methods of gravity separation. It is most important for the reader to understand that each application of the equipment should be considered on its own merit, as no two suites of minerals respond exactly alike in mineral processing circuits. The information herein should be useful as a guide toward increasing the metallurgical efficiency of the processes, irrespective of the type of minerals being concentrated.It is highly recommended that certain tools be made available to the personnel responsible for metallurgical performance of the spirals and cones; these include a set of standard type laboratory screens, a medium quality petrographic microscope, and a vanning plaque or gold pan. These devices, when used in conjunction with a basic understanding of the mill circuit, provide immediate knowledge on the characteristics of any sample in the mill circuit. The information gained by visual evaluation of sized fractions of products can solve many of the basic problems of mineral beneficiation, and at the same time increase the interest of the non-technical personnel associated with the plant operation. There are many problems associated with obtaining satisfactory performance from a mill operation. Many of the problems have to be solved using a technical approach. Some of the problems, however, can be solved with practical knowledge and common sense. It is hoped this chapter can provide a guide to both techniques."

Jan 1, 1989

By B. R. MacKay

Introduction The Corbin coalfield is one of the smallest, and at the same time one of the principal, producing bituminous-coal areas in southeastern British Columbia, and is unique on account of the great original thickness of one of its coal seams and the remarkable concentration of coal in a small area that has occurred through intense folding and faulting of the measures. These are such that the deposit has been referred to at times as "the world's thickest coal seam" and as" a mountain of coal." The determination of the number, thickness, and character of the seams present, and the structure, extent, and geological relationship of the several deposits, are of vital interest both to the operating company in its endeavour to evolve the most efficient method of mining these exceptionally thick deposits and to the Government in estimating the coal resources of the different fields. With the object of ascertaining these data the writer was assigned in 1930 to geologically map and study the Corbin coal deposit. A topographic map covering Coal mountain and the immediate vicinity on a scale of 1 inch =800 feet, with a contour interval of 25 feet, made by the Topographic Division of the Geological Survey, served as the base for the geological mapping.

Jan 1, 1931

By M. Kamyab

The Deep Exploration Technology project, as part of the Australian Cooperative Research Centre, is developing technologies to drill deep boreholes for mineral exploration purposes. The aim of the initiative is to transfer drilling technologies from oil and gas into mining applications. Several modifications have to be pondered due to this technology exchange: smaller cuttings sizes because of using impregnated diamond bits; narrower annulus space; higher drilling fluid velocity and likelihood of turbulent flow regime in the annulus; and higher pressure loss. In particular the results of our lab experiments have shown that the increase in concentration of small size cuttings can significantly change the rheology of the mud when drilling in hard rocks. This, in return, could have a noticeable increase in the pressure loss encountered along the annulus space. As a continuation of the above study, numerical simulations were conducted to investigate the cuttings transport behaviour in small size annulus space. Fluid velocity, annulus size, cuttings concentration, cuttings density, and cuttings size were some of the parameters that were varied to see their effects on cuttings transportation and the pressure loss along the annulus space. The results indicate that, due to the differences between oil and gas and mining drilling, conventional oil well planning is not applicable for mineral exploration drilling and numerical simulation would help in this matter.

Aug 1, 2013

By A. G. Doll

The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less. This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference.

Jan 1, 2012

By Zorigtkhuu Davaanyam, Bern Klein, Stefan Nadolski, Amit Kumar

"The High Pressure Grinding Rolls (HPGR) is a relatively new comminution technology that has been shown to be more energy efficient compared to semi-autogeneous (SAG) mills. Full and fair consideration cannot be given to HPGR-based comminution circuits in early stage projects, because presently pilot scale testing is required for assessing and sizing; pilot scale testing requires bulk samples weighing more than one tonne. A CAMIRO research program was conducted at the University of British Columbia to develop bench scale tests that would reduce the quantity of sample required to assess HPGR.Three test procedures were developed.1. The Direct Calibration Methodology calibrates piston press test results to pilot scale test results such that piston press tests can then be used to determine the energy–size reduction relationship for a range of ore types.2. The Database Calibrated Methodology, which is similar to the Direct Calibration Methodology except that it calibrates piston press tests against a database of pilot scale and piston press tests.3. The Semi-Mechanistic Methodology was developed to use piston press test results as an input for an HPGR based energy-size reduction performance model.Through utilization of these methodologies, the energy–size reduction performance of an HPGR can be predicted with minimal sample requirement. In addition, piston press testing is far more cost effective, faster, and accessible than pilot-scale HPGR testing.IntroductionOne could argue that in the future, decisions regarding selection of comminution circuits will be made primarily on the basis of energy consumption. The following facts and predictions support the argument:"

Jan 1, 2015

By Eric Bain Wasmund, Lance Christodoulou, Julio Jairo Carmona Franco, María Fernanda Castillo, Jose Concha

"A number of technologies are in practice for selectively removing coarse gold from conventional grinding circuits. These circuits are often designed so that the grinding mill output is size classified, with large (or high density) particles being removed before the tails are returned to the mill. Because of the high relative SG of gold, and the fact that some forms of gold such as free gold do not break apart during conventional grinding, coarse gold can accumulate in the circulating load, and eventually be lost.Eriez has developed a flotation cell that uses fluidized water to enhance flotation of coarse particles. More than 40 units have been sold in industrial minerals, and we are now exploring applications for the HydroFloat® in the gold industry.Mineros S.A currently produces approximately 120,000 oz of gold per year by gravity concentrating alluvial gold ore with a mean particle size of 330 microns, followed by further concentration using a Falcon separator. A 400 mm diameter pilot-scale HydroFloat® was added to the tails of the Falcon to test whether additional gold could be captured. Enrichments of 50-600 times and recoveries normally in excess of 95% were achieved. This allowed direct smelting of the gold concentrate. Metallurgical results and operating parameters such as water addition and power will be discussed during the presentation.This result opens the possibility that the HydroFloat® could be used directly in the grinding circuit, for removing coarse gold in the circulating load. This work also shows the possibility that the HydroFloat® can produce a throwaway tail, which will reduce the size of the circulating load stream and the grinding requirements of the circuit."

Jan 1, 2015

By M. Kreuh

An investigation of the pressure pulse spectrum generated by the gas dispersion processes in a Peirce Smith copper converter was undertaken via the simultaneous measurement of four tuyeres using high frequency pressure transducers. The data was captured, stored, and analyzed using digital data processing techniques; including power spectral density plots, band-pass filtering, and a principal component analysis (PCA). The process was characterized throughout by a dominant 3 Hz pulse signature attributed to the formation of lateral gas envelopes. In particular, test tuyeres in the tuyere line tended to operate synchronously at the dominant frequency, regardless of operating conditions tested and despite being distributed along the converter. Synchronous behavior is thought to arise from the acoustic coupling and possible resonance behavior of the gas delivery system on the converter.

Jan 1, 2007

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By Davis. B. R.

There are a number of hydrogen storage systems proposed for automotive applications. However, all of the current suggestions fall short of the DOE targets for storage density and volumetric density. The DOE has suggested that only through radically new ideas will a practical solution to hydrogen storage for automotive applications be realized. This paper provides some background in chemical hydrogen storage and discusses roadblocks to the implementation of some proposed technologies.

Jan 1, 2005