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By Vladislava A. Ignatkina, Victor D. Samyguin

"Within the limits of two-phase approach, considering mass transfer with pulp and air streams was shown that each bubble appears to be an elementary carrier, transporting particles from the collection zone into the froth. The kinetics of flotation was described by the exponential equation in which first order flotation speed constant has to be replaced with two-phased coefficient of a mass transfer. Criteria of selectivity of two ore fractions separation, based on determination of optimum time at which maximum difference between extractions and components content in separated fractions were offered. An interrelation between optimum time of pulp residence in a flowing chamber of a flotation machine, time of bubbles mineralization and an optimum airflow has been ascertained. Cumulative criterion of mass transfer efficiency of flotation process has been ascertained to be a form of the spectrum and its position on axis of three-phase coefficient of a mass transfer.INTRODUCTIONRegularities of a mass transfer of three bearing streams: pulp stream, air stream and froth stream underlie theory of mineral complexes flotation (Samygin, Filippov, & Shekhirev, 2003)However, only description of mass transfer in pulp stream by means of kinetic equations that were simple and convenient for practical use, has gained a full distribution (Tykhonov, 2009;Rubinstein&Filippov, 1980; Saleh, 2010).Within the limits of a single-phase approach, the role of gas stream in increase of speed and selectivity of flotation, was associated with an improvement of hydrodynamic mode. An influence of particles and bubbles sizes (Rubinstein&Filippov, 1980; Rubinstein&Samygin, 1998, Samygin et al., 2003; Dai, Fornasiero,& Ralston, 2000), of pulpflow and airflow (Finch& Dobby, 1990) and turbulent energy intensity (Shubert, 1979; Massinaei, 2007) on the flotation process has been studied. It was stated that flotation selectivity is increasing by means of gradual airflow increase from first to final cameras of the impeller flotation machine (Aslan&Boz,2010; Finch, 2011) and by means of using a multizone flotation machine (Samyguin, Filippov, Matinin, Lekhatinov, &Tertyshnikov, 2013)."

Jan 1, 2016

By S. J. Buckler

Many metallurgical processes use submerged gas injection to increase the contact area between gas and liquid phases in order to promote faster overall reaction rates. The work presented in this paper is part of an experimental investigation to measure the gas-liquid interfacial area available in bubble plumes within molten metal baths. Measurements of the nitrogen absorption rate during submerged injection into molten iron baths have been used to estimate the interfacial areas of the bubble plumes. A theoretical model was used to predict the superficial nitrogen transfer rate under mixed liquid phase mass transfer -interfacial reaction control. The interfacial area was calculated by dividing the overall nitrogen absorption rate by the superficial rate. Reasonable agreement was obtained between the interfacial areas measured in our laboratory with data from a comparable system reported in the literature. The experimental results were compared with the predictions of three theoretical models and one empirical correlation. The models of Turkdogan (3) and Zhao and Themelis (5) gave the best agreement with our data.

Jan 1, 2004

By L. T. Munn

"IT IS NOT necessary here to dwell on the fact that sulphur is currently in short supply. It may be well, however, to •point out that this •storage is not merely a temporary condition, but that, judging by trends in world consumption of sulphur, it may •be anticipated that requirements will double in the next ten years.Even with improved techniques for mining elemental sulphur in the United States and the new finds in Louisiana, there is much concern as to how these future sulphur requirements can be met. It appears necessary to .turn more and more to other sources than elemental sulphur for •additional production. The three major alternative sources were:(1) By-product sulphuric acid •from smelter gases.(2) Sulphur and sulphuric acid from iron sulphides.(3) Sulphur from hydrogen sulphide contained in natural gas. The Jumping Pound sulphur plant of the Shell Oil Company of Canada, Limited, is designed to produce sulphur by the •third of these methods.Jumping Pound is a natural gas field about 20 miles west of Calgary where Shell has a number of producing wells."

Jan 1, 1952

By J. D. T. Steyl, C. A. Biley

"The chemistry of electrolyte systems containing iron remains generally poorly understood despite their prevalence in many natural and industrial processes, particularly in hydrometallurgy. These systems are typically challenging to study and model due to their affinity for complex formation and precipitation even at low pH. Recent developments in the hydrometallurgical processing of nickel laterites at Anglo American have called for a deeper understanding of the fundamental chemistry of the Fe2(SO4)3–FeSO4–H2SO4–H2O system. This paper details the development of an internally consistent, Pitzer ion-interaction model of this system, with explicit recognition of important contact ion pairs (CIPs). The primary application of this model is a thermodynamic framework for the interpretation of kinetic processes occurring during iron(III) reduction with SO2. Adopting a rigorous thermodynamic basis for the system chemistry facilitates the formulation of simple rate expressions that are capable of inherently capturing complex effects. While the iron(III) reduction case study remains the focus of this work, the developments have more universal applications and the thermodynamic speciation model can be extended into other systems containing acidic ferric sulfate.INTRODUCTIONIron is present in nearly all hydrometallurgical refining circuits typically as both a necessary and unwanted impurity and needs to be removed and disposed in a safe and efficient manner. This is generally performed by precipitation to form a range of solids such as hematite, goethite or jarosite. Numerous studies in the open literature have focussed on the removal of iron from refractory gold sulfide ore (Berezowsky & Weir, 1989; Berezowsky et al., 1991) and zinc pressure leaching (Buban, 1999; Ismael, 2003), and PGM matte sulfide circuits (Dutrizac & Monhemius, 1986). Moreover, since ferric iron is a strong oxidizing agent, it has been used extensively as a leaching agent for sulfide minerals (Dreisinger, 2006). Given the outlook of challenging economic conditions, declining ore grades and increasing levels of impurities, effective iron management is going to become increasingly critical to all hydrometallurgical processes.Against this background, and considering the widespread importance of acidic iron sulfate systems throughout natural and industrial processes, it is unexpected that the knowledge of the fundamental solution chemistry of these systems contains such significant gaps, particularly at the conditions typically found in hydrometallurgical applications. Existing literature describing the measurement and modelling of solution speciation in these systems have highlighted their significant chemical complexity (Magini & Caminiti, 1977; Magini, 1979; Lee & Tavlarides, 1985; Stipp, 1990; Papangelakis et al., 1994; Gil et al., 1995; Majzlan & Myneni, 2005; Kormanyos et al., 2008; Yue et al., 2014). Partially responsible for the lack of quantitative speciation measurements is the strong tendency of ferric to hydrolyse at even low pH (Flynn, 1984), complicating the laboratory study of such systems. Moreover, the large number of aqueous species that may co-exist simultaneously makes the study of individual species and the modelling of the numerous interactions between these species extremely difficult (Dry & Bryson, 1988; Stipp, 1990; Majzlan & Myeni, 2005; Kobylin et al., 2007)."

Jan 1, 2016

By W. H. Zieman

NORMAN WEISS, Milling Engineer, American Smelting• and Refining Company: The subject of the Forum on Rod and Ball Mill Liners is very fascinating, and there is no end of discussion when operators get together on grinding. However, the hypotheses and suppositions easily outrun the facts, especially when we •consider the inaccuracy of many reported observations. Still surprisingly small is the number of concentrators even reasonably well equipped to measure power consumption of each grinding mill, together with running time, so that data on this tangible factor, at least, can be obtained with precision. While the more elaborate devices of this nature, producing for each 24-hour period the total power consumption, average kilowatt hours per hour, short-term demand chart, instantaneous demand, and print-out, may cost in the neighbourhood of $2,500 per mill and may be difficult to justify, the combination of an ammeter, watthour meter, and running-time meter will cost only a few hundred dollars, so there appears to be little reason not to in-stall them in view of their numerous advantages.

Jan 1, 1959

By W. L. Dam

Grand Junction, Colorado’s legacy with uranium mining and milling serves as a model attracting international interest. Access to water and central location to carnotite ore containing uranium and vanadium resulted in the World War II military creating a site in Grand Junction for developing extraction techniques; subsequently, several commercial mill sites were built in the area. Uranium mills produced ore into the 1970’s as well as tonnes of radioactive waste tailings. Tailings contain radium that emits radon gas. Despite the radiation hazard, sandy tailings were added to concrete and became incorporated into roads, schools, businesses and homes. Clean up of sites containing tailings and mill sites began in the 1970’s involving city, state, and federal officials. The Climax mill site had become an auto junk yard mixed with mill tailings. A new disposal site was built out of town and away from the river in the 1990’s. After Climax mill tailings were removed to the disposal site, the land sat vacant for two decades until citizens and city officials developed a masterplan for the riverfront property. The Las Colonias river park is being built in stages including an amphitheater, gardens, businesses and parks. One of the biggest obstacles to site remediation and reuse was overcoming public outrage, fear, and lack of trust which made funding sources scarce.

Jan 1, 2020

The rock mass classification systems were developed for different functions, including support selection, excavation method selection and the determination of rock mass engineering properties for excavation design, among others. This explains in part why we have several rock mass classification systems. It is often cautioned that the rock mass classifications are to be used for preliminary excavation support design, but this caution is now often overlooked and detail/final support design based on the rock mass classification systems. This paper advocates differentiating between rock mass classification for pre-excavation support planning and rock mass classification for at-face excavation performance assessment. It is concluded that most at-face excavation performance problems are attributable to confusing the virgin rock mass rating with the rock mass rating on exposure during excavation, and that this observation is independent of the method of excavation. Procedures are then presented for virgin rock mass rating and for at-face rock mass rating/assessment during excavation.

May 1, 2009

By J. S. Stewart

THIS paper was prompted by a persistent demand for what information we have that will throw light on the oil and gas possibilities of the Maritime Provinces. The problems involved were made familiar to the writer during three seasons of field work in New Brunswick and Nova Scotia. The reasons for renewed interest are: (1) In many parts of that region, the surface is underlain by a thick series of unaltered sedimentary rocks. (2) Oil seepages occur, and oil in commercial quantity has been exploited' near Moncton, New Brunswick, for many years. (3) In recent years, a new method of attack has been developed toward the finding of stratigraphic traps. This method is based on a detailed study of the geological history of the region, as revealed in surface outcrops and samples from deep wells. The well samples show the lateral variation of strata, far from any possible surface outcrop of the same beds. Sufficient work has now been done in the Maritime Provinces to reveal the broad features of the geological history and the character and distribution of the various rock formations. Comparatively little deep drilling has been done in this region, but the holes are widely scattered and the samples from them have added much to the information obtained from the numerous outcrops of bed-rock. The following discussion gives a summary of available information that has a bearing on the subject.

Jan 1, 1943

By W. Leblanc, J. C. Marsh, D. Kettle, J. Tompkins, G. Hartley

"The Lingan Mine is the newest of the four operating collieries of the Cape Breton Development Corporation and is located on the east coast of Cape Breton Island. Development of slopes began in 1969 using four Dosco Roadheaders. Production commenced in October 1972, when a partial extraction section utilizing a continuous miner, loader and shuttle car was installed. A second Joy unit is scheduled to begin production early in 1973. This paper describes the production and development operations, the ventilation system and the equipment in use at the mine."

Jan 1, 1973

By J. G. Speight

Laboratory studies indicate that autogenous heating of low-rank coal can be prevented by a prior treatment which involves immersing the coal for short (5-15 min.) periods in an inert liquid at temperatures between ~ 350° and 400°C. Such "carbonization" effectively reduces the accessible pore volume of the coal to levels at which heat generation through subsequent sorption of moisture and oxygen is too slow to cause significant temperature rises in a stockpile. In addition, this treatment also irreversibly removes most of the moisture held in the raw coal and raises its calorific value by as much as 10-12%.

Jan 1, 1973

By D. Pérez Escobar

Multiphase steels are quite sensitive to hydrogen embrittlement. Laboratory tests to evaluate this often use electrochemical, charging to introduce hydrogen into the sample, but damage purely caused by hydrogen charging has to be avoided. A ferrite-bainite steel, was charged using various conditions to identify when surface blisters occurred. Samples were also checked for internal, damage by electron microscopy. This study was repeated for three other multiphase steels and pure iron. An HSLA steel, was found to be more resistant whereas pure iron was quite susceptible to internal, hydrogen damage. For al, industrial, steels, cracks concentrated in the middle of the sample were attributed to inclusions and segregations, inherent to production.

Jan 1, 2010

By J. C. Farge, G. G. Jacox

"The effect of composition and process variables on the properties of Marmet and modified Ni-Hard slugs will be discussed. The effect of shape on the over-all performance of grinding media and its relationship to the end product has been investigated and these results will be reviewed. The cost effectiveness of slugs versus balls has been well documented under various operating conditions and this will be presented in detail. IntroductionThe selection of grinding media is based on the cost-to-wear ratio combined with the consideration that it must stand repeated impacts without breaking. The specific consumption of grinding balls and slugs depend s primarily on their microstructure, which, in turn, is controlled by chemical composition and by the processing condition s to which they are subjected during manufacture.The first part of the paper deals with the optimization of alloy content to produce cast iron slugs with microstructures consisting essentially of marten site and carbide and with hardnesses of 650 B.H.N. and higher. The second part deals with the use of cast iron slugs to replace forged steel balls in milling operations. Tests indicate that the shape of the media has little if any effect on results and that the hardness and microstructure of grinding media will determine its relative performance. Where price is equal under similar milling conditions, the cost effectiveness of cast iron slugs is superior to that of forged steel balls.In order to understand the role of alloying elements in cast irons, it is judicious to consider the microstructural changes which occur during solidification and subsequent cooling, particularly from above the eutectoid temperature. Solidification starts with the formation and growth of dendrites of austenite. As temperature decreases, an eutectic nucleates and grows between the primary austenite dendrites. Immediately after solidification, the structure consists of proeutectic austenite and of the eutectic of primary carbides and austenite. On cooling to room temperature, austenite can be retained or transformed to pearlite, bainite, martensite or mixtures thereof. It is necessary to prevent decomposition of austenite into pearlite by adjusting the alloy content. For best abrasion resistance, the microstructure at room temperature should consist essentially of martensite and carbide. These types of irons are known as ""martensitic irons "". Depending on the carbon content of the austenite and cooling rate, "" as-cast"" martensitic irons will contain different proportions of martensite and retained austenite. The more carbon in solution in the austenite, the lower is the temperature at which the martensitic transfoemation takes place. By the time room temperature is reached ., the transformation is seldom complete, and the end product is generally a mixture of martensite and retained austenite."

Jan 1, 1980

By Gulshan Kumar Pradhan, Yogendra Pratap Singh, Dhawanm Nikhil

"Potassium (K) is one of the essential elements for the growth of plants and thereby for humans. In fertilizers, potash demand has been steadily increasing at ~3.5% annually. Water soluble potash deposits are rare and highly localized. India is neither present on the world potash production map nor it has adequate potash rich rocks. The K-bearing minerals are recovered either by using conventional underground mining methods or though solution mining methods. India possesses a vast resource of silicate rocks such as glauconitic sandstone and Feldspar. These rocks are basically a group of alumino silicate of potassium, sodium and calcium (K2O%: 5-12, Na2O%: 3-10%, SiO2%: 52-65, Al2O3%: 15-20, Fe2O3%:, 5-7 and MgO%: 2-3.5).The K extraction from silicate rocks has received little attention probably due to the slow release, the locked structure of alumina-silicate minerals, and the unavailability of appropriate economic processes & their know-how. In fact due to this India imports all of its potash demand (about 3.5 million tons per annum) from different countries.In the present work, an attempt has been made to identify the structural and chemical alteration of desired K mineral phase in silicate rock (~K2O%: 10.5, Na2O%: 2%, SiO2%: 55, Al2O3%: 19, Fe2O3%, 5-6, MgO%: 2.5) under different conditions such as acid leaching, thermal treatment and chemical processing. Different treatments are aimed to increase K availability which is related to the modifications in mineralogical composition. The modifications in the feed sample and treated samples are studied through SEM-EDAX, XRD, EPMA and optical microscope. With the combination of treatments, it is possible to extract more than 90% K and the formation of sylvite phase (water soluble) confirms the dissolution of potash values."

Jan 1, 2016

By F. McGravie, S. T. Solinski, W. W. Robertson

During this, the Centennial year of the discovery of the Hall-Heroult process, it seems appropriate to review some of the developments which have taken place in Canada and to explain why it has become an important world centre for the production of primary aluminum. For many years after it was recognized that the element aluminum existed, scientists were frustrated in their efforts to isolate it. In the early 1800s H. C. Oersted and Frederick Woehler prepared small quantities sufficient to measure some of the physical properties. A quasi-commercial process involving reduction with metallic sodium was developed by the French scientist H. St. Claire Deville in 1855 but the cost was very high ($30. 00 per kg). It was not until 1886 that Charles Martin Hall in the United States and P.L.T. Heroult in France, more or less simultaneously but completely independently, discovered the process which is essentially that in use today. Some of the early pioneers in the industry quickly recognized the potential of the hydro-electric resources in Canada as economic energy suppliers for aluminum production. The first commercial production in Canada was in Shawinigan, Quebec in 1901, only 15 years after the process was discovered. Subsequently operating plants were established at nine different locations in Canada (Quebec and British Columbia) (Table 1). Operations continue today in all locations except one (La Tuque). The table shows present plant capacity which for the older plants was reached in an evolutionary manner including replacement of obsolete capacity or upgrading and modernization of existing designs.

Jan 1, 1999

By M. A. Vos

"Aggregates are the low-cost mineral raw material of building construction. Large volumes of aggregate are consumed each year. The availability of aggregates in southern Ontario is discussed in the context of the geological formations in which they occur. Sand and gravel are abundant in glacial deposits and in recent sediments. A knowledge of the glacial history is important for their discovery. Bedrock formations provide a variety of aggregates in Ontario. Knowledge of the rock types involved and of the depth of overburden are important for evaluation of the aggregate potential of bedrock resources in an area. Utilization of available resources intensifies as the population increases. Urban development makes it progressively more difficult to satisfy the demands of the construction industry. The effects of urban development on the aggregate resource base of an area are illustrated by developments and consumption statistics in the Toronto- centred region. There is an obvious need for a comprehensive survey of available resources in urban areas to serve as a guide in land-use planning. To fill this need, staff members of the Industrial Minerals Section, Geological Branch, Ontario Department of Mines and Northern Affairs, are engaged in mapping projects and mineral resource studies in southern Ontario as well as in some urban areas of northern Ontario."

Jan 1, 1972

By D. C. Fraser

"Geophysical Engineering and Surveys Limited of the Keevil Mining Group have routinely conducted ground surveys with VLF-EM receivers for the past two years. Both Crone's Radem and Ronka's EM16 have been used.VLF-EM dip-angle data often yield complex patterns which require considerable study for a proper interpretation. A method was developed which allows field operators to transform the noncontourable dip angles into contourable data, producing conductor patterns which are immediately apparent to exploration personnel untrained in VLF-EM interpretation.VLF-EM contoured data generally peak very close to the top of a conductor, thereby allowing drill holes to be spotted accurately. However, the data generally should not be used alone to select drill targets because structures may be sufficiently conductive to yield strong anomalies. Thus, magnetic and/or vertical-loop EM correlations may be considered as necessary criteria for drilling.VLF-EM surveys can replace IP surveys in certain environments. For example, the Restigouche orebody in the Bathurst camp of New Brunswick yielded a VLF-EM anomaly as distinct as that obtained by IP, although the body did not respond to vertical-or horizontal-loop EM. However, the cupriferous breccia pipes of the Triba mine near Batchawana, Ontario yield strong IP anomalies but not VLF-EM anomalies, illustrating that disseminated ore targets should be sought with IP rather than with VLF-EM."

Jan 1, 1971

By Oleg G. Tovmachenko

We have studied optical properties of fluorescent nanoparticles. These particles consist of a metal (gold/silver) core, an empty and a dye labelled silica shells. The different dye molecules with moderate quantum yields (about 0.3) has been used. Almost all of types of nanoparticles show fluorescence enhancement. This enhancement is strongly dependent on the degree of the overlap between the surface plasmon band of the metal and the absorption/emission band of the dye molecules. The results are interpreted in terms of competition between local field enhancement and quenching of fluorescence by the metal surface.

Oct 1, 2003

By G. G. Campbell

"HistoricalBARYTES was mined in Nova Scotia as early as 1874 from a deposit at Five Islands, on the north shore of Minas Basin. The first record of the presence of the mineral at the Walton site appears in a report by Selwyn in l893, who states: ""Barytes in considerable quantity occurs in veins in lime-stones at Walton and Pembroke"". The exact site of the present workings was marked •on a map published by Fletcher in 1905.The economic •possibilities of this deposit, however, were not recognized until 1940, at which time we were at war with Germany, who up to that time had supplied 50 per cent of the world's requirements.At that time the Nova Scotia Department of Mines, recognizing the need for certain strategic minerals, induced Canadian Industrial Minerals, Limited, to send prospectors into 'the area to look for manganese. No manganese deposits were found, but a deposit of barytes was directed to their attention, and exploration and development work on the occurrence was proceeded with.IntroductionThe south shore of Minas Basin between the Avon river at Windsor and the Stewiacke river at Maitland has long been known as a potential source of mineral wealth. It had attracted the attention of mineralogists and in the past had produced considerable tonnages of manganese ore and gypsum. Depletion of ore in surface and near surface deposits resulted in a dwindling production, until today only deposits of gypsum are worked."

Jan 1, 1952

By J. D. Jones

The geographic occurrence of economic mineral deposits presents a variety of problems in modern tailings disposal operations. This paper presents case histories in several sectors of the mineral industry as well as the several stages of operations planning required for new designs, system expansion, reactivation of abandoned systems and upgrading to present environmental standards.

Jan 1, 1978

By L. Li

To accommodate the large payloads and harsh operating conditions associated with heavy vehicles in the mining industry, off-the-road (OTR) tires are typically used with heavy mining vehicles. These tires have increased abrasion and wear resistance due to their thicker tread, sidewall and bead thicknesses. Given these features, OTR tires are much stiffer than conventional passenger vehicle tires and cannot be mounted to a single-piece rim without damaging the structural integrity of the tire during the mounting process. Therefore, multi-piece wheels are used with OTR tires to facilitate mounting. While these assemblies are necessary, several instances of their failure have been reported to result in injuries or fatalities within the mining workplace. Many of these failures were specifically reported to be caused by the disengagement of the wheel lock ring - a component used to securely engage the assembly during operation. In this study, a threaded-connection locking mechanism has been proposed in place of the traditional lock ring design. The performance of this threaded-connection was numerically evaluated in a pull-out test against a conventional five-piece wheel assembly. The pull-out test was devised as a means of quantifying the engagement ability of each wheel?s locking mechanism. A high degree of modelling accuracy was maintained throughout the analysis by validating the vertical and horizontal static loaddeflection behaviour of the rim model of the five-piece wheel assembly against experimental data. Through validation, the model data were found to be within 10.5 and 4.80 %, for vertical and lateral loaddeflection behaviour, respectively. Results from the pull-out analysis found that the threaded-connection demonstrated a 113 % increase in the force required for disengagement to occur relative to the conventional five-piece design - a force of 9,550 kN in total.

Aug 1, 2013