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By G. I. Mathieu, R. W. Bruce

Flotation schemes for the separation of molybdenite from other minerals are based on utilizing the Inherent hydrophobicity of molygdenite (Fuerstenau1). This natural floatability was attributed to the crystalline structure of molybdenite by Gaudin et al.2 who suggested that any surface formed by the rupture of van der Wall's bonds should be hydrophobic and, therefore, naturally floatable. Other authors argued that "natural floatability" is dependent of adsorption of hydrocarbon ions and/or molecu1es on the surface of the minerals. This theory, albeit-c questioned 1,2 has long been recognized in actual practice of molybdenite flotation as the latter in carried out with hydrocarbons, such as fuel oil, kerosene and stove oil. Although conferring ready floatability to molybdenite, these presents generally have little effect on other sulphides and silicates. However, talc is a noteworthy exception because of its innate floatability4. Not withstanding the reason for this behavior which has also been attributed to crystal structure2 its end results as in the case of molybdenite is an immediate flotation response to frothing oils arid kerosene, as was observed by Baranovski5, Sutherland and Wark6.

Jan 1, 1974

By P. J. Williams, A. R. Foster

Petrographic studies, assay records, and laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS) analyses of major sulfides suggest nearly all of the gold at the Ernest Henry Cu-Au deposit occurs in the form of native gold or electrum (95-65 wt.% Au); sylvanite and dissolved gold in cobaltite, chalcopyrite, and pyrite make only minor contributions. LA-ICP-MS analyses of the gold contents of chalcopyrite gave from 8 to 139 ppb (mean = 56 ppb), more than an order of magnitude lower than those experimentally determined in chalcopyrite in equilibrium with native gold at the estimated mineralization temperatures (350°-450°C). Gold content is more variable in pyrite (1-400 ppb, mean = 77 ppb) and highest in narrow growth zones of a subordinate type of complexly zoned pyrite wherein it is associated with elevated As, Ag, Sn, Sb, Te, and Bi. Deposition of gold-electrum was closely associated with, but preceded some of the chalcopyrite deposition, as indicated by microtextures and lower bulk Au:Cu ratios in late-stage chalcopyrite-rich veins. Gold grains have maximum dimensions from <1 to 50 micrometers, and are heterogeneously distributed with most occurring in microscale clusters. Fifty-five out of 76 grains recorded in polished sections are in contact with both chalcopyrite and pyrite, and many of the rest are in sites where such a relationship could exist in the third dimension. The dominant textural sites are intergrowths with chalcopyrite in microveinlets cutting pyrite, and on faces of pyrite grains in contact with chalcopyrite. Scanning electron microscopy, electron microprobe analysis, and proton induced X-ray emission studies show that pyrite associated with gold includes complexly zoned, weakly zoned, arsenian, and arsenic-poor types. The textures are compatible with the possibility that most gold was deposited electrochemically as native metal on pyrite surfaces. The textural distribution of gold has important metallurgical implications given that the ore processing circuits at Ernest Henry and most other sulfide copper mines are designed to exclude pyrite (and arsenic) from concentrates.

Jan 1, 2007

By Deni Lessard, Roger Demers, Noël R. Billette

"The Quebec Mining Association has for many years been supportive of the activities of the Centre de recherches minérales which were initiated to ensure regular production hoist and cable inspections to maintain safety and productivity standards in underground mines in Quebec. CRM and CANMET have agreed to fund a Quebec Mineral Development Agreement contract to capture this accumulated knowledge. Using VP-EXPERT to process the information and subdirectories to store regulations, the prototype access D-BASE III records on hoist information and LOTUS 123for simulating working conditions that meet local regulations and expert rules of thumb criteria. Objectives are to improve safety in emergency operating procedures, maximize hoist productivity and safety, and promote knowledge transfer to operators."

Jan 1, 1992

By Richard Klimpel

"Over the last 15 years, there has been a number of plant scale sulfide mineral flotation tests organized by this author specifically aimed at understanding how flotation rate varies with reagent type and dosage. With regard to the Interaction of collector dosage, particle size, and frother type, the eight specific trends listed in the paper (Illustrated with data from two specific case studies) are qualitatively the same for almost all plants studied in some depth. The Interaction of flotation rate K and equilibrium (Infinite time) recovery R in the plant has been denoted as the R/K trade-off. The effect of collector dosage on the rate of flotation of specific particle size intervals is particularly interesting and once understood, is quite useful In understanding how industrial flotation plants respond to changing reagent type and dosage. The location and magnitude of the R/K trade-off can be different for various ores and various plant configurations, but the RIK trade-off is almost always present. The purpose of this paper is to clearly describe and illustrate the nature of this very Important flotation system Interaction so that operating engineers have a starting reference point for beginning successful plant Improvement studiesIntroductionIt is well recognized by industrial froth flotation plant operators that improving existing sulfide circuit performance is often difficult due to the self-compensating systems nature of the froth flotation system, e.g. Klimpel (1988, 1989, 1995). Extensive plant testing with existing and new reagents by this author throughout the world has clearly shown that one of the more important self-compensating mechanisms is the Interaction between collector dosage, frother type, and particle size. The term self-compensation in flotation simply means that as the plant operator consistently changes one parameter in the same direction, the nature of the froth flotation system Is such that the circuit will eventually begin to resist this controlled parameter change by automatic (uncontrolled) changes In other parameters and the overall circuit performance will go through a maximum or minimum (hence causing the operator to stop the parameter change)."

Jan 1, 1997

By W. E. Cockfield

"The Stump Lake mining camp is in Nicola mining division of southern British Columbia. It lies about halfway between the cities of Kamloops and Merritt.The deposits at Stump Lake are among the earliest lode discoveries of British Columbia, many of the claims having been staked between 1882 and 1885. A considerable amount of work was done prior to 189Cl, after which very little was done until 1916. Since that time mining has been carried on at intervals, much of it on the same deposits, by a number of companies, including the Donahue Mines Corporation, the Planet Mines and Reduction Company, the Nicola Mines and Metals Company, the Consolidated Nicola Goldfields, Limited, and others. According to the British Columbia Department of Mines, total production from the area has been: gold, 8,520 oz.; silver, 259,413 oz.; copper, 40,822 lb.; lead, 2,208,859 lb.; and zinc, 367,869 lb. Most of the production has come from the Enterprise vein and a branch of the Enterprrsethe King William vein."

Jan 1, 1954

By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly, H. Khadivinassab

A combined experimental / numerical approach is proposed to investigate the bulk transfer of solute due to liquid metal feeding during shape casting of aluminum alloy A356 (Al-7Si-0.3Mg). A dumbbell-shaped experimental casting geometry has been developed, which promotes solute redistribution due to liquid metal feeding. The redistribution of solute in trial castings is evaluated based on the area fraction of eutectic phases. In the numerical model, silicon species segregation during solidification are calculated assuming the Scheil approximation, and are coupled with macro-scale solute transport due to Darcy flow in the mushy zone and feeding flow. The model has been implemented within the commercial CFD software, FLUENT, which simultaneously solves the thermal, fluid flow fields and species segregation on the macro-scale. The experimental and numerical results are compared and contrasted to examine the effects of liquid metal feeding in this casting.

Jan 1, 2014

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By Osamu Inoue, Takashi Yamashita, Takashi Ikemoto

The expansion project in Naoshima smelter and refinery to meet enhancing recycling business of E-scrap was successfully completed in 2016 to have a capacity of 110,000 tpa of E-scrap treatment. Increasing treatment of E-scrap has raised the Ni content of copper anode to 4000 ppm on average, which is double the level of 10 years ago, and to 6000 ppm or more occasionally. The tank house has refined such copper anode to copper cathode with starter sheets. Since most Ni in Copper anode dissolves in copper electrolyte, the Ni content of the electrolyte has increased to 27 g/L and more. Ni accumulated in the electrolyte has increased power consumption during the electrolytic refining of copper, although cathode quality has been controlled satisfactory so far. In order to ensure sustainable operation while growing E- scrap business, the NiSO4 process has been expanded recently so as to recover Ni in the electrolyte more and the pressurized-leaching technology will be introduced to the slime leaching process so as to enhance the capacity of slime treatment and to improve Ni recovery in the near future. INTRODUCTION In recent years, the treatment amount of E-scrap at Naoshima smelter and refinery has increased according to the growth of its recycling business as shown in Figure 1, while impurities from E-scrap have concentrated in copper anode as well. Especially, Ni content in anode has been increasing remarkably since 2012, causing to raise Ni content in the electrolyte as shown in Figure 2. The increment of Ni content in copper anode and electrolyte has adversely affected the electrorefining process, slime leaching process, and NiSO4 crystallization process at the tank house. Such severe conditions provided opportunities to redesign the tank house to establish a robust process to which more Ni is acceptable.

Jan 1, 2019

Despite the claims of energy efficiency and the considerable development that has gone into dramatically extending rolls’ life and facilitating rolls’ change-out, in the six years since the last SAG conference, only a few HPGR operations have entered the realm of mineral processing. Risk barriers to the take-up of new equipment or processes are: a massive increase in materials handling issues as well as in the number of pieces of equipment required, low total circuit potential energy savings, and similar or higher capital costs. An alternative route is to make use of the complementary strengths of the HPGR and SAG in hybrid circuits. Minimising materials handling issues, providing an ideal balanced feed to the AG or SAG mill, and improving controllability through shifting grinding load as the RoM feed changes, are all potential major advantages to this approach. Conceptual circuit layouts, based on real measured ore and equipment data, are presented here to illustrate the potential production upside, the reduction in operating costs and the reduction in the physical and energy footprints.

Jan 1, 2012

By P. A. Riveros

Antimony is commonly found in copper electrolytes and can contaminate the cathode deposit. Several methods, such as ion exchange, solvent extraction and precipitation, have been developed to remove antimony from copper electrolytes. However, past research has been carried out almost exclusively with Sb(III), whereas the presence and behavior of Sb(V) in the electrorefining circuit have been largely ignored. In this study, the behavior of Sb(V) species was monitored and compared to that of Sb(III) species, using specially developed analytical and SEM-EDS techniques. Significant differences in the behavior of the two species were noted. Although the solubility of Sb(III) increases with temperature in synthetic copper electrolytes, the solubility of Sb(V) appears to be constant over the range from 30 to 80°C. Whereas Sb(III) forms several crystalline oxy-sulphate compounds, Sb(V) appears to remain as an amorphous oxide. Both Sb(III) and Sb(V) are extracted by aminophosphonic resins, and Sb(III) is readily eluted by HC1 or complexing agents. By contrast, concentrated HC1 elutes Sb(V) inefficiently and complexing agents, such as EDTA and tartaric acid, do not elute Sb(V) to any significant extent. This observation implies that in industrial practice, unless special measures are taken, Sb(V) will accumulate on the resin, eventually impeding the ion exchange process.

Jan 1, 2007

By Z. Mubarok

An overview of the problems encountered the electrorefining of copper anodes containing high levels of nickel and antimony is presented. Our investigations have been focusing on the passivation behaviour of the anodes with high contents of Ni, Sb, Sn, and Pb, the formations of kupferglimmer and floating slimes. The results of linear voltammetry, chronopotentiometry and electrolysis test revealed a noticeable lower resistance of the anodes to passivation in comparison to those with lower contents of Ni, Sb, Sn, and Pb. Anode containing kupferglimmer exhibited oxygen gas evolution during the passivation state. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) indicated that tin can replace and/or join antimony in the kupferglimmer structure. Under specified experimental conditions, floating slimes precipitations took place with high Ni, Sb, Sn, and Pb anodes prior to the end of one anode period.

Jan 1, 2007

By Sergio Fuentes

During the past fifteen years, mines utilizing the block caving method have improved performance and systematically reduced total mining costs. This paper describes improvements in mine design, mine planning and mine management, including methods enabling the Chilean and International mining industry to ensure cost savings and productivity growth while using the block caving method. These improvements have encouraged the re-evaluation of underground operations at operating and closed open pits, and challenge surface mining applications as the only low cost mining method. This paper describes a strategy to estimate the optimum open pit to underground transition time during the life of a mine.

May 1, 2003

By Denis Thibodeau

The selected mining method for the Rodeo lower Zone is slot and slash. Initial design indicated that the stope height should be limited to a maximum of 18 m, thus six levels were needed to extract the ore. Higher stope height in the Rodeo Lower Zone means less development thus less capital required to extract the available reserves. It was proposed to eliminate one level by establishing 30 m and 24 m level intervals. To ensure that no stability problems will be encountered by eliminating one level, a Matthew analysis, based on diamond drill core information, was performed for the Lower Rodeo Ore Body. In addition, comparisons between the rock mass quality of Meikle Main Zone below 1825 L and Meikle East Zone between 1600 L and 1750 L with the rock mass quality of the Lower Rodeo were made

May 1, 2002

By R. W. Boyle

"PREFACEThis paper comprises two parts. The first part discusses lithochemical surveys based on major, minor and trace elements in whole-rock samples from primary enveloping halos. The second part continues with discussions of surveys based on leakage halos, zonation of elements, stable and radioactive isotopic distributions, geothermometric, geobarometric, thermolumin escent, pedochemical, hydrochemical, atmochemical and biogeochemical methods. A selected bibliography follows the second part of the paper.ABSTRACTAreal (two-dimensional) geochemical surveys, based mainly on secondary dispersion halos and trains in media such as surface waters, soils and drainage sediments, have proven particularly successful in recent years and have greatly assisted in the discovery of a large number of varied mineral deposits. Three-dimensional surveys based on primary halos and leakage halos have received relatively little attention by research organizations and the mineral industry. Such surveys offer many novel approaches for discovering blind mineral deposits deeply buried below overburden or within their host bedrocks. This paper reviews detailed methods for the discovery of blind mineral deposits based on sampling rocks (lithochemical methods), soils and other types of overburden (pedochemical methods), waters (hydrochemical methods), gases (atmochemical methods) and biological materials (biogeochemical methods) . All are applicable to the discovery of blind deposits; the efficacy of each or in combination depends essentially on the type of mineralization, the extent of the development of the primary and secondary dispersion halos, and the finances available for sampling techniques employing overburden drilling, bedrock drilling, and sophisticated water, gas and vegetation collection."

Jan 1, 1982

The Boleo project is located in Mexico close to the town of Santa Rosalia on the Baja Peninsula. The Boleo deposit contains copper, cobalt, zinc and manganese values as oxides with minor sulfides. The Boleo deposit is metallurgically challenging due to: 1) the requirement to recover four separate metals; 2) the presence of high levels of clay in the deposit resulting in difficult solid-liquid separations, and; 3) the need to use seawater for the bulk of the processing. Baja Mining, Bateman Engineering and SGS Lakefield Research have collaborated to develop and test a process flowsheet to recover copper, cobalt, zinc and manganese products at Boleo. The key steps in the flowsheet are: ? Feed preparation (scrubbing and ball milling of oversize) in copper raffinate ? Ore leaching using oxidative and reductive leaching ? CCD washing using high rate thickening technology ? Copper SXlEW ? Treatment of a bleed solution for cobalt, zinc and manganese recovery The process for cobalt, zinc and manganese recovery involves iron and aluminum removal followed by cobalt/zinc bulk extraction using CSIRO&apos;s DSX solvent extraction system and selective zinc and cobalt stripping. The zinc strip solution is evaporated to produce zinc sulfate monohydrate crystals to market and cobalt is recovered via a further SXlEW process as high purity metal. Manganese is precipitated as manganese carbonate from the DSX raffinate solution. This paper will review the Boleo process flowsheet and provide detailed results from the 2006 pilot plant operation conducted at SGS Lakefield in Canada.

Jan 1, 2007

By M. S. Ünal

Creation of 3D model of coal seams is a tedious and time consuming operation. Computer aided 3D solid modelling of coal seams can be performed in a fast and detailed manner. However, in case of having tectonically disturbed coal seams where faults may be observed, expert opinion is necessary to decide the geometry of the coal seam. The aim of this study is detection of fault zones with computers by using drill hole data. Firstly, a digital database is generated by using the drill hole data. Surface models of the layers are produced by applying triangulation method on coal seam roof elevations. The generated surface is divided into small squares and consequently dip and dip direction values are calculated for each square. Variograms for dip and dip direction are determined and maps showing the variation of dip and dip direction are generated by using geostatistical methods such as kriging and co-kriging. Examination of disconformities observed on estimation maps created by kriging and co-kriging clearly reveals the extension of faults. The method used in this study is applied to detect fault lines of a known mine field. 3D solid modelling of the coal seam has also been performed by using conventional cross-section method. The results of both methods were in good agreement. Identification of major faults by using the method introduced in this study could certainly simplify 3D solid modelling of coal seams.

Aug 1, 2013

By Jerry Danni

In order to remain viable today, corporations must view the environment as a strategic issue, and integrate environmental management throughout the organization. Corporate programs that used to be based primarily on regulatory compliance now must emphasize strategic environmental management systems, and must integrate these environmental systems with basic business functions. The mining industry today is global, and must have an organizational structure that can embrace different cultures, physical settings, and regulatory regimes. Sound environmental management practices are not different from good management principles. An effective environmental management system should be a complementary system to an organization?s overall management framework, integrated and aligned with the existing management structure. Integrating environmental management into core business functions is just good business. An effective environmental management system is a critical component of a company?s commitment to environmental, social and economic accountability. This paper presents the elements of the Kinross Gold Corporation strategic environmental management system and discusses the integration of the environmental management system into the core business functions throughout the Company

May 1, 2003

By Chris Larsen, Ian Orford, Marilene Renaud, Mike Cooper, Lud Strah

"An AG/SAG mill was commissioned at the Brunswick Mine concentrator in October 1998. This paper discusses the original liner design for the bi-directional AG/SAG mill, observed liner wear, subsequent liner design modifications, and benefits. The mill liners consist of steel top hat shell liners, steel end liners, rubber grates and rubber lined pulp lifters.Lifter profile and plate thickness measurements were made on monthly shop days. Trends of wear rates were used to project when liners required replacement. Wear profile information was also used to determine where liner re-design would improve wear life or minimize scrap loss. Charge motion simulation modeling was used as a tool to assist liner design modifications.INTRODUCTIONThe Noranda Inc. Brunswick Mine, located near Bathurst, New Brunswick, is a large underground lead/zinc mine with a nominal production rate of 10,000 tonnes per day. The Brunswick concentrator commenced operation in 1964 with conventional surface crushing followed by rod and ball milling to reduce run of mine ore to the required size to feed two parallel flotation circuits. In 1998 the AG (autogenous grinding) mill was commissioned for a nominal production rate of 9,000 tonnes per day replacing two surface crushing plants, three rod mills and three primary ball mills. In May of 1999 the mining rate was increased and the service of the AG mill was changed to a SAG (semi-autogenous grinding) mill with the addition of 4 inch steel balls (4% volume). The mill operates in closed circuit with 0.66 meter horizontal cyclones to produce a ground product of 90 micron nominal size (K80).The AG/SAG mill liners are steel (Norsteel, chrome-moly steel) with rubber grates and rubber lined pulp lifters.The original liner design was based on studying other AG/SAG mills and recommendations by the liner supplier, Norcast. Design factors taken into account were total cost of lining (including material and labour), protection of mill shell and impact on operating performance."

Jan 1, 2003

An essential tool for every step ? Early field survey ? Handheld satellite phones ? Portable satellite phones ? Exploration and Drilling ? Handheld satellite phones ? Portable satellite phones ? Production ? Handheld and portable ? Fixed Satellites systems ? Asset tracking systems Main applications via satellite ? Voice and Fax communication ? Internet access and E-mail ? Video conferencing ? Interconnection to mobile phones, 2 way radios, long range WIFI ? Equipment Tele-maintenance ? Telemedicine ? Crew and morale calling ? Vehicle and asset tracking

May 1, 2006

By H. Soltanzadeh

This paper summarizes semi-analytical and closed-form solutions that can be used to assess the poroelastic stress changes induced within a porous formation (reservoir) during a pore pressure change. Further, solutions are presented for the stress discontinuities at the interfaces between reservoirs and the rocks that surround them. When used in combination with rock failure criteria, these solutions enable relatively simple analyses of the potential for induced fracturing or fault reactivation within a reservoir or the rock immediately adjacent to it. The latter, in particular, is useful for assessing if the hydraulic integrity of the surrounding rock (i.e., the bounding seal) will be affected by a pore pressure change. The use of the approach presented in this paper is illustrated with an analysis of a pinnacle reef with dimensions and properties representative of reefs in the Zama oil field, northwestern Alberta, Canada. Scenarios of pore pressure decrease (during historical production operations) and pore pressure increase (during several years of acid gas injection operations) are analyzed, for three different idealizations of reservoir properties and geometry (two plane strain and one axisymmetric). These results suggest that that the potential for induced fracturing is not significant at any point within the reservoir or the surrounding rock for both the production and injection scenarios that were simulated. Similarly, fault reactivation was not predicted for the reservoir or any of the points that were analyzed in the surrounding rock. However, fault orientations having the greatest potential for reactivating during historical production operations were identified; thus, illustrating a means of using geomechanical models to focus geological characterization efforts on the features that are most critical to acid gas containment.

May 1, 2009