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By Antonio Segatori, Bjørn Holmedal, Kai Zhang, Trond Aukrust, Knut Marthinsen

"The visual appearance and mechanical properties of aluminium alloy extrusions are strongly dependent on the microstructure and texture of the extruded profiles, where the desired microstructure and texture may depend on the specific applications. In the present work, the evolution of deformation, as well as recrystallization textures during extrusion of AA6xxx aluminium alloys, have been experimentally and numerically investigated. Extrusion trials were performed in a laboratory extrusion set-up, which enabled immediate water-quenching of the profiles at the exit of the die, and thus the possibility to capture the deformation texture prior to post-extrusion recrystallization. The textures and their through-thickness variations were experimentally measured by the electron back-scatter diffraction technique (EBSD, and the deformation textures numerically modelled by coupling FEM flow simulations and crystal plasticity (CP) simulations. Different CP models as well as different choices of model parameters were employed and evaluated for texture predictions. With an appropriate choice of crystal plasticity model and model parameters, the deformation texture can mainly be predicted, although the accurate intensities are hard to reproduce. The corresponding recrystallization textures, either generated through spontaneous recrystallization of the extruded profiles or through post-extrusion annealing, are far more challenging to reproduce with available recrystallization models.INTRODUCTION Extrusion is a widely applied thermal-mechanical process to produce aluminium profiles. The properties of the profiles, for example mechanical, fatigue, fracture, corrosion as well surface appearance, are strongly dependent on the underlying microstructure and texture, and the requirements with respect to these aspects may vary with applications (Ralston et al., 2010; Dumoulin et al., 2012; Donati et al., 2013). Moreover, it is often a challenge to produce extrusions with a consistent and homogenous grain structure and texture along as well as through the cross section of the profiles. It is thus vital to understand and be able to predict (model) how different microstructures and textures are formed and how they evolve during and after extrusion, as basis for controlling the final appearance and properties of extruded profiles."

Jan 1, 2018

"Bay d'Espoir is in the approximate center of the south coast of Newfoundland. The geology of the area can most conveniently be considered in terms of three units: (1) an Ordovician or older polydeformed terrain termed the Little Passage Gneisses; (2) a Lower-Middle Ordovician volcano-sedimentary sequence assigned to the Baie d'Espoir Group; and (3) granitoid intrusive rocks of mid-Paleozoic age. Mineralizing events accompanied the formation of the latter two units.The Baie d'Espoir Group comprises a dominantly sedimentary sequence of pre-Middle Ordovician shelf and distal turbidite sediments deposited on the eastern margin of Iapetus. A significant volcanic component is, however, present in the Isle Galet Formation, consisting of up to 30% felsic volcanic rocks interbedded with sedimentary and epiclastic rocks. The Isle Galet Formation hosts several disseminated to thinly bedded Pb-Zn-Ag occurrences associated with altered felsic tuff and graphitic shale. They occasionally grade laterally into pyrite iron formation and appear to have been deposited in a very distal volcanic environment. The Isle Galet Formation is a time equivalent of the mineralized pre-Caradocian island-arc sequences of central Newfoundland, but differs from them both in style of volcanism and in the nature of the associated mineral deposits. It is, however, comparable in many respects to mineralized volcanic sequences in the La Poile Bay area of southwestern Newfoundland.Mineralization associated with granitoid rocks in Bay d'Espoir is best developed around the southeast margin of the North Bay Granite, where two-mica leucogranite forms a marginal phase. Numerous minor base metal showings occupy quartz, quartz-carbonate and barite veins in the adjacent sedimentary rocks. Collectively, the showings exhibit a well-developed, zonal pattern around the granite margin; molybdenite (±py, cpy) predominates near the contact, giving way outward to galena (±sph, py, asp, cpy) and eventually to stibnite (±asp, py) at the periphery. Mineralization associated with granites in similar settings elsewhere in southern Newfoundland includes tungsten in the Grey River and Granite Lake areas and molybdenite in the Rencontre Lake area."

Jan 1, 1982

By D. Holz

In this work we present a novel level set-based model for the real-time simulation of soil deformations. A level set defined by a signed distance function and sampled in a regular 3D grid represents and tracks the soil volume under deformation. Moving away from classical 2.5D heightfield representations of soil to a full 3D volume representation allows for improved tracking of cutting tool operations and the simulation of near-vertical or vertical soil faces. The proposed level set representation furthermore provides a versatile mathematical platform for modeling additional effects such as soil slip, and does not suffer from the sampling limitations of commonly used heightfields. Cutting forces applied to the tool are simulated via a formulation based on the Fundamental Equation of Earthmoving, modified to support inclined soil surfaces and transient states of tool motion. Discretisation of this 2D cutting force model with respect to the tool surface allows capturing the effects of irregular 3D terrain shapes on blades and buckets. The surcharge created during cutting operations is tracked in the form of particles and included in the soil failure force computation. We make use of an adaptive, hybrid level set-based and particle-based soil deformation scheme, which allows the soil deformation to be simulated in real-time.

Aug 1, 2013

By D. H. Stonehouse

Of the f ive Canadian cement producing regions- Atlantic, Quebec, Ontario, Prairie and Pacific-Ontario has the greatest capacity and normally produces the most cement. However, during the last 5 years the greatest activity within the industry in Canada has been in the Prairie and Pacific regions where major capacity increases have taken place. Most Canadian cement companies produce normal Portland, high-earlystrength Portland and sulphate resisting Portland cements. Some companies also manufacture moderate Portland cement, and low-heat-of-hydration Portland cement. Escalating energy costs highlight the need for technology research into more energy-efficient equipment for the energy-intensive cement industry. The industry is well integrated and plants are well situated to support construction in Canada. Expansion into the United States has become common during the past decade.

Jan 1, 1984

By F. Hampshire

"IntroductionThis paper is intended to cover questions raised by operating staff at various installations and is not intended to give comprehensive coverage of power plant and power system design. The paper is concerned mainly with the electrics , although a brief section gives the reasons for selection of diesels rather than other prime movers.The material is not new but brings out points which seem to be raised regularly during the design , commissioning and operation o f a new plant. Diesels versus other Prime MoversDiesel-electric plant for the mining industry falls into two major categories -emergency power and prim e power.1) Emergency power (for use only when the regular utility supply has failed) requires reliable starting and operation and reasonable first cost. Fuel economy and maintenance are of little importance as the machine(s) generate few kilowatt hours only. The diesel's competition in this field is the gas turbine, however diesels are more widely used than gas turbines in this application.2) Prime power is a different situation as the bottom line of total cost is highly affected by fuel costs.In general , mines which are within reasonable transmission distance of an existing utility find the lowest net cost result s from hooking up to the utility. If a min e is remote from an electric utility then the possible alternatives are:a) Hydro- electric power if there is a site capable of development at reasonable cost including the cost of transmission facilities. Such sites are not common, but brief and inexpensive considerationof this possibility is warranted .b) Diesel power with consideration of different grades of fuel.c) Thermal (steam) power generation from coal or oil.d) Gas turbines.In addition to the above there is the possibility of wind power (as a supplementary source) and a number of technologies which may become feasible in the future (e.g. small nuclear plants, fuel cells). For obvious reasons, small isolated generating systems required for remote mines, tend to lean to conservative technology.Among the fossil fuel plants, the diesel enjoys advantage on over-all costs as summarized in Table 1."

Jan 1, 1986

By W. A. Jones

"The Hollinger gold mine is in the Porcupine area, Cochrane district, in northern Ontario. The adjacent town of Timmins, which has a population of 25,856, lies 490 miles by railway north of the city of Toronto.The property was staked in the late summer of 1909. The original four claims were staked by Benjamin Hollinger, after whom the mine was named. Development commenced in the autumn of 1909 and mill construction in the winter of 1910. A catastrophic forest fire swept the district in 19ll, destroying the surface plant, so that the original 300-ton mill was not completed until June 1912. From that date up to December 31, 1945, 44,280,750 tons of ore have yielded 13,636,796 oz. gold and 2,613,354 oz. silver. The total value of the production has been $363,638,315.0REBODIES AND MINERALIZATIONThe orebodies consist of quartz veins, stringer lodes, and scockworks, with associated pyritized wall-rocks. The width of individual orebodies, as exposed by mining operations, ranges from 1 to 70 feet and averaged approximately 10 feet in 1942. The vein system forms a complex pattern in a favourable zone, which in places is 6,000 feet long and 4,000 feet wide. The deepest level being developed is 5,150 feet below the surface. Few veins are persistent for long distances, although some are continuous for more than 1,000 feet longitudinally and vertically.The host rocks consist of a closely folded series of Precambrian lava flows of Keewatin age. These are schistose and hydrothermally altered, but are believed to have originally been of intermediate to basic composition. The schistosity strikes N.70°E. and dips to the south at 75° to 80°. The structure of the formations is complex, but in the principal ore-bearing zone the general dip of the flows is to the south at a slightly flatter attitude than the schistosity."

Jan 1, 1954

By T L. Horsley

This paper deals with the drilling and blasting methods employed at the Cassiar mine, which is located just south of the B.C.-Yukon border. It covers both the "pit" and "peak" mining operations. Specific problems, such as working in frozen ground, are discussed, and the breaking characteristics of the various rock formations are outlined. The paper concludes with a brief mention of the equipment used in the operation, as "~ell as an outline of the breaking costs. Introduction T HE Cassiar asbestos mine is located just south of the British Columbia -Yukon border high on a spur of McDame mountain. Chrysotile asbestos fibre occurs in a faulted enlargement of a serpentine sill lying conformably be-tween a series of sedimentary beds and volcanic flows which dip at 45 degrees into the mountain. One end of the orebody is eroded by a cirque in which a layer of permanently frozen ore and waste talus lies at the end of the mining benches. The topography at the mine is steep, with no flat areas. Roads, dumps, and areas for crushing,

Jan 1, 1965

By Garth D. Kirkham

The Problem The Don deposit is a series of two sub-vertical zones that pose a number of challenges with respect to modeling and interpolation. The first challenge is that, based on data and observations, the mineralization and, more importantly, the grade is layered or banded and is stratigraphically controlled. The second challenge is that, due to the undulations of the deposit and extreme changes in dip, using a standard oriented ellipse to guide the estimation process is not appropriate and does not result in an estimate that is representative on a local scale. In order to solve this problem an adapted methodology of relative elevation modelling, has been devised to effectively model and estimate deposits faced with these challenges. Relative Elevation Designed for bedded seam and gridded surface With variable dip and vertical grade variability

May 1, 2013

By D. C. Sharpstone

THE Polaris-Taku mine is a new gold property, situated in the far north-west corner of British Columbia. Production was started in November, 1937, at the rate of 150 tons a day, and recently has been increased to 200 tons. The property, which promises to become one of British Columbia's important gold mines, was developed and brought into production in twenty-nine months after work was started on it as a virtual prospect in June, 1935, by Edward C. Congdon and associates. Inaccessibility, extraordinarily complicated geological problems, and difficult metallurgy retarded development of the property before acquisition by the present interests, an::l, in fact, discouraged two companies that had spent substantial sums upon it from continuing development. This paper is concerned with reviewing the development of the property and describing the principal features of the geology, the mining and metallurgical practices, and the equipment employed. Acknowledgments The writer is indebted to Mr. Edward C. Congdon, President of the Polaris-Taku Mining Company, and to various members of the mine staff for their assistance in assembling the data for this paper. Special thanks are due to Mr. George G. Griswold, Jr., of Butte, Montana, who generously and painstakingly prepared the section dealing with milling and power. Microscopic studies of ores were made by Professors Frank Grout an::l G. M. Schwartz, of the University of Minnesota, and by Mr. Griswold.

Jan 1, 1938

By I. H. Warren, F. A. Forward, A. Vizsolyi

"Observations are reported on the pressure leaching of material produced by subjecting chalcopyrite to two types of heat treatment. Calcination of the mineral at 825°C, in the absence of oxygen, induces some sulphur loss by volatization, producing a material from which copper can be leached more rapidly than from chalcopyrite. Treatment of the mineral with elemental sulphur at 475°C leads to sulphur uptake accompanied by a change in mineralogical structure of the chalcopyrite. Copper is prefer-entially and rapidly leached from the sulphur-treated material. A tentative explanation of the sulphur-chalcopyrite re-action is presented."

Jan 1, 1968

By Luis Bergh, Juan Olivares, Juan Durán, Juan Yianatos

"In the last decades heuristic approaches based on logic rules have been one favored tool to control flotation units and plants on top of distributed control systems. Fundamental knowledge on flotation processes, expressed in reliable models, and programs to assure the quality of the information, contained in available measurements, are still insufficient to develop robust predictive control strategies. In this paper the idea of using simplified models, when a known disturbance is coming into the process, is explored. As a first approach, the set points of the froth depth and air flow rate controllers are estimated based on this model. Since these target predictions are only approximate, a conventional feedback expert system, based on logic rules, continues the task of calculating the set points of the distributed controllers, in order to decrease the gap between actual and desirable metallurgical targets. This combined actions permitted a fast response of the process to change the operation of the circuit when a measured disturbance is detected. This control system was implemented and experimentally evaluated in a pilot rougher flotation circuit, with three pneumatic cells, with froth depth and air flow rate controllers in each cell. Since the circuit is operated for the air-water system, a phenomenological model, with parameters estimated from industrial data, is fed on-line with real operating variables and virtual values, characterizing the feed (grades, solids%, particle size distribution), in order to predict the metallurgical targets (recovery and concentrate grade). Several cases are discussed showing the benefits of this control system and the possible improvements to work on. INTRODUCTIONToday, large size mechanical flotation cells of 100 to 300 m3 are used in rougher operation in different flotation industrial plants, in Chile and worldwide. However, in spite of the advances in fundamental research and the notable growing in equipment size, with more complete instrumentation systems, there are still a lack of reliable data for industrial flotation modeling and simulation to advance in better control systems design."

Jan 1, 2016

By Helen Francis

Over the last decade, lower ore grades and deeper mine environments have demanded that mining companies develop new technologies (tools and processes) to ensure a mine?s economic sustainability. At Inco Ltd., this demand has lead to the focus of technological development within the area of automation. Delineation (Drilling and Interpretation) is a key step in the determination of ore grade and location and therefore was chosen as a priority area for enhancement through automation. Focusing on the tools (the diamond drill) automation, significant benefits have been consistently achieved in terms of productivity, process efficiency, operational safety, cost reduction, component life cycles and machine reliability. It is suggested that optimum benefits have yet to be achieved, and will not be achieved until the human aspects of automation have been properly addressed. Since project inception, the human aspects of automation were recognized as critical to the success of the diamond drill automation project. However, it was only upon the installation of the Automated Diamond Drill in the field and its continued use on a daily basis that this issue received due attention. The human aspects of automation can be broadly addressed as economic, physical and psychological. This paper, with examples from the field, will discuss the human aspects of automation in each of these areas. The paper will draw from observations and experiences acquired throughout this project and recommend implementation strategies that should be utilized in future automation projects to enhance both the acceptance of automation and the success of the automated process itself.

May 1, 2002

By Graeme G. Strathdee

"IntroductionThis paper presents an overview of the industry status, describes current potash industry practices at three mills, and summarizes developments that have taken place since the previous review by Banks (1985).The commodity potash is produced in both New Brunswick and Saskatchewan from the evaporite ore sylvinite. This ore is a mixture of co-crystallized halite, NaCl, and sylvite, KCl, and a minor assortment of silica, carbonate, sulphate, and clay minerals. Carnallite, KMgCl3.6H20, is also dispersed throughout the bedded deposits and can affect the recovery of sylvite for fertilizer and industrial uses.Canada continues to be a principal source of supply of agricultural and industrial potash products. Figure 1 shows the sector performance between 1989 and 1997 in the context of the world supply and demand situation as reported by Prud'homme (1997) of Natural Resources Canada.Potash industry output is traditionally measured as the quantity of potassium nutrient and reported as tonnes ofK20. Mineralogically, the principal form of potash produced in Canada is sylvite, KCl, and 1 nutrient tonne K20 corresponds to approximately 1.64 tonnes of sylvite of agricultural grade, about 95% KCI. In 1997, the Canadian industry milling capacity was 13.4 million metric tons (Mt) ofK20 (22 Mt KCl) while the actual production was 9.0 Mt K20 (14.8 Mt KCl). Worldwide milling capacity in 1997 was 35.9 Mt K20 (58.8 Mt KCl) and global consumption was 25.3 Mt K20 (41.6 Mt KCl). Canadian producers can deliver about 35% of the global demand for potash commodities"

Jan 1, 2000

By Tadeusz W. Wlodek

THE known phenomenon that a test-piece of ferro-magnetic steel is magnetic after it has been broken in tension indicates that, while it is being loaded, the steel acquires magnetic properties. In the present investigation of the influence of the stress on the magnetic flux, repeated pulsating stresses of increasing amplitude, varying from zero to the maximum tensile value, i.e., pull-pull loading, were employed. The specimens were prepared from two types of carbon steel and two of alloy steel. The magnitude of the magnetic flux was determined indirectly. The voltage and mode of variation of the electromotive force induced in a coil surrounding the stressed steel specimen were measured as an indication of the varying magnetic flux within the specimen. Curves representing the electromotive force induced by the varying magnetic flux show that as the tensile load increased so also the magnetic flux increased, with a corresponding increase in measured e.m.f. At a certain stress there is a sharp bend in the voltage curve (point Win the diagram, Figure 5); this critical stress corresponds very closely with the yield stress (0.2 per cent permanent strain). Beyond this point, slight increases in the stress produce large increases in the voltage. The wave form of the e.m.f. was registered on an oscillograph. Analysis of the curves so obtained demonstrated the necessity of continuing these experiments, in order to determine the type of induced wave form associated with various types and amplitudes of stresses. In these experiments, the shape of the stress wave was sinusoidal, although the shape of the induced e.m.f. was sinusoidal only up to a certain load and became more and more complex above this load.

Jan 1, 1944

By H. Perez, A. Lavoie, V. Prévost, P. Létourneau, P. Lind

The Home smelter is a custom copper smelter located in Rouyn-Noranda, Quebec. In 2005, the smelter produced 145,000 t of copper containing 807,000 oz of gold, 20,388,000 oz of silver in addition to 515,000 t of sulphuric acid. Recently, a flexible flow sheet has been developed incorporating the intermittent use of the Noranda Continuous Converter allowing for the increasing or decreasing of production based on market conditions, while attaining 90% or greater sulphur fixation regardless of operating mode. For 2006, the smelter is operating in full production mode and production is expected to be approximately 185,000 tm of copper. Mechanical modifications, process changes, metallurgical concepts, minor element treatments, and operational techniques that have allowed the smelter to develop this flexibility are presented. Current efforts to increase the productivity of the converter aisle and anode furnaces as well as improvements being made to address fugitive emissions are also discussed.

Jan 1, 2007

By E. J. Burrough

MR. J. J. McIntyre (International Coal & Coke Company, Ltd., and McGi1livray Creek Coal & Coke Company, Ltd., Coleman, Alta): Mr. Burrough's excellent paper, Metallurgical Coals of the Crowsnest Area, seems especially timely now, when the need for developing iron industries in the west, as well as in the east, is receiving so much attention. His -thorough review of the 'coking' industry is an especially valuable contribution, along with which the following brief remarks on coking in the Crowsnest Pass area of British Columbia and Alberta may be in order. When the Crowsnest Pass line of the Canadian Pacific railway was built there were great expectations for the non-ferrous metal industry; quite a number of smelter's were al-ready in operation in British Columbia and the northwestern United States, and further expansion was confidently expected. The suitability of the medium-volatile coking coals of the Pass for making metallurgical coke had been recognized from the time the fields were first explored. By the time the mines were fairly well developed there was already a market to war-rant the building of coking plants, and a common belief that expansion of the market would require a large coking industry. The first coke production was from plants built by the Crowsnest Pass Coal Company, Ltd., at Fernie, B.C. in 1903, and the International Coal and Coke Company, Ltd., at Coleman, Alberta. These plants were followed by others built by the Crowsnest Pass Coal Company, at Michel, B.C., by West Canadian Collieries, Ltd., at Lille, Alberta, and by Leitch Collieries, Ltd., at Passburg Alberta, and by a plant at Hosmer, B.C.

Jan 1, 1951

By W. Wallace

The aerospace industry celebrated 100 years of powered flight in 2003, and the remarkable achievements that have occurred during the past 100 years are in no small way due to major developments in materials. Modern alloys for airframes, engines and other major sub-systems have evolved through the intelligent application of new processing concepts involving melting, casting, hot and cold working, heat treatment and more recently vapour phase processing. Alloy design has evolved in parallel to allow maximum benefits to be achieved from these processing advances. However, the pace of development seems to be slowing and future gains are likely to be made by learning how to extract major value from aerospace assets. Understanding the modes of deterioration and establishing cost effective lifetimes by holistic life cycle management seem to be the way of the future. Extending component lifetimes by repair, rejuvenation and refurbishment are all viable possibilities and they offer great opportunities for Canada, which, traditionally, has been a major user of modern aerospace materials rather than a supplier. The challenges for metallurgist, physicists and engineers will be no less than in the past and should create new business opportunities for Canada. The scenario described above will be developed by calling upon examples drawn from the author's experience.

Jan 1, 2004

By J. A. Finch

"Much progress has been made over the last several years in the ability to measure flotation cell hydrodynamic parameters in both the laboratory and plant. These techniques have allowed fundamental research to proceed to determine the effects that frother chemistry has on the main hydrodynamic parameters (gas hold up, bubble size) as well as on the amount of froth generation and water content of froth. A research program was begun that brought together a team consisting of private companies and a University with expertise in hydrodynamic characterization (McGill), flotation reagent applications (Flottec) and chemical synthesis (Sasol N.A.) with the purpose of characterizing frother chemistries with two goals in mind: Determine which frother chemistry can provide optimized cell hydrodynamics; and, create new frother chemistries with specific hydrodynamic properties.This paper describes the key steps that were taken that led to the development of new frother chemistry for use in flotation.The first step was the characterization of the major frother chemical families in a two phase system. The parameters measured were gas hold up, bubble size, froth height and water carrying rate at different concentrations and gas velocities.Analysis of the data indicated that definite patterns existed between frother chemistry and hydrodynamics and showed that frothers could be grouped into classes. More importantly, by modifying known frothers through chemical reaction it was shown that these frothers could be moved from one class to another. As a result of this better understanding of the interdependence of hydrodynamic and chemical properties, a new frother chemistry was proposed that was predicted to perform similarly to MIBC.The new frother was synthesized and hydrodynamic testing confirmed that the chemical performed similar to MIBC. Laboratory flotation tests were conducted on two different ore types that also confirmed the similar performance of the new chemical and MIBC. Subsequently, the new product was placed on a plant for a short period of time. The results showed that the product was an excellent frother but increased the flotation rate slightly more than MIBC at the same addition rate.Further research showed that the new frother chemistry was a family of products. By changing the reaction the resultant products could be made to be slightly weaker or stronger than MIBC but that this chemistry cannot provide hydrodynamic/froth characteristics similar to strong frothers like glycols and glycol ethers. Further work is planned to conduct longer plant trials to confirm the efficacy of this new frother family."

Jan 1, 2007

By M. Rafieazad, P. Fathi, X. Duan, M. Mohammadi, A. M. Nasiri

"Direct metal laser sintering (DMLS) is a metal additive manufacturing technology that creates highly complex components by fusing metal powder into a solid part. In this study, the impact of surface roughness on corrosion resistivity of AlSi10Mg_200C alloy manufactured through DMLS was investigated. The as-printed DMLS-AlSi10Mg _200C alloy was subjected to various surface finishing processes including grinding and sandblasting. The corrosion performance of the surfaces was then evaluated using potentiodynamic polarization testing and electrochemical impedance spectroscopy (EIS) in a 3.5 wt.% NaCl solution to mimic seawater environment. Surface characterization and corrosion morphology of the samples were assessed by Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) spectroscopy. The results of this study show that the surface finishing process and the resultant surface roughness has a significant impact on the corrosion resistivity of the DMLS-AlSi10Mg_200C alloy in the seawater environment.INTRODUCTION Direct Metal Laser Sintering (DMLS), also known as Selective Laser Melting (SLM) (Sames, List, Pannala, Dehoff, & Babu, 2016), Laser Beam Melting (LBM), or Laser Metal Fusion (LMF) (Herzog, Seyda, Wycisk, & Emmelmann, 2016), is an additive manufacturing process that utilizes a precise, high-power laser to micro-join powdered metals and alloys layer by layer to form almost fully dense and functional components in three dimensions from the 3D computer-aided design (CAD) data. Complex geometries not possible with conventional manufacturing processes can be readily manufactured with high accuracy using the DMLS process with no need to time-consuming tooling."

Jan 1, 2018

By N. Schreithofer

The deposition of octadecylamine (ODA) at the KCI crystal/NaCI-KCI brine interface was investigated using atomic force microscopy (AFM). The AFM images of freshly cleaved KCI specimens immersed in KCI-NaCI saturated brine at room temperature reveal disappearance with time of the atomic steps and formation of cubic NaC1 crystals. These crystals were found to form when the specimen was withdrawn from the saturated solution. Depending on the way of contacting the specimens with the octadecylamine dispersion, the AFM images show huge differences in the deposition patterns of ODA on KCI crystals. Adequate dispersion was found to help the formation of quite even ODA coverage. The coverage was several monolayers thicker when air/brine/solid contact took place, suggesting that in the potash flotation the collector is likely to be carried to the solid surfaces by air bubbles. The presence of methyl-isobutyl carbinol (M IBC) enhanced the dispersion of ODA in brine, thus helping the spreading of the surfactant on the KCI crystal surface.

Jan 1, 2006