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By Augustine O. Orumwense, Micheline Boisclair

"The use of stirred mill to complement tumbling mills in grinding fine grained minerals is increasingly becoming an attractive processing option. Parameters such as agitation speed, grinding media type and size, feed pulp density, and grinding time were studied in order to elucidate their impact on stirred milling. Test results showed that the parameters have a profound effect on stirred mill efficiency and operating cost. A comparative test with a tumbling ball mill was also made and the specific energies of both mills in fine grinding were analyzed. A difference of over 40% in energy savings particularly when the product size is smaller than 20 µm was obtained with the stirred mill.INTRODUCTIONIn industrial processes where very fine and ultrafine particles are required such as in chemical, ink, food, paint and lacquer, pulp and paper, plastics, pharmaceutical, metallurgical and ceramic industries, the use of stirred mills for grinding is well established. Mineral processing plants are gradually shifting focus to the use of stirred mills for fine grinding and /or regrinding purposes as the target liberation size gets very small. A number of plants processing finely/sparsely disseminated ores are known to have adopted stirred milling technology for their fine grinding needs (Enderle et al., 1997; Harbort et al., 1999; Gao et al., 2000; Davey, 2003 & 2006; Pease et al., 2006).There are different kinds/designs of stirred mills available on the market but, all can be divided into two sub groups namely fluidized and non-fluidized types. The non-fluidized stirred mills consist of Tower mill, Vertimill, Sala agitated mill (SAM), and ANI-Metprotech (SVM). These mills are characterized by their low-speed and the use of fairly coarse grinding media size, 3 – 20 mm. Hence, they are mostly suitable for relatively coarse grinding application. The fluidized type includes the Isamill, Netzsch mill and Stirred mill detritor (SMD). These mills have a characteristic high agitator speed, use fine grinding media size of 0.5 – 5 mm, and are employed in very fine grinding operations. The superior fine grinding capability of stirred mills is attributable to two main process parameters, which are the use of fine grinding media and a high mill speed."

Jan 1, 2008

By Polysius AG

"The Lone Tree demonstration was an important milestone in bringing High Pressure Grinding Roll (HPGR) technology into hard rock applications in the mining industry. HPGRs have become standard equipment in the cement, iron ore, and diamond industries over the past fifteen years, but their use in severe duties found in the hard rock mining sector has been restricted due to high roll wear and subsequent low availability. HPGR availability has historically been limited because of frequent downtime for edge weld rebuilding as the rolls wore and short tyre life from high roll surface wear rates.Recent advancements in HPGR wear protection are now being evaluated for commercial applications in the gold and copper mining industry where this technology may offer benefits in comminuting hard and/or abrasive ores and in improving metal recovery in heap leaching applications.Proving the feasibility of HPGRs for processing competent, abrasive gold ore, Newmont Mining Corporation, the world's largest gold producer, operated an HPGR demonstration plant employing a POLYSIUS (POLYCOM) HPGR incorporating some unique wear protection, at their Lone Tree gold mine near Winnemucca, Nevada. Results of the successful demonstration are presented and evaluated in this paper.The Lone Tree HPGR demonstration plant operated for three months, from April through June 2003. The HPGR operated for 1626 hours and processed 141,000 tons of ore. This technology demonstration focused on measuring operating performance, wear characteristics, and availability of today's HPGR technology.Polysius' innovative roll surface wear protection system eliminated edge-welding downtime. Improved surface wear protection extended tyre life to predicted durations acceptable for very abrasive service. The POLYCOM HPGR is now deemed suitable for selected hard rock applications."

Jan 1, 2005

By Manqiu Xu, Peter Wells, Gord Bacon

"A methodology is proposed for milling flowsheet design using flotation rate, selectivity and residence time distribution data. The flotation rate data and the difference in flotation rates between the main minerals to be separated are determined from laboratory batch tests. The residence time distribution (RTD) data is calculated using the tanks-in-series model assuming each flotation cell is a perfect reactor. The rate, selectivity and RTD data can be used to calculate the optimum flotation cell number in a bank for rougher/scavenger in a commercial plant.This methodology is demonstrated in a case study of a nickel sulfide ore. It is shown that miniplant rougher/scavenger data can be closely predicted from a batch test using the proposed methodology.INTRODUCTIONIt has been the trend in the past several decades that large flotation cells are increasingly used. This is largely driven by the economics as ore grades are getting lower and the rate of ore processing must be increased in order to keep mining operations economically viable. The development and evaluation of 250 to 500 m3 WEMCO SmartCell and Outokumpu TankCell flotation machines are well in progress. There are many advantages in using large cells: fewer cells, less floor space, lower power cost (although this is now being questioned for fine particle flotation), simpler circuit, simpler control, and lower auxiliary equipment cost (Arbiter, 1999). As flotation cells are getting larger, the importance of cell hydrodynamics, namely, air/slurry dispersion, power intensity, froth transfer, residence time distribution (RTD) and short-circuiting are being fully recognized (Jonaitis, 1999; Weber, et al., 1999; Gomez and Finch, 2002). It is not the intention of this paper to discuss flotation cell scale-up. The intention is to answer what is the optimum number and size of cells in a flotation bank for a given throughput. Figure 1 illustrates this problem facing design engineers. The same mean residence time required for a given throughput can be achieved in a single large cell, or many smaller cells in a row. A few cells of large size may be more cost-effective but they may not be as effective as more cells of smaller size in achieving the optimum metallurgy."

Jan 1, 2005

By M. R. Khalesi, S. Bellec, C. Bazin, D. Hodouin

This paper proposes a classification model to predict the split coefficient of gold ore particles as a function of the particle size and gold content. The model is calibrated and validated using data obtained from the sampling of an industrial grinding circuit. Model calibration is based on a complete simulation of the circuit and involves parameters related to the gold grain distribution in the ore as well as a grinding and liberation model. Since cyanide is added into the studied grinding circuit, assumptions related to gold dissolution in the mills are made to allow simulation results which reflect industrial behaviour patterns.

Jan 1, 2011

By M. A. Cawley, J. W. Jordan

"IntroductionTHE ORE PILLARS in the lower ""A"" ore body of Waite Amulet Mines, Limited, can be divided into two groups, those mined in the open by sub-level blast-hole methods, and those to be mined .against coarse rock fill. Of the three pillars in the last group one has been mined and is dealt with in this paper. The method of mining pillars against coarse rock fill was suggested by the late Dr. Oliver Hall, who was Consulting Engineer for the Company when recovery of No. 2 East pillar was being planned.HistoryThe Waite Amulet mine is in northwestern Quebec, nine miles north of the town of Noranda. The property is approximately three miles long by one mile wide. The present Company, which was formed by the amalgamation of Amulet Mines, Limited, and Waite Ackerman-Montgomery Mines, Limited, commenced operations in the summer of 1937. In the fall of 1939 a new .flotation mill was erected with a capacity of 1,200 tons per day, which was increased to 1,800 tons per day in 1943. The mill is presently operated at 1,400 tons per day.To date, seven orebodies have been found, the major ones being Lower A, East Waite, and Waite. Three separate concentrates are produced, copper, zinc, and pyrite. Total tonnage mined to the end of 1954 from all orebodies has been 7,340,000 tons, which averaged 4.6 per cent copper, 5.3 per cent zinc, and 0.037 oz. gold and 1.27 oz. silver per ton."

Jan 1, 1955

By Arnaud Faucher, Claude Bazin, Marilène Renaud, Mohamed Mai Manga

"Grinding circuits are operated in the presence of disturbances due to ore changes and equipment malfunctions. One of the challenges faced by the operators is the detection of a disturbance, the identification of its origin and of the action needed to minimize its impact on the process. Hydrocyclones overloading, worn or partly plugged apexes of the units of a nest, surging and internal liner detachment may cause a loss of classification capacity and quality. Recovery losses in downstream leaching or flotation circuits justify the effort in developing techniques for the detection of hydrocyclone malfunction. Two approaches for the detection of hydrocyclone fault are presented in this paper. The first proposed method uses the conventional sensors available in a grinding circuit allowing real time detection of hydrocyclone abnormal operation. The second technique is based on the use of vibration sensors installed on the hydrocyclone of a nest. This last technique enables the classification of the hydrocyclone malfunction as surging, overloading and plugged apex. The two techniques can be combined to increase the robustness of the problem detection.INTRODUCTIONHydrocyclones are used for many purposes ranging from water separation, fines removal and obviously for the preparation of the feed for subsequent concentration circuits in a mineral processing plant. The strategic role of the hydrocyclones for the preparation of the feed to the concentration circuit is often underestimated because of their simplicity of operation and robustness (Napier-Munn et al., 1996; McIvor, 1988). It remains that despite their simplicity, hydrocyclones have been studied extensively from 1970 to 1990 with the objective of developing mathematical models of their operation to be incorporated into grinding circuit simulators (Napier-Munn et al., 1996; Lynch, 1977; Flintoff et al., 1987). Such a development effort is already an acknowledgement of the importance of these units in a mineral processing plant. Several authors (Del Villar et al., 1996; Plitt and Kawatra, 1979; Casali et al., 1998) proposed soft sensors to estimate the classification efficiency of hydrocyclones using sensor measurements. However, few of the proposed sensors are used in the industry. More recently several papers were published to discuss the application of 3-D modelling of the hydrocyclones (Narasimha et al., 2005; Cullivan et al., 2004) and sensors (Bond et al., 1999; Neesse et al., 2003; Hou et al., 1998; Olson and Waterman, 2004; Williams et al., 1995; Willams et al., 1997) to help in the detection of hydrocyclone malfunction."

Jan 1, 2010

By T. Motegi

Semisolid casting provides grain refinement of the cast structure and prevents macro-segregation. The conventional semisolid slurry is obtained by electromagnetic or mechanical stirring. In our process, the magnesium alloy (AZ31) slurry is made using an inclined cooling plate instead of the conventional methods. The slurry obtained is cast into a twin-roll caster and makes a continuous sheet of 2 or 3 mm thick. The most important factors that influence the sheet casting are the casting temperature and twin-roll speed.

Jan 1, 2007

By P. Simon, G. Falkinger, G. Angerer, B. Gerold

"This contribution presents an investigation of the evolution of shrinkage pores during hot rolling with a special focus on the microscopic mechanism. The reliable closure of pores, which inevitably occur during the casting process, is of crucial technological importance for high-quality hot rolled plate products. Therefore, lab-scale tests were carried out under different typical thermomechanical loadings. Extensive data from optical microscopy was collected before and after deformation. The analysis shows that the average volume of pores evolves similar to the volume of an idealized arrangement of voids in an ideally plastic matrix. The average shape of the shrinkage pores, however, was found to be almost constant during deformation. Even though individual pores exhibit complex morphologies far from any idealized geometries, the overall evolution of a large number of pores is well captured by simple assumptions. In addition to the quantitative analysis, a schematic representation of this counter-intuitive behavior is provided. A simple ‘Gurson’-type void evolution equation was implemented in a three-dimensional Finite-Element model of the industrial hot rolling process. With the help of this mechanism-based process simulation the thermomechanical closure of shrinkage pores during the rolling process has been optimized for a variety of plate products.INTRODUCTION Aluminum alloys of the 7xxx series are widely used in the aircraft industry. They have to meet high quality standards regarding microstructure as well as mechanical properties. For hot-rolled aircraft plates, one of the most important quality requirements is that they are free from pores. Pores, however, are inevitably created during the casting process either due to shrinkage or due to the dissolution of gas from the melt. The pores have to be closed mechanically during the hot-rolling process. Therefore, the mechanism of so-called pore closure or void closure has a high technological relevance for the production of aircraft plates. The behaviour of voids in a ductile matrix subjected to mechanical deformation has been extensively studied, especially in the context of damage mechanics. A recent review (Besson et al., 2010) on modeling methods for ductile damage gives a good impression on how much experimental as well as theoretical effort has been dedicated to the problem of void evolution under mechanical loadings. Although void closure has been studied to a far lesser degree, it obeys to the same general theoretical evolution laws as void growth. The most basic theoretical result is that hydrostatic pressure drives void closure, while hydrostatic tension leads to void growth. The mechanism of void closure depends on the void shape. This is illustrated by the example of a flat penny-shaped void, which under compression obviously closes much faster than a sphere with the same volume. Theoretical models have been developed for the evolution of simplified void geometries, such as spheres or cylinders (e.g. Gurson, 1977), spheroidal (Gologanu et al., 1997) and ellipsoidal voids (Ponte-Castaneda, 1994). In industrial cast ingots, however, the pores exhibit very complex morphologies, which are far from any idealized geometry. X-ray tomography revealed ‘tortuous’ voids in a 5xxx aluminium alloy (Chaijaruwanich et al., 2006)."

Jan 1, 2018

By O. A. Bascur, J. Patrick. Kennedy

"The lack of integration of mining and metallurgical information at sufficient detail to act is a problem. Without such data, mine cut-off grade can not be optimized on a per grade basis. It is difficult to determine economics without integration of mine transactions, stockpile inventories, process flows and assays. Actions also require real time information from manufacturing assets, but corrected for gross errors from trucks, shovels, conveyors, faulty sensors, bad instrument calibration. Validation methods must include process models to identify corrupt actionable information. This paper presents new tools that use the model the process to sift through available data, identify and eliminate gross errors, and use statistical data reconciliation to create material balanced, internally consistent values. Uses of models allow data to be unified for useby both monitoring and decision making processes.A Real Time Performance Management (RtPM) uses unifying analysis methods to empower everyone in the organization with unparallel real-time intelligence, enabling them to continuously improve performance.BACKGROUNDExtraction of metals has become a global business; new economic and environmental forcing factors are present today which were unheard a couple of years ago that are causing companies to focus on plant operations. High ROI actions can be achieved internally which will increase mining and metallurgical processing unit efficiency and reducing operating costs if the proper information is provided those in the complex that can act. Large changes are possible with many of these small steps if the barriers for action are removed. The chief impediments are lack of infrastructure including the data, computing tools and essential data and bad information.Increased demands will be placed on the types, quantity and priority of information. Metallurgical complexes are attempting to become better neighbors, increase productivity, improve customer service, and satisfy the regulators and compliance groups -- all with fewer people and less costs."

Jan 1, 2004

By S. Vongpaisal, T. R. Yu

"A set of new blast damage criteria has been developed, with special reference to blasthole mining operations, for assessing damage by incorporating the vibration level, rock properties, site characteristics and the effects of ground support systems. The main objective of this work was to provide a database with reasonable accuracy for use in optimizing blast design, numerical analysis and ground control expert system module development.The new damage criteria allow one to estimate the degree of damage to rock structures in terms of a dimensionless parameter defined as Blast Damage Index (BDI). This allows for the description of blast damage in a unified form, and facilitates the development of codes for numerical modelling to express the degree of blast damage universally. A number of field investigations from several stope production and slot opening blasts at a large underground base metal mine were carried out to verify the developed index. The results show a good correlation between the observed damage and the type of damage predicted from the BDI values.Practical measures are also provided for minimizing blast damage in large underground blasthole mining operations"

Jan 1, 1996

By G. P. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Stress-corrosion cracking (SCC) tests were conducted in the near-neutral pH standard solution, NS4, and in an actual soil solution, using four-point bending at high a stress ratio and low frequency conditions very similar to those of operational pipelines. Pitting incubation appeared first and then pitting initiated and grew in both solutions although there were many more pits on the specimen tested in soil purged with 5% CO2 + 95% N2 than in the specimen tested in NS4 solution purged with the same gas. These observations show that samples in soil solution are more susceptible to pitting than those in NS4 solution. When the pit reached a critical size, the increased stress concentration around the pits, resulted in the transition to a crack.

Jan 1, 2005

By W. C. Whittaker

Introduction When one thinks of a coal stripping deposit, the picture that usually comes to mind is that of a more or less flat seam from two to twenty feet in thickness overlain by ten to fifty feet of overburden, in suitable ratio for economic operation. This is the usual type of stripping deposit and is quite a common occurrence in various parts of the prairie provinces. Rather unusual types of coal stripping deposits are being presently worked as open-cut mines by Sterling Collieries, Limited, and the Co al Valley Mining Company, Limited, at Miles 47 and 48 on the Alberta Coal Branch, some 150 miles south west of Edmonton. These deposits are of interest chiefly because they represent turned-up and greatly thickened sections of the Mynheer seam, and as such they present their own problems, peculiar to the commercial exploitation of a seam of this type. The area in which these deposits occur was originally owned by the Pacific Pass Collieries, whose operations, however, were confined to under-ground mining at Lovett, some eight miles to the southeast. It was not until l918 that the value of these deposits was realized, when the Company now known as Sterling Collieries, Limited, opened their pit at Mile 47. At the inception of the work, coal was loaded directly into the railway cars by men using wheelbarrows. In 1920, a tipple was built, after which the coal was loaded by steam shovel into mine cars, hauled by steam dinkeys, and loaded over the tipple into railway cars. In 1922, the Coal Valley Mining Company entered the field at Mile 48, with an entirely mechanical equipment, and at the present rime these two are the only stripping properties in Alberta using mechanical equipment both for the removal of overburden and the loading of the coal. These Companies have operated continuously since that time, and have to date mined and shipped 4,000,000 tons of coal, and moved some 5,255,000 cubic yards of stripping. The present annual coal output for the two mines is about 240,000 tons.

Jan 1, 1935

By Carlos F. Perucca, Maria Virginia Ramírez A.

"Chile based SQM S.A., exploits potassium chloride rich salts at the Salar de Atacama, in northern Chile. The process includes the solar evaporation of natural brines existing in the Salar salt bed, followed by conventional flotation to recover Muriate of Potash (MOP) for fertilizer use.This paper describes a structured method developed to aid in understanding the metallurgical response of the solar evaporated salts to conventional flotation. The method uses classical metallurgical data analysis combined with laboratory and plant-scale testing, and rudimentary mineralogical studies.As a result of the study, several changes were made to the flotation circuit which produced an operation that is much more consistent and easier to control, and has an increased recovery. An optimized circuit, currently being financially evaluated, has also been conceptually designed based on the findings of this work.INTRODUCTIONSQM S.A. is the world’s largest producer and distributor of specialty fertilizers, iodine, lithium, as well as a wide array of industrial and specialty chemicals. SQM is a public corporation whose shares are traded in the Santiago and the New York Stock Exchanges.SQM S.A. exploits the mineral rights at the Salar de Atacama in northern Chile. Its production processes involve the solar evaporation of natural brines existing in the Salar salt bed, aimed at the recovery of Potassium, Lithium and Boron compounds."

Jan 1, 2004

By R. D. Brown

The first step in achieving a rationalization of Canada's crazy patch-work quilt of mining taxes and policies was achieved with the release last November of a major federal-provincial report on the taxation of the Canadian mining industry. The Report, prepared by a group of federal and provincial civil servants, sets out a concise and informative discussion of the major taxation and incentive issues facing the mining industry, and puts forward major recommendations for more rational and moderate taxation policies. It will be considered by federal and provincial Finance and Resource Ministers for possible action by the respective governments. The Report was prepared in response to a directive from the federal and provincial First Ministers in February 1978 to review the federal and provincial taxation of the resource areas. Although the Report is more successful in identifying problems rather than concrete solutions, and reflects some continuing differences of opinion between the governments involved, it does represent an important first step in a comprehensive review of our resource tax policies. This article summarizes the Report, which is some sixty pages in length. Although a detailed discussion of it is beyond the scope of this article, the report itself is recommended reading for those concerned about the current state of the Canadian mining industry.

Jan 1, 1979

"11.1. IntroductionThe recovery of platinum-group elements (POE) from ores is a subject which has received almost no mention in the literature. Edwards (1975) refers to the process used for refining of the POE, throughout the Western World, as a so-called ""conventional"" process .... ""not because of the simplicity or convenience of the operations, but more probably because of the inertia of established processes and the aura of secrecy with which the major platinum refiners have surrounded this process."" There is no doubt in this writer's mind that the latter is also applicable to the dearth of knowledge of the mineralogy, geochemistry and ore deposits of PGE and that the poor recoveries, mainly attributed to the mineral beneficiation stages of concentration, are also affected by this traditional secrecy. Fortunately, this attitude is changing, due no doubt to the advantages that accrue from more open research which may be critically assessed in the literature in the traditional manner. Examples of this more open approach to recoveries and recovery problems are represented by Newman (1973), who gave some typical recovery percentages for Merensky Reef ores, and the recent encouragement and cooperation on mill samples from the Sudbury area by lnco Metals Company (cf. Cabri, 1981a).In general, platinum-group elements are recovered from an ore by the use of a physical concentration method, such as gravity separation or flotation, followed by further upgrading using further physical, wet chemical or pyrometallurgical techniques. The final process of refining in which the individual platinum-group elements are produced in pure form is outside the scope of this chapter.Platinum-group element deposits naturally fall into different categories according to the recovery process best suited for them, viz. those amenable to gravity separation, those amenable to flotation, and those where platinum-group elements are by-products of base metal sulphide, chromite and miscellaneous other deposits."

Jan 1, 1979

By L. Xu, A. Vazirnegad, R. Bhaskar

"Respirable dust samples are collected by the U.S. Mine Safety and Health Administration (MSHA) and mine operators as part of the requirements of the Federal Coal Mine Health and Safety Act of 1969. About 1.85 million respirable dust samples collected by MSHA were analyzed for the period 197/ to 1990 f or the states of Alabama, Colorado, Illinois, Kentucky, Ohio, Pennsylvania, Utah, Virginia, and West Virginia. Trends in coal dust exposure of continuous miner operators, helpers, and roof bolters were analyzed. The reported production in each of the nine states was analyzed. The relationship between average dust exposure and coal production was evaluated. In addition, the differences between mine operator and MSHA inspector collected data were examined for each state. The average exposure levels for the three occupations - miner operator, miner helper, and roof bolter were also compared.The data indicate that the dust exposure levels have significantly dropped over the last twenty years, while at the same time production has increased, attesting to the ability of the U.S. mining industry to adapt successfully to the stringent dust control regulations. In terms of coal production, it appears that some states, such as Utah, Illinois, and Kentucky, were able to increase their production significantly relative to others, such as Pennsylvania and Virginia. The relationship between dust concentration and coal production is, at best, tenuous. 11 implies that existing dust control technology has assisted several mine operators to meet dust standards, while, at the same time, enabling mines to produce more coal than before. Comparison of data collected by MSHA and mine operators indicate that MSHA inspectors recorded higher dust levels and lower shift production relative to mine operators."

Jan 1, 1993

By B. Rivard, D. Francis

A layered Archean magma chamber is exposed at the base of the Yasinski segment of the La Grande greenstone belt. This intrusive complex lies beneath a sequence of mafic volcanics and is underlain by granitoid basement which is crosscut by a swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm define a pronounced Fe-enrichment trend. The volcanic patterns of the La Grande and Eas tmain greens tone belts, however, define a series of iron depletion trends which originate in the iron enrichment trend of the gabbroic intrusives. These patterns suggest that the gabbros produced in the intrusive complex may serve as parental liquids for some of the lava suites of the James Bay greens tone belts.

Jan 1, 1984

By J. A. Finch

Solvent-coated air bubbles in the Air-Assisted Solvent Extraction (AASX) process achieve the dual role of high solvent specific surface area and ease of phase separation. The thickness of the solvent film is of fundamental interest but difficult to measure directly in the process itself. As an approach interferometry (in the UV-vis region) was used to measure the time dependent thickness of a film formed by blowing an air bubble in kerosene-based solvents. The film was stabilized by the presence of 1.5 ppm silicone oil, as employed in AASX. The film appears to comprise two layers; an outer "free" layer of almost constant thickness and an inner "bound" layer which decreased in thickness with time. The bound layer is considered relevant to AASX. For a 20 mm diameter bubble blown in LIX/kerosene solvent the initial thickness was ~ 3 um which decreased over 10 minutes to a final rupture thickness of 500 nm. The bound layer thickness and time to rupture decreased with decreasing bubble size. Correspondence to prior indirect estimates of solvent layer thickness is examined.

Jan 1, 2006

By Henry Hengeveld

Are the IPCC results credible? The most recent IPCC assessment is??an admirable summary of research activities in climate science? US National Academy of Science 2001 report to President Bush Joint statement by Academies of Science from 17 other countries ? May 2001 ?The work of the?IPCC represents the consensus of the international science community on climate change science. We recognize IPCC as the world?s most reliable source of information?and endorse its method of achieving this consensus.?

Nov 1, 2002

By J. P. Morris, J. T. Novak, E. A. Sarver

"A variety of reagents are utilized in coal preparation, but aside from performing their desired function relatively little is known about the behavior of these reagents within the processing circuits. Where exactly do reagents go once dosed? In this paper, we present preliminary results of partitioning studies on frother (i.e., MIBC) and collector (i.e., diesel) chemicals commonly used in coal flotation, and examine implications for water management (e.g., in closed-loop systems). Additionally, we discuss the usefulness of such data in predicting environmental transport and fate of chemicals – which is currently a top priority for industry.INTRODUCTIONThe purpose of coal preparation is to upgrade mined coal into more valuable products. Since coal is primarily used as a fuel source for electricity generation, product specifications are typically contracted to minimize unwanted constituents that detract from the overall heat value (e.g., ash and moisture) or that add to environmental pollution or other problems like corrosion at a power plant (e.g., sulfur) (Pitt & Millward, 1979). Failure to meet specifications results in a financial penalty for the coal producer (Szwilski, 1986), and thus preparation processes have evolved to simultaneously optimize recovery of valuable “clean” coal with rejection of mineral matter and moisture. In addition to advancements in equipment and circuitry, development and application of various chemical reagents has dramatically improved the performance of coal preparation processes.Contemporary preparation plants typically include multiple circuits that can be categorized by the size of particles they process: coarse, intermediate, and fine/ultra-fine (Figure 1). Coarse and intermediate circuits generally rely on size classification and gravity separations (e.g., dense-media cyclones), and do not require significant chemical reagents. However, fine and ultra-fine circuits often use froth flotation to separate coal from impurities, which requires chemical additives (Table 1). The primary additives include collectors, which coat the surface of the coal particles to render them (more) hydrophobic and thus more likely to attach to air bubbles and float; and frothers, which aid in the formation and stability of the froth that will accumulate the floated coal particles. Modifiers are also commonly added to flotation circuits to regulate pH in instances where coal or impurity characteristics may change water chemistries (Laskowski, 2001). Following flotation, coagulants and flocculants are often utilized in solid-liquid separations (i.e., dewatering or clarification) for coal products, and for tailings slurries prior to their disposal in impoundments. Coagulants function via double-layer compression1 to bring colloidal particles together, while flocculants promote bridging between the grouped colloids – and the combined result is enhanced sedimentation (Wills, 2006). Defoaming or anti-foaming agents may also be required to avoid fouling of dewatering operations."

Jan 1, 2012