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By M. M. Papic, G. M. Kimber

"Hat Creek coal was treated by the liquid solvent extraction process in a continuous plant at the U.K. National Coal Board Coal Research Establishment.Extraction levels of over 80 per cent dry-mineral-matter-free (dmmf) coal were achieved.Total light oil yield was around 47 per cent of the dmmf coal. The light oil was shown to be a good feedstock for secondary refining into gasoline, jet fuel and diesel fuel.In spite of the high mineral matter content of the coal the solid residue was successfully removed from the coal extract by filtration.IntroductionBritish Columbia Hydro (BCH) and the National Coal Board of Great Britain (NCB) undertook a joint project to test the Hat Creek coal from British Columbia in the NCB's coal liquefaction process designed to produce transport fuels and feedstocks for the chemical industry by the liquid solvent extraction of coal(1), In this process most of the coal is dissolved in an aromatic solvent and the residual solids consisting of mineral matter and undissolved coal are removed by filtration. The resultant coal extract solution is fed to a hydrocracker for conversion to light liquid products and a fraction suitable for recycling as solvent. The light liquid products can be converted to gasoline and diesel fuel in a secondary refining stage.The dissolution of the coal is effected by heat-treating a slurry at a temperature in the region of 400°C which causes some bonds in the coal to rupture with the formation of radicals(2,3). These radicals are stabilized by hydrogen transfer from the hydroaromatic groups in the solvent, resulting in a reduction in the molecular weight of the coal. In the absence of donor groups the radicals combine to form an insoluble high molecular weight product(4). From studies of the kinetics of these reactions it has been shown that the formation and stabilization of the radicals is rapid at temperatures around 400°C(2,3). The dissolution of the depolymerizing coal is, however, relatively slow and the need to ensure complete dissolution in order to achieve a high extraction restricts the selection of digestion time(5). Further, it is important that digests do not contain depolymerizing coal as it may re-form under the applied stress in the filter cake inhibiting flow through the bed and resulting in low filtration rates(6).Thus, in practice relatively long digestion times are generally required in order to ensure complete dissolution of the depolymerizing coal, while it is also important to avoid depletion of the hydrogen donor groups in the solvent which would lower the rate of hydrogen donation to the coal and thus reduce the extraction yield and adversely affect the filtration(7). Clearly it is desirable to optimize the digestion time and temperature with regard to the extraction yield and filtration properties.The precise control of the distribution of products from the hydro-cracker is important for the composition of the recycle process solvent. The principal functions of the solvent are to provide a source of donatable hydrogen and a vehicle for the dissolution of the depolymerizing coal. Hydrogen transfer from the solvent, achieved by the conversion of hydroaromatic to aromatic groups, stabilizes the radicals formed by thermal cleavage of some of the bonds in the coal resulting in a progressive reduction in the size of the coal molecules(8,9) and dissolution in the solvent. The combination of radicals would result in the formation of insoluble material and a reduced extraction yield of the coal(4). Thus to achieve a high extraction yield the solvent should contain sufficient hydrogen donor groups to prevent extensive radical combination. The composition of the solvent should also be controlled to allow dissolution of the depolymerizing coal and to prevent precipitation of this material during the subsequent processing of the coal digest and extract solution. The formation of a precipitate not only reduces the extraction yield of the coal and adve"

Jan 1, 1985

By H. T. Fargey

This paper considers the social, economic and political factors and their influence on future production and marketing of Western Canadian minerals. Among the subjects discussed are inflation, taxation, anti-combines legislation, unstable international currency relationships, economic nationalism and protectionism, the European Common Market and environmentalism.

Jan 1, 1973

By J. J. Barakso, S. J. Horsky, H. V. Warren

"A review of past and present biogeochemical studies is given. Early and more recent analytical procedures are described and compared. Tables 1-5 give silver concentrations in various organs of some plant species at different localities. Table 6 and conclusions provide guidelines for exploring for silver using biogeochemistry.IntroductionBiogeochemistry has been shown to be a useful tool in the search for gold deposits, especially those of the disseminated type (Warren and Barakso 1982). The purpose of this paper is to demonstrate that biogeochemistry can also be of assistance in searching for silver concentrations buried by as much as twenty feet of overburden without inflicting any damage on the environment."

Jan 1, 1984

By A. C. Ter-Oganesyants, N. N. Anisimova, G. P. Kotukhova, G. N. Dylko

The process utilized at Norilsk Nickel Polar Circle Division for treating slimes from the electrorefining of copper and nickel was developed in the late nineteen fifties and has survived without any fundamental changes. This technology is a combination of pyro and hydrometallurgical operations to produce PGM concentrates that are sent away for refining. The characteristic feature of the current technology is multiple-stage, extended cycle treatment with significant incomplete production, low labour and automation efficiency and poor hygiene and sanitary conditions. To eliminate all negative aspects mentioned above, specialists of Norilsk Nickel Polar Circle Division have developed a new hydrometallurgical process for treating electrolytic slimes. The main steps of the flow sheet developed are autoclave leaching of the slimes and electrochemical opening-up of a cake from autoclave leaching. The implementation of the new process will allow Norilsk Nickel Polar Circle Division to shorten the process cycle 4-5-fold thus reducing the volume of incomplete production, considerably increase labour efficiency, simultaneously improving working conditions, upgrade the final concentrate, reducing costs and increasing PGM recovery during refining and, ensure higher security of precious metals by employing automated processes and vacuum sealed units.

Jan 1, 2004

By Mafalda Arias

Most mining and mineral exploration companies? operate in remote locations, in Canada or internationally. Not knowing the cultural imprint of your team and the places where your company is active, may lead to problems. To set the foundation for a better world, it?s important to built trust and relationships inside your global team, within communities and together with stakeholders. Building the ?invisible asset? and developing intercultural awareness is an important part of leadership programs for geologists and engineers on your team, and should be a key component of your Corporate Social Responsibility initiatives. Why is culture important for mining and mineral corporations in their CSR initiatives? Because culture is the foundation of your organizational identity. Understanding the impact of identity, for an organization and for each individual, will provide a description of the experiences and values that affect every work placed interaction, with your clients, with colleagues, with suppliers, with the community of the host country. Each one of us sees and evaluates the world through our perceptions. Through these perceptions we give meaning; how we view and understand our reality which sets the tone for how relationships are built. This is what I call building the ?invisible asset?. Identity, experiences, values and beliefs are invisible commodities, locating them can be as difficult as finding a mine. But if they are not located, the commodity does not have value. Just like in the work we do in our industry. For example when you are working in an underground gold mine and the vein is lost, you keep on working and trying to find the vein; time passes, money is being used and no results. You decide to bring an expert on this type of deposits who gave you directions that allowed you to find the vein. To be a responsible citizen of the world and to set the foundation for a better world, it is imperative to go deep, as deep as your next drilling program, because only there and then, can you develop the cultural sensitivity and the ability to become an agent of change for responsible, sustainable and profitable businesses.

Oct 1, 2010

By K. G. Markkola

Since 2005, Compafifa Contractual Minera Candelaria (CCMC) has defined various strategies which aim to optimize the usage of the available energy in each of the SAG grinding circuit modules (SABC-A configuration). For this purpose, the use of larger size balls along with operating with an optimum balls/load ratio has been implemented. Additionally, in the ball mills, the amount of balls in relation to the equipment's usable diameter has been optimized. In the pebble crushing circuit, the percentage of material passing 12 mm (112 in) product has been increased by 15% by: (1) modifying the crusher mantle profile, (2) implementing a strategy for maximizing the power in each crusher, (3) using continuous improvement tools (Lean - Six Sigma), (4) redesigning SAG mills discharge grates, and (5) changing discharge grates in order to control the crusher feed size distribution profile. All these activities have improved plant throughput by 1,000 t/d with no significant capital investment. As part of the energy consumption optimization study, we have considered determining the optimum operational rate of each SAG mill, in relation to the mill liner life and also the improving the control strategy in conventional grinding.

Jan 1, 2007

By Per-Lennart Nystedt

"The Boliden Lead Kaldo Plant for the treatment of lead bearing flue-dust from the Copper Smelter and the Slag Fuming Plant has been in operation at the Ronnskar Works of Boliden Metall since the middle of 1976. At the present stage, the plant can treat lead-bearing dust of different kinds and compositions. The process allows good separation of arsenic and halogens from lead.The flue dust from the Copper Smelter and the Slag Fuming Plant is very complex and, apart from lead, also contains zinc, copper, tin, bismuth, cadmium, antimony, arsenic, sulphur, silver, chlorine and fluorine. The metallurgical process has been developed by Boliden Metall and has been tested on a pilot scale at the Foundation for Metallurgical Research (MEFOS) in Lulea, Sweden.The pelletized dust is smelted in the converter, where the heat is generated by an oil oxygen burner. The second step consists of reduction with coke. A lead bullion and slag are obtained. The slag, transported in liquid form, is treated in the Slag Fuming Plant for the recovery of zinc. The third step is the elimination of arsenic from the bullion. This is achieved by treating the lead with iron (turnings or pellets). The result is a crude lead and speiss. The lead contains silver, tin, antimony and bismuth, and is suitable for the final refining stages in normal plant equipment for refined lead.For process control, we use the rapid analysis centre, which is pneumatically and electronically linked to 'all major plant sections and allows for a quick turn-around between delivery of the sample and feedback of results. All three steps in the process are performed in the same converter.Since the starting up of the plant, the original process has been subjected to some modifications. Initial problems related to equipment, maintenance and environment have been solved step by step. Examples are quoted. Recent operating particulars are presented."

Jan 1, 1980

By V. A. Chanturiya, T. N. Matveeva, N. K. Gromova, T. A. Ivanova

"The research is aimed at solving the problem of increasing the extraction of gold from refractory ores, which are the main source of growth in gold production in the next decades. The purpose of the research is the development and scientific substantiation of the reagent modes for flotation extracting of gold from refractory ores using eco-friendly low-cost herbal modifiers (HM), providing increase in gold recovery and quality of gold concentrates. In the course of research laboratory techniques for the preparation of experimental samples of HM were developed, which included the sequence of operations of grinding Heraclium leaves and stems grinding, 2-stages extraction at a temperature of 50-60 °C, short-term ultrasonic treatment, filtration and subsequent unification of extracts. According to the developed method, the experimental samples of HM and conducted research were tested to analyze their sorption and flotation activity related to the extraction of gold from refractory gold ores.New data on adsorption and flotation properties of Heraclium stems and leaves extracts (HSE) in selective flotation of Au-sulfide minerals were obtained using UV-spectroscopy, scanning electronic and laser microscopy and atomic force microscopy. The dimensions and shapes of adsorbed hydrophilic films of herbal reagents were identified and mechanism of formation of stable insoluble compounds on the surface of minerals in flotation was explained.Research flotation tests carried out on samples of refractory gold ore of one of Russia deposits showed the possibility of effective use of herbal modifiers to improve qualitative and quantitative indicators of enrichment compared with the standard reagent regime. New reagent modes, using herbal modifiers in an amount of 5 to 10 ml of the extract (300 - 600 g / t, respectively) improves the quality of the concentrate: gold content attains 14.7 g / t, 1.34 times higher than in the baseline experiment and provides a gain of 3.13% extraction.The developed reagent regime with herbal modifiers is the author's original design, patented (patent of the Russian Federation) and have no analogues in the world of mineral processing. (Application number 2015116125 from 04.28.2015, ""The method of flotation separation of sulfide minerals using herbal modifier"", Russia). Actual application of new plant extracts as modifiers in flotation of sulfide minerals is the possibility of replacing of highly toxic chemical compounds by environmentally safe substances of plant origin. Implementation of the developed methods of extracting gold from refractory minerals with herbal modifiers will help to improve gold recovery at 3-5% and the quality concentrate of not less than 1.2 times, leading to higher productivity and a reduction of the negative man-made effects on the environment ."

Jan 1, 2016

By A. Alfantazi, M. Mahon

The current efficiency in zinc electrowinning is a key indicator of the performance in a cell house. This is typically measured by comparing the weight of the cathode to the electric current applied over the deposition period. This calculation can be cumbersome because the deposition history of each pulled set of cathodes will be unique. It will depend on the applied current and electrolyte conditions from onset of deposition until the cathode is removed and stripped. Not accounting for these can introduce errors to the calculated current efficiency. To track this history and reconcile the current efficiency, a time based computer process simulation was made of an industrial cell house. Two months of hourly recorded measurements from the cell house were input to the simulation, including current to the cell houses, concentrations, flow rate, and temperature of the purified leach solution. The simulation’s predictions of the concentration of zinc in the circulated, spent, and returned electrolyte all showed good agreement with the industrial data over the two months giving a validated zinc balance. The simulation was then tuned to predict the instantaneous current efficiency for all times, as well as the expected masses for the deposits given their deposition history.

Jan 1, 2014

By A. Aaltonen, S. Paloranta, H. Myllykangas

A property based dynamic model of flotation was built and validated for training purposes. The model is based on the work of the AMIRA P9 project. The recovery of each particle with composition and size is calculated in a given simulation step. The model takes into account machine and operational parameters such as air flowrate and froth height. The model was created using fullscale test data on Pyhlisalmi Cu-Zn-pyrite ore with flotation kinetics of multiphase particles determined. Simulation and validation shows that model can predict the dynamic behavior of the process accurately enough for training purposes.

Jan 1, 2009

By Mario Bergeron

L'exploration géologique pour les EOP (EOP: platine, palladium, iridium, osmium, ruthénium, rhodium) requiert avant tout des méthodes appropriees à la mesure de ces élémenIs. L'approche analytique choisie doit tenir compte de plusieurs facteurs, les plus importants étant: le type de materiel analysé, sa representativite, la sensibitite de la methode et les cotits reliés à son utilisation. Dans cette optique, plusieurs démarches ana/ytiquessont possibles, toutes requérant une étape de préconcentration. L 'une des plus adéquate consiste à effectuer une préconcentration par fusion plombeuse suivie d'une analyse par émission au plasma, cette procédure permettant de mesurer Ie platine, la palladium et Ie rhodium à des couts compétitifs (15 $/échantillon). Advenant 10 presence de teneurs appréciables de l'un ou plusieurs de ces éléments, une préconcentration par fusion au sulfure de nickel suivie d 'une analyse par activation neutronique assure alors la mesure de tous les EGP ainsi que celie de l’or (90 $/échantillon). Il est important de noter que Ie nickel, ades teneurs superieures à 4%, interfère au cours de l'étape de préconcentration par fusion plombeuse, ce qui se traduit pas sous-dosage des concentrations en platine, effectivement presentes dans l'échantillon. Ainsi, les géologues à la recherche d'EPG dans des environnements géologiques riches en nickel devraient s'assurer que l'analyse utilise, au cours de l'étape de préconcentration, une fusion au sulfure de nickel.

Jan 1, 1990

By H. L. Cameron

Introduction Since the beginning of gold mining in Nova Scotia in the year 1860, the biggest problem o the mine operators has been to find and follow the ore zones in the narrow quartz veins. It was early recognized that all veins were not gold bearing and that, in those that were, the commercial ore was confined to limited zones. A large number of geologists and mining engineers have been interested enough to give time and thought to the problem, but, until the last four or five years preceding World War II, they were handicapped by lack of exact data from mining operations. The necessary data could only be obtained by daily checking of underground operations. Such daily checks were instituted at a number of mines during the period 1935-40 and, in every case, were successful in delimiting the ore zone or zones for the particular mine. The present paper deals with the results of this work as applied to practical ore finding. It is an attempt at extrapolation, from observations in the four districts with which the writer is personally familiar, co other districts in which similar conditions or structures are reported.

Jan 1, 1947

By Michael Bowker

Au/TiO2 catalysts were prepared by incipient wetness impregnation and tested for the room temperature photocatalytic reforming of methanol in aqueous solution. These catalysts proved to be more active, on a molar basis, than Pd/TiO2. The dependence on loading of gold was different from that of palladium, showing a double maximum in yield at 0.1 and 2 wt. % with low rate below 0.01% and above 10%. A model is proposed for the reaction involving band gap excitation of titania electrons which are used to oxidise the methanol via adsorbed CO. With palladium, photoreforming of CO and water can be achieved, but this is much less effective on gold, presumably due to the much weaker bonding of CO on Au.

Oct 1, 2003

By L. Boyd, A. Charland, G. Potts, D. Fragomeni, N. O. Lotter

"The Raglan orebody and concentrator has been the subject of study in Process Mineralogy at Falconbridge since 1998. (Lotter and Tuzun, 1998) The orebody is classified into three distinct textural groups, or end members. These are referred to as disseminated, net-textured, and Massive Sulphides, and differ in terms of mineral grain size, nickel grade, hardness, and mineral association. In this paper, it will be shown that the sampling and characterisation of each end member on an individual basis develops a higher-level understanding of the processing requirements and behaviour of the mixture of ore as presented to the mill.The end members have been used in robust prediction of recovery at various grind size p80 from laboratory scale High Confidence Flotation Tests. Weighted mean mixtures of the end members have been mathematically combined to determine impact of textural distribution on metallurgical performance as a function of grind size.The ore end members also vary in hardness and breakage mechanism and have been used to model throughput capability for existing, optimized and retrofit grinding circuits. This modeling has provided a range of expected throughputs as the relative proportions of each end member varies.Finally, the differing grinding requirement per end member has led to the development of grinding and flotation strategy that increases rougher flotation recovery and provides flowsheet options for a concentrator expansion. This leads to further understanding of the plant performance as a function of ore mixture."

Jan 1, 2005

By A. W. Davis

Sapping and mining have constituted an important part of siege operations ever since powder came into general use in Europe. Before this period, famine was the main weapon in the hands of the besiegers, and the history of the middle ages is replete with accounts of sieges lasting two and three years. With the advent of explosives, a position impregnable to assault might be readily won by mining under, and blowing up, its defences. The natural offensive against this method of attack is to countermine and stop the attackers underground before their objective is reached. Thus developed the art of military mining. The French and British, in the Peninsular war, were adepts at this method of warfare, and the explosion of a mine and the formation of a breach were the usual preludes to the general assault of a position. In the Crimea, at Sebastopol, the British and Russians did a lot of underground fighting, as the old maps of their galleries, now in the museum at Chatham, will testify. In the siege of Port Arthur, in still later times, the Japanese and Russians were hard at it as well.

Jan 1, 1926

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012

By I. Imris

The chemical industries are using different type of catalysts, which after application usually produced many tons heap of residues. One of them is cupric oxide catalyst with high content of copper and silica. The recovery of copper from the waste has become major interest from a viewpoint of environmental protection and recycling of resources. The thermodynamic analysis and experimental results suggest that the copper from cupric oxide catalyst can be extracted by plasma reduction process. By plasma reduction process the inert slag and copper with following chemical composition: 99.04 % Cu, 0,042 % Fe could be obtained.

Jan 1, 2007

By Dean S. Rogers

"In February 1980, Dome Mines Limited announced a $50 million expansion program which would result in a 50% increase in mill capacity from the present 1,815 tonnes per day to an eventual production rate of 2, 720 tonnes per day in the year 1984. As an integral and necessary part of this planned expansion, a new vertical production shaft, No. 8 Shaft, would be sunk from surface to a depth of 1,645 metres.Throughout the seventy-year history of mining at the Dome, gold has been found in a number of different rock types and in association with a number of different structural settings. However, the key to successfully locating ore deposits lies in the recognition of the favourable environments in which they generally occur. First and foremost, the exercise of locating the No. 8 shaft became an exercise in geological deduction based on the projection of these favourable lithologic environments.In November 1980, after detailed engineering work was completed, the total cost of the project was estimated at $75.5 million 1980 dollars or $91 million dollars allowing for inflation over a four-year construction period. These estimates include the shaft, significant replacement and alterations to the milling process, and an upgrading of the plant."

Jan 1, 1982

By Scott Beer

What New Technologies Will Drive Economic Improvements? ??Historical ?1060?s: Mainframe Technologies ?1970?s: Mini Computing ?1980?s: Workstation Computing ?1990?s: Personal Computing ?2000?s: Network Computing Internet PDAs Cellular phones ??What?s the next technology improvement? ??What?s next for Mining?

May 1, 2009

By M. Nowak

Extreme high grades often exert too much influence on surrounding block estimates, leading to a smearing of high grades that can cause overestimation of mineral resources. This concern underlies the decision to cap high grades, i.e., to lower the highest grades in a drill hole data set to some level deemed to be reasonable for producing reliable resource estimates. The choice of a capping level can, by itself, have a large influence on the analysis of the economic viability of a project. Despite this, it is often a choice that is made arbitrarily, guided more by art and tradition than by sound technical analysis. This paper makes suggestions for good capping practices, using methods and procedures that have been presented elsewhere, in the technical literature and in conference papers. The authors propose to use capping only if absolutely necessary, and review examples of cases where capping may not be necessary, or where capping does not make the estimates more reliable. It addresses two particular instances where capping is recommended: (1) where there is good reason to believe that estimation with uncapped grades will overstate the true underlying average grade, and (2) where there is potential for overly optimistic assessments of local block grades in the vicinity of some very high grade assays. The proposed capping practice is based on adjustments to only a very few high grade assays. The level of this capping can be assessed by bootstrapping and through analysis of the effect of extreme values on summary statistics like the average and the coefficient of variation. The paper recommends that good practice include an examination of the potential for local overestimation in higher grade areas.

Aug 1, 2013