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By G. T. Fisher

A continuous process is used at Phelps Dodge Sierrita Inc. to produce copper sulfate pentahydrate via a solution extraction ? crystallization approach to supply the animal feed market. A review of the fundamental concepts of the process and unit operations is presented. Improvements in the process are aimed at achieving a controlled size distribution of product crystals (-40+80 mesh) with minimization of fines by primary nucleation and crystal breakage. An independent temperature control design was implemented for the heat transfer medium (water) in each crystallizer, albeit using common headers in and out of the chiller. This design was developed to maintain a controlled degree of supersaturation in each vessel while preventing localized spontaneous nucleation of fines and reducing encrustation of the heat transfer surfaces in each crystallizer. A model was developed to calculate the heat load and heat transfer coefficient of each crystallizer along with the saturation copper tenor as a function of temperature and free acid.

Jan 1, 2007

By Jae-Chun Lee, Rajiv Ranjan Srivastava, Min-seuk Kim, Byung-Su Kim

Recycling of spent hydrotreating catalysts (HTC) can potentially contribute towards the sustainable extraction of metal values. Treating such materials by hydrometallurgical methods to separate metals from the leach liquor of either acid/alkali media is a major step. In the present study, separation of molybdenum from HCl leach liquor of spent NiMo type HTC has been investigated by applying solvent extraction using Cyanex-923. For this, the chloride solution containing 973 mg/L Mo, 254 mg/L Ni and 1634 mg/L Al was taken as the aqueous feed. The parameters including contact time, concentration of the extractant, acid and chloride, and phase ratio were varied to investigate their effect on the extraction efficiency. The McCabe-Thiele plot suggests that > 99% Mo-loading using a 2-stage extraction process. From the molybdenum depleted solution, nickel was selectively extracted by Cyanex-301 leaving Al in the raffinate.

Jan 1, 2014

By D. C. Fraser

Copper occurs invisibly in a geo-logical environment characterized by swampy conditions and an accumulation of forest peat. This swamp, located in southeastern New Brunswick, contains up to ten per cent cop-per (dry weight), in the organic sediments. This occurrence appears unique in that the metal is apparently organically combined in a chelate compound. Unlike the acidic nature of most peat bogs, the pH of the cup-riferous peat is nearly neutral. Analyses of the peat and associated soils have indicated that the bulk of the copper is contained in the organic sediments. It appears that the cop-per distribution is affected by capillarity, evaporation and the growth of frost crystals, and that the copper fixation is effected by organic sequestration resulting in the metal being bound to the nitrogen or oxygen components of the forest peat. While such a fixation mechanism is not definitely established as responsible for the immobilization of the metal, the facts at hand are compatible with

Jan 1, 1961

By D. A. Jacobson

Mining operations, whether new or existing, are constantly looking for ways to maximize production and improve energy efficiency, while keeping the footprint required to a minimum. The Nordberg MP1250 cone crusher was designed with these three goals in mind. A series of side-by-side evaluations comparing an MP1250 to an MP1000 were completed at two Freeport-McMoRan operations. The first evaluation began October 2009 in a tertiary position and the second began March 2010 in a secondary position, where it remains in full production today. Utilizing 25% higher power capacity than the existing MP1000 tertiary crushers, the MP1250 had 29% higher capacity and 17% lower specific energy, adjusted for differences in feed and product size. The MP1250 compared to the existing MP1000 secondary crushers achieved 30% higher capacity at a slightly reduced specific energy, while achieving a finer product. The MP1250?s higher capacity and energy efficiency may have application in many crushing plants. Depending on site specific economic factors, greenfield projects may benefit from a smaller footprint and less ancillary equipment, whereas brownfield projects may benefit from higher capacity or a finer product within the same footprint.

Jan 1, 2012

By G. Paillard, I. E. Puddington, A. F. Sirianni, F. W. Meadus

Experiments with some selected Nova Scotia coals and a single sample of American anthracite, reconstituted in granular form with lower sulphur and ash contents by spherical agglomeration methods, are described. The effect of different bridging liquids, grinding times, gangue depressents and modes of agitation on the final product are discussed. The application of agglomeration techniques as a means of drying wet coal fines is also noted.

Jan 1, 1968

By Fathi Habashi, Michel Pagé, Farouk T. Awadalla

"Chrysotile asbestos can be dyed with certain dyestuffs to form stable coloured products whose hemolytic and cytotoxicity are greatly reduced. Examples of these dyes are Thiazol Yellow G (a monazo dye) and Trypan Blue (a diazo dye). Other dye stuffs, for example, basic dyes with triphenyl methane structure, Brilliant Yellow (a diazo dye), and Methylene Blue (a thiazine dye) colour asbestos but do not reduce its toxicity. Similarly alizarin, 8-hydroxyquinoline, and representative members of the phthalein group Bromocresol Purple and Phenolphthalein.IntroductionThere is, at present, a controversy regarding the dangers of asbestos fibres, and attempts are being made to render it less toxic. One of these attempts consisted of treating chrysotile asbestos with gaseous phosphorus oxychloride, POCI], at ambient temperature and in absence of moisture. The product had to be heated at 300°C to 500°C to expel exess entrained reagent to get a material containing 0.5070 to 5% phosphate groups and known as Chrysophosphate (Lalancette and Dunnigan, 1982). This product showed decreased toxicity as measured by its hemolytic effect on red blood cells (fable 1). In another approach, Flowers (1983) showed that when chrysotile asbestos was thoroughly mixed with a solution of ferric ammonium sulphate and the slurry was then filtered and dried, the product showed a marked decrease in cytotoxicity.In the present investigation the problem of toxicity was considered from a different point-of-view. Chrysotile asbestos is a hydrated magnesium silicate that can be represented by the structural model shown in Figure 1 from which it can be seen that magnesium hydroxide groups, Mg(OH)2, form a part of the silicate structure. Certain organic reagents that are known to react with magnesium ion in solution to form chelates were reacted with asbestos to find out whether a chelate was also formed on the fibres, and if so , what will be the hemolytic action and cytotoxicity of the product."

Jan 1, 1991

By C. P. Browning

Copper, as far as we know, was the first metal used by man, and due to the fact that it occurs in many places in the 'native' state, and also to the ease with which it may be shaped, it has played an important part in the evolution of civilization. Copper tools with inscriptions dating back to 6,000 B.C. are known in Egypt, where the metal probably got its start as a useful material in human hands. Just how far back the use of copper in Canada dates is difficult to say, but it was in use by the Indians in the Lake Superior country long before the arrival of the first white man. For many generations the Eskimos also have used copper derived fr0m deposits of the native metal found in the Coronation Gulf district. Due to the metal's many unique qualities, imperishable with age, ancient implements and utensils are apparently as good today as when they were made, having withstood the onslaught of time probably better than objects of any of the other base metals. Copper alloys so well with other metals that today it is second only to iron in its industrial value. Even at the beginning of the eighteenth century the world's production of copper was probably not more than seven thousand tons a year, with Great Britain producing three-fourths of this. One hundred years ago the mines of the United States, Chili, Mexico, Canada, South Africa, Australia, and Tasmania, which now produce about nine-tenths of the copper of the world, were totally undeveloped. Ln 1926 the world production of copper was approximately 1,658,000 tons, which was seventy thousand tons greater than in the preceding year; but growing demand absorbed the increased production, so that the stock of rough copper throughout the world is comparatively small. Of this huge tonnage of the metal, Canada produced four percent, two-thirds of it emanating from British Columbia, nearly one-third from the Province of Ontario, and the balance from Quebec.

Jan 1, 1927

By E. S. Moore

Introduction The geology of the Sudbury nickel field has been studied extensively, but there are few reports dealing with the structure of the interior of the basin. It was not until the Treadwell-Yukon zinc-lead deposits were discovered that attention was strongly directed toward the large-scale faulting that has split the basin parallel to its long axis. This faulting has been responsible for the , ore deposits in the basin and it may be regarded in many ways as the most important geological event, next to the intrusion and differentiation of the nickel eruptive sheet, that has occurred in the Sudbury region. The early reports on the nickel region by Bell, and Barlow, were chiefly concerned with the nickel-copper ores and with the formations of the region. Coleman was the first geologist to map the nickel eruptive as a continuous sheet around the belt and to emphasize its basin character. On the map accompanying his later report, he shows an important offset in the nickel eruptive at its southwest end, where the large fault cuts this portion of the basin, but the fault was not traced into its interior, as little detailed work was clone in the basin at that time. No ore-bodies had been developed outside of the nickel-copper deposits associated with the norite when the map was prepared, and attention was mostly concentrated on the nickel eruptive. Coleman did, however, map and name the various formations found within the basin and, in general, his delineation of these has remained the standard for prospectors and other workers in the field until the present day.

Jan 1, 1930

By J. M. Carr

The history, geological setting and local geology of the Magnum vein system, 100 miles west of Fort Nelson in northeastern British Columbia, are described. The system comprises a number of quartz-ankerite veins, mineralized with chalcopyrite and lesser pyrite, occurring in a steep northeastly zone of deformation and subsequent dike intrusion within otherwise little-deformed Precambrian sedimentary rocks. In April of 1970, Churchill Copper Corporation began producing copper concentrates in a 750-tpd mill fed from the Magnum mine.

Jan 1, 1971

By B. P. Simser, R. K. Brummer, A. Mortazavi, P. P. Andrieux

"A large-scale panel destress blast was fired at Brunswick mine in the fall of 1999 in order to reduce the ground stresses in a critically important neighbouring mining region. This work, sponsored by the Mining Division of CAMIRO and Brunswick mine, consisted in heavily choke-blasting — and subsequently leaving in place — a massive waste sulphide pillar in the southwest end of the 1000 m level. This paper describes the approach and design methodology used to try to maximize breakage in the rock mass in the area to destress, while minimizing damage to critical infrastructures in the vicinity. The loading operations, as well as the results of the blast — in terms of its field performances, as recorded by near-field blast vibration monitoring equipment, visual postblast assessments and measured impact on the regional stress field — are discussed as well. A brief comparison between the measured stress changes and inelastic numerical modelling of the test site is also presented.Un tir à grande échelle de relâchement des contraintes dans un pilier a été effectué à la mine Brunswick à la fin de l’automne 1999 dans le but de diminuer les contraintes de terrain dans une très importante zone de production adjascente. Ces travaux, financés par la division minière de CAMIRO et la mine Brunswick, consistaient à tirer violemment sans aucune face libre, et à laisser en place, un pilier de sulphures massifs au sud-ouest du niveau 1000 m. Cet article décrit l’approche et la démarche conceptuelle utilisées pour tenter de maximiser les fractures dans le pilier visé, tout en minimisant les dommages collatéraux à des infrastructures critiques se trouvant dans les environs immédiats. Les opérations de chargement des explosifs et les résultats du tir — en termes de ses performances, telles qu’évaluées par de l’équipement de monitoring rapproché des vibrations de tir, d’observations visuelles, et de son impact sur les contraintes de terrain locales — sont également discutés."

Jan 1, 2003

By W. Evans, C. E. Ells

Nuclear power reactors using zirconium alloy pressure tubes generate electricity in several countries. Such reactors are particularly important in Ontario, where CANDUs* generate about 30% of the total electricity produced in the Province. Starting with the commitment of NPD-2 in 1956, the pressure tubes of the first five CANDU reactors were made of coldworked Zircaloy-Z, an alloy of Zr and Sn. This alloy was developed by the US Navy, but the decision to use it in a cold-worked condition was based on AECL work. In 1958, the USSR published information on a new alloy, Zr-2.5 wt% Nb. The Nb promotes stabilization of the (3-phase in the material, thus presenting opportunities of exploiting metallurgically strong pressure tubes analogous to the heat-treatable cx-{3 titanium alloys. After construction of two reactors using Zr-2.5 wt% Nb in a quenched and aged condition, an extensive development program on cold-worked Zr-2.5 wt% Nb pressure tubes resulted in them becoming the reference tubes for all CANDU reactors committed since 1966. Anticipating the future needs of the domestic and export markets, AECL have pressure tubes of Zr-3.3 wt% Sn-0.8 wt% Nb-0.8 wt% Mo (Excel) in an advanced state of development. These tubes will be used in an annealed condition; our projections show that they will have improved dimensional stability over the lifetime of the reactors. These improvements result from experimental programs leading to an understanding of the relationship between microstructures and fabrication variables and effects of the environment during service in nuclear reactors.

Jan 1, 1981

By Michael Cooper, Eric Konigsmann, A. Moerman

"A paste backfill plant and underground piping distribution system was commissioned at the Brunswick Mine in June, 1998. Concentrator tailings, composed mainly of pyrite and lesser amounts of silicate minerals with a P80 of 37um (45 YO-20 pm), are pumped to the backfill plant. The backfill plant uses conventional thickening and disc filtering to dewater the solids, which are then mixed with binder in twin screw mixers. The paste is discharged through a gob hopper and one of three boreholes by gravity. Approximately 65% of the concentrator tailings will be placed underground at full production. The remaining thickened tailings will be pumped to an existing impoundment area. Application of paste technology will completely replace the use of cemented rock fill in the mine by the end of 1998.The design capacity of the paste backfill plant is a total of 360 dmtph of cemented paste through two parallel production lines. The plant is highly instrumented and controlled via a hybrid Programmable Logic Controller (PLC-5) and Fisher ProVox Distributed Control System that is in communication with the property information highway. Video and audio signals from the underground system are carried to the surface plant via a leaky feeder communications/fiber optic system.The underground distribution system consists of a network of 200mm diameter boreholes and piping. There are approximately 3.5km of boreholes and 5.5km of piping in the system. To minimize pressures, the greatest piping length from any borehole is approximately 400m with all piping being open-ended. There are no valves in the entire paste distribution system.Construction of the plant, including installation of piping to and from the plant and preparation of the underground distribution system, was completed in less than one year from the time of management approval for the $M 22.3 project."

Jan 1, 1999

By J. C. Loretto, H. A. Simons

The paper discusses how, in the routine testing of ores, insufficient communication between the laboratory and the design personnel can lead to misunderstanding or misinterpretation of test results and consequent design errors. A number of examples are given together with suggested modified interpretations and the resulting dollar savings indicated by these new interpretations.

Jan 1, 1972

By Paul B. Warrington

This paper presents a discussion of the factors affecting copper scrap markets, including such items as price levels, freight. grades of material, sources and packaging. Reference will also be made to the effective life and turn-around of the copper content of some products. Introduction IN TERMS OF SIZE, copper scrap is second only to ferrous scrap in tonnage recycled. However, in total value, it is second to none. For example, world scrap recovery during the preceding 4 years averaged just under 2,300,000 metric tons per annum, and at an average price of 70 ¢ a pound, this works out at a turnover of about $3.5 billion, which indicates that the copper scrap industry, or recycling as it is now becoming known , is a substantial one.

Jan 1, 1977

By F. Doxey

Introduction In order to improve outputs and to reduce or hold mining costs, many attempts have been made to mechanize the getting and loading of coal in the major coal producing countries, and machines of various kinds and sizes have been designed and manufactured. Some of the most important are: Joy Continuous Miner Joy Coal Auger Goodman Mining Machine Lee-Norse Koal-Master Jeffrey Colmol Cardox Hordsecg Recovery Drill German Coal Plough British Coal Plough with agitated blades M. & C. Samson Stripper AB Meco-Moore Cutter Loader Joy Gloucester Getter The three last named are the chief longwall machines in use and the AB Meco-Moore and the Samson Stripper are doing a good job in their respective applications. It is understood that the Gloucester Getter recently installed in a British colliery also shows reasonable promise. It was felt, however, that to meet the conditions of the mines in Nova Scotia, any machine developed must have certain distinctive characteristics. It must: ( 1) Be able to cut and deliver coal in quantity and of the right sizes ( 2) Be easily manoeuvrable ( 3) Be suitable for longwall operations ( 4) Not interfere with timbers already set ( 5) Cut its own stable (6) Work on reasonably heavy gradients

Jan 1, 1951

By R. Therrien, L. Gosselin, J. Raymond

ABSTRACT: The ground-source heat pump is a low-carbon technology that uses the earth’s renewable geothermal energy to heat and cool buildings, with an ef?ciency 3 to 4.5 times that of conventional systems. These high performances are achieved by exchanging heat with the earth using a ?uid that is groundwater, surface water or closed loop water. Expensive installations, such as water wells or buriedcoils, are however necessary to transport the ?uid in and out of the earth, making ground-source heat pumps more costly than conventional systems. Installation costs can be reduced in mining environments due to the abundance and the accessibility of resources to be used with heat pumps. Examples of system design calculations using data from the Mouska and Doyon mines in Abitibi show signi?cant installation cost savings using dewatering mine water or ground heat exchangers installed below oxidizing waste rocks. Ground-source heat pump technology is reviewed and scoping calculations are presented to illustrate how such systems can be installed in mining environments.

Jan 1, 2010

By E. A. Roux

As the first mine-to-metal zinc operation utilising atmospheric leaching, solvent extraction and electrowinning, Skorpion Zinc faces unique challenges and opportunities. One of these challenges is found in the solvent extraction circuit, in which di-ethylhexyl phosphoric acid (D2EHPA) is used as the organic extractant. Although D2EHPA is an excellent extractant for zinc, it suffers from the co-extraction of ferric iron, which is produced during leaching and by the corrosion of the grinding media. This situation is partially mitigated by iron precipitation in the neutralisation step prior to solvent extraction. Unfortunately, some ferric iron still reports to the solvent extraction process. This leads to a slow build up of iron in the organic phase. Chemical stripping is used to maintain the Fe concentration at an acceptable level. In this paper, the efficiency of the iron removal process is discussed.

Jan 1, 2006

By H. Z. Liu, J. M. Zhao, F. C. Wang

"Novel silicate-alginate composite beads containing 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester (P507) were synthesized and applied for the adsorption of Nd3+ from aqueous solutions. The adsorption amount of Nd3+ has been increased owing to the introduction of P507. The effect of equilibrium pH (pHe), the kinetic and isotherm experiments were investigated. The adsorption reaches equilibrium at 9 h and the maximum uptake capacity is up to 195.4 mg/(g dry adsorbent). The Langmuir isotherm equations are used to describe the adsorption process. Complete desorption can be realized with 0.2 M HCl within 20 min. INTRODUCTIONRare earth elements (REEs) have found various applications in different domains, such as metallurgy industry, ceramic industry, nuclear fuel control, photo-electro-magnetic functional materials owing to their unique properties. Neodymium (Nd), as a representative of all of the most valuable REEs, is widely used as catalysts, laser crystals, capacitors, rubber additives, Nd-Fe-B magnets, hydrogen storage and so on. Thus, the separation and purification of neodymium is significant. Unfortunately, Nd always coexists with other REEs and selective separation of the individual Nd from the REEs mixtures is still extremely difficult owing to their strictly similar atomic structures and chemical properties.Liquid-liquid extraction (LLE) and solid-liquid adsorption (SLA) are the most widely adopted techniques for the separation of REEs in the hydrometallurgical fields. The LLE process is well suited for large-scale continuous operation because of its inherent high capacity and fast kinetics. Nowadays, as a commercial extractant, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507) has been extensively studied for extraction and separation of REEs since it has considerably good extractability and high separation efficiency (Xu et al., 1992). SLA is one of the effective and green separation methods with some prominent advantages, such as easy regeneration of adsorbents, small footprint size, less industrial wastes, higher enrichment factors and column efficiency,rapid solid–liquid separation without emulsion and so on. Hence, the introduction of extractants with excellent performance into adsorbents will integrate the advantages of LLE and SLA (Lee et al., 2009)."

Jan 1, 2012

By Lloyd W. Trevoy

Syncrude Canada Limited is presently studying commercial production of heavy minerals from plant tailings of the openpit A lhabasca tar sands operation. When tar sands are processed and upgraded to synthetic crude oil, heavy minerals can be removed f rom the extraction circuit and beneficiated to provide concentrates of zircon and titanium minerals. Calculated recovery rates indicate that crude oil production capabilities of 105,000 barrels per day would provide 26,000 tonnes of zircon and 114,000 tonnes of titanium minerals annually. The titanium minerals concentrate is a mixture of ilmenite, leucoxene and rutile; it could be used as recovered or upgraded to synthetic rutile. With the consrruction of further synthetic crude oil plants in Western Canada, a large reserve of heavy minerals will become available.

Jan 1, 1984

By P. C. Holloway, A. Tshilombo, T. Xue, M. J. Collins, R. Lopetinsky, I. Mihaylov, I. M. Masters

The Voisey’s Bay deposit contains a trace amount of cadmium, which reports to solution during pressure leaching of the nickel concentrate at Vale’s Long Harbour Hydrometallurgy Plant, and must be removed to produce high quality nickel cathode. In 2006, Vale approached Sherritt Technologies to collaborate on the development of a process for removing cadmium to low levels (<1 mg/L) in the nickel raffinate. Following successful bench scale and pilot plant testing at Sherritt’s laboratories, the cadmium removal process was then moved through engineering and construction, culminating in the successful commissioning and startup of a cadmium removal circuit at the Long Harbour Hydrometallurgy Plant in 2017. This paper presents the results of this collaboration and the challenges that were encountered through each stage of development, as well as current results from operation of the commercial cadmium removal circuit. INTRODUCTION Vale’s Long Harbour Processing Plant, with a nameplate capacity of 50,000 t/y nickel, began operation in 2014. In addition to electrolytic nickel rounds, the plant also produces electrolytic cobalt rounds and copper cathode. The Long Harbour Processing Plant uses a unique hydrometallurgical process developed by Vale Base Metals Technology Centre, as shown in Figure 1, to treat a nickel sulphide concentrate produced at the Voisey’s Bay mine and mill located in northern Labrador (VBN concentrate) (Stevens et al., 2009).

Jan 1, 2019