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By F. McCarthy, W. Zhang, R. McDonald

"The processing of nickel laterites has been a topic of major interest at CSIRO for almost twenty years. During this period CSIRO has collaborated with other researchers and industry in developing a better understanding of existing processes and been actively involved in testing/developing new beneficiation and process options for these ores. The current paper summarises the results of selected studies and highlights improvements that have been achieved. Key topics to be discussed include enhancements in the mineralogical characterisation, beneficiation approaches, improvements in the understanding and application of leaching technologies, the development of synergistic solvent extraction (SSX) for the recovery of nickel/cobalt from laterite leach liquors and the collaborative development of the Direct Nickel process. Future opportunities and key research questions will be briefly examined.INTRODUCTION Nickel laterite ores comprise a significant resource in Australia and according to United States Geological Survey data nearly a quarter of world reserves are located there (USGS, 2016). More specifically, around 95% of Australian nickel resources (laterite and sulfide) are located in Western Australia (Australian Government, 2017). Given the recent closure of Queensland Nickel, essentially all of Australian nickel production occurs in Western Australia and the primary producers of processed nickel products include Nickel West (Kwinana) with ~84,000 t saleable nickel metal in 2016 (BHP Billiton, 2017), Minara Resources (Murrin Murrin) with 46,700 t nickel metal produced in 2015 (Glencore Australia, 2017), and First Quantum Minerals Ltd (Ravensthorpe) who sold 25,882 t nickel as mixed hydroxide product in 2016 (First Quantum Minerals, 2017). The total sales of nickel from Western Australia in the 2015-16 financial year were 175,722 t. The study of nickel laterites at CSIRO recommenced at the time second generation High Pressure Acid Leaching (HPAL) plants were being commissioned at Bulong, Cawse and Murrin Murrin in the late 1990’s. A combination of technical and engineering issues meant that the ramp-up times at these operations were slower than expected and the outcomes resulting from the attendant problems are well documented (e.g. Griffin & Becker, 2000; Reid & Barnett, 2002; O’Callaghan, 2003) while the issues faced at the BHP-Billiton-built Ravensthorpe plant have been addressed by the current owners of this project, First Quantum Minerals Ltd (Piper, 2012)."

Jan 1, 2017

By Liang Zhen, Jian-Tang Jiang, Guo-Ai Li, Xiao-Ya Wang

"Deformation behavior of 2A97 aluminum alloy containing coarse secondary phases was studied using uniaxial hot compression (HC, 340–490°C, 0.4001–1 s-1). The flow stress could be described by a Zener-Hollomon parameter in hyperbolic sine function with the hot deformation activation energy of 237 kJ/mol. Based on the experimental data and dynamic materials model, processing maps were generated to demonstrate the hot workability of the alloy. The coarse secondary phases experienced dissolution by varying degree under different deformation temperature, which producing different effects on the microstructure evolution. When deformed at relatively low temperatures, a mass of fine grains shaped up in the original grains and grain boundaries, and the dominating deformation mechanism was believed to be dynamic recrystallization. As the deformation temperature rising to 490°C, most secondary phases disappeared and few recrystallized grains were observed, indicating that the secondary phases dissolved sufficiently along with dynamic recovery occurred during the hot deformation. Particle stimulated nucleation related to the coarse secondary phases was believed to promote the recrystallization and the recrystallization behavior was sensitive to deformation temperature.INTRODUCTION Al-Li alloys has received much attention as new promising structural materials in the aircraft and aerospace industries, due to their lower density, higher elastic modulus and improved fatigue crack growth resistance in comparison with the conventional commercial aluminum alloys (Ou Ling, 2015). 2A97 alloy is one of the 3rd generation Al-Li alloys targeting at comprehensive improvement of aviation aluminum alloy and applications for wing spars and ribs to other internal structures for transport aircraft. Al-Li alloys are usually formed by hot deformation, either by rolling or extruding. The deformation behavior and resulted microstructure evolution during the forming process mainly dominates the formability of the alloy and the serving performances as well. Therefore, the deformation behavior and microstructure evolution at elevated temperature need be made clear for optimizing the hot processing parameters and controlling microstructure evolution."

Jan 1, 2018

By Pizhi Zhao, Yingdong Li, Hailong Cao, Yingjuan Feng

"Three types of anodic films (unsealed, hot water sealed and agent sealed) were prepared to study the effects of anodizing pores structure on the adhesive bonding performance of AA5754 automotive sheets. The morphology of the anodic films was examined by using scanning electron microscope (SEM) and the composition was examined by glow discharge optical emission spectroscopy (GDOES). The adhesive bonding strength and durability in corrosive environment were investigated by using single lap shear test and salt spray corrosion test (SST), respectively. The results showed that the pores structure could significantly influence the adhesive bonding performance. The unsealed sample showed porous structure and provided high bonding strength, however, the durability was poor in corrosive environment. The hot water sealed sample showed fine and loose hydrated alumin a structure on the surface and provided high durability in corrosive environment, but the bonding strength was low. In contrast, the agent sealed sample provided both high bonding strength and durability in corrosive environment.INTRODUCTIONAdhesively bonded aluminum joints by using adhesives have been widely used for the realization of lightweight design in industrial applications like automotive and aerospace industry[1, 2]. Durable bonds which are capable of taking structural loads can be created due to a careful consideration of the way in which the joint is formed, the type of adhesive and the appropriate treatment of the adherend surfaces prior to bonding[3-6]. Experiences demonstrate that the surface treatment is the most critical step which could not be disregarded, since it is essential to achieve long-term service capability [7].In structural applications, a bonded assembly is expected to maintain a significant load and may be combined with exposure to harsh environmental conditions in its service life. For this purpose, the pretreatment for structural bonding of aluminum alloy must provide not only strong tensile strength and durability but also good corrosion resistance. Chromic acid anodizing (CAA) process provides an anodized layer which has good corrosion resistance while also exhibiting useful adhesion characteristics as well as lacquer coating retaining characteristics[8].However, the use of Cr (VI) is unadvised from a health and environmental point of view since it is toxic and carcinogenic, and this process is gradually limited even prohibited. Boeing's phosphoric acid anodizing(PAA) process provides a more open pore structure allowing penetration of high molecular primers/adhesives[8]and PAA process is the most widely used pre-surface treatment suitable for adhesive bonding between aluminum alloy components. Rahimi et al. demonstrated that nanostructure can be produced by PAA process and is affected by the time of pretreatment and anodizing parameters [9]. Xu et al.investigated the influence of surface energy and roughness on adhesive bonding through PAAprocess and provided improved adhesion performance under certain anodizing parameter[10]. However, PAA process is normally not recommended for a major concern of deterioration of the mechanical performance of the joints as a result of exposure to a wet and corrosive environment. Sulfuric acid anodizing(SAA)process, recently, has been widely used for corrosion protection and good base coating for the adhesion of lacquers in aerospace manufacturing[11]. The good performance is explained by properties such as the porous morphology and high adsorptive power of the oxide film, the chemical and electrical inertness of the anodized layer. Moreover, modified sulfuric acid could also used for adhesive bonding. Lunder et al. found that anodizing in hot sulfuric acid is promising as a simple, very rapid and environmentally friendly pre-treatment for adhesive bonding[12].Saeedikhani et al. studied the process of phosphoric/boric/sulfuric acids anodizing and found it was is a promising pre-treatment for adhesive bon"

Jan 1, 2018

By Rodolfo Espinosa

"Industrias Peñoles, S.A. de C.V. in Mexico, has nine mining operations, six managed by Peñoles (base metal mines) and three managed by Fresnillo plc (precious metal mines). Seven of the operations use flotation and the other two are heap leach operations, one for gold and the other one for copper.This paper gives a brief introduction of Peñoles, shows mine locations and describes the main process characteristics of each concentrator. It also presents four of the new operating practices that were implemented over the last four years to improve the economics of the mining operations. These include (1) the use of centrifugal gravity concentrators to increase the recovery of gravity recoverable gold (GRG) and silver (GRS), (2) the use of expert systems to reduce process variability while increasing grades and recoveries, (3) the application of the Six Sigma methodology to key projects to ensure success and personnel development and (4) the use of water chemistry fundamentals to identify chemistry problems and design adequate solutions for improving grades and recoveries.INTRODUCTIONPeñoles was founded in 1887. It is a mining group with integrated smelting, refining and chemicals producing operations. Peñoles is the world largest producer of refined silver and metallic bismuth, the leading Latin American producer of refined gold and lead. It is amongst the world leading producers of refined zinc and sodium sulfate.Peñoles operates and controls six underground mines in Mexico and is the largest producer of zinc and lead of the country. It also produces copper concentrates and cathodes. Through its 77.1% equity stake in Fresnillo plc (a London Stock Exchange listed company); Peñoles is also a significant producer of gold and silver. Fresnillo plc operates three precious metal mines in Mexico. While Fresnillo is the world largest primary silver mine, Ciénega and Herradura are two leading gold mines of Mexico. Figure 1 shows a map of Mexico indicating the locations of the Peñoles mines. The main process characteristics of each concentrator are listed in Table 1."

Jan 1, 2011

By Ian Ewart, Trevor Bergfeldt, Gourab Satapathy, Ajay Patel

"Conventional electrowinning (EW) of nickel from sulfate electrolytes is complicated by several factors including the requirement for a diaphragm cell to separate the anolyte and catholyte and the need to minimize nickel mist emissions. Developed and commercialized by emewCorporation, this novel process electrowins high purity nickel cathode (99.5%) from copper refinery bleed streams using the proprietary emew vortex EW technology. The emew nickel process incorporates high flow rate in an enclosed cylindrical EW cell operating at high current densities that overcomes the challenges of conventional nickel EW and completely eliminates the risk of nickel mist emissions. The tubular cathodes are easily harvested and mitigate the effect of plating stresses inherent in nickel EW. The present paper describes the emew nickel process and its most recent application to copper refinery bleed streams at full-scale.INTRODUCTION To meet the stringent demand of customers, nickel producers are giving prime importance to production of high purity nickel cathodes. The major challenge for refineries is to improve cathode quality and appearance despite fluctuating electrolyte impurity levels. The basis of achieving good quality cathode includes the control of electrolyte impurities and consistency of specific process conditions. The commercial operation of emew nickel technology has been successfully implemented and has demonstrated the ability to produce high quality nickel cathode from refinery bleeds. This paper emphasizes the importance of upstream impurity removal to achieve the required nickel emew feed composition by evaluating the benefits of using selective precipitation as a purification scheme with the aim of improving the overall nickel recovery while ensuring suitable nickel concentration in the advanced electrolyte is achieved. Nickel electrowinning is similar to other electrowinning processes that employ insoluble metal anodes & cathodes. It requires the passage of direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. For the recovery of nickel from solution, the most common methods are electrowinning and hydrogen reduction. Electrowinning usually occurs from sulfate, chloride or mixed sulfate/chloride electrolytes. In sulfate electrolytes, nickel electrowinning cells are normally designed to achieve specific criteria as outlined below (Robinson & Tuppa, 2002):"

Jan 1, 2017

By J. C. Moreno, G. Rios, M. Palacios

The Huelva smelter was commissioned in 1970 coinciding with the shutdown of the old smelter in the Rio Tinto mine site. That new smelter consisted of two Momoda blast furnaces with a capacity of 500 dmtpd of concentrate. Nevertheless, soon after their start-up, it was clear that an increase in the smelting capacity was needed. After an analysis of the existing alternatives at that time, the flash smelting technology was chosen. The new Outokumpu Flash Smelting Furnace (FSF) came into operation on 18 September1975, with an initial capacity of 900 dmtpd of concentrate, using four Venturi-type burners and preheated atmospheric air. Since that date the Huelva Smelter team, together with Outokumpu (now called Outotec), have continuously improved our FSF design, process conditions and operational practices, leading to a present capacity of 3,500 dmtpd of concentrate. Since 1975, five smelting campaigns have been completed, the last ending in November 2013 with the rebuilding of the original FSF hearth. This paper describes the history of these improvements and the lessons learned.

Jan 1, 2014

By J. Tuominen

Outokumpu Direct-to-Blister Flash Smelting is currently in operation in two smelters, a third one is under construction and a fourth one is in the design phase. The two smelters in operation are the Glogow 2 smelter of KGHM Polska Miedz S.A. in Poland and the Olympic Dam smelter of BHP Billiton in Australia. The Outokumpu Direct-to-Blister smelter of Konkola Copper Mines Plc. in Zambia is under construction and the new smelter of Glogow 1 is under design and waiting for final go-ahead decision. Additionally, the Garfield smelter of Kennecott Utah Copper Corp. makes blister copper out of matte in a Flash Converting furnace. A similar operation is under construction for Y anggu Xiangguang Copper Co. in China. The slag cleaning process, which is needed to clean the slag of the Direct-to-Blister Flash Smelting Furnace, has different requirements depending on the feed to the flash furnace. These differences are discussed in the paper. The differences between the processes and slag produced are discussed as well as the metallurgical requirements for slag cleaning. The Direct-to-Blister process, where the blister copper is produced directly from concentrate in one step, requires at least a partial treatment of the slag in an electric slag cleaning furnace. The existing impurities determine the specific requirements of the actual cleaning process. The different processes are discussed in the paper. The newest developments of Outokumpu Technology Oy for electric slag cleaning furnace design are presented as well as the characteristics which the furnace shape gives to the process.

Jan 1, 2007

By N. Chow, W. McCombe, G. Remple, J. Nikkari, L. Nightingale-Mercer

Orano Canada Inc. (Orano) operates the McClean Lake mill in northern Saskatchewan, processing high concentration uranium ore, delivered in slurry form, from the Cameco operated Cigar Lake mine. This slurry is ultimately processed into the purified uranium oxide product known as calcined yellowcake. During the calcining process, sulphate (SO42-) entrained in the yellowcake undergoes thermal decomposition into sulphur dioxide (SO2). SO2 is a colourless gas that poses health and safety risks. Since 2016, an anhydrous ammonia dosing system was successfully added to the existing Venturi particulate scrubber system to provide efficient removal of SO2 from the calciner off-gas. Within the pH controlled scrubber solution, SO2 exists in a pH dependent equilibrium with sulphite/bisulphite (SO32-/ HSO3-). The presence of a significant fraction of reduced sulphite and bisulphite in mill solutions presents a hazard in downstream circuits. Should these solutions drop in pH, either through natural oxidation or inadvertent mixing with low pH solutions, the solution equilibrium will shift from SO32-/HSO3- in favour of SO2, resulting in the evolution of SO2 gas from any liquid surfaces. In 2018, Hatch Ltd. (Hatch) and Orano implemented a design change in the calciner scrubber system. Blowdown from this system is now treated in an oxidation pre-step utilizing hydrogen peroxide (H2O2) and anhydrous ammonia (NH3) for pH control, in order to convert the residual sulphite/bisulphite present in solution to stable ammonium sulphate product. This paper will detail some of the challenges and actions undertaken to minimize SO2 risk, culminating in the recent introduction of a novel system designed to oxidize sulphite/bisulphite and prevent mobilization from the calciner scrubber solution into other mill areas where there is the potential for acidification and SO2 release.

Jan 1, 2020

By A Palynchuk

The development of welded pipe has paralleled the general industrial development and, in particular, that of the petroleum industry. The petroleum industry's need for high-grade, economical pipeline material to make many 'of its projects feasible has been a significant factor in the development of light-wall, high-grade welded pipe. The modern welding processes, such as high-frequency, electric resistance, flash, submerged arc, etc., have some basically different characteristics. The modern high-frequency weld mill is a complex of specialized equipment that is integrated into a production unit. Each component in the unit performs a specific function in the production process. Quality control must be built into the process on an operating basis and, to maintain the quality required for pipeline standards, must be more than a policing operation. The further development of the welded pipe industry will be determined by changing and increasing demands. The technical and economic views and requirements that will influence the development have to be resolved.

Jan 1, 1964

By Daniel E. Walsh, P. D. Rao

"A four-inch compound water cyclone (CWC) was tested to evaluate its gold recovery characteristics when processing -4.8 mm run-or-pit, placer material. Neutron activated placer gold particles (840 to 37 microns) were used as radiotracers (/98Au) in a closed circuit ewe test loop to determine concentrator recovery; a procedure believed unique to this study. The effect on gold recovery of gold size and shape, feed pulp density, feed pressure, vortex finder clearance (VFC), ewe cone type, top-size of the feed solids, presence or absence of heavy minerals in the feed, and the quantity of-37 micron slimes in the feed was investigated in over 300 tests.CWC concentration ratio and the top-size of the underflow solids were both affected by cone type, VFC, and feed pressure. Gold recovery was significantly affected by gold size, gold shape, and concentration ratio. These effects are complex, because significant size-concentration ratio and size-shape interactions exist. Radiotracer techniques showed gold particles had a residence time within the ewe of approximately one second. This study suggests ewe gold recovery is a concentration. This work suggests ewe gold recovery is a function of particle size and shape, and the flow rate through the cyclone. CWC cone ""bed density"" is considered important only as a thin, protective layer, which shields coarser gold particles from the entraining currents and facilitates their movement through the CWC.IntroductionCompound water cyclones (CWC), or automedium cyclones, are enhanced gravity concentrators for the beneficiation for slurries of sand, coal, and ground ore (Fig. 1). They are called compound water cyclones because of the compound slopes of their basal cones (Fig. 2) and are operated to suppress classification phenomena in favour of gravity concentration effects. The compound water cyclone is not a new wet concentrator. It was developed in the late 1950s by Dr. Jan Visman through research sponsored by Canada's Department of Energy, Mines, and Resources. Since that time, it has become a common unit in coal washeries for cleaning fine coal. CWCs and other versions of concentrating cyclones have also shown promise for heavy minerals and precious metals recovery."

Jan 1, 1988

By Mei-Yan Yang, Qiu-Ying Wang, Ltd. Yunnan Yuntong Zinc Co., Guo-Mu Chen, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"Historically, alot of jarosite was found in the leaching residue when leaching indium from secondary zinc oxide materials. The reasons for the formation of indium bearing jarosite were theoretically analyzed. The influence of controlling the acidity and the addition of reagents on the indium leaching yield during secondary zinc oxide processing was investigated. In order to increase the leaching yield of indium, a measure of controlling the creation and destruction of jarosite was proposed. The production data shows that the leaching yield of indium was increased from 60 to 96%, and the content of indium in leaching residue simultaneously decreased from 900g/t to 100–200g/t when implementing such controlling measures.INTRODUCTIONIndium does not occur as independent minerals in the earth’s crust and is mainly associated with complex sulphide minerals. Specifically some sphalerites can contain as much as 900g/t of indium. Most indium is recovered from by-products of copper, lead or zinc metallurgy. Therefore, the research on the recovery of by-products in non-ferrous metallurgy is important(Sinclair et al, 2006). The main technologies used for this objective in China include: •,pre-neutralization-reduction-precipitation indium process(Yu et al, 2008), •,countercurrent oxidizing acid leaching process and sulphation roasting-water leaching process(Cao, 2005), •,oxygen pressure acid leaching of zinc concentrate-P204 extraction process(Yang et al, 2006), •,doubleacid leaching-solvent extraction process on lead dross from a reverbatory furnace flue dust(Liu, 2003),•,an acid leaching-solvent extraction process on smelting ash(Zhouet al, 2005). Although high pressure and extreme conditions can be used to improve extraction from high iron bearing indium residues(autoclave processing), mild extraction with lower cost and lower environmental impact are preferred.This paper describes both how the indium extraction using mild conditions in a secondary zinc circuit was quite low and, how through XRD and chemical analysis jarosite formation was found as the main cause. The paper then proceeds to discuss a method for improving the leaching yield and the application of this method in industrial practice."

Jan 1, 2016

By Norman A. M Macleod

FOR the past seven years, all flotation at the Britannia mill has been done in Forrester Air-Lift cells. Prior to 1931, the roughing and part of the cleaning operation had been performed in four 21-cell and two 14-cell M.S. machines. The resulting economies in reagent, power, maintenance, and general operating costs, and the increased recovery, more than justified the exclusive use of the Forrester machine. About three years ago, the possibility of still further improving the efficiency of the flotation section was the subject of considerable discussion and experiment. Arising from these experiments, tests were made of the practicability of using a cell of greater depth than that of any pneumatic or mechanically-agitated machine in common use. Cells were constructed with depths of 7 .5 feet, 10 feet, and 15 feet, and, in all cases, a very definite improvement in operation was indicated. The cell now being used in the mill treats from 5,500 to 6,200 tons of dry feed per day. It is 100 ft. long by 5 ft. wide by 8 ft. deep, and has replaced a total length of over 500 feet of standard Forrester machine. The choice of a depth of 8 feet was governed by the type of blower which was available-in this case, a Roots-Connersville blower, driven by a synchronous motor and delivering 6,000 c.f.m. of free air at 4.0 pounds per square inch. At the Chelan Division of the Howe Sound Company, where a new mill was recently built, all flotation is carried on in cells 10 feet deep, with good results.

Jan 1, 1938

By Fred C. Delabbio

The successful implementation of a new technology in an underground production mine requires many challenges to be overcome. These challenges include mine hardening of new technology, mitigation of safety risks and hazards, mine operation support, and technology transfer to mine staff. In the end, the majority of these challenges relate to the human aspects of implementation. The approach selected to overcome these challenges must be customized and appropriate for each unique situation. This paper outlines the approach used to address these challenges as part of successful implementation and resulting demonstration of the hydrogen fuel cell locomotive at the Placer Dome (CLA) Limited, Campbell Mine. This technology demonstration at Campbell Mine is critical for determining technical, regulatory and implementation aspects to be incorporated into future fuel cell prototypes such as the LHD project.

May 1, 2003

By J. M. Skeaff

"The main solution, ore and residue pulp streams in the Rio Algom Quirke I uranium mill at Elliot Lake have been sampled and analyzed for radium-226. Analysis of the ore and leached residues indicates that Ra-226 dissolves and precipitates within the first pachuca tank. A maximum of approximately 0.2% of the Ra-226 in the ore remains in solution during leaching.IntroductionConcern over the acid drainage and radionuclide dissolution problems associated with uranium tailings disposal sites in Canada has prompted investigation into methods for improving current uranium processing practice.Present commercial practice usually involves leaching of the uranium ore with sulphuric acid, ion-exchange separation of the uranyl sulphate complex from the leach liquor and"" precipitation of the uranium as yellowcake. Daughter products of U-238, such as Th-230, Pb-21O and Ra-226 remain with the tailings and undergo long-term dissolution.Table I summarizes the probable behaviour of the radionuclides during milling. The concern here is with Ra-226, because it will deposit in the bones if ingested and is ""thus considered a serious health hazard(1), Similarly, Po-218 and Bi-214, which are daughter products of Rn-222, can be retained in the lungs and are considered to be the principal sources of radiation dosage(2) arising from the inhalation of Rn-222. Previous investigations(3-9l indicate or imply that Ra-226 undergoes redistribution during milling. However, detailed published information on the behaviour of Ra-226 in the uranium milling process appears to be lacking. A knowledge of the behaviour of Ra-226 in uranium mills, particularly during leaching, could lead to improved methods for its control.This paper reports the occurrence of Ra-226 in the Rio Algom mill. The main objectives of the study were to determine (1) the distribution of Ra-226 within the solids, (2) at what point, and how rapidly, redistribution occurs and (3) whether there are high concentrations of Ra-226 in solution."

Jan 1, 1981

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By J. W. G. Hannon

FOLLOWING the experimental work of Denny, Robson, and Irwin, and the clinical investigation by Crombie and Blaisdell, an investigation of aluminium therapy was begun at Washington, Pa., which is situated in a very large industrial section of the State. Some of the men to be studied were from plants manufacturing silica brick, refractories used in steel and glass manufacturing, and semi-porcelain table-ware; others were workers in foundries, sand blasters, and men engaged in the quarrying of ganister rock. This group of workmen gave an opportunity to study the effects of aluminium on various types of silicosis which differed somewhat from that found in hard-rock miners. EXPOSURE In their occupations, the men studied were exposed to silica dust concentrations ranging from 17 to 97 per cent free silica. In the silica brick industries, the unfired product averages 96 per cent silica in the form of quartz, whereas the fired brick contains 50 to 62 per cent cristobalite plus 17 to 30 per cent tridymite, forms of silica that, on account of their higher solubility, are more toxic than quartz. The operational dust counts in the plants varied from 15 to 9,500 particles per c.c., and the median particle size from the aerial samples was 1.0 micron for the green product and 2.0 microns for the fired product. The length of exposure varied with the occupation as well as with the individual plant, but disabling silicosis could be produced in less than four years in certain exposures. The average time needed to produce radiological silicosis in those susceptible to this disease was eight years. Some of the men in our series of cases have been treated as long as fifteen years after exposure had ceased, and have improved under treatment.

Jan 1, 1944

By P. O. Sandstrom

"Atlas Copco is introducing a new patented method for full-face boring. This paper presents the basic principles of the boring action and discusses the present experience regarding performance and costs. The Atlas Copco ""Full-facers"" are designed for hard-rock applications, although they are successfully boring in soft ground without major changes. The unique patented boring principle referred to as the 'Undercutting Method' permits these machines to bore, economically, in harder ground than machines based on the 'crushing principle'. This is mainly due to considerably lower cutting-tool costs, as the tungsten carbide tips only are in contact with one-third of the bored volume. The remaining rock is 'undercut' and peels off from a slight back pressure.The undercutting method also permits boring of non-circular headings and Atlas Copco has already manufactured two machines for rectangular drifts. This concept could revolutionize development work in mines employing trackless equipment."

Jan 1, 1971

By B. D. H. Knights, N. B. du Preez

The recovery of the economy of the Democratic Republic of Congo has allowed for the rapid increase in production of copper from this region, while the increased price of cobalt continues to support the recovery of that country’s economy. This has enabled the modernization of the process technology used, particularly the change from direct electrowinning of copper to solvent extraction-electrowinning. With this change has come a variety of technical challenges in optimizing the recovery of cobalt from these sources. In this paper, we discuss aspects of the flowsheets for the production of cobalt from the ores of the DRC and Zambia, highlighting the technological improvements that have been made. Following this description of the practice, we assess the challenges of further improving the recovery and purity of cobalt from these sources. INTRODUCTION The African Copperbelt (Figure 1) is by far the biggest producer and holds the greatest reserves of cobalt (Sheed, 2015). However, the ores of this great mining region are extracted primarily for their copper content, and cobalt is a by-product. The ratio of copper-to-cobalt is between 6 and 20 to 1, with the ores from the DRC richer in cobalt than those from Zambia. The overall supply of cobalt, shown in Figure 2, is increasing due to an increase in demand for its use as a battery material. Cobalt is used in superalloys, hard metals, pigments, catalysts magnets, tyre adhesives, lithium-ion rechargeable batteries, and wear-resistant coatings, amongst others. Although these generic categories persist, Figure 3 shows how the relative usage of cobalt is changing due to the uptake of electric vehicles in China and Europe. Cobalt is a key element in lithium-ion batteries, and because it is widely anticipated that electric vehicles will be legislatively encouraged, it is anticipated that the demand for cobalt will rise. This anticipated increase in demand resulted in an increase in the price for cobalt, to which suppliers responded over-eagerly, and the price has dropped dramatically in the first few months of 2019, as shown in Figure 4. However, there is a clear cycle of price peaks in cobalt’s history.

Jan 1, 2019

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami, G. P. Cole

"The past several decades have seen a steady increase in the use of atmospheric monitoring systems (AMS) in underground mines as sensor technology has advanced and costs for this technology have decreased. The AMS is a reliable tool for early mine fire warning by detecting gaseous products of combustion in underground mines. During a mine fire emergency, mine decision makers rely heavily on the prompt and accurate knowledge of the ventilation and fire situation in the mine, such as fire location, fire size, and the spread of smoke to make effective and efficient decisions on firefighting strategies and miner evacuation. Meanwhile, a prediction of the potential for fire development at a later time, such as whether the currently designated mine escapeways will be contaminated by smoke and toxic gases with the progress of the fire, is critical for effective decision-making to save lives that are in danger. The AMS monitoring data, including carbon monoxide (CO) concentration, airflow rate, smoke, etc., can provide information as to whether the smoke has reached the locations where AMS sensors are installed and if a mine-wide smoke spread has occurred. The National Institute for Occupational Safety and Health (NIOSH) has undertaken a task to integrate real-time AMS monitoring data with the mine fire simulation program, MFIRE, to simulate and predict the spread of smoke and toxic gas in a ventilation network based on the real-time AMS data. This paper reports the developed real-time method for characterizing the size and location of an underground mine fire and for predicting the spread of contaminants throughout the mine ventilation network using sensor data from the AMS.INTRODUCTIONNIOSH conducts research to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions in underground mines. The advancement of senor technology and the increasing demand for real-time mine parameters monitoring have led to extended applications of atmospheric monitoring systems (AMS) in underground mines worldwide. In the United States, AMS is primarily used for early mine fire warning by detecting carbon monoxide (CO) in fire hazard areas, such as belt entries. Mine fires can grow rapidly, and time is the critical element. Prompt detection, timely and accurate warnings to those miners potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground mine fire (Conti et al., 2005). The early detection of a mine fire could gain time for the first responders to put out the fire before it develops into a disaster. An AMS system with CO sensors has especially played an important role in the early detection of mine fires. The continuous monitoring of an underground mine atmosphere with an AMS could generate a large amount of data in a mine fire event. However, the current application of AMS is mainly limited to sending out an alarm when monitored CO concentration exceeds a certain level. An opportunity arises as to whether these data can be further used in fire emergency response. In order to make effective decisions on firefighting strategies, mine workers’ seeking refuges, evacuation and escape, and the timing on when to send rescuers, decision makers need accurate and timely knowledge of the ventilation and fire situation in the mine. Information about the fire intensity, where in the mine the smoke and toxic gases have spread, and whether designated mine escapeways have been compromised by smoke and toxic gases from the fire would greatly increase the effectiveness of these decisions. However, the monitored AMS data only provides atmospheric conditions in the vicinity of sensor locations. What is concluded from the monitored AMS data highly depends on the decision makers’ capability and experience. Predictive insight into fire growth and smoke transport would greatly help decision makers during a fire emergency."

Jan 1, 2019

By D. A. Akinlade, N. L. Richards, D. C. Murray, W. F. Caley

To investigate the effect of adding Ti to a Ni-Cr-Fe powder metallurgy alloy, a thermodynamic software package was used to predict the phase transformations that occurred during thermal processing. Specifically, the effect of adding 3w/o Ti to a 6w/o Al modified ternary Ni-Cr-Fe alloy (the quaternary) was simulated and the phase transformations that might occur in the material on sintering were obtained using the thermodynamic modeling tool. These predictions were subsequently compared with experimental results obtained by X-ray diffraction and metallography. For comparison, selected compacts were prepared containing only the ternary + 3w/o Ti (no Al). Based upon compressibility curves, the optimum pressure for producing the new Ti compacts was 500 MPa vs 600 MPa for the quaternary composition with Ti. In each case, hardness of the base alloy was enhanced by the Ti addition whereas the residual porosity remained relatively constant at about 19%. Finally, although SEM/EDS failed to confirm the presence of Ti in the gamma prime intermetallic, XRD spectra showed a shift in lattice parameter on addition of Ti, suggesting that the intermetallic was of the form Ni3(Al,Ti).

Jan 1, 2010