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By E. J. Marcotte

"INCO LIMITED'S Shebandowan Mine and Mill is located in a scenic tourist and cottage area near the western tip of Lower Shebandowan Lake, approximately 90 Km west of Thunder Bay, Ontario. This nicely designed complex is a positive indication that mining operations can co-exist in harmony within the natural environment.The Shebandowan complex processed nickel-copper ore from 1973 to 1985, inclusive, after which operations were shut down.In late 1988, INCO LIMITED decided to place the Shebandowan complex back into operation, under contract, to mine and mill the remainder of the ore body, according to their specifications. MaclSAAC'S EXPLORATIONS was the successful bidder for the project. Following preliminary rehabilitation, operations were re-activated in late March, 1989. The ore mined to date is of a moderately lower nickel grade than the majority of previous years. However, a higher tonnage rate, combined with improved nickel recoveries, has contributed to a viable operation.A series of mill operating and equipment modifications has enabled MaclSAAC EXPLORATIONS to achieve the quality and grade of nickel-copper concentrates specified, and at the same time, expand mill tonnage throughput while attaining increased nickel recovenes."

Jan 1, 1992

By D. F. Zhang, X. Q. Jiang, N. Tahreen, D. L. Chen, F. S. Pan, D. Y. Li

Alloying with rare-earth elements has been proven to be an important tool for magnesium to achieve superior properties via texture randomization. The role of yttrium in texture weakening and the link between texture and formability are fairly well known. Since annealing is a vital part of metal processing which could significantly contribute to ductility, it is important to ascertain the impact of annealing in terms of texture change. Also, an understanding about texture development during pre- and post-deformation annealing is essential to improve the industrial deformation processing as texture is closely related to formability. While there is independent information in the literature regarding the effect of rare-earth addition and heat treatment on the texture formation, no systematic studies have been reported on the collective impact of yttrium addition, annealing and deformation on texture evolution. The present study was, therefore, aimed to identify the inter-relationship among texture evolution, yttrium content, heat treatment and deformation behavior in an extruded Mg-Zn-Mn-Y alloy. Annealing at 450°C for 1 hour and uniaxial compression tests at a certain amount of deformation were performed. The deformed and annealed samples were then subjected to annealing and compression test, respectively, followed by texture measurements. It was observed that yttrium addition effectively weakened the crystallographic texture in all conditions, which was evident from the changes in the microstructures and textures.

Jan 1, 2015

By W. J. S. Craigen, G. E. Wittur

"In the context of today's continuously changing world, there are many factors which must be considered when attempting to assess the ability of Canada's primary copper producers to remain competitive in the face of increasing competition in world markets. In this paper, we have attempted to document those factors that will have the greatest impact on the future viability of Canada's copper industry, and to suggest possible strategies to fully utilize whatever inherent advantages Canada may have to enhance its competitive position. Technological factors related to the efficiency of precious and by-product metals recovery, energy type and utilization efficiency, production and sale of sulphur by-products, and control of 502 emissions are given high priority in this evaluation of Canada's future needs to remain competitive. Particular emphasis is placed on assessing the relative viability of hydrometallurgical versus pyrometallurgical processes for copper; to address uniquely Canadian conditions and problems. Due consideration is also given to the economic incentives required to allow Canada's copper producers to compete under anticipated world market conditions and to facilitate the continued development of Canada's copper resources. IntroductionWhen we try to assess the viability or competitiveness of any industry the bottom line is still usually, ""Can we produce a pound of product cheaper than the competition?"" Canada's copper industry is certainly no exception. However, as with most resource-based industries dependent upon exports, there are many factors which have a significant effect on the cost components which make up the total cost of producing and selling a pound of copper. It is desirable therefore to have as clear a picture as possible of the cost components, the major factors affecting them, and how they compare with the competition, particularly the third-world copper producers.In this paper we have attempted to provide a brief outlook for world copper markets and a brief overview of Canada's competitive position. We have also attempted to document those factors which will have the greatest impact on future production costs, and have suggested possible initiatives to utilize inherent Canadian advantages to enhance our competitive position. Special emphasis has been placed on technological initiatives designed to make full use of these ""advantages"", to develop superior beneficiation and extraction! refining technologies. Major factors considered in the present study are:"

Jan 1, 1986

By I. Yutronic

Compañía Minera Doña Inés de Collahuasi's (CMDIC) Concentrator Plant is located at 4300 meters above sea level, approximately 2000 kms north from Santiago, Chile. The concentrator has three grinding lines. Each one, Lines 1 and 2, have one SAG mill at the primary grinding stage followed by a secondary grinding and classification stage consisting of one ball mill, two hydrocyclone batteries and a sump with two pumps. Line 3 has one SAG mill (Gearless Mill Drive), followed by a secondary grinding and classification consisting two ball mills, four hydrocyclone batteries and a sump with four pumps. Average throughput for these three lines is 150 Ktons per day. Peak values of 180 ktons per day have been achieved. Since late 2008 and throughout 2009 and 2010, Operations and Automation areas developed an optimization program for the grinding process, considering the implementation of Model Predictive Controllers (MPC) for the three SAG mills, and later, extending MPC to the secondary grinding and classification stages. The implementation of a MPC solution was based on stability considerations (high variability of the SAG process, high interaction between sump level control and classification efficiency, etc), requirements for an automated and consistent operation, the need to maximize throughput under timevarying scenarios and, in the long term, optimization of grinding process considering Specific Energy Consumption, among other parameters. MPC solutions had proven control robustness and strong optimizing capabilities in terms of helping in discovering new operational points and so achieving all of the aforementioned goals. On the first stage of the program, MPC implementation considered identification of dynamical process control models based mainly on historical data, in order to know the impact of a group of Manipulated Variables over Controlled Variables. Also, the impact of measured Disturbance Variables was modeled in order to take into account the high impact and interaction of these variables over the processes. At the end of this stage, 4 controllers were successfully operating for the 3 SAG mills and the secondary grinding and classification process. In response to challenges made by the working group, the second stage of the development of control applications in the grinding process required to achieve a design and implementation of a solution capable of governing the milling process, in addition to stabilization and optimization of both processes (SAG milling and secondary grinding), to integrate from a point of view of process control and automation. Therefore, in the second stage, MPC performance was continuously monitored and optimized through advanced tuning, inclusion of more process models (with proper step tests), redefinition of specific optimization criteria and adjustment to new process needs. Finally, successful MPC implementation at Collahuasi has proved that fast development and deployment of process control solutions is possible and allows immediate process stability, higher throughput, specific energy consumption reduction, and successful product size control, among many others.

Jan 1, 2012

By Chuanhui Cao, Shimei Liu, Xiaojing Li, Yueyuan Zhou

"Force analysis on weakly-magnetic particles and non-magnetic particles in magnetic field are presented, using a kind of permanent magnetic drum magnetic separator, which is designed with strong specific magnetic force and open magnetic system. Its surface peak intensity reaches to 1.0T, and the distribution density of capture line is 1.25×103/dm2. Qualitative analysis on the particles including its magnetic property, particle size, motion speed, magnetic field intensity, etc. is also presented to calculate the separating parameters for the drum separator. Experiment was conducted for the separation of fine weakly magnetic minerals for example ilmenite. The practicability to separate the minerals using separator designed with open magnetic system has been proved, providing an economic way for efficient separation of micro-fine weakly magnetic minerals and upgrading of non-metallic minerals. INTRODUCTIONMagnetic separation is a mineral processing method based on the differences of magnetic properties between minerals in inhomogeneous magnetic field (Sun, 2007). Currently for separation of micro-disseminated weakly magnetic iron ore, electromagnetic high intensity magnetic separators with closed structure of magnet system are often used. And for the separation of strongly magnetic minerals such as magnetite, low intensity drum magnetic separators with open magnet system are often used. In order to lower the operation costs and improve energy efficiency, it is important to develop efficient high intensity permanent magnetic separator with open magnet system, to some extent replacing high intensity electromagnetic separator.Oberteuffer (1974) discussed the magnetic force and competing forces in magnetic separators which compete with the magnetic forces and act on all of the particles which travel through the separator are those of gravity, hydrodynamic drag, fraction, and inertia in magnetic separation."

Jan 1, 2016

By D. Sagara, V. G. Makhado

"A model based control strategy was implemented at Loulo Gold Mine in Mali, to stabilise the thickener underflow stream density. This stream acts as the feed to the leaching circuit. pH control of the leaching circuit was integrated with the model-based controller due to slow process dynamics that are not suited to PID control. The controller performance was quantified over a period of 6 months, and was compared to the performance before implementation. The model based controller reduced process variability for both thickener underflow density and pH considerably, and resulted in a reduction in flocculant and lime consumption of 9.32 and 6.55%, respectively. INTRODUCTION Reagent consumption in gold processing plants significantly contributes to the total operational costs. In a typical Carbon-in-pulp (CIP) circuit, the reagent consumption associated with leaching, adsorption, elution and regeneration contribute to approximately 15% of the total operational costs (Stange, 1999). At Loulo Gold Mine, the reagent consumption associated with leaching, adsorption, elution and regeneration contributes to 6% of the total operational costs. As such, a reduction in reagent consumption will present a significant opportunity for savings on operating expenditure. Variability in feed ore characteristics results in continuous changes in steady state operating regions, which presents process control challenges as a result of the long residence times in some of the process units associated with gold processing plants. Overdosing often occurs in the presence of process variability to ensure safe operation and to maintain recovery targets. As a means of reducing reagent consumption and accounting for significant changes in the feed to gold plants, some of the plants have resorted to improving their process control strategies around their circuits. This paper focuses on the implementation of a model predictive based controller at Loulo Gold Mine on their thickener and Carbon-in-leach (CIL) tank to: •,stabilise the thickener underflow density, and •,the CIL tank pH."

Jan 1, 2017

By R. Pandher, R. Schonewille, N. Tripathi

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGE TM METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011

By R. Pandher, R. Schonewille

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGETH METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011

By G. J. McTeer, D. L. Verhelst, D. J. Rioux

Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. Since 1997, KIVCETTM flash smelting technology has been utilized for the treatment of zinc plant residues and lead concentrates. Trail Operations’ furnace uses four water-cooled jackets for bullion tapping. This paper provides an overview of KIVCET bullion tapping for the past 16 years, and discusses successes and challenges encountered with respect to operations, training and monitoring.

Jan 1, 2015

By T. Bednarski, T. McCallum, L. Moya, L. Nsenga, B. Mbao

The accumulation of solids in solvent extraction (SX) circuits can cause problems with the physical and economic performance of the operation. These solids are responsible for the formation of crud, a solid stabilized emulsion containing organic, aqueous, air, and fine solid particles. The build-up of crud in SX settlers can limit SX operation throughput, require plant downtime, lead to higher organic losses, or result in higher aqueous in organic entrainment (all of which can have a significant, negative economic impact). Current practices for crud management are typically reactive. Crud is physically removed after it has been allowed to build to excessive levels in the circuit and processed mechanically using centrifuges or filtration. A new proactive solution has been developed to prevent crud formation and build-up. Low ppm dosage of an additive, ACORGA® CR60, into the pregnant leach solution (PLS) has resulted in reduced crud formation in pilot and commercial scale for a variety of PLS streams. This paper will review results from operations in North America and Africa, covering heap leach, concentrate leach, and agitated leach feeds. INTRODUCTION Crud formation and build-up in solvent extraction (SX) circuits has been a long time topic discussed and claimed to be crucial to the whole hydrometallurgical process (Liu, et al, 2006). Crud formation is present in all SX systems be it copper, uranium, zinc, etc., and Ritcey (1980) defined crud as a stabilized emulsion containing organic, aqueous, and fine solid particles. The ore type and feed composition is a major determining factor of crud formation and typically contains Si, Al, Fe, P, and sulfates (Ritcey, 1980). It typically builds at the interface between the organic and aqueous, but can also be observed as floating crud on the surface of the settler, or bottom crud, which is common to find in circuits treating agitated leach feeds such as in Africa. As crud formation has been unavoidable, many of the current crud management techniques are reactive, allowing crud to form and build in SX circuits. Once it does, it is removed and treated via different mechanical techniques, typically through some type of filtration or three-phase centrifuge, to remove the solids and recover the organic phase trapped within the emulsion (Ritcey, 1980). Automated pumping systems have also been designed and are frequently used in North American operations. The time and capital required to react to crud formation can be an overwhelming aspect to SX operation.

Jan 1, 2019

By V. J. Southey

"This paper reviews the history of Wabana Mines from 1892 to 1966, inclusive, in order to clarify the essential factors involved in the achievement of maximum mining efficiency and in the search for an acceptable product to satisfy changing market requirements. It outlines the progressive steps taken to mechanize both surface and underground operations, and forecasts anticipated performance, assuming certain major plans could have been implemented. Results of extensive research in the treatment of the complex ore are discussed. Selected processing alternatives are compared as to feasibility in a summary incorporating estimated capital and operating costs."

Jan 1, 1969

By C. Yoo

"Geosynthetics engineering has made phenomenal advances during the last decade in areas of manufacturing as well as practical applications. As a result, geosynthetics are now being recognized as essential construction materials that can be used to facilitate construction, ensure better performance of the structures and reduce the long-term maintenance in routine civil engineering works. The creative use of geosynthetics in geo-engineering practice is expected to continuously expand as innovative materials and products are becoming available. In this paper, a wide variety of geosynthetic products available to geoengineers to solve a wide range of problems are briefly presented along with their functions and possible applications. Fundamentals of geotextile filter design principles are then introduced for use in the tunnel drainage system. Practical applications of geosynthetics relevant for tunnel engineering are also highlighted with emphasis on the issues associated with the geotextile filter application for use in the tunnel drainage system.INTRODUCTIONGeosynthetics have emerged as essential engineering materials in a wide range of civil engineering applications, e.g., transportation, geotechnical, geoenvironmental, hydraulics, and private development since the first geosynthetic conference in Paris, 1977 (Koerner 2012). Due to their costeffectiveness, ease of installation, and well established mechanical and hydraulic properties, geosynthetics are now playing important roles in the field of geo-engineering.As indicated in the 9th Bucahanan Lecture paper by Holtz (2001), major developments in civil engineering have only been possible with the parallel developments in the technology of construction materials. For example, larger scale structures became possible with the help of developments in concrete, reinforced concrete, and prestressed reinforced concrete technology which replaced wood and building stone as construction materials. The best example of a parallel development in geo-engineering between the material and the geotechnical application may perhaps be the soil reinforcement technology which has a direct analogy with reinforced concrete as a polymeric reinforcement material provides added level of tensile resistance and stability to soils that have little to no tensile strength, thus giving additional margin of safety."

Jan 1, 2015

By B. F. Haanel

IN the fall of 1929, a paper was presented at the Annual Western Meeting of the Institute entitled The Fuel Research Laboratories at Ottawa and the Scope of Their Investigations. At that time, the equipment of the laboratories had not been completely installed, but the regular routine work was being carried on as usual, and several large-scale investigations were being conducted. It is now five years since that paper was presented, and it seems fitting that a brief description of the investigations which have been undertaken, together with results-especially those which have reference to western Canadian fuels-be presented at this Annual Western Meeting. The coal mining industry of western Canada has, within the past few years, suffered many unfortunate vicissitudes. The replacement of coals by oil, for bunkering ships, for operating railway locomotives, and for heating, has weighed heavily on the coal mining industry of British Columbia and Alberta generally, but more particularly in the Crowsnest Pass area and Vancouver-and hydro-electric developments have also left their impress. With a full appreciation of these conditions, the Department of Mines planned research and large-scale investigations which it was considered would be of the greatest benefit to the coal industry, and the results have amply justified the plans and anticipations. The fact, however, must not be lost sight of, that the application of the findings of certain of these investigations would not have been feasible had not the Federal Government assisted the transportation of coal by the application of railway subventions. These subventions permitted Canadian coals to compete at competitive points with United States coals, and it must be admitted also in this connection that certain of the collieries which have benefitted, both as a result of the railway subventions and the investigations conducted by the Fuel Research Laboratories of the Department of Mines, made special efforts to produce a coal which was capable of competing with the American product, by special preparation at the mines.

Jan 1, 1936

By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By F. Stober, D. Wanblad, J. Ndlovu, L. R. Nelson, L. P. S. de Villiers

The single six-in-line furnace of the Polokwane Smelter is the largest installed high-intensity furnace for platinum group metals (PGM) base metals sulphide smelting in the world. The furnace employs state-of-the art technology to deliver a planned throughput of 650 000 t/a dry concentrate at a design 68 MW power input. This furnace, at double the capacity of previously existing PGM furnaces, offers low unit operating and capital cost through the resulting economies of scale. Key features of the design include:

Jan 1, 2005

By Jim Wickens, Andy Cole, John Pekrul

"The roaster facility at Barrick Goldstrike Mine treats double-refractory sulfidic/carbonaceous gold ore. Prior to oxidation in the roasters, the ore is ground in two parallel dry grinding circuits utilizing 19’ Ø x 75’ double rotator mills. The design plant throughput was 12,000 dstpd. However, process improvements have significantly increased throughput rates by 25-50%. The current daily throughput record is 20,078 dstpd. Grinding circuit improvements contributing to this success include feed size reduction, ball size optimization, automatic ball charging optimization, and operating strategy changes. In addition to the changes already made, this paper discusses future optimization initiatives including on-stream particle size analysis and “real-time” ore hardness determination techniques.INTRODUCTIONBarrick Goldstrike Mines is located 29 miles Northeast of Carlin, Nevada, USA. Through 2001, the property has produced over 23 million ounces of gold making it one of the premier gold operations in the world.Prior to Barrick’s ownership, the property began producing gold from a small heap leach operation in 1975. The small-scale heap leach production continued through 1986, and in January 1987, Barrick acquired the property. Increased exploration activity by Barrick significantly increased gold reserves. In August 1988, a 4,500 dstpd mill facility was commissioned to treat high grade oxide ore. Also, heap leach operations had significantly expanded. In 1990, the mill was expanded to 6,000 dstpd, and the first autoclave was commissioned to treat refractory sulfide ore. By the end of 1996, the mill and pressure oxidation facility had expanded to 16,000 dstpd and heap leaching had ceased as oxide reserves were exhausted. In 2000, a roaster facility was commissioned to treat double-refractory sulfidic/carbonaceous ore."

Jan 1, 2003

AGENDA ? Company Overview ? Industry Direction ? Technology to support maintenance ? data access, connectivity, process historian, downtime & production reporting. ? Case Studies Company Overview Corporate Offices Client Base ?16 consecutive years of growth & profitability ?#39 of Top 50 Control Companies (Worldwide) ?470 employees ?TSX: MTK Industry Direction Improved visibility into the business so they can: ? Reduce cost through better understanding of where costs are being incurred and making timely decisions. ? Optimize operations while leveraging existing assets. ? Have a single version of the ?truth? ? Deliver reliably to stakeholders on the demand for increased accountability (safety, environmental, regulatory performance etc?). ? Respond quicker to market conditions in order to out perform the competition ? Best in Class approach. Web is becoming the standard user interface.

Apr 1, 2005

The cost benefits of controlling dilution of extracted ore have been very well understood by miners and mining professionals for many years. However, as we strive towards more mechanization, the dilution factor has been compromised in order to fit ?equipment? that is better suited to provide improved safety and productivity. Alternately, the drilling and ground support is accomplished by handheld drilling. In 2007, a short study, commissioned by CAMIRO (Canadian Mining Industry Research Organization) on the safety of hand held drilling vs. mechanized drilling, concluded that the risk of injury with handheld drills was seven times greater than with mechanized drills. Armed with this data, MEDATech Engineering proposed to the CAMIRO group to fund development of a ?MICRO Bolter?.

May 1, 2009

By J. Kempken, R. Hagmann, C. -P. Reip, W. Hennig

The CSP technology symbolizes a highly productive process for the cost-effective production of steel grades with a range of sophisticated properties comprising both the inner quality of hot strip, its surface formation as well as the relating technological characteristics. Thanks to extensive development work undertaken during the last 15 years, the range of steel grades that can be produced was continuously expanded and the process technology optimized. The present paper describes the ongoing development work concerning the production of higher-strength, microalloyed pipe steels. The resulting hot strip, due to the associated thickness and the potential pipe diameters, is particularly suited for being processed to HFI-welded pipes. Based both on ferrite-pearlite as well as very fine-grained, ferrite-bainite hot-strip microstructures, strength levels of up to grade API X80 can be realized. It can be demonstrated that hot strip produced in a CSP plant has very good toughness values at temperatures down to -60°C and can even make application with required sour-gas resistance possible.

Jan 1, 2005

By Carmen M. Neculita

Optimizing the long-term efficiency of passive systems for the treatment of highly contaminated acid mine drainage (AMD) is still a challenging issue. The optimization lies, among others, on improving the understanding and quantification of metal removal mechanisms in order to predict and enhance the stability of neo-formed minerals in secondary phases. Sorption, and precipitation as oxides-hydroxides, carbonates and bio-sulfides are likely the most important metal removal mechanisms involved in passive biotreatment of both slightly and highly contaminated AMD. In the same time, the preferred mechanism is precipitation of metal sulfides that are more stable and less pH dependent than carbonates and oxides-hydroxides. However, results of relatively recent research studies performed at laboratory scale showed that sulfides accounted only for up to 15% of total metals removed in passive bioreactors treating highly contaminated AMD dominated by iron (around 500 mg/L). Several approaches were used in the aforementioned studies to understand and quantify metal removal mechanisms in spent reactive mixtures collected from long-term (12-15 months) operating column bioreactors. These included: thermodynamic equilibrium modeling and various chemical extractions and mineralogical analyses (such as single and sequential extractions, acid volatile sulfides-simultaneously extracted metals determination, scanning electron microscopy, X-ray diffraction, and thermo-gravimetric analysis). The large proportion of metals (85%) removed by sorption and precipitation as oxides-hydroxides and carbonates suggests a relatively high mobility of the neoformed minerals, especially in low pH conditions. However, no data is available on the long-term stability of spent reactive mixtures and, on the implications for the sustainable management of this type of solid waste. Lately there is almost a consensus that the efficiency of highly contaminated AMD treatment is warranted by the use of multi-step passive systems, including both chemical and biological units, installed sequentially. However, very few well-documented studies are available on the design, construction, operation and long-term efficiency of these multi-step systems. A leading example is the tri-unit passive system installed on the abandoned Lorraine mine site (Québec) to treat a highly contaminated AMD dominated by iron (about 2,500 mg/L). This tri-step system (160 m3), consisting in two bioreactors separated by a unit filled with wood ashes, achieves to date a satisfactory removal of iron (up to 99%). Moreover, based on the data collected during laboratory testing, iron was mainly removed in the wood ashes unit (from around 3,200 mg/L to 10 mg/L) by precipitation of oxides-hydroxides as predominant mechanism and only partially by sorption. However, no data is available on the actual metal removal mechanisms in the field. Overall, theses multi-step systems are more complex and their long-term performance is even less predictable than the single unit systems. This paper presents the current knowledge and the research needs on metal removal mechanisms in passive bioreactors and multi-step systems for the long-term treatment of highly contaminated AMD. KEYWORDS

Aug 1, 2013