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By Jae-sang Ahn

As the amount of construction information used in the growing construction field increases, the importance of efficient construction field management has been growing. Therefore, construction industry have been tried to introduce and conjugate various software and IT technology such as PMIS, Web Camera, RFID, GPS, PDA. However, existing IT technology especially PMIS have not been performed systematically because of difficulty of real time information collection and decision-making from the insufficient handy equipment. These problems make construction manager cannot efficiently respond to diverse condition occur in construction sites. In addition, after the completion, individual who use PMIS have to move another site and use another system so than cannot use information from previous sites. On the other hand, development of IT technology transmute PDA phone for text-based work like schedule management, internet research to smart phone for network based multimedia service. In other words, smart phone is not just IT equipment but new way for overall industry and it can satisfy the demand IT technology on construction sites. Therefore, the purpose of this study is introduce mobile based individual unit PMIS system using cloud computing and SNS which is in development progress. It is expected to be possible to collect and record the real-time information that occur at the site and make rapid decisions based on the recorded information, by converting the office works that are managed based on the site PC or Web, if the site management system that is based on the smart phones and Cloud computing that will be constructed through this research are utilized. After this study, it is necessary to research about interwork with project unit PMIS system and test on real construction site.

Aug 1, 2013

By D. A. McIsaac

In these days, when mass production seems to be the watchword of all industrial companies, nothing is left undone to attain this end. Transportation, where necessary, becomes a question of very great importance. For this reason every mechanical contrivance known to man is employed, with its resultant advantages. So successful has man's ingenuity been that, offhand, we are inclined to say that practically all transportation on a large scale is done mechanically, that is, where speed and economy are desiderata. Granting this, one would think that to read a paper on the horse before your honourable and highly technical Society would surely be a waste of time, and that any Company employing old-fashioned 'horse' power would certainly be very much behind the time, to say the least. However, the fact remains that the biggest industry in our country today-coal mining-must use horse power to a great extent, being compelled -both by considerations of economy and by necessity. For this reason,' in the production of coal under present conditions, the pit horse is of great importance to this industry and is to be considered seriously as one of the units that help to make coal mining a success or a failure. Hence, in employing horses as a power for transportation, care must be exercised in selecting the animals, and the care of this power must be considered as seriously as any other department of such an organization. In selecting a pit horse, several things must be borne in mind, that is, one must get as much horse power as possible in as compact a form as is practicable. This determines the type of horse we must use, which is of very great importance under our present conditions of coal mining. With low roof, steep grades, and forced production, a distinct type of animal must be selected.

Jan 1, 1930

By D. A. McIsaac

In these days, when mass production seems to be the watchword of all industrial companies, nothing is left undone to attain this end. Transportation, where necessary, becomes a question of very great importance. For this reason every mechanical contrivance known to man is employed, with its resultant advantages. So successful has man's ingenuity been that, offhand, we are inclined to say that practically all transportation ?On a large scale is done mechanically, that is, where speed and economy are desiderata. Granting this, one would think that to read a paper on the horse before your honourable and highly technical Society would surely be a waste of time, and that any Company employing old-fashioned 'horse' power would certainly be very much behind the time, to say the least. However, the fact remains that the biggest industry in our country today-coal mining-must use horse power to a great extent, being compelled both by considerations of economy and by necessity. For this reason,' in the production of coal under present conditions, the pit horse is of great importance to this industry and is to be considered seriously as one of the units that help to make coal mining a success or a failure. Hence, in employing horses as a power for transportation, care must be exercised in selecting the animals, and the care of this power must be considered as seriously as any other department of such an organization. In selecting a pit horse, several things must be borne in mind, that is, one must get as much horse power as possible in as compact a form is practicable. This determines the type of horse we must use, which is of very great importance under our present conditions of coal mining. With low roof, steep grades, and forced production, a distinct type of animal must be selected.

Jan 1, 1930

By T. Holmes, S. Davison

"The Special Standard Surge bin at Agrium’s Vanscoy Potash Operations (VPO) has been plagued with flow problems and wear, and corrosion issues for it’s entire working life. Investigation showed that the carbon steel construction, bin geometry, and resultant funnel-flow pattern were directly responsible for production losses and disproportionate maintenance and capital costs. Potash enters this bin at between 140°C and 165°C, but the stagnant potash outside the active flow channel was much cooler, allowing moisture to migrate toward the outer regions, which caused corrosion of the walls and reduced live capacity as the potash in this area hardened and built up on the walls over time.A 2013 inspection revealed holes and paper-thin areas in the lower cylinder wall sections and in the conical hopper. The only thing preventing major leaks and even a potentially catastrophic failure was the buildup of stagnant hardened product on the cone walls. It was concluded that the cone had reached the end of its life and required replacement. VPO’s original plan was to replace the cone in kind and repair the cylinder as necessary; however, a failure-mode and bin-performance investigation combined with a lifecycle- cost analysis indicated it would be better to redesign the hopper.For success in retrofit projects, it is essential at the design stage to consider the bulk solid flow properties and the operating environment involved. Because education in this area is not offered at a university level, engineers often do not fully appreciate the effects of the flow properties of bulk solids on bulk material handling equipment.Jenike & Johanson conducted flow properties tests on samples of potash and using the data, redesigned the bin and the feeder. After the modifications, VPO’s surge bin provides safer, more reliable operation with a much longer predicted working life. Using this retrofit as an example, we aim to provide a general understanding of bulk solids flow theory and highlight the importance of customizing the design to the appropriate flow properties in the cost effectiveness, reliability, and safety of a bulk material handling system."

Jan 1, 2016

By George H. Hope, Steve Ciccone

"The Red Dog Mine is both the largest known zinc reserve and the largest zinc producer in the world. The mine started in 1989, and by 1999 had increased production from approximately 300,000 tonnes per year (t/yr) of zinc concentrate to in excess of 900,000 t/yr. The VIP Mill Optimization Project further increased zinc concentrate production to 1.1M t/yr while improving both product quality and zinc recovery. The Mill Optimization project also addressed a number of issues related to risk reduction: power generation capacity, water treatment capacity and concentrate thickening. The project was faced with numerous challenges, the most daunting of which was the schedule. This US$105M project was executed, from conception to completion, inside of two years. Less than nine months elapsed from concept to delivery of materials and equipment to site. The project also faced a 100-day ice-free shipping window, the challenges of construction in an Arctic environment, and an extremely tight labour market for qualified craft personnel. These challenges were successfully addressed with several innovative approaches to project execution, including an Alliance contracting arrangement between the owner, engineer and contractor; full integration of the team; construction of modules in Anchorage; and fast-track engineering, procurement and construction.INTRODUCTIONThe Red Dog Mine, which began operations in 1989, is located above the Arctic Circle in Northwest Alaska, approximately 145 km north of Kotzebue (Figure 1). An 80-km road connects the mine site to the DeLong Mountain Transportation System (DMTS) port site. Red Dog is the largest known zinc deposit in the world, with known reserves totalling 94.5M tonnes, and is the largest zinc producer with a concentrate production rate of more than 1.1M t/yr.Open-pit mining is by typical drill, blast and load operation using moderately sized mining equipment. Ore is processed through conventional crushing, grinding, and flotation to produce separate lead and zinc concentrates. Filtered zinc and lead concentrates are trucked year-round to the DMTS port site, where they are stored in two A-frame buildings, 330 and 440 m long. A lightering barge system is used to transfer concentrate from the shallow water load-out to deep-sea vessels anchored approximately two miles offshore. Shipping is limited to a 100-day, ice-free window beginning in early July."

Jan 1, 2003

By A. C. Hawken, L. M. Strah

"The Report outlines the Conversion to Rubber Mill Liners and steel grinding balls from the old style Cobalt pocket liners and flint pebbles which had been used in 5'x22' Fraser-Chalmers tube mills for over fifty years. An outline of the past history and some of the plant modifications are mentioned as well.The details pertaining to considerations, modifications and repairs carried out on the mills are described. Factors influencing the rubber liner design are outlined along with the description of the rubber liner design.The performance and advantages to date are given and concludes with brief summary.HISTORYThe original amalgamation-cyanidation mill of Dome Mines Limited went into operation in 1912. Milling has been continuous since 1912, except for two periods; one of 17 months commencing in December 1917, and the other of about 12 months, when fire destroyed the plant in November 1929. Initially the capacity of the mill was 350 tons a day. In 1916 it was raised to 750 tons a day, following which there was a gradual expansion to 1,500 tons a day."

Jan 1, 1977

By Brian Hart, Zhe Chen, Liuyin Xia, Mana Pourdasht, Stamen Dimov

"Gold losses related to carbonaceous matter (CM) during processing are a significant problem in the gold processing industry. Inherent CM in gold ores can behave similarly to activated carbon in its ability to adsorb gold cyanide. This phenomenon is termed preg-robbing as the surface adsorbed gold cannot, for the most part, be recovered. Research has identified that gold adsorption by inherent CM is linked to the specific surface area, pore structure, degree of C disorder and surface functional groups. One of the strategies to inhibit CM preg-robbing prior to leaching is a chemical oxidation; a process linked to modification of the surface functionality. In this study, the variability in gold cyanide adsorption due to oxidation with different reagents has been investigated. Variability in gold cyanide adsorption by CM is examined in relation to structural and surface modifications using TOF-SIMS, XPS and Raman spectroscopy.INTRODUCTION A major obstacle for effective gold recovery during carbon in leach (CIL) or carbon in pulp (CIP) processes carbonaceous gold ores is the presence of carbonaceous matter (c-matter) which has the ability to adsorb, or preg-rob gold from the cyanide leach solution. It can be responsible for poor recoveries as the carbonaceous materials (CMs) within the ore competes with activated carbon used during the leaching and adsorption phase of processing (Cay, 2014). Preg-robbing capacity can vary significantly with mild preg-robbing ores showing absorption capacities of less than 1 g Au/t ore, while severe preg-robbing ores may have CM with the capacity to preg-rob more than 500 g Au/t ore (Dunne, 2007). Research by a number of groups have shown that the degree of C disorder has some influence on the ability of the carbonaceous material to adsorb Au(CN)2- (Miller et al, 2005, Helm et al, 2009, Hart et al, 2010). It is also apparent the adsorption characteristics of carbonaceous material is affected by changes in surface chemistry (Dimov, 2016). Various treatment including; flotation to remove the carbonaceous material (Wills, 2010), addition of surface blinding agents (for example kerosene) to passivate or blanket the carbon surfaces (Dimov, 2016), addition of strong adsorbents (eg. activated carbon or resin) to compete with the carbonaceous material and passivation or surface coating by oxidation (pressure, roasting, chlorination and biological oxidation), have been employed prior to leaching in an attempt to minimize the gold losses (Dunne, 2013)."

Jan 1, 2017

By F. Mackay, S. A. B. da Fontoura

"The theoretical solution for a viscoelastic well was presented by Gnirk and Johnson in 1964. From this an exercise was executed to validate the numerical simulation of a cemented salt well. The exercise comprised the geomechanical behavior through time of a cemented salt well, this was achieved using a finite element commercial software. This simulation showed the accuracy of the theoretical solution for viscoelastic materials such as salt rock. The theoretical solution presented elastic and viscoelastic analytic equations for the tangential and radial stresses. The equations for the elastic material (casing and cement) and for the viscoelastic material (salt rock) are presented here: Where equations 1a & 1b are the radial and tangential stresses of the elastic material; equations 2a & 2b are the radial and tangential stresses of the viscoelastic material; and a, r and b are the geometrical parameters explained in Figure 1. These equations are function of Pb, a stress time dependent factor that comes from the Burgers model of viscoelasticity. This is well explained in Gnirk and Johnson (1964) and for the sake of simplicity is not disclosed here. Po is the stress at section A-A’ dependent of the depth h."

Jan 1, 2015

By M. Pearson, L. Zunti

Pressure vessels in hydrometallurgy and many chemical process industries throughout the world require the use of specific lining systems to protect the parent vessel materials from corrosion and/or abrasion. Typically, these lining systems are required for processes that are corrosive and operate at elevated temperatures. Two basic lining system types arc: 1) refractory linings in conjunction with an impervious corrosion resistant membrane, and 2) metal-clad vessels consisting of titanium or other corrosion resistant metal bonded to a carbon steel shell. Operating conditions play a key role in selecting the type of lining system to be utilized for a specific application. Lining systems in turn have an impact on the process vessel size, which ultimately affects the capital cost of the vessel. The capital costs for each type of lining system must be considered for each application, as well as maintenance concerns, quality control, and delivery. It is clear that operating conditions play a key role in the final selection of lining systems utilized for specific projects based on initial capital cost, life-cycle maintenance costs, and overall service life. This paper will examine the fundamentals of each lining system, their inherent technical strengths and weaknesses, and present relative cost comparisons for each lining system as they apply to specific operating conditions and vessel sizes.

Jan 1, 2004

By Bruce Conard

For many years, Bruce Conard has been engaged in reading about and discussing the desired sustainability of the mining and metals resource industry. He has, however, become concerned that there is a greater issue that requires our urgent attention: what challenges do we face as a global society? His Distinguished Lecturer presentation traces the idea of environmentally sustainable economic development but concludes that a business’ interest in its sustainability is predicated on the sustainability of our global society. Conard reviews some of the most serious challenges, including population growth, clean energy supplies, freshwater availability and climate change, and calls on scientists and engineers not only to apply their skills in helping solve these challenges, but most urgently, to speak with intelligence and passion about the need to act now.

Jan 1, 2014

By C. W. Chao, M. Melashvili, F. Hilário

The processing of a bulk concentrate containing copper as chalcocite, enargite, bornite and chalcopyrite along with pyrite and precious metals of silver and gold was studied. A leaching study was undertaken to examine the application of the atmospheric acid leaching process to a bulk copper concentrate for copper recovery followed by cyanidation or thiosulfate leaching for gold and silver recovery. The extraction of copper exceeded 90% under some conditions and the recovery of gold and silver reached a maximum of 44 and 45%, respectively. A sample of bulk concentrate was roasted in air to oxidize the sulfides with release of sulfur dioxide followed by acid leaching of the roaster calcine and cyanidation of the acid leach solution. The copper extraction reached over 92% and the gold extraction exceeded 88%. The sulfur dioxide may be captured for acid production. INTRODUCTION The processing of a large primary copper deposit in Indonesia is under investigation. One of the possible routes for processing involves flotation of a bulk copper-gold concentrate followed by treatment by an atmospheric leach/SX-EW process for copper recovery. The atmospheric leach residue would then be leached for recovery of gold and silver. A second route involves roasting of the concentrate followed by acid leaching and SX-EW for copper recovery. The leach residue from the roaster calcine would then be leached for recovery of gold and silver. The roaster off-gases could be used for sulfuric acid manufacture, enabling the production of a valuable by-product. The Cobre Las Cruces (CLC) process (Munoz, Garcia, & Delgado, 2017) was designed to treat a resource of copper discovered close to Seville, Spain. The process was developed by Outotec with MK Gold (original project owner). INMET Mining subsequently purchased the deposit from MK Gold and built the copper processing facility. The CLC process is similar to the Mt. Gordon Copper process; except that OKTOP reactors have been installed instead of a low temperature, low pressure autoclave process. The plant was designed to treat 1.3 mtpa of ore at a grade of 6.2% Cu to produce 72,000 tpa of cathode copper over a 15 year project life. The main gangue mineral at Cobre Las Cruces was pyrite. The Cobre Las Cruces ore is therefore similar to a rougher flotation concentrate containing copper minerals and pyrite. The roasting of a rougher flotation concentrate can be designed to produce hematite, basic copper oxides and sulfur dioxide off gas. The acid leaching of the basic copper oxides may produce soluble copper for SX-EW recovery of copper. The sulfur dioxide off-gas may be used to make sulfuric acid.

Jan 1, 2019

The rock mass classification systems were developed for different functions, including support selection, excavation method selection and the determination of rock mass engineering properties for excavation design, among others. This explains in part why we have several rock mass classification systems. It is often cautioned that the rock mass classifications are to be used for preliminary excavation support design, but this caution is now often overlooked and detail/final support design based on the rock mass classification systems. This paper advocates differentiating between rock mass classification for pre-excavation support planning and rock mass classification for at-face excavation performance assessment. It is concluded that most at-face excavation performance problems are attributable to confusing the virgin rock mass rating with the rock mass rating on exposure during excavation, and that this observation is independent of the method of excavation. Procedures are then presented for virgin rock mass rating and for at-face rock mass rating/assessment during excavation.

May 1, 2009

By M. K. Kim

This study presents a framework for quality inspection of precast concrete components using the 3D laser scanning technique. As precast concrete-based rapid bridge construction is getting standardized, quality assessment of the precast concrete becomes critical for preventing any failures during the construction process. Moreover, as Building Information Modeling (BIM) gains popularity in the construction industry, autonomous and intelligent inspection systems are needed. Current method for quality control of precast concrete components, however, heavily relies on visual inspection and contacttype measurements, which are time and labor demanding. Also, storage and delivery systems of inspection information such as the procedures and results of quality inspection are lacking. To overcome these limitations of the current quality assessment technique for precast concrete, this study aims to develop a BIM-based framework for efficient quality inspection of precast concrete with the use of a 3D laser scanner. First, we formulate practical guidelines including detailed inspection procedure, selection of optimized scanner and scan location, inspection criteria, and data storage and delivery system. Second, to investigate the applicability of 3D laser scanning to precast concrete quality inspection based on the proposed framework, a case study inspecting quality of a lab-scale object assumed as precast concrete component is presented for detecting defects.

Aug 1, 2013

By Christoph Müller

Information exchange for mine process optimization is essential. Today, modern mining equipment uses the IREDES standard to exchange production plans and reports for easy management and storage. To gain further benefits from process optimization, a mine wide access to real-time information is needed as e.g.: The current status of a machine, operational details etc. Presently, real-time data exchange systems are developed by machine producers. Each machine producer uses its own way of gathering, managing, and storing production data. These proprietary mining processes increase the complexity of cross platform data exchange and management for mines which involves machines produced by different vendors. Casting and unifying the data requires much effort. For this purpose, ?IREDES On-line? currently is being introduced. The standard defines an open, web based method for the exchange of volatile real time machine information. Two different principles are used: Web Services for cross platform information exchange within the IT world and the optional OPC UA for use with automation and process control systems. With such a standard information from machines of different vendors may be managed by using one common platform without spending the effort for dedicated interface development. Additionally, information management and storage will become straight forward since all the data are of the same format. The IREDES On-line standard utilizes the latest IT technologies as well as the knowledge and experiences gained from the previous IREDES standard. The paper explains the benefits, the use, as well as the technical design of the standard and gives application examples from the practice.

Oct 1, 2009

By Greg Yuriy

This paper discusses research carried out by the Laurentian University Mining Automation Laboratory (LUMAL) in the field of discrete-event simulation of mine equipment systems and reliability assessment of these machinery using genetic algorithms. The AutoMod simulation package, from Brooks-PRI Automation Inc., is used in this research. It is a 3-D discrete-event simulation/animation software tool for creating realistic depictions of manufacturing and materials handling systems. Discrete-event simulation involves modeling of real-life systems based on variables and events which occur or change at distinct points in time. In our case, a two level, multi-drift sublevel stoping model was created in AutoMod for the simulation of the equipment fleet employed in the development cycle (drilling, explosives loading, blasting, materials hauling, ground support) of a typical underground mine in the nickel mining region of Sudbury in Ontario, Canada. The equipment primarily considered in the simulation is Load-Haul-Dump (LHD) vehicles (scooptrams), drills, explosives-loaders and roof bolters. The purpose of the simulation study is to assess the impact of equipment failures to mine?s production throughput. In more detail, using Mean Time Between Failures (MTBF) data of scooptrams derived from a reliability assessment model based on genetic algorithms, LHD failures are incorporated into the simulation model. These failures cause production interruptions to the development cycle and consequently loss of hauling capacity. This paper will indicate the significance of equipment failures to a mine?s production and suggest a methodology based on the combination of discrete-event simulation and a predictive reliability assessment model using genetic algorithms for the study and analysis of mine equipment systems.

May 1, 2003

By Sabine Noelte, Mikko Petteri Rantamäki, Christopher Robben, Anssi Takala, Karl-Erik Rånman

"Sensor-based ore sorting is on its way to establish as a standard option for physical separation. The increasing number of installations in coal, iron ore, industrial minerals and hard-rock metal mining segments underlines the technological and financial potential that is beginning to be untapped. The Ma’aden Phosphate installation with 1.650 t/h sensor-based ore sorter feed sets a new benchmark for the possible capacity of stationary installations. Besides stationary installations, including multiple sorters parallel in different size ranges and multiple stages, containerised semi-mobile plants are applied. These offer two advantages, first being the reduction of transport costs when applied close to the mining face. The second is that semi-mobile systems enable processing of tens of thousands of tonnes of ore in a piloting phase with an approximate duration of 0.5 to six months, verifying the results laboratory mini-bulk tests on 5–10 tonnes of sample. This is especially important for low-grade metal ores because of the inherent Fundamental Sampling Error, as well as the Grouping and Segregation Error. The paper elaborates the results achieved within the I2MINE project, treating polymetallic ore at the Boliden Concentrator in Sweden.INTRODUCTIONSensor-based ore sorting (SBS) is becoming a standard option for physical separation, applied in all segments of mineral production. The Umm Wu’al project sets the bar for stationary SBS installations with 1,650 t/h feed (TOMRA, 2015). TOMRA Sorting Solutions has finalised an agreement in cooperation with Outotec to supply Outotec-branded sorting solutions for the mining and metallurgical industry (TOMRA, 2014). Especially for low-grade hard rock metal ores, an interdisciplinary approach is necessary applying experts for all aspects of mineral production. Due to the impact on the whole process stream, it is important on the end user side to have high level managerial support and involve all disciplines to ensure that all stake holders are involved in the analysis."

Jan 1, 2016

By Hans E. Madeisky, Bruce W. Downing

The acid rock drainage (ARD) buffering capacity of mine waste is governed by its bulk chemical composition and its mineral assemblage. Conventional acid base accounting (ABA) tests can be used to predict short-term buffering, but should be used with caution to model or predict the long-term ARD buffering capacity of mine waste. ABA data for mine waste samples from four different deposit types: an orthosite-hosted magmatic sul?de nickel, dunite-hosted magmatic sul?denickel, porphyry copper-gold, and volcanic-hosted high sul?dation epithermal silver, were compared with whole-rock geochemical and petrographic data obtained from the same samples. Our objective was to devise and test a method of predicting ARD buffering capacity based on bulk chemistry and modal mineralogy. In other words, we developed a quantitative theoretical method for calculating neutralizing potential, relying on easily obtainable and relatively inexpensive whole-rock and sulfur XRF analyses, which could substitute for conventional ABA procedures in situations where these procedures are either too costly or too time consuming. For each deposit type, models were devised that reasonably approximate the net neutralization potential estimated by the ABA data obtained from laboratory tests. Once an appropriate model has been developed and tested, portable X-ray ?uorescence equipment, already used for grade control at many mine sites, could provide the whole-rock and sulfur analyses required to estimate the ARD potential of the waste material. Although this approach is not intended as a substitute for the legally mandated ABA test procedure, it could facilitate the timely and cost-effective management and mitigation of ARD at a mine site.

Jan 1, 1997

By J. D. Stinnette

Traditionally, airflow requirements for diesel equipment operating in underground environments such as mines and tunnels were determined by multiplying the vehicle power by a ventilation rate that was either mandated by regulations(s) or determined empirically from known quantities. In some cases, utilization factors were further used to adjust (reduce) the total airflow calculations for a diesel equipment fleet. However, in light of the drastic reductions to diesel equipment emissions mandated by the US EPA Tier IV and EURO Stage 4 regulations, there is currently a great deal of uncertainty in the underground mining industry among those responsible for the ventilation of planned new mines or the expansion of current mines. Tier IV engine standards mandate a reduction of DPM and NOx of approximately 95%, but can ventilation rates at mines with Tier IV equipment (or equivalent) really be reduced by a factor of twenty? This paper outlines some of the factors that affect the airflow required for the ventilation of modern diesel-powered equipment and examines how they can be applied in determining a reasonable ventilation rate for Tier IV compliant equipment operating in subterranean environments.

Aug 1, 2013

By R. Cammack

"A fundamental component of the Hoek–Brown empirical rock failure criterion is assessing an appropriate mi constant. In developing their empirical criterion Hoek and Brown normalised triaxial test results by dividing the principal stresses at failure by the uniaxial compressive strength to provide mi values for typical rock types. Experience shows that Hoek triaxial tests for individual lithology types commonly have a large inherent scatter. In addition, tests are often conducted on core from random locations, which although being of one parent rock type, display variations in density as well as minor variations in grain size and alteration.This paper presents experience from projects the authors have been involved in which large sample populations of triaxial and UCS tests on similar rock types were available. Geophysical logging data was also available for some projects. The methods used to estimate the compressive strength for each sample and the effects on normalising the data sets are described. The variability of the data and uncertainties and assumptions involved in the process of assigning a mi value from the normalised data are also discussed."

Jan 1, 2015

By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003